# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2014

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
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# 
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#  data retrieval see:
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#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
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data_llc07b

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C30 H24 Au Cl O P2'
_chemical_formula_sum            'C30 H24 Au Cl O P2'
_chemical_formula_weight         694.85

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P 21/c'
_symmetry_space_group_name_Hall  '-P 2ybc '
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   8.8665(14)
_cell_length_b                   30.022(5)
_cell_length_c                   9.8878(16)
_cell_angle_alpha                90.00
_cell_angle_beta                 96.811(2)
_cell_angle_gamma                90.00
_cell_volume                     2613.4(7)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    9996
_cell_measurement_theta_min      2.16
_cell_measurement_theta_max      27.94

_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.13
_exptl_crystal_density_meas      'not measured'
_exptl_crystal_density_diffrn    1.766
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1352
_exptl_absorpt_coefficient_mu    5.876
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.2381
_exptl_absorpt_correction_T_max  0.4660
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            29185
_diffrn_reflns_av_R_equivalents  0.0678
_diffrn_reflns_av_sigmaI/netI    0.0554
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -38
_diffrn_reflns_limit_k_max       38
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_theta_min         2.18
_diffrn_reflns_theta_max         27.00
_reflns_number_total             5702
_reflns_number_gt                4053
_reflns_threshold_expression     I>2σ(I)

_computing_data_collection       'SMART (Bruker, 1998)'
_computing_cell_refinement       'SAINT+ ver. 6.2 (Bruker, 2001)'
_computing_data_reduction        'SAINT+ ver. 6.2 (Bruker, 2001)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'


_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0300P)²+7.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5702
_refine_ls_number_parameters     316
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0691
_refine_ls_R_factor_gt           0.0348
_refine_ls_wR_factor_ref         0.0808
_refine_ls_wR_factor_gt          0.0677
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.29883(3) 0.383243(8) 0.38804(2) 0.02187(7) Uani 1 1 d . . .
Cl1 Cl 0.43084(18) 0.34040(5) 0.55203(16) 0.0299(3) Uani 1 1 d . . .
P1 P 0.17103(17) 0.42617(5) 0.22962(16) 0.0199(3) Uani 1 1 d . . .
P2 P -0.08928(17) 0.34463(5) 0.26699(16) 0.0215(3) Uani 1 1 d . . .
O1 O 0.0506(5) 0.33499(14) 0.2026(4) 0.0285(10) Uani 1 1 d . . .
C1 C -0.0271(6) 0.43756(19) 0.2546(6) 0.0188(12) Uani 1 1 d . . .
C2 C -0.1360(7) 0.40395(19) 0.2660(6) 0.0220(13) Uani 1 1 d . . .
C3 C -0.2854(7) 0.4161(2) 0.2759(6) 0.0242(13) Uani 1 1 d . . .
H3A H -0.3593 0.3934 0.2814 0.029 Uiso 1 1 calc R . .
C4 C -0.3297(7) 0.4603(2) 0.2780(6) 0.0267(14) Uani 1 1 d . . .
H4A H -0.4324 0.4678 0.2856 0.032 Uiso 1 1 calc R . .
C5 C -0.2235(7) 0.4931(2) 0.2688(6) 0.0275(14) Uani 1 1 d . . .
H5A H -0.2528 0.5235 0.2707 0.033 Uiso 1 1 calc R . .
C6 C -0.0739(7) 0.4821(2) 0.2570(6) 0.0264(14) Uani 1 1 d . . .
H6A H -0.0018 0.5052 0.2504 0.032 Uiso 1 1 calc R . .
C7 C 0.2592(6) 0.48115(19) 0.2306(6) 0.0209(13) Uani 1 1 d . . .
C8 C 0.2942(7) 0.5019(2) 0.1127(6) 0.0252(14) Uani 1 1 d . . .
H8A H 0.2676 0.4881 0.0268 0.030 Uiso 1 1 calc R . .
C9 C 0.3678(7) 0.5428(2) 0.1196(7) 0.0320(15) Uani 1 1 d . . .
H9A H 0.3918 0.5567 0.0385 0.038 Uiso 1 1 calc R . .
C10 C 0.4064(7) 0.5634(2) 0.2440(7) 0.0329(16) Uani 1 1 d . . .
H10A H 0.4557 0.5916 0.2482 0.039 Uiso 1 1 calc R . .
C11 C 0.3730(7) 0.5430(2) 0.3620(7) 0.0302(15) Uani 1 1 d . . .
H11A H 0.3995 0.5571 0.4475 0.036 Uiso 1 1 calc R . .
C12 C 0.3010(7) 0.5021(2) 0.3557(6) 0.0268(14) Uani 1 1 d . . .
H12A H 0.2797 0.4881 0.4374 0.032 Uiso 1 1 calc R . .
C13 C 0.1634(6) 0.40821(19) 0.0537(6) 0.0213(13) Uani 1 1 d . . .
C14 C 0.0400(7) 0.4186(2) -0.0399(6) 0.0267(14) Uani 1 1 d . . .
H14A H -0.0424 0.4351 -0.0120 0.032 Uiso 1 1 calc R . .
C15 C 0.0359(7) 0.4052(2) -0.1738(6) 0.0284(14) Uani 1 1 d . . .
H15A H -0.0497 0.4122 -0.2374 0.034 Uiso 1 1 calc R . .
C16 C 0.1571(7) 0.3813(2) -0.2164(6) 0.0306(14) Uani 1 1 d . . .
H16A H 0.1554 0.3725 -0.3088 0.037 Uiso 1 1 calc R . .
C17 C 0.2795(8) 0.3705(2) -0.1219(7) 0.0339(16) Uani 1 1 d . . .
H17A H 0.3620 0.3540 -0.1494 0.041 Uiso 1 1 calc R . .
C18 C 0.2825(7) 0.3838(2) 0.0124(6) 0.0287(13) Uani 1 1 d . . .
H18A H 0.3668 0.3761 0.0767 0.034 Uiso 1 1 calc R . .
C19 C -0.2553(7) 0.31840(19) 0.1780(6) 0.0238(13) Uani 1 1 d . . .
C20 C -0.2600(7) 0.3138(2) 0.0375(6) 0.0309(15) Uani 1 1 d . . .
H20A H -0.1783 0.3246 -0.0074 0.037 Uiso 1 1 calc R . .
C21 C -0.3829(8) 0.2937(2) -0.0365(7) 0.0373(17) Uani 1 1 d . . .
H21A H -0.3852 0.2908 -0.1325 0.045 Uiso 1 1 calc R . .
C22 C -0.5016(8) 0.2777(2) 0.0260(7) 0.0353(16) Uani 1 1 d . . .
H22A H -0.5849 0.2635 -0.0260 0.042 Uiso 1 1 calc R . .
C23 C -0.4995(7) 0.2824(2) 0.1658(7) 0.0347(16) Uani 1 1 d . . .
H23A H -0.5827 0.2721 0.2094 0.042 Uiso 1 1 calc R . .
C24 C -0.3757(7) 0.3023(2) 0.2418(7) 0.0300(15) Uani 1 1 d . . .
H24A H -0.3734 0.3049 0.3378 0.036 Uiso 1 1 calc R . .
C25 C -0.0748(7) 0.3257(2) 0.4422(6) 0.0233(13) Uani 1 1 d . . .
C26 C 0.0318(7) 0.2933(2) 0.4815(7) 0.0299(15) Uani 1 1 d . . .
H26A H 0.1020 0.2842 0.4215 0.036 Uiso 1 1 calc R . .
C27 C 0.0356(8) 0.2741(2) 0.6102(7) 0.0352(16) Uani 1 1 d . . .
H27A H 0.1078 0.2515 0.6374 0.042 Uiso 1 1 calc R . .
C28 C -0.0655(8) 0.2878(2) 0.6991(7) 0.0366(17) Uani 1 1 d . . .
H28A H -0.0642 0.2741 0.7859 0.044 Uiso 1 1 calc R . .
C29 C -0.1670(8) 0.3210(2) 0.6605(7) 0.0361(17) Uani 1 1 d . . .
H29A H -0.2329 0.3314 0.7228 0.043 Uiso 1 1 calc R . .
C30 C -0.1749(7) 0.3398(2) 0.5318(6) 0.0295(15) Uani 1 1 d . . .
H30A H -0.2482 0.3622 0.5049 0.035 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.2310(15) . ?
Au1 Cl1 2.2812(15) . ?
P1 C13 1.815(6) . ?
P1 C7 1.826(6) . ?
P1 C1 1.835(6) . ?
P2 O1 1.488(4) . ?
P2 C19 1.804(6) . ?
P2 C25 1.813(6) . ?
P2 C2 1.828(6) . ?
C1 C6 1.402(8) . ?
C1 C2 1.411(8) . ?
C2 C3 1.388(8) . ?
C3 C4 1.384(8) . ?
C3 H3A 0.9500 . ?
C4 C5 1.374(8) . ?
C4 H4A 0.9500 . ?
C5 C6 1.385(8) . ?
C5 H5A 0.9500 . ?
C6 H6A 0.9500 . ?
C7 C8 1.390(8) . ?
C7 C12 1.398(8) . ?
C8 C9 1.388(8) . ?
C8 H8A 0.9500 . ?
C9 C10 1.383(9) . ?
C9 H9A 0.9500 . ?
C10 C11 1.381(9) . ?
C10 H10A 0.9500 . ?
C11 C12 1.381(9) . ?
C11 H11A 0.9500 . ?
C12 H12A 0.9500 . ?
C13 C14 1.382(8) . ?
C13 C18 1.387(8) . ?
C14 C15 1.380(8) . ?
C14 H14A 0.9500 . ?
C15 C16 1.398(9) . ?
C15 H15A 0.9500 . ?
C16 C17 1.384(9) . ?
C16 H16A 0.9500 . ?
C17 C18 1.383(9) . ?
C17 H17A 0.9500 . ?
C18 H18A 0.9500 . ?
C19 C24 1.389(8) . ?
C19 C20 1.392(8) . ?
C20 C21 1.379(9) . ?
C20 H20A 0.9500 . ?
C21 C22 1.369(9) . ?
C21 H21A 0.9500 . ?
C22 C23 1.387(9) . ?
C22 H22A 0.9500 . ?
C23 C24 1.390(9) . ?
C23 H23A 0.9500 . ?
C24 H24A 0.9500 . ?
C25 C26 1.380(9) . ?
C25 C30 1.392(9) . ?
C26 C27 1.394(9) . ?
C26 H26A 0.9500 . ?
C27 C28 1.389(10) . ?
C27 H27A 0.9500 . ?
C28 C29 1.368(9) . ?
C28 H28A 0.9500 . ?
C29 C30 1.386(9) . ?
C29 H29A 0.9500 . ?
C30 H30A 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 Cl1 179.04(6) . . ?
C13 P1 C7 103.9(3) . . ?
C13 P1 C1 104.9(3) . . ?
C7 P1 C1 104.3(3) . . ?
C13 P1 Au1 117.4(2) . . ?
C7 P1 Au1 109.68(19) . . ?
C1 P1 Au1 115.33(19) . . ?
O1 P2 C19 112.3(3) . . ?
O1 P2 C25 112.3(3) . . ?
C19 P2 C25 106.9(3) . . ?
O1 P2 C2 112.8(3) . . ?
C19 P2 C2 104.6(3) . . ?
C25 P2 C2 107.5(3) . . ?
C6 C1 C2 118.3(5) . . ?
C6 C1 P1 118.0(4) . . ?
C2 C1 P1 123.6(4) . . ?
C3 C2 C1 119.1(5) . . ?
C3 C2 P2 118.2(4) . . ?
C1 C2 P2 122.7(4) . . ?
C4 C3 C2 121.8(6) . . ?
C4 C3 H3A 119.1 . . ?
C2 C3 H3A 119.1 . . ?
C5 C4 C3 119.2(6) . . ?
C5 C4 H4A 120.4 . . ?
C3 C4 H4A 120.4 . . ?
C4 C5 C6 120.4(6) . . ?
C4 C5 H5A 119.8 . . ?
C6 C5 H5A 119.8 . . ?
C5 C6 C1 121.1(6) . . ?
C5 C6 H6A 119.5 . . ?
C1 C6 H6A 119.5 . . ?
C8 C7 C12 118.6(6) . . ?
C8 C7 P1 122.6(4) . . ?
C12 C7 P1 118.7(4) . . ?
C9 C8 C7 120.4(6) . . ?
C9 C8 H8A 119.8 . . ?
C7 C8 H8A 119.8 . . ?
C10 C9 C8 120.3(6) . . ?
C10 C9 H9A 119.8 . . ?
C8 C9 H9A 119.8 . . ?
C11 C10 C9 119.8(6) . . ?
C11 C10 H10A 120.1 . . ?
C9 C10 H10A 120.1 . . ?
C10 C11 C12 120.1(6) . . ?
C10 C11 H11A 120.0 . . ?
C12 C11 H11A 120.0 . . ?
C11 C12 C7 120.8(6) . . ?
C11 C12 H12A 119.6 . . ?
C7 C12 H12A 119.6 . . ?
C14 C13 C18 119.5(6) . . ?
C14 C13 P1 120.8(4) . . ?
C18 C13 P1 119.7(5) . . ?
C15 C14 C13 120.3(6) . . ?
C15 C14 H14A 119.8 . . ?
C13 C14 H14A 119.8 . . ?
C14 C15 C16 120.3(6) . . ?
C14 C15 H15A 119.8 . . ?
C16 C15 H15A 119.8 . . ?
C17 C16 C15 119.1(6) . . ?
C17 C16 H16A 120.5 . . ?
C15 C16 H16A 120.5 . . ?
C18 C17 C16 120.3(6) . . ?
C18 C17 H17A 119.8 . . ?
C16 C17 H17A 119.8 . . ?
C17 C18 C13 120.4(6) . . ?
C17 C18 H18A 119.8 . . ?
C13 C18 H18A 119.8 . . ?
C24 C19 C20 119.1(6) . . ?
C24 C19 P2 123.8(5) . . ?
C20 C19 P2 117.1(5) . . ?
C21 C20 C19 120.1(6) . . ?
C21 C20 H20A 120.0 . . ?
C19 C20 H20A 120.0 . . ?
C22 C21 C20 121.0(6) . . ?
C22 C21 H21A 119.5 . . ?
C20 C21 H21A 119.5 . . ?
C21 C22 C23 119.6(6) . . ?
C21 C22 H22A 120.2 . . ?
C23 C22 H22A 120.2 . . ?
C22 C23 C24 119.9(6) . . ?
C22 C23 H23A 120.0 . . ?
C24 C23 H23A 120.0 . . ?
C19 C24 C23 120.2(6) . . ?
C19 C24 H24A 119.9 . . ?
C23 C24 H24A 119.9 . . ?
C26 C25 C30 120.2(6) . . ?
C26 C25 P2 117.3(5) . . ?
C30 C25 P2 122.3(5) . . ?
C25 C26 C27 119.3(6) . . ?
C25 C26 H26A 120.3 . . ?
C27 C26 H26A 120.3 . . ?
C28 C27 C26 120.5(6) . . ?
C28 C27 H27A 119.7 . . ?
C26 C27 H27A 119.7 . . ?
C29 C28 C27 119.4(6) . . ?
C29 C28 H28A 120.3 . . ?
C27 C28 H28A 120.3 . . ?
C28 C29 C30 120.9(7) . . ?
C28 C29 H29A 119.6 . . ?
C30 C29 H29A 119.6 . . ?
C29 C30 C25 119.6(6) . . ?
C29 C30 H30A 120.2 . . ?
C25 C30 H30A 120.2 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C13 P1 C1 C6 -103.7(5) . . . . ?
C7 P1 C1 C6 5.3(5) . . . . ?
Au1 P1 C1 C6 125.6(4) . . . . ?
C13 P1 C1 C2 73.7(5) . . . . ?
C7 P1 C1 C2 -177.3(5) . . . . ?
Au1 P1 C1 C2 -57.0(5) . . . . ?
C6 C1 C2 C3 1.5(9) . . . . ?
P1 C1 C2 C3 -175.9(4) . . . . ?
C6 C1 C2 P2 -179.0(4) . . . . ?
P1 C1 C2 P2 3.6(7) . . . . ?
O1 P2 C2 C3 157.1(5) . . . . ?
C19 P2 C2 C3 34.8(5) . . . . ?
C25 P2 C2 C3 -78.5(5) . . . . ?
O1 P2 C2 C1 -22.3(6) . . . . ?
C19 P2 C2 C1 -144.7(5) . . . . ?
C25 P2 C2 C1 102.0(5) . . . . ?
C1 C2 C3 C4 -1.5(9) . . . . ?
P2 C2 C3 C4 179.0(5) . . . . ?
C2 C3 C4 C5 0.6(9) . . . . ?
C3 C4 C5 C6 0.4(9) . . . . ?
C4 C5 C6 C1 -0.3(9) . . . . ?
C2 C1 C6 C5 -0.7(9) . . . . ?
P1 C1 C6 C5 176.9(5) . . . . ?
C13 P1 C7 C8 4.8(6) . . . . ?
C1 P1 C7 C8 -104.8(5) . . . . ?
Au1 P1 C7 C8 131.1(5) . . . . ?
C13 P1 C7 C12 -171.5(5) . . . . ?
C1 P1 C7 C12 78.9(5) . . . . ?
Au1 P1 C7 C12 -45.2(5) . . . . ?
C12 C7 C8 C9 -0.6(9) . . . . ?
P1 C7 C8 C9 -176.9(5) . . . . ?
C7 C8 C9 C10 -0.4(10) . . . . ?
C8 C9 C10 C11 0.7(10) . . . . ?
C9 C10 C11 C12 -0.1(10) . . . . ?
C10 C11 C12 C7 -0.9(9) . . . . ?
C8 C7 C12 C11 1.2(9) . . . . ?
P1 C7 C12 C11 177.7(5) . . . . ?
C7 P1 C13 C14 -88.7(5) . . . . ?
C1 P1 C13 C14 20.6(6) . . . . ?
Au1 P1 C13 C14 150.1(4) . . . . ?
C7 P1 C13 C18 91.3(5) . . . . ?
C1 P1 C13 C18 -159.5(5) . . . . ?
Au1 P1 C13 C18 -30.0(6) . . . . ?
C18 C13 C14 C15 -0.6(9) . . . . ?
P1 C13 C14 C15 179.4(5) . . . . ?
C13 C14 C15 C16 -0.6(10) . . . . ?
C14 C15 C16 C17 1.3(10) . . . . ?
C15 C16 C17 C18 -0.8(10) . . . . ?
C16 C17 C18 C13 -0.4(10) . . . . ?
C14 C13 C18 C17 1.1(9) . . . . ?
P1 C13 C18 C17 -178.9(5) . . . . ?
O1 P2 C19 C24 146.3(5) . . . . ?
C25 P2 C19 C24 22.7(6) . . . . ?
C2 P2 C19 C24 -91.1(6) . . . . ?
O1 P2 C19 C20 -32.9(6) . . . . ?
C25 P2 C19 C20 -156.5(5) . . . . ?
C2 P2 C19 C20 89.8(5) . . . . ?
C24 C19 C20 C21 0.1(10) . . . . ?
P2 C19 C20 C21 179.3(5) . . . . ?
C19 C20 C21 C22 -0.3(11) . . . . ?
C20 C21 C22 C23 1.0(11) . . . . ?
C21 C22 C23 C24 -1.5(11) . . . . ?
C20 C19 C24 C23 -0.7(10) . . . . ?
P2 C19 C24 C23 -179.9(5) . . . . ?
C22 C23 C24 C19 1.4(10) . . . . ?
O1 P2 C25 C26 -20.8(6) . . . . ?
C19 P2 C25 C26 102.9(5) . . . . ?
C2 P2 C25 C26 -145.4(5) . . . . ?
O1 P2 C25 C30 164.9(5) . . . . ?
C19 P2 C25 C30 -71.4(6) . . . . ?
C2 P2 C25 C30 40.3(6) . . . . ?
C30 C25 C26 C27 1.7(9) . . . . ?
P2 C25 C26 C27 -172.7(5) . . . . ?
C25 C26 C27 C28 -0.9(10) . . . . ?
C26 C27 C28 C29 -1.5(10) . . . . ?
C27 C28 C29 C30 3.0(11) . . . . ?
C28 C29 C30 C25 -2.2(10) . . . . ?
C26 C25 C30 C29 -0.2(9) . . . . ?
P2 C25 C30 C29 174.0(5) . . . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        27.00
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         0.953
_refine_diff_density_min         -1.047
_refine_diff_density_rms         0.165
_database_code_depnum_ccdc_archive 'CCDC 1013315'
