# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2014

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1032346'
_audit_update_record             
;
2014-11-03 deposited with the CCDC.
2014-12-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C20 H17 Ag3 F6 N2 O4'
_chemical_formula_weight         786.97

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.6958(6)
_cell_length_b                   10.9562(9)
_cell_length_c                   11.7739(12)
_cell_angle_alpha                104.463(8)
_cell_angle_beta                 101.053(7)
_cell_angle_gamma                93.006(6)
_cell_volume                     1181.99(17)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    2758
_cell_measurement_theta_min      3.6500
_cell_measurement_theta_max      28.6620

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.2
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.211
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             756
_exptl_absorpt_coefficient_mu    2.538
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.72083
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
; 
CrysAlisPro, Agilent Technologies,
Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET)
(compiled Dec  3 2012,18:21:49)
;
_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Sapphire3, Gemini ultra'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean 16.1903
_diffrn_standards_number         9466
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            7824
_diffrn_reflns_av_R_equivalents  0.0517
_diffrn_reflns_av_sigmaI/netI    0.0703
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_theta_min         3.01
_diffrn_reflns_theta_max         28.69
_reflns_number_total             4151
_reflns_number_gt                3651
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker FRAMBO'
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0281P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4151
_refine_ls_number_parameters     346
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0432
_refine_ls_R_factor_gt           0.0380
_refine_ls_wR_factor_ref         0.0917
_refine_ls_wR_factor_gt          0.0876
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_restrained_S_all      1.037
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.01834(3) 0.98891(3) 0.28491(3) 0.02472(12) Uani 1 1 d . . .
Ag2 Ag 0.31029(3) 1.00296(3) 0.42872(3) 0.02565(12) Uani 1 1 d . . .
Ag3 Ag 0.07179(4) 0.88480(4) 0.49296(3) 0.03195(13) Uani 1 1 d . . .
C1 C 0.1803(5) 0.9146(5) 0.0583(5) 0.0316(12) Uani 1 1 d . . .
H1 H 0.2566 0.9636 0.1144 0.038 Uiso 1 1 calc R . .
C2 C 0.1966(5) 0.8656(5) -0.0569(5) 0.0376(13) Uani 1 1 d . . .
H2 H 0.2823 0.8803 -0.0782 0.045 Uiso 1 1 calc R . .
C3 C 0.0814(6) 0.7930(5) -0.1417(5) 0.0390(13) Uani 1 1 d . . .
H3 H 0.0886 0.7593 -0.2209 0.047 Uiso 1 1 calc R . .
C4 C -0.0414(5) 0.7727(5) -0.1060(4) 0.0310(11) Uani 1 1 d . . .
H4 H -0.1188 0.7241 -0.1609 0.037 Uiso 1 1 calc R . .
C5 C -0.0514(5) 0.8247(4) 0.0131(4) 0.0209(9) Uani 1 1 d . . .
C6 C -0.1825(4) 0.8058(4) 0.0581(4) 0.0196(9) Uani 1 1 d . . .
C7 C -0.3004(5) 0.7287(5) -0.0132(4) 0.0300(11) Uani 1 1 d . . .
H7 H -0.2989 0.6842 -0.0913 0.036 Uiso 1 1 calc R . .
C8 C -0.4212(5) 0.7177(5) 0.0317(5) 0.0350(12) Uani 1 1 d . . .
H8 H -0.5016 0.6666 -0.0159 0.042 Uiso 1 1 calc R . .
C9 C -0.4203(5) 0.7839(5) 0.1480(5) 0.0349(12) Uani 1 1 d . . .
H9 H -0.5002 0.7791 0.1803 0.042 Uiso 1 1 calc R . .
C10 C -0.2982(5) 0.8571(5) 0.2153(4) 0.0277(11) Uani 1 1 d . . .
H10 H -0.2968 0.9005 0.2943 0.033 Uiso 1 1 calc R . .
C11 C 0.1341(4) 1.1251(4) 0.4395(4) 0.0241(10) Uani 1 1 d . . .
C12 C 0.1852(5) 1.2325(5) 0.4926(4) 0.0259(10) Uani 1 1 d . . .
C13 C 0.2461(5) 1.3665(5) 0.5500(4) 0.0317(11) Uani 1 1 d . . .
C14 C 0.2004(9) 1.4428(6) 0.4596(6) 0.077(3) Uani 1 1 d . . .
H14A H 0.2288 1.4051 0.3860 0.116 Uiso 1 1 calc R . .
H14B H 0.2443 1.5283 0.4915 0.116 Uiso 1 1 calc R . .
H14C H 0.0996 1.4428 0.4445 0.116 Uiso 1 1 calc R . .
C15 C 0.4074(6) 1.3706(6) 0.5799(5) 0.0519(17) Uani 1 1 d . . .
H15A H 0.4350 1.3256 0.6395 0.078 Uiso 1 1 calc R . .
H15B H 0.4484 1.4571 0.6103 0.078 Uiso 1 1 calc R . .
H15C H 0.4399 1.3316 0.5087 0.078 Uiso 1 1 calc R . .
C16 C 0.1932(6) 1.4178(5) 0.6649(5) 0.0439(14) Uani 1 1 d . . .
H16A H 0.0917 1.4086 0.6471 0.066 Uiso 1 1 calc R . .
H16B H 0.2274 1.5059 0.6981 0.066 Uiso 1 1 calc R . .
H16C H 0.2271 1.3713 0.7219 0.066 Uiso 1 1 calc R . .
C17 C 0.2091(5) 0.7299(5) 0.2756(4) 0.0290(11) Uani 1 1 d . A .
C18 C 0.2049(6) 0.6070(5) 0.1779(5) 0.0372(13) Uani 1 1 d . . .
C19 C 0.3889(5) 0.8662(4) 0.6371(4) 0.0239(10) Uani 1 1 d . . .
C20 C 0.4867(5) 0.8213(5) 0.7363(4) 0.0265(10) Uani 1 1 d . . .
F1 F 0.074(2) 0.560(2) 0.123(2) 0.127(11) Uani 0.50 1 d P A 1
F2 F 0.262(2) 0.5268(17) 0.2253(16) 0.095(8) Uani 0.50 1 d P A 1
F3 F 0.265(2) 0.626(2) 0.0932(19) 0.097(9) Uani 0.50 1 d P A 1
F1A F 0.1015(18) 0.5259(18) 0.1592(19) 0.089(8) Uani 0.50 1 d P A 2
F2A F 0.3154(18) 0.5416(19) 0.1999(16) 0.100(9) Uani 0.50 1 d P A 2
F3A F 0.215(3) 0.6211(15) 0.0725(18) 0.089(8) Uani 0.50 1 d P A 2
F4 F 0.6181(3) 0.8110(3) 0.7189(3) 0.0436(8) Uani 1 1 d . . .
F5 F 0.4999(3) 0.9057(3) 0.8426(2) 0.0368(7) Uani 1 1 d . . .
F6 F 0.4376(3) 0.7111(3) 0.7489(3) 0.0498(9) Uani 1 1 d . . .
N1 N -0.1816(4) 0.8688(3) 0.1724(3) 0.0227(8) Uani 1 1 d . . .
N2 N 0.0598(4) 0.8952(4) 0.0941(3) 0.0247(9) Uani 1 1 d . . .
O1 O 0.4498(3) 0.9327(3) 0.5859(3) 0.0265(7) Uani 1 1 d . . .
O2 O 0.2629(3) 0.8352(3) 0.6269(3) 0.0360(9) Uani 1 1 d . . .
O3 O 0.1088(4) 0.7346(3) 0.3276(3) 0.0422(9) Uani 1 1 d . . .
O4 O 0.3124(3) 0.8090(3) 0.2910(3) 0.0331(8) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C11 2.117(4) . ?
Ag1 N1 2.263(3) . ?
Ag1 N2 2.345(4) . ?
Ag1 Ag3 2.9225(6) . ?
Ag1 Ag3 2.9519(6) 2_576 ?
Ag1 Ag2 2.9816(5) . ?
Ag2 C11 2.228(5) . ?
Ag2 O4 2.333(3) . ?
Ag2 O1 2.389(3) . ?
Ag2 O1 2.445(3) 2_676 ?
Ag2 Ag3 2.9054(5) . ?
Ag3 C11 2.293(4) 2_576 ?
Ag3 O3 2.315(4) . ?
Ag3 O2 2.372(3) . ?
Ag3 Ag3 2.9302(8) 2_576 ?
Ag3 Ag1 2.9519(6) 2_576 ?
C1 N2 1.340(6) . ?
C1 C2 1.371(7) . ?
C1 H1 0.9300 . ?
C2 C3 1.400(7) . ?
C2 H2 0.9300 . ?
C3 C4 1.362(7) . ?
C3 H3 0.9300 . ?
C4 C5 1.400(6) . ?
C4 H4 0.9300 . ?
C5 N2 1.348(5) . ?
C5 C6 1.492(6) . ?
C6 N1 1.348(5) . ?
C6 C7 1.379(6) . ?
C7 C8 1.385(7) . ?
C7 H7 0.9300 . ?
C8 C9 1.379(7) . ?
C8 H8 0.9300 . ?
C9 C10 1.377(6) . ?
C9 H9 0.9300 . ?
C10 N1 1.337(6) . ?
C10 H10 0.9300 . ?
C11 C12 1.214(6) . ?
C11 Ag3 2.293(4) 2_576 ?
C12 C13 1.491(6) . ?
C13 C16 1.525(7) . ?
C13 C14 1.526(8) . ?
C13 C15 1.532(7) . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 O3 1.242(6) . ?
C17 O4 1.244(5) . ?
C17 C18 1.530(7) . ?
C18 F1A 1.252(15) . ?
C18 F2 1.252(17) . ?
C18 F3 1.300(17) . ?
C18 F3A 1.309(19) . ?
C18 F1 1.323(19) . ?
C18 F2A 1.339(17) . ?
C19 O2 1.226(5) . ?
C19 O1 1.247(5) . ?
C19 C20 1.554(6) . ?
C20 F6 1.328(5) . ?
C20 F4 1.335(5) . ?
C20 F5 1.336(5) . ?
O1 Ag2 2.445(3) 2_676 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C11 Ag1 N1 152.96(15) . . ?
C11 Ag1 N2 134.73(14) . . ?
N1 Ag1 N2 71.75(12) . . ?
C11 Ag1 Ag3 68.55(13) . . ?
N1 Ag1 Ag3 101.87(10) . . ?
N2 Ag1 Ag3 126.22(10) . . ?
C11 Ag1 Ag3 50.57(12) . 2_576 ?
N1 Ag1 Ag3 102.49(10) . 2_576 ?
N2 Ag1 Ag3 171.93(9) . 2_576 ?
Ag3 Ag1 Ag3 59.839(16) . 2_576 ?
C11 Ag1 Ag2 48.24(13) . . ?
N1 Ag1 Ag2 148.72(10) . . ?
N2 Ag1 Ag2 98.78(9) . . ?
Ag3 Ag1 Ag2 58.947(13) . . ?
Ag3 Ag1 Ag2 89.039(15) 2_576 . ?
C11 Ag2 O4 127.97(14) . . ?
C11 Ag2 O1 128.19(14) . . ?
O4 Ag2 O1 91.06(12) . . ?
C11 Ag2 O1 126.39(14) . 2_676 ?
O4 Ag2 O1 89.95(11) . 2_676 ?
O1 Ag2 O1 78.23(11) . 2_676 ?
C11 Ag2 Ag3 67.73(12) . . ?
O4 Ag2 Ag3 86.82(8) . . ?
O1 Ag2 Ag3 84.76(7) . . ?
O1 Ag2 Ag3 162.63(8) 2_676 . ?
C11 Ag2 Ag1 45.13(11) . . ?
O4 Ag2 Ag1 82.85(8) . . ?
O1 Ag2 Ag1 143.94(7) . . ?
O1 Ag2 Ag1 136.93(7) 2_676 . ?
Ag3 Ag2 Ag1 59.513(13) . . ?
C11 Ag3 O3 121.63(14) 2_576 . ?
C11 Ag3 O2 111.12(14) 2_576 . ?
O3 Ag3 O2 93.92(14) . . ?
C11 Ag3 Ag2 156.91(12) 2_576 . ?
O3 Ag3 Ag2 76.39(8) . . ?
O2 Ag3 Ag2 79.25(8) . . ?
C11 Ag3 Ag1 108.01(12) 2_576 . ?
O3 Ag3 Ag1 71.33(10) . . ?
O2 Ag3 Ag1 140.15(8) . . ?
Ag2 Ag3 Ag1 61.540(13) . . ?
C11 Ag3 Ag3 66.56(12) 2_576 2_576 ?
O3 Ag3 Ag3 130.20(11) . 2_576 ?
O2 Ag3 Ag3 131.26(9) . 2_576 ?
Ag2 Ag3 Ag3 90.945(19) . 2_576 ?
Ag1 Ag3 Ag3 60.578(16) . 2_576 ?
C11 Ag3 Ag1 45.49(11) 2_576 2_576 ?
O3 Ag3 Ag1 163.26(9) . 2_576 ?
O2 Ag3 Ag1 83.94(9) . 2_576 ?
Ag2 Ag3 Ag1 119.222(17) . 2_576 ?
Ag1 Ag3 Ag1 120.161(16) . 2_576 ?
Ag3 Ag3 Ag1 59.584(16) 2_576 2_576 ?
N2 C1 C2 123.1(4) . . ?
N2 C1 H1 118.4 . . ?
C2 C1 H1 118.4 . . ?
C1 C2 C3 118.5(4) . . ?
C1 C2 H2 120.7 . . ?
C3 C2 H2 120.7 . . ?
C4 C3 C2 118.6(5) . . ?
C4 C3 H3 120.7 . . ?
C2 C3 H3 120.7 . . ?
C3 C4 C5 120.2(4) . . ?
C3 C4 H4 119.9 . . ?
C5 C4 H4 119.9 . . ?
N2 C5 C4 120.8(4) . . ?
N2 C5 C6 116.3(4) . . ?
C4 C5 C6 122.9(4) . . ?
N1 C6 C7 121.0(4) . . ?
N1 C6 C5 116.9(3) . . ?
C7 C6 C5 122.1(4) . . ?
C6 C7 C8 119.8(4) . . ?
C6 C7 H7 120.1 . . ?
C8 C7 H7 120.1 . . ?
C9 C8 C7 118.9(4) . . ?
C9 C8 H8 120.5 . . ?
C7 C8 H8 120.5 . . ?
C10 C9 C8 118.4(4) . . ?
C10 C9 H9 120.8 . . ?
C8 C9 H9 120.8 . . ?
N1 C10 C9 123.1(4) . . ?
N1 C10 H10 118.5 . . ?
C9 C10 H10 118.5 . . ?
C12 C11 Ag1 151.9(4) . . ?
C12 C11 Ag2 107.7(3) . . ?
Ag1 C11 Ag2 86.63(17) . . ?
C12 C11 Ag3 101.3(3) . 2_576 ?
Ag1 C11 Ag3 83.94(14) . 2_576 ?
Ag2 C11 Ag3 133.9(2) . 2_576 ?
C11 C12 C13 176.2(5) . . ?
C12 C13 C16 110.1(4) . . ?
C12 C13 C14 107.4(4) . . ?
C16 C13 C14 110.9(5) . . ?
C12 C13 C15 108.5(4) . . ?
C16 C13 C15 109.6(4) . . ?
C14 C13 C15 110.3(5) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C13 C16 H16A 109.5 . . ?
C13 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C13 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
O3 C17 O4 130.1(5) . . ?
O3 C17 C18 114.6(4) . . ?
O4 C17 C18 115.3(4) . . ?
F1A C18 F2 79.5(15) . . ?
F1A C18 F3 123.1(13) . . ?
F2 C18 F3 111.8(14) . . ?
F1A C18 F3A 105.9(14) . . ?
F2 C18 F3A 125.2(12) . . ?
F3 C18 F3A 21.6(18) . . ?
F1A C18 F1 29.8(16) . . ?
F2 C18 F1 108.6(15) . . ?
F3 C18 F1 104.6(15) . . ?
F3A C18 F1 83.8(15) . . ?
F1A C18 F2A 102.8(14) . . ?
F2 C18 F2A 30.0(13) . . ?
F3 C18 F2A 83.3(14) . . ?
F3A C18 F2A 100.3(12) . . ?
F1 C18 F2A 127.1(14) . . ?
F1A C18 C17 116.9(10) . . ?
F2 C18 C17 108.8(10) . . ?
F3 C18 C17 111.3(10) . . ?
F3A C18 C17 115.4(8) . . ?
F1 C18 C17 111.6(11) . . ?
F2A C18 C17 113.5(9) . . ?
O2 C19 O1 130.7(4) . . ?
O2 C19 C20 113.7(4) . . ?
O1 C19 C20 115.4(4) . . ?
F6 C20 F4 107.6(4) . . ?
F6 C20 F5 106.6(4) . . ?
F4 C20 F5 105.5(3) . . ?
F6 C20 C19 113.2(4) . . ?
F4 C20 C19 113.4(4) . . ?
F5 C20 C19 110.1(4) . . ?
C10 N1 C6 118.8(4) . . ?
C10 N1 Ag1 122.5(3) . . ?
C6 N1 Ag1 118.7(3) . . ?
C1 N2 C5 118.7(4) . . ?
C1 N2 Ag1 125.0(3) . . ?
C5 N2 Ag1 116.1(3) . . ?
C19 O1 Ag2 118.3(3) . . ?
C19 O1 Ag2 139.1(3) . 2_676 ?
Ag2 O1 Ag2 101.77(11) . 2_676 ?
C19 O2 Ag3 126.8(3) . . ?
C17 O3 Ag3 129.8(3) . . ?
C17 O4 Ag2 115.4(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Ag1 Ag2 C11 -146.1(2) . . . . ?
N2 Ag1 Ag2 C11 144.76(19) . . . . ?
Ag3 Ag1 Ag2 C11 -88.02(17) . . . . ?
Ag3 Ag1 Ag2 C11 -33.22(17) 2_576 . . . ?
C11 Ag1 Ag2 O4 178.53(19) . . . . ?
N1 Ag1 Ag2 O4 32.4(2) . . . . ?
N2 Ag1 Ag2 O4 -36.71(13) . . . . ?
Ag3 Ag1 Ag2 O4 90.51(8) . . . . ?
Ag3 Ag1 Ag2 O4 145.31(8) 2_576 . . . ?
C11 Ag1 Ag2 O1 96.6(2) . . . . ?
N1 Ag1 Ag2 O1 -49.5(2) . . . . ?
N2 Ag1 Ag2 O1 -118.63(17) . . . . ?
Ag3 Ag1 Ag2 O1 8.59(14) . . . . ?
Ag3 Ag1 Ag2 O1 63.39(14) 2_576 . . . ?
C11 Ag1 Ag2 O1 -99.3(2) . . . 2_676 ?
N1 Ag1 Ag2 O1 114.6(2) . . . 2_676 ?
N2 Ag1 Ag2 O1 45.50(15) . . . 2_676 ?
Ag3 Ag1 Ag2 O1 172.72(12) . . . 2_676 ?
Ag3 Ag1 Ag2 O1 -132.48(12) 2_576 . . 2_676 ?
C11 Ag1 Ag2 Ag3 88.02(17) . . . . ?
N1 Ag1 Ag2 Ag3 -58.09(18) . . . . ?
N2 Ag1 Ag2 Ag3 -127.22(9) . . . . ?
Ag3 Ag1 Ag2 Ag3 54.797(18) 2_576 . . . ?
C11 Ag2 Ag3 C11 -18.1(4) . . . 2_576 ?
O4 Ag2 Ag3 C11 -151.6(3) . . . 2_576 ?
O1 Ag2 Ag3 C11 117.1(3) . . . 2_576 ?
O1 Ag2 Ag3 C11 128.8(4) 2_676 . . 2_576 ?
Ag1 Ag2 Ag3 C11 -68.0(3) . . . 2_576 ?
C11 Ag2 Ag3 O3 125.86(16) . . . . ?
O4 Ag2 Ag3 O3 -7.66(14) . . . . ?
O1 Ag2 Ag3 O3 -99.02(14) . . . . ?
O1 Ag2 Ag3 O3 -87.2(3) 2_676 . . . ?
Ag1 Ag2 Ag3 O3 75.91(11) . . . . ?
C11 Ag2 Ag3 O2 -137.39(15) . . . . ?
O4 Ag2 Ag3 O2 89.09(13) . . . . ?
O1 Ag2 Ag3 O2 -2.27(12) . . . . ?
O1 Ag2 Ag3 O2 9.5(3) 2_676 . . . ?
Ag1 Ag2 Ag3 O2 172.67(10) . . . . ?
C11 Ag2 Ag3 Ag1 49.95(12) . . . . ?
O4 Ag2 Ag3 Ag1 -83.57(9) . . . . ?
O1 Ag2 Ag3 Ag1 -174.93(8) . . . . ?
O1 Ag2 Ag3 Ag1 -163.2(3) 2_676 . . . ?
C11 Ag2 Ag3 Ag3 -5.46(12) . . . 2_576 ?
O4 Ag2 Ag3 Ag3 -138.98(9) . . . 2_576 ?
O1 Ag2 Ag3 Ag3 129.66(8) . . . 2_576 ?
O1 Ag2 Ag3 Ag3 141.4(3) 2_676 . . 2_576 ?
Ag1 Ag2 Ag3 Ag3 -55.404(17) . . . 2_576 ?
C11 Ag2 Ag3 Ag1 -60.64(12) . . . 2_576 ?
O4 Ag2 Ag3 Ag1 165.84(9) . . . 2_576 ?
O1 Ag2 Ag3 Ag1 74.48(8) . . . 2_576 ?
O1 Ag2 Ag3 Ag1 86.3(3) 2_676 . . 2_576 ?
Ag1 Ag2 Ag3 Ag1 -110.587(19) . . . 2_576 ?
C11 Ag1 Ag3 C11 104.30(14) . . . 2_576 ?
N1 Ag1 Ag3 C11 -49.25(16) . . . 2_576 ?
N2 Ag1 Ag3 C11 -125.20(16) . . . 2_576 ?
Ag3 Ag1 Ag3 C11 48.42(12) 2_576 . . 2_576 ?
Ag2 Ag1 Ag3 C11 157.52(12) . . . 2_576 ?
C11 Ag1 Ag3 O3 -137.52(15) . . . . ?
N1 Ag1 Ag3 O3 68.93(13) . . . . ?
N2 Ag1 Ag3 O3 -7.02(13) . . . . ?
Ag3 Ag1 Ag3 O3 166.60(9) 2_576 . . . ?
Ag2 Ag1 Ag3 O3 -84.30(9) . . . . ?
C11 Ag1 Ag3 O2 -64.51(19) . . . . ?
N1 Ag1 Ag3 O2 141.94(18) . . . . ?
N2 Ag1 Ag3 O2 65.99(18) . . . . ?
Ag3 Ag1 Ag3 O2 -120.39(15) 2_576 . . . ?
Ag2 Ag1 Ag3 O2 -11.29(14) . . . . ?
C11 Ag1 Ag3 Ag2 -53.22(13) . . . . ?
N1 Ag1 Ag3 Ag2 153.23(10) . . . . ?
N2 Ag1 Ag3 Ag2 77.28(10) . . . . ?
Ag3 Ag1 Ag3 Ag2 -109.102(19) 2_576 . . . ?
C11 Ag1 Ag3 Ag3 55.88(13) . . . 2_576 ?
N1 Ag1 Ag3 Ag3 -97.67(10) . . . 2_576 ?
N2 Ag1 Ag3 Ag3 -173.62(10) . . . 2_576 ?
Ag2 Ag1 Ag3 Ag3 109.102(19) . . . 2_576 ?
C11 Ag1 Ag3 Ag1 55.88(13) . . . 2_576 ?
N1 Ag1 Ag3 Ag1 -97.67(10) . . . 2_576 ?
N2 Ag1 Ag3 Ag1 -173.62(10) . . . 2_576 ?
Ag3 Ag1 Ag3 Ag1 0.0 2_576 . . 2_576 ?
Ag2 Ag1 Ag3 Ag1 109.102(19) . . . 2_576 ?
N2 C1 C2 C3 0.8(8) . . . . ?
C1 C2 C3 C4 -0.8(8) . . . . ?
C2 C3 C4 C5 0.6(8) . . . . ?
C3 C4 C5 N2 -0.1(8) . . . . ?
C3 C4 C5 C6 -179.8(5) . . . . ?
N2 C5 C6 N1 5.2(6) . . . . ?
C4 C5 C6 N1 -175.2(4) . . . . ?
N2 C5 C6 C7 -175.5(4) . . . . ?
C4 C5 C6 C7 4.2(7) . . . . ?
N1 C6 C7 C8 1.5(7) . . . . ?
C5 C6 C7 C8 -177.8(5) . . . . ?
C6 C7 C8 C9 -0.5(8) . . . . ?
C7 C8 C9 C10 -0.8(8) . . . . ?
C8 C9 C10 N1 1.3(8) . . . . ?
N1 Ag1 C11 C12 -97.1(8) . . . . ?
N2 Ag1 C11 C12 69.1(9) . . . . ?
Ag3 Ag1 C11 C12 -170.7(8) . . . . ?
Ag3 Ag1 C11 C12 -102.7(8) 2_576 . . . ?
Ag2 Ag1 C11 C12 122.4(8) . . . . ?
N1 Ag1 C11 Ag2 140.4(3) . . . . ?
N2 Ag1 C11 Ag2 -53.4(3) . . . . ?
Ag3 Ag1 C11 Ag2 66.91(11) . . . . ?
Ag3 Ag1 C11 Ag2 134.8(2) 2_576 . . . ?
N1 Ag1 C11 Ag3 5.6(4) . . . 2_576 ?
N2 Ag1 C11 Ag3 171.79(14) . . . 2_576 ?
Ag3 Ag1 C11 Ag3 -67.92(10) . . . 2_576 ?
Ag2 Ag1 C11 Ag3 -134.8(2) . . . 2_576 ?
O4 Ag2 C11 C12 -157.2(3) . . . . ?
O1 Ag2 C11 C12 72.8(4) . . . . ?
O1 Ag2 C11 C12 -32.2(4) 2_676 . . . ?
Ag3 Ag2 C11 C12 136.2(4) . . . . ?
Ag1 Ag2 C11 C12 -155.3(4) . . . . ?
O4 Ag2 C11 Ag1 -1.9(2) . . . . ?
O1 Ag2 C11 Ag1 -131.93(13) . . . . ?
O1 Ag2 C11 Ag1 123.15(13) 2_676 . . . ?
Ag3 Ag2 C11 Ag1 -68.54(11) . . . . ?
O4 Ag2 C11 Ag3 76.4(3) . . . 2_576 ?
O1 Ag2 C11 Ag3 -53.7(3) . . . 2_576 ?
O1 Ag2 C11 Ag3 -158.6(2) 2_676 . . 2_576 ?
Ag3 Ag2 C11 Ag3 9.7(2) . . . 2_576 ?
Ag1 Ag2 C11 Ag3 78.3(3) . . . 2_576 ?
Ag1 C11 C12 C13 -12(8) . . . . ?
Ag2 C11 C12 C13 106(7) . . . . ?
Ag3 C11 C12 C13 -110(7) 2_576 . . . ?
C11 C12 C13 C16 135(7) . . . . ?
C11 C12 C13 C14 14(7) . . . . ?
C11 C12 C13 C15 -105(7) . . . . ?
O3 C17 C18 F1A 1.2(14) . . . . ?
O4 C17 C18 F1A -179.2(12) . . . . ?
O3 C17 C18 F2 -86.4(12) . . . . ?
O4 C17 C18 F2 93.2(12) . . . . ?
O3 C17 C18 F3 149.9(14) . . . . ?
O4 C17 C18 F3 -30.5(15) . . . . ?
O3 C17 C18 F3A 126.8(13) . . . . ?
O4 C17 C18 F3A -53.6(14) . . . . ?
O3 C17 C18 F1 33.4(14) . . . . ?
O4 C17 C18 F1 -147.0(13) . . . . ?
O3 C17 C18 F2A -118.2(12) . . . . ?
O4 C17 C18 F2A 61.4(13) . . . . ?
O2 C19 C20 F6 33.2(6) . . . . ?
O1 C19 C20 F6 -150.5(4) . . . . ?
O2 C19 C20 F4 156.1(4) . . . . ?
O1 C19 C20 F4 -27.6(6) . . . . ?
O2 C19 C20 F5 -86.0(5) . . . . ?
O1 C19 C20 F5 90.3(5) . . . . ?
C9 C10 N1 C6 -0.3(7) . . . . ?
C9 C10 N1 Ag1 -179.7(4) . . . . ?
C7 C6 N1 C10 -1.1(7) . . . . ?
C5 C6 N1 C10 178.3(4) . . . . ?
C7 C6 N1 Ag1 178.3(3) . . . . ?
C5 C6 N1 Ag1 -2.4(5) . . . . ?
C11 Ag1 N1 C10 -11.2(6) . . . . ?
N2 Ag1 N1 C10 179.1(4) . . . . ?
Ag3 Ag1 N1 C10 54.6(4) . . . . ?
Ag3 Ag1 N1 C10 -6.8(4) 2_576 . . . ?
Ag2 Ag1 N1 C10 102.6(4) . . . . ?
C11 Ag1 N1 C6 169.5(4) . . . . ?
N2 Ag1 N1 C6 -0.2(3) . . . . ?
Ag3 Ag1 N1 C6 -124.7(3) . . . . ?
Ag3 Ag1 N1 C6 173.9(3) 2_576 . . . ?
Ag2 Ag1 N1 C6 -76.7(4) . . . . ?
C2 C1 N2 C5 -0.3(8) . . . . ?
C2 C1 N2 Ag1 -174.8(4) . . . . ?
C4 C5 N2 C1 0.0(7) . . . . ?
C6 C5 N2 C1 179.7(4) . . . . ?
C4 C5 N2 Ag1 175.0(4) . . . . ?
C6 C5 N2 Ag1 -5.3(5) . . . . ?
C11 Ag1 N2 C1 4.3(5) . . . . ?
N1 Ag1 N2 C1 177.7(4) . . . . ?
Ag3 Ag1 N2 C1 -90.7(4) . . . . ?
Ag3 Ag1 N2 C1 132.5(6) 2_576 . . . ?
Ag2 Ag1 N2 C1 -33.0(4) . . . . ?
C11 Ag1 N2 C5 -170.4(3) . . . . ?
N1 Ag1 N2 C5 3.1(3) . . . . ?
Ag3 Ag1 N2 C5 94.6(3) . . . . ?
Ag3 Ag1 N2 C5 -42.2(8) 2_576 . . . ?
Ag2 Ag1 N2 C5 152.4(3) . . . . ?
O2 C19 O1 Ag2 -5.8(7) . . . . ?
C20 C19 O1 Ag2 178.6(3) . . . . ?
O2 C19 O1 Ag2 -173.3(4) . . . 2_676 ?
C20 C19 O1 Ag2 11.1(7) . . . 2_676 ?
C11 Ag2 O1 C19 61.0(4) . . . . ?
O4 Ag2 O1 C19 -81.9(3) . . . . ?
O1 Ag2 O1 C19 -171.7(4) 2_676 . . . ?
Ag3 Ag2 O1 C19 4.8(3) . . . . ?
Ag1 Ag2 O1 C19 -2.7(4) . . . . ?
C11 Ag2 O1 Ag2 -127.38(16) . . . 2_676 ?
O4 Ag2 O1 Ag2 89.73(12) . . . 2_676 ?
O1 Ag2 O1 Ag2 0.0 2_676 . . 2_676 ?
Ag3 Ag2 O1 Ag2 176.43(10) . . . 2_676 ?
Ag1 Ag2 O1 Ag2 169.00(4) . . . 2_676 ?
O1 C19 O2 Ag3 2.7(8) . . . . ?
C20 C19 O2 Ag3 178.3(3) . . . . ?
C11 Ag3 O2 C19 -157.2(4) 2_576 . . . ?
O3 Ag3 O2 C19 76.6(4) . . . . ?
Ag2 Ag3 O2 C19 1.3(4) . . . . ?
Ag1 Ag3 O2 C19 11.4(5) . . . . ?
Ag3 Ag3 O2 C19 -80.4(4) 2_576 . . . ?
Ag1 Ag3 O2 C19 -120.0(4) 2_576 . . . ?
O4 C17 O3 Ag3 -6.7(9) . . . . ?
C18 C17 O3 Ag3 172.9(4) . . . . ?
C11 Ag3 O3 C17 175.4(4) 2_576 . . . ?
O2 Ag3 O3 C17 -66.8(5) . . . . ?
Ag2 Ag3 O3 C17 11.1(4) . . . . ?
Ag1 Ag3 O3 C17 75.3(5) . . . . ?
Ag3 Ag3 O3 C17 90.6(5) 2_576 . . . ?
Ag1 Ag3 O3 C17 -148.8(3) 2_576 . . . ?
O3 C17 O4 Ag2 -5.2(7) . . . . ?
C18 C17 O4 Ag2 175.3(4) . . . . ?
C11 Ag2 O4 C17 -48.5(4) . . . . ?
O1 Ag2 O4 C17 94.5(3) . . . . ?
O1 Ag2 O4 C17 172.7(3) 2_676 . . . ?
Ag3 Ag2 O4 C17 9.8(3) . . . . ?
Ag1 Ag2 O4 C17 -49.8(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         0.661
_refine_diff_density_min         -0.673
_refine_diff_density_rms         0.158
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1032347'
_audit_update_record             
;
2014-11-03 deposited with the CCDC.
2014-12-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C32 H25 Ag4 F9 N4 O6'
_chemical_formula_sum            'C32 H25 Ag4 F9 N4 O6'
_chemical_formula_weight         1164.04

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.2836(4)
_cell_length_b                   13.1097(8)
_cell_length_c                   17.4703(12)
_cell_angle_alpha                97.256(5)
_cell_angle_beta                 91.880(5)
_cell_angle_gamma                102.055(5)
_cell_volume                     1837.07(19)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    6790
_cell_measurement_theta_min      2.3432
_cell_measurement_theta_max      30.7307

_exptl_crystal_description       strip-like
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.07
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.104
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1124
_exptl_absorpt_coefficient_mu    2.195
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.80653
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            15859
_diffrn_reflns_av_R_equivalents  0.0371
_diffrn_reflns_av_sigmaI/netI    0.0593
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_theta_min         2.35
_diffrn_reflns_theta_max         26.00
_reflns_number_total             7012
_reflns_number_gt                4775
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'CrysAlis CCD, Oxford Diffraction Ltd'
_computing_cell_refinement       'CrysAlis RED, Oxford Diffraction Ltd'
_computing_data_reduction        'CrysAlis RED, Oxford Diffraction Ltd'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0206P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7012
_refine_ls_number_parameters     496
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0617
_refine_ls_R_factor_gt           0.0343
_refine_ls_wR_factor_ref         0.0678
_refine_ls_wR_factor_gt          0.0639
_refine_ls_goodness_of_fit_ref   1.205
_refine_ls_restrained_S_all      1.205
_refine_ls_shift/su_max          0.024
_refine_ls_shift/su_mean         0.002

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.53655(4) 0.57764(3) 0.20387(2) 0.02803(10) Uani 1 1 d . . .
Ag2 Ag 0.49858(5) 0.66041(3) 0.35977(2) 0.03281(10) Uani 1 1 d . . .
Ag3 Ag 0.25762(5) 0.68512(3) 0.24251(2) 0.03624(11) Uani 1 1 d . . .
Ag4 Ag 0.87195(5) 0.72025(3) 0.26874(2) 0.03918(11) Uani 1 1 d . . .
N1 N 0.4607(5) 0.4098(3) 0.1500(2) 0.0287(9) Uani 1 1 d . . .
N2 N 0.6721(5) 0.5598(3) 0.0882(2) 0.0331(10) Uani 1 1 d . . .
C101 C 0.3482(6) 0.3396(4) 0.1796(3) 0.0358(12) Uani 1 1 d . . .
H10A H 0.2942 0.3620 0.2224 0.043 Uiso 1 1 calc R . .
C102 C 0.3095(8) 0.2347(4) 0.1486(3) 0.0519(16) Uani 1 1 d . . .
H10B H 0.2323 0.1869 0.1709 0.062 Uiso 1 1 calc R . .
C103 C 0.3859(9) 0.2020(5) 0.0847(4) 0.0644(19) Uani 1 1 d . . .
H10C H 0.3593 0.1319 0.0624 0.077 Uiso 1 1 calc R . .
C104 C 0.5027(8) 0.2737(4) 0.0538(3) 0.0509(16) Uani 1 1 d . . .
H10D H 0.5587 0.2521 0.0116 0.061 Uiso 1 1 calc R . .
C105 C 0.5363(6) 0.3795(4) 0.0867(3) 0.0319(12) Uani 1 1 d . . .
C201 C 0.7716(6) 0.6361(4) 0.0585(3) 0.0361(13) Uani 1 1 d . . .
H20A H 0.7865 0.7047 0.0835 0.043 Uiso 1 1 calc R . .
C202 C 0.8540(6) 0.6184(5) -0.0079(3) 0.0426(14) Uani 1 1 d . . .
H20B H 0.9225 0.6739 -0.0271 0.051 Uiso 1 1 calc R . .
C203 C 0.8328(7) 0.5181(5) -0.0445(3) 0.0456(14) Uani 1 1 d . . .
H20C H 0.8875 0.5037 -0.0890 0.055 Uiso 1 1 calc R . .
C204 C 0.7285(6) 0.4380(4) -0.0144(3) 0.0379(13) Uani 1 1 d . . .
H20D H 0.7097 0.3693 -0.0395 0.045 Uiso 1 1 calc R . .
C205 C 0.6534(6) 0.4603(4) 0.0522(3) 0.0269(11) Uani 1 1 d . . .
N3 N 0.5915(5) 0.7311(3) 0.4869(2) 0.0304(9) Uani 1 1 d . . .
N4 N 0.3464(5) 0.5629(3) 0.4401(2) 0.0322(10) Uani 1 1 d . . .
C301 C 0.7132(6) 0.8172(4) 0.5065(3) 0.0400(13) Uani 1 1 d . . .
H30A H 0.7686 0.8498 0.4676 0.048 Uiso 1 1 calc R . .
C302 C 0.7581(7) 0.8585(4) 0.5829(3) 0.0436(14) Uani 1 1 d . . .
H30B H 0.8441 0.9172 0.5954 0.052 Uiso 1 1 calc R . .
C303 C 0.6743(7) 0.8120(5) 0.6392(3) 0.0485(15) Uani 1 1 d . . .
H30C H 0.7025 0.8392 0.6909 0.058 Uiso 1 1 calc R . .
C304 C 0.5496(7) 0.7260(5) 0.6205(3) 0.0444(14) Uani 1 1 d . . .
H30D H 0.4907 0.6950 0.6591 0.053 Uiso 1 1 calc R . .
C305 C 0.5100(6) 0.6841(4) 0.5422(3) 0.0308(12) Uani 1 1 d . . .
C401 C 0.2271(6) 0.4789(4) 0.4155(3) 0.0413(14) Uani 1 1 d . . .
H40A H 0.2028 0.4620 0.3625 0.050 Uiso 1 1 calc R . .
C402 C 0.1371(7) 0.4153(4) 0.4630(3) 0.0449(14) Uani 1 1 d . . .
H40B H 0.0568 0.3563 0.4429 0.054 Uiso 1 1 calc R . .
C403 C 0.1717(7) 0.4431(4) 0.5428(3) 0.0436(14) Uani 1 1 d . . .
H40C H 0.1140 0.4027 0.5773 0.052 Uiso 1 1 calc R . .
C404 C 0.2912(7) 0.5306(4) 0.5694(3) 0.0426(14) Uani 1 1 d . . .
H40D H 0.3146 0.5501 0.6223 0.051 Uiso 1 1 calc R . .
C405 C 0.3781(6) 0.5906(4) 0.5174(3) 0.0306(12) Uani 1 1 d . . .
C1 C 0.5825(6) 0.7329(4) 0.2612(3) 0.0278(11) Uani 1 1 d . . .
C2 C 0.6277(6) 0.8256(4) 0.2535(3) 0.0325(12) Uani 1 1 d . . .
C3 C 0.6646(7) 0.9383(4) 0.2414(3) 0.0449(14) Uani 1 1 d . . .
C4 C 0.6727(8) 0.9473(5) 0.1545(3) 0.0581(17) Uani 1 1 d . . .
H4A H 0.5690 0.9116 0.1280 0.087 Uiso 1 1 calc R . .
H4B H 0.7595 0.9156 0.1340 0.087 Uiso 1 1 calc R . .
H4C H 0.6945 1.0202 0.1473 0.087 Uiso 1 1 calc R . .
C5 C 0.8309(7) 0.9939(4) 0.2842(4) 0.0619(18) Uani 1 1 d . . .
H5A H 0.8256 0.9868 0.3382 0.093 Uiso 1 1 calc R . .
H5B H 0.8533 1.0672 0.2781 0.093 Uiso 1 1 calc R . .
H5C H 0.9174 0.9625 0.2632 0.093 Uiso 1 1 calc R . .
C6 C 0.5256(8) 0.9864(5) 0.2771(4) 0.0654(19) Uani 1 1 d . . .
H6A H 0.4215 0.9512 0.2508 0.098 Uiso 1 1 calc R . .
H6B H 0.5459 1.0599 0.2718 0.098 Uiso 1 1 calc R . .
H6C H 0.5227 0.9781 0.3309 0.098 Uiso 1 1 calc R . .
O11 O 1.0160(5) 0.8182(3) 0.1770(2) 0.0499(10) Uani 1 1 d . . .
O12 O 1.2406(5) 0.7657(3) 0.1328(2) 0.0442(9) Uani 1 1 d . . .
C11 C 1.1320(6) 0.8188(4) 0.1346(3) 0.0331(12) Uani 1 1 d . . .
C12 C 1.1383(7) 0.8949(5) 0.0752(4) 0.0480(15) Uani 1 1 d . . .
F11 F 1.1410(7) 0.9904(3) 0.1072(3) 0.1159(17) Uani 1 1 d . . .
F12 F 1.2647(6) 0.9031(5) 0.0338(3) 0.136(2) Uani 1 1 d . . .
F13 F 1.0049(5) 0.8745(4) 0.0289(3) 0.1043(17) Uani 1 1 d . . .
O21 O 0.2546(5) 0.7803(4) 0.3639(2) 0.0728(15) Uani 1 1 d . . .
O22 O 0.0010(5) 0.7936(4) 0.3872(2) 0.0757(15) Uani 1 1 d . . .
C21 C 0.1490(7) 0.8060(4) 0.4017(3) 0.0358(12) Uani 1 1 d . . .
C22 C 0.2107(6) 0.8632(4) 0.4846(3) 0.0335(12) Uani 1 1 d . . .
F21 F 0.3666(4) 0.9093(3) 0.4904(2) 0.0601(9) Uani 1 1 d . . .
F22 F 0.1906(4) 0.7915(2) 0.53498(17) 0.0548(9) Uani 1 1 d . . .
F23 F 0.1231(4) 0.9328(2) 0.50981(17) 0.0520(9) Uani 1 1 d . . .
O31 O 0.8480(4) 0.5343(3) 0.2607(2) 0.0412(9) Uani 1 1 d . . .
O32 O 1.1058(4) 0.5131(3) 0.23293(19) 0.0360(8) Uani 1 1 d . . .
C31 C 0.9550(7) 0.4849(4) 0.2436(3) 0.0315(12) Uani 1 1 d . . .
C32 C 0.8943(6) 0.3623(4) 0.2302(3) 0.0341(12) Uani 1 1 d . . .
F31 F 0.9809(4) 0.3159(2) 0.2744(2) 0.0635(10) Uani 1 1 d . . .
F32 F 0.9073(4) 0.3237(3) 0.15761(18) 0.0610(9) Uani 1 1 d . . .
F33 F 0.7364(4) 0.3307(2) 0.24418(18) 0.0525(8) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C1 2.104(5) . ?
Ag1 N1 2.232(4) . ?
Ag1 N2 2.353(4) . ?
Ag1 Ag2 2.8543(5) . ?
Ag1 Ag3 3.0003(6) . ?
Ag1 Ag4 3.0963(6) . ?
Ag2 C1 2.137(5) . ?
Ag2 N4 2.255(4) . ?
Ag2 N3 2.336(4) . ?
Ag2 Ag3 2.9078(5) . ?
Ag3 O12 2.317(3) 1_455 ?
Ag3 O32 2.324(3) 1_455 ?
Ag3 O21 2.325(4) . ?
Ag3 C1 2.632(5) . ?
Ag3 Ag4 3.3594(6) 1_455 ?
Ag4 O22 2.296(4) 1_655 ?
Ag4 O11 2.376(4) . ?
Ag4 O31 2.390(4) . ?
Ag4 C1 2.438(5) . ?
Ag4 C2 2.702(5) . ?
Ag4 Ag3 3.3594(6) 1_655 ?
N1 C101 1.333(6) . ?
N1 C105 1.346(6) . ?
N2 C201 1.329(6) . ?
N2 C205 1.351(6) . ?
C101 C102 1.379(7) . ?
C102 C103 1.368(9) . ?
C103 C104 1.376(9) . ?
C104 C105 1.399(7) . ?
C105 C205 1.482(7) . ?
C201 C202 1.384(7) . ?
C202 C203 1.362(8) . ?
C203 C204 1.384(8) . ?
C204 C205 1.366(7) . ?
N3 C305 1.336(6) . ?
N3 C301 1.346(6) . ?
N4 C401 1.332(6) . ?
N4 C405 1.356(6) . ?
C301 C302 1.384(7) . ?
C302 C303 1.357(8) . ?
C303 C304 1.358(8) . ?
C304 C305 1.410(7) . ?
C305 C405 1.470(7) . ?
C401 C402 1.376(8) . ?
C402 C403 1.400(7) . ?
C403 C404 1.368(8) . ?
C404 C405 1.397(7) . ?
C1 C2 1.221(6) . ?
C2 C3 1.488(7) . ?
C3 C6 1.538(8) . ?
C3 C5 1.538(8) . ?
C3 C4 1.540(8) . ?
O11 C11 1.231(6) . ?
O12 C11 1.246(6) . ?
O12 Ag3 2.316(3) 1_655 ?
C11 C12 1.523(8) . ?
C12 F12 1.287(7) . ?
C12 F13 1.309(6) . ?
C12 F11 1.300(7) . ?
O21 C21 1.192(6) . ?
O22 C21 1.216(6) . ?
O22 Ag4 2.296(4) 1_455 ?
C21 C22 1.561(7) . ?
C22 F21 1.301(5) . ?
C22 F23 1.323(5) . ?
C22 F22 1.356(6) . ?
O31 C31 1.226(6) . ?
O32 C31 1.253(6) . ?
O32 Ag3 2.324(3) 1_655 ?
C31 C32 1.566(7) . ?
C32 F32 1.320(6) . ?
C32 F31 1.321(5) . ?
C32 F33 1.328(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ag1 N1 173.39(17) . . ?
C1 Ag1 N2 113.75(17) . . ?
N1 Ag1 N2 72.28(15) . . ?
C1 Ag1 Ag2 48.20(13) . . ?
N1 Ag1 Ag2 126.86(11) . . ?
N2 Ag1 Ag2 156.17(10) . . ?
C1 Ag1 Ag3 59.01(13) . . ?
N1 Ag1 Ag3 115.31(10) . . ?
N2 Ag1 Ag3 129.91(10) . . ?
Ag2 Ag1 Ag3 59.497(13) . . ?
C1 Ag1 Ag4 51.73(12) . . ?
N1 Ag1 Ag4 133.49(10) . . ?
N2 Ag1 Ag4 84.15(9) . . ?
Ag2 Ag1 Ag4 72.215(15) . . ?
Ag3 Ag1 Ag4 110.625(16) . . ?
C1 Ag2 N4 163.46(15) . . ?
C1 Ag2 N3 123.69(16) . . ?
N4 Ag2 N3 71.60(14) . . ?
C1 Ag2 Ag1 47.21(12) . . ?
N4 Ag2 Ag1 121.96(10) . . ?
N3 Ag2 Ag1 154.79(10) . . ?
C1 Ag2 Ag3 60.63(12) . . ?
N4 Ag2 Ag3 104.13(9) . . ?
N3 Ag2 Ag3 138.73(9) . . ?
Ag1 Ag2 Ag3 62.750(14) . . ?
O12 Ag3 O32 115.01(12) 1_455 1_455 ?
O12 Ag3 O21 119.80(15) 1_455 . ?
O32 Ag3 O21 112.91(16) 1_455 . ?
O12 Ag3 C1 96.02(14) 1_455 . ?
O32 Ag3 C1 122.49(13) 1_455 . ?
O21 Ag3 C1 87.16(14) . . ?
O12 Ag3 Ag2 140.76(10) 1_455 . ?
O32 Ag3 Ag2 95.06(8) 1_455 . ?
O21 Ag3 Ag2 63.68(9) . . ?
C1 Ag3 Ag2 45.04(10) . . ?
O12 Ag3 Ag1 99.77(9) 1_455 . ?
O32 Ag3 Ag1 82.87(8) 1_455 . ?
O21 Ag3 Ag1 120.44(9) . . ?
C1 Ag3 Ag1 43.26(10) . . ?
Ag2 Ag3 Ag1 57.753(12) . . ?
O12 Ag3 Ag4 85.37(10) 1_455 1_455 ?
O32 Ag3 Ag4 77.72(8) 1_455 1_455 ?
O21 Ag3 Ag4 71.43(10) . 1_455 ?
C1 Ag3 Ag4 155.75(10) . 1_455 ?
Ag2 Ag3 Ag4 127.239(17) . 1_455 ?
Ag1 Ag3 Ag4 160.257(17) . 1_455 ?
O22 Ag4 O11 105.95(16) 1_655 . ?
O22 Ag4 O31 106.84(16) 1_655 . ?
O11 Ag4 O31 121.35(13) . . ?
O22 Ag4 C1 111.94(15) 1_655 . ?
O11 Ag4 C1 109.17(14) . . ?
O31 Ag4 C1 101.62(14) . . ?
O22 Ag4 C2 103.70(15) 1_655 . ?
O11 Ag4 C2 88.13(14) . . ?
O31 Ag4 C2 127.95(13) . . ?
C1 Ag4 C2 26.86(14) . . ?
O22 Ag4 Ag1 137.98(12) 1_655 . ?
O11 Ag4 Ag1 113.94(9) . . ?
O31 Ag4 Ag1 62.87(8) . . ?
C1 Ag4 Ag1 42.65(11) . . ?
C2 Ag4 Ag1 66.12(10) . . ?
O22 Ag4 Ag3 79.08(10) 1_655 1_655 ?
O11 Ag4 Ag3 64.94(9) . 1_655 ?
O31 Ag4 Ag3 75.40(9) . 1_655 ?
C1 Ag4 Ag3 168.90(10) . 1_655 ?
C2 Ag4 Ag3 152.27(11) . 1_655 ?
Ag1 Ag4 Ag3 129.477(16) . 1_655 ?
C101 N1 C105 119.9(5) . . ?
C101 N1 Ag1 122.3(4) . . ?
C105 N1 Ag1 117.7(3) . . ?
C201 N2 C205 118.0(4) . . ?
C201 N2 Ag1 126.5(4) . . ?
C205 N2 Ag1 115.4(3) . . ?
N1 C101 C102 121.9(5) . . ?
C103 C102 C101 119.2(6) . . ?
C102 C103 C104 119.4(6) . . ?
C103 C104 C105 119.3(6) . . ?
N1 C105 C104 120.2(5) . . ?
N1 C105 C205 118.8(4) . . ?
C104 C105 C205 121.0(5) . . ?
N2 C201 C202 123.1(5) . . ?
C203 C202 C201 118.7(5) . . ?
C202 C203 C204 118.8(5) . . ?
C205 C204 C203 119.7(5) . . ?
N2 C205 C204 121.7(5) . . ?
N2 C205 C105 115.2(4) . . ?
C204 C205 C105 122.9(5) . . ?
C305 N3 C301 119.8(4) . . ?
C305 N3 Ag2 116.0(3) . . ?
C301 N3 Ag2 124.1(3) . . ?
C401 N4 C405 118.1(5) . . ?
C401 N4 Ag2 123.3(3) . . ?
C405 N4 Ag2 118.6(3) . . ?
N3 C301 C302 121.7(5) . . ?
C303 C302 C301 118.8(5) . . ?
C302 C303 C304 120.3(5) . . ?
C303 C304 C305 119.4(5) . . ?
N3 C305 C304 120.0(5) . . ?
N3 C305 C405 117.3(4) . . ?
C304 C305 C405 122.7(5) . . ?
N4 C401 C402 124.6(5) . . ?
C401 C402 C403 117.2(5) . . ?
C404 C403 C402 119.2(5) . . ?
C403 C404 C405 120.2(5) . . ?
N4 C405 C404 120.7(5) . . ?
N4 C405 C305 116.4(4) . . ?
C404 C405 C305 122.9(5) . . ?
C2 C1 Ag1 144.7(4) . . ?
C2 C1 Ag2 130.7(4) . . ?
Ag1 C1 Ag2 84.59(18) . . ?
C2 C1 Ag4 88.7(3) . . ?
Ag1 C1 Ag4 85.61(16) . . ?
Ag2 C1 Ag4 100.07(16) . . ?
C2 C1 Ag3 107.4(3) . . ?
Ag1 C1 Ag3 77.73(14) . . ?
Ag2 C1 Ag3 74.32(15) . . ?
Ag4 C1 Ag3 162.8(2) . . ?
C1 C2 C3 174.0(5) . . ?
C1 C2 Ag4 64.4(3) . . ?
C3 C2 Ag4 121.3(3) . . ?
C2 C3 C6 106.4(5) . . ?
C2 C3 C5 109.1(4) . . ?
C6 C3 C5 109.3(5) . . ?
C2 C3 C4 110.2(5) . . ?
C6 C3 C4 111.7(5) . . ?
C5 C3 C4 109.9(5) . . ?
C11 O11 Ag4 141.3(3) . . ?
C11 O12 Ag3 113.0(3) . 1_655 ?
O11 C11 O12 129.7(5) . . ?
O11 C11 C12 113.7(5) . . ?
O12 C11 C12 116.6(5) . . ?
F12 C12 F13 108.3(6) . . ?
F12 C12 F11 105.0(5) . . ?
F13 C12 F11 102.0(5) . . ?
F12 C12 C11 115.3(5) . . ?
F13 C12 C11 113.0(5) . . ?
F11 C12 C11 112.2(5) . . ?
C21 O21 Ag3 134.4(4) . . ?
C21 O22 Ag4 123.6(4) . 1_455 ?
O21 C21 O22 131.0(5) . . ?
O21 C21 C22 114.4(5) . . ?
O22 C21 C22 114.6(5) . . ?
F21 C22 F23 108.9(4) . . ?
F21 C22 F22 106.8(4) . . ?
F23 C22 F22 105.7(4) . . ?
F21 C22 C21 113.5(5) . . ?
F23 C22 C21 112.4(4) . . ?
F22 C22 C21 109.1(4) . . ?
C31 O31 Ag4 127.1(4) . . ?
C31 O32 Ag3 126.5(3) . 1_655 ?
O31 C31 O32 132.6(5) . . ?
O31 C31 C32 115.2(5) . . ?
O32 C31 C32 112.2(4) . . ?
F32 C32 F31 107.6(4) . . ?
F32 C32 F33 105.7(4) . . ?
F31 C32 F33 107.0(4) . . ?
F32 C32 C31 111.2(4) . . ?
F31 C32 C31 111.9(4) . . ?
F33 C32 C31 113.1(4) . . ?

_diffrn_measured_fraction_theta_max 0.969
_diffrn_reflns_theta_full        26.00
_diffrn_measured_fraction_theta_full 0.969
_refine_diff_density_max         0.838
_refine_diff_density_min         -0.658
_refine_diff_density_rms         0.112
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 1032348'
_audit_update_record             
;
2014-11-03 deposited with the CCDC.
2014-12-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C63 H52 Ag6 F20 N6 O10'
_chemical_formula_weight         2080.33

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 2/C '

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   17.5532(2)
_cell_length_b                   21.0654(4)
_cell_length_c                   38.9740(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 97.5110(10)
_cell_angle_gamma                90.00
_cell_volume                     14287.6(4)
_cell_formula_units_Z            8
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    12452
_cell_measurement_theta_min      3.2925
_cell_measurement_theta_max      62.2157

_exptl_crystal_description       strip
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.04
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.934
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             8112
_exptl_absorpt_coefficient_mu    13.939
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.32767
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02) 
;
_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'Enhance (Cu) X-ray Source'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean 16.1903
_diffrn_standards_number         59826
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            32165
_diffrn_reflns_av_R_equivalents  0.0375
_diffrn_reflns_av_sigmaI/netI    0.0466
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -44
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_theta_min         3.29
_diffrn_reflns_theta_max         62.42
_reflns_number_total             11128
_reflns_number_gt                8197
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker FRAMBO'
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0689P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         11128
_refine_ls_number_parameters     970
_refine_ls_number_restraints     5
_refine_ls_R_factor_all          0.0554
_refine_ls_R_factor_gt           0.0388
_refine_ls_wR_factor_ref         0.1070
_refine_ls_wR_factor_gt          0.0993
_refine_ls_goodness_of_fit_ref   0.976
_refine_ls_restrained_S_all      0.979
_refine_ls_shift/su_max          0.078
_refine_ls_shift/su_mean         0.005

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.62602(2) 0.46226(2) 0.808428(11) 0.03309(12) Uani 1 1 d . A .
Ag2 Ag 0.74379(3) 0.54719(2) 0.820166(13) 0.04309(13) Uani 1 1 d . A .
Ag3 Ag 0.75555(3) 0.60592(2) 0.894438(13) 0.04075(13) Uani 1 1 d D . .
Ag4 Ag 0.62890(2) 0.52485(2) 0.887332(11) 0.03400(12) Uani 1 1 d . A .
Ag5 Ag 0.68796(2) 0.56269(2) 0.960273(12) 0.03904(13) Uani 1 1 d . A .
Ag6 Ag 0.73558(3) 0.42374(3) 0.874066(13) 0.04946(15) Uani 1 1 d . . .
C1 C 0.4251(4) 0.4494(3) 0.95696(15) 0.0378(15) Uani 1 1 d . . .
H1A H 0.3771 0.4305 0.9567 0.045 Uiso 1 1 calc R . .
C2 C 0.9843(6) 0.5991(6) 0.8855(3) 0.103(4) Uani 1 1 d . . .
H2A H 1.0294 0.5736 0.8913 0.154 Uiso 1 1 calc R . .
H2B H 0.9644 0.6115 0.9063 0.154 Uiso 1 1 calc R . .
H2C H 0.9972 0.6362 0.8732 0.154 Uiso 1 1 calc R . .
C3 C 0.9255(4) 0.5619(4) 0.8634(2) 0.059(2) Uani 1 1 d . . .
H3A H 0.9459 0.5486 0.8426 0.071 Uiso 1 1 calc R A .
H3B H 0.9128 0.5241 0.8757 0.071 Uiso 1 1 calc R . .
C4 C 0.8774(8) 0.7276(8) 0.9358(4) 0.081(7) Uani 0.50 1 d PD A 1
H4A H 0.9117 0.7365 0.9564 0.122 Uiso 0.50 1 calc PR A 1
H4B H 0.8375 0.7590 0.9328 0.122 Uiso 0.50 1 calc PR A 1
H4C H 0.9054 0.7285 0.9162 0.122 Uiso 0.50 1 calc PR A 1
C4A C 0.8054(8) 0.7418(5) 0.9413(3) 0.049(4) Uani 0.50 1 d PD B 2
H4AA H 0.8145 0.7607 0.9639 0.073 Uiso 0.50 1 calc PR B 2
H4AB H 0.7641 0.7636 0.9276 0.073 Uiso 0.50 1 calc PR B 2
H4AC H 0.8511 0.7448 0.9303 0.073 Uiso 0.50 1 calc PR B 2
C5 C 0.4890(4) 0.4131(3) 0.95686(15) 0.0366(14) Uani 1 1 d . . .
H5A H 0.4854 0.3691 0.9564 0.044 Uiso 1 1 calc R . .
C6 C 0.5607(4) 0.4432(3) 0.95749(15) 0.0371(14) Uani 1 1 d . . .
H6A H 0.6042 0.4181 0.9573 0.045 Uiso 1 1 calc R . .
C7 C 0.5061(3) 0.5425(3) 0.95827(14) 0.0318(13) Uani 1 1 d . A .
C8 C 0.4320(3) 0.5164(3) 0.95753(14) 0.0320(13) Uani 1 1 d . . .
C9 C 0.3666(3) 0.5573(3) 0.95742(16) 0.0400(15) Uani 1 1 d . . .
H9A H 0.3177 0.5399 0.9560 0.048 Uiso 1 1 calc R . .
C10 C 0.3755(4) 0.6210(3) 0.95940(18) 0.0445(16) Uani 1 1 d . . .
H10A H 0.3326 0.6466 0.9599 0.053 Uiso 1 1 calc R . .
C11 C 0.4491(3) 0.6495(3) 0.96075(16) 0.0372(14) Uani 1 1 d . . .
C12 C 0.5151(3) 0.6108(3) 0.96002(15) 0.0330(13) Uani 1 1 d . A .
C13 C 0.4603(4) 0.7154(3) 0.96359(19) 0.0477(17) Uani 1 1 d . . .
H13A H 0.4184 0.7421 0.9644 0.057 Uiso 1 1 calc R . .
C14 C 0.5946(4) 0.6977(3) 0.96353(18) 0.0443(16) Uani 1 1 d . . .
H14A H 0.6437 0.7147 0.9642 0.053 Uiso 1 1 calc R . .
C15 C 0.5324(4) 0.7404(3) 0.9651(2) 0.0506(18) Uani 1 1 d . . .
H15A H 0.5405 0.7839 0.9671 0.061 Uiso 1 1 calc R . .
C16 C 0.3801(3) 0.4632(3) 0.86753(15) 0.0381(15) Uani 1 1 d . . .
C17 C 0.3125(4) 0.5008(4) 0.86410(16) 0.0412(15) Uani 1 1 d . . .
H17A H 0.2649 0.4807 0.8613 0.049 Uiso 1 1 calc R . .
C18 C 0.3149(4) 0.5638(4) 0.86481(17) 0.0455(17) Uani 1 1 d . . .
H18A H 0.2693 0.5868 0.8626 0.055 Uiso 1 1 calc R . .
C19 C 0.3874(3) 0.5968(3) 0.86895(15) 0.0376(15) Uani 1 1 d . . .
C20 C 0.3926(4) 0.6631(4) 0.87013(17) 0.0442(16) Uani 1 1 d . . .
H20A H 0.3482 0.6876 0.8687 0.053 Uiso 1 1 calc R . .
C21 C 0.4643(4) 0.6923(3) 0.87347(19) 0.0483(17) Uani 1 1 d . . .
H21A H 0.4688 0.7363 0.8738 0.058 Uiso 1 1 calc R . .
C22 C 0.5288(4) 0.6538(3) 0.87633(16) 0.0378(14) Uani 1 1 d . . .
H22A H 0.5768 0.6732 0.8789 0.045 Uiso 1 1 calc R . .
C23 C 0.4560(3) 0.5625(3) 0.87205(15) 0.0332(14) Uani 1 1 d . A .
C24 C 0.4530(3) 0.4937(3) 0.87149(14) 0.0315(13) Uani 1 1 d . A .
C25 C 0.5162(4) 0.3969(3) 0.87629(15) 0.0377(14) Uani 1 1 d . . .
H25A H 0.5619 0.3740 0.8796 0.045 Uiso 1 1 calc R . .
C26 C 0.4469(4) 0.3635(3) 0.87209(16) 0.0410(15) Uani 1 1 d . . .
H26A H 0.4468 0.3193 0.8721 0.049 Uiso 1 1 calc R . .
C27 C 0.4041(4) 0.3066(3) 0.78620(16) 0.0402(15) Uani 1 1 d . . .
H27A H 0.3617 0.2798 0.7825 0.048 Uiso 1 1 calc R . .
C28 C 0.4759(4) 0.2815(3) 0.79472(17) 0.0404(15) Uani 1 1 d . . .
H28A H 0.4830 0.2379 0.7971 0.049 Uiso 1 1 calc R . .
C29 C 0.5383(4) 0.3230(3) 0.79981(17) 0.0381(14) Uani 1 1 d . . .
H29A H 0.5873 0.3061 0.8054 0.046 Uiso 1 1 calc R . .
C30 C 0.3939(3) 0.3727(3) 0.78295(15) 0.0367(14) Uani 1 1 d . . .
C31 C 0.4596(3) 0.4106(3) 0.78893(14) 0.0312(13) Uani 1 1 d . A .
C32 C 0.3212(4) 0.4020(3) 0.77367(16) 0.0401(15) Uani 1 1 d . . .
H32A H 0.2778 0.3764 0.7692 0.048 Uiso 1 1 calc R . .
C33 C 0.3132(3) 0.4643(3) 0.77123(16) 0.0392(15) Uani 1 1 d . . .
H33A H 0.2645 0.4816 0.7652 0.047 Uiso 1 1 calc R . .
C34 C 0.3782(3) 0.5057(3) 0.77777(14) 0.0317(13) Uani 1 1 d . . .
C35 C 0.4516(3) 0.4787(3) 0.78703(14) 0.0306(13) Uani 1 1 d . A .
C36 C 0.3736(4) 0.5719(3) 0.77602(15) 0.0362(14) Uani 1 1 d . . .
H36A H 0.3264 0.5914 0.7696 0.043 Uiso 1 1 calc R . .
C37 C 0.4378(4) 0.6078(3) 0.78369(16) 0.0412(15) Uani 1 1 d . . .
H37A H 0.4344 0.6519 0.7831 0.049 Uiso 1 1 calc R . .
C38 C 0.5085(4) 0.5783(3) 0.79242(15) 0.0353(14) Uani 1 1 d . . .
H38A H 0.5521 0.6034 0.7973 0.042 Uiso 1 1 calc R . .
C39 C 0.8438(4) 0.6221(3) 0.76963(19) 0.0460(17) Uani 1 1 d . . .
C40 C 0.8560(5) 0.6438(4) 0.7325(2) 0.063(2) Uani 1 1 d . . .
C41 C 0.8797(5) 0.5939(5) 0.7095(2) 0.066(2) Uani 1 1 d . . .
C42 C 0.7989(3) 0.6091(3) 1.02730(18) 0.0422(16) Uani 1 1 d . . .
C43 C 0.8238(4) 0.6076(4) 1.06682(19) 0.0496(18) Uani 1 1 d . . .
C44 C 0.8704(4) 0.5495(5) 1.0796(2) 0.060(2) Uani 1 1 d . . .
C45 C 0.7007(4) 0.6908(3) 0.8337(2) 0.052(2) Uani 1 1 d . . .
C46 C 0.6873(6) 0.7546(4) 0.8146(3) 0.077(3) Uani 1 1 d . . .
C47 C 0.3794(4) 0.3964(3) 0.86791(16) 0.0416(16) Uani 1 1 d . . .
H47A H 0.3329 0.3747 0.8653 0.050 Uiso 1 1 calc R . .
C48 C 0.7452(3) 0.4430(3) 0.81942(16) 0.0368(14) Uani 1 1 d . A .
C49 C 0.8003(4) 0.4102(3) 0.81732(17) 0.0392(15) Uani 1 1 d . A .
C50 C 0.8688(4) 0.3714(4) 0.8122(2) 0.056(2) Uani 1 1 d . . .
C51 C 0.7431(3) 0.5115(3) 0.91499(15) 0.0321(13) Uani 1 1 d . A .
C52 C 0.9263(4) 0.3707(4) 0.8460(2) 0.064(2) Uani 1 1 d . . .
H52A H 0.9031 0.3499 0.8640 0.096 Uiso 1 1 calc R . .
H52B H 0.9394 0.4135 0.8529 0.096 Uiso 1 1 calc R . .
H52C H 0.9719 0.3482 0.8421 0.096 Uiso 1 1 calc R . .
C53 C 0.9048(5) 0.4036(6) 0.7827(2) 0.082(3) Uani 1 1 d . . .
H53A H 0.8685 0.4035 0.7620 0.123 Uiso 1 1 calc R . .
H53B H 0.9502 0.3809 0.7787 0.123 Uiso 1 1 calc R . .
H53C H 0.9181 0.4466 0.7891 0.123 Uiso 1 1 calc R . .
C54 C 0.8422(6) 0.3036(4) 0.8027(2) 0.078(3) Uani 1 1 d . . .
H54A H 0.8068 0.3043 0.7818 0.117 Uiso 1 1 calc R . .
H54B H 0.8173 0.2861 0.8211 0.117 Uiso 1 1 calc R . .
H54C H 0.8859 0.2779 0.7994 0.117 Uiso 1 1 calc R . .
C55 C 0.7878(3) 0.4790(3) 0.93463(16) 0.0334(14) Uani 1 1 d . A .
C56 C 0.8437(3) 0.4427(3) 0.95917(17) 0.0408(15) Uani 1 1 d . . .
C57 C 0.7982(5) 0.4083(5) 0.9848(2) 0.069(2) Uani 1 1 d . . .
H57A H 0.7718 0.4389 0.9971 0.103 Uiso 1 1 calc R . .
H57B H 0.8330 0.3843 1.0009 0.103 Uiso 1 1 calc R . .
H57C H 0.7615 0.3801 0.9723 0.103 Uiso 1 1 calc R . .
C58 C 0.9010(4) 0.4891(4) 0.9781(2) 0.058(2) Uani 1 1 d . . .
H58A H 0.9289 0.5100 0.9617 0.087 Uiso 1 1 calc R . .
H58B H 0.9363 0.4665 0.9946 0.087 Uiso 1 1 calc R . .
H58C H 0.8740 0.5202 0.9899 0.087 Uiso 1 1 calc R . .
C59 C 0.6201(8) 0.7825(7) 0.8146(4) 0.122(6) Uani 1 1 d . . .
C60 C 0.8869(4) 0.3952(4) 0.9393(2) 0.0544(19) Uani 1 1 d . . .
H60A H 0.9148 0.4175 0.9235 0.082 Uiso 1 1 calc R . .
H60B H 0.8509 0.3667 0.9267 0.082 Uiso 1 1 calc R . .
H60C H 0.9221 0.3714 0.9554 0.082 Uiso 1 1 calc R . .
C61 C 0.7176(4) 0.2900(4) 0.8996(2) 0.0523(19) Uani 1 1 d . . .
C62 C 0.6698(8) 0.2344(5) 0.9093(5) 0.131(6) Uani 1 1 d . . .
C63 C 0.6319(8) 0.2374(5) 0.9384(3) 0.100(4) Uani 1 1 d . . .
F1 F 0.8930(3) 0.5533(3) 1.11343(12) 0.0864(17) Uani 1 1 d . . .
F2 F 0.8315(3) 0.4966(2) 1.07404(13) 0.0728(13) Uani 1 1 d . . .
F3 F 0.9327(3) 0.5458(4) 1.06389(14) 0.0902(18) Uani 1 1 d . . .
F4 F 0.7609(2) 0.6078(2) 1.08395(10) 0.0583(11) Uani 1 1 d . . .
F5 F 0.8651(3) 0.6601(3) 1.07749(11) 0.0721(14) Uani 1 1 d . . .
F6 F 0.8985(4) 0.6199(4) 0.67980(15) 0.116(3) Uani 1 1 d . . .
F7 F 0.8266(4) 0.5520(3) 0.70006(14) 0.097(2) Uani 1 1 d . . .
F8 F 0.9067(5) 0.6915(3) 0.73350(16) 0.147(4) Uani 1 1 d . . .
F9 F 0.7868(4) 0.6675(4) 0.71565(17) 0.120(3) Uani 1 1 d . . .
F10 F 0.7013(4) 0.7509(3) 0.78037(13) 0.0877(17) Uani 1 1 d . . .
F11 F 0.7419(3) 0.8007(3) 0.82880(16) 0.0949(19) Uani 1 1 d . . .
F12 F 0.9408(4) 0.5646(4) 0.72423(19) 0.124(3) Uani 1 1 d . . .
F13 F 0.6112(4) 0.8412(3) 0.7998(2) 0.123(3) Uani 1 1 d . . .
F14 F 0.6069(4) 0.7939(3) 0.84957(15) 0.0905(18) Uani 1 1 d . . .
F15 F 0.5633(3) 0.7433(3) 0.7988(2) 0.120(3) Uani 1 1 d . . .
F16 F 0.5883(6) 0.2386(4) 0.8878(3) 0.229(7) Uani 1 1 d . . .
F17 F 0.6976(4) 0.1784(2) 0.9047(2) 0.107(2) Uani 1 1 d . . .
F18 F 0.7155(5) 0.2372(4) 0.96142(16) 0.129(3) Uani 1 1 d . . .
F19 F 0.5962(4) 0.2853(3) 0.9475(2) 0.123(3) Uani 1 1 d . . .
F20 F 0.5968(3) 0.1843(3) 0.94699(17) 0.0943(18) Uani 1 1 d . . .
N1 N 0.5870(3) 0.6356(2) 0.96113(13) 0.0347(11) Uani 1 1 d . . .
N2 N 0.5692(3) 0.5055(2) 0.95839(12) 0.0317(11) Uani 1 1 d . . .
N3 N 0.5260(3) 0.5907(2) 0.87560(13) 0.0325(11) Uani 1 1 d . . .
N4 N 0.5198(3) 0.4599(2) 0.87579(12) 0.0307(11) Uani 1 1 d . . .
N5 N 0.5307(3) 0.3856(2) 0.79704(12) 0.0304(11) Uani 1 1 d . . .
N6 N 0.5158(3) 0.5158(2) 0.79405(12) 0.0318(11) Uani 1 1 d . . .
O1 O 0.7467(2) 0.5712(2) 1.01714(12) 0.0444(11) Uani 1 1 d . . .
O2 O 0.8422(9) 0.6629(8) 0.9386(3) 0.105(6) Uani 0.50 1 d PD A 1
O2A O 0.7847(5) 0.6746(4) 0.9446(2) 0.038(2) Uani 0.50 1 d PD B 2
H101 H 0.817(2) 0.653(3) 0.9520(14) 0.046 Uiso 1 1 d D . .
O3 O 0.8355(3) 0.6458(3) 1.01082(12) 0.0573(14) Uani 1 1 d . . .
O4 O 0.8025(3) 0.5747(2) 0.76909(12) 0.0528(13) Uani 1 1 d . . .
O5 O 0.8731(3) 0.6549(2) 0.79369(13) 0.0538(13) Uani 1 1 d . . .
O6 O 0.6837(3) 0.6439(3) 0.81534(16) 0.0589(14) Uani 1 1 d . A .
O7 O 0.7260(3) 0.6948(2) 0.86483(14) 0.0554(13) Uani 1 1 d . A .
O8 O 0.6865(3) 0.3429(2) 0.90289(15) 0.0548(13) Uani 1 1 d . A .
O9 O 0.7762(3) 0.2771(3) 0.88769(19) 0.0796(19) Uani 1 1 d . A .
O10 O 0.8580(3) 0.5988(2) 0.85420(13) 0.0436(11) Uani 1 1 d . A .
H100 H 0.860(5) 0.616(4) 0.838(2) 0.052 Uiso 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C48 2.119(6) . ?
Ag1 N6 2.246(5) . ?
Ag1 N5 2.325(5) . ?
Ag1 Ag2 2.7270(6) . ?
Ag1 Ag6 3.1009(7) . ?
Ag1 Ag4 3.3403(6) . ?
Ag2 C48 2.194(7) . ?
Ag2 O6 2.290(5) . ?
Ag2 O4 2.428(5) . ?
Ag2 O10 2.504(5) . ?
Ag2 Ag3 3.1299(7) . ?
Ag2 Ag6 3.3580(7) . ?
Ag3 C51 2.166(6) . ?
Ag3 O7 2.225(5) . ?
Ag3 O2A 2.431(9) . ?
Ag3 O2 2.456(8) . ?
Ag3 O10 2.541(4) . ?
Ag3 Ag4 2.7884(6) . ?
Ag3 Ag5 3.1011(6) . ?
Ag4 C51 2.166(6) . ?
Ag4 N3 2.276(5) . ?
Ag4 N4 2.349(5) . ?
Ag4 Ag6 2.9266(6) . ?
Ag4 Ag5 3.0035(7) . ?
Ag5 O1 2.326(5) . ?
Ag5 N1 2.348(5) . ?
Ag5 C51 2.379(6) . ?
Ag5 N2 2.401(5) . ?
Ag6 C48 2.196(6) . ?
Ag6 O8 2.271(5) . ?
Ag6 C51 2.434(6) . ?
Ag6 C49 2.631(6) . ?
Ag6 C55 2.683(6) . ?
C1 C5 1.358(10) . ?
C1 C8 1.417(10) . ?
C2 C3 1.479(13) . ?
C3 O10 1.423(9) . ?
C4 O2 1.506(10) . ?
C4A O2A 1.471(9) . ?
C5 C6 1.407(9) . ?
C6 N2 1.320(9) . ?
C7 N2 1.353(8) . ?
C7 C8 1.409(8) . ?
C7 C12 1.449(9) . ?
C8 C9 1.435(9) . ?
C9 C10 1.351(10) . ?
C10 C11 1.419(9) . ?
C11 C13 1.403(10) . ?
C11 C12 1.419(9) . ?
C12 N1 1.361(8) . ?
C13 C15 1.365(10) . ?
C14 N1 1.318(9) . ?
C14 C15 1.422(10) . ?
C16 C47 1.407(10) . ?
C16 C17 1.418(10) . ?
C16 C24 1.423(9) . ?
C17 C18 1.327(11) . ?
C18 C19 1.442(10) . ?
C19 C23 1.395(9) . ?
C19 C20 1.399(10) . ?
C20 C21 1.391(10) . ?
C21 C22 1.385(9) . ?
C22 N3 1.329(8) . ?
C23 N3 1.355(8) . ?
C23 C24 1.451(9) . ?
C24 N4 1.363(8) . ?
C25 N4 1.329(9) . ?
C25 C26 1.395(9) . ?
C26 C47 1.365(10) . ?
C27 C28 1.367(10) . ?
C27 C30 1.407(10) . ?
C28 C29 1.395(9) . ?
C29 N5 1.329(8) . ?
C30 C31 1.396(9) . ?
C30 C32 1.422(9) . ?
C31 N5 1.353(8) . ?
C31 C35 1.443(9) . ?
C32 C33 1.324(10) . ?
C33 C34 1.431(9) . ?
C34 C36 1.398(9) . ?
C34 C35 1.411(9) . ?
C35 N6 1.370(8) . ?
C36 C37 1.357(9) . ?
C37 C38 1.390(9) . ?
C38 N6 1.324(8) . ?
C39 O5 1.223(9) . ?
C39 O4 1.233(9) . ?
C39 C40 1.558(11) . ?
C40 F8 1.340(10) . ?
C40 F9 1.396(11) . ?
C40 C41 1.478(13) . ?
C41 F7 1.301(10) . ?
C41 F12 1.304(12) . ?
C41 F6 1.359(11) . ?
C42 O3 1.235(8) . ?
C42 O1 1.242(8) . ?
C42 C43 1.546(10) . ?
C43 F5 1.357(9) . ?
C43 F4 1.364(8) . ?
C43 C44 1.519(12) . ?
C44 F2 1.309(10) . ?
C44 F3 1.324(9) . ?
C44 F1 1.328(10) . ?
C45 O6 1.233(10) . ?
C45 O7 1.240(10) . ?
C45 C46 1.540(11) . ?
C46 C59 1.319(15) . ?
C46 F10 1.390(11) . ?
C46 F11 1.423(12) . ?
C48 C49 1.201(9) . ?
C49 C50 1.489(9) . ?
C50 C54 1.533(13) . ?
C50 C53 1.538(12) . ?
C50 C52 1.553(11) . ?
C51 C55 1.231(9) . ?
C55 C56 1.488(9) . ?
C56 C58 1.523(10) . ?
C56 C60 1.526(10) . ?
C56 C57 1.538(11) . ?
C59 F13 1.365(13) . ?
C59 F15 1.376(18) . ?
C59 F14 1.431(16) . ?
C61 O9 1.213(9) . ?
C61 O8 1.255(9) . ?
C61 C62 1.517(13) . ?
C62 F17 1.298(12) . ?
C62 C63 1.388(17) . ?
C62 F16 1.564(18) . ?
C63 F19 1.263(13) . ?
C63 F20 1.341(12) . ?
C63 F18 1.619(16) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C48 Ag1 N6 160.3(2) . . ?
C48 Ag1 N5 124.9(2) . . ?
N6 Ag1 N5 74.14(18) . . ?
C48 Ag1 Ag2 52.02(18) . . ?
N6 Ag1 Ag2 108.75(13) . . ?
N5 Ag1 Ag2 176.50(12) . . ?
C48 Ag1 Ag6 45.06(17) . . ?
N6 Ag1 Ag6 139.31(12) . . ?
N5 Ag1 Ag6 109.20(12) . . ?
Ag2 Ag1 Ag6 70.030(18) . . ?
C48 Ag1 Ag4 89.63(17) . . ?
N6 Ag1 Ag4 86.57(12) . . ?
N5 Ag1 Ag4 111.95(11) . . ?
Ag2 Ag1 Ag4 70.528(16) . . ?
Ag6 Ag1 Ag4 53.891(13) . . ?
C48 Ag2 O6 153.4(2) . . ?
C48 Ag2 O4 102.8(2) . . ?
O6 Ag2 O4 87.7(2) . . ?
C48 Ag2 O10 115.6(2) . . ?
O6 Ag2 O10 89.17(17) . . ?
O4 Ag2 O10 86.24(16) . . ?
C48 Ag2 Ag1 49.58(16) . . ?
O6 Ag2 Ag1 103.83(12) . . ?
O4 Ag2 Ag1 114.37(11) . . ?
O10 Ag2 Ag1 155.64(12) . . ?
C48 Ag2 Ag3 114.08(16) . . ?
O6 Ag2 Ag3 72.44(15) . . ?
O4 Ag2 Ag3 132.85(11) . . ?
O10 Ag2 Ag3 52.18(10) . . ?
Ag1 Ag2 Ag3 111.80(2) . . ?
C48 Ag2 Ag6 40.13(16) . . ?
O6 Ag2 Ag6 133.10(15) . . ?
O4 Ag2 Ag6 139.05(13) . . ?
O10 Ag2 Ag6 95.84(12) . . ?
Ag1 Ag2 Ag6 60.217(16) . . ?
Ag3 Ag2 Ag6 74.373(17) . . ?
C51 Ag3 O7 159.5(2) . . ?
C51 Ag3 O2A 105.7(3) . . ?
O7 Ag3 O2A 85.8(3) . . ?
C51 Ag3 O2 105.8(4) . . ?
O7 Ag3 O2 91.9(4) . . ?
O2A Ag3 O2 25.8(4) . . ?
C51 Ag3 O10 106.75(18) . . ?
O7 Ag3 O10 82.27(17) . . ?
O2A Ag3 O10 116.1(2) . . ?
O2 Ag3 O10 92.2(4) . . ?
C51 Ag3 Ag4 49.95(16) . . ?
O7 Ag3 Ag4 109.56(15) . . ?
O2A Ag3 Ag4 121.7(2) . . ?
O2 Ag3 Ag4 141.4(3) . . ?
O10 Ag3 Ag4 121.48(12) . . ?
C51 Ag3 Ag5 49.92(15) . . ?
O7 Ag3 Ag5 125.99(13) . . ?
O2A Ag3 Ag5 64.71(19) . . ?
O2 Ag3 Ag5 80.4(3) . . ?
O10 Ag3 Ag5 150.66(12) . . ?
Ag4 Ag3 Ag5 61.052(15) . . ?
C51 Ag3 Ag2 88.94(16) . . ?
O7 Ag3 Ag2 82.54(14) . . ?
O2A Ag3 Ag2 163.74(19) . . ?
O2 Ag3 Ag2 143.2(4) . . ?
O10 Ag3 Ag2 51.12(12) . . ?
Ag4 Ag3 Ag2 73.182(17) . . ?
Ag5 Ag3 Ag2 131.53(2) . . ?
C51 Ag4 N3 146.8(2) . . ?
C51 Ag4 N4 134.3(2) . . ?
N3 Ag4 N4 73.20(18) . . ?
C51 Ag4 Ag3 49.92(16) . . ?
N3 Ag4 Ag3 104.35(13) . . ?
N4 Ag4 Ag3 174.48(11) . . ?
C51 Ag4 Ag6 54.68(16) . . ?
N3 Ag4 Ag6 156.57(13) . . ?
N4 Ag4 Ag6 93.83(12) . . ?
Ag3 Ag4 Ag6 86.733(19) . . ?
C51 Ag4 Ag5 51.76(15) . . ?
N3 Ag4 Ag5 101.24(13) . . ?
N4 Ag4 Ag5 120.51(11) . . ?
Ag3 Ag4 Ag5 64.619(16) . . ?
Ag6 Ag4 Ag5 102.164(18) . . ?
C51 Ag4 Ag1 107.98(15) . . ?
N3 Ag4 Ag1 98.03(13) . . ?
N4 Ag4 Ag1 71.34(11) . . ?
Ag3 Ag4 Ag1 104.426(17) . . ?
Ag6 Ag4 Ag1 58.872(15) . . ?
Ag5 Ag4 Ag1 159.710(18) . . ?
O1 Ag5 N1 100.19(17) . . ?
O1 Ag5 C51 124.72(19) . . ?
N1 Ag5 C51 133.45(19) . . ?
O1 Ag5 N2 110.04(15) . . ?
N1 Ag5 N2 71.03(17) . . ?
C51 Ag5 N2 100.69(18) . . ?
O1 Ag5 Ag4 167.85(12) . . ?
N1 Ag5 Ag4 91.11(12) . . ?
C51 Ag5 Ag4 45.67(15) . . ?
N2 Ag5 Ag4 69.32(11) . . ?
O1 Ag5 Ag3 126.59(10) . . ?
N1 Ag5 Ag3 101.00(12) . . ?
C51 Ag5 Ag3 44.16(14) . . ?
N2 Ag5 Ag3 123.14(11) . . ?
Ag4 Ag5 Ag3 54.329(15) . . ?
C48 Ag6 O8 134.5(2) . . ?
C48 Ag6 C51 119.4(2) . . ?
O8 Ag6 C51 103.71(19) . . ?
C48 Ag6 C49 26.9(2) . . ?
O8 Ag6 C49 124.6(2) . . ?
C51 Ag6 C49 129.9(2) . . ?
C48 Ag6 C55 135.4(2) . . ?
O8 Ag6 C55 89.88(19) . . ?
C51 Ag6 C55 27.3(2) . . ?
C49 Ag6 C55 130.63(19) . . ?
C48 Ag6 Ag4 99.71(17) . . ?
O8 Ag6 Ag4 99.53(12) . . ?
C51 Ag6 Ag4 46.56(14) . . ?
C49 Ag6 Ag4 125.73(14) . . ?
C55 Ag6 Ag4 71.45(13) . . ?
C48 Ag6 Ag1 43.09(16) . . ?
O8 Ag6 Ag1 111.72(14) . . ?
C51 Ag6 Ag1 108.44(14) . . ?
C49 Ag6 Ag1 67.93(14) . . ?
C55 Ag6 Ag1 135.73(14) . . ?
Ag4 Ag6 Ag1 67.237(16) . . ?
C48 Ag6 Ag2 40.09(17) . . ?
O8 Ag6 Ag2 160.11(13) . . ?
C51 Ag6 Ag2 79.55(14) . . ?
C49 Ag6 Ag2 59.96(15) . . ?
C55 Ag6 Ag2 100.19(13) . . ?
Ag4 Ag6 Ag2 68.136(16) . . ?
Ag1 Ag6 Ag2 49.754(14) . . ?
C5 C1 C8 119.4(6) . . ?
O10 C3 C2 110.6(8) . . ?
C1 C5 C6 119.0(6) . . ?
N2 C6 C5 123.1(6) . . ?
N2 C7 C8 121.9(6) . . ?
N2 C7 C12 119.3(5) . . ?
C8 C7 C12 118.8(6) . . ?
C7 C8 C1 117.8(6) . . ?
C7 C8 C9 120.1(6) . . ?
C1 C8 C9 122.1(5) . . ?
C10 C9 C8 120.6(6) . . ?
C9 C10 C11 121.4(6) . . ?
C13 C11 C12 117.6(6) . . ?
C13 C11 C10 122.6(6) . . ?
C12 C11 C10 119.8(6) . . ?
N1 C12 C11 122.4(6) . . ?
N1 C12 C7 118.4(5) . . ?
C11 C12 C7 119.2(5) . . ?
C15 C13 C11 120.3(6) . . ?
N1 C14 C15 124.0(6) . . ?
C13 C15 C14 117.8(7) . . ?
C47 C16 C17 123.5(6) . . ?
C47 C16 C24 117.3(6) . . ?
C17 C16 C24 119.2(6) . . ?
C18 C17 C16 122.1(6) . . ?
C17 C18 C19 120.7(6) . . ?
C23 C19 C20 117.5(6) . . ?
C23 C19 C18 119.9(6) . . ?
C20 C19 C18 122.6(6) . . ?
C21 C20 C19 119.9(6) . . ?
C22 C21 C20 118.0(6) . . ?
N3 C22 C21 123.8(6) . . ?
N3 C23 C19 122.8(6) . . ?
N3 C23 C24 118.1(5) . . ?
C19 C23 C24 119.1(6) . . ?
N4 C24 C16 121.7(6) . . ?
N4 C24 C23 119.4(5) . . ?
C16 C24 C23 118.9(5) . . ?
N4 C25 C26 123.0(6) . . ?
C47 C26 C25 119.1(6) . . ?
C28 C27 C30 120.4(6) . . ?
C27 C28 C29 118.3(6) . . ?
N5 C29 C28 122.8(6) . . ?
C31 C30 C27 117.3(6) . . ?
C31 C30 C32 119.3(6) . . ?
C27 C30 C32 123.4(6) . . ?
N5 C31 C30 122.2(6) . . ?
N5 C31 C35 118.6(5) . . ?
C30 C31 C35 119.2(6) . . ?
C33 C32 C30 122.1(6) . . ?
C32 C33 C34 121.1(6) . . ?
C36 C34 C35 117.3(5) . . ?
C36 C34 C33 124.0(6) . . ?
C35 C34 C33 118.7(6) . . ?
N6 C35 C34 121.4(6) . . ?
N6 C35 C31 119.0(5) . . ?
C34 C35 C31 119.6(5) . . ?
C37 C36 C34 120.3(6) . . ?
C36 C37 C38 119.6(6) . . ?
N6 C38 C37 122.3(6) . . ?
O5 C39 O4 131.2(7) . . ?
O5 C39 C40 116.8(6) . . ?
O4 C39 C40 111.9(7) . . ?
F8 C40 F9 106.3(8) . . ?
F8 C40 C41 108.2(7) . . ?
F9 C40 C41 105.4(7) . . ?
F8 C40 C39 111.4(7) . . ?
F9 C40 C39 109.0(6) . . ?
C41 C40 C39 116.0(8) . . ?
F7 C41 F12 108.7(10) . . ?
F7 C41 F6 106.1(7) . . ?
F12 C41 F6 106.7(7) . . ?
F7 C41 C40 114.0(7) . . ?
F12 C41 C40 110.5(8) . . ?
F6 C41 C40 110.4(9) . . ?
O3 C42 O1 130.4(7) . . ?
O3 C42 C43 115.6(6) . . ?
O1 C42 C43 113.9(6) . . ?
F5 C43 F4 106.4(6) . . ?
F5 C43 C44 108.2(6) . . ?
F4 C43 C44 106.1(6) . . ?
F5 C43 C42 111.0(6) . . ?
F4 C43 C42 110.3(6) . . ?
C44 C43 C42 114.4(6) . . ?
F2 C44 F3 108.5(8) . . ?
F2 C44 F1 107.3(7) . . ?
F3 C44 F1 107.8(6) . . ?
F2 C44 C43 112.6(6) . . ?
F3 C44 C43 109.7(7) . . ?
F1 C44 C43 110.8(8) . . ?
O6 C45 O7 130.6(7) . . ?
O6 C45 C46 114.3(8) . . ?
O7 C45 C46 115.2(8) . . ?
C59 C46 F10 107.2(10) . . ?
C59 C46 F11 104.7(11) . . ?
F10 C46 F11 102.5(8) . . ?
C59 C46 C45 118.0(9) . . ?
F10 C46 C45 112.3(8) . . ?
F11 C46 C45 110.8(8) . . ?
C26 C47 C16 120.2(6) . . ?
C49 C48 Ag1 151.5(6) . . ?
C49 C48 Ag2 126.0(5) . . ?
Ag1 C48 Ag2 78.4(2) . . ?
C49 C48 Ag6 97.2(5) . . ?
Ag1 C48 Ag6 91.9(2) . . ?
Ag2 C48 Ag6 99.8(3) . . ?
C48 C49 C50 175.9(7) . . ?
C48 C49 Ag6 55.9(4) . . ?
C50 C49 Ag6 128.1(5) . . ?
C49 C50 C54 108.6(7) . . ?
C49 C50 C53 106.0(6) . . ?
C54 C50 C53 112.0(8) . . ?
C49 C50 C52 109.7(6) . . ?
C54 C50 C52 109.8(7) . . ?
C53 C50 C52 110.7(7) . . ?
C55 C51 Ag3 130.9(5) . . ?
C55 C51 Ag4 148.7(5) . . ?
Ag3 C51 Ag4 80.1(2) . . ?
C55 C51 Ag5 94.6(4) . . ?
Ag3 C51 Ag5 85.9(2) . . ?
Ag4 C51 Ag5 82.58(18) . . ?
C55 C51 Ag6 87.7(4) . . ?
Ag3 C51 Ag6 117.0(2) . . ?
Ag4 C51 Ag6 78.8(2) . . ?
Ag5 C51 Ag6 146.9(3) . . ?
C51 C55 C56 177.0(7) . . ?
C51 C55 Ag6 65.0(4) . . ?
C56 C55 Ag6 117.6(4) . . ?
C55 C56 C58 108.6(6) . . ?
C55 C56 C60 109.9(6) . . ?
C58 C56 C60 109.0(5) . . ?
C55 C56 C57 107.8(5) . . ?
C58 C56 C57 110.8(7) . . ?
C60 C56 C57 110.7(7) . . ?
C46 C59 F13 117.1(9) . . ?
C46 C59 F15 109.1(13) . . ?
F13 C59 F15 108.6(12) . . ?
C46 C59 F14 109.3(12) . . ?
F13 C59 F14 103.2(11) . . ?
F15 C59 F14 109.2(9) . . ?
O9 C61 O8 129.8(8) . . ?
O9 C61 C62 116.5(7) . . ?
O8 C61 C62 113.4(7) . . ?
F17 C62 C63 112.6(11) . . ?
F17 C62 C61 115.9(8) . . ?
C63 C62 C61 120.6(12) . . ?
F17 C62 F16 108.1(13) . . ?
C63 C62 F16 86.0(10) . . ?
C61 C62 F16 108.7(11) . . ?
F19 C63 F20 109.5(10) . . ?
F19 C63 C62 125.1(10) . . ?
F20 C63 C62 116.9(11) . . ?
F19 C63 F18 107.0(11) . . ?
F20 C63 F18 105.8(8) . . ?
C62 C63 F18 87.4(11) . . ?
C14 N1 C12 117.9(6) . . ?
C14 N1 Ag5 125.5(4) . . ?
C12 N1 Ag5 116.6(4) . . ?
C6 N2 C7 118.9(5) . . ?
C6 N2 Ag5 126.5(4) . . ?
C7 N2 Ag5 114.7(4) . . ?
C22 N3 C23 118.0(5) . . ?
C22 N3 Ag4 125.4(4) . . ?
C23 N3 Ag4 116.0(4) . . ?
C25 N4 C24 118.8(5) . . ?
C25 N4 Ag4 128.2(4) . . ?
C24 N4 Ag4 112.7(4) . . ?
C29 N5 C31 119.0(5) . . ?
C29 N5 Ag1 127.7(4) . . ?
C31 N5 Ag1 113.2(4) . . ?
C38 N6 C35 119.0(5) . . ?
C38 N6 Ag1 126.0(4) . . ?
C35 N6 Ag1 115.0(4) . . ?
C42 O1 Ag5 124.8(4) . . ?
C4 O2 Ag3 127.8(10) . . ?
C4A O2A Ag3 122.0(7) . . ?
C39 O4 Ag2 119.4(5) . . ?
C45 O6 Ag2 126.3(5) . . ?
C45 O7 Ag3 118.7(5) . . ?
C61 O8 Ag6 114.6(5) . . ?
C3 O10 Ag2 118.6(5) . . ?
C3 O10 Ag3 120.7(4) . . ?
Ag2 O10 Ag3 76.70(12) . . ?

_diffrn_measured_fraction_theta_max 0.976
_diffrn_reflns_theta_full        62.42
_diffrn_measured_fraction_theta_full 0.976
_refine_diff_density_max         1.348
_refine_diff_density_min         -0.942
_refine_diff_density_rms         0.115
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_4
_database_code_depnum_ccdc_archive 'CCDC 1032349'
_audit_update_record             
;
2014-11-03 deposited with the CCDC.
2014-12-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C70 H50 Ag8 F30 N8 O12'
_chemical_formula_weight         2628.14

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   23.1111(6)
_cell_length_b                   14.8580(3)
_cell_length_c                   26.0686(6)
_cell_angle_alpha                90.00
_cell_angle_beta                 115.028(2)
_cell_angle_gamma                90.00
_cell_volume                     8111.0(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    11377
_cell_measurement_theta_min      2.0817
_cell_measurement_theta_max      30.6681

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.152
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             5072
_exptl_absorpt_coefficient_mu    2.022
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.70324
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Oxford, CCD'
_diffrn_measurement_method       '/w scan'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            21620
_diffrn_reflns_av_R_equivalents  0.0309
_diffrn_reflns_av_sigmaI/netI    0.0401
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_theta_min         2.09
_diffrn_reflns_theta_max         26.00
_reflns_number_total             7817
_reflns_number_gt                6003
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       CCD

_computing_cell_refinement       RED

_computing_data_reduction        RED

_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0335P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7817
_refine_ls_number_parameters     577
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0423
_refine_ls_R_factor_gt           0.0270
_refine_ls_wR_factor_ref         0.0645
_refine_ls_wR_factor_gt          0.0599
_refine_ls_goodness_of_fit_ref   1.003
_refine_ls_restrained_S_all      1.003
_refine_ls_shift/su_max          0.023
_refine_ls_shift/su_mean         0.002

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.169662(13) 0.573019(19) -0.100501(11) 0.02212(7) Uani 1 1 d . . .
Ag2 Ag 0.167033(13) 0.499061(19) -0.211755(11) 0.02089(7) Uani 1 1 d . . .
Ag3 Ag 0.079323(13) 0.636864(18) -0.207463(11) 0.01960(7) Uani 1 1 d . . .
Ag4 Ag -0.032334(13) 0.486598(19) -0.214198(11) 0.02264(7) Uani 1 1 d . . .
C11 C 0.08300(16) 0.4999(2) -0.18161(14) 0.0195(8) Uani 1 1 d . . .
C12 C 0.09559(17) 0.4369(3) -0.14881(14) 0.0212(8) Uani 1 1 d . . .
C13 C 0.10811(19) 0.3531(3) -0.11402(16) 0.0286(9) Uani 1 1 d . . .
C14 C 0.0726(2) 0.3559(3) -0.07734(16) 0.0373(11) Uani 1 1 d . . .
H14A H 0.0867 0.4067 -0.0523 0.056 Uiso 1 1 calc R . .
H14B H 0.0807 0.3015 -0.0555 0.056 Uiso 1 1 calc R . .
H14C H 0.0276 0.3612 -0.1008 0.056 Uiso 1 1 calc R . .
C15 C 0.0867(2) 0.2724(3) -0.15471(19) 0.0368(10) Uani 1 1 d . . .
H15A H 0.0420 0.2777 -0.1790 0.055 Uiso 1 1 calc R . .
H15B H 0.0943 0.2177 -0.1333 0.055 Uiso 1 1 calc R . .
H15C H 0.1105 0.2715 -0.1773 0.055 Uiso 1 1 calc R . .
C16 C 0.1806(2) 0.3446(3) -0.0769(2) 0.0520(14) Uani 1 1 d . . .
H16A H 0.1949 0.3947 -0.0513 0.078 Uiso 1 1 calc R . .
H16B H 0.2030 0.3443 -0.1007 0.078 Uiso 1 1 calc R . .
H16C H 0.1891 0.2896 -0.0557 0.078 Uiso 1 1 calc R . .
N1 N 0.20443(14) 0.7224(2) -0.09104(12) 0.0217(7) Uani 1 1 d . . .
N2 N 0.12442(14) 0.6537(2) -0.04800(12) 0.0217(7) Uani 1 1 d . . .
C101 C 0.24499(17) 0.7526(3) -0.11144(14) 0.0237(9) Uani 1 1 d . . .
H10A H 0.2580 0.7134 -0.1323 0.028 Uiso 1 1 calc R . .
C102 C 0.26845(18) 0.8392(3) -0.10295(15) 0.0281(9) Uani 1 1 d . . .
H10B H 0.2960 0.8583 -0.1184 0.034 Uiso 1 1 calc R . .
C103 C 0.25012(19) 0.8971(3) -0.07102(15) 0.0299(9) Uani 1 1 d . . .
H10C H 0.2650 0.9561 -0.0648 0.036 Uiso 1 1 calc R . .
C104 C 0.20908(18) 0.8658(3) -0.04836(15) 0.0256(9) Uani 1 1 d . . .
H10D H 0.1967 0.9033 -0.0262 0.031 Uiso 1 1 calc R . .
C105 C 0.18674(16) 0.7776(2) -0.05927(13) 0.0191(8) Uani 1 1 d . . .
C201 C 0.08334(18) 0.6205(3) -0.02989(16) 0.0302(9) Uani 1 1 d . . .
H20A H 0.0701 0.5612 -0.0390 0.036 Uiso 1 1 calc R . .
C202 C 0.05873(19) 0.6687(3) 0.00190(16) 0.0325(10) Uani 1 1 d . . .
H20B H 0.0306 0.6421 0.0145 0.039 Uiso 1 1 calc R . .
C204 C 0.11891(17) 0.7936(3) -0.00542(15) 0.0257(9) Uani 1 1 d . . .
H20C H 0.1315 0.8534 0.0020 0.031 Uiso 1 1 calc R . .
C205 C 0.14232(17) 0.7407(2) -0.03660(13) 0.0200(8) Uani 1 1 d . . .
C203 C 0.07735(19) 0.7580(3) 0.01439(16) 0.0310(10) Uani 1 1 d . . .
H20D H 0.0621 0.7928 0.0356 0.037 Uiso 1 1 calc R . .
N3 N 0.12004(13) 0.7629(2) -0.22911(11) 0.0177(6) Uani 1 1 d . . .
N4 N 0.03953(13) 0.75953(19) -0.17856(11) 0.0174(6) Uani 1 1 d . . .
C301 C 0.16202(17) 0.7616(3) -0.25217(14) 0.0213(8) Uani 1 1 d . . .
H30A H 0.1726 0.7063 -0.2626 0.026 Uiso 1 1 calc R . .
C302 C 0.19035(17) 0.8377(3) -0.26131(14) 0.0258(9) Uani 1 1 d . . .
H30B H 0.2192 0.8341 -0.2775 0.031 Uiso 1 1 calc R . .
C303 C 0.17463(19) 0.9190(3) -0.24576(15) 0.0284(9) Uani 1 1 d . . .
H30C H 0.1929 0.9717 -0.2514 0.034 Uiso 1 1 calc R . .
C304 C 0.13194(18) 0.9223(3) -0.22189(15) 0.0251(8) Uani 1 1 d . . .
H30D H 0.1205 0.9773 -0.2118 0.030 Uiso 1 1 calc R . .
C305 C 0.10578(16) 0.8425(2) -0.21293(13) 0.0176(8) Uani 1 1 d . . .
C401 C 0.00197(17) 0.7529(3) -0.15149(14) 0.0231(8) Uani 1 1 d . . .
H40A H -0.0130 0.6964 -0.1477 0.028 Uiso 1 1 calc R . .
C404 C 0.04515(18) 0.9174(3) -0.16341(15) 0.0272(9) Uani 1 1 d . . .
H40B H 0.0603 0.9734 -0.1680 0.033 Uiso 1 1 calc R . .
C405 C 0.06139(16) 0.8408(2) -0.18439(13) 0.0183(8) Uani 1 1 d . . .
C402 C -0.01558(17) 0.8261(3) -0.12898(15) 0.0273(9) Uani 1 1 d . . .
H40C H -0.0414 0.8192 -0.1099 0.033 Uiso 1 1 calc R . .
C403 C 0.00592(19) 0.9096(3) -0.13532(16) 0.0339(10) Uani 1 1 d . . .
H40D H -0.0056 0.9604 -0.1210 0.041 Uiso 1 1 calc R . .
O1 O 0.16958(13) 0.55046(19) -0.29550(10) 0.0301(6) Uani 1 1 d . . .
O2 O 0.06329(13) 0.5537(2) -0.35035(11) 0.0323(7) Uani 1 1 d . . .
C1 C 0.12046(19) 0.5613(2) -0.34039(15) 0.0241(8) Uani 1 1 d . . .
C2 C 0.13260(19) 0.5891(3) -0.39212(15) 0.0294(9) Uani 1 1 d . . .
C3 C 0.1969(2) 0.6282(3) -0.38104(16) 0.0316(10) Uani 1 1 d . . .
F1 F 0.08916(12) 0.6517(2) -0.42358(11) 0.0568(8) Uani 1 1 d . . .
F2 F 0.12452(14) 0.51641(19) -0.42560(11) 0.0517(7) Uani 1 1 d . . .
F3 F 0.24460(11) 0.57129(18) -0.35462(10) 0.0412(6) Uani 1 1 d . . .
F4 F 0.19945(12) 0.65042(18) -0.43053(9) 0.0439(6) Uani 1 1 d . . .
F5 F 0.20782(13) 0.70332(17) -0.35064(10) 0.0463(7) Uani 1 1 d . . .
O3 O 0.27446(12) 0.51978(18) -0.06331(10) 0.0284(6) Uani 1 1 d . . .
O4 O 0.27255(12) 0.4981(2) -0.14938(11) 0.0372(7) Uani 1 1 d . . .
C4 C 0.29607(17) 0.4955(3) -0.09737(15) 0.0224(8) Uani 1 1 d . . .
C5 C 0.36521(19) 0.4582(3) -0.06890(17) 0.0338(10) Uani 1 1 d . . .
C6 C 0.3829(2) 0.4058(3) -0.01412(19) 0.0392(11) Uani 1 1 d . . .
F6 F 0.40752(12) 0.5272(2) -0.05686(11) 0.0546(8) Uani 1 1 d . . .
F7 F 0.37615(14) 0.4034(2) -0.10483(12) 0.0774(11) Uani 1 1 d . . .
F8 F 0.34056(14) 0.3421(2) -0.02076(14) 0.0700(10) Uani 1 1 d . . .
F9 F 0.38637(13) 0.4592(2) 0.02747(10) 0.0559(8) Uani 1 1 d . . .
F10 F 0.43971(13) 0.3668(2) 0.00197(12) 0.0624(9) Uani 1 1 d . . .
O5 O -0.16765(13) 0.34797(18) -0.26098(12) 0.0326(7) Uani 1 1 d . . .
O6 O -0.06546(14) 0.34529(19) -0.19780(12) 0.0379(7) Uani 1 1 d . . .
C7 C -0.12077(19) 0.3164(3) -0.22222(16) 0.0270(9) Uani 1 1 d . . .
C8 C -0.1323(2) 0.2255(3) -0.19931(19) 0.0412(11) Uani 1 1 d . . .
C9 C -0.0810(3) 0.1552(3) -0.1820(2) 0.0485(13) Uani 1 1 d . . .
F11 F -0.18380(17) 0.1811(2) -0.23879(17) 0.122(2) Uani 1 1 d . . .
F12 F -0.14656(18) 0.2375(2) -0.15534(15) 0.0799(11) Uani 1 1 d . . .
F13 F -0.05817(18) 0.1460(2) -0.22088(15) 0.0745(10) Uani 1 1 d . . .
F14 F -0.03154(14) 0.1828(2) -0.13384(13) 0.0701(10) Uani 1 1 d . . .
F15 F -0.10028(14) 0.07675(16) -0.17173(12) 0.0531(8) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O3 2.333(3) . ?
Ag1 N1 2.338(3) . ?
Ag1 N2 2.370(3) . ?
Ag1 C11 2.466(3) . ?
Ag1 C12 2.604(4) . ?
Ag1 Ag3 2.8475(4) . ?
Ag1 Ag2 3.0779(4) . ?
Ag2 O4 2.288(3) . ?
Ag2 O1 2.337(3) . ?
Ag2 O5 2.357(3) 2_554 ?
Ag2 C11 2.383(4) . ?
Ag2 Ag4 2.8926(4) 2_554 ?
Ag2 Ag3 2.9164(4) . ?
Ag3 C11 2.135(4) . ?
Ag3 N3 2.271(3) . ?
Ag3 N4 2.307(3) . ?
Ag3 Ag4 2.9083(4) 2_554 ?
Ag3 Ag4 3.3603(4) . ?
Ag4 O2 2.314(3) 2_554 ?
Ag4 O6 2.335(3) . ?
Ag4 C11 2.439(3) . ?
Ag4 C11 2.469(3) 2_554 ?
Ag4 Ag4 2.8422(6) 2_554 ?
Ag4 Ag2 2.8926(4) 2_554 ?
Ag4 Ag3 2.9082(4) 2_554 ?
C11 C12 1.217(5) . ?
C11 Ag4 2.469(3) 2_554 ?
C12 C13 1.495(5) . ?
C13 C14 1.501(6) . ?
C13 C15 1.538(6) . ?
C13 C16 1.546(6) . ?
N1 C101 1.336(5) . ?
N1 C105 1.346(5) . ?
N2 C201 1.322(5) . ?
N2 C205 1.351(5) . ?
C101 C102 1.377(5) . ?
C102 C103 1.382(6) . ?
C103 C104 1.393(6) . ?
C104 C105 1.394(5) . ?
C105 C205 1.488(5) . ?
C201 C202 1.386(6) . ?
C202 C203 1.390(6) . ?
C204 C203 1.375(6) . ?
C204 C205 1.394(5) . ?
N3 C305 1.343(5) . ?
N3 C301 1.340(5) . ?
N4 C401 1.334(5) . ?
N4 C405 1.342(4) . ?
C301 C302 1.377(5) . ?
C302 C303 1.371(5) . ?
C303 C304 1.372(6) . ?
C304 C305 1.395(5) . ?
C305 C405 1.501(5) . ?
C401 C402 1.376(5) . ?
C404 C405 1.381(5) . ?
C404 C403 1.391(6) . ?
C402 C403 1.371(6) . ?
O1 C1 1.249(4) . ?
O2 C1 1.239(5) . ?
O2 Ag4 2.314(3) 2_554 ?
C1 C2 1.545(5) . ?
C2 F2 1.351(5) . ?
C2 F1 1.359(4) . ?
C2 C3 1.506(6) . ?
C3 F5 1.330(5) . ?
C3 F3 1.326(5) . ?
C3 F4 1.357(4) . ?
O3 C4 1.242(4) . ?
O4 C4 1.229(4) . ?
C4 C5 1.552(5) . ?
C5 F7 1.344(5) . ?
C5 F6 1.358(5) . ?
C5 C6 1.523(6) . ?
C6 F8 1.319(5) . ?
C6 F9 1.318(5) . ?
C6 F10 1.330(5) . ?
O5 C7 1.220(4) . ?
O5 Ag2 2.356(3) 2_554 ?
O6 C7 1.239(5) . ?
C7 C8 1.545(6) . ?
C8 F12 1.331(6) . ?
C8 F11 1.369(5) . ?
C8 C9 1.499(7) . ?
C9 F15 1.316(5) . ?
C9 F13 1.332(6) . ?
C9 F14 1.356(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Ag1 N1 91.60(10) . . ?
O3 Ag1 N2 124.45(9) . . ?
N1 Ag1 N2 71.01(11) . . ?
O3 Ag1 C11 122.05(10) . . ?
N1 Ag1 C11 128.85(11) . . ?
N2 Ag1 C11 108.75(11) . . ?
O3 Ag1 C12 106.98(10) . . ?
N1 Ag1 C12 156.14(10) . . ?
N2 Ag1 C12 108.17(11) . . ?
C11 Ag1 C12 27.59(11) . . ?
O3 Ag1 Ag3 136.22(7) . . ?
N1 Ag1 Ag3 82.18(7) . . ?
N2 Ag1 Ag3 94.42(7) . . ?
C11 Ag1 Ag3 46.69(8) . . ?
C12 Ag1 Ag3 74.07(8) . . ?
O3 Ag1 Ag2 82.75(6) . . ?
N1 Ag1 Ag2 107.90(7) . . ?
N2 Ag1 Ag2 152.53(7) . . ?
C11 Ag1 Ag2 49.43(8) . . ?
C12 Ag1 Ag2 61.33(8) . . ?
Ag3 Ag1 Ag2 58.817(9) . . ?
O4 Ag2 O1 103.02(10) . . ?
O4 Ag2 O5 93.91(10) . 2_554 ?
O1 Ag2 O5 91.36(10) . 2_554 ?
O4 Ag2 C11 122.53(10) . . ?
O1 Ag2 C11 130.72(10) . . ?
O5 Ag2 C11 102.35(11) 2_554 . ?
O4 Ag2 Ag4 175.11(8) . 2_554 ?
O1 Ag2 Ag4 80.96(7) . 2_554 ?
O5 Ag2 Ag4 83.10(7) 2_554 2_554 ?
C11 Ag2 Ag4 54.78(8) . 2_554 ?
O4 Ag2 Ag3 121.73(8) . . ?
O1 Ag2 Ag3 95.68(7) . . ?
O5 Ag2 Ag3 140.65(7) 2_554 . ?
C11 Ag2 Ag3 46.15(9) . . ?
Ag4 Ag2 Ag3 60.085(9) 2_554 . ?
O4 Ag2 Ag1 75.06(7) . . ?
O1 Ag2 Ag1 139.94(7) . . ?
O5 Ag2 Ag1 128.62(7) 2_554 . ?
C11 Ag2 Ag1 51.80(8) . . ?
Ag4 Ag2 Ag1 103.786(11) 2_554 . ?
Ag3 Ag2 Ag1 56.645(9) . . ?
C11 Ag3 N3 154.05(12) . . ?
C11 Ag3 N4 128.20(12) . . ?
N3 Ag3 N4 72.20(10) . . ?
C11 Ag3 Ag1 57.21(9) . . ?
N3 Ag3 Ag1 107.98(7) . . ?
N4 Ag3 Ag1 99.89(7) . . ?
C11 Ag3 Ag4 56.14(9) . 2_554 ?
N3 Ag3 Ag4 121.95(7) . 2_554 ?
N4 Ag3 Ag4 138.92(7) . 2_554 ?
Ag1 Ag3 Ag4 109.459(12) . 2_554 ?
C11 Ag3 Ag2 53.64(10) . . ?
N3 Ag3 Ag2 101.62(7) . . ?
N4 Ag3 Ag2 161.23(7) . . ?
Ag1 Ag3 Ag2 64.539(9) . . ?
Ag4 Ag3 Ag2 59.551(9) 2_554 . ?
C11 Ag3 Ag4 46.37(9) . . ?
N3 Ag3 Ag4 157.59(7) . . ?
N4 Ag3 Ag4 97.96(7) . . ?
Ag1 Ag3 Ag4 93.356(11) . . ?
Ag4 Ag3 Ag4 53.334(11) 2_554 . ?
Ag2 Ag3 Ag4 93.577(11) . . ?
O2 Ag4 O6 91.61(11) 2_554 . ?
O2 Ag4 C11 109.90(10) 2_554 . ?
O6 Ag4 C11 113.80(11) . . ?
O2 Ag4 C11 128.09(11) 2_554 2_554 ?
O6 Ag4 C11 103.50(11) . 2_554 ?
C11 Ag4 C11 108.45(9) . 2_554 ?
O2 Ag4 Ag4 152.59(7) 2_554 2_554 ?
O6 Ag4 Ag4 115.11(8) . 2_554 ?
C11 Ag4 Ag4 55.11(8) . 2_554 ?
C11 Ag4 Ag4 54.13(8) 2_554 2_554 ?
O2 Ag4 Ag2 83.17(7) 2_554 2_554 ?
O6 Ag4 Ag2 80.57(7) . 2_554 ?
C11 Ag4 Ag2 159.43(8) . 2_554 ?
C11 Ag4 Ag2 52.06(8) 2_554 2_554 ?
Ag4 Ag4 Ag2 106.156(14) 2_554 2_554 ?
O2 Ag4 Ag3 92.37(7) 2_554 2_554 ?
O6 Ag4 Ag3 139.89(7) . 2_554 ?
C11 Ag4 Ag3 102.17(9) . 2_554 ?
C11 Ag4 Ag3 45.88(9) 2_554 2_554 ?
Ag4 Ag4 Ag3 71.503(9) 2_554 2_554 ?
Ag2 Ag4 Ag3 60.367(10) 2_554 2_554 ?
O2 Ag4 Ag3 98.20(7) 2_554 . ?
O6 Ag4 Ag3 153.09(7) . . ?
C11 Ag4 Ag3 39.30(9) . . ?
C11 Ag4 Ag3 90.04(8) 2_554 . ?
Ag4 Ag4 Ag3 55.163(8) 2_554 . ?
Ag2 Ag4 Ag3 125.327(12) 2_554 . ?
Ag3 Ag4 Ag3 64.974(11) 2_554 . ?
C12 C11 Ag3 157.0(3) . . ?
C12 C11 Ag2 104.0(3) . . ?
Ag3 C11 Ag2 80.20(12) . . ?
C12 C11 Ag4 94.8(3) . . ?
Ag3 C11 Ag4 94.33(13) . . ?
Ag2 C11 Ag4 143.86(15) . . ?
C12 C11 Ag1 82.5(2) . . ?
Ag3 C11 Ag1 76.10(11) . . ?
Ag2 C11 Ag1 78.78(10) . . ?
Ag4 C11 Ag1 134.89(15) . . ?
C12 C11 Ag4 124.9(3) . 2_554 ?
Ag3 C11 Ag4 77.99(11) . 2_554 ?
Ag2 C11 Ag4 73.16(10) . 2_554 ?
Ag4 C11 Ag4 70.77(9) . 2_554 ?
Ag1 C11 Ag4 144.45(16) . 2_554 ?
C11 C12 C13 173.8(4) . . ?
C11 C12 Ag1 69.9(2) . . ?
C13 C12 Ag1 115.7(2) . . ?
C12 C13 C14 110.3(3) . . ?
C12 C13 C15 107.9(3) . . ?
C14 C13 C15 111.0(3) . . ?
C12 C13 C16 109.2(3) . . ?
C14 C13 C16 110.1(4) . . ?
C15 C13 C16 108.4(4) . . ?
C101 N1 C105 119.1(3) . . ?
C101 N1 Ag1 123.0(3) . . ?
C105 N1 Ag1 117.6(2) . . ?
C201 N2 C205 118.5(4) . . ?
C201 N2 Ag1 125.2(3) . . ?
C205 N2 Ag1 116.2(2) . . ?
N1 C101 C102 123.0(4) . . ?
C101 C102 C103 118.6(4) . . ?
C102 C103 C104 119.0(4) . . ?
C103 C104 C105 119.2(4) . . ?
N1 C105 C104 121.0(3) . . ?
N1 C105 C205 117.4(3) . . ?
C104 C105 C205 121.5(3) . . ?
N2 C201 C202 124.0(4) . . ?
C203 C202 C201 117.9(4) . . ?
C203 C204 C205 120.5(4) . . ?
N2 C205 C204 120.6(4) . . ?
N2 C205 C105 117.6(3) . . ?
C204 C205 C105 121.8(3) . . ?
C204 C203 C202 118.4(4) . . ?
C305 N3 C301 118.2(3) . . ?
C305 N3 Ag3 117.7(2) . . ?
C301 N3 Ag3 123.7(3) . . ?
C401 N4 C405 119.1(3) . . ?
C401 N4 Ag3 123.6(3) . . ?
C405 N4 Ag3 116.9(2) . . ?
N3 C301 C302 123.6(3) . . ?
C303 C302 C301 117.9(3) . . ?
C302 C303 C304 119.8(4) . . ?
C303 C304 C305 119.4(4) . . ?
N3 C305 C304 121.0(3) . . ?
N3 C305 C405 116.8(3) . . ?
C304 C305 C405 122.2(3) . . ?
N4 C401 C402 122.9(4) . . ?
C405 C404 C403 119.1(4) . . ?
N4 C405 C404 121.2(3) . . ?
N4 C405 C305 116.1(3) . . ?
C404 C405 C305 122.7(3) . . ?
C403 C402 C401 118.4(4) . . ?
C402 C403 C404 119.3(4) . . ?
C1 O1 Ag2 123.0(2) . . ?
C1 O2 Ag4 121.1(2) . 2_554 ?
O2 C1 O1 130.6(4) . . ?
O2 C1 C2 114.4(3) . . ?
O1 C1 C2 115.1(3) . . ?
F2 C2 F1 107.0(3) . . ?
F2 C2 C3 106.7(3) . . ?
F1 C2 C3 105.6(3) . . ?
F2 C2 C1 108.9(3) . . ?
F1 C2 C1 110.4(3) . . ?
C3 C2 C1 117.7(3) . . ?
F5 C3 F3 108.6(3) . . ?
F5 C3 F4 106.8(3) . . ?
F3 C3 F4 106.8(3) . . ?
F5 C3 C2 111.1(4) . . ?
F3 C3 C2 112.9(3) . . ?
F4 C3 C2 110.3(3) . . ?
C4 O3 Ag1 117.5(2) . . ?
C4 O4 Ag2 128.7(2) . . ?
O4 C4 O3 130.9(4) . . ?
O4 C4 C5 115.1(3) . . ?
O3 C4 C5 113.9(3) . . ?
F7 C5 F6 106.8(4) . . ?
F7 C5 C6 106.8(4) . . ?
F6 C5 C6 106.7(3) . . ?
F7 C5 C4 110.0(3) . . ?
F6 C5 C4 109.7(3) . . ?
C6 C5 C4 116.4(4) . . ?
F8 C6 F9 108.9(4) . . ?
F8 C6 F10 107.9(4) . . ?
F9 C6 F10 107.1(3) . . ?
F8 C6 C5 110.7(4) . . ?
F9 C6 C5 111.2(4) . . ?
F10 C6 C5 110.9(4) . . ?
C7 O5 Ag2 120.0(2) . 2_554 ?
C7 O6 Ag4 124.4(2) . . ?
O5 C7 O6 130.8(4) . . ?
O5 C7 C8 114.7(3) . . ?
O6 C7 C8 114.5(3) . . ?
F12 C8 F11 105.0(5) . . ?
F12 C8 C9 106.7(4) . . ?
F11 C8 C9 102.5(4) . . ?
F12 C8 C7 111.2(4) . . ?
F11 C8 C7 111.6(3) . . ?
C9 C8 C7 118.7(4) . . ?
F15 C9 F13 109.9(4) . . ?
F15 C9 F14 107.7(4) . . ?
F13 C9 F14 106.6(4) . . ?
F15 C9 C8 112.6(4) . . ?
F13 C9 C8 111.1(4) . . ?
F14 C9 C8 108.5(4) . . ?

_diffrn_measured_fraction_theta_max 0.981
_diffrn_reflns_theta_full        26.00
_diffrn_measured_fraction_theta_full 0.981
_refine_diff_density_max         0.839
_refine_diff_density_min         -0.766
_refine_diff_density_rms         0.103
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_5
_database_code_depnum_ccdc_archive 'CCDC 1032350'
_audit_update_record             
;
2014-11-03 deposited with the CCDC.
2014-12-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C78 H50 Ag8 F30 N8 O12'
_chemical_formula_weight         2724.22

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   23.2589(8)
_cell_length_b                   15.9256(4)
_cell_length_c                   25.5945(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 111.372(3)
_cell_angle_gamma                90.00
_cell_volume                     8828.6(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    7281
_cell_measurement_theta_min      2.1677
_cell_measurement_theta_max      32.7153

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.050
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             5264
_exptl_absorpt_coefficient_mu    1.862
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.89935
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Oxford, CCD'
_diffrn_measurement_method       '/w scan'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            22839
_diffrn_reflns_av_R_equivalents  0.0358
_diffrn_reflns_av_sigmaI/netI    0.0486
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_theta_min         2.56
_diffrn_reflns_theta_max         26.00
_reflns_number_total             8532
_reflns_number_gt                5451
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       CCD
_computing_cell_refinement       RED
_computing_data_reduction        RED
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0815P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8532
_refine_ls_number_parameters     613
_refine_ls_number_restraints     30
_refine_ls_R_factor_all          0.0808
_refine_ls_R_factor_gt           0.0485
_refine_ls_wR_factor_ref         0.1449
_refine_ls_wR_factor_gt          0.1294
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_restrained_S_all      1.081
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.16190(2) 1.45169(4) 0.28611(2) 0.05896(18) Uani 1 1 d . . .
Ag2 Ag 0.03156(2) 1.45797(4) 0.21138(3) 0.05996(18) Uani 1 1 d . . .
Ag3 Ag 0.07463(2) 1.59323(3) 0.29545(2) 0.05391(17) Uani 1 1 d . . .
Ag4 Ag 0.16548(3) 1.53514(4) 0.39773(2) 0.05851(18) Uani 1 1 d . . .
C1 C 0.0785(3) 1.4646(4) 0.3181(3) 0.0456(15) Uani 1 1 d . . .
C2 C 0.0948(3) 1.4046(4) 0.3493(3) 0.0499(16) Uani 1 1 d . . .
C3 C 0.1074(3) 1.3259(5) 0.3829(3) 0.0602(19) Uani 1 1 d . . .
C4 C 0.1767(4) 1.3163(8) 0.4156(6) 0.123(5) Uani 1 1 d . . .
H4A H 0.1984 1.3131 0.3892 0.185 Uiso 1 1 calc R . .
H4B H 0.1843 1.2649 0.4381 0.185 Uiso 1 1 calc R . .
H4C H 0.1919 1.3649 0.4403 0.185 Uiso 1 1 calc R . .
C5 C 0.0734(5) 1.3311(6) 0.4247(4) 0.092(3) Uani 1 1 d . . .
H5A H 0.0289 1.3362 0.4038 0.139 Uiso 1 1 calc R . .
H5B H 0.0880 1.3803 0.4489 0.139 Uiso 1 1 calc R . .
H5C H 0.0817 1.2802 0.4477 0.139 Uiso 1 1 calc R . .
C6 C 0.0842(5) 1.2525(6) 0.3444(5) 0.095(3) Uani 1 1 d . . .
H6A H 0.0399 1.2591 0.3232 0.143 Uiso 1 1 calc R . .
H6B H 0.0914 1.2007 0.3665 0.143 Uiso 1 1 calc R . .
H6C H 0.1062 1.2496 0.3183 0.143 Uiso 1 1 calc R . .
N1 N 0.1075(2) 1.6063(4) 0.4444(2) 0.0516(14) Uani 1 1 d . . .
N2 N 0.1964(2) 1.6762(4) 0.4120(2) 0.0521(14) Uani 1 1 d . . .
N3 N 0.0320(2) 1.7109(3) 0.31987(19) 0.0393(11) Uani 1 1 d . . .
N4 N 0.1233(2) 1.7088(4) 0.2757(2) 0.0484(13) Uani 1 1 d . . .
C101 C 0.0621(4) 1.5738(5) 0.4583(3) 0.065(2) Uani 1 1 d . . .
H10A H 0.0505 1.5170 0.4486 0.078 Uiso 1 1 calc R . .
C102 C 0.0309(4) 1.6188(7) 0.4861(4) 0.074(2) Uani 1 1 d . . .
H10B H -0.0004 1.5927 0.4961 0.089 Uiso 1 1 calc R . .
C103 C 0.0457(4) 1.7000(6) 0.4987(3) 0.071(2) Uani 1 1 d . . .
H10C H 0.0243 1.7315 0.5174 0.085 Uiso 1 1 calc R . .
C104 C 0.0922(3) 1.7385(5) 0.4844(3) 0.0547(18) Uani 1 1 d . . .
C105 C 0.1214(3) 1.6882(4) 0.4565(3) 0.0458(15) Uani 1 1 d . . .
C106 C 0.1088(4) 1.8239(6) 0.4954(3) 0.068(2) Uani 1 1 d . . .
H10D H 0.0882 1.8574 0.5139 0.081 Uiso 1 1 calc R . .
C201 C 0.2400(3) 1.7105(6) 0.3973(3) 0.065(2) Uani 1 1 d . . .
H20A H 0.2597 1.6762 0.3785 0.078 Uiso 1 1 calc R . .
C202 C 0.2585(3) 1.7918(6) 0.4075(3) 0.071(2) Uani 1 1 d . . .
H20B H 0.2905 1.8129 0.3964 0.085 Uiso 1 1 calc R . .
C203 C 0.2299(4) 1.8438(6) 0.4343(3) 0.070(2) Uani 1 1 d . . .
H20C H 0.2408 1.9014 0.4409 0.085 Uiso 1 1 calc R . .
C204 C 0.1841(3) 1.8083(5) 0.4514(3) 0.0549(17) Uani 1 1 d . . .
C205 C 0.1693(3) 1.7256(5) 0.4398(3) 0.0473(15) Uani 1 1 d . . .
C206 C 0.1523(4) 1.8583(5) 0.4808(3) 0.072(2) Uani 1 1 d . . .
H20D H 0.1630 1.9156 0.4893 0.087 Uiso 1 1 calc R . .
C301 C -0.0108(3) 1.7109(4) 0.3426(3) 0.0472(15) Uani 1 1 d . . .
H30A H -0.0280 1.6590 0.3480 0.057 Uiso 1 1 calc R . .
C302 C -0.0315(3) 1.7855(6) 0.3588(3) 0.063(2) Uani 1 1 d . . .
H30B H -0.0627 1.7839 0.3746 0.076 Uiso 1 1 calc R . .
C303 C -0.0071(3) 1.8594(5) 0.3520(3) 0.065(2) Uani 1 1 d . . .
H30C H -0.0206 1.9102 0.3634 0.078 Uiso 1 1 calc R . .
C304 C 0.0380(3) 1.8612(4) 0.3283(3) 0.0538(17) Uani 1 1 d . . .
C305 C 0.0572(3) 1.7847(4) 0.3131(2) 0.0423(14) Uani 1 1 d . . .
C306 C 0.0675(4) 1.9376(5) 0.3205(4) 0.076(2) Uani 1 1 d . . .
H30D H 0.0550 1.9898 0.3308 0.091 Uiso 1 1 calc R . .
C401 C 0.1677(3) 1.7094(5) 0.2553(3) 0.0604(19) Uani 1 1 d . . .
H40A H 0.1808 1.6569 0.2460 0.072 Uiso 1 1 calc R . .
C402 C 0.1968(4) 1.7817(6) 0.2466(3) 0.072(2) Uani 1 1 d . . .
H40B H 0.2288 1.7782 0.2319 0.086 Uiso 1 1 calc R . .
C403 C 0.1783(4) 1.8573(6) 0.2596(3) 0.072(2) Uani 1 1 d . . .
H40C H 0.1970 1.9077 0.2537 0.086 Uiso 1 1 calc R . .
C404 C 0.1305(3) 1.8605(5) 0.2823(3) 0.0582(18) Uani 1 1 d . . .
C405 C 0.1047(3) 1.7840(4) 0.2896(2) 0.0407(13) Uani 1 1 d . . .
C406 C 0.1114(4) 1.9364(5) 0.2993(4) 0.067(2) Uani 1 1 d . . .
H40D H 0.1304 1.9876 0.2954 0.080 Uiso 1 1 calc R . .
O11 O 0.2632(3) 1.4512(6) 0.3442(3) 0.102(3) Uani 1 1 d . . .
O12 O 0.2663(2) 1.4874(4) 0.4297(3) 0.0842(19) Uani 1 1 d . . .
C11 C 0.2866(3) 1.4598(5) 0.3942(4) 0.061(2) Uani 1 1 d . . .
C12 C 0.3535(4) 1.4334(7) 0.4197(4) 0.080(3) Uani 1 1 d . . .
F11 F 0.3746(3) 1.4043(5) 0.3820(3) 0.136(3) Uani 1 1 d . . .
F12 F 0.3918(3) 1.5027(5) 0.4394(3) 0.137(3) Uani 1 1 d . . .
C13 C 0.3712(7) 1.3769(11) 0.4664(7) 0.130(5) Uani 1 1 d . . .
F13 F 0.3348(4) 1.3108(6) 0.4511(6) 0.217(6) Uani 1 1 d . . .
F14 F 0.3658(5) 1.4082(9) 0.5115(3) 0.213(6) Uani 1 1 d . . .
F15 F 0.4291(3) 1.3488(6) 0.4830(3) 0.154(3) Uani 1 1 d . . .
O21 O 0.1594(3) 1.3164(4) 0.2463(3) 0.0850(18) Uani 1 1 d . . .
O22 O 0.0614(3) 1.3273(4) 0.1901(3) 0.097(2) Uani 1 1 d . . .
C21 C 0.1126(5) 1.2941(5) 0.2086(4) 0.070(2) Uani 1 1 d . . .
C22 C 0.1161(6) 1.2110(7) 0.1798(5) 0.100(3) Uani 1 1 d . . .
F21 F 0.1580(5) 1.2054(7) 0.1598(5) 0.181(3) Uani 1 1 d U . .
F22 F 0.0615(8) 1.1989(8) 0.1258(3) 0.306(10) Uani 1 1 d . . .
C23 C 0.0971(9) 1.1392(13) 0.1966(8) 0.164(6) Uani 1 1 d U . .
F23 F 0.1573(6) 1.1370(9) 0.2474(6) 0.243(5) Uani 1 1 d U . .
F24 F 0.0577(4) 1.1384(6) 0.2185(4) 0.161(3) Uani 1 1 d U . .
F25 F 0.1044(4) 1.0648(5) 0.1727(4) 0.146(3) Uani 1 1 d U . .
O31 O 0.1743(3) 1.5098(5) 0.2081(3) 0.0856(18) Uani 1 1 d . . .
O32 O 0.0743(3) 1.5224(4) 0.1521(3) 0.0819(18) Uani 1 1 d . . .
C31 C 0.1296(5) 1.5242(5) 0.1631(4) 0.070(2) Uani 1 1 d . . .
C32 C 0.1523(5) 1.5452(10) 0.1148(4) 0.107(4) Uani 1 1 d . . .
F31 F 0.1315(7) 1.4942(12) 0.0754(4) 0.277(9) Uani 1 1 d . . .
F32 F 0.1154(5) 1.6247(12) 0.0877(6) 0.284(10) Uani 1 1 d . . .
C33 C 0.2065(11) 1.5847(12) 0.1207(7) 0.176(9) Uani 1 1 d . . .
F33 F 0.2382(8) 1.5055(11) 0.1390(6) 0.275(9) Uani 1 1 d . . .
F34 F 0.2218(6) 1.6430(8) 0.1540(4) 0.220(6) Uani 1 1 d . . .
F35 F 0.2102(4) 1.6045(7) 0.0718(3) 0.167(4) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O11 2.283(6) . ?
Ag1 O31 2.311(6) . ?
Ag1 C1 2.372(6) . ?
Ag1 O21 2.375(6) . ?
Ag1 Ag2 2.9380(8) . ?
Ag1 Ag3 3.1002(8) . ?
Ag1 Ag4 3.1242(8) . ?
Ag2 O22 2.321(6) . ?
Ag2 O32 2.332(6) . ?
Ag2 C1 2.394(6) 2 ?
Ag2 C1 2.547(7) . ?
Ag2 Ag2 2.8597(11) 2 ?
Ag2 Ag3 2.9499(8) . ?
Ag2 Ag3 3.2336(8) 2 ?
Ag3 C1 2.121(7) . ?
Ag3 N4 2.311(5) . ?
Ag3 N3 2.310(5) . ?
Ag3 Ag4 2.8535(8) . ?
Ag3 Ag2 3.2335(8) 2 ?
Ag4 O12 2.313(5) . ?
Ag4 N2 2.346(6) . ?
Ag4 N1 2.389(5) . ?
Ag4 C1 2.550(7) . ?
Ag4 C2 2.660(7) . ?
C1 C2 1.213(9) . ?
C1 Ag2 2.394(6) 2 ?
C2 C3 1.488(10) . ?
C3 C6 1.497(12) . ?
C3 C4 1.531(12) . ?
C3 C5 1.546(11) . ?
N1 C101 1.335(9) . ?
N1 C105 1.353(9) . ?
N2 C201 1.322(9) . ?
N2 C205 1.361(8) . ?
N3 C301 1.324(7) . ?
N3 C305 1.353(8) . ?
N4 C401 1.315(8) . ?
N4 C405 1.364(8) . ?
C101 C102 1.386(11) . ?
C102 C103 1.347(13) . ?
C103 C104 1.404(11) . ?
C104 C105 1.403(9) . ?
C104 C106 1.415(11) . ?
C105 C205 1.456(9) . ?
C106 C206 1.318(12) . ?
C201 C202 1.359(12) . ?
C202 C203 1.390(12) . ?
C203 C204 1.409(11) . ?
C204 C205 1.365(10) . ?
C204 C206 1.467(11) . ?
C301 C302 1.400(10) . ?
C302 C303 1.346(12) . ?
C303 C304 1.390(10) . ?
C304 C305 1.400(9) . ?
C304 C306 1.445(11) . ?
C305 C405 1.437(9) . ?
C306 C406 1.319(12) . ?
C401 C402 1.395(12) . ?
C402 C403 1.362(13) . ?
C403 C404 1.428(11) . ?
C404 C405 1.402(10) . ?
C404 C406 1.411(11) . ?
O11 C11 1.203(10) . ?
O12 C11 1.247(9) . ?
C11 C12 1.509(11) . ?
C12 F11 1.315(10) . ?
C12 F12 1.392(12) . ?
C12 C13 1.433(16) . ?
C13 F14 1.304(16) . ?
C13 F15 1.333(13) . ?
C13 F13 1.319(18) . ?
O21 C21 1.217(10) . ?
O22 C21 1.229(10) . ?
C21 C22 1.532(12) . ?
C22 F21 1.258(11) . ?
C22 C23 1.35(2) . ?
C22 F22 1.510(17) . ?
F22 C23 1.94(2) . ?
C23 F24 1.236(17) . ?
C23 F25 1.373(19) . ?
C23 F23 1.52(2) . ?
O31 C31 1.260(11) . ?
O32 C31 1.212(11) . ?
C31 C32 1.549(13) . ?
C32 F31 1.246(15) . ?
C32 C33 1.368(19) . ?
C32 F32 1.545(18) . ?
C33 F34 1.222(16) . ?
C33 F35 1.323(13) . ?
C33 F33 1.45(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O11 Ag1 O31 98.0(2) . . ?
O11 Ag1 C1 123.8(2) . . ?
O31 Ag1 C1 129.6(2) . . ?
O11 Ag1 O21 97.7(3) . . ?
O31 Ag1 O21 89.1(3) . . ?
C1 Ag1 O21 109.4(2) . . ?
O11 Ag1 Ag2 178.2(2) . . ?
O31 Ag1 Ag2 81.26(17) . . ?
C1 Ag1 Ag2 56.12(16) . . ?
O21 Ag1 Ag2 83.91(15) . . ?
O11 Ag1 Ag3 120.1(2) . . ?
O31 Ag1 Ag3 93.83(18) . . ?
C1 Ag1 Ag3 43.11(16) . . ?
O21 Ag1 Ag3 141.13(14) . . ?
Ag2 Ag1 Ag3 58.416(18) . . ?
O11 Ag1 Ag4 74.28(18) . . ?
O31 Ag1 Ag4 130.49(18) . . ?
C1 Ag1 Ag4 53.17(16) . . ?
O21 Ag1 Ag4 140.02(17) . . ?
Ag2 Ag1 Ag4 104.96(2) . . ?
Ag3 Ag1 Ag4 54.572(17) . . ?
O22 Ag2 O32 90.4(3) . . ?
O22 Ag2 C1 110.0(2) . 2 ?
O32 Ag2 C1 115.9(2) . 2 ?
O22 Ag2 C1 104.0(2) . . ?
O32 Ag2 C1 124.1(2) . . ?
C1 Ag2 C1 109.12(18) 2 . ?
O22 Ag2 Ag2 115.8(2) . 2 ?
O32 Ag2 Ag2 153.81(16) . 2 ?
C1 Ag2 Ag2 57.18(16) 2 2 ?
C1 Ag2 Ag2 52.17(14) . 2 ?
O22 Ag2 Ag1 78.27(15) . . ?
O32 Ag2 Ag1 81.66(16) . . ?
C1 Ag2 Ag1 159.74(16) 2 . ?
C1 Ag2 Ag1 50.63(14) . . ?
Ag2 Ag2 Ag1 102.58(3) 2 . ?
O22 Ag2 Ag3 140.83(16) . . ?
O32 Ag2 Ag3 92.36(18) . . ?
C1 Ag2 Ag3 103.73(17) 2 . ?
C1 Ag2 Ag3 44.66(15) . . ?
Ag2 Ag2 Ag3 67.62(2) 2 . ?
Ag1 Ag2 Ag3 63.542(19) . . ?
O22 Ag2 Ag3 150.75(15) . 2 ?
O32 Ag2 Ag3 99.80(15) . 2 ?
C1 Ag2 Ag3 40.99(16) 2 2 ?
C1 Ag2 Ag3 92.93(15) . 2 ?
Ag2 Ag2 Ag3 57.515(16) 2 2 ?
Ag1 Ag2 Ag3 130.12(2) . 2 ?
Ag3 Ag2 Ag3 66.59(2) . 2 ?
C1 Ag3 N4 148.5(2) . . ?
C1 Ag3 N3 133.6(2) . . ?
N4 Ag3 N3 72.89(18) . . ?
C1 Ag3 Ag4 59.52(18) . . ?
N4 Ag3 Ag4 101.61(13) . . ?
N3 Ag3 Ag4 105.19(12) . . ?
C1 Ag3 Ag2 57.55(18) . . ?
N4 Ag3 Ag2 119.00(13) . . ?
N3 Ag3 Ag2 136.44(12) . . ?
Ag4 Ag3 Ag2 111.93(2) . . ?
C1 Ag3 Ag1 49.83(17) . . ?
N4 Ag3 Ag1 100.11(14) . . ?
N3 Ag3 Ag1 165.51(12) . . ?
Ag4 Ag3 Ag1 63.142(18) . . ?
Ag2 Ag3 Ag1 58.043(18) . . ?
C1 Ag3 Ag2 47.75(17) . 2 ?
N4 Ag3 Ag2 160.71(13) . 2 ?
N3 Ag3 Ag2 99.23(12) . 2 ?
Ag4 Ag3 Ag2 97.43(2) . 2 ?
Ag2 Ag3 Ag2 54.86(2) . 2 ?
Ag1 Ag3 Ag2 91.16(2) . 2 ?
O12 Ag4 N2 92.7(2) . . ?
O12 Ag4 N1 131.6(2) . . ?
N2 Ag4 N1 70.42(19) . . ?
O12 Ag4 C1 123.0(2) . . ?
N2 Ag4 C1 130.9(2) . . ?
N1 Ag4 C1 100.4(2) . . ?
O12 Ag4 C2 106.4(2) . . ?
N2 Ag4 C2 157.3(2) . . ?
N1 Ag4 C2 103.8(2) . . ?
C1 Ag4 C2 26.8(2) . . ?
O12 Ag4 Ag3 138.39(17) . . ?
N2 Ag4 Ag3 85.10(13) . . ?
N1 Ag4 Ag3 86.59(13) . . ?
C1 Ag4 Ag3 45.81(15) . . ?
C2 Ag4 Ag3 72.55(16) . . ?
O12 Ag4 Ag1 82.50(15) . . ?
N2 Ag4 Ag1 117.00(13) . . ?
N1 Ag4 Ag1 145.82(13) . . ?
C1 Ag4 Ag1 48.12(14) . . ?
C2 Ag4 Ag1 55.62(14) . . ?
Ag3 Ag4 Ag1 62.285(19) . . ?
C2 C1 Ag3 155.7(6) . . ?
C2 C1 Ag1 93.5(5) . . ?
Ag3 C1 Ag1 87.1(2) . . ?
C2 C1 Ag2 102.3(5) . 2 ?
Ag3 C1 Ag2 91.3(2) . 2 ?
Ag1 C1 Ag2 143.4(3) . 2 ?
C2 C1 Ag4 81.7(4) . . ?
Ag3 C1 Ag4 74.67(19) . . ?
Ag1 C1 Ag4 78.71(19) . . ?
Ag2 C1 Ag4 135.8(3) 2 . ?
C2 C1 Ag2 125.6(5) . . ?
Ag3 C1 Ag2 77.8(2) . . ?
Ag1 C1 Ag2 73.25(18) . . ?
Ag2 C1 Ag2 70.65(18) 2 . ?
Ag4 C1 Ag2 141.3(3) . . ?
C1 C2 C3 172.8(7) . . ?
C1 C2 Ag4 71.5(4) . . ?
C3 C2 Ag4 115.5(5) . . ?
C2 C3 C6 109.3(7) . . ?
C2 C3 C4 110.3(6) . . ?
C6 C3 C4 109.7(8) . . ?
C2 C3 C5 108.2(6) . . ?
C6 C3 C5 110.2(7) . . ?
C4 C3 C5 109.3(8) . . ?
C101 N1 C105 117.5(6) . . ?
C101 N1 Ag4 126.5(5) . . ?
C105 N1 Ag4 116.0(4) . . ?
C201 N2 C205 117.3(7) . . ?
C201 N2 Ag4 125.1(5) . . ?
C205 N2 Ag4 117.5(4) . . ?
C301 N3 C305 119.1(5) . . ?
C301 N3 Ag3 125.8(4) . . ?
C305 N3 Ag3 115.0(4) . . ?
C401 N4 C405 117.8(6) . . ?
C401 N4 Ag3 127.6(5) . . ?
C405 N4 Ag3 114.5(4) . . ?
N1 C101 C102 123.3(8) . . ?
C103 C102 C101 118.9(8) . . ?
C102 C103 C104 120.7(7) . . ?
C103 C104 C105 116.5(7) . . ?
C103 C104 C106 123.3(7) . . ?
C105 C104 C106 120.2(7) . . ?
N1 C105 C104 123.1(6) . . ?
N1 C105 C205 118.2(6) . . ?
C104 C105 C205 118.7(7) . . ?
C206 C106 C104 121.7(7) . . ?
N2 C201 C202 124.2(8) . . ?
C203 C202 C201 119.1(7) . . ?
C202 C203 C204 117.8(8) . . ?
C205 C204 C203 118.6(7) . . ?
C205 C204 C206 120.1(7) . . ?
C203 C204 C206 121.3(8) . . ?
N2 C205 C204 123.0(6) . . ?
N2 C205 C105 117.8(6) . . ?
C204 C205 C105 119.3(6) . . ?
C106 C206 C204 120.1(8) . . ?
N3 C301 C302 121.7(7) . . ?
C303 C302 C301 119.8(7) . . ?
C302 C303 C304 119.7(7) . . ?
C303 C304 C305 118.1(7) . . ?
C303 C304 C306 123.3(7) . . ?
C305 C304 C306 118.5(7) . . ?
N3 C305 C304 121.6(6) . . ?
N3 C305 C405 118.7(5) . . ?
C304 C305 C405 119.7(6) . . ?
C406 C306 C304 121.5(7) . . ?
N4 C401 C402 124.6(8) . . ?
C403 C402 C401 118.4(7) . . ?
C402 C403 C404 119.5(7) . . ?
C405 C404 C406 120.3(7) . . ?
C405 C404 C403 117.3(7) . . ?
C406 C404 C403 122.3(7) . . ?
N4 C405 C404 122.4(6) . . ?
N4 C405 C305 118.8(6) . . ?
C404 C405 C305 118.8(6) . . ?
C306 C406 C404 121.1(7) . . ?
C11 O11 Ag1 130.7(5) . . ?
C11 O12 Ag4 117.6(5) . . ?
O11 C11 O12 132.2(7) . . ?
O11 C11 C12 115.0(8) . . ?
O12 C11 C12 112.8(7) . . ?
F11 C12 F12 100.6(8) . . ?
F11 C12 C13 108.6(9) . . ?
F12 C12 C13 104.1(10) . . ?
F11 C12 C11 112.6(8) . . ?
F12 C12 C11 111.0(8) . . ?
C13 C12 C11 118.2(9) . . ?
F14 C13 F15 105.0(13) . . ?
F14 C13 F13 108.1(15) . . ?
F15 C13 F13 107.0(13) . . ?
F14 C13 C12 114.0(13) . . ?
F15 C13 C12 115.3(12) . . ?
F13 C13 C12 107.1(13) . . ?
C21 O21 Ag1 118.6(5) . . ?
C21 O22 Ag2 128.7(6) . . ?
O22 C21 O21 130.1(8) . . ?
O22 C21 C22 113.6(9) . . ?
O21 C21 C22 116.3(9) . . ?
F21 C22 C23 117.4(13) . . ?
F21 C22 F22 97.8(10) . . ?
C23 C22 F22 85.4(13) . . ?
F21 C22 C21 116.3(10) . . ?
C23 C22 C21 119.7(11) . . ?
F22 C22 C21 112.1(10) . . ?
C22 F22 C23 43.9(7) . . ?
F24 C23 F25 115.1(18) . . ?
F24 C23 C22 122.4(17) . . ?
F25 C23 C22 118.8(15) . . ?
F24 C23 F23 102.4(15) . . ?
F25 C23 F23 97.8(14) . . ?
C22 C23 F23 89.3(15) . . ?
F24 C23 F22 107.1(14) . . ?
F25 C23 F22 94.9(11) . . ?
C22 C23 F22 50.7(11) . . ?
F23 C23 F22 138.9(16) . . ?
C31 O31 Ag1 122.8(6) . . ?
C31 O32 Ag2 121.8(6) . . ?
O32 C31 O31 131.3(8) . . ?
O32 C31 C32 117.5(9) . . ?
O31 C31 C32 111.2(8) . . ?
F31 C32 C33 117.4(12) . . ?
F31 C32 C31 111.1(11) . . ?
C33 C32 C31 125.5(11) . . ?
F31 C32 F32 100.5(12) . . ?
C33 C32 F32 90.7(14) . . ?
C31 C32 F32 103.8(9) . . ?
F34 C33 F35 112.1(13) . . ?
F34 C33 C32 116.6(14) . . ?
F35 C33 C32 112.4(17) . . ?
F34 C33 F33 117(2) . . ?
F35 C33 F33 108.3(14) . . ?
C32 C33 F33 88.5(13) . . ?

_diffrn_measured_fraction_theta_max 0.982
_diffrn_reflns_theta_full        26.00
_diffrn_measured_fraction_theta_full 0.982
_refine_diff_density_max         1.571
_refine_diff_density_min         -0.678
_refine_diff_density_rms         0.107
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_6
_database_code_depnum_ccdc_archive 'CCDC 1032351'
_audit_update_record             
;
2014-11-03 deposited with the CCDC.
2014-12-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C78 H82 Ag10 F12 N2 O8 P2'
_chemical_formula_weight         2544.10

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.7629(3)
_cell_length_b                   15.3551(3)
_cell_length_c                   23.4186(4)
_cell_angle_alpha                90.077(2)
_cell_angle_beta                 92.357(2)
_cell_angle_gamma                104.900(2)
_cell_volume                     4431.07(16)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    20286
_cell_measurement_theta_min      2.3989
_cell_measurement_theta_max      32.7155

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.22
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.907
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2472
_exptl_absorpt_coefficient_mu    2.270
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.65915
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
;
_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Oxford Gemini S Ultra'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            39978
_diffrn_reflns_av_R_equivalents  0.0322
_diffrn_reflns_av_sigmaI/netI    0.0417
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         2.40
_diffrn_reflns_theta_max         25.00
_reflns_number_total             15412
_reflns_number_gt                11618
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       CCD
_computing_cell_refinement       RED
_computing_data_reduction        RED
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0891P)²+4.8874P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         15412
_refine_ls_number_parameters     1009
_refine_ls_number_restraints     48
_refine_ls_R_factor_all          0.0585
_refine_ls_R_factor_gt           0.0391
_refine_ls_wR_factor_ref         0.1406
_refine_ls_wR_factor_gt          0.1138
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_restrained_S_all      1.060
_refine_ls_shift/su_max          0.017
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag -0.44790(5) 0.69756(3) 0.39853(2) 0.04208(15) Uani 1 1 d . . .
Ag2 Ag -0.42062(4) 0.53715(3) 0.34711(2) 0.03179(13) Uani 1 1 d . . .
Ag3 Ag -0.38549(4) 0.43363(3) 0.44931(2) 0.03687(14) Uani 1 1 d . . .
Ag4 Ag -0.57953(4) 0.51843(3) 0.43499(2) 0.03115(13) Uani 1 1 d . . .
Ag5 Ag -0.61251(5) 0.34682(3) 0.48860(2) 0.03926(14) Uani 1 1 d . . .
Ag6 Ag -0.05695(6) 0.82814(4) 0.12123(2) 0.05105(18) Uani 1 1 d . . .
Ag7 Ag -0.07770(5) 0.83902(4) 0.00149(2) 0.04399(15) Uani 1 1 d . . .
Ag8 Ag 0.06509(4) 1.00302(3) 0.06904(2) 0.03103(13) Uani 1 1 d . . .
Ag9 Ag -0.10745(4) 0.99366(3) 0.14724(2) 0.03391(13) Uani 1 1 d . . .
Ag10 Ag -0.14564(5) 1.05527(4) 0.03214(2) 0.03937(14) Uani 1 1 d . . .
P1 P -0.51663(14) 0.59292(11) 0.27062(7) 0.0304(4) Uani 1 1 d . . .
P2 P -0.01832(14) 0.96799(11) 0.23680(7) 0.0284(4) Uani 1 1 d . . .
N1 N -0.4383(4) 0.7633(3) 0.3081(2) 0.0329(13) Uani 1 1 d . . .
N2 N -0.0816(5) 0.7898(3) 0.2173(2) 0.0349(13) Uani 1 1 d . . .
C1 C -0.2872(6) 0.8520(4) 0.4765(3) 0.0369(16) Uani 1 1 d . . .
C2 C -0.2155(8) 0.9475(5) 0.4827(4) 0.061(2) Uani 1 1 d . . .
C3 C -0.2594(6) 0.4109(4) 0.3406(3) 0.0346(16) Uani 1 1 d . . .
C4 C -0.1727(7) 0.3775(5) 0.3084(4) 0.051(2) Uani 1 1 d . . .
C5 C -0.2848(6) 1.1036(5) 0.1301(3) 0.0395(17) Uani 1 1 d . . .
C6 C -0.3735(8) 1.1449(7) 0.1502(4) 0.061(2) Uani 1 1 d . . .
C7 C -0.1436(6) 0.6440(5) 0.0512(3) 0.0389(16) Uani 1 1 d . . .
C8 C -0.1756(9) 0.5399(5) 0.0445(4) 0.060(2) Uani 1 1 d . . .
C11 C -0.5943(6) 0.6418(4) 0.4644(3) 0.0335(15) Uani 1 1 d . . .
C12 C -0.6161(6) 0.7141(5) 0.4653(3) 0.0401(17) Uani 1 1 d . . .
C13 C -0.6542(7) 0.7974(5) 0.4695(4) 0.051(2) Uani 1 1 d . . .
C14 C -0.7574(12) 0.7759(9) 0.4905(7) 0.118(5) Uani 1 1 d U . .
H14A H -0.8071 0.7379 0.4633 0.177 Uiso 1 1 calc R . .
H14B H -0.7797 0.8301 0.4967 0.177 Uiso 1 1 calc R . .
H14C H -0.7570 0.7447 0.5259 0.177 Uiso 1 1 calc R . .
C15 C -0.6107(17) 0.8618(12) 0.4304(9) 0.156(7) Uani 1 1 d U . .
H15A H -0.6438 0.8436 0.3932 0.234 Uiso 1 1 calc R . .
H15B H -0.5339 0.8685 0.4295 0.234 Uiso 1 1 calc R . .
H15C H -0.6241 0.9182 0.4411 0.234 Uiso 1 1 calc R . .
C16 C -0.5806(18) 0.8589(14) 0.5173(9) 0.185(9) Uani 1 1 d U . .
H16A H -0.6028 0.9137 0.5212 0.278 Uiso 1 1 calc R . .
H16B H -0.5062 0.8729 0.5069 0.278 Uiso 1 1 calc R . .
H16C H -0.5880 0.8276 0.5530 0.278 Uiso 1 1 calc R . .
C21 C -0.3218(5) 0.5976(4) 0.4257(3) 0.0265(13) Uani 1 1 d . . .
C22 C -0.2378(6) 0.6066(4) 0.4539(3) 0.0344(15) Uani 1 1 d . . .
C23 C -0.1279(6) 0.6219(5) 0.4800(4) 0.0475(19) Uani 1 1 d . . .
C24 C -0.0616(7) 0.5741(7) 0.4424(4) 0.069(3) Uani 1 1 d . . .
H24A H -0.0952 0.5105 0.4411 0.103 Uiso 1 1 calc R . .
H24B H 0.0110 0.5846 0.4585 0.103 Uiso 1 1 calc R . .
H24C H -0.0596 0.5977 0.4044 0.103 Uiso 1 1 calc R . .
C25 C -0.1318(9) 0.5858(9) 0.5412(5) 0.091(4) Uani 1 1 d . . .
H25A H -0.1726 0.6164 0.5639 0.137 Uiso 1 1 calc R . .
H25B H -0.0593 0.5962 0.5575 0.137 Uiso 1 1 calc R . .
H25C H -0.1659 0.5223 0.5405 0.137 Uiso 1 1 calc R . .
C26 C -0.0708(8) 0.7240(6) 0.4817(5) 0.081(3) Uani 1 1 d . . .
H26A H -0.1102 0.7548 0.5051 0.121 Uiso 1 1 calc R . .
H26B H -0.0688 0.7473 0.4436 0.121 Uiso 1 1 calc R . .
H26C H 0.0019 0.7331 0.4974 0.121 Uiso 1 1 calc R . .
C31 C -0.5667(5) 0.3979(4) 0.3982(3) 0.0311(14) Uani 1 1 d . . .
C32 C -0.5759(6) 0.3357(4) 0.3660(3) 0.0343(15) Uani 1 1 d . . .
C33 C -0.5966(8) 0.2590(5) 0.3220(3) 0.054(2) Uani 1 1 d . . .
C34 C -0.5564(12) 0.2884(9) 0.2666(6) 0.111(4) Uani 1 1 d U . .
H34A H -0.5982 0.3265 0.2499 0.166 Uiso 1 1 calc R . .
H34B H -0.5626 0.2369 0.2422 0.166 Uiso 1 1 calc R . .
H34C H -0.4816 0.3215 0.2709 0.166 Uiso 1 1 calc R . .
C35 C -0.7078(13) 0.2077(10) 0.3247(7) 0.128(5) Uani 1 1 d U . .
H35A H -0.7547 0.2424 0.3092 0.193 Uiso 1 1 calc R . .
H35B H -0.7243 0.1934 0.3637 0.193 Uiso 1 1 calc R . .
H35C H -0.7185 0.1529 0.3028 0.193 Uiso 1 1 calc R . .
C36 C -0.5239(15) 0.1968(11) 0.3493(8) 0.140(6) Uani 1 1 d U . .
H36A H -0.5306 0.1449 0.3252 0.210 Uiso 1 1 calc R . .
H36B H -0.5484 0.1778 0.3866 0.210 Uiso 1 1 calc R . .
H36C H -0.4493 0.2307 0.3523 0.210 Uiso 1 1 calc R . .
C41 C 0.1110(5) 0.8834(4) 0.0585(3) 0.0331(15) Uani 1 1 d . . .
C42 C 0.1497(6) 0.8225(5) 0.0706(3) 0.0404(17) Uani 1 1 d . . .
C43 C 0.2074(7) 0.7528(6) 0.0844(4) 0.057(2) Uani 1 1 d . . .
C44 C 0.3206(9) 0.7991(8) 0.1123(6) 0.097(4) Uani 1 1 d . . .
H44A H 0.3117 0.8282 0.1474 0.146 Uiso 1 1 calc R . .
H44B H 0.3603 0.8431 0.0867 0.146 Uiso 1 1 calc R . .
H44C H 0.3600 0.7545 0.1201 0.146 Uiso 1 1 calc R . .
C45 C 0.2319(13) 0.7092(9) 0.0283(6) 0.116(5) Uani 1 1 d U . .
H45A H 0.1649 0.6797 0.0084 0.174 Uiso 1 1 calc R . .
H45B H 0.2724 0.6659 0.0374 0.174 Uiso 1 1 calc R . .
H45C H 0.2736 0.7551 0.0046 0.174 Uiso 1 1 calc R . .
C46 C 0.1420(13) 0.6853(10) 0.1232(7) 0.127(5) Uani 1 1 d U . .
H46A H 0.0734 0.6569 0.1045 0.191 Uiso 1 1 calc R . .
H46B H 0.1303 0.7149 0.1576 0.191 Uiso 1 1 calc R . .
H46C H 0.1803 0.6406 0.1325 0.191 Uiso 1 1 calc R . .
C51 C -0.1886(5) 0.9011(4) 0.0733(3) 0.0283(14) Uani 1 1 d . . .
C52 C -0.2572(6) 0.8734(5) 0.0392(3) 0.0378(16) Uani 1 1 d . . .
C53 C -0.3597(6) 0.8361(5) 0.0036(3) 0.0449(18) Uani 1 1 d . . .
C54 C -0.4211(8) 0.7470(7) 0.0302(4) 0.071(3) Uani 1 1 d . . .
H54A H -0.3777 0.7045 0.0292 0.107 Uiso 1 1 calc R . .
H54B H -0.4884 0.7232 0.0089 0.107 Uiso 1 1 calc R . .
H54C H -0.4358 0.7577 0.0691 0.107 Uiso 1 1 calc R . .
C55 C -0.3363(8) 0.8146(8) -0.0569(4) 0.079(3) Uani 1 1 d . . .
H55A H -0.2918 0.7728 -0.0561 0.119 Uiso 1 1 calc R . .
H55B H -0.2989 0.8690 -0.0752 0.119 Uiso 1 1 calc R . .
H55C H -0.4034 0.7884 -0.0778 0.119 Uiso 1 1 calc R . .
C56 C -0.4314(8) 0.9036(7) 0.0063(5) 0.073(3) Uani 1 1 d . . .
H56A H -0.3949 0.9594 -0.0108 0.109 Uiso 1 1 calc R . .
H56B H -0.4443 0.9144 0.0455 0.109 Uiso 1 1 calc R . .
H56C H -0.4994 0.8789 -0.0141 0.109 Uiso 1 1 calc R . .
C61 C 0.0327(5) 1.1246(4) 0.0917(3) 0.0289(14) Uani 1 1 d . . .
C62 C 0.0348(5) 1.1950(4) 0.1153(3) 0.0315(14) Uani 1 1 d . . .
C63 C 0.0407(6) 1.2807(4) 0.1467(3) 0.0399(17) Uani 1 1 d . . .
C64 C 0.0057(9) 1.2604(6) 0.2075(4) 0.068(3) Uani 1 1 d . . .
H64A H 0.0537 1.2301 0.2268 0.102 Uiso 1 1 calc R . .
H64B H -0.0670 1.2225 0.2067 0.102 Uiso 1 1 calc R . .
H64C H 0.0083 1.3157 0.2273 0.102 Uiso 1 1 calc R . .
C65 C -0.0352(9) 1.3311(6) 0.1152(5) 0.073(3) Uani 1 1 d . . .
H65A H -0.0124 1.3439 0.0769 0.109 Uiso 1 1 calc R . .
H65B H -0.0317 1.3866 0.1351 0.109 Uiso 1 1 calc R . .
H65C H -0.1084 1.2941 0.1142 0.109 Uiso 1 1 calc R . .
C66 C 0.1580(8) 1.3394(6) 0.1461(4) 0.068(3) Uani 1 1 d . . .
H66A H 0.2055 1.3091 0.1659 0.103 Uiso 1 1 calc R . .
H66B H 0.1627 1.3961 0.1648 0.103 Uiso 1 1 calc R . .
H66C H 0.1791 1.3498 0.1074 0.103 Uiso 1 1 calc R . .
C101 C -0.4549(5) 0.7139(5) 0.2604(3) 0.0354(15) Uani 1 1 d . . .
C102 C -0.4302(6) 0.7494(5) 0.2060(3) 0.0460(19) Uani 1 1 d . . .
H10A H -0.4420 0.7127 0.1735 0.055 Uiso 1 1 calc R . .
C103 C -0.3865(7) 0.8435(5) 0.2028(3) 0.050(2) Uani 1 1 d . . .
H10B H -0.3678 0.8705 0.1678 0.060 Uiso 1 1 calc R . .
C104 C -0.3720(6) 0.8949(5) 0.2526(4) 0.052(2) Uani 1 1 d . . .
H10C H -0.3444 0.9571 0.2518 0.062 Uiso 1 1 calc R . .
C105 C -0.3994(6) 0.8518(5) 0.3027(3) 0.0422(17) Uani 1 1 d . . .
H10D H -0.3901 0.8870 0.3358 0.051 Uiso 1 1 calc R . .
C201 C -0.6585(6) 0.5915(5) 0.2827(3) 0.0376(16) Uani 1 1 d . . .
C202 C -0.7009(7) 0.6623(5) 0.2749(4) 0.059(2) Uani 1 1 d . . .
H20A H -0.6568 0.7169 0.2631 0.071 Uiso 1 1 calc R . .
C203 C -0.8104(8) 0.6554(7) 0.2841(5) 0.079(3) Uani 1 1 d . . .
H20B H -0.8396 0.7043 0.2776 0.095 Uiso 1 1 calc R . .
C204 C -0.8731(7) 0.5764(7) 0.3026(5) 0.072(3) Uani 1 1 d . . .
H20C H -0.9449 0.5726 0.3106 0.086 Uiso 1 1 calc R . .
C205 C -0.8342(7) 0.5020(7) 0.3099(4) 0.062(2) Uani 1 1 d . . .
H20D H -0.8800 0.4474 0.3204 0.074 Uiso 1 1 calc R . .
C206 C -0.7258(6) 0.5090(6) 0.3014(3) 0.0482(19) Uani 1 1 d . . .
H20E H -0.6972 0.4598 0.3080 0.058 Uiso 1 1 calc R . .
C301 C -0.5231(6) 0.5407(4) 0.1998(3) 0.0363(16) Uani 1 1 d . . .
C302 C -0.6008(7) 0.5436(5) 0.1590(3) 0.053(2) Uani 1 1 d . . .
H30A H -0.6545 0.5723 0.1672 0.063 Uiso 1 1 calc R . .
C303 C -0.6019(9) 0.5057(7) 0.1066(4) 0.070(3) Uani 1 1 d . . .
H30B H -0.6565 0.5074 0.0794 0.084 Uiso 1 1 calc R . .
C304 C -0.5219(9) 0.4649(7) 0.0940(4) 0.073(3) Uani 1 1 d . . .
H30C H -0.5218 0.4392 0.0580 0.088 Uiso 1 1 calc R . .
C305 C -0.4404(9) 0.4619(7) 0.1352(4) 0.072(3) Uani 1 1 d . . .
H30D H -0.3856 0.4349 0.1264 0.086 Uiso 1 1 calc R . .
C306 C -0.4409(7) 0.4983(6) 0.1884(3) 0.052(2) Uani 1 1 d . . .
H30E H -0.3881 0.4951 0.2163 0.063 Uiso 1 1 calc R . .
C401 C -0.0791(5) 0.8519(4) 0.2579(3) 0.0308(14) Uani 1 1 d . . .
C402 C -0.1215(6) 0.8291(5) 0.3115(3) 0.0427(18) Uani 1 1 d . . .
H40A H -0.1186 0.8733 0.3391 0.051 Uiso 1 1 calc R . .
C403 C -0.1684(6) 0.7381(5) 0.3228(3) 0.0480(19) Uani 1 1 d . . .
H40B H -0.1993 0.7208 0.3577 0.058 Uiso 1 1 calc R . .
C404 C -0.1676(7) 0.6744(5) 0.2809(4) 0.049(2) Uani 1 1 d . . .
H40C H -0.1954 0.6133 0.2875 0.059 Uiso 1 1 calc R . .
C405 C -0.1246(7) 0.7039(5) 0.2290(3) 0.0459(19) Uani 1 1 d . . .
H40D H -0.1258 0.6610 0.2007 0.055 Uiso 1 1 calc R . .
C501 C 0.1242(5) 0.9709(4) 0.2366(3) 0.0312(14) Uani 1 1 d . . .
C502 C 0.1923(6) 1.0350(4) 0.2019(3) 0.0347(15) Uani 1 1 d . . .
H50A H 0.1635 1.0741 0.1796 0.042 Uiso 1 1 calc R . .
C503 C 0.3032(6) 1.0393(5) 0.2011(3) 0.0410(17) Uani 1 1 d . . .
H50B H 0.3482 1.0815 0.1784 0.049 Uiso 1 1 calc R . .
C504 C 0.3454(7) 0.9820(5) 0.2334(4) 0.050(2) Uani 1 1 d . . .
H50C H 0.4192 0.9856 0.2328 0.060 Uiso 1 1 calc R . .
C505 C 0.2819(7) 0.9203(5) 0.2661(4) 0.055(2) Uani 1 1 d . . .
H50D H 0.3120 0.8809 0.2873 0.066 Uiso 1 1 calc R . .
C506 C 0.1723(6) 0.9145(5) 0.2689(3) 0.0452(18) Uani 1 1 d . . .
H50E H 0.1302 0.8723 0.2927 0.054 Uiso 1 1 calc R . .
C601 C -0.0311(6) 1.0379(4) 0.2969(3) 0.0341(15) Uani 1 1 d . . .
C602 C -0.1211(6) 1.0753(5) 0.2949(3) 0.0389(16) Uani 1 1 d . . .
H60A H -0.1705 1.0628 0.2638 0.047 Uiso 1 1 calc R . .
C603 C -0.1366(7) 1.1295(5) 0.3379(3) 0.050(2) Uani 1 1 d . . .
H60B H -0.1967 1.1532 0.3368 0.060 Uiso 1 1 calc R . .
C604 C -0.0597(8) 1.1493(6) 0.3844(4) 0.061(2) Uani 1 1 d . . .
H60C H -0.0701 1.1854 0.4145 0.073 Uiso 1 1 calc R . .
C605 C 0.0280(9) 1.1164(6) 0.3855(4) 0.067(3) Uani 1 1 d . . .
H60D H 0.0801 1.1325 0.4153 0.081 Uiso 1 1 calc R . .
C606 C 0.0416(7) 1.0584(5) 0.3424(3) 0.052(2) Uani 1 1 d . . .
H60E H 0.1007 1.0334 0.3446 0.063 Uiso 1 1 calc R . .
O1 O -0.3287(5) 0.8334(3) 0.4275(3) 0.0610(16) Uani 1 1 d . . .
O2 O -0.2990(5) 0.8062(3) 0.5201(2) 0.0557(15) Uani 1 1 d . . .
O3 O -0.3026(4) 0.4589(3) 0.3130(2) 0.0388(11) Uani 1 1 d . . .
O4 O -0.2716(5) 0.3818(3) 0.3899(2) 0.0477(13) Uani 1 1 d . . .
O5 O -0.2709(4) 1.1159(3) 0.0773(2) 0.0457(12) Uani 1 1 d . . .
O6 O -0.2452(4) 1.0631(4) 0.1649(2) 0.0438(12) Uani 1 1 d . . .
O7 O -0.1445(6) 0.6840(4) 0.0048(3) 0.0610(16) Uani 1 1 d . . .
O8 O -0.1197(5) 0.6744(3) 0.0990(2) 0.0561(15) Uani 1 1 d . . .
F1 F -0.2110(7) 0.9801(4) 0.5359(3) 0.105(2) Uani 1 1 d . . .
F2 F -0.1136(5) 0.9496(4) 0.4727(4) 0.107(2) Uani 1 1 d . . .
F3 F -0.2464(6) 1.0070(3) 0.4512(3) 0.092(2) Uani 1 1 d . . .
F4 F -0.1241(5) 0.4379(4) 0.2702(3) 0.094(2) Uani 1 1 d . . .
F5 F -0.0942(5) 0.3623(4) 0.3424(3) 0.0855(18) Uani 1 1 d . . .
F6 F -0.2167(5) 0.3038(4) 0.2798(3) 0.091(2) Uani 1 1 d . . .
F7 F -0.4708(6) 1.0902(8) 0.1377(4) 0.155(4) Uani 1 1 d . . .
F8 F -0.3790(8) 1.2171(6) 0.1284(4) 0.151(4) Uani 1 1 d . . .
F9 F -0.3774(8) 1.1452(7) 0.2074(3) 0.141(4) Uani 1 1 d . . .
F10 F -0.1707(6) 0.4994(4) 0.0932(3) 0.111(3) Uani 1 1 d . . .
F11 F -0.2779(6) 0.5104(4) 0.0261(2) 0.087(2) Uani 1 1 d . . .
F12 F -0.1165(8) 0.5131(4) 0.0089(5) 0.150(4) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O1 2.325(5) . ?
Ag1 N1 2.342(5) . ?
Ag1 C11 2.454(6) . ?
Ag1 C21 2.557(6) . ?
Ag1 Ag2 2.8471(7) . ?
Ag1 Ag5 2.8554(8) 2_466 ?
Ag1 Ag4 2.9774(7) . ?
Ag2 C21 2.245(6) . ?
Ag2 O3 2.319(5) . ?
Ag2 P1 2.4098(17) . ?
Ag2 Ag4 2.9113(7) . ?
Ag2 Ag3 2.9571(7) . ?
Ag3 C11 2.321(6) 2_466 ?
Ag3 O4 2.333(5) . ?
Ag3 C31 2.490(6) . ?
Ag3 C21 2.508(6) . ?
Ag3 Ag4 2.8890(7) 2_466 ?
Ag3 Ag5 3.0422(8) . ?
Ag3 Ag4 3.0875(7) . ?
Ag4 C11 2.071(7) . ?
Ag4 C31 2.088(7) . ?
Ag4 Ag5 2.8601(7) . ?
Ag4 Ag3 2.8890(7) 2_466 ?
Ag4 Ag5 3.2422(8) 2_466 ?
Ag5 C31 2.305(6) . ?
Ag5 O2 2.335(5) 2_466 ?
Ag5 C21 2.441(6) 2_466 ?
Ag5 C22 2.624(7) 2_466 ?
Ag5 Ag1 2.8554(8) 2_466 ?
Ag5 Ag4 3.2422(8) 2_466 ?
Ag6 O8 2.340(5) . ?
Ag6 N2 2.340(5) . ?
Ag6 C51 2.480(7) . ?
Ag6 C41 2.607(7) . ?
Ag6 Ag7 2.8150(8) . ?
Ag6 Ag9 2.8490(8) . ?
Ag6 Ag8 3.0241(7) . ?
Ag7 C61 2.312(6) 2_575 ?
Ag7 O7 2.315(5) . ?
Ag7 C51 2.573(6) . ?
Ag7 C41 2.634(7) . ?
Ag7 C52 2.664(7) . ?
Ag7 Ag8 2.9101(7) 2_575 ?
Ag7 Ag10 3.0314(8) 2_575 ?
Ag7 Ag8 3.0915(8) . ?
Ag8 C41 2.083(7) . ?
Ag8 C61 2.087(7) . ?
Ag8 Ag10 2.8532(7) 2_575 ?
Ag8 Ag9 2.8971(7) . ?
Ag8 Ag7 2.9101(7) 2_575 ?
Ag8 Ag10 3.0893(8) . ?
Ag9 C51 2.276(6) . ?
Ag9 O6 2.329(5) . ?
Ag9 P2 2.4260(17) . ?
Ag9 C61 2.699(6) . ?
Ag9 Ag10 2.9212(7) . ?
Ag10 C41 2.337(6) 2_575 ?
Ag10 O5 2.332(5) . ?
Ag10 C51 2.494(6) . ?
Ag10 C61 2.597(6) . ?
Ag10 Ag8 2.8531(7) 2_575 ?
Ag10 Ag7 3.0313(8) 2_575 ?
P1 C301 1.830(7) . ?
P1 C101 1.841(7) . ?
P1 C201 1.839(7) . ?
P2 C501 1.808(7) . ?
P2 C601 1.807(7) . ?
P2 C401 1.829(6) . ?
N1 C101 1.328(9) . ?
N1 C105 1.329(9) . ?
N2 C405 1.327(8) . ?
N2 C401 1.338(9) . ?
C1 O2 1.232(9) . ?
C1 O1 1.246(9) . ?
C1 C2 1.519(10) . ?
C2 F3 1.304(10) . ?
C2 F2 1.322(11) . ?
C2 F1 1.335(11) . ?
C3 O3 1.201(9) . ?
C3 O4 1.240(9) . ?
C3 C4 1.553(9) . ?
C4 F6 1.298(10) . ?
C4 F5 1.321(11) . ?
C4 F4 1.341(10) . ?
C5 O6 1.199(9) . ?
C5 O5 1.264(9) . ?
C5 C6 1.522(10) . ?
C6 F8 1.238(11) . ?
C6 F7 1.329(13) . ?
C6 F9 1.343(11) . ?
C7 O8 1.209(9) . ?
C7 O7 1.249(9) . ?
C7 C8 1.551(10) . ?
C8 F12 1.283(11) . ?
C8 F10 1.306(11) . ?
C8 F11 1.322(12) . ?
C11 C12 1.212(9) . ?
C11 Ag3 2.321(6) 2_466 ?
C12 C13 1.486(10) . ?
C13 C15 1.372(17) . ?
C13 C14 1.385(15) . ?
C13 C16 1.58(2) . ?
C15 C16 2.06(3) . ?
C21 C22 1.212(10) . ?
C21 Ag5 2.441(6) 2_466 ?
C22 C23 1.469(11) . ?
C22 Ag5 2.624(7) 2_466 ?
C23 C25 1.536(13) . ?
C23 C26 1.549(12) . ?
C23 C24 1.550(11) . ?
C31 C32 1.195(9) . ?
C32 C33 1.526(9) . ?
C33 C34 1.446(14) . ?
C33 C35 1.439(16) . ?
C33 C36 1.609(19) . ?
C41 C42 1.194(10) . ?
C41 Ag10 2.337(6) 2_575 ?
C42 C43 1.476(10) . ?
C43 C46 1.489(16) . ?
C43 C45 1.553(16) . ?
C43 C44 1.554(13) . ?
C51 C52 1.155(10) . ?
C52 C53 1.503(10) . ?
C53 C55 1.514(12) . ?
C53 C54 1.538(12) . ?
C53 C56 1.552(12) . ?
C61 C62 1.207(9) . ?
C61 Ag7 2.312(6) 2_575 ?
C62 C63 1.490(9) . ?
C63 C64 1.518(11) . ?
C63 C66 1.537(11) . ?
C63 C65 1.552(12) . ?
C101 C102 1.403(9) . ?
C102 C103 1.411(11) . ?
C103 C104 1.387(12) . ?
C104 C105 1.362(10) . ?
C201 C202 1.343(11) . ?
C201 C206 1.416(10) . ?
C202 C203 1.400(12) . ?
C203 C204 1.354(13) . ?
C204 C205 1.365(13) . ?
C205 C206 1.383(12) . ?
C301 C302 1.359(11) . ?
C301 C306 1.404(11) . ?
C302 C303 1.356(11) . ?
C303 C304 1.369(15) . ?
C304 C305 1.400(15) . ?
C305 C306 1.365(12) . ?
C401 C402 1.396(9) . ?
C402 C403 1.402(10) . ?
C403 C404 1.387(12) . ?
C404 C405 1.382(11) . ?
C501 C506 1.391(10) . ?
C501 C502 1.417(9) . ?
C502 C503 1.401(10) . ?
C503 C504 1.359(11) . ?
C504 C505 1.342(11) . ?
C505 C506 1.382(11) . ?
C601 C606 1.366(11) . ?
C601 C602 1.410(10) . ?
C602 C603 1.358(10) . ?
C603 C604 1.414(13) . ?
C604 C605 1.341(14) . ?
C605 C606 1.392(11) . ?
O2 Ag5 2.335(5) 2_466 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Ag1 N1 84.40(19) . . ?
O1 Ag1 C11 113.7(2) . . ?
N1 Ag1 C11 134.4(2) . . ?
O1 Ag1 C21 96.5(2) . . ?
N1 Ag1 C21 119.4(2) . . ?
C11 Ag1 C21 100.5(2) . . ?
O1 Ag1 Ag2 133.76(18) . . ?
N1 Ag1 Ag2 88.95(14) . . ?
C11 Ag1 Ag2 103.37(16) . . ?
C21 Ag1 Ag2 48.73(14) . . ?
O1 Ag1 Ag5 79.56(14) . 2_466 ?
N1 Ag1 Ag5 161.00(13) . 2_466 ?
C11 Ag1 Ag5 62.64(16) . 2_466 ?
C21 Ag1 Ag5 53.28(14) . 2_466 ?
Ag2 Ag1 Ag5 94.79(2) . 2_466 ?
O1 Ag1 Ag4 146.08(14) . . ?
N1 Ag1 Ag4 129.44(13) . . ?
C11 Ag1 Ag4 43.50(16) . . ?
C21 Ag1 Ag4 70.59(13) . . ?
Ag2 Ag1 Ag4 59.930(16) . . ?
Ag5 Ag1 Ag4 67.502(18) 2_466 . ?
C21 Ag2 O3 98.0(2) . . ?
C21 Ag2 P1 135.32(15) . . ?
O3 Ag2 P1 111.93(13) . . ?
C21 Ag2 Ag1 58.88(16) . . ?
O3 Ag2 Ag1 147.81(13) . . ?
P1 Ag2 Ag1 79.32(4) . . ?
C21 Ag2 Ag4 75.96(16) . . ?
O3 Ag2 Ag4 138.53(12) . . ?
P1 Ag2 Ag4 99.35(5) . . ?
Ag1 Ag2 Ag4 62.258(17) . . ?
C21 Ag2 Ag3 55.65(14) . . ?
O3 Ag2 Ag3 79.08(12) . . ?
P1 Ag2 Ag3 158.95(5) . . ?
Ag1 Ag2 Ag3 101.02(2) . . ?
Ag4 Ag2 Ag3 63.482(17) . . ?
C11 Ag3 O4 111.9(2) 2_466 . ?
C11 Ag3 C31 107.5(2) 2_466 . ?
O4 Ag3 C31 105.9(2) . . ?
C11 Ag3 C21 132.2(2) 2_466 . ?
O4 Ag3 C21 97.31(19) . . ?
C31 Ag3 C21 99.2(2) . . ?
C11 Ag3 Ag4 45.22(17) 2_466 2_466 ?
O4 Ag3 Ag4 145.54(14) . 2_466 ?
C31 Ag3 Ag4 106.17(15) . 2_466 ?
C21 Ag3 Ag4 89.86(14) . 2_466 ?
C11 Ag3 Ag2 163.66(17) 2_466 . ?
O4 Ag3 Ag2 82.95(13) . . ?
C31 Ag3 Ag2 60.17(14) . . ?
C21 Ag3 Ag2 47.64(15) . . ?
Ag4 Ag3 Ag2 124.55(2) 2_466 . ?
C11 Ag3 Ag5 60.71(18) 2_466 . ?
O4 Ag3 Ag5 131.99(13) . . ?
C31 Ag3 Ag5 47.97(14) . . ?
C21 Ag3 Ag5 123.08(15) . . ?
Ag4 Ag3 Ag5 66.214(18) 2_466 . ?
Ag2 Ag3 Ag5 104.59(2) . . ?
C11 Ag3 Ag4 106.21(17) 2_466 . ?
O4 Ag3 Ag4 137.16(14) . . ?
C31 Ag3 Ag4 42.30(16) . . ?
C21 Ag3 Ag4 69.28(15) . . ?
Ag4 Ag3 Ag4 76.79(2) 2_466 . ?
Ag2 Ag3 Ag4 57.537(16) . . ?
Ag5 Ag3 Ag4 55.621(16) . . ?
C11 Ag4 C31 175.0(2) . . ?
C11 Ag4 Ag5 131.82(17) . . ?
C31 Ag4 Ag5 52.76(17) . . ?
C11 Ag4 Ag3 52.73(17) . 2_466 ?
C31 Ag4 Ag3 132.07(17) . 2_466 ?
Ag5 Ag4 Ag3 79.50(2) . 2_466 ?
C11 Ag4 Ag2 112.40(17) . . ?
C31 Ag4 Ag2 64.59(17) . . ?
Ag5 Ag4 Ag2 110.66(2) . . ?
Ag3 Ag4 Ag2 144.93(2) 2_466 . ?
C11 Ag4 Ag1 54.67(17) . . ?
C31 Ag4 Ag1 122.39(17) . . ?
Ag5 Ag4 Ag1 154.73(3) . . ?
Ag3 Ag4 Ag1 98.38(2) 2_466 . ?
Ag2 Ag4 Ag1 57.812(17) . . ?
C11 Ag4 Ag3 129.2(2) . . ?
C31 Ag4 Ag3 53.38(18) . . ?
Ag5 Ag4 Ag3 61.387(18) . . ?
Ag3 Ag4 Ag3 103.21(2) 2_466 . ?
Ag2 Ag4 Ag3 58.980(16) . . ?
Ag1 Ag4 Ag3 95.22(2) . . ?
C11 Ag4 Ag5 58.2(2) . 2_466 ?
C31 Ag4 Ag5 124.25(18) . 2_466 ?
Ag5 Ag4 Ag5 105.29(2) . 2_466 ?
Ag3 Ag4 Ag5 59.162(17) 2_466 2_466 ?
Ag2 Ag4 Ag5 85.832(19) . 2_466 ?
Ag1 Ag4 Ag5 54.456(16) . 2_466 ?
Ag3 Ag4 Ag5 70.964(18) . 2_466 ?
C31 Ag5 O2 107.2(2) . 2_466 ?
C31 Ag5 C21 137.5(2) . 2_466 ?
O2 Ag5 C21 106.65(19) 2_466 2_466 ?
C31 Ag5 C22 123.4(2) . 2_466 ?
O2 Ag5 C22 96.5(2) 2_466 2_466 ?
C21 Ag5 C22 27.4(2) 2_466 2_466 ?
C31 Ag5 Ag1 150.63(16) . 2_466 ?
O2 Ag5 Ag1 84.85(14) 2_466 2_466 ?
C21 Ag5 Ag1 57.10(15) 2_466 2_466 ?
C22 Ag5 Ag1 80.11(15) 2_466 2_466 ?
C31 Ag5 Ag4 46.16(17) . . ?
O2 Ag5 Ag4 144.70(15) 2_466 . ?
C21 Ag5 Ag4 91.89(13) 2_466 . ?
C22 Ag5 Ag4 86.33(14) 2_466 . ?
Ag1 Ag5 Ag4 130.06(2) 2_466 . ?
C31 Ag5 Ag3 53.37(16) . . ?
O2 Ag5 Ag3 125.26(16) 2_466 . ?
C21 Ag5 Ag3 120.40(15) 2_466 . ?
C22 Ag5 Ag3 138.01(15) 2_466 . ?
Ag1 Ag5 Ag3 97.64(2) 2_466 . ?
Ag4 Ag5 Ag3 62.992(17) . . ?
C31 Ag5 Ag4 100.53(16) . 2_466 ?
O2 Ag5 Ag4 140.03(15) 2_466 2_466 ?
C21 Ag5 Ag4 67.23(15) 2_466 2_466 ?
C22 Ag5 Ag4 91.53(16) 2_466 2_466 ?
Ag1 Ag5 Ag4 58.042(17) 2_466 2_466 ?
Ag4 Ag5 Ag4 74.71(2) . 2_466 ?
Ag3 Ag5 Ag4 54.625(16) . 2_466 ?
O8 Ag6 N2 87.58(19) . . ?
O8 Ag6 C51 105.8(2) . . ?
N2 Ag6 C51 117.5(2) . . ?
O8 Ag6 C41 104.1(2) . . ?
N2 Ag6 C41 134.9(2) . . ?
C51 Ag6 C41 101.2(2) . . ?
O8 Ag6 Ag7 80.87(14) . . ?
N2 Ag6 Ag7 165.12(14) . . ?
C51 Ag6 Ag7 57.74(14) . . ?
C41 Ag6 Ag7 57.98(15) . . ?
O8 Ag6 Ag9 148.07(17) . . ?
N2 Ag6 Ag9 87.87(14) . . ?
C51 Ag6 Ag9 49.98(14) . . ?
C41 Ag6 Ag9 101.39(15) . . ?
Ag7 Ag6 Ag9 96.95(2) . . ?
O8 Ag6 Ag8 140.51(14) . . ?
N2 Ag6 Ag8 129.87(13) . . ?
C51 Ag6 Ag8 70.80(14) . . ?
C41 Ag6 Ag8 42.63(14) . . ?
Ag7 Ag6 Ag8 63.820(19) . . ?
Ag9 Ag6 Ag8 59.024(17) . . ?
C61 Ag7 O7 107.4(2) 2_575 . ?
C61 Ag7 C51 133.0(2) 2_575 . ?
O7 Ag7 C51 104.8(2) . . ?
C61 Ag7 C41 103.4(2) 2_575 . ?
O7 Ag7 C41 108.2(2) . . ?
C51 Ag7 C41 98.0(2) . . ?
C61 Ag7 C52 118.4(2) 2_575 . ?
O7 Ag7 C52 94.5(2) . . ?
C51 Ag7 C52 25.4(2) . . ?
C41 Ag7 C52 123.4(2) . . ?
C61 Ag7 Ag6 160.07(16) 2_575 . ?
O7 Ag7 Ag6 84.51(15) . . ?
C51 Ag7 Ag6 54.59(14) . . ?
C41 Ag7 Ag6 57.06(15) . . ?
C52 Ag7 Ag6 75.31(16) . . ?
C61 Ag7 Ag8 45.33(16) 2_575 2_575 ?
O7 Ag7 Ag8 144.34(15) . 2_575 ?
C51 Ag7 Ag8 89.71(13) . 2_575 ?
C41 Ag7 Ag8 101.61(14) . 2_575 ?
C52 Ag7 Ag8 84.84(15) . 2_575 ?
Ag6 Ag7 Ag8 129.06(3) . 2_575 ?
C61 Ag7 Ag10 56.24(15) 2_575 2_575 ?
O7 Ag7 Ag10 127.72(17) . 2_575 ?
C51 Ag7 Ag10 122.27(14) . 2_575 ?
C41 Ag7 Ag10 48.08(14) . 2_575 ?
C52 Ag7 Ag10 137.76(15) . 2_575 ?
Ag6 Ag7 Ag10 103.83(3) . 2_575 ?
Ag8 Ag7 Ag10 62.620(18) 2_575 2_575 ?
C61 Ag7 Ag8 102.12(16) 2_575 . ?
O7 Ag7 Ag8 142.80(16) . . ?
C51 Ag7 Ag8 68.55(14) . . ?
C41 Ag7 Ag8 41.72(15) . . ?
C52 Ag7 Ag8 90.91(16) . . ?
Ag6 Ag7 Ag8 61.382(19) . . ?
Ag8 Ag7 Ag8 72.79(2) 2_575 . ?
Ag10 Ag7 Ag8 55.537(17) 2_575 . ?
C41 Ag8 C61 171.1(3) . . ?
C41 Ag8 Ag10 53.80(18) . 2_575 ?
C61 Ag8 Ag10 132.21(17) . 2_575 ?
C41 Ag8 Ag9 115.07(18) . . ?
C61 Ag8 Ag9 63.14(17) . . ?
Ag10 Ag8 Ag9 151.06(2) 2_575 . ?
C41 Ag8 Ag7 133.91(18) . 2_575 ?
C61 Ag8 Ag7 52.00(17) . 2_575 ?
Ag10 Ag8 Ag7 80.33(2) 2_575 2_575 ?
Ag9 Ag8 Ag7 107.37(2) . 2_575 ?
C41 Ag8 Ag6 57.94(18) . . ?
C61 Ag8 Ag6 120.54(17) . . ?
Ag10 Ag8 Ag6 103.08(2) 2_575 . ?
Ag9 Ag8 Ag6 57.473(19) . . ?
Ag7 Ag8 Ag6 152.75(3) 2_575 . ?
C41 Ag8 Ag10 131.16(19) . . ?
C61 Ag8 Ag10 56.31(17) . . ?
Ag10 Ag8 Ag10 106.41(2) 2_575 . ?
Ag9 Ag8 Ag10 58.307(16) . . ?
Ag7 Ag8 Ag10 60.612(19) 2_575 . ?
Ag6 Ag8 Ag10 92.96(2) . . ?
C41 Ag8 Ag7 57.30(19) . . ?
C61 Ag8 Ag7 130.18(17) . . ?
Ag10 Ag8 Ag7 61.163(18) 2_575 . ?
Ag9 Ag8 Ag7 90.10(2) . . ?
Ag7 Ag8 Ag7 107.21(2) 2_575 . ?
Ag6 Ag8 Ag7 54.798(17) . . ?
Ag10 Ag8 Ag7 73.94(2) . . ?
C51 Ag9 O6 99.5(2) . . ?
C51 Ag9 P2 132.98(16) . . ?
O6 Ag9 P2 109.77(13) . . ?
C51 Ag9 C61 101.2(2) . . ?
O6 Ag9 C61 101.40(19) . . ?
P2 Ag9 C61 107.73(14) . . ?
C51 Ag9 Ag6 56.56(16) . . ?
O6 Ag9 Ag6 145.61(13) . . ?
P2 Ag9 Ag6 79.61(4) . . ?
C61 Ag9 Ag6 107.06(14) . . ?
C51 Ag9 Ag8 75.90(17) . . ?
O6 Ag9 Ag8 140.20(12) . . ?
P2 Ag9 Ag8 100.80(4) . . ?
C61 Ag9 Ag8 43.60(14) . . ?
Ag6 Ag9 Ag8 63.503(19) . . ?
C51 Ag9 Ag10 55.69(15) . . ?
O6 Ag9 Ag10 80.47(12) . . ?
P2 Ag9 Ag10 162.08(5) . . ?
C61 Ag9 Ag10 54.88(13) . . ?
Ag6 Ag9 Ag10 100.39(2) . . ?
Ag8 Ag9 Ag10 64.140(18) . . ?
C41 Ag10 O5 111.0(2) 2_575 . ?
C41 Ag10 C51 136.0(2) 2_575 . ?
O5 Ag10 C51 100.5(2) . . ?
C41 Ag10 C61 103.8(2) 2_575 . ?
O5 Ag10 C61 102.3(2) . . ?
C51 Ag10 C61 98.4(2) . . ?
C41 Ag10 Ag8 46.01(17) 2_575 2_575 ?
O5 Ag10 Ag8 150.48(13) . 2_575 ?
C51 Ag10 Ag8 92.64(15) . 2_575 ?
C61 Ag10 Ag8 101.75(14) . 2_575 ?
C41 Ag10 Ag9 160.20(16) 2_575 . ?
O5 Ag10 Ag9 82.94(13) . . ?
C51 Ag10 Ag9 48.93(14) . . ?
C61 Ag10 Ag9 58.20(13) . . ?
Ag8 Ag10 Ag9 124.68(2) 2_575 . ?
C41 Ag10 Ag7 57.03(17) 2_575 2_575 ?
O5 Ag10 Ag7 125.14(13) . 2_575 ?
C51 Ag10 Ag7 125.00(16) . 2_575 ?
C61 Ag10 Ag7 47.74(14) . 2_575 ?
Ag8 Ag10 Ag7 63.299(18) 2_575 2_575 ?
Ag9 Ag10 Ag7 103.63(2) . 2_575 ?
C41 Ag10 Ag8 103.99(16) 2_575 . ?
O5 Ag10 Ag8 135.81(13) . . ?
C51 Ag10 Ag8 69.48(16) . . ?
C61 Ag10 Ag8 41.94(14) . . ?
Ag8 Ag10 Ag8 73.59(2) 2_575 . ?
Ag9 Ag10 Ag8 57.552(17) . . ?
Ag7 Ag10 Ag8 56.768(17) 2_575 . ?
C301 P1 C101 105.5(3) . . ?
C301 P1 C201 103.7(3) . . ?
C101 P1 C201 101.8(3) . . ?
C301 P1 Ag2 117.8(2) . . ?
C101 P1 Ag2 110.0(2) . . ?
C201 P1 Ag2 116.3(2) . . ?
C501 P2 C601 105.3(3) . . ?
C501 P2 C401 102.0(3) . . ?
C601 P2 C401 105.8(3) . . ?
C501 P2 Ag9 118.0(2) . . ?
C601 P2 Ag9 116.5(2) . . ?
C401 P2 Ag9 107.7(2) . . ?
C101 N1 C105 117.0(6) . . ?
C101 N1 Ag1 121.7(4) . . ?
C105 N1 Ag1 120.4(5) . . ?
C405 N2 C401 118.5(6) . . ?
C405 N2 Ag6 117.5(5) . . ?
C401 N2 Ag6 121.9(4) . . ?
O2 C1 O1 129.9(7) . . ?
O2 C1 C2 116.6(7) . . ?
O1 C1 C2 113.5(7) . . ?
F3 C2 F2 109.6(8) . . ?
F3 C2 F1 104.1(7) . . ?
F2 C2 F1 104.2(9) . . ?
F3 C2 C1 115.0(8) . . ?
F2 C2 C1 110.6(7) . . ?
F1 C2 C1 112.6(8) . . ?
O3 C3 O4 132.2(6) . . ?
O3 C3 C4 114.5(7) . . ?
O4 C3 C4 113.3(7) . . ?
F6 C4 F5 107.9(7) . . ?
F6 C4 F4 106.3(8) . . ?
F5 C4 F4 106.1(7) . . ?
F6 C4 C3 111.1(7) . . ?
F5 C4 C3 113.7(7) . . ?
F4 C4 C3 111.4(6) . . ?
O6 C5 O5 132.0(7) . . ?
O6 C5 C6 116.6(7) . . ?
O5 C5 C6 111.3(7) . . ?
F8 C6 F7 103.5(9) . . ?
F8 C6 F9 113.3(9) . . ?
F7 C6 F9 98.8(9) . . ?
F8 C6 C5 117.0(8) . . ?
F7 C6 C5 110.4(8) . . ?
F9 C6 C5 111.9(7) . . ?
O8 C7 O7 129.7(7) . . ?
O8 C7 C8 116.9(7) . . ?
O7 C7 C8 113.4(7) . . ?
F12 C8 F10 109.3(9) . . ?
F12 C8 F11 107.8(9) . . ?
F10 C8 F11 104.4(8) . . ?
F12 C8 C7 111.7(8) . . ?
F10 C8 C7 112.5(7) . . ?
F11 C8 C7 110.7(8) . . ?
C12 C11 Ag4 160.5(6) . . ?
C12 C11 Ag3 114.3(5) . 2_466 ?
Ag4 C11 Ag3 82.1(2) . 2_466 ?
C12 C11 Ag1 91.7(5) . . ?
Ag4 C11 Ag1 81.8(2) . . ?
Ag3 C11 Ag1 136.8(3) 2_466 . ?
C11 C12 C13 173.6(7) . . ?
C15 C13 C14 128.7(12) . . ?
C15 C13 C12 114.0(10) . . ?
C14 C13 C12 109.1(8) . . ?
C15 C13 C16 88.3(12) . . ?
C14 C13 C16 104.8(12) . . ?
C12 C13 C16 107.1(11) . . ?
C13 C15 C16 49.9(9) . . ?
C13 C16 C15 41.8(8) . . ?
C22 C21 Ag2 146.8(5) . . ?
C22 C21 Ag5 84.7(4) . 2_466 ?
Ag2 C21 Ag5 127.1(3) . 2_466 ?
C22 C21 Ag3 92.5(4) . . ?
Ag2 C21 Ag3 76.71(17) . . ?
Ag5 C21 Ag3 95.9(2) 2_466 . ?
C22 C21 Ag1 135.9(5) . . ?
Ag2 C21 Ag1 72.39(19) . . ?
Ag5 C21 Ag1 69.63(16) 2_466 . ?
Ag3 C21 Ag1 124.3(3) . . ?
C21 C22 C23 171.3(7) . . ?
C21 C22 Ag5 67.9(4) . 2_466 ?
C23 C22 Ag5 118.9(5) . 2_466 ?
C22 C23 C25 110.7(7) . . ?
C22 C23 C26 110.1(7) . . ?
C25 C23 C26 108.8(8) . . ?
C22 C23 C24 108.5(7) . . ?
C25 C23 C24 110.6(8) . . ?
C26 C23 C24 108.1(8) . . ?
C32 C31 Ag4 162.6(6) . . ?
C32 C31 Ag5 110.3(5) . . ?
Ag4 C31 Ag5 81.1(2) . . ?
C32 C31 Ag3 110.4(5) . . ?
Ag4 C31 Ag3 84.3(2) . . ?
Ag5 C31 Ag3 78.65(19) . . ?
C31 C32 C33 174.6(8) . . ?
C34 C33 C35 117.9(11) . . ?
C34 C33 C32 112.9(7) . . ?
C35 C33 C32 108.5(9) . . ?
C34 C33 C36 108.3(11) . . ?
C35 C33 C36 106.3(10) . . ?
C32 C33 C36 101.4(9) . . ?
C42 C41 Ag8 158.2(6) . . ?
C42 C41 Ag10 116.4(5) . 2_575 ?
Ag8 C41 Ag10 80.2(2) . 2_575 ?
C42 C41 Ag6 94.8(5) . . ?
Ag8 C41 Ag6 79.4(2) . . ?
Ag10 C41 Ag6 137.2(3) 2_575 . ?
C42 C41 Ag7 115.8(6) . . ?
Ag8 C41 Ag7 81.0(2) . . ?
Ag10 C41 Ag7 74.89(18) 2_575 . ?
Ag6 C41 Ag7 64.96(16) . . ?
C41 C42 C43 174.7(8) . . ?
C42 C43 C46 109.8(9) . . ?
C42 C43 C45 109.6(8) . . ?
C46 C43 C45 112.3(10) . . ?
C42 C43 C44 108.8(7) . . ?
C46 C43 C44 111.3(10) . . ?
C45 C43 C44 104.8(10) . . ?
C52 C51 Ag9 153.8(6) . . ?
C52 C51 Ag6 130.6(5) . . ?
Ag9 C51 Ag6 73.46(19) . . ?
C52 C51 Ag10 92.7(5) . . ?
Ag9 C51 Ag10 75.37(17) . . ?
Ag6 C51 Ag10 126.1(3) . . ?
C52 C51 Ag7 81.7(5) . . ?
Ag9 C51 Ag7 121.8(3) . . ?
Ag6 C51 Ag7 67.67(17) . . ?
Ag10 C51 Ag7 94.4(2) . . ?
C51 C52 C53 169.8(8) . . ?
C51 C52 Ag7 72.9(5) . . ?
C53 C52 Ag7 116.2(5) . . ?
C52 C53 C55 111.9(7) . . ?
C52 C53 C54 108.1(6) . . ?
C55 C53 C54 107.0(8) . . ?
C52 C53 C56 108.4(7) . . ?
C55 C53 C56 112.9(8) . . ?
C54 C53 C56 108.3(8) . . ?
C62 C61 Ag8 163.1(5) . . ?
C62 C61 Ag7 105.8(5) . 2_575 ?
Ag8 C61 Ag7 82.7(2) . 2_575 ?
C62 C61 Ag10 114.2(5) . . ?
Ag8 C61 Ag10 81.7(2) . . ?
Ag7 C61 Ag10 76.02(18) 2_575 . ?
C62 C61 Ag9 107.0(5) . . ?
Ag8 C61 Ag9 73.26(18) . . ?
Ag7 C61 Ag9 137.9(3) 2_575 . ?
Ag10 C61 Ag9 66.92(14) . . ?
C61 C62 C63 177.2(7) . . ?
C62 C63 C64 109.8(6) . . ?
C62 C63 C66 108.3(6) . . ?
C64 C63 C66 110.9(7) . . ?
C62 C63 C65 108.9(7) . . ?
C64 C63 C65 110.0(7) . . ?
C66 C63 C65 108.8(7) . . ?
N1 C101 C102 123.8(6) . . ?
N1 C101 P1 114.6(5) . . ?
C102 C101 P1 121.6(6) . . ?
C101 C102 C103 116.9(7) . . ?
C104 C103 C102 118.9(7) . . ?
C105 C104 C103 118.2(7) . . ?
N1 C105 C104 125.1(7) . . ?
C202 C201 C206 119.2(7) . . ?
C202 C201 P1 124.5(6) . . ?
C206 C201 P1 116.3(6) . . ?
C201 C202 C203 121.1(8) . . ?
C204 C203 C202 118.9(9) . . ?
C203 C204 C205 122.0(8) . . ?
C204 C205 C206 119.1(8) . . ?
C205 C206 C201 119.7(8) . . ?
C302 C301 C306 120.3(7) . . ?
C302 C301 P1 123.1(6) . . ?
C306 C301 P1 116.6(6) . . ?
C301 C302 C303 121.5(9) . . ?
C302 C303 C304 119.4(10) . . ?
C303 C304 C305 120.1(9) . . ?
C306 C305 C304 120.3(10) . . ?
C305 C306 C301 118.3(8) . . ?
N2 C401 C402 122.2(6) . . ?
N2 C401 P2 114.6(4) . . ?
C402 C401 P2 123.3(5) . . ?
C401 C402 C403 118.7(7) . . ?
C404 C403 C402 118.4(7) . . ?
C405 C404 C403 118.5(7) . . ?
N2 C405 C404 123.6(7) . . ?
C506 C501 C502 117.3(7) . . ?
C506 C501 P2 124.3(5) . . ?
C502 C501 P2 118.4(5) . . ?
C503 C502 C501 119.8(7) . . ?
C504 C503 C502 120.2(7) . . ?
C505 C504 C503 120.9(8) . . ?
C504 C505 C506 121.0(7) . . ?
C505 C506 C501 120.9(7) . . ?
C606 C601 C602 118.8(7) . . ?
C606 C601 P2 124.4(6) . . ?
C602 C601 P2 116.7(5) . . ?
C603 C602 C601 120.8(7) . . ?
C602 C603 C604 119.0(8) . . ?
C605 C604 C603 120.5(8) . . ?
C604 C605 C606 120.4(9) . . ?
C601 C606 C605 120.5(9) . . ?
C1 O1 Ag1 125.8(4) . . ?
C1 O2 Ag5 118.4(5) . 2_466 ?
C3 O3 Ag2 126.0(4) . . ?
C3 O4 Ag3 119.4(4) . . ?
C5 O5 Ag10 119.9(4) . . ?
C5 O6 Ag9 124.5(5) . . ?
C7 O7 Ag7 120.1(5) . . ?
C7 O8 Ag6 124.5(5) . . ?

_diffrn_measured_fraction_theta_max 0.987
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.987
_refine_diff_density_max         1.666
_refine_diff_density_min         -1.261
_refine_diff_density_rms         0.168
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_7
_database_code_depnum_ccdc_archive 'CCDC 1032352'
_audit_update_record             
;
2014-11-03 deposited with the CCDC.
2014-12-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C82 H82 Ag10 F20 N2 O8 P2'
_chemical_formula_weight         2744.14

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.2155(8)
_cell_length_b                   15.8405(6)
_cell_length_c                   24.0035(9)
_cell_angle_alpha                85.409(3)
_cell_angle_beta                 84.320(4)
_cell_angle_gamma                71.747(4)
_cell_volume                     4742.2(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    5781
_cell_measurement_theta_min      3.5390
_cell_measurement_theta_max      60.3900

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.922
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2664
_exptl_absorpt_coefficient_mu    17.288
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.37414
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET)
(compiled Dec  3 2012,18:21:49)  
;
_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'Enhance Ultra (Cu) X-ray Source'
_diffrn_radiation_monochromator  mirror
_diffrn_measurement_device_type  'Xcalibur, Sapphire3, Gemini ultra'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean 16.1903
_diffrn_standards_number         24322
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            24187
_diffrn_reflns_av_R_equivalents  0.0633
_diffrn_reflns_av_sigmaI/netI    0.0938
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         3.53
_diffrn_reflns_theta_max         60.68
_reflns_number_total             13855
_reflns_number_gt                11167
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker FRAMBO'
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0870P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         13855
_refine_ls_number_parameters     1135
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0746
_refine_ls_R_factor_gt           0.0620
_refine_ls_wR_factor_ref         0.1689
_refine_ls_wR_factor_gt          0.1544
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_restrained_S_all      1.038
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag2 Ag 0.59311(5) 1.00351(4) 0.14247(3) 0.03060(18) Uani 1 1 d . . .
Ag4 Ag 0.43023(5) 1.01036(4) 0.06818(3) 0.03073(18) Uani 1 1 d . . .
Ag3 Ag 0.63591(6) 1.05203(5) 0.02544(3) 0.03840(19) Uani 1 1 d . . .
Ag5 Ag 0.57930(7) 0.83872(5) 0.01290(3) 0.0410(2) Uani 1 1 d . . .
Ag1 Ag 0.55010(8) 0.84106(5) 0.13109(3) 0.0470(2) Uani 1 1 d . . .
P1 P 0.49965(18) 0.98815(14) 0.23303(9) 0.0250(5) Uani 1 1 d . . .
F7 F 0.8769(9) 1.2017(9) 0.0822(4) 0.116(4) Uani 1 1 d . . .
F4 F 0.6735(11) 0.5080(6) -0.0087(4) 0.112(4) Uani 1 1 d . . .
F6 F 0.9522(6) 1.0719(6) 0.1282(6) 0.126(5) Uani 1 1 d . . .
F3 F 0.7388(12) 0.4089(5) 0.0551(5) 0.130(5) Uani 1 1 d . . .
F8 F 0.9168(8) 1.2289(7) 0.1752(4) 0.102(3) Uani 1 1 d . . .
F5 F 0.8097(9) 0.5203(7) 0.0328(5) 0.111(4) Uani 1 1 d . . .
F10 F 0.8410(12) 1.1377(11) 0.2189(5) 0.142(6) Uani 1 1 d . . .
F9 F 0.7483(8) 1.2548(8) 0.1682(7) 0.149(6) Uani 1 1 d . . .
F2 F 0.5580(10) 0.5295(7) 0.0846(8) 0.166(7) Uani 1 1 d . . .
F1 F 0.7005(12) 0.5176(6) 0.1311(4) 0.134(5) Uani 1 1 d . . .
O1 O 0.7287(6) 1.0660(5) 0.1513(3) 0.0421(17) Uani 1 1 d . . .
O2 O 0.7556(7) 1.1098(6) 0.0613(3) 0.054(2) Uani 1 1 d . . .
O3 O 0.6346(8) 0.6844(5) 0.0291(3) 0.063(2) Uani 1 1 d . . .
O4 O 0.6077(8) 0.6873(5) 0.1211(3) 0.056(2) Uani 1 1 d . . .
N1 N 0.5716(6) 0.8114(5) 0.2272(3) 0.0283(16) Uani 1 1 d . . .
C121 C 0.3577(7) 0.9951(6) 0.2362(4) 0.029(2) Uani 1 1 d . . .
C24 C 0.3200(12) 1.3416(8) 0.1198(6) 0.072(4) Uani 1 1 d . . .
H24A H 0.3053 1.3552 0.0812 0.108 Uiso 1 1 calc R . .
H24B H 0.3054 1.3959 0.1386 0.108 Uiso 1 1 calc R . .
H24C H 0.2755 1.3078 0.1374 0.108 Uiso 1 1 calc R . .
C126 C 0.3146(9) 0.9389(7) 0.2706(5) 0.046(3) Uani 1 1 d . . .
H126 H 0.3579 0.8951 0.2935 0.055 Uiso 1 1 calc R . .
C22 C 0.5095(13) 1.3329(9) 0.0874(7) 0.075(4) Uani 1 1 d . . .
H22A H 0.5818 1.2942 0.0869 0.113 Uiso 1 1 calc R . .
H22B H 0.5049 1.3879 0.1031 0.113 Uiso 1 1 calc R . .
H22C H 0.4877 1.3445 0.0498 0.113 Uiso 1 1 calc R . .
C125 C 0.2069(10) 0.9478(8) 0.2712(6) 0.059(3) Uani 1 1 d . . .
H125 H 0.1773 0.9118 0.2957 0.070 Uiso 1 1 calc R . .
C23 C 0.4662(11) 1.2711(8) 0.1838(5) 0.061(3) Uani 1 1 d . . .
H23A H 0.4206 1.2416 0.2053 0.092 Uiso 1 1 calc R . .
H23B H 0.4579 1.3268 0.1997 0.092 Uiso 1 1 calc R . .
H23C H 0.5392 1.2342 0.1846 0.092 Uiso 1 1 calc R . .
C123 C 0.1864(9) 1.0654(8) 0.2014(5) 0.048(3) Uani 1 1 d . . .
H123 H 0.1427 1.1092 0.1786 0.058 Uiso 1 1 calc R . .
C7 C 0.3893(8) 0.8946(6) 0.0671(4) 0.033(2) Uani 1 1 d . . .
C124 C 0.1443(9) 1.0091(8) 0.2357(5) 0.048(3) Uani 1 1 d . . .
H124 H 0.0729 1.0129 0.2347 0.058 Uiso 1 1 calc R . .
C8 C 0.3450(8) 0.8387(7) 0.0836(4) 0.038(2) Uani 1 1 d . . .
C122 C 0.2931(8) 1.0570(6) 0.2009(4) 0.033(2) Uani 1 1 d . . .
H122 H 0.3221 1.0934 0.1764 0.040 Uiso 1 1 calc R . .
C112 C 0.5904(9) 1.0998(7) 0.2758(4) 0.039(2) Uani 1 1 d . . .
H112 H 0.6412 1.0830 0.2457 0.046 Uiso 1 1 calc R . .
C9 C 0.2881(10) 0.7758(8) 0.1037(5) 0.052(3) Uani 1 1 d . . .
C111 C 0.5063(8) 1.0639(6) 0.2844(4) 0.034(2) Uani 1 1 d . . .
C11 C 0.3013(18) 0.7108(12) 0.0581(7) 0.106(7) Uani 1 1 d . . .
H11A H 0.2647 0.7418 0.0263 0.160 Uiso 1 1 calc R . .
H11B H 0.2715 0.6645 0.0722 0.160 Uiso 1 1 calc R . .
H11C H 0.3758 0.6850 0.0470 0.160 Uiso 1 1 calc R . .
C116 C 0.4340(9) 1.0868(7) 0.3299(4) 0.039(2) Uani 1 1 d . . .
H116 H 0.3809 1.0595 0.3371 0.047 Uiso 1 1 calc R . .
C10 C 0.1704(13) 0.8280(13) 0.1143(9) 0.103(6) Uani 1 1 d . . .
H10A H 0.1616 0.8662 0.1446 0.155 Uiso 1 1 calc R . .
H10B H 0.1298 0.7874 0.1237 0.155 Uiso 1 1 calc R . .
H10C H 0.1455 0.8634 0.0811 0.155 Uiso 1 1 calc R . .
C115 C 0.4389(10) 1.1507(8) 0.3657(4) 0.049(3) Uani 1 1 d . . .
H115 H 0.3863 1.1695 0.3947 0.059 Uiso 1 1 calc R . .
C12 C 0.3315(15) 0.7260(12) 0.1565(7) 0.095(6) Uani 1 1 d . . .
H12A H 0.4079 0.7028 0.1511 0.143 Uiso 1 1 calc R . .
H12B H 0.3021 0.6779 0.1654 0.143 Uiso 1 1 calc R . .
H12C H 0.3122 0.7657 0.1867 0.143 Uiso 1 1 calc R . .
C114 C 0.5237(10) 1.1856(7) 0.3571(5) 0.050(3) Uani 1 1 d . . .
H114 H 0.5300 1.2258 0.3817 0.060 Uiso 1 1 calc R . .
C4 C 0.6319(11) 0.6514(7) 0.0768(5) 0.051(3) Uani 1 1 d . . .
C113 C 0.5986(10) 1.1610(7) 0.3123(5) 0.047(3) Uani 1 1 d . . .
H113 H 0.6546 1.1853 0.3065 0.056 Uiso 1 1 calc R . .
C5 C 0.6550(18) 0.5484(9) 0.0847(7) 0.090(6) Uani 1 1 d . . .
C135 C 0.6169(8) 0.7268(6) 0.2449(4) 0.037(2) Uani 1 1 d . . .
H135 H 0.6219 0.6816 0.2214 0.045 Uiso 1 1 calc R . .
C134 C 0.6564(9) 0.7047(7) 0.2970(5) 0.046(3) Uani 1 1 d . . .
H134 H 0.6863 0.6452 0.3082 0.055 Uiso 1 1 calc R . .
C17 C 0.8444(10) 0.8350(12) -0.0485(6) 0.080(5) Uani 1 1 d . . .
H17A H 0.8009 0.7992 -0.0557 0.120 Uiso 1 1 calc R . .
H17B H 0.9141 0.8122 -0.0675 0.120 Uiso 1 1 calc R . .
H17C H 0.8117 0.8953 -0.0618 0.120 Uiso 1 1 calc R . .
C133 C 0.6515(9) 0.7704(7) 0.3323(4) 0.040(2) Uani 1 1 d . . .
H133 H 0.6819 0.7564 0.3665 0.048 Uiso 1 1 calc R . .
C18 C 0.9301(12) 0.883(2) 0.0255(8) 0.163(14) Uani 1 1 d . . .
H18A H 0.9037 0.9434 0.0116 0.245 Uiso 1 1 calc R . .
H18B H 0.9999 0.8553 0.0077 0.245 Uiso 1 1 calc R . .
H18C H 0.9344 0.8808 0.0653 0.245 Uiso 1 1 calc R . .
C132 C 0.6002(8) 0.8581(7) 0.3155(4) 0.037(2) Uani 1 1 d . . .
H132 H 0.5918 0.9038 0.3392 0.045 Uiso 1 1 calc R . .
C131 C 0.5620(7) 0.8762(6) 0.2632(3) 0.0252(19) Uani 1 1 d . . .
C6 C 0.718(2) 0.4929(10) 0.0396(6) 0.114(8) Uani 1 1 d . . .
C15 C 0.8543(10) 0.8323(9) 0.0127(5) 0.061(3) Uani 1 1 d . . .
C16 C 0.9027(17) 0.7371(15) 0.0348(9) 0.154(12) Uani 1 1 d . . .
H16A H 0.9266 0.7370 0.0712 0.231 Uiso 1 1 calc R . .
H16B H 0.9622 0.7074 0.0097 0.231 Uiso 1 1 calc R . .
H16C H 0.8499 0.7067 0.0372 0.231 Uiso 1 1 calc R . .
C1 C 0.7721(9) 1.0992(7) 0.1112(4) 0.040(2) Uani 1 1 d . . .
C2 C 0.8647(9) 1.1330(10) 0.1257(6) 0.060(3) Uani 1 1 d . . .
C21 C 0.4355(9) 1.2880(7) 0.1234(5) 0.041(2) Uani 1 1 d . . .
C20 C 0.4489(7) 1.2004(6) 0.0997(4) 0.029(2) Uani 1 1 d . . .
C19 C 0.4581(7) 1.1304(6) 0.0812(4) 0.029(2) Uani 1 1 d . . .
C3 C 0.8352(15) 1.1939(12) 0.1741(7) 0.083(5) Uani 1 1 d . . .
C13 C 0.6768(8) 0.9024(6) 0.0772(4) 0.031(2) Uani 1 1 d . . .
C14 C 0.7526(9) 0.8721(7) 0.0444(4) 0.041(2) Uani 1 1 d . . .
Ag8 Ag -0.07623(5) 0.48046(4) 0.57021(3) 0.02839(17) Uani 1 1 d . . .
Ag7 Ag 0.08917(5) 0.44726(4) 0.64703(3) 0.02908(17) Uani 1 1 d . . .
Ag10 Ag 0.12240(6) 0.34966(4) 0.48431(3) 0.03765(19) Uani 1 1 d . . .
Ag6 Ag 0.10822(6) 0.55493(5) 0.54335(3) 0.03349(18) Uani 1 1 d . . .
Ag9 Ag 0.06969(6) 0.29742(4) 0.59653(3) 0.03441(18) Uani 1 1 d . . .
P2 P -0.00685(18) 0.38694(15) 0.72263(9) 0.0297(5) Uani 1 1 d . . .
F20 F 0.3931(15) 0.0329(10) 0.5569(11) 0.254(15) Uani 1 1 d . . .
F12 F 0.4113(7) 0.5846(8) 0.6428(3) 0.090(3) Uani 1 1 d . . .
F11 F 0.2788(8) 0.6951(5) 0.6712(4) 0.094(3) Uani 1 1 d . . .
F14 F 0.4069(7) 0.6112(6) 0.7501(4) 0.079(2) Uani 1 1 d . . .
F19 F 0.3872(11) -0.0874(5) 0.5248(5) 0.135(5) Uani 1 1 d . . .
F13 F 0.3814(6) 0.4873(5) 0.7377(3) 0.069(2) Uani 1 1 d . . .
F17 F 0.3196(12) 0.0351(6) 0.4530(4) 0.138(5) Uani 1 1 d . . .
F15 F 0.2495(7) 0.5971(6) 0.7662(3) 0.073(2) Uani 1 1 d . . .
F16 F 0.1893(9) 0.0077(6) 0.4956(7) 0.140(5) Uani 1 1 d . . .
F18 F 0.271(3) -0.0181(9) 0.5869(7) 0.303(19) Uani 1 1 d . . .
O5 O 0.1629(7) 0.1573(5) 0.5606(4) 0.057(2) Uani 1 1 d . . .
O6 O 0.2173(7) 0.1998(4) 0.4751(3) 0.0468(18) Uani 1 1 d . . .
O7 O 0.2043(5) 0.5156(4) 0.6745(3) 0.0366(15) Uani 1 1 d . . .
O8 O 0.2190(6) 0.6007(4) 0.5964(3) 0.0378(16) Uani 1 1 d . . .
N2 N 0.0816(6) 0.2225(5) 0.6865(3) 0.0343(18) Uani 1 1 d . . .
C27 C 0.330(3) -0.0059(13) 0.5391(9) 0.144(12) Uani 1 1 d . . .
C214 C -0.0379(13) 0.5047(10) 0.8929(5) 0.071(4) Uani 1 1 d . . .
H214 H -0.0431 0.5283 0.9277 0.085 Uiso 1 1 calc R . .
C233 C 0.1336(10) 0.1356(9) 0.7883(6) 0.063(4) Uani 1 1 d . . .
H233 H 0.1546 0.1064 0.8224 0.075 Uiso 1 1 calc R . .
C224 C -0.2789(10) 0.3267(8) 0.6966(6) 0.056(3) Uani 1 1 d . . .
H224 H -0.3001 0.2762 0.6957 0.067 Uiso 1 1 calc R . .
C29 C 0.3171(9) 0.6042(8) 0.6726(5) 0.045(3) Uani 1 1 d . . .
C30 C 0.3382(10) 0.5736(9) 0.7312(5) 0.053(3) Uani 1 1 d . . .
C213 C 0.0361(15) 0.5188(12) 0.8520(6) 0.087(5) Uani 1 1 d . . .
H213 H 0.0790 0.5530 0.8586 0.105 Uiso 1 1 calc R . .
C40 C -0.2615(10) 0.2455(9) 0.5255(7) 0.071(4) Uani 1 1 d . . .
H40A H -0.2969 0.2636 0.5615 0.107 Uiso 1 1 calc R . .
H40B H -0.2828 0.1973 0.5141 0.107 Uiso 1 1 calc R . .
H40C H -0.2806 0.2947 0.4985 0.107 Uiso 1 1 calc R . .
C48 C 0.0050(13) 0.7138(11) 0.7041(7) 0.098(6) Uani 1 1 d . . .
H48A H 0.0272 0.6582 0.7256 0.146 Uiso 1 1 calc R . .
H48B H -0.0072 0.7620 0.7283 0.146 Uiso 1 1 calc R . .
H48C H 0.0598 0.7162 0.6752 0.146 Uiso 1 1 calc R . .
C25 C 0.2096(9) 0.1461(7) 0.5140(5) 0.043(3) Uani 1 1 d . . .
C26 C 0.2649(10) 0.0463(7) 0.5012(5) 0.048(3) Uani 1 1 d . . .
C235 C 0.1249(8) 0.1351(7) 0.6903(5) 0.047(3) Uani 1 1 d . . .
H235 H 0.1378 0.1038 0.6578 0.056 Uiso 1 1 calc R . .
C234 C 0.1518(9) 0.0884(8) 0.7409(5) 0.055(3) Uani 1 1 d . . .
H234 H 0.1814 0.0268 0.7427 0.066 Uiso 1 1 calc R . .
C232 C 0.0848(9) 0.2253(8) 0.7856(4) 0.050(3) Uani 1 1 d . . .
H232 H 0.0689 0.2572 0.8179 0.060 Uiso 1 1 calc R . .
C215 C -0.1034(11) 0.4571(9) 0.8839(5) 0.058(3) Uani 1 1 d . . .
H215 H -0.1533 0.4482 0.9120 0.069 Uiso 1 1 calc R . .
C216 C -0.0952(9) 0.4234(8) 0.8340(4) 0.048(3) Uani 1 1 d . . .
H216 H -0.1417 0.3923 0.8277 0.058 Uiso 1 1 calc R . .
C211 C -0.0198(8) 0.4325(7) 0.7904(4) 0.038(2) Uani 1 1 d . . .
C212 C 0.0460(11) 0.4816(10) 0.8009(6) 0.062(3) Uani 1 1 d . . .
H212 H 0.0973 0.4895 0.7732 0.075 Uiso 1 1 calc R . .
C28 C 0.2372(7) 0.5710(6) 0.6445(4) 0.032(2) Uani 1 1 d . . .
C231 C 0.0591(7) 0.2682(6) 0.7333(4) 0.032(2) Uani 1 1 d . . .
C221 C -0.1433(7) 0.3924(6) 0.7094(4) 0.032(2) Uani 1 1 d . . .
C225 C -0.1768(8) 0.3188(7) 0.7082(5) 0.044(3) Uani 1 1 d . . .
H225 H -0.1293 0.2625 0.7154 0.052 Uiso 1 1 calc R . .
C222 C -0.2151(8) 0.4745(7) 0.6988(5) 0.045(3) Uani 1 1 d . . .
H222 H -0.1937 0.5250 0.6996 0.054 Uiso 1 1 calc R . .
C223 C -0.3184(9) 0.4841(9) 0.6871(5) 0.059(3) Uani 1 1 d . . .
H223 H -0.3662 0.5402 0.6798 0.071 Uiso 1 1 calc R . .
C109 C -0.3493(9) 0.4089(10) 0.6862(5) 0.060(3) Uani 1 1 d . . .
H109 H -0.4187 0.4142 0.6785 0.072 Uiso 1 1 calc R . .
C43 C -0.0643(7) 0.5950(6) 0.6009(4) 0.032(2) Uani 1 1 d . . .
C44 C -0.0770(7) 0.6526(6) 0.6358(4) 0.033(2) Uani 1 1 d . . .
C45 C -0.0968(8) 0.7216(7) 0.6779(4) 0.040(2) Uani 1 1 d . . .
C47 C -0.1357(11) 0.8151(8) 0.6481(5) 0.059(3) Uani 1 1 d . . .
H47A H -0.0807 0.8231 0.6209 0.089 Uiso 1 1 calc R . .
H47B H -0.1518 0.8597 0.6752 0.089 Uiso 1 1 calc R . .
H47C H -0.1988 0.8205 0.6296 0.089 Uiso 1 1 calc R . .
C36 C 0.3655(11) 0.4218(11) 0.4530(6) 0.080(5) Uani 1 1 d . . .
H36A H 0.3264 0.3961 0.4314 0.119 Uiso 1 1 calc R . .
H36B H 0.4356 0.4142 0.4348 0.119 Uiso 1 1 calc R . .
H36C H 0.3284 0.4842 0.4560 0.119 Uiso 1 1 calc R . .
C35 C 0.4346(8) 0.2778(8) 0.5069(6) 0.056(3) Uani 1 1 d . . .
H35A H 0.4662 0.2545 0.5415 0.083 Uiso 1 1 calc R . .
H35B H 0.4896 0.2700 0.4768 0.083 Uiso 1 1 calc R . .
H35C H 0.3857 0.2468 0.4998 0.083 Uiso 1 1 calc R . .
C34 C 0.4326(9) 0.4171(9) 0.5488(6) 0.067(4) Uani 1 1 d . . .
H34A H 0.4045 0.4808 0.5453 0.100 Uiso 1 1 calc R . .
H34B H 0.5077 0.3989 0.5375 0.100 Uiso 1 1 calc R . .
H34C H 0.4218 0.3972 0.5871 0.100 Uiso 1 1 calc R . .
C32 C 0.2656(7) 0.3855(6) 0.5391(4) 0.029(2) Uani 1 1 d . . .
C31 C 0.1839(6) 0.3886(5) 0.5683(3) 0.0233(18) Uani 1 1 d . . .
C33 C 0.3750(8) 0.3761(7) 0.5113(4) 0.038(2) Uani 1 1 d . . .
C37 C -0.0888(8) 0.3641(6) 0.5424(4) 0.034(2) Uani 1 1 d . . .
C38 C -0.1084(8) 0.2950(6) 0.5373(4) 0.038(2) Uani 1 1 d . . .
C39 C -0.1413(9) 0.2152(7) 0.5295(4) 0.042(2) Uani 1 1 d . . .
C46 C -0.1832(13) 0.7105(9) 0.7221(6) 0.080(5) Uani 1 1 d . . .
H46A H -0.2435 0.7076 0.7041 0.120 Uiso 1 1 calc R . .
H46B H -0.2049 0.7603 0.7457 0.120 Uiso 1 1 calc R . .
H46C H -0.1555 0.6566 0.7445 0.120 Uiso 1 1 calc R . .
C42 C -0.1081(13) 0.1491(8) 0.5788(5) 0.065(4) Uani 1 1 d . . .
H42A H -0.0318 0.1303 0.5794 0.097 Uiso 1 1 calc R . .
H42B H -0.1315 0.0983 0.5752 0.097 Uiso 1 1 calc R . .
H42C H -0.1403 0.1768 0.6131 0.097 Uiso 1 1 calc R . .
C41 C -0.0859(11) 0.1756(8) 0.4742(5) 0.062(3) Uani 1 1 d . . .
H41A H -0.1087 0.2184 0.4437 0.093 Uiso 1 1 calc R . .
H41B H -0.1045 0.1230 0.4688 0.093 Uiso 1 1 calc R . .
H41C H -0.0099 0.1605 0.4753 0.093 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag2 C13 2.278(9) . ?
Ag2 O1 2.336(7) . ?
Ag2 P1 2.425(2) . ?
Ag2 C19 2.681(9) . ?
Ag2 Ag1 2.8422(9) . ?
Ag2 Ag4 2.8996(9) . ?
Ag2 Ag3 2.9008(9) . ?
Ag4 C7 2.071(9) . ?
Ag4 C19 2.098(9) . ?
Ag4 Ag3 2.8417(9) 2_675 ?
Ag4 Ag5 2.9384(10) 2_675 ?
Ag4 Ag1 3.0241(10) . ?
Ag4 Ag3 3.0562(10) . ?
Ag4 Ag5 3.1206(10) . ?
Ag3 O2 2.320(7) . ?
Ag3 C7 2.330(9) 2_675 ?
Ag3 C13 2.514(9) . ?
Ag3 C19 2.583(9) . ?
Ag3 Ag4 2.8417(9) 2_675 ?
Ag3 Ag5 3.0184(11) 2_675 ?
Ag5 O3 2.333(8) . ?
Ag5 C19 2.340(9) 2_675 ?
Ag5 C13 2.553(9) . ?
Ag5 C7 2.632(9) . ?
Ag5 C14 2.695(10) . ?
Ag5 Ag1 2.8266(10) . ?
Ag5 Ag4 2.9384(10) 2_675 ?
Ag5 Ag3 3.0184(11) 2_675 ?
Ag1 O4 2.337(7) . ?
Ag1 N1 2.345(7) . ?
Ag1 C13 2.409(9) . ?
Ag1 C7 2.628(10) . ?
P1 C111 1.814(9) . ?
P1 C131 1.829(9) . ?
P1 C121 1.839(9) . ?
F7 C2 1.480(17) . ?
F4 C6 1.32(2) . ?
F6 C2 1.257(16) . ?
F3 C6 1.302(18) . ?
F8 C3 1.361(16) . ?
F5 C6 1.41(3) . ?
F10 C3 1.333(19) . ?
F9 C3 1.26(2) . ?
F2 C5 1.40(2) . ?
F1 C5 1.305(19) . ?
O1 C1 1.236(12) . ?
O2 C1 1.226(13) . ?
O3 C4 1.223(14) . ?
O4 C4 1.212(14) . ?
N1 C135 1.338(12) . ?
N1 C131 1.362(12) . ?
C121 C122 1.377(14) . ?
C121 C126 1.380(14) . ?
C24 C21 1.504(18) . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
C126 C125 1.384(17) . ?
C126 H126 0.9300 . ?
C22 C21 1.542(18) . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C125 C124 1.363(17) . ?
C125 H125 0.9300 . ?
C23 C21 1.526(16) . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C123 C124 1.372(16) . ?
C123 C122 1.374(15) . ?
C123 H123 0.9300 . ?
C7 C8 1.227(13) . ?
C7 Ag3 2.330(9) 2_675 ?
C124 H124 0.9300 . ?
C8 C9 1.453(14) . ?
C122 H122 0.9300 . ?
C112 C113 1.392(14) . ?
C112 C111 1.391(14) . ?
C112 H112 0.9300 . ?
C9 C12 1.50(2) . ?
C9 C10 1.52(2) . ?
C9 C11 1.523(19) . ?
C111 C116 1.369(15) . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C116 C115 1.400(14) . ?
C116 H116 0.9300 . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C115 C114 1.388(16) . ?
C115 H115 0.9300 . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
C114 C113 1.379(17) . ?
C114 H114 0.9300 . ?
C4 C5 1.562(18) . ?
C113 H113 0.9300 . ?
C5 C6 1.46(2) . ?
C135 C134 1.378(15) . ?
C135 H135 0.9300 . ?
C134 C133 1.377(16) . ?
C134 H134 0.9300 . ?
C17 C15 1.484(18) . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C133 C132 1.388(15) . ?
C133 H133 0.9300 . ?
C18 C15 1.53(2) . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C132 C131 1.374(13) . ?
C132 H132 0.9300 . ?
C15 C14 1.458(16) . ?
C15 C16 1.52(2) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C1 C2 1.560(15) . ?
C2 C3 1.51(2) . ?
C21 C20 1.494(13) . ?
C20 C19 1.194(13) . ?
C19 Ag5 2.340(9) 2_675 ?
C13 C14 1.207(15) . ?
Ag8 C43 2.068(9) . ?
Ag8 C37 2.069(10) . ?
Ag8 Ag10 2.8094(9) 2_566 ?
Ag8 Ag7 2.8944(9) . ?
Ag8 Ag6 2.9231(9) 2_566 ?
Ag8 Ag9 2.9950(9) . ?
Ag8 Ag6 3.0195(9) . ?
Ag7 C31 2.254(8) . ?
Ag7 O7 2.296(6) . ?
Ag7 P2 2.417(2) . ?
Ag7 Ag9 2.8416(9) . ?
Ag7 Ag6 2.9380(9) . ?
Ag10 C43 2.268(10) 2_566 ?
Ag10 O6 2.328(7) . ?
Ag10 C31 2.439(8) . ?
Ag10 C32 2.630(9) . ?
Ag10 Ag8 2.8094(9) 2_566 ?
Ag10 Ag9 2.8387(10) . ?
Ag10 Ag6 3.0608(10) 2_566 ?
Ag6 C37 2.329(9) 2_566 ?
Ag6 O8 2.339(6) . ?
Ag6 C43 2.474(9) . ?
Ag6 C31 2.553(8) . ?
Ag6 Ag8 2.9231(9) 2_566 ?
Ag6 Ag10 3.0608(10) 2_566 ?
Ag9 O5 2.360(8) . ?
Ag9 N2 2.375(8) . ?
Ag9 C31 2.414(8) . ?
Ag9 C37 2.475(9) . ?
P2 C211 1.802(10) . ?
P2 C231 1.818(10) . ?
P2 C221 1.837(9) . ?
F20 C27 1.30(3) . ?
F12 C29 1.333(14) . ?
F11 C29 1.369(14) . ?
F14 C30 1.359(13) . ?
F19 C27 1.329(18) . ?
F13 C30 1.309(15) . ?
F17 C26 1.295(15) . ?
F15 C30 1.343(15) . ?
F16 C26 1.347(15) . ?
F18 C27 1.36(4) . ?
O5 C25 1.221(13) . ?
O6 C25 1.230(13) . ?
O7 C28 1.245(11) . ?
O8 C28 1.229(12) . ?
N2 C235 1.321(13) . ?
N2 C231 1.343(13) . ?
C27 C26 1.36(2) . ?
C214 C215 1.355(19) . ?
C214 C213 1.37(2) . ?
C214 H214 0.9300 . ?
C233 C232 1.362(18) . ?
C233 C234 1.37(2) . ?
C233 H233 0.9300 . ?
C224 C109 1.363(19) . ?
C224 C225 1.369(16) . ?
C224 H224 0.9300 . ?
C29 C30 1.475(17) . ?
C29 C28 1.547(14) . ?
C213 C212 1.381(19) . ?
C213 H213 0.9300 . ?
C40 C39 1.518(17) . ?
C40 H40A 0.9600 . ?
C40 H40B 0.9600 . ?
C40 H40C 0.9600 . ?
C48 C45 1.507(18) . ?
C48 H48A 0.9600 . ?
C48 H48B 0.9600 . ?
C48 H48C 0.9600 . ?
C25 C26 1.561(15) . ?
C235 C234 1.389(16) . ?
C235 H235 0.9300 . ?
C234 H234 0.9300 . ?
C232 C231 1.398(14) . ?
C232 H232 0.9300 . ?
C215 C216 1.331(16) . ?
C215 H215 0.9300 . ?
C216 C211 1.403(15) . ?
C216 H216 0.9300 . ?
C211 C212 1.387(16) . ?
C212 H212 0.9300 . ?
C221 C222 1.370(15) . ?
C221 C225 1.374(14) . ?
C225 H225 0.9300 . ?
C222 C223 1.380(16) . ?
C222 H222 0.9300 . ?
C223 C109 1.377(19) . ?
C223 H223 0.9300 . ?
C109 H109 0.9300 . ?
C43 C44 1.249(14) . ?
C43 Ag10 2.268(10) 2_566 ?
C44 C45 1.494(14) . ?
C45 C46 1.521(17) . ?
C45 C47 1.548(16) . ?
C47 H47A 0.9600 . ?
C47 H47B 0.9600 . ?
C47 H47C 0.9600 . ?
C36 C33 1.521(17) . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?
C35 C33 1.515(16) . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?
C34 C33 1.534(16) . ?
C34 H34A 0.9600 . ?
C34 H34B 0.9600 . ?
C34 H34C 0.9600 . ?
C32 C31 1.218(13) . ?
C32 C33 1.499(13) . ?
C37 C38 1.218(14) . ?
C37 Ag6 2.329(9) 2_566 ?
C38 C39 1.491(14) . ?
C39 C42 1.519(16) . ?
C39 C41 1.532(17) . ?
C46 H46A 0.9600 . ?
C46 H46B 0.9600 . ?
C46 H46C 0.9600 . ?
C42 H42A 0.9600 . ?
C42 H42B 0.9600 . ?
C42 H42C 0.9600 . ?
C41 H41A 0.9600 . ?
C41 H41B 0.9600 . ?
C41 H41C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C13 Ag2 O1 99.7(3) . . ?
C13 Ag2 P1 131.5(2) . . ?
O1 Ag2 P1 110.53(17) . . ?
C13 Ag2 C19 101.8(3) . . ?
O1 Ag2 C19 102.2(3) . . ?
P1 Ag2 C19 107.4(2) . . ?
C13 Ag2 Ag1 54.8(2) . . ?
O1 Ag2 Ag1 144.00(19) . . ?
P1 Ag2 Ag1 79.62(5) . . ?
C19 Ag2 Ag1 107.43(19) . . ?
C13 Ag2 Ag4 75.0(2) . . ?
O1 Ag2 Ag4 140.59(18) . . ?
P1 Ag2 Ag4 100.76(6) . . ?
C19 Ag2 Ag4 43.95(19) . . ?
Ag1 Ag2 Ag4 63.55(3) . . ?
C13 Ag2 Ag3 56.5(2) . . ?
O1 Ag2 Ag3 80.72(17) . . ?
P1 Ag2 Ag3 161.69(6) . . ?
C19 Ag2 Ag3 54.96(19) . . ?
Ag1 Ag2 Ag3 99.92(3) . . ?
Ag4 Ag2 Ag3 63.59(2) . . ?
C7 Ag4 C19 171.2(4) . . ?
C7 Ag4 Ag3 53.9(3) . 2_675 ?
C19 Ag4 Ag3 132.3(3) . 2_675 ?
C7 Ag4 Ag2 115.6(3) . . ?
C19 Ag4 Ag2 62.5(3) . . ?
Ag3 Ag4 Ag2 150.52(3) 2_675 . ?
C7 Ag4 Ag5 133.8(3) . 2_675 ?
C19 Ag4 Ag5 52.2(2) . 2_675 ?
Ag3 Ag4 Ag5 80.17(3) 2_675 2_675 ?
Ag2 Ag4 Ag5 106.81(3) . 2_675 ?
C7 Ag4 Ag1 58.6(3) . . ?
C19 Ag4 Ag1 119.7(3) . . ?
Ag3 Ag4 Ag1 103.49(3) 2_675 . ?
Ag2 Ag4 Ag1 57.30(2) . . ?
Ag5 Ag4 Ag1 152.40(3) 2_675 . ?
C7 Ag4 Ag3 130.7(3) . . ?
C19 Ag4 Ag3 56.5(2) . . ?
Ag3 Ag4 Ag3 105.35(3) 2_675 . ?
Ag2 Ag4 Ag3 58.22(2) . . ?
Ag5 Ag4 Ag3 60.43(2) 2_675 . ?
Ag1 Ag4 Ag3 92.63(3) . . ?
C7 Ag4 Ag5 56.7(3) . . ?
C19 Ag4 Ag5 130.5(2) . . ?
Ag3 Ag4 Ag5 60.61(2) 2_675 . ?
Ag2 Ag4 Ag5 90.27(3) . . ?
Ag5 Ag4 Ag5 107.63(3) 2_675 . ?
Ag1 Ag4 Ag5 54.75(2) . . ?
Ag3 Ag4 Ag5 74.12(3) . . ?
O2 Ag3 C7 109.7(3) . 2_675 ?
O2 Ag3 C13 100.8(3) . . ?
C7 Ag3 C13 136.0(3) 2_675 . ?
O2 Ag3 C19 102.5(3) . . ?
C7 Ag3 C19 104.9(3) 2_675 . ?
C13 Ag3 C19 98.3(3) . . ?
O2 Ag3 Ag4 148.51(19) . 2_675 ?
C7 Ag3 Ag4 45.9(2) 2_675 2_675 ?
C13 Ag3 Ag4 92.7(2) . 2_675 ?
C19 Ag3 Ag4 103.5(2) . 2_675 ?
O2 Ag3 Ag2 82.96(18) . . ?
C7 Ag3 Ag2 161.6(2) 2_675 . ?
C13 Ag3 Ag2 49.1(2) . . ?
C19 Ag3 Ag2 58.2(2) . . ?
Ag4 Ag3 Ag2 126.25(3) 2_675 . ?
O2 Ag3 Ag5 124.8(2) . 2_675 ?
C7 Ag3 Ag5 57.2(2) 2_675 2_675 ?
C13 Ag3 Ag5 125.7(2) . 2_675 ?
C19 Ag3 Ag5 48.6(2) . 2_675 ?
Ag4 Ag3 Ag5 64.27(2) 2_675 2_675 ?
Ag2 Ag3 Ag5 104.70(3) . 2_675 ?
O2 Ag3 Ag4 136.76(19) . . ?
C7 Ag3 Ag4 104.9(2) 2_675 . ?
C13 Ag3 Ag4 69.1(2) . . ?
C19 Ag3 Ag4 42.66(19) . . ?
Ag4 Ag3 Ag4 74.65(3) 2_675 . ?
Ag2 Ag3 Ag4 58.19(2) . . ?
Ag5 Ag3 Ag4 57.85(2) 2_675 . ?
O3 Ag5 C19 107.8(3) . 2_675 ?
O3 Ag5 C13 107.5(3) . . ?
C19 Ag5 C13 133.0(3) 2_675 . ?
O3 Ag5 C7 105.1(3) . . ?
C19 Ag5 C7 103.1(3) 2_675 . ?
C13 Ag5 C7 96.6(3) . . ?
O3 Ag5 C14 98.6(3) . . ?
C19 Ag5 C14 117.6(3) 2_675 . ?
C13 Ag5 C14 26.4(3) . . ?
C7 Ag5 C14 123.0(3) . . ?
O3 Ag5 Ag1 84.2(2) . . ?
C19 Ag5 Ag1 159.9(2) 2_675 . ?
C13 Ag5 Ag1 52.92(19) . . ?
C7 Ag5 Ag1 57.4(2) . . ?
C14 Ag5 Ag1 74.9(2) . . ?
O3 Ag5 Ag4 146.8(2) . 2_675 ?
C19 Ag5 Ag4 45.1(2) 2_675 2_675 ?
C13 Ag5 Ag4 89.7(2) . 2_675 ?
C7 Ag5 Ag4 100.7(2) . 2_675 ?
C14 Ag5 Ag4 84.1(2) . 2_675 ?
Ag1 Ag5 Ag4 127.86(3) . 2_675 ?
O3 Ag5 Ag3 125.0(2) . 2_675 ?
C19 Ag5 Ag3 55.9(2) 2_675 2_675 ?
C13 Ag5 Ag3 120.9(2) . 2_675 ?
C7 Ag5 Ag3 48.1(2) . 2_675 ?
C14 Ag5 Ag3 136.3(2) . 2_675 ?
Ag1 Ag5 Ag3 104.00(3) . 2_675 ?
Ag4 Ag5 Ag3 61.72(2) 2_675 2_675 ?
O3 Ag5 Ag4 140.2(2) . . ?
C19 Ag5 Ag4 101.7(2) 2_675 . ?
C13 Ag5 Ag4 67.6(2) . . ?
C7 Ag5 Ag4 41.1(2) . . ?
C14 Ag5 Ag4 90.5(3) . . ?
Ag1 Ag5 Ag4 60.89(3) . . ?
Ag4 Ag5 Ag4 72.37(3) 2_675 . ?
Ag3 Ag5 Ag4 55.12(2) 2_675 . ?
O4 Ag1 N1 87.9(3) . . ?
O4 Ag1 C13 107.9(3) . . ?
N1 Ag1 C13 116.8(3) . . ?
O4 Ag1 C7 101.9(3) . . ?
N1 Ag1 C7 136.5(3) . . ?
C13 Ag1 C7 100.4(3) . . ?
O4 Ag1 Ag5 80.48(19) . . ?
N1 Ag1 Ag5 163.99(19) . . ?
C13 Ag1 Ag5 57.7(2) . . ?
C7 Ag1 Ag5 57.6(2) . . ?
O4 Ag1 Ag2 151.1(2) . . ?
N1 Ag1 Ag2 87.18(17) . . ?
C13 Ag1 Ag2 50.6(2) . . ?
C7 Ag1 Ag2 101.2(2) . . ?
Ag5 Ag1 Ag2 97.74(3) . . ?
O4 Ag1 Ag4 139.3(2) . . ?
N1 Ag1 Ag4 130.19(18) . . ?
C13 Ag1 Ag4 70.9(2) . . ?
C7 Ag1 Ag4 42.3(2) . . ?
Ag5 Ag1 Ag4 64.36(3) . . ?
Ag2 Ag1 Ag4 59.15(2) . . ?
C111 P1 C131 105.8(4) . . ?
C111 P1 C121 104.8(4) . . ?
C131 P1 C121 102.8(4) . . ?
C111 P1 Ag2 115.0(3) . . ?
C131 P1 Ag2 108.1(3) . . ?
C121 P1 Ag2 119.0(3) . . ?
C1 O1 Ag2 123.4(6) . . ?
C1 O2 Ag3 121.4(6) . . ?
C4 O3 Ag5 120.5(7) . . ?
C4 O4 Ag1 125.2(7) . . ?
C135 N1 C131 117.8(8) . . ?
C135 N1 Ag1 117.7(6) . . ?
C131 N1 Ag1 122.9(5) . . ?
C122 C121 C126 119.0(9) . . ?
C122 C121 P1 117.9(7) . . ?
C126 C121 P1 123.0(8) . . ?
C21 C24 H24A 109.5 . . ?
C21 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C21 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C121 C126 C125 120.2(11) . . ?
C121 C126 H126 119.9 . . ?
C125 C126 H126 119.9 . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C124 C125 C126 120.0(10) . . ?
C124 C125 H125 120.0 . . ?
C126 C125 H125 120.0 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C124 C123 C122 119.9(11) . . ?
C124 C123 H123 120.1 . . ?
C122 C123 H123 120.1 . . ?
C8 C7 Ag4 157.0(8) . . ?
C8 C7 Ag3 114.8(8) . 2_675 ?
Ag4 C7 Ag3 80.2(3) . 2_675 ?
C8 C7 Ag1 98.2(7) . . ?
Ag4 C7 Ag1 79.2(3) . . ?
Ag3 C7 Ag1 136.6(4) 2_675 . ?
C8 C7 Ag5 117.7(7) . . ?
Ag4 C7 Ag5 82.2(3) . . ?
Ag3 C7 Ag5 74.7(3) 2_675 . ?
Ag1 C7 Ag5 65.0(2) . . ?
C125 C124 C123 120.2(10) . . ?
C125 C124 H124 119.9 . . ?
C123 C124 H124 119.9 . . ?
C7 C8 C9 177.4(12) . . ?
C123 C122 C121 120.6(9) . . ?
C123 C122 H122 119.7 . . ?
C121 C122 H122 119.7 . . ?
C113 C112 C111 119.9(10) . . ?
C113 C112 H112 120.0 . . ?
C111 C112 H112 120.0 . . ?
C8 C9 C12 110.7(10) . . ?
C8 C9 C10 107.8(11) . . ?
C12 C9 C10 110.5(13) . . ?
C8 C9 C11 108.3(10) . . ?
C12 C9 C11 110.0(14) . . ?
C10 C9 C11 109.5(14) . . ?
C116 C111 C112 119.6(8) . . ?
C116 C111 P1 123.8(7) . . ?
C112 C111 P1 116.6(8) . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C111 C116 C115 121.0(9) . . ?
C111 C116 H116 119.5 . . ?
C115 C116 H116 119.5 . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C114 C115 C116 118.8(10) . . ?
C114 C115 H115 120.6 . . ?
C116 C115 H115 120.6 . . ?
C9 C12 H12A 109.5 . . ?
C9 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C9 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C113 C114 C115 120.5(9) . . ?
C113 C114 H114 119.8 . . ?
C115 C114 H114 119.8 . . ?
O4 C4 O3 129.6(10) . . ?
O4 C4 C5 112.1(11) . . ?
O3 C4 C5 118.2(11) . . ?
C114 C113 C112 120.0(10) . . ?
C114 C113 H113 120.0 . . ?
C112 C113 H113 120.0 . . ?
F1 C5 F2 110.9(15) . . ?
F1 C5 C6 107.7(16) . . ?
F2 C5 C6 99.9(16) . . ?
F1 C5 C4 110.9(13) . . ?
F2 C5 C4 108.5(15) . . ?
C6 C5 C4 118.4(13) . . ?
N1 C135 C134 122.1(9) . . ?
N1 C135 H135 119.0 . . ?
C134 C135 H135 119.0 . . ?
C133 C134 C135 120.2(9) . . ?
C133 C134 H134 119.9 . . ?
C135 C134 H134 119.9 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C134 C133 C132 118.3(9) . . ?
C134 C133 H133 120.9 . . ?
C132 C133 H133 120.9 . . ?
C15 C18 H18A 109.5 . . ?
C15 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C15 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C131 C132 C133 118.9(10) . . ?
C131 C132 H132 120.5 . . ?
C133 C132 H132 120.5 . . ?
N1 C131 C132 122.7(8) . . ?
N1 C131 P1 112.8(6) . . ?
C132 C131 P1 124.5(7) . . ?
F3 C6 F4 109.5(15) . . ?
F3 C6 F5 112(2) . . ?
F4 C6 F5 108.1(14) . . ?
F3 C6 C5 110.5(14) . . ?
F4 C6 C5 115(2) . . ?
F5 C6 C5 101.4(15) . . ?
C14 C15 C17 113.0(10) . . ?
C14 C15 C16 109.4(12) . . ?
C17 C15 C16 110.1(15) . . ?
C14 C15 C18 107.0(11) . . ?
C17 C15 C18 110.9(14) . . ?
C16 C15 C18 106.2(16) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
O2 C1 O1 131.2(10) . . ?
O2 C1 C2 113.6(10) . . ?
O1 C1 C2 115.3(9) . . ?
F6 C2 F7 109.5(11) . . ?
F6 C2 C3 114.9(13) . . ?
F7 C2 C3 95.9(11) . . ?
F6 C2 C1 112.9(11) . . ?
F7 C2 C1 108.3(10) . . ?
C3 C2 C1 113.8(10) . . ?
C20 C21 C24 106.4(9) . . ?
C20 C21 C23 108.4(9) . . ?
C24 C21 C23 111.9(11) . . ?
C20 C21 C22 108.1(10) . . ?
C24 C21 C22 111.1(11) . . ?
C23 C21 C22 110.7(10) . . ?
C19 C20 C21 178.9(11) . . ?
C20 C19 Ag4 160.8(8) . . ?
C20 C19 Ag5 105.9(7) . 2_675 ?
Ag4 C19 Ag5 82.7(3) . 2_675 ?
C20 C19 Ag3 117.7(7) . . ?
Ag4 C19 Ag3 80.8(3) . . ?
Ag5 C19 Ag3 75.5(3) 2_675 . ?
C20 C19 Ag2 107.7(7) . . ?
Ag4 C19 Ag2 73.6(3) . . ?
Ag5 C19 Ag2 137.9(4) 2_675 . ?
Ag3 C19 Ag2 66.9(2) . . ?
F9 C3 F10 117.9(19) . . ?
F9 C3 F8 110.6(14) . . ?
F10 C3 F8 106.3(12) . . ?
F9 C3 C2 111.5(13) . . ?
F10 C3 C2 103.3(14) . . ?
F8 C3 C2 106.4(14) . . ?
C14 C13 Ag2 149.1(8) . . ?
C14 C13 Ag1 133.8(8) . . ?
Ag2 C13 Ag1 74.6(3) . . ?
C14 C13 Ag3 91.1(7) . . ?
Ag2 C13 Ag3 74.3(3) . . ?
Ag1 C13 Ag3 126.5(4) . . ?
C14 C13 Ag5 83.4(6) . . ?
Ag2 C13 Ag5 124.1(4) . . ?
Ag1 C13 Ag5 69.4(2) . . ?
Ag3 C13 Ag5 94.6(3) . . ?
C13 C14 C15 170.7(11) . . ?
C13 C14 Ag5 70.2(6) . . ?
C15 C14 Ag5 117.2(8) . . ?
C43 Ag8 C37 177.9(4) . . ?
C43 Ag8 Ag10 52.8(3) . 2_566 ?
C37 Ag8 Ag10 129.0(2) . 2_566 ?
C43 Ag8 Ag7 66.5(3) . . ?
C37 Ag8 Ag7 112.4(3) . . ?
Ag10 Ag8 Ag7 112.88(3) 2_566 . ?
C43 Ag8 Ag6 129.7(3) . 2_566 ?
C37 Ag8 Ag6 52.3(2) . 2_566 ?
Ag10 Ag8 Ag6 77.63(3) 2_566 2_566 ?
Ag7 Ag8 Ag6 141.32(3) . 2_566 ?
C43 Ag8 Ag9 124.0(3) . . ?
C37 Ag8 Ag9 54.9(3) . . ?
Ag10 Ag8 Ag9 152.67(3) 2_566 . ?
Ag7 Ag8 Ag9 57.67(2) . . ?
Ag6 Ag8 Ag9 95.30(3) 2_566 . ?
C43 Ag8 Ag6 54.4(2) . . ?
C37 Ag8 Ag6 126.7(3) . . ?
Ag10 Ag8 Ag6 63.23(2) 2_566 . ?
Ag7 Ag8 Ag6 59.53(2) . . ?
Ag6 Ag8 Ag6 98.98(2) 2_566 . ?
Ag9 Ag8 Ag6 92.47(3) . . ?
C31 Ag7 O7 98.7(3) . . ?
C31 Ag7 P2 132.2(2) . . ?
O7 Ag7 P2 115.14(18) . . ?
C31 Ag7 Ag9 55.1(2) . . ?
O7 Ag7 Ag9 146.04(17) . . ?
P2 Ag7 Ag9 79.35(6) . . ?
C31 Ag7 Ag8 78.2(2) . . ?
O7 Ag7 Ag8 139.03(17) . . ?
P2 Ag7 Ag8 94.70(6) . . ?
Ag9 Ag7 Ag8 62.94(2) . . ?
C31 Ag7 Ag6 57.1(2) . . ?
O7 Ag7 Ag6 81.45(17) . . ?
P2 Ag7 Ag6 154.74(6) . . ?
Ag9 Ag7 Ag6 97.43(3) . . ?
Ag8 Ag7 Ag6 62.35(2) . . ?
C43 Ag10 O6 107.0(3) 2_566 . ?
C43 Ag10 C31 142.9(3) 2_566 . ?
O6 Ag10 C31 104.4(3) . . ?
C43 Ag10 C32 128.9(3) 2_566 . ?
O6 Ag10 C32 95.5(3) . . ?
C31 Ag10 C32 27.5(3) . . ?
C43 Ag10 Ag8 46.6(2) 2_566 2_566 ?
O6 Ag10 Ag8 144.17(18) . 2_566 ?
C31 Ag10 Ag8 96.42(19) . 2_566 ?
C32 Ag10 Ag8 89.71(19) . 2_566 ?
C43 Ag10 Ag9 147.5(2) 2_566 . ?
O6 Ag10 Ag9 85.28(18) . . ?
C31 Ag10 Ag9 53.80(19) . . ?
C32 Ag10 Ag9 77.7(2) . . ?
Ag8 Ag10 Ag9 130.33(3) 2_566 . ?
C43 Ag10 Ag6 52.8(2) 2_566 2_566 ?
O6 Ag10 Ag6 127.3(2) . 2_566 ?
C31 Ag10 Ag6 118.30(19) . 2_566 ?
C32 Ag10 Ag6 136.31(19) . 2_566 ?
Ag8 Ag10 Ag6 61.74(2) 2_566 2_566 ?
Ag9 Ag10 Ag6 95.63(3) . 2_566 ?
C37 Ag6 O8 109.9(3) 2_566 . ?
C37 Ag6 C43 109.7(3) 2_566 . ?
O8 Ag6 C43 102.9(3) . . ?
C37 Ag6 C31 132.0(3) 2_566 . ?
O8 Ag6 C31 96.6(2) . . ?
C43 Ag6 C31 101.9(3) . . ?
C37 Ag6 Ag8 44.6(2) 2_566 2_566 ?
O8 Ag6 Ag8 143.74(17) . 2_566 ?
C43 Ag6 Ag8 110.1(2) . 2_566 ?
C31 Ag6 Ag8 91.19(19) . 2_566 ?
C37 Ag6 Ag7 167.7(2) 2_566 . ?
O8 Ag6 Ag7 81.41(16) . . ?
C43 Ag6 Ag7 61.7(2) . . ?
C31 Ag6 Ag7 47.85(19) . . ?
Ag8 Ag6 Ag7 127.49(3) 2_566 . ?
C37 Ag6 Ag8 109.6(2) 2_566 . ?
O8 Ag6 Ag8 134.98(17) . . ?
C43 Ag6 Ag8 42.8(2) . . ?
C31 Ag6 Ag8 71.66(18) . . ?
Ag8 Ag6 Ag8 81.02(2) 2_566 . ?
Ag7 Ag6 Ag8 58.12(2) . . ?
C37 Ag6 Ag10 64.6(2) 2_566 2_566 ?
O8 Ag6 Ag10 129.73(18) . 2_566 ?
C43 Ag6 Ag10 46.9(2) . 2_566 ?
C31 Ag6 Ag10 124.93(18) . 2_566 ?
Ag8 Ag6 Ag10 69.48(2) 2_566 2_566 ?
Ag7 Ag6 Ag10 104.80(3) . 2_566 ?
Ag8 Ag6 Ag10 55.03(2) . 2_566 ?
O5 Ag9 N2 86.4(3) . . ?
O5 Ag9 C31 104.7(3) . . ?
N2 Ag9 C31 119.3(3) . . ?
O5 Ag9 C37 107.6(3) . . ?
N2 Ag9 C37 129.3(3) . . ?
C31 Ag9 C37 104.2(3) . . ?
O5 Ag9 Ag10 79.59(19) . . ?
N2 Ag9 Ag10 161.8(2) . . ?
C31 Ag9 Ag10 54.6(2) . . ?
C37 Ag9 Ag10 66.9(2) . . ?
O5 Ag9 Ag7 145.3(2) . . ?
N2 Ag9 Ag7 88.03(19) . . ?
C31 Ag9 Ag7 50.0(2) . . ?
C37 Ag9 Ag7 102.4(2) . . ?
Ag10 Ag9 Ag7 96.79(3) . . ?
O5 Ag9 Ag8 145.3(2) . . ?
N2 Ag9 Ag8 125.3(2) . . ?
C31 Ag9 Ag8 73.88(19) . . ?
C37 Ag9 Ag8 43.2(2) . . ?
Ag10 Ag9 Ag8 71.53(2) . . ?
Ag7 Ag9 Ag8 59.39(2) . . ?
C211 P2 C231 105.7(4) . . ?
C211 P2 C221 104.9(4) . . ?
C231 P2 C221 103.1(4) . . ?
C211 P2 Ag7 117.2(3) . . ?
C231 P2 Ag7 109.6(3) . . ?
C221 P2 Ag7 115.1(3) . . ?
C25 O5 Ag9 124.7(7) . . ?
C25 O6 Ag10 118.9(7) . . ?
C28 O7 Ag7 124.1(6) . . ?
C28 O8 Ag6 122.3(6) . . ?
C235 N2 C231 119.4(9) . . ?
C235 N2 Ag9 119.0(7) . . ?
C231 N2 Ag9 120.9(6) . . ?
F20 C27 F19 109(2) . . ?
F20 C27 C26 112(2) . . ?
F19 C27 C26 117.3(13) . . ?
F20 C27 F18 101.9(18) . . ?
F19 C27 F18 105(2) . . ?
C26 C27 F18 110(3) . . ?
C215 C214 C213 121.6(11) . . ?
C215 C214 H214 119.2 . . ?
C213 C214 H214 119.2 . . ?
C232 C233 C234 120.3(11) . . ?
C232 C233 H233 119.9 . . ?
C234 C233 H233 119.9 . . ?
C109 C224 C225 119.8(11) . . ?
C109 C224 H224 120.1 . . ?
C225 C224 H224 120.1 . . ?
F12 C29 F11 105.7(10) . . ?
F12 C29 C30 107.2(10) . . ?
F11 C29 C30 107.0(10) . . ?
F12 C29 C28 110.8(9) . . ?
F11 C29 C28 107.4(9) . . ?
C30 C29 C28 118.1(9) . . ?
F13 C30 F15 107.8(11) . . ?
F13 C30 F14 106.7(10) . . ?
F15 C30 F14 105.9(9) . . ?
F13 C30 C29 113.1(10) . . ?
F15 C30 C29 112.4(10) . . ?
F14 C30 C29 110.6(10) . . ?
C214 C213 C212 119.2(13) . . ?
C214 C213 H213 120.4 . . ?
C212 C213 H213 120.4 . . ?
C39 C40 H40A 109.5 . . ?
C39 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C39 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C45 C48 H48A 109.5 . . ?
C45 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C45 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
O5 C25 O6 130.9(10) . . ?
O5 C25 C26 114.0(10) . . ?
O6 C25 C26 115.0(9) . . ?
F17 C26 F16 102.5(11) . . ?
F17 C26 C27 106.2(16) . . ?
F16 C26 C27 106.4(18) . . ?
F17 C26 C25 113.6(10) . . ?
F16 C26 C25 109.1(10) . . ?
C27 C26 C25 117.7(10) . . ?
N2 C235 C234 122.4(11) . . ?
N2 C235 H235 118.8 . . ?
C234 C235 H235 118.8 . . ?
C233 C234 C235 118.2(11) . . ?
C233 C234 H234 120.9 . . ?
C235 C234 H234 120.9 . . ?
C233 C232 C231 118.6(11) . . ?
C233 C232 H232 120.7 . . ?
C231 C232 H232 120.7 . . ?
C216 C215 C214 118.8(12) . . ?
C216 C215 H215 120.6 . . ?
C214 C215 H215 120.6 . . ?
C215 C216 C211 123.3(11) . . ?
C215 C216 H216 118.3 . . ?
C211 C216 H216 118.3 . . ?
C212 C211 C216 116.5(10) . . ?
C212 C211 P2 119.4(8) . . ?
C216 C211 P2 124.0(8) . . ?
C213 C212 C211 120.5(13) . . ?
C213 C212 H212 119.7 . . ?
C211 C212 H212 119.7 . . ?
O8 C28 O7 130.6(9) . . ?
O8 C28 C29 115.8(8) . . ?
O7 C28 C29 113.5(9) . . ?
N2 C231 C232 121.1(9) . . ?
N2 C231 P2 114.8(7) . . ?
C232 C231 P2 124.1(8) . . ?
C222 C221 C225 118.2(9) . . ?
C222 C221 P2 118.0(7) . . ?
C225 C221 P2 123.7(8) . . ?
C224 C225 C221 121.2(11) . . ?
C224 C225 H225 119.4 . . ?
C221 C225 H225 119.4 . . ?
C221 C222 C223 121.5(11) . . ?
C221 C222 H222 119.2 . . ?
C223 C222 H222 119.2 . . ?
C109 C223 C222 118.7(12) . . ?
C109 C223 H223 120.6 . . ?
C222 C223 H223 120.6 . . ?
C224 C109 C223 120.5(11) . . ?
C224 C109 H109 119.8 . . ?
C223 C109 H109 119.8 . . ?
C44 C43 Ag8 156.7(8) . . ?
C44 C43 Ag10 114.3(7) . 2_566 ?
Ag8 C43 Ag10 80.6(3) . 2_566 ?
C44 C43 Ag6 116.2(7) . . ?
Ag8 C43 Ag6 82.8(3) . . ?
Ag10 C43 Ag6 80.3(3) 2_566 . ?
C43 C44 C45 177.7(10) . . ?
C44 C45 C48 110.4(9) . . ?
C44 C45 C46 109.0(9) . . ?
C48 C45 C46 111.1(12) . . ?
C44 C45 C47 109.0(8) . . ?
C48 C45 C47 108.1(11) . . ?
C46 C45 C47 109.1(10) . . ?
C45 C47 H47A 109.5 . . ?
C45 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C45 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C33 C36 H36A 109.5 . . ?
C33 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C33 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C33 C35 H35A 109.5 . . ?
C33 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C33 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C31 C32 C33 171.0(10) . . ?
C31 C32 Ag10 67.5(6) . . ?
C33 C32 Ag10 119.8(6) . . ?
C32 C31 Ag7 141.9(7) . . ?
C32 C31 Ag9 139.7(7) . . ?
Ag7 C31 Ag9 74.9(2) . . ?
C32 C31 Ag10 85.1(6) . . ?
Ag7 C31 Ag10 129.6(4) . . ?
Ag9 C31 Ag10 71.6(2) . . ?
C32 C31 Ag6 90.4(6) . . ?
Ag7 C31 Ag6 75.1(2) . . ?
Ag9 C31 Ag6 121.9(3) . . ?
Ag10 C31 Ag6 92.1(3) . . ?
C32 C33 C35 108.4(8) . . ?
C32 C33 C36 109.6(9) . . ?
C35 C33 C36 109.8(10) . . ?
C32 C33 C34 107.6(8) . . ?
C35 C33 C34 109.3(9) . . ?
C36 C33 C34 112.0(10) . . ?
C38 C37 Ag8 165.7(9) . . ?
C38 C37 Ag6 108.1(7) . 2_566 ?
Ag8 C37 Ag6 83.1(3) . 2_566 ?
C38 C37 Ag9 96.4(7) . . ?
Ag8 C37 Ag9 81.9(3) . . ?
Ag6 C37 Ag9 131.1(4) 2_566 . ?
C37 C38 C39 175.1(11) . . ?
C38 C39 C40 108.1(10) . . ?
C38 C39 C42 108.5(9) . . ?
C40 C39 C42 111.9(10) . . ?
C38 C39 C41 108.1(9) . . ?
C40 C39 C41 109.0(10) . . ?
C42 C39 C41 111.2(11) . . ?
C45 C46 H46A 109.5 . . ?
C45 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C45 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C39 C42 H42A 109.5 . . ?
C39 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C39 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C39 C41 H41A 109.5 . . ?
C39 C41 H41B 109.5 . . ?
H41A C41 H41B 109.5 . . ?
C39 C41 H41C 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C13 Ag2 Ag4 C7 64.0(4) . . . . ?
O1 Ag2 Ag4 C7 151.1(4) . . . . ?
P1 Ag2 Ag4 C7 -66.4(3) . . . . ?
C19 Ag2 Ag4 C7 -170.4(4) . . . . ?
Ag1 Ag2 Ag4 C7 6.2(3) . . . . ?
Ag3 Ag2 Ag4 C7 123.7(3) . . . . ?
C13 Ag2 Ag4 C19 -125.6(4) . . . . ?
O1 Ag2 Ag4 C19 -38.5(4) . . . . ?
P1 Ag2 Ag4 C19 104.0(3) . . . . ?
Ag1 Ag2 Ag4 C19 176.6(3) . . . . ?
Ag3 Ag2 Ag4 C19 -65.9(3) . . . . ?
C13 Ag2 Ag4 Ag3 2.7(2) . . . 2_675 ?
O1 Ag2 Ag4 Ag3 89.8(3) . . . 2_675 ?
P1 Ag2 Ag4 Ag3 -127.67(8) . . . 2_675 ?
C19 Ag2 Ag4 Ag3 128.3(3) . . . 2_675 ?
Ag1 Ag2 Ag4 Ag3 -55.09(6) . . . 2_675 ?
Ag3 Ag2 Ag4 Ag3 62.41(6) . . . 2_675 ?
C13 Ag2 Ag4 Ag5 -97.2(2) . . . 2_675 ?
O1 Ag2 Ag4 Ag5 -10.1(3) . . . 2_675 ?
P1 Ag2 Ag4 Ag5 132.43(6) . . . 2_675 ?
C19 Ag2 Ag4 Ag5 28.4(3) . . . 2_675 ?
Ag1 Ag2 Ag4 Ag5 -154.98(3) . . . 2_675 ?
Ag3 Ag2 Ag4 Ag5 -37.48(3) . . . 2_675 ?
C13 Ag2 Ag4 Ag1 57.8(2) . . . . ?
O1 Ag2 Ag4 Ag1 144.9(3) . . . . ?
P1 Ag2 Ag4 Ag1 -72.58(6) . . . . ?
C19 Ag2 Ag4 Ag1 -176.6(3) . . . . ?
Ag3 Ag2 Ag4 Ag1 117.50(3) . . . . ?
C13 Ag2 Ag4 Ag3 -59.7(2) . . . . ?
O1 Ag2 Ag4 Ag3 27.4(3) . . . . ?
P1 Ag2 Ag4 Ag3 169.92(6) . . . . ?
C19 Ag2 Ag4 Ag3 65.9(3) . . . . ?
Ag1 Ag2 Ag4 Ag3 -117.50(3) . . . . ?
C13 Ag2 Ag4 Ag5 11.3(2) . . . . ?
O1 Ag2 Ag4 Ag5 98.4(3) . . . . ?
P1 Ag2 Ag4 Ag5 -119.04(6) . . . . ?
C19 Ag2 Ag4 Ag5 136.9(3) . . . . ?
Ag1 Ag2 Ag4 Ag5 -46.46(3) . . . . ?
Ag3 Ag2 Ag4 Ag5 71.05(3) . . . . ?
C13 Ag2 Ag3 O2 -110.9(4) . . . . ?
O1 Ag2 Ag3 O2 -2.7(3) . . . . ?
P1 Ag2 Ag3 O2 126.9(3) . . . . ?
C19 Ag2 Ag3 O2 109.4(3) . . . . ?
Ag1 Ag2 Ag3 O2 -146.1(2) . . . . ?
Ag4 Ag2 Ag3 O2 160.1(2) . . . . ?
C13 Ag2 Ag3 C7 114.3(8) . . . 2_675 ?
O1 Ag2 Ag3 C7 -137.5(8) . . . 2_675 ?
P1 Ag2 Ag3 C7 -7.9(8) . . . 2_675 ?
C19 Ag2 Ag3 C7 -25.4(8) . . . 2_675 ?
Ag1 Ag2 Ag3 C7 79.0(7) . . . 2_675 ?
Ag4 Ag2 Ag3 C7 25.3(7) . . . 2_675 ?
O1 Ag2 Ag3 C13 108.2(3) . . . . ?
P1 Ag2 Ag3 C13 -122.2(3) . . . . ?
C19 Ag2 Ag3 C13 -139.7(4) . . . . ?
Ag1 Ag2 Ag3 C13 -35.2(3) . . . . ?
Ag4 Ag2 Ag3 C13 -89.0(3) . . . . ?
C13 Ag2 Ag3 C19 139.7(4) . . . . ?
O1 Ag2 Ag3 C19 -112.1(3) . . . . ?
P1 Ag2 Ag3 C19 17.5(3) . . . . ?
Ag1 Ag2 Ag3 C19 104.4(2) . . . . ?
Ag4 Ag2 Ag3 C19 50.7(2) . . . . ?
C13 Ag2 Ag3 Ag4 56.2(3) . . . 2_675 ?
O1 Ag2 Ag3 Ag4 164.46(19) . . . 2_675 ?
P1 Ag2 Ag3 Ag4 -65.94(19) . . . 2_675 ?
C19 Ag2 Ag3 Ag4 -83.4(2) . . . 2_675 ?
Ag1 Ag2 Ag3 Ag4 20.98(5) . . . 2_675 ?
Ag4 Ag2 Ag3 Ag4 -32.75(4) . . . 2_675 ?
C13 Ag2 Ag3 Ag5 124.9(3) . . . 2_675 ?
O1 Ag2 Ag3 Ag5 -126.90(19) . . . 2_675 ?
P1 Ag2 Ag3 Ag5 2.70(19) . . . 2_675 ?
C19 Ag2 Ag3 Ag5 -14.8(2) . . . 2_675 ?
Ag1 Ag2 Ag3 Ag5 89.62(3) . . . 2_675 ?
Ag4 Ag2 Ag3 Ag5 35.89(3) . . . 2_675 ?
C13 Ag2 Ag3 Ag4 89.0(3) . . . . ?
O1 Ag2 Ag3 Ag4 -162.79(19) . . . . ?
P1 Ag2 Ag3 Ag4 -33.20(18) . . . . ?
C19 Ag2 Ag3 Ag4 -50.7(2) . . . . ?
Ag1 Ag2 Ag3 Ag4 53.73(3) . . . . ?
C7 Ag4 Ag3 O2 -127.4(5) . . . . ?
C19 Ag4 Ag3 O2 46.5(4) . . . . ?
Ag3 Ag4 Ag3 O2 177.4(3) 2_675 . . . ?
Ag2 Ag4 Ag3 O2 -29.5(3) . . . . ?
Ag5 Ag4 Ag3 O2 108.4(3) 2_675 . . . ?
Ag1 Ag4 Ag3 O2 -77.9(3) . . . . ?
Ag5 Ag4 Ag3 O2 -130.0(3) . . . . ?
C7 Ag4 Ag3 C7 90.2(4) . . . 2_675 ?
C19 Ag4 Ag3 C7 -96.0(4) . . . 2_675 ?
Ag3 Ag4 Ag3 C7 34.9(2) 2_675 . . 2_675 ?
Ag2 Ag4 Ag3 C7 -172.0(2) . . . 2_675 ?
Ag5 Ag4 Ag3 C7 -34.0(2) 2_675 . . 2_675 ?
Ag1 Ag4 Ag3 C7 139.7(2) . . . 2_675 ?
Ag5 Ag4 Ag3 C7 87.5(2) . . . 2_675 ?
C7 Ag4 Ag3 C13 -43.8(4) . . . . ?
C19 Ag4 Ag3 C13 130.0(4) . . . . ?
Ag3 Ag4 Ag3 C13 -99.1(2) 2_675 . . . ?
Ag2 Ag4 Ag3 C13 54.0(2) . . . . ?
Ag5 Ag4 Ag3 C13 -168.0(2) 2_675 . . . ?
Ag1 Ag4 Ag3 C13 5.7(2) . . . . ?
Ag5 Ag4 Ag3 C13 -46.5(2) . . . . ?
C7 Ag4 Ag3 C19 -173.9(5) . . . . ?
Ag3 Ag4 Ag3 C19 130.9(3) 2_675 . . . ?
Ag2 Ag4 Ag3 C19 -76.0(3) . . . . ?
Ag5 Ag4 Ag3 C19 62.0(3) 2_675 . . . ?
Ag1 Ag4 Ag3 C19 -124.3(3) . . . . ?
Ag5 Ag4 Ag3 C19 -176.5(3) . . . . ?
C7 Ag4 Ag3 Ag4 55.2(3) . . . 2_675 ?
C19 Ag4 Ag3 Ag4 -130.9(3) . . . 2_675 ?
Ag3 Ag4 Ag3 Ag4 0.0 2_675 . . 2_675 ?
Ag2 Ag4 Ag3 Ag4 153.10(4) . . . 2_675 ?
Ag5 Ag4 Ag3 Ag4 -68.95(3) 2_675 . . 2_675 ?
Ag1 Ag4 Ag3 Ag4 104.76(3) . . . 2_675 ?
Ag5 Ag4 Ag3 Ag4 52.62(2) . . . 2_675 ?
C7 Ag4 Ag3 Ag2 -97.9(3) . . . . ?
C19 Ag4 Ag3 Ag2 76.0(3) . . . . ?
Ag3 Ag4 Ag3 Ag2 -153.10(4) 2_675 . . . ?
Ag5 Ag4 Ag3 Ag2 137.95(3) 2_675 . . . ?
Ag1 Ag4 Ag3 Ag2 -48.35(2) . . . . ?
Ag5 Ag4 Ag3 Ag2 -100.49(3) . . . . ?
C7 Ag4 Ag3 Ag5 124.2(3) . . . 2_675 ?
C19 Ag4 Ag3 Ag5 -62.0(3) . . . 2_675 ?
Ag3 Ag4 Ag3 Ag5 68.95(3) 2_675 . . 2_675 ?
Ag2 Ag4 Ag3 Ag5 -137.95(3) . . . 2_675 ?
Ag1 Ag4 Ag3 Ag5 173.70(3) . . . 2_675 ?
Ag5 Ag4 Ag3 Ag5 121.56(2) . . . 2_675 ?
C7 Ag4 Ag5 O3 -40.8(5) . . . . ?
C19 Ag4 Ag5 O3 133.0(5) . . . . ?
Ag3 Ag4 Ag5 O3 -104.7(4) 2_675 . . . ?
Ag2 Ag4 Ag5 O3 80.1(4) . . . . ?
Ag5 Ag4 Ag5 O3 -172.1(4) 2_675 . . . ?
Ag1 Ag4 Ag5 O3 31.8(4) . . . . ?
Ag3 Ag4 Ag5 O3 136.8(4) . . . . ?
C7 Ag4 Ag5 C19 96.6(4) . . . 2_675 ?
C19 Ag4 Ag5 C19 -89.6(4) . . . 2_675 ?
Ag3 Ag4 Ag5 C19 32.7(2) 2_675 . . 2_675 ?
Ag2 Ag4 Ag5 C19 -142.5(2) . . . 2_675 ?
Ag5 Ag4 Ag5 C19 -34.7(2) 2_675 . . 2_675 ?
Ag1 Ag4 Ag5 C19 169.2(2) . . . 2_675 ?
Ag3 Ag4 Ag5 C19 -85.7(2) . . . 2_675 ?
C7 Ag4 Ag5 C13 -131.5(4) . . . . ?
C19 Ag4 Ag5 C13 42.3(4) . . . . ?
Ag3 Ag4 Ag5 C13 164.6(2) 2_675 . . . ?
Ag2 Ag4 Ag5 C13 -10.6(2) . . . . ?
Ag5 Ag4 Ag5 C13 97.2(2) 2_675 . . . ?
Ag1 Ag4 Ag5 C13 -58.9(2) . . . . ?
Ag3 Ag4 Ag5 C13 46.2(2) . . . . ?
C19 Ag4 Ag5 C7 173.8(5) . . . . ?
Ag3 Ag4 Ag5 C7 -63.9(3) 2_675 . . . ?
Ag2 Ag4 Ag5 C7 120.9(3) . . . . ?
Ag5 Ag4 Ag5 C7 -131.3(3) 2_675 . . . ?
Ag1 Ag4 Ag5 C7 72.6(3) . . . . ?
Ag3 Ag4 Ag5 C7 177.6(3) . . . . ?
C7 Ag4 Ag5 C14 -145.0(4) . . . . ?
C19 Ag4 Ag5 C14 28.8(4) . . . . ?
Ag3 Ag4 Ag5 C14 151.1(2) 2_675 . . . ?
Ag2 Ag4 Ag5 C14 -24.1(2) . . . . ?
Ag5 Ag4 Ag5 C14 83.7(2) 2_675 . . . ?
Ag1 Ag4 Ag5 C14 -72.4(2) . . . . ?
Ag3 Ag4 Ag5 C14 32.7(2) . . . . ?
C7 Ag4 Ag5 Ag1 -72.6(3) . . . . ?
C19 Ag4 Ag5 Ag1 101.2(3) . . . . ?
Ag3 Ag4 Ag5 Ag1 -136.54(3) 2_675 . . . ?
Ag2 Ag4 Ag5 Ag1 48.33(3) . . . . ?
Ag5 Ag4 Ag5 Ag1 156.08(4) 2_675 . . . ?
Ag3 Ag4 Ag5 Ag1 105.04(3) . . . . ?
C7 Ag4 Ag5 Ag4 131.3(3) . . . 2_675 ?
C19 Ag4 Ag5 Ag4 -54.9(3) . . . 2_675 ?
Ag3 Ag4 Ag5 Ag4 67.39(2) 2_675 . . 2_675 ?
Ag2 Ag4 Ag5 Ag4 -107.75(3) . . . 2_675 ?
Ag5 Ag4 Ag5 Ag4 0.0 2_675 . . 2_675 ?
Ag1 Ag4 Ag5 Ag4 -156.08(4) . . . 2_675 ?
Ag3 Ag4 Ag5 Ag4 -51.04(2) . . . 2_675 ?
C7 Ag4 Ag5 Ag3 63.9(3) . . . 2_675 ?
C19 Ag4 Ag5 Ag3 -122.3(3) . . . 2_675 ?
Ag2 Ag4 Ag5 Ag3 -175.14(3) . . . 2_675 ?
Ag5 Ag4 Ag5 Ag3 -67.39(2) 2_675 . . 2_675 ?
Ag1 Ag4 Ag5 Ag3 136.54(3) . . . 2_675 ?
Ag3 Ag4 Ag5 Ag3 -118.43(2) . . . 2_675 ?
O3 Ag5 Ag1 O4 -1.2(3) . . . . ?
C19 Ag5 Ag1 O4 126.8(7) 2_675 . . . ?
C13 Ag5 Ag1 O4 -118.3(4) . . . . ?
C7 Ag5 Ag1 O4 110.8(3) . . . . ?
C14 Ag5 Ag1 O4 -101.8(3) . . . . ?
Ag4 Ag5 Ag1 O4 -171.8(2) 2_675 . . . ?
Ag3 Ag5 Ag1 O4 123.4(2) 2_675 . . . ?
Ag4 Ag5 Ag1 O4 158.9(2) . . . . ?
O3 Ag5 Ag1 N1 42.5(7) . . . . ?
C19 Ag5 Ag1 N1 170.5(9) 2_675 . . . ?
C13 Ag5 Ag1 N1 -74.6(7) . . . . ?
C7 Ag5 Ag1 N1 154.6(7) . . . . ?
C14 Ag5 Ag1 N1 -58.1(7) . . . . ?
Ag4 Ag5 Ag1 N1 -128.0(6) 2_675 . . . ?
Ag3 Ag5 Ag1 N1 167.1(6) 2_675 . . . ?
Ag4 Ag5 Ag1 N1 -157.3(6) . . . . ?
O3 Ag5 Ag1 C13 117.1(4) . . . . ?
C19 Ag5 Ag1 C13 -114.9(7) 2_675 . . . ?
C7 Ag5 Ag1 C13 -130.9(4) . . . . ?
C14 Ag5 Ag1 C13 16.5(4) . . . . ?
Ag4 Ag5 Ag1 C13 -53.4(3) 2_675 . . . ?
Ag3 Ag5 Ag1 C13 -118.3(3) 2_675 . . . ?
Ag4 Ag5 Ag1 C13 -82.8(3) . . . . ?
O3 Ag5 Ag1 C7 -112.1(4) . . . . ?
C19 Ag5 Ag1 C7 15.9(7) 2_675 . . . ?
C13 Ag5 Ag1 C7 130.9(4) . . . . ?
C14 Ag5 Ag1 C7 147.3(3) . . . . ?
Ag4 Ag5 Ag1 C7 77.4(2) 2_675 . . . ?
Ag3 Ag5 Ag1 C7 12.6(2) 2_675 . . . ?
Ag4 Ag5 Ag1 C7 48.1(2) . . . . ?
O3 Ag5 Ag1 Ag2 149.6(3) . . . . ?
C19 Ag5 Ag1 Ag2 -82.4(6) 2_675 . . . ?
C13 Ag5 Ag1 Ag2 32.5(3) . . . . ?
C7 Ag5 Ag1 Ag2 -98.4(2) . . . . ?
C14 Ag5 Ag1 Ag2 49.0(2) . . . . ?
Ag4 Ag5 Ag1 Ag2 -20.96(6) 2_675 . . . ?
Ag3 Ag5 Ag1 Ag2 -85.83(4) 2_675 . . . ?
Ag4 Ag5 Ag1 Ag2 -50.26(3) . . . . ?
O3 Ag5 Ag1 Ag4 -160.2(3) . . . . ?
C19 Ag5 Ag1 Ag4 -32.2(6) 2_675 . . . ?
C13 Ag5 Ag1 Ag4 82.8(3) . . . . ?
C7 Ag5 Ag1 Ag4 -48.1(2) . . . . ?
C14 Ag5 Ag1 Ag4 99.2(2) . . . . ?
Ag4 Ag5 Ag1 Ag4 29.31(5) 2_675 . . . ?
Ag3 Ag5 Ag1 Ag4 -35.56(3) 2_675 . . . ?
C13 Ag2 Ag1 O4 48.3(5) . . . . ?
O1 Ag2 Ag1 O4 -3.4(5) . . . . ?
P1 Ag2 Ag1 O4 -114.2(4) . . . . ?
C19 Ag2 Ag1 O4 140.6(4) . . . . ?
Ag4 Ag2 Ag1 O4 138.2(4) . . . . ?
Ag3 Ag2 Ag1 O4 84.4(4) . . . . ?
C13 Ag2 Ag1 N1 128.7(4) . . . . ?
O1 Ag2 Ag1 N1 77.0(3) . . . . ?
P1 Ag2 Ag1 N1 -33.8(2) . . . . ?
C19 Ag2 Ag1 N1 -139.0(3) . . . . ?
Ag4 Ag2 Ag1 N1 -141.45(19) . . . . ?
Ag3 Ag2 Ag1 N1 164.80(19) . . . . ?
O1 Ag2 Ag1 C13 -51.7(4) . . . . ?
P1 Ag2 Ag1 C13 -162.5(3) . . . . ?
C19 Ag2 Ag1 C13 92.3(4) . . . . ?
Ag4 Ag2 Ag1 C13 89.8(3) . . . . ?
Ag3 Ag2 Ag1 C13 36.1(3) . . . . ?
C13 Ag2 Ag1 C7 -94.3(4) . . . . ?
O1 Ag2 Ag1 C7 -146.1(4) . . . . ?
P1 Ag2 Ag1 C7 103.2(2) . . . . ?
C19 Ag2 Ag1 C7 -2.0(3) . . . . ?
Ag4 Ag2 Ag1 C7 -4.5(2) . . . . ?
Ag3 Ag2 Ag1 C7 -58.2(2) . . . . ?
C13 Ag2 Ag1 Ag5 -36.0(3) . . . . ?
O1 Ag2 Ag1 Ag5 -87.7(3) . . . . ?
P1 Ag2 Ag1 Ag5 161.51(6) . . . . ?
C19 Ag2 Ag1 Ag5 56.3(2) . . . . ?
Ag4 Ag2 Ag1 Ag5 53.86(3) . . . . ?
Ag3 Ag2 Ag1 Ag5 0.11(4) . . . . ?
C13 Ag2 Ag1 Ag4 -89.8(3) . . . . ?
O1 Ag2 Ag1 Ag4 -141.6(3) . . . . ?
P1 Ag2 Ag1 Ag4 107.65(6) . . . . ?
C19 Ag2 Ag1 Ag4 2.5(2) . . . . ?
Ag3 Ag2 Ag1 Ag4 -53.75(3) . . . . ?
C7 Ag4 Ag1 O4 36.2(5) . . . . ?
C19 Ag4 Ag1 O4 -153.8(4) . . . . ?
Ag3 Ag4 Ag1 O4 5.1(3) 2_675 . . . ?
Ag2 Ag4 Ag1 O4 -150.4(3) . . . . ?
Ag5 Ag4 Ag1 O4 -89.5(4) 2_675 . . . ?
Ag3 Ag4 Ag1 O4 -101.3(3) . . . . ?
Ag5 Ag4 Ag1 O4 -32.9(3) . . . . ?
C7 Ag4 Ag1 N1 -118.9(4) . . . . ?
C19 Ag4 Ag1 N1 51.1(4) . . . . ?
Ag3 Ag4 Ag1 N1 -149.9(2) 2_675 . . . ?
Ag2 Ag4 Ag1 N1 54.6(2) . . . . ?
Ag5 Ag4 Ag1 N1 115.5(2) 2_675 . . . ?
Ag3 Ag4 Ag1 N1 103.6(2) . . . . ?
Ag5 Ag4 Ag1 N1 172.0(2) . . . . ?
C7 Ag4 Ag1 C13 131.7(4) . . . . ?
C19 Ag4 Ag1 C13 -58.3(4) . . . . ?
Ag3 Ag4 Ag1 C13 100.6(2) 2_675 . . . ?
Ag2 Ag4 Ag1 C13 -54.9(2) . . . . ?
Ag5 Ag4 Ag1 C13 6.0(2) 2_675 . . . ?
Ag3 Ag4 Ag1 C13 -5.9(2) . . . . ?
Ag5 Ag4 Ag1 C13 62.6(2) . . . . ?
C19 Ag4 Ag1 C7 170.0(4) . . . . ?
Ag3 Ag4 Ag1 C7 -31.0(3) 2_675 . . . ?
Ag2 Ag4 Ag1 C7 173.5(3) . . . . ?
Ag5 Ag4 Ag1 C7 -125.6(3) 2_675 . . . ?
Ag3 Ag4 Ag1 C7 -137.5(3) . . . . ?
Ag5 Ag4 Ag1 C7 -69.1(3) . . . . ?
C7 Ag4 Ag1 Ag5 69.1(3) . . . . ?
C19 Ag4 Ag1 Ag5 -120.9(3) . . . . ?
Ag3 Ag4 Ag1 Ag5 38.05(3) 2_675 . . . ?
Ag2 Ag4 Ag1 Ag5 -117.42(3) . . . . ?
Ag5 Ag4 Ag1 Ag5 -56.53(7) 2_675 . . . ?
Ag3 Ag4 Ag1 Ag5 -68.41(3) . . . . ?
C7 Ag4 Ag1 Ag2 -173.5(3) . . . . ?
C19 Ag4 Ag1 Ag2 -3.5(3) . . . . ?
Ag3 Ag4 Ag1 Ag2 155.48(3) 2_675 . . . ?
Ag5 Ag4 Ag1 Ag2 60.90(6) 2_675 . . . ?
Ag3 Ag4 Ag1 Ag2 49.01(2) . . . . ?
Ag5 Ag4 Ag1 Ag2 117.42(3) . . . . ?
C13 Ag2 P1 C111 149.3(5) . . . . ?
O1 Ag2 P1 C111 24.4(4) . . . . ?
C19 Ag2 P1 C111 -86.3(4) . . . . ?
Ag1 Ag2 P1 C111 168.5(4) . . . . ?
Ag4 Ag2 P1 C111 -131.2(4) . . . . ?
Ag3 Ag2 P1 C111 -101.3(4) . . . . ?
C13 Ag2 P1 C131 31.4(5) . . . . ?
O1 Ag2 P1 C131 -93.5(4) . . . . ?
C19 Ag2 P1 C131 155.8(4) . . . . ?
Ag1 Ag2 P1 C131 50.6(3) . . . . ?
Ag4 Ag2 P1 C131 110.9(3) . . . . ?
Ag3 Ag2 P1 C131 140.8(3) . . . . ?
C13 Ag2 P1 C121 -85.2(5) . . . . ?
O1 Ag2 P1 C121 149.9(4) . . . . ?
C19 Ag2 P1 C121 39.2(4) . . . . ?
Ag1 Ag2 P1 C121 -66.0(3) . . . . ?
Ag4 Ag2 P1 C121 -5.7(3) . . . . ?
Ag3 Ag2 P1 C121 24.2(4) . . . . ?
C13 Ag2 O1 C1 55.3(8) . . . . ?
P1 Ag2 O1 C1 -163.3(8) . . . . ?
C19 Ag2 O1 C1 -49.1(8) . . . . ?
Ag1 Ag2 O1 C1 95.9(8) . . . . ?
Ag4 Ag2 O1 C1 -22.9(10) . . . . ?
Ag3 Ag2 O1 C1 1.8(8) . . . . ?
C7 Ag3 O2 C1 171.7(9) 2_675 . . . ?
C13 Ag3 O2 C1 -40.6(9) . . . . ?
C19 Ag3 O2 C1 60.6(9) . . . . ?
Ag4 Ag3 O2 C1 -154.5(7) 2_675 . . . ?
Ag2 Ag3 O2 C1 5.4(9) . . . . ?
Ag5 Ag3 O2 C1 108.5(9) 2_675 . . . ?
Ag4 Ag3 O2 C1 30.4(11) . . . . ?
C19 Ag5 O3 C4 -160.7(10) 2_675 . . . ?
C13 Ag5 O3 C4 50.9(11) . . . . ?
C7 Ag5 O3 C4 -51.2(11) . . . . ?
C14 Ag5 O3 C4 76.5(11) . . . . ?
Ag1 Ag5 O3 C4 2.8(10) . . . . ?
Ag4 Ag5 O3 C4 169.0(8) 2_675 . . . ?
Ag3 Ag5 O3 C4 -100.2(10) 2_675 . . . ?
Ag4 Ag5 O3 C4 -24.8(12) . . . . ?
N1 Ag1 O4 C4 -168.4(11) . . . . ?
C13 Ag1 O4 C4 -50.9(11) . . . . ?
C7 Ag1 O4 C4 54.3(11) . . . . ?
Ag5 Ag1 O4 C4 0.6(10) . . . . ?
Ag2 Ag1 O4 C4 -88.2(11) . . . . ?
Ag4 Ag1 O4 C4 30.4(12) . . . . ?
O4 Ag1 N1 C135 7.1(7) . . . . ?
C13 Ag1 N1 C135 -101.9(7) . . . . ?
C7 Ag1 N1 C135 112.3(7) . . . . ?
Ag5 Ag1 N1 C135 -35.9(11) . . . . ?
Ag2 Ag1 N1 C135 -144.4(7) . . . . ?
Ag4 Ag1 N1 C135 171.1(6) . . . . ?
O4 Ag1 N1 C131 172.6(7) . . . . ?
C13 Ag1 N1 C131 63.6(7) . . . . ?
C7 Ag1 N1 C131 -82.3(8) . . . . ?
Ag5 Ag1 N1 C131 129.5(7) . . . . ?
Ag2 Ag1 N1 C131 21.1(7) . . . . ?
Ag4 Ag1 N1 C131 -23.4(8) . . . . ?
C111 P1 C121 C122 91.0(7) . . . . ?
C131 P1 C121 C122 -158.7(7) . . . . ?
Ag2 P1 C121 C122 -39.3(8) . . . . ?
C111 P1 C121 C126 -91.7(8) . . . . ?
C131 P1 C121 C126 18.6(9) . . . . ?
Ag2 P1 C121 C126 138.0(7) . . . . ?
C122 C121 C126 C125 -2.9(15) . . . . ?
P1 C121 C126 C125 179.9(9) . . . . ?
C121 C126 C125 C124 3.2(18) . . . . ?
C19 Ag4 C7 C8 4(4) . . . . ?
Ag3 Ag4 C7 C8 -133(2) 2_675 . . . ?
Ag2 Ag4 C7 C8 79(2) . . . . ?
Ag5 Ag4 C7 C8 -126(2) 2_675 . . . ?
Ag1 Ag4 C7 C8 85(2) . . . . ?
Ag3 Ag4 C7 C8 148(2) . . . . ?
Ag5 Ag4 C7 C8 151(2) . . . . ?
C19 Ag4 C7 Ag3 137(2) . . . 2_675 ?
Ag2 Ag4 C7 Ag3 -147.71(12) . . . 2_675 ?
Ag5 Ag4 C7 Ag3 6.9(4) 2_675 . . 2_675 ?
Ag1 Ag4 C7 Ag3 -141.6(3) . . . 2_675 ?
Ag3 Ag4 C7 Ag3 -78.7(3) . . . 2_675 ?
Ag5 Ag4 C7 Ag3 -75.7(2) . . . 2_675 ?
C19 Ag4 C7 Ag1 -81(2) . . . . ?
Ag3 Ag4 C7 Ag1 141.6(3) 2_675 . . . ?
Ag2 Ag4 C7 Ag1 -6.1(3) . . . . ?
Ag5 Ag4 C7 Ag1 148.55(15) 2_675 . . . ?
Ag3 Ag4 C7 Ag1 62.9(3) . . . . ?
Ag5 Ag4 C7 Ag1 65.93(18) . . . . ?
C19 Ag4 C7 Ag5 -147(2) . . . . ?
Ag3 Ag4 C7 Ag5 75.7(2) 2_675 . . . ?
Ag2 Ag4 C7 Ag5 -72.0(2) . . . . ?
Ag5 Ag4 C7 Ag5 82.6(3) 2_675 . . . ?
Ag1 Ag4 C7 Ag5 -65.93(18) . . . . ?
Ag3 Ag4 C7 Ag5 -3.0(4) . . . . ?
O4 Ag1 C7 C8 46.3(7) . . . . ?
N1 Ag1 C7 C8 -53.3(8) . . . . ?
C13 Ag1 C7 C8 157.3(7) . . . . ?
Ag5 Ag1 C7 C8 116.8(7) . . . . ?
Ag2 Ag1 C7 C8 -151.1(6) . . . . ?
Ag4 Ag1 C7 C8 -156.8(8) . . . . ?
O4 Ag1 C7 Ag4 -156.8(3) . . . . ?
N1 Ag1 C7 Ag4 103.5(4) . . . . ?
C13 Ag1 C7 Ag4 -45.9(3) . . . . ?
Ag5 Ag1 C7 Ag4 -86.4(2) . . . . ?
Ag2 Ag1 C7 Ag4 5.7(3) . . . . ?
O4 Ag1 C7 Ag3 -93.9(6) . . . 2_675 ?
N1 Ag1 C7 Ag3 166.5(4) . . . 2_675 ?
C13 Ag1 C7 Ag3 17.1(6) . . . 2_675 ?
Ag5 Ag1 C7 Ag3 -23.4(4) . . . 2_675 ?
Ag2 Ag1 C7 Ag3 68.7(6) . . . 2_675 ?
Ag4 Ag1 C7 Ag3 63.0(5) . . . 2_675 ?
O4 Ag1 C7 Ag5 -70.4(3) . . . . ?
N1 Ag1 C7 Ag5 -170.1(3) . . . . ?
C13 Ag1 C7 Ag5 40.5(3) . . . . ?
Ag2 Ag1 C7 Ag5 92.11(14) . . . . ?
Ag4 Ag1 C7 Ag5 86.4(2) . . . . ?
O3 Ag5 C7 C8 -13.4(9) . . . . ?
C19 Ag5 C7 C8 99.4(9) 2_675 . . . ?
C13 Ag5 C7 C8 -123.6(8) . . . . ?
C14 Ag5 C7 C8 -124.6(8) . . . . ?
Ag1 Ag5 C7 C8 -86.2(8) . . . . ?
Ag4 Ag5 C7 C8 145.5(8) 2_675 . . . ?
Ag3 Ag5 C7 C8 110.3(9) 2_675 . . . ?
Ag4 Ag5 C7 C8 -167.8(10) . . . . ?
O3 Ag5 C7 Ag4 154.3(3) . . . . ?
C19 Ag5 C7 Ag4 -92.8(3) 2_675 . . . ?
C13 Ag5 C7 Ag4 44.2(3) . . . . ?
C14 Ag5 C7 Ag4 43.2(4) . . . . ?
Ag1 Ag5 C7 Ag4 81.6(3) . . . . ?
Ag4 Ag5 C7 Ag4 -46.7(3) 2_675 . . . ?
Ag3 Ag5 C7 Ag4 -81.9(3) 2_675 . . . ?
O3 Ag5 C7 Ag3 -123.7(3) . . . 2_675 ?
C19 Ag5 C7 Ag3 -10.9(3) 2_675 . . 2_675 ?
C13 Ag5 C7 Ag3 126.1(3) . . . 2_675 ?
C14 Ag5 C7 Ag3 125.1(3) . . . 2_675 ?
Ag1 Ag5 C7 Ag3 163.5(3) . . . 2_675 ?
Ag4 Ag5 C7 Ag3 35.2(2) 2_675 . . 2_675 ?
Ag4 Ag5 C7 Ag3 81.9(3) . . . 2_675 ?
O3 Ag5 C7 Ag1 72.7(3) . . . . ?
C19 Ag5 C7 Ag1 -174.4(2) 2_675 . . . ?
C13 Ag5 C7 Ag1 -37.4(3) . . . . ?
C14 Ag5 C7 Ag1 -38.4(3) . . . . ?
Ag4 Ag5 C7 Ag1 -128.36(11) 2_675 . . . ?
Ag3 Ag5 C7 Ag1 -163.5(3) 2_675 . . . ?
Ag4 Ag5 C7 Ag1 -81.6(3) . . . . ?
C126 C125 C124 C123 -3.3(18) . . . . ?
C122 C123 C124 C125 3.2(17) . . . . ?
Ag4 C7 C8 C9 46(26) . . . . ?
Ag3 C7 C8 C9 -81(25) 2_675 . . . ?
Ag1 C7 C8 C9 128(25) . . . . ?
Ag5 C7 C8 C9 -166(25) . . . . ?
C124 C123 C122 C121 -2.9(15) . . . . ?
C126 C121 C122 C123 2.7(14) . . . . ?
P1 C121 C122 C123 -179.9(8) . . . . ?
C7 C8 C9 C12 -116(25) . . . . ?
C7 C8 C9 C10 5(26) . . . . ?
C7 C8 C9 C11 124(25) . . . . ?
C113 C112 C111 C116 -2.2(15) . . . . ?
C113 C112 C111 P1 177.6(8) . . . . ?
C131 P1 C111 C116 -82.8(10) . . . . ?
C121 P1 C111 C116 25.4(10) . . . . ?
Ag2 P1 C111 C116 158.0(8) . . . . ?
C131 P1 C111 C112 97.3(8) . . . . ?
C121 P1 C111 C112 -154.5(8) . . . . ?
Ag2 P1 C111 C112 -21.9(9) . . . . ?
C112 C111 C116 C115 4.7(16) . . . . ?
P1 C111 C116 C115 -175.2(9) . . . . ?
C111 C116 C115 C114 -5.3(18) . . . . ?
C116 C115 C114 C113 3.3(18) . . . . ?
Ag1 O4 C4 O3 2(2) . . . . ?
Ag1 O4 C4 C5 -173.9(10) . . . . ?
Ag5 O3 C4 O4 -3(2) . . . . ?
Ag5 O3 C4 C5 171.9(11) . . . . ?
C115 C114 C113 C112 -1.0(18) . . . . ?
C111 C112 C113 C114 0.4(17) . . . . ?
O4 C4 C5 F1 -35(2) . . . . ?
O3 C4 C5 F1 148.7(15) . . . . ?
O4 C4 C5 F2 86.8(16) . . . . ?
O3 C4 C5 F2 -89.3(17) . . . . ?
O4 C4 C5 C6 -160.4(19) . . . . ?
O3 C4 C5 C6 23(3) . . . . ?
C131 N1 C135 C134 -2.2(14) . . . . ?
Ag1 N1 C135 C134 164.1(8) . . . . ?
N1 C135 C134 C133 -1.0(16) . . . . ?
C135 C134 C133 C132 4.0(16) . . . . ?
C134 C133 C132 C131 -3.8(15) . . . . ?
C135 N1 C131 C132 2.4(13) . . . . ?
Ag1 N1 C131 C132 -163.1(7) . . . . ?
C135 N1 C131 P1 179.5(7) . . . . ?
Ag1 N1 C131 P1 14.1(9) . . . . ?
C133 C132 C131 N1 0.6(14) . . . . ?
C133 C132 C131 P1 -176.2(7) . . . . ?
C111 P1 C131 N1 -174.6(6) . . . . ?
C121 P1 C131 N1 75.8(7) . . . . ?
Ag2 P1 C131 N1 -50.9(7) . . . . ?
C111 P1 C131 C132 2.5(9) . . . . ?
C121 P1 C131 C132 -107.1(8) . . . . ?
Ag2 P1 C131 C132 126.2(7) . . . . ?
F1 C5 C6 F3 47(3) . . . . ?
F2 C5 C6 F3 -69(2) . . . . ?
C4 C5 C6 F3 173.4(18) . . . . ?
F1 C5 C6 F4 171.1(16) . . . . ?
F2 C5 C6 F4 55.3(19) . . . . ?
C4 C5 C6 F4 -62(3) . . . . ?
F1 C5 C6 F5 -72.6(17) . . . . ?
F2 C5 C6 F5 171.6(13) . . . . ?
C4 C5 C6 F5 54(2) . . . . ?
Ag3 O2 C1 O1 -6.4(17) . . . . ?
Ag3 O2 C1 C2 173.1(8) . . . . ?
Ag2 O1 C1 O2 2.4(17) . . . . ?
Ag2 O1 C1 C2 -177.1(7) . . . . ?
O2 C1 C2 F6 -97.4(15) . . . . ?
O1 C1 C2 F6 82.2(15) . . . . ?
O2 C1 C2 F7 24.0(14) . . . . ?
O1 C1 C2 F7 -156.4(10) . . . . ?
O2 C1 C2 C3 129.4(13) . . . . ?
O1 C1 C2 C3 -51.1(16) . . . . ?
C24 C21 C20 C19 -42(62) . . . . ?
C23 C21 C20 C19 78(62) . . . . ?
C22 C21 C20 C19 -162(62) . . . . ?
C21 C20 C19 Ag4 -9(64) . . . . ?
C21 C20 C19 Ag5 106(62) . . . 2_675 ?
C21 C20 C19 Ag3 -173(100) . . . . ?
C21 C20 C19 Ag2 -100(62) . . . . ?
C7 Ag4 C19 C20 -17(4) . . . . ?
Ag3 Ag4 C19 C20 115(2) 2_675 . . . ?
Ag2 Ag4 C19 C20 -97(3) . . . . ?
Ag5 Ag4 C19 C20 118(3) 2_675 . . . ?
Ag1 Ag4 C19 C20 -94(3) . . . . ?
Ag3 Ag4 C19 C20 -165(3) . . . . ?
Ag5 Ag4 C19 C20 -161(2) . . . . ?
C7 Ag4 C19 Ag5 -136(2) . . . 2_675 ?
Ag3 Ag4 C19 Ag5 -3.7(4) 2_675 . . 2_675 ?
Ag2 Ag4 C19 Ag5 144.8(3) . . . 2_675 ?
Ag1 Ag4 C19 Ag5 148.08(11) . . . 2_675 ?
Ag3 Ag4 C19 Ag5 76.4(2) . . . 2_675 ?
Ag5 Ag4 C19 Ag5 80.8(3) . . . 2_675 ?
C7 Ag4 C19 Ag3 148(2) . . . . ?
Ag3 Ag4 C19 Ag3 -80.1(3) 2_675 . . . ?
Ag2 Ag4 C19 Ag3 68.44(17) . . . . ?
Ag5 Ag4 C19 Ag3 -76.4(2) 2_675 . . . ?
Ag1 Ag4 C19 Ag3 71.7(2) . . . . ?
Ag5 Ag4 C19 Ag3 4.5(4) . . . . ?
C7 Ag4 C19 Ag2 79(2) . . . . ?
Ag3 Ag4 C19 Ag2 -148.53(14) 2_675 . . . ?
Ag5 Ag4 C19 Ag2 -144.8(3) 2_675 . . . ?
Ag1 Ag4 C19 Ag2 3.3(3) . . . . ?
Ag3 Ag4 C19 Ag2 -68.44(17) . . . . ?
Ag5 Ag4 C19 Ag2 -64.0(3) . . . . ?
O2 Ag3 C19 C20 25.2(8) . . . . ?
C7 Ag3 C19 C20 -89.5(8) 2_675 . . . ?
C13 Ag3 C19 C20 128.3(8) . . . . ?
Ag4 Ag3 C19 C20 -136.9(8) 2_675 . . . ?
Ag2 Ag3 C19 C20 98.6(8) . . . . ?
Ag5 Ag3 C19 C20 -100.6(8) 2_675 . . . ?
Ag4 Ag3 C19 C20 174.6(10) . . . . ?
O2 Ag3 C19 Ag4 -149.4(3) . . . . ?
C7 Ag3 C19 Ag4 96.0(3) 2_675 . . . ?
C13 Ag3 C19 Ag4 -46.3(3) . . . . ?
Ag4 Ag3 C19 Ag4 48.6(3) 2_675 . . . ?
Ag2 Ag3 C19 Ag4 -76.0(2) . . . . ?
Ag5 Ag3 C19 Ag4 84.8(3) 2_675 . . . ?
O2 Ag3 C19 Ag5 125.8(3) . . . 2_675 ?
C7 Ag3 C19 Ag5 11.1(3) 2_675 . . 2_675 ?
C13 Ag3 C19 Ag5 -131.1(3) . . . 2_675 ?
Ag4 Ag3 C19 Ag5 -36.3(2) 2_675 . . 2_675 ?
Ag2 Ag3 C19 Ag5 -160.8(3) . . . 2_675 ?
Ag4 Ag3 C19 Ag5 -84.8(3) . . . 2_675 ?
O2 Ag3 C19 Ag2 -73.4(2) . . . . ?
C7 Ag3 C19 Ag2 171.9(2) 2_675 . . . ?
C13 Ag3 C19 Ag2 29.7(3) . . . . ?
Ag4 Ag3 C19 Ag2 124.52(11) 2_675 . . . ?
Ag5 Ag3 C19 Ag2 160.8(3) 2_675 . . . ?
Ag4 Ag3 C19 Ag2 76.0(2) . . . . ?
C13 Ag2 C19 C20 -146.7(7) . . . . ?
O1 Ag2 C19 C20 -43.9(7) . . . . ?
P1 Ag2 C19 C20 72.5(7) . . . . ?
Ag1 Ag2 C19 C20 156.8(6) . . . . ?
Ag4 Ag2 C19 C20 159.9(8) . . . . ?
Ag3 Ag2 C19 C20 -113.2(7) . . . . ?
C13 Ag2 C19 Ag4 53.4(3) . . . . ?
O1 Ag2 C19 Ag4 156.1(2) . . . . ?
P1 Ag2 C19 Ag4 -87.5(2) . . . . ?
Ag1 Ag2 C19 Ag4 -3.2(3) . . . . ?
Ag3 Ag2 C19 Ag4 86.8(2) . . . . ?
C13 Ag2 C19 Ag5 -5.1(6) . . . 2_675 ?
O1 Ag2 C19 Ag5 97.7(6) . . . 2_675 ?
P1 Ag2 C19 Ag5 -146.0(5) . . . 2_675 ?
Ag1 Ag2 C19 Ag5 -61.7(6) . . . 2_675 ?
Ag4 Ag2 C19 Ag5 -58.5(5) . . . 2_675 ?
Ag3 Ag2 C19 Ag5 28.4(4) . . . 2_675 ?
C13 Ag2 C19 Ag3 -33.5(3) . . . . ?
O1 Ag2 C19 Ag3 69.3(2) . . . . ?
P1 Ag2 C19 Ag3 -174.32(9) . . . . ?
Ag1 Ag2 C19 Ag3 -90.01(15) . . . . ?
Ag4 Ag2 C19 Ag3 -86.8(2) . . . . ?
F6 C2 C3 F9 178.3(15) . . . . ?
F7 C2 C3 F9 63.7(15) . . . . ?
C1 C2 C3 F9 -49.3(19) . . . . ?
F6 C2 C3 F10 -54.1(17) . . . . ?
F7 C2 C3 F10 -168.7(11) . . . . ?
C1 C2 C3 F10 78.3(16) . . . . ?
F6 C2 C3 F8 57.6(17) . . . . ?
F7 C2 C3 F8 -57.0(14) . . . . ?
C1 C2 C3 F8 -170.0(12) . . . . ?
O1 Ag2 C13 C14 -7.5(16) . . . . ?
P1 Ag2 C13 C14 -136.3(15) . . . . ?
C19 Ag2 C13 C14 97.2(16) . . . . ?
Ag1 Ag2 C13 C14 -159.6(17) . . . . ?
Ag4 Ag2 C13 C14 132.4(16) . . . . ?
Ag3 Ag2 C13 C14 64.5(15) . . . . ?
O1 Ag2 C13 Ag1 152.1(2) . . . . ?
P1 Ag2 C13 Ag1 23.3(4) . . . . ?
C19 Ag2 C13 Ag1 -103.2(3) . . . . ?
Ag4 Ag2 C13 Ag1 -67.95(16) . . . . ?
Ag3 Ag2 C13 Ag1 -135.9(3) . . . . ?
O1 Ag2 C13 Ag3 -72.0(3) . . . . ?
P1 Ag2 C13 Ag3 159.19(12) . . . . ?
C19 Ag2 C13 Ag3 32.8(3) . . . . ?
Ag1 Ag2 C13 Ag3 135.9(3) . . . . ?
Ag4 Ag2 C13 Ag3 67.98(15) . . . . ?
O1 Ag2 C13 Ag5 -156.8(4) . . . . ?
P1 Ag2 C13 Ag5 74.4(5) . . . . ?
C19 Ag2 C13 Ag5 -52.0(5) . . . . ?
Ag1 Ag2 C13 Ag5 51.1(3) . . . . ?
Ag4 Ag2 C13 Ag5 -16.9(3) . . . . ?
Ag3 Ag2 C13 Ag5 -84.8(4) . . . . ?
O4 Ag1 C13 C14 7.9(12) . . . . ?
N1 Ag1 C13 C14 104.8(11) . . . . ?
C7 Ag1 C13 C14 -98.3(11) . . . . ?
Ag5 Ag1 C13 C14 -57.9(10) . . . . ?
Ag2 Ag1 C13 C14 165.7(12) . . . . ?
Ag4 Ag1 C13 C14 -129.0(11) . . . . ?
O4 Ag1 C13 Ag2 -157.7(2) . . . . ?
N1 Ag1 C13 Ag2 -60.9(3) . . . . ?
C7 Ag1 C13 Ag2 96.0(3) . . . . ?
Ag5 Ag1 C13 Ag2 136.5(3) . . . . ?
Ag4 Ag1 C13 Ag2 65.30(18) . . . . ?
O4 Ag1 C13 Ag3 145.9(4) . . . . ?
N1 Ag1 C13 Ag3 -117.3(4) . . . . ?
C7 Ag1 C13 Ag3 39.6(5) . . . . ?
Ag5 Ag1 C13 Ag3 80.0(4) . . . . ?
Ag2 Ag1 C13 Ag3 -56.4(3) . . . . ?
Ag4 Ag1 C13 Ag3 8.9(3) . . . . ?
O4 Ag1 C13 Ag5 65.8(3) . . . . ?
N1 Ag1 C13 Ag5 162.7(2) . . . . ?
C7 Ag1 C13 Ag5 -40.5(3) . . . . ?
Ag2 Ag1 C13 Ag5 -136.5(3) . . . . ?
Ag4 Ag1 C13 Ag5 -71.17(15) . . . . ?
O2 Ag3 C13 C14 -81.7(7) . . . . ?
C7 Ag3 C13 C14 52.1(8) 2_675 . . . ?
C19 Ag3 C13 C14 173.8(7) . . . . ?
Ag4 Ag3 C13 C14 69.8(6) 2_675 . . . ?
Ag2 Ag3 C13 C14 -152.4(8) . . . . ?
Ag5 Ag3 C13 C14 129.7(6) 2_675 . . . ?
Ag4 Ag3 C13 C14 142.2(7) . . . . ?
O2 Ag3 C13 Ag2 70.7(3) . . . . ?
C7 Ag3 C13 Ag2 -155.5(3) 2_675 . . . ?
C19 Ag3 C13 Ag2 -33.8(3) . . . . ?
Ag4 Ag3 C13 Ag2 -137.85(18) 2_675 . . . ?
Ag5 Ag3 C13 Ag2 -77.9(3) 2_675 . . . ?
Ag4 Ag3 C13 Ag2 -65.42(17) . . . . ?
O2 Ag3 C13 Ag1 127.3(4) . . . . ?
C7 Ag3 C13 Ag1 -99.0(5) 2_675 . . . ?
C19 Ag3 C13 Ag1 22.8(5) . . . . ?
Ag4 Ag3 C13 Ag1 -81.3(4) 2_675 . . . ?
Ag2 Ag3 C13 Ag1 56.5(3) . . . . ?
Ag5 Ag3 C13 Ag1 -21.4(5) 2_675 . . . ?
Ag4 Ag3 C13 Ag1 -8.9(3) . . . . ?
O2 Ag3 C13 Ag5 -165.1(3) . . . . ?
C7 Ag3 C13 Ag5 -31.3(5) 2_675 . . . ?
C19 Ag3 C13 Ag5 90.4(3) . . . . ?
Ag4 Ag3 C13 Ag5 -13.7(2) 2_675 . . . ?
Ag2 Ag3 C13 Ag5 124.2(4) . . . . ?
Ag5 Ag3 C13 Ag5 46.2(3) 2_675 . . . ?
Ag4 Ag3 C13 Ag5 58.7(2) . . . . ?
O3 Ag5 C13 C14 73.8(7) . . . . ?
C19 Ag5 C13 C14 -63.2(8) 2_675 . . . ?
C7 Ag5 C13 C14 -178.1(7) . . . . ?
Ag1 Ag5 C13 C14 142.0(8) . . . . ?
Ag4 Ag5 C13 C14 -77.3(6) 2_675 . . . ?
Ag3 Ag5 C13 C14 -133.6(6) 2_675 . . . ?
Ag4 Ag5 C13 C14 -148.4(7) . . . . ?
O3 Ag5 C13 Ag2 -121.5(5) . . . . ?
C19 Ag5 C13 Ag2 101.5(5) 2_675 . . . ?
C7 Ag5 C13 Ag2 -13.4(5) . . . . ?
C14 Ag5 C13 Ag2 164.7(10) . . . . ?
Ag1 Ag5 C13 Ag2 -53.3(3) . . . . ?
Ag4 Ag5 C13 Ag2 87.4(4) 2_675 . . . ?
Ag3 Ag5 C13 Ag2 31.1(5) 2_675 . . . ?
Ag4 Ag5 C13 Ag2 16.3(3) . . . . ?
O3 Ag5 C13 Ag1 -68.2(3) . . . . ?
C19 Ag5 C13 Ag1 154.8(3) 2_675 . . . ?
C7 Ag5 C13 Ag1 39.9(3) . . . . ?
C14 Ag5 C13 Ag1 -142.0(8) . . . . ?
Ag4 Ag5 C13 Ag1 140.64(17) 2_675 . . . ?
Ag3 Ag5 C13 Ag1 84.4(2) 2_675 . . . ?
Ag4 Ag5 C13 Ag1 69.64(16) . . . . ?
O3 Ag5 C13 Ag3 164.4(3) . . . . ?
C19 Ag5 C13 Ag3 27.3(5) 2_675 . . . ?
C7 Ag5 C13 Ag3 -87.5(3) . . . . ?
C14 Ag5 C13 Ag3 90.6(7) . . . . ?
Ag1 Ag5 C13 Ag3 -127.4(4) . . . . ?
Ag4 Ag5 C13 Ag3 13.2(2) 2_675 . . . ?
Ag3 Ag5 C13 Ag3 -43.1(3) 2_675 . . . ?
Ag4 Ag5 C13 Ag3 -57.8(2) . . . . ?
Ag2 C13 C14 C15 61(8) . . . . ?
Ag1 C13 C14 C15 -91(7) . . . . ?
Ag3 C13 C14 C15 121(7) . . . . ?
Ag5 C13 C14 C15 -144(7) . . . . ?
Ag2 C13 C14 Ag5 -154.8(16) . . . . ?
Ag1 C13 C14 Ag5 52.9(8) . . . . ?
Ag3 C13 C14 Ag5 -94.5(3) . . . . ?
C17 C15 C14 C13 -178(7) . . . . ?
C16 C15 C14 C13 59(8) . . . . ?
C18 C15 C14 C13 -56(8) . . . . ?
C17 C15 C14 Ag5 40.3(15) . . . . ?
C16 C15 C14 Ag5 -82.8(15) . . . . ?
C18 C15 C14 Ag5 162.6(12) . . . . ?
O3 Ag5 C14 C13 -112.1(7) . . . . ?
C19 Ag5 C14 C13 132.5(6) 2_675 . . . ?
C7 Ag5 C14 C13 2.3(8) . . . . ?
Ag1 Ag5 C14 C13 -30.6(6) . . . . ?
Ag4 Ag5 C14 C13 101.2(7) 2_675 . . . ?
Ag3 Ag5 C14 C13 64.1(7) 2_675 . . . ?
Ag4 Ag5 C14 C13 29.0(6) . . . . ?
O3 Ag5 C14 C15 61.8(9) . . . . ?
C19 Ag5 C14 C15 -53.6(9) 2_675 . . . ?
C13 Ag5 C14 C15 173.9(13) . . . . ?
C7 Ag5 C14 C15 176.2(8) . . . . ?
Ag1 Ag5 C14 C15 143.3(9) . . . . ?
Ag4 Ag5 C14 C15 -84.9(8) 2_675 . . . ?
Ag3 Ag5 C14 C15 -122.1(8) 2_675 . . . ?
Ag4 Ag5 C14 C15 -157.1(8) . . . . ?
C43 Ag8 Ag7 C31 -120.2(3) . . . . ?
C37 Ag8 Ag7 C31 61.7(4) . . . . ?
Ag10 Ag8 Ag7 C31 -94.2(2) 2_566 . . . ?
Ag6 Ag8 Ag7 C31 4.7(2) 2_566 . . . ?
Ag9 Ag8 Ag7 C31 56.7(2) . . . . ?
Ag6 Ag8 Ag7 C31 -58.9(2) . . . . ?
C43 Ag8 Ag7 O7 -30.5(4) . . . . ?
C37 Ag8 Ag7 O7 151.3(4) . . . . ?
Ag10 Ag8 Ag7 O7 -4.6(3) 2_566 . . . ?
Ag6 Ag8 Ag7 O7 94.3(3) 2_566 . . . ?
Ag9 Ag8 Ag7 O7 146.3(3) . . . . ?
Ag6 Ag8 Ag7 O7 30.8(3) . . . . ?
C43 Ag8 Ag7 P2 107.6(3) . . . . ?
C37 Ag8 Ag7 P2 -70.5(3) . . . . ?
Ag10 Ag8 Ag7 P2 133.56(6) 2_566 . . . ?
Ag6 Ag8 Ag7 P2 -127.51(7) 2_566 . . . ?
Ag9 Ag8 Ag7 P2 -75.51(6) . . . . ?
Ag6 Ag8 Ag7 P2 168.92(6) . . . . ?
C43 Ag8 Ag7 Ag9 -176.8(3) . . . . ?
C37 Ag8 Ag7 Ag9 5.0(3) . . . . ?
Ag10 Ag8 Ag7 Ag9 -150.93(3) 2_566 . . . ?
Ag6 Ag8 Ag7 Ag9 -52.00(4) 2_566 . . . ?
Ag6 Ag8 Ag7 Ag9 -115.57(3) . . . . ?
C43 Ag8 Ag7 Ag6 -61.3(3) . . . . ?
C37 Ag8 Ag7 Ag6 120.6(3) . . . . ?
Ag10 Ag8 Ag7 Ag6 -35.36(3) 2_566 . . . ?
Ag6 Ag8 Ag7 Ag6 63.57(5) 2_566 . . . ?
Ag9 Ag8 Ag7 Ag6 115.57(3) . . . . ?
C31 Ag7 Ag6 C37 95.0(13) . . . 2_566 ?
O7 Ag7 Ag6 C37 -158.8(13) . . . 2_566 ?
P2 Ag7 Ag6 C37 -25.3(13) . . . 2_566 ?
Ag9 Ag7 Ag6 C37 55.5(13) . . . 2_566 ?
Ag8 Ag7 Ag6 C37 1.4(13) . . . 2_566 ?
C31 Ag7 Ag6 O8 -107.0(3) . . . . ?
O7 Ag7 Ag6 O8 -0.8(2) . . . . ?
P2 Ag7 Ag6 O8 132.7(2) . . . . ?
Ag9 Ag7 Ag6 O8 -146.52(18) . . . . ?
Ag8 Ag7 Ag6 O8 159.37(18) . . . . ?
C31 Ag7 Ag6 C43 143.3(3) . . . . ?
O7 Ag7 Ag6 C43 -110.5(3) . . . . ?
P2 Ag7 Ag6 C43 23.0(3) . . . . ?
Ag9 Ag7 Ag6 C43 103.8(2) . . . . ?
Ag8 Ag7 Ag6 C43 49.7(2) . . . . ?
O7 Ag7 Ag6 C31 106.2(3) . . . . ?
P2 Ag7 Ag6 C31 -120.3(3) . . . . ?
Ag9 Ag7 Ag6 C31 -39.5(2) . . . . ?
Ag8 Ag7 Ag6 C31 -93.6(2) . . . . ?
C31 Ag7 Ag6 Ag8 48.8(2) . . . 2_566 ?
O7 Ag7 Ag6 Ag8 154.97(18) . . . 2_566 ?
P2 Ag7 Ag6 Ag8 -71.52(15) . . . 2_566 ?
Ag9 Ag7 Ag6 Ag8 9.26(4) . . . 2_566 ?
Ag8 Ag7 Ag6 Ag8 -44.86(4) . . . 2_566 ?
C31 Ag7 Ag6 Ag8 93.6(2) . . . . ?
O7 Ag7 Ag6 Ag8 -160.17(17) . . . . ?
P2 Ag7 Ag6 Ag8 -26.67(15) . . . . ?
Ag9 Ag7 Ag6 Ag8 54.11(3) . . . . ?
C31 Ag7 Ag6 Ag10 124.0(2) . . . 2_566 ?
O7 Ag7 Ag6 Ag10 -129.76(17) . . . 2_566 ?
P2 Ag7 Ag6 Ag10 3.75(15) . . . 2_566 ?
Ag9 Ag7 Ag6 Ag10 84.52(3) . . . 2_566 ?
Ag8 Ag7 Ag6 Ag10 30.41(2) . . . 2_566 ?
C43 Ag8 Ag6 C37 -98.2(4) . . . 2_566 ?
C37 Ag8 Ag6 C37 83.9(4) . . . 2_566 ?
Ag10 Ag8 Ag6 C37 -36.4(3) 2_566 . . 2_566 ?
Ag7 Ag8 Ag6 C37 -179.7(3) . . . 2_566 ?
Ag6 Ag8 Ag6 C37 34.8(3) 2_566 . . 2_566 ?
Ag9 Ag8 Ag6 C37 130.6(3) . . . 2_566 ?
C43 Ag8 Ag6 O8 51.9(4) . . . . ?
C37 Ag8 Ag6 O8 -125.9(4) . . . . ?
Ag10 Ag8 Ag6 O8 113.8(2) 2_566 . . . ?
Ag7 Ag8 Ag6 O8 -29.5(2) . . . . ?
Ag6 Ag8 Ag6 O8 -175.0(2) 2_566 . . . ?
Ag9 Ag8 Ag6 O8 -79.2(2) . . . . ?
C37 Ag8 Ag6 C43 -177.9(4) . . . . ?
Ag10 Ag8 Ag6 C43 61.9(3) 2_566 . . . ?
Ag7 Ag8 Ag6 C43 -81.5(3) . . . . ?
Ag6 Ag8 Ag6 C43 133.1(3) 2_566 . . . ?
Ag9 Ag8 Ag6 C43 -131.2(3) . . . . ?
C43 Ag8 Ag6 C31 132.7(4) . . . . ?
C37 Ag8 Ag6 C31 -45.2(4) . . . . ?
Ag10 Ag8 Ag6 C31 -165.5(2) 2_566 . . . ?
Ag7 Ag8 Ag6 C31 51.2(2) . . . . ?
Ag6 Ag8 Ag6 C31 -94.3(2) 2_566 . . . ?
Ag9 Ag8 Ag6 C31 1.5(2) . . . . ?
C43 Ag8 Ag6 Ag8 -133.1(3) . . . 2_566 ?
C37 Ag8 Ag6 Ag8 49.1(3) . . . 2_566 ?
Ag10 Ag8 Ag6 Ag8 -71.18(2) 2_566 . . 2_566 ?
Ag7 Ag8 Ag6 Ag8 145.49(3) . . . 2_566 ?
Ag6 Ag8 Ag6 Ag8 0.0 2_566 . . 2_566 ?
Ag9 Ag8 Ag6 Ag8 95.77(3) . . . 2_566 ?
C43 Ag8 Ag6 Ag7 81.5(3) . . . . ?
C37 Ag8 Ag6 Ag7 -96.4(3) . . . . ?
Ag10 Ag8 Ag6 Ag7 143.33(3) 2_566 . . . ?
Ag6 Ag8 Ag6 Ag7 -145.49(3) 2_566 . . . ?
Ag9 Ag8 Ag6 Ag7 -49.72(2) . . . . ?
C43 Ag8 Ag6 Ag10 -61.9(3) . . . 2_566 ?
C37 Ag8 Ag6 Ag10 120.3(3) . . . 2_566 ?
Ag7 Ag8 Ag6 Ag10 -143.33(3) . . . 2_566 ?
Ag6 Ag8 Ag6 Ag10 71.18(2) 2_566 . . 2_566 ?
Ag9 Ag8 Ag6 Ag10 166.95(3) . . . 2_566 ?
C43 Ag10 Ag9 O5 109.8(5) 2_566 . . . ?
O6 Ag10 Ag9 O5 -4.8(3) . . . . ?
C31 Ag10 Ag9 O5 -116.5(3) . . . . ?
C32 Ag10 Ag9 O5 -101.5(3) . . . . ?
Ag8 Ag10 Ag9 O5 179.5(2) 2_566 . . . ?
Ag6 Ag10 Ag9 O5 122.2(2) 2_566 . . . ?
C43 Ag10 Ag9 N2 150.3(7) 2_566 . . . ?
O6 Ag10 Ag9 N2 35.7(6) . . . . ?
C31 Ag10 Ag9 N2 -76.0(6) . . . . ?
C32 Ag10 Ag9 N2 -61.0(6) . . . . ?
Ag8 Ag10 Ag9 N2 -140.0(6) 2_566 . . . ?
Ag6 Ag10 Ag9 N2 162.7(6) 2_566 . . . ?
C43 Ag10 Ag9 C31 -133.7(5) 2_566 . . . ?
O6 Ag10 Ag9 C31 111.7(3) . . . . ?
C32 Ag10 Ag9 C31 15.0(3) . . . . ?
Ag8 Ag10 Ag9 C31 -63.9(2) 2_566 . . . ?
Ag6 Ag10 Ag9 C31 -121.2(2) 2_566 . . . ?
C43 Ag10 Ag9 C37 -4.6(5) 2_566 . . . ?
O6 Ag10 Ag9 C37 -119.2(3) . . . . ?
C31 Ag10 Ag9 C37 129.1(3) . . . . ?
C32 Ag10 Ag9 C37 144.1(3) . . . . ?
Ag8 Ag10 Ag9 C37 65.2(3) 2_566 . . . ?
Ag6 Ag10 Ag9 C37 7.9(2) 2_566 . . . ?
C43 Ag10 Ag9 Ag7 -105.2(4) 2_566 . . . ?
O6 Ag10 Ag9 Ag7 140.2(2) . . . . ?
C31 Ag10 Ag9 Ag7 28.5(2) . . . . ?
C32 Ag10 Ag9 Ag7 43.5(2) . . . . ?
Ag8 Ag10 Ag9 Ag7 -35.43(5) 2_566 . . . ?
Ag6 Ag10 Ag9 Ag7 -92.72(3) 2_566 . . . ?
C43 Ag10 Ag9 Ag8 -50.7(4) 2_566 . . . ?
O6 Ag10 Ag9 Ag8 -165.3(2) . . . . ?
C31 Ag10 Ag9 Ag8 83.0(2) . . . . ?
C32 Ag10 Ag9 Ag8 98.0(2) . . . . ?
Ag8 Ag10 Ag9 Ag8 19.09(5) 2_566 . . . ?
Ag6 Ag10 Ag9 Ag8 -38.20(2) 2_566 . . . ?
C31 Ag7 Ag9 O5 51.0(4) . . . . ?
O7 Ag7 Ag9 O5 5.9(5) . . . . ?
P2 Ag7 Ag9 O5 -113.7(3) . . . . ?
Ag8 Ag7 Ag9 O5 145.3(3) . . . . ?
Ag6 Ag7 Ag9 O5 91.6(3) . . . . ?
C31 Ag7 Ag9 N2 131.9(3) . . . . ?
O7 Ag7 Ag9 N2 86.8(4) . . . . ?
P2 Ag7 Ag9 N2 -32.9(2) . . . . ?
Ag8 Ag7 Ag9 N2 -133.8(2) . . . . ?
Ag6 Ag7 Ag9 N2 172.5(2) . . . . ?
O7 Ag7 Ag9 C31 -45.1(4) . . . . ?
P2 Ag7 Ag9 C31 -164.7(3) . . . . ?
Ag8 Ag7 Ag9 C31 94.3(3) . . . . ?
Ag6 Ag7 Ag9 C31 40.6(3) . . . . ?
C31 Ag7 Ag9 C37 -98.3(3) . . . . ?
O7 Ag7 Ag9 C37 -143.4(4) . . . . ?
P2 Ag7 Ag9 C37 97.0(2) . . . . ?
Ag8 Ag7 Ag9 C37 -3.9(2) . . . . ?
Ag6 Ag7 Ag9 C37 -57.6(2) . . . . ?
C31 Ag7 Ag9 Ag10 -30.5(3) . . . . ?
O7 Ag7 Ag9 Ag10 -75.6(3) . . . . ?
P2 Ag7 Ag9 Ag10 164.75(6) . . . . ?
Ag8 Ag7 Ag9 Ag10 63.82(3) . . . . ?
Ag6 Ag7 Ag9 Ag10 10.12(3) . . . . ?
C31 Ag7 Ag9 Ag8 -94.3(3) . . . . ?
O7 Ag7 Ag9 Ag8 -139.4(3) . . . . ?
P2 Ag7 Ag9 Ag8 100.93(6) . . . . ?
Ag6 Ag7 Ag9 Ag8 -53.69(2) . . . . ?
C43 Ag8 Ag9 O5 -141.8(5) . . . . ?
C37 Ag8 Ag9 O5 40.3(5) . . . . ?
Ag10 Ag8 Ag9 O5 -68.2(4) 2_566 . . . ?
Ag7 Ag8 Ag9 O5 -145.3(4) . . . . ?
Ag6 Ag8 Ag9 O5 5.0(4) 2_566 . . . ?
Ag6 Ag8 Ag9 O5 -94.2(4) . . . . ?
C43 Ag8 Ag9 N2 65.6(4) . . . . ?
C37 Ag8 Ag9 N2 -112.3(4) . . . . ?
Ag10 Ag8 Ag9 N2 139.2(2) 2_566 . . . ?
Ag7 Ag8 Ag9 N2 62.1(2) . . . . ?
Ag6 Ag8 Ag9 N2 -147.5(2) 2_566 . . . ?
Ag6 Ag8 Ag9 N2 113.2(2) . . . . ?
C43 Ag8 Ag9 C31 -49.2(4) . . . . ?
C37 Ag8 Ag9 C31 133.0(4) . . . . ?
Ag10 Ag8 Ag9 C31 24.5(2) 2_566 . . . ?
Ag7 Ag8 Ag9 C31 -52.7(2) . . . . ?
Ag6 Ag8 Ag9 C31 97.7(2) 2_566 . . . ?
Ag6 Ag8 Ag9 C31 -1.6(2) . . . . ?
C43 Ag8 Ag9 C37 177.9(4) . . . . ?
Ag10 Ag8 Ag9 C37 -108.5(3) 2_566 . . . ?
Ag7 Ag8 Ag9 C37 174.4(3) . . . . ?
Ag6 Ag8 Ag9 C37 -35.3(3) 2_566 . . . ?
Ag6 Ag8 Ag9 C37 -134.5(3) . . . . ?
C43 Ag8 Ag9 Ag10 -106.5(3) . . . . ?
C37 Ag8 Ag9 Ag10 75.6(3) . . . . ?
Ag10 Ag8 Ag9 Ag10 -32.89(7) 2_566 . . . ?
Ag7 Ag8 Ag9 Ag10 -110.03(3) . . . . ?
Ag6 Ag8 Ag9 Ag10 40.33(3) 2_566 . . . ?
Ag6 Ag8 Ag9 Ag10 -58.93(3) . . . . ?
C43 Ag8 Ag9 Ag7 3.5(3) . . . . ?
C37 Ag8 Ag9 Ag7 -174.4(3) . . . . ?
Ag10 Ag8 Ag9 Ag7 77.14(7) 2_566 . . . ?
Ag6 Ag8 Ag9 Ag7 150.36(3) 2_566 . . . ?
Ag6 Ag8 Ag9 Ag7 51.10(2) . . . . ?
C31 Ag7 P2 C211 152.4(5) . . . . ?
O7 Ag7 P2 C211 21.8(4) . . . . ?
Ag9 Ag7 P2 C211 169.4(4) . . . . ?
Ag8 Ag7 P2 C211 -129.3(4) . . . . ?
Ag6 Ag7 P2 C211 -105.8(4) . . . . ?
C31 Ag7 P2 C231 32.1(4) . . . . ?
O7 Ag7 P2 C231 -98.5(4) . . . . ?
Ag9 Ag7 P2 C231 49.1(3) . . . . ?
Ag8 Ag7 P2 C231 110.4(3) . . . . ?
Ag6 Ag7 P2 C231 133.9(3) . . . . ?
C31 Ag7 P2 C221 -83.5(4) . . . . ?
O7 Ag7 P2 C221 145.8(4) . . . . ?
Ag9 Ag7 P2 C221 -66.6(3) . . . . ?
Ag8 Ag7 P2 C221 -5.3(4) . . . . ?
Ag6 Ag7 P2 C221 18.3(4) . . . . ?
N2 Ag9 O5 C25 -161.9(10) . . . . ?
C31 Ag9 O5 C25 -42.6(10) . . . . ?
C37 Ag9 O5 C25 67.9(10) . . . . ?
Ag10 Ag9 O5 C25 6.3(9) . . . . ?
Ag7 Ag9 O5 C25 -80.6(11) . . . . ?
Ag8 Ag9 O5 C25 40.2(12) . . . . ?
C43 Ag10 O6 C25 -142.5(8) 2_566 . . . ?
C31 Ag10 O6 C25 57.6(8) . . . . ?
C32 Ag10 O6 C25 84.0(8) . . . . ?
Ag8 Ag10 O6 C25 -178.9(6) 2_566 . . . ?
Ag9 Ag10 O6 C25 6.8(8) . . . . ?
Ag6 Ag10 O6 C25 -86.7(8) 2_566 . . . ?
C31 Ag7 O7 C28 55.7(7) . . . . ?
P2 Ag7 O7 C28 -158.9(6) . . . . ?
Ag9 Ag7 O7 C28 91.7(7) . . . . ?
Ag8 Ag7 O7 C28 -26.2(8) . . . . ?
Ag6 Ag7 O7 C28 1.1(7) . . . . ?
C37 Ag6 O8 C28 176.2(7) 2_566 . . . ?
C43 Ag6 O8 C28 59.4(8) . . . . ?
C31 Ag6 O8 C28 -44.4(8) . . . . ?
Ag8 Ag6 O8 C28 -145.5(6) 2_566 . . . ?
Ag7 Ag6 O8 C28 1.1(7) . . . . ?
Ag8 Ag6 O8 C28 26.1(8) . . . . ?
Ag10 Ag6 O8 C28 103.3(7) 2_566 . . . ?
O5 Ag9 N2 C235 -3.7(8) . . . . ?
C31 Ag9 N2 C235 -108.6(8) . . . . ?
C37 Ag9 N2 C235 106.2(8) . . . . ?
Ag10 Ag9 N2 C235 -43.5(11) . . . . ?
Ag7 Ag9 N2 C235 -149.4(7) . . . . ?
Ag8 Ag9 N2 C235 161.0(7) . . . . ?
O5 Ag9 N2 C231 166.9(7) . . . . ?
C31 Ag9 N2 C231 62.0(8) . . . . ?
C37 Ag9 N2 C231 -83.2(8) . . . . ?
Ag10 Ag9 N2 C231 127.1(7) . . . . ?
Ag7 Ag9 N2 C231 21.2(7) . . . . ?
Ag8 Ag9 N2 C231 -28.4(8) . . . . ?
F12 C29 C30 F13 -63.2(12) . . . . ?
F11 C29 C30 F13 -176.2(9) . . . . ?
C28 C29 C30 F13 62.6(14) . . . . ?
F12 C29 C30 F15 174.4(10) . . . . ?
F11 C29 C30 F15 61.5(12) . . . . ?
C28 C29 C30 F15 -59.7(14) . . . . ?
F12 C29 C30 F14 56.3(13) . . . . ?
F11 C29 C30 F14 -56.6(13) . . . . ?
C28 C29 C30 F14 -177.8(10) . . . . ?
C215 C214 C213 C212 -2(3) . . . . ?
Ag9 O5 C25 O6 -2.9(19) . . . . ?
Ag9 O5 C25 C26 179.9(7) . . . . ?
Ag10 O6 C25 O5 -4.3(17) . . . . ?
Ag10 O6 C25 C26 172.9(7) . . . . ?
F20 C27 C26 F17 84(2) . . . . ?
F19 C27 C26 F17 -43(3) . . . . ?
F18 C27 C26 F17 -162.8(18) . . . . ?
F20 C27 C26 F16 -167(2) . . . . ?
F19 C27 C26 F16 66(3) . . . . ?
F18 C27 C26 F16 -54(2) . . . . ?
F20 C27 C26 C25 -44(3) . . . . ?
F19 C27 C26 C25 -172(2) . . . . ?
F18 C27 C26 C25 69(3) . . . . ?
O5 C25 C26 F17 -176.1(13) . . . . ?
O6 C25 C26 F17 6.2(17) . . . . ?
O5 C25 C26 F16 70.3(14) . . . . ?
O6 C25 C26 F16 -107.5(13) . . . . ?
O5 C25 C26 C27 -51(2) . . . . ?
O6 C25 C26 C27 131(2) . . . . ?
C231 N2 C235 C234 -2.3(16) . . . . ?
Ag9 N2 C235 C234 168.5(8) . . . . ?
C232 C233 C234 C235 3.7(19) . . . . ?
N2 C235 C234 C233 -0.8(18) . . . . ?
C234 C233 C232 C231 -3.3(19) . . . . ?
C213 C214 C215 C216 0(2) . . . . ?
C214 C215 C216 C211 2(2) . . . . ?
C215 C216 C211 C212 -1.8(18) . . . . ?
C215 C216 C211 P2 179.7(10) . . . . ?
C231 P2 C211 C212 106.0(10) . . . . ?
C221 P2 C211 C212 -145.5(10) . . . . ?
Ag7 P2 C211 C212 -16.4(11) . . . . ?
C231 P2 C211 C216 -75.5(10) . . . . ?
C221 P2 C211 C216 33.0(11) . . . . ?
Ag7 P2 C211 C216 162.1(8) . . . . ?
C214 C213 C212 C211 2(3) . . . . ?
C216 C211 C212 C213 0(2) . . . . ?
P2 C211 C212 C213 178.6(13) . . . . ?
Ag6 O8 C28 O7 -0.7(14) . . . . ?
Ag6 O8 C28 C29 176.7(7) . . . . ?
Ag7 O7 C28 O8 -0.6(14) . . . . ?
Ag7 O7 C28 C29 -178.0(6) . . . . ?
F12 C29 C28 O8 -58.5(13) . . . . ?
F11 C29 C28 O8 56.5(12) . . . . ?
C30 C29 C28 O8 177.4(10) . . . . ?
F12 C29 C28 O7 119.3(10) . . . . ?
F11 C29 C28 O7 -125.7(10) . . . . ?
C30 C29 C28 O7 -4.8(14) . . . . ?
C235 N2 C231 C232 2.6(14) . . . . ?
Ag9 N2 C231 C232 -167.9(8) . . . . ?
C235 N2 C231 P2 -176.8(7) . . . . ?
Ag9 N2 C231 P2 12.7(9) . . . . ?
C233 C232 C231 N2 0.1(16) . . . . ?
C233 C232 C231 P2 179.5(9) . . . . ?
C211 P2 C231 N2 -176.5(7) . . . . ?
C221 P2 C231 N2 73.7(7) . . . . ?
Ag7 P2 C231 N2 -49.4(7) . . . . ?
C211 P2 C231 C232 4.1(10) . . . . ?
C221 P2 C231 C232 -105.7(9) . . . . ?
Ag7 P2 C231 C232 131.2(8) . . . . ?
C211 P2 C221 C222 70.3(9) . . . . ?
C231 P2 C221 C222 -179.3(8) . . . . ?
Ag7 P2 C221 C222 -60.0(9) . . . . ?
C211 P2 C221 C225 -111.2(9) . . . . ?
C231 P2 C221 C225 -0.8(10) . . . . ?
Ag7 P2 C221 C225 118.5(8) . . . . ?
C109 C224 C225 C221 -0.4(19) . . . . ?
C222 C221 C225 C224 0.3(16) . . . . ?
P2 C221 C225 C224 -178.2(9) . . . . ?
C225 C221 C222 C223 -0.2(17) . . . . ?
P2 C221 C222 C223 178.3(9) . . . . ?
C221 C222 C223 C109 0.2(19) . . . . ?
C225 C224 C109 C223 0(2) . . . . ?
C222 C223 C109 C224 0(2) . . . . ?
C37 Ag8 C43 C44 -23(12) . . . . ?
Ag10 Ag8 C43 C44 132(2) 2_566 . . . ?
Ag7 Ag8 C43 C44 -78(2) . . . . ?
Ag6 Ag8 C43 C44 143.8(19) 2_566 . . . ?
Ag9 Ag8 C43 C44 -81(2) . . . . ?
Ag6 Ag8 C43 C44 -146(2) . . . . ?
C37 Ag8 C43 Ag10 -155(10) . . . 2_566 ?
Ag7 Ag8 C43 Ag10 149.6(3) . . . 2_566 ?
Ag6 Ag8 C43 Ag10 11.5(4) 2_566 . . 2_566 ?
Ag9 Ag8 C43 Ag10 146.42(12) . . . 2_566 ?
Ag6 Ag8 C43 Ag10 81.3(2) . . . 2_566 ?
C37 Ag8 C43 Ag6 124(10) . . . . ?
Ag10 Ag8 C43 Ag6 -81.3(2) 2_566 . . . ?
Ag7 Ag8 C43 Ag6 68.39(18) . . . . ?
Ag6 Ag8 C43 Ag6 -69.8(3) 2_566 . . . ?
Ag9 Ag8 C43 Ag6 65.2(3) . . . . ?
C37 Ag6 C43 C44 -96.2(8) 2_566 . . . ?
O8 Ag6 C43 C44 20.7(8) . . . . ?
C31 Ag6 C43 C44 120.4(8) . . . . ?
Ag8 Ag6 C43 C44 -143.9(7) 2_566 . . . ?
Ag7 Ag6 C43 C44 93.5(8) . . . . ?
Ag8 Ag6 C43 C44 165.9(10) . . . . ?
Ag10 Ag6 C43 C44 -112.4(8) 2_566 . . . ?
C37 Ag6 C43 Ag8 97.9(3) 2_566 . . . ?
O8 Ag6 C43 Ag8 -145.2(3) . . . . ?
C31 Ag6 C43 Ag8 -45.5(3) . . . . ?
Ag8 Ag6 C43 Ag8 50.2(3) 2_566 . . . ?
Ag7 Ag6 C43 Ag8 -72.4(2) . . . . ?
Ag10 Ag6 C43 Ag8 81.7(3) 2_566 . . . ?
C37 Ag6 C43 Ag10 16.2(4) 2_566 . . 2_566 ?
O8 Ag6 C43 Ag10 133.2(2) . . . 2_566 ?
C31 Ag6 C43 Ag10 -127.2(3) . . . 2_566 ?
Ag8 Ag6 C43 Ag10 -31.4(3) 2_566 . . 2_566 ?
Ag7 Ag6 C43 Ag10 -154.1(3) . . . 2_566 ?
Ag8 Ag6 C43 Ag10 -81.7(3) . . . 2_566 ?
Ag8 C43 C44 C45 -45(26) . . . . ?
Ag10 C43 C44 C45 82(25) 2_566 . . . ?
Ag6 C43 C44 C45 173(100) . . . . ?
C43 C44 C45 C48 151(24) . . . . ?
C43 C44 C45 C46 29(25) . . . . ?
C43 C44 C45 C47 -90(25) . . . . ?
C43 Ag10 C32 C31 132.1(6) 2_566 . . . ?
O6 Ag10 C32 C31 -110.9(6) . . . . ?
Ag8 Ag10 C32 C31 104.6(6) 2_566 . . . ?
Ag9 Ag10 C32 C31 -27.0(5) . . . . ?
Ag6 Ag10 C32 C31 58.3(7) 2_566 . . . ?
C43 Ag10 C32 C33 -53.9(8) 2_566 . . . ?
O6 Ag10 C32 C33 63.2(7) . . . . ?
C31 Ag10 C32 C33 174.1(11) . . . . ?
Ag8 Ag10 C32 C33 -81.3(7) 2_566 . . . ?
Ag9 Ag10 C32 C33 147.1(7) . . . . ?
Ag6 Ag10 C32 C33 -127.6(6) 2_566 . . . ?
C33 C32 C31 Ag7 57(6) . . . . ?
Ag10 C32 C31 Ag7 -157.9(11) . . . . ?
C33 C32 C31 Ag9 -91(6) . . . . ?
Ag10 C32 C31 Ag9 53.7(9) . . . . ?
C33 C32 C31 Ag10 -145(6) . . . . ?
C33 C32 C31 Ag6 123(6) . . . . ?
Ag10 C32 C31 Ag6 -92.1(3) . . . . ?
O7 Ag7 C31 C32 -3.0(12) . . . . ?
P2 Ag7 C31 C32 -139.0(10) . . . . ?
Ag9 Ag7 C31 C32 -159.4(12) . . . . ?
Ag8 Ag7 C31 C32 135.4(12) . . . . ?
Ag6 Ag7 C31 C32 70.8(11) . . . . ?
O7 Ag7 C31 Ag9 156.4(2) . . . . ?
P2 Ag7 C31 Ag9 20.4(3) . . . . ?
Ag8 Ag7 C31 Ag9 -65.14(13) . . . . ?
Ag6 Ag7 C31 Ag9 -129.7(2) . . . . ?
O7 Ag7 C31 Ag10 -154.0(4) . . . . ?
P2 Ag7 C31 Ag10 70.1(5) . . . . ?
Ag9 Ag7 C31 Ag10 49.6(3) . . . . ?
Ag8 Ag7 C31 Ag10 -15.5(4) . . . . ?
Ag6 Ag7 C31 Ag10 -80.1(4) . . . . ?
O7 Ag7 C31 Ag6 -73.9(2) . . . . ?
P2 Ag7 C31 Ag6 150.17(13) . . . . ?
Ag9 Ag7 C31 Ag6 129.7(2) . . . . ?
Ag8 Ag7 C31 Ag6 64.59(12) . . . . ?
O5 Ag9 C31 C32 7.6(11) . . . . ?
N2 Ag9 C31 C32 101.9(11) . . . . ?
C37 Ag9 C31 C32 -105.2(11) . . . . ?
Ag10 Ag9 C31 C32 -57.8(10) . . . . ?
Ag7 Ag9 C31 C32 160.4(12) . . . . ?
Ag8 Ag9 C31 C32 -136.3(11) . . . . ?
O5 Ag9 C31 Ag7 -152.8(3) . . . . ?
N2 Ag9 C31 Ag7 -58.6(3) . . . . ?
C37 Ag9 C31 Ag7 94.4(3) . . . . ?
Ag10 Ag9 C31 Ag7 141.8(3) . . . . ?
Ag8 Ag9 C31 Ag7 63.29(15) . . . . ?
O5 Ag9 C31 Ag10 65.4(3) . . . . ?
N2 Ag9 C31 Ag10 159.6(2) . . . . ?
C37 Ag9 C31 Ag10 -47.4(3) . . . . ?
Ag7 Ag9 C31 Ag10 -141.8(3) . . . . ?
Ag8 Ag9 C31 Ag10 -78.51(14) . . . . ?
O5 Ag9 C31 Ag6 146.1(4) . . . . ?
N2 Ag9 C31 Ag6 -119.7(4) . . . . ?
C37 Ag9 C31 Ag6 33.3(5) . . . . ?
Ag10 Ag9 C31 Ag6 80.7(3) . . . . ?
Ag7 Ag9 C31 Ag6 -61.1(3) . . . . ?
Ag8 Ag9 C31 Ag6 2.2(3) . . . . ?
C43 Ag10 C31 C32 -73.3(8) 2_566 . . . ?
O6 Ag10 C31 C32 73.8(6) . . . . ?
Ag8 Ag10 C31 C32 -76.9(6) 2_566 . . . ?
Ag9 Ag10 C31 C32 146.7(7) . . . . ?
Ag6 Ag10 C31 C32 -138.1(5) 2_566 . . . ?
C43 Ag10 C31 Ag7 89.2(6) 2_566 . . . ?
O6 Ag10 C31 Ag7 -123.8(4) . . . . ?
C32 Ag10 C31 Ag7 162.5(9) . . . . ?
Ag8 Ag10 C31 Ag7 85.6(4) 2_566 . . . ?
Ag9 Ag10 C31 Ag7 -50.8(4) . . . . ?
Ag6 Ag10 C31 Ag7 24.4(5) 2_566 . . . ?
C43 Ag10 C31 Ag9 140.0(4) 2_566 . . . ?
O6 Ag10 C31 Ag9 -72.9(2) . . . . ?
C32 Ag10 C31 Ag9 -146.7(7) . . . . ?
Ag8 Ag10 C31 Ag9 136.45(13) 2_566 . . . ?
Ag6 Ag10 C31 Ag9 75.2(2) 2_566 . . . ?
C43 Ag10 C31 Ag6 16.9(6) 2_566 . . . ?
O6 Ag10 C31 Ag6 164.0(2) . . . . ?
C32 Ag10 C31 Ag6 90.2(6) . . . . ?
Ag8 Ag10 C31 Ag6 13.4(2) 2_566 . . . ?
Ag9 Ag10 C31 Ag6 -123.1(3) . . . . ?
Ag6 Ag10 C31 Ag6 -47.9(3) 2_566 . . . ?
C37 Ag6 C31 C32 52.3(7) 2_566 . . . ?
O8 Ag6 C31 C32 -72.2(6) . . . . ?
C43 Ag6 C31 C32 -176.9(6) . . . . ?
Ag8 Ag6 C31 C32 72.3(6) 2_566 . . . ?
Ag7 Ag6 C31 C32 -144.3(7) . . . . ?
Ag8 Ag6 C31 C32 152.4(6) . . . . ?
Ag10 Ag6 C31 C32 137.9(5) 2_566 . . . ?
C37 Ag6 C31 Ag7 -163.4(3) 2_566 . . . ?
O8 Ag6 C31 Ag7 72.1(2) . . . . ?
C43 Ag6 C31 Ag7 -32.5(3) . . . . ?
Ag8 Ag6 C31 Ag7 -143.36(16) 2_566 . . . ?
Ag8 Ag6 C31 Ag7 -63.23(15) . . . . ?
Ag10 Ag6 C31 Ag7 -77.8(2) 2_566 . . . ?
C37 Ag6 C31 Ag9 -102.4(5) 2_566 . . . ?
O8 Ag6 C31 Ag9 133.2(4) . . . . ?
C43 Ag6 C31 Ag9 28.5(4) . . . . ?
Ag8 Ag6 C31 Ag9 -82.3(4) 2_566 . . . ?
Ag7 Ag6 C31 Ag9 61.0(3) . . . . ?
Ag8 Ag6 C31 Ag9 -2.2(3) . . . . ?
Ag10 Ag6 C31 Ag9 -16.7(5) 2_566 . . . ?
C37 Ag6 C31 Ag10 -32.8(5) 2_566 . . . ?
O8 Ag6 C31 Ag10 -157.3(2) . . . . ?
C43 Ag6 C31 Ag10 98.1(3) . . . . ?
Ag8 Ag6 C31 Ag10 -12.8(2) 2_566 . . . ?
Ag7 Ag6 C31 Ag10 130.6(3) . . . . ?
Ag8 Ag6 C31 Ag10 67.37(18) . . . . ?
Ag10 Ag6 C31 Ag10 52.8(3) 2_566 . . . ?
C31 C32 C33 C35 70(6) . . . . ?
Ag10 C32 C33 C35 -71.9(10) . . . . ?
C31 C32 C33 C36 -170(6) . . . . ?
Ag10 C32 C33 C36 48.0(12) . . . . ?
C31 C32 C33 C34 -48(6) . . . . ?
Ag10 C32 C33 C34 170.0(7) . . . . ?
C43 Ag8 C37 C38 25(13) . . . . ?
Ag10 Ag8 C37 C38 -130(3) 2_566 . . . ?
Ag7 Ag8 C37 C38 79(4) . . . . ?
Ag6 Ag8 C37 C38 -142(4) 2_566 . . . ?
Ag9 Ag8 C37 C38 84(3) . . . . ?
Ag6 Ag8 C37 C38 147(3) . . . . ?
C43 Ag8 C37 Ag6 167(10) . . . 2_566 ?
Ag10 Ag8 C37 Ag6 12.5(4) 2_566 . . 2_566 ?
Ag7 Ag8 C37 Ag6 -138.51(15) . . . 2_566 ?
Ag9 Ag8 C37 Ag6 -133.4(4) . . . 2_566 ?
Ag6 Ag8 C37 Ag6 -70.7(3) . . . 2_566 ?
C43 Ag8 C37 Ag9 -60(11) . . . . ?
Ag10 Ag8 C37 Ag9 145.90(13) 2_566 . . . ?
Ag7 Ag8 C37 Ag9 -5.1(3) . . . . ?
Ag6 Ag8 C37 Ag9 133.4(4) 2_566 . . . ?
Ag6 Ag8 C37 Ag9 62.7(3) . . . . ?
O5 Ag9 C37 C38 37.0(8) . . . . ?
N2 Ag9 C37 C38 -63.1(9) . . . . ?
C31 Ag9 C37 C38 147.8(7) . . . . ?
Ag10 Ag9 C37 C38 107.1(7) . . . . ?
Ag7 Ag9 C37 C38 -160.8(7) . . . . ?
Ag8 Ag9 C37 C38 -165.7(9) . . . . ?
O5 Ag9 C37 Ag8 -157.2(3) . . . . ?
N2 Ag9 C37 Ag8 102.7(3) . . . . ?
C31 Ag9 C37 Ag8 -46.5(4) . . . . ?
Ag10 Ag9 C37 Ag8 -87.2(2) . . . . ?
Ag7 Ag9 C37 Ag8 5.0(3) . . . . ?
O5 Ag9 C37 Ag6 -83.8(6) . . . 2_566 ?
N2 Ag9 C37 Ag6 176.1(4) . . . 2_566 ?
C31 Ag9 C37 Ag6 27.0(6) . . . 2_566 ?
Ag10 Ag9 C37 Ag6 -13.8(5) . . . 2_566 ?
Ag7 Ag9 C37 Ag6 78.4(6) . . . 2_566 ?
Ag8 Ag9 C37 Ag6 73.4(5) . . . 2_566 ?
Ag8 C37 C38 C39 85(14) . . . . ?
Ag6 C37 C38 C39 -56(13) 2_566 . . . ?
Ag9 C37 C38 C39 167(13) . . . . ?
C37 C38 C39 C40 -16(14) . . . . ?
C37 C38 C39 C42 -138(13) . . . . ?
C37 C38 C39 C41 102(13) . . . . ?

_diffrn_measured_fraction_theta_max 0.965
_diffrn_reflns_theta_full        60.68
_diffrn_measured_fraction_theta_full 0.965
_refine_diff_density_max         2.121
_refine_diff_density_min         -2.125
_refine_diff_density_rms         0.238
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_8
_database_code_depnum_ccdc_archive 'CCDC 1032353'
_audit_update_record             
;
2014-11-03 deposited with the CCDC.
2014-12-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C80 H88 Ag12 F20 N4 O8'
_chemical_formula_weight         2907.98

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   25.1013(8)
_cell_length_b                   14.2636(5)
_cell_length_c                   27.7281(7)
_cell_angle_alpha                90.00
_cell_angle_beta                 99.447(3)
_cell_angle_gamma                90.00
_cell_volume                     9793.0(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    8526
_cell_measurement_theta_min      2.3076
_cell_measurement_theta_max      30.7260

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.972
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             5616
_exptl_absorpt_coefficient_mu    2.429
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.83822
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Oxford Gemini S Ultra'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            26005
_diffrn_reflns_av_R_equivalents  0.0370
_diffrn_reflns_av_sigmaI/netI    0.0634
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_theta_min         2.31
_diffrn_reflns_theta_max         26.00
_reflns_number_total             9462
_reflns_number_gt                6030
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Oxford Gemini S Ultra'
_computing_cell_refinement       'CrysAlis RED, Oxford Diffraction Ltd.'
_computing_data_reduction        'CrysAlis RED, Oxford Diffraction Ltd.'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0306P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         9462
_refine_ls_number_parameters     559
_refine_ls_number_restraints     120
_refine_ls_R_factor_all          0.0647
_refine_ls_R_factor_gt           0.0357
_refine_ls_wR_factor_ref         0.0820
_refine_ls_wR_factor_gt          0.0770
_refine_ls_goodness_of_fit_ref   1.098
_refine_ls_restrained_S_all      1.119
_refine_ls_shift/su_max          0.039
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.171051(17) 0.23448(3) 0.037261(15) 0.03788(12) Uani 1 1 d . . .
Ag2 Ag 0.281965(16) 0.32717(3) 0.046185(14) 0.03266(12) Uani 1 1 d . . .
Ag3 Ag 0.202308(17) 0.38017(3) -0.038165(15) 0.03830(12) Uani 1 1 d . . .
Ag4 Ag 0.240926(18) 0.19705(3) 0.125419(15) 0.03958(12) Uani 1 1 d . . .
Ag5 Ag 0.354179(19) 0.23132(4) 0.124994(17) 0.04582(14) Uani 1 1 d . . .
Ag6 Ag 0.24991(2) 0.39377(3) 0.136533(16) 0.04543(13) Uani 1 1 d . . .
C11 C 0.2100(2) 0.3958(4) 0.05152(18) 0.0330(13) Uani 1 1 d . . .
C12 C 0.1747(2) 0.4475(4) 0.0599(2) 0.0385(14) Uani 1 1 d . . .
C13 C 0.1316(3) 0.5128(6) 0.0675(3) 0.068(2) Uani 1 1 d U . .
C14 C 0.1392(6) 0.6012(11) 0.0494(6) 0.194(6) Uani 1 1 d U . .
H14A H 0.1708 0.6305 0.0691 0.291 Uiso 1 1 calc R . .
H14B H 0.1071 0.6397 0.0508 0.291 Uiso 1 1 calc R . .
H14C H 0.1450 0.5962 0.0154 0.291 Uiso 1 1 calc R . .
C15 C 0.1127(5) 0.5003(10) 0.1135(4) 0.188(7) Uani 1 1 d U . .
H15A H 0.1410 0.5194 0.1403 0.282 Uiso 1 1 calc R . .
H15B H 0.1038 0.4341 0.1175 0.282 Uiso 1 1 calc R . .
H15C H 0.0804 0.5387 0.1139 0.282 Uiso 1 1 calc R . .
C16 C 0.0781(4) 0.4806(8) 0.0304(4) 0.139(4) Uani 1 1 d U . .
H16A H 0.0666 0.4186 0.0400 0.208 Uiso 1 1 calc R . .
H16B H 0.0861 0.4777 -0.0030 0.208 Uiso 1 1 calc R . .
H16C H 0.0490 0.5260 0.0317 0.208 Uiso 1 1 calc R . .
C21 C 0.3606(2) 0.2786(5) 0.0467(2) 0.0428(16) Uani 1 1 d . . .
C22 C 0.4087(3) 0.2852(4) 0.0515(2) 0.0426(15) Uani 1 1 d . . .
C23 C 0.4677(3) 0.2976(6) 0.0557(3) 0.068(2) Uani 1 1 d U . .
C24 C 0.4922(4) 0.3098(8) 0.1082(4) 0.117(3) Uani 1 1 d U . .
H24A H 0.4872 0.2522 0.1262 0.176 Uiso 1 1 calc R . .
H24B H 0.4745 0.3621 0.1221 0.176 Uiso 1 1 calc R . .
H24C H 0.5308 0.3230 0.1106 0.176 Uiso 1 1 calc R . .
C25 C 0.4923(4) 0.2199(9) 0.0339(6) 0.191(7) Uani 1 1 d U . .
H25A H 0.4869 0.1621 0.0517 0.287 Uiso 1 1 calc R . .
H25B H 0.5310 0.2317 0.0358 0.287 Uiso 1 1 calc R . .
H25C H 0.4754 0.2133 -0.0004 0.287 Uiso 1 1 calc R . .
C26 C 0.4782(4) 0.3862(7) 0.0277(4) 0.111(3) Uani 1 1 d U . .
H26A H 0.4642 0.4408 0.0429 0.166 Uiso 1 1 calc R . .
H26B H 0.4601 0.3809 -0.0063 0.166 Uiso 1 1 calc R . .
H26C H 0.5172 0.3936 0.0285 0.166 Uiso 1 1 calc R . .
C31 C 0.2168(2) 0.0974(4) 0.0696(2) 0.0386(14) Uani 1 1 d . . .
C32 C 0.2085(3) 0.0179(5) 0.0571(2) 0.0471(16) Uani 1 1 d . . .
C33 C 0.1930(4) -0.0794(5) 0.0425(3) 0.075(2) Uani 1 1 d U . .
C34 C 0.1984(6) -0.1035(10) -0.0057(5) 0.191(6) Uani 1 1 d U . .
H34A H 0.1709 -0.0705 -0.0287 0.287 Uiso 1 1 calc R . .
H34B H 0.1936 -0.1713 -0.0102 0.287 Uiso 1 1 calc R . .
H34C H 0.2344 -0.0855 -0.0118 0.287 Uiso 1 1 calc R . .
C35 C 0.2441(6) -0.1442(11) 0.0673(5) 0.199(6) Uani 1 1 d U . .
H35A H 0.2761 -0.1277 0.0531 0.299 Uiso 1 1 calc R . .
H35B H 0.2354 -0.2105 0.0610 0.299 Uiso 1 1 calc R . .
H35C H 0.2513 -0.1331 0.1027 0.299 Uiso 1 1 calc R . .
C36 C 0.1515(5) -0.1132(7) 0.0647(6) 0.177(7) Uani 1 1 d U . .
H36A H 0.1181 -0.0794 0.0522 0.266 Uiso 1 1 calc R . .
H36B H 0.1605 -0.1040 0.1002 0.266 Uiso 1 1 calc R . .
H36C H 0.1464 -0.1802 0.0577 0.266 Uiso 1 1 calc R . .
C41 C 0.2973(3) 0.2667(5) 0.1782(2) 0.0464(16) Uani 1 1 d . . .
C42 C 0.3357(3) 0.2691(4) 0.2114(2) 0.0472(16) Uani 1 1 d . . .
C43 C 0.3767(3) 0.2725(6) 0.2561(2) 0.066(2) Uani 1 1 d U . .
C44 C 0.4187(4) 0.3475(10) 0.2481(3) 0.136(5) Uani 1 1 d U . .
H44A H 0.4009 0.4087 0.2430 0.204 Uiso 1 1 calc R . .
H44B H 0.4347 0.3311 0.2193 0.204 Uiso 1 1 calc R . .
H44C H 0.4470 0.3504 0.2769 0.204 Uiso 1 1 calc R . .
C45 C 0.4043(4) 0.1776(7) 0.2650(3) 0.114(3) Uani 1 1 d U . .
H45A H 0.3778 0.1306 0.2714 0.171 Uiso 1 1 calc R . .
H45B H 0.4332 0.1818 0.2934 0.171 Uiso 1 1 calc R . .
H45C H 0.4197 0.1593 0.2361 0.171 Uiso 1 1 calc R . .
C46 C 0.3512(4) 0.3004(7) 0.2991(3) 0.100(3) Uani 1 1 d U . .
H46A H 0.3252 0.2522 0.3052 0.149 Uiso 1 1 calc R . .
H46B H 0.3325 0.3604 0.2924 0.149 Uiso 1 1 calc R . .
H46C H 0.3792 0.3067 0.3281 0.149 Uiso 1 1 calc R . .
N1 N 0.2266(2) 0.4543(4) 0.20860(19) 0.0476(13) Uani 1 1 d . . .
N2 N 0.3057(2) 0.5242(4) 0.16348(19) 0.0573(15) Uani 1 1 d . . .
C101 C 0.1918(3) 0.4094(5) 0.2322(3) 0.064(2) Uani 1 1 d . . .
H10A H 0.1681 0.3643 0.2151 0.077 Uiso 1 1 calc R . .
C102 C 0.1893(3) 0.4266(6) 0.2807(3) 0.082(3) Uani 1 1 d . . .
H10B H 0.1640 0.3938 0.2965 0.099 Uiso 1 1 calc R . .
C103 C 0.2229(3) 0.4903(6) 0.3059(3) 0.077(2) Uani 1 1 d . . .
H10C H 0.2214 0.5038 0.3391 0.093 Uiso 1 1 calc R . .
C104 C 0.2593(3) 0.5349(5) 0.2818(3) 0.066(2) Uani 1 1 d . . .
H10D H 0.2844 0.5780 0.2990 0.079 Uiso 1 1 calc R . .
C105 C 0.2599(3) 0.5176(5) 0.2328(2) 0.0480(16) Uani 1 1 d . . .
C201 C 0.3425(4) 0.5590(6) 0.1397(3) 0.081(3) Uani 1 1 d . . .
H20A H 0.3479 0.5293 0.1102 0.097 Uiso 1 1 calc R . .
C202 C 0.3741(4) 0.6371(6) 0.1554(3) 0.089(3) Uani 1 1 d . . .
H20B H 0.3993 0.6618 0.1366 0.107 Uiso 1 1 calc R . .
C203 C 0.3675(4) 0.6766(6) 0.1986(3) 0.082(3) Uani 1 1 d . . .
H20C H 0.3889 0.7288 0.2110 0.098 Uiso 1 1 calc R . .
C204 C 0.3297(3) 0.6410(5) 0.2243(3) 0.074(2) Uani 1 1 d . . .
H20D H 0.3247 0.6688 0.2543 0.089 Uiso 1 1 calc R . .
C205 C 0.2985(3) 0.5625(4) 0.2056(2) 0.0485(16) Uani 1 1 d . . .
O1 O 0.15332(17) 0.2181(3) 0.15518(15) 0.0523(12) Uani 1 1 d . . .
O2 O 0.10061(16) 0.2258(3) 0.08117(15) 0.0509(11) Uani 1 1 d . . .
C1 C 0.1103(3) 0.2136(4) 0.1259(3) 0.0447(16) Uani 1 1 d . . .
C2 C 0.0607(3) 0.1815(7) 0.1480(3) 0.072(2) Uani 1 1 d . . .
C3 C 0.0544(5) 0.0791(9) 0.1494(5) 0.114(4) Uani 1 1 d . . .
F1 F 0.06289(17) 0.2127(3) 0.19412(15) 0.0826(14) Uani 1 1 d . . .
F2 F 0.01272(17) 0.2153(4) 0.12130(18) 0.0927(15) Uani 1 1 d . . .
F3 F 0.0975(3) 0.0427(4) 0.1761(3) 0.134(2) Uani 1 1 d . . .
F4 F 0.0474(3) 0.0449(5) 0.1037(3) 0.156(3) Uani 1 1 d . . .
F5 F 0.0100(3) 0.0556(5) 0.1681(3) 0.166(3) Uani 1 1 d . . .
O3 O 0.14020(19) 0.4846(3) -0.07841(19) 0.0688(14) Uani 1 1 d . . .
O4 O 0.0928(2) 0.3993(4) -0.13827(18) 0.0749(16) Uani 1 1 d . . .
C4 C 0.1044(3) 0.4704(5) -0.1134(2) 0.0472(17) Uani 1 1 d . . .
C5 C 0.0666(3) 0.5540(5) -0.1273(3) 0.0553(18) Uani 1 1 d . . .
C6 C 0.0298(4) 0.5494(8) -0.1763(3) 0.087(3) Uani 1 1 d . . .
F6 F 0.03581(17) 0.5690(3) -0.09310(16) 0.0872(14) Uani 1 1 d . . .
F7 F 0.0953(2) 0.6332(3) -0.12969(18) 0.0929(15) Uani 1 1 d . . .
F8 F -0.0038(2) 0.4806(5) -0.1791(2) 0.130(2) Uani 1 1 d . . .
F9 F 0.0016(3) 0.6265(4) -0.1853(2) 0.161(3) Uani 1 1 d . . .
F10 F 0.0591(2) 0.5378(4) -0.21206(18) 0.1136(19) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O2 2.309(4) . ?
Ag1 C21 2.342(6) 7 ?
Ag1 C31 2.368(6) . ?
Ag1 C11 2.506(6) . ?
Ag1 Ag4 2.8159(6) . ?
Ag1 Ag2 2.9006(6) 7 ?
Ag1 Ag2 3.0551(6) . ?
Ag1 Ag3 3.1379(6) . ?
Ag2 C11 2.080(6) . ?
Ag2 C21 2.091(6) . ?
Ag2 Ag1 2.9006(6) 7 ?
Ag2 Ag6 2.9134(6) . ?
Ag2 Ag3 2.9163(6) . ?
Ag2 Ag5 2.9377(6) . ?
Ag2 Ag3 2.9967(6) 7 ?
Ag2 Ag4 3.1742(6) . ?
Ag3 O3 2.307(4) . ?
Ag3 C31 2.361(6) 7 ?
Ag3 C11 2.472(5) . ?
Ag3 Ag2 2.9966(6) 7 ?
Ag3 Ag5 3.0357(6) 7 ?
Ag3 Ag4 3.1982(6) 7 ?
Ag4 C41 2.110(6) . ?
Ag4 C31 2.115(6) . ?
Ag4 O1 2.491(4) . ?
Ag4 Ag6 2.8277(7) . ?
Ag4 Ag5 2.8864(7) . ?
Ag4 Ag3 3.1982(6) 7 ?
Ag5 C41 2.270(6) . ?
Ag5 O4 2.284(5) 7 ?
Ag5 C21 2.303(6) . ?
Ag5 C42 2.570(6) . ?
Ag5 Ag3 3.0356(6) 7 ?
Ag6 N1 2.338(5) . ?
Ag6 C41 2.362(6) . ?
Ag6 N2 2.374(5) . ?
Ag6 C11 2.405(5) . ?
C11 C12 1.206(7) . ?
C12 C13 1.468(9) . ?
C13 C14 1.381(15) . ?
C13 C15 1.445(13) . ?
C13 C16 1.620(13) . ?
C21 C22 1.196(8) . ?
C21 Ag1 2.342(6) 7 ?
C22 C23 1.477(9) . ?
C23 C25 1.447(13) . ?
C23 C24 1.494(12) . ?
C23 C26 1.529(11) . ?
C31 C32 1.195(8) . ?
C31 Ag3 2.361(6) 7 ?
C32 C33 1.479(9) . ?
C33 C34 1.408(14) . ?
C33 C36 1.382(11) . ?
C33 C35 1.637(16) . ?
C41 C42 1.219(8) . ?
C42 C43 1.477(9) . ?
C43 C46 1.498(10) . ?
C43 C45 1.522(11) . ?
C43 C44 1.543(13) . ?
N1 C105 1.334(7) . ?
N1 C101 1.337(8) . ?
N2 C201 1.318(9) . ?
N2 C205 1.328(7) . ?
C101 C102 1.379(9) . ?
C102 C103 1.353(10) . ?
C103 C104 1.373(10) . ?
C104 C105 1.384(9) . ?
C105 C205 1.468(9) . ?
C201 C202 1.396(10) . ?
C202 C203 1.357(11) . ?
C203 C204 1.373(10) . ?
C204 C205 1.417(9) . ?
O1 C1 1.241(7) . ?
O2 C1 1.235(7) . ?
C1 C2 1.545(9) . ?
C2 F1 1.347(8) . ?
C2 F2 1.393(8) . ?
C2 C3 1.470(14) . ?
C3 F4 1.342(13) . ?
C3 F3 1.314(12) . ?
C3 F5 1.347(11) . ?
O3 C4 1.227(7) . ?
O4 C4 1.234(8) . ?
O4 Ag5 2.284(5) 7 ?
C4 C5 1.533(9) . ?
C5 F7 1.348(8) . ?
C5 F6 1.335(8) . ?
C5 C6 1.515(11) . ?
C6 F8 1.288(12) . ?
C6 F9 1.308(9) . ?
C6 F10 1.339(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Ag1 C21 110.83(18) . 7 ?
O2 Ag1 C31 96.95(18) . . ?
C21 Ag1 C31 112.1(2) 7 . ?
O2 Ag1 C11 106.22(17) . . ?
C21 Ag1 C11 106.9(2) 7 . ?
C31 Ag1 C11 123.1(2) . . ?
O2 Ag1 Ag4 87.36(11) . . ?
C21 Ag1 Ag4 155.47(15) 7 . ?
C31 Ag1 Ag4 47.18(15) . . ?
C11 Ag1 Ag4 82.28(12) . . ?
O2 Ag1 Ag2 148.33(11) . 7 ?
C21 Ag1 Ag2 45.47(14) 7 7 ?
C31 Ag1 Ag2 79.45(14) . 7 ?
C11 Ag1 Ag2 101.82(12) . 7 ?
Ag4 Ag1 Ag2 110.986(19) . 7 ?
O2 Ag1 Ag2 138.35(11) . . ?
C21 Ag1 Ag2 105.75(15) 7 . ?
C31 Ag1 Ag2 87.03(14) . . ?
C11 Ag1 Ag2 42.52(13) . . ?
Ag4 Ag1 Ag2 65.307(15) . . ?
Ag2 Ag1 Ag2 73.225(16) 7 . ?
O2 Ag1 Ag3 133.16(11) . . ?
C21 Ag1 Ag3 58.08(16) 7 . ?
C31 Ag1 Ag3 129.86(14) . . ?
C11 Ag1 Ag3 50.45(11) . . ?
Ag4 Ag1 Ag3 121.057(19) . . ?
Ag2 Ag1 Ag3 59.350(15) 7 . ?
Ag2 Ag1 Ag3 56.166(14) . . ?
C11 Ag2 C21 170.2(2) . . ?
C11 Ag2 Ag1 132.11(14) . 7 ?
C21 Ag2 Ag1 53.00(15) . 7 ?
C11 Ag2 Ag6 54.55(14) . . ?
C21 Ag2 Ag6 119.71(15) . . ?
Ag1 Ag2 Ag6 172.15(2) 7 . ?
C11 Ag2 Ag3 56.37(14) . . ?
C21 Ag2 Ag3 127.91(15) . . ?
Ag1 Ag2 Ag3 75.751(16) 7 . ?
Ag6 Ag2 Ag3 110.813(18) . . ?
C11 Ag2 Ag5 127.08(14) . . ?
C21 Ag2 Ag5 51.20(15) . . ?
Ag1 Ag2 Ag5 99.802(17) 7 . ?
Ag6 Ag2 Ag5 74.687(16) . . ?
Ag3 Ag2 Ag5 167.26(2) . . ?
C11 Ag2 Ag3 126.58(16) . 7 ?
C21 Ag2 Ag3 62.47(19) . 7 ?
Ag1 Ag2 Ag3 64.271(15) 7 7 ?
Ag6 Ag2 Ag3 116.355(19) . 7 ?
Ag3 Ag2 Ag3 106.122(16) . 7 ?
Ag5 Ag2 Ag3 61.522(15) . 7 ?
C11 Ag2 Ag1 54.49(15) . . ?
C21 Ag2 Ag1 134.79(19) . . ?
Ag1 Ag2 Ag1 106.777(16) 7 . ?
Ag6 Ag2 Ag1 80.450(16) . . ?
Ag3 Ag2 Ag1 63.352(15) . . ?
Ag5 Ag2 Ag1 107.560(19) . . ?
Ag3 Ag2 Ag1 72.323(16) 7 . ?
C11 Ag2 Ag4 80.89(15) . . ?
C21 Ag2 Ag4 102.39(17) . . ?
Ag1 Ag2 Ag4 126.549(19) 7 . ?
Ag6 Ag2 Ag4 55.156(15) . . ?
Ag3 Ag2 Ag4 116.680(18) . . ?
Ag5 Ag2 Ag4 56.203(15) . . ?
Ag3 Ag2 Ag4 62.354(15) 7 . ?
Ag1 Ag2 Ag4 53.708(13) . . ?
O3 Ag3 C31 106.73(19) . 7 ?
O3 Ag3 C11 111.33(19) . . ?
C31 Ag3 C11 115.44(19) 7 . ?
O3 Ag3 Ag2 151.07(13) . . ?
C31 Ag3 Ag2 79.24(14) 7 . ?
C11 Ag3 Ag2 44.47(13) . . ?
O3 Ag3 Ag2 133.46(12) . 7 ?
C31 Ag3 Ag2 88.54(15) 7 7 ?
C11 Ag3 Ag2 100.01(14) . 7 ?
Ag2 Ag3 Ag2 73.881(16) . 7 ?
O3 Ag3 Ag5 76.34(13) . 7 ?
C31 Ag3 Ag5 95.51(15) 7 7 ?
C11 Ag3 Ag5 142.57(13) . 7 ?
Ag2 Ag3 Ag5 132.05(2) . 7 ?
Ag2 Ag3 Ag5 58.280(14) 7 7 ?
O3 Ag3 Ag1 121.79(13) . . ?
C31 Ag3 Ag1 131.35(14) 7 . ?
C11 Ag3 Ag1 51.40(13) . . ?
Ag2 Ag3 Ag1 60.482(14) . . ?
Ag2 Ag3 Ag1 56.379(14) 7 . ?
Ag5 Ag3 Ag1 92.659(18) 7 . ?
O3 Ag3 Ag4 101.89(13) . 7 ?
C31 Ag3 Ag4 41.39(15) 7 7 ?
C11 Ag3 Ag4 145.16(13) . 7 ?
Ag2 Ag3 Ag4 100.688(17) . 7 ?
Ag2 Ag3 Ag4 61.544(14) 7 7 ?
Ag5 Ag3 Ag4 55.090(14) 7 7 ?
Ag1 Ag3 Ag4 117.860(19) . 7 ?
C41 Ag4 C31 154.5(2) . . ?
C41 Ag4 O1 104.0(2) . . ?
C31 Ag4 O1 99.23(19) . . ?
C41 Ag4 Ag1 139.80(17) . . ?
C31 Ag4 Ag1 55.22(16) . . ?
O1 Ag4 Ag1 78.86(10) . . ?
C41 Ag4 Ag6 54.87(17) . . ?
C31 Ag4 Ag6 139.01(16) . . ?
O1 Ag4 Ag6 84.45(11) . . ?
Ag1 Ag4 Ag6 86.194(18) . . ?
C41 Ag4 Ag5 51.22(17) . . ?
C31 Ag4 Ag5 105.98(16) . . ?
O1 Ag4 Ag5 154.79(10) . . ?
Ag1 Ag4 Ag5 115.97(2) . . ?
Ag6 Ag4 Ag5 76.790(18) . . ?
C41 Ag4 Ag2 86.97(17) . . ?
C31 Ag4 Ag2 88.48(16) . . ?
O1 Ag4 Ag2 124.30(10) . . ?
Ag1 Ag4 Ag2 60.985(14) . . ?
Ag6 Ag4 Ag2 57.733(15) . . ?
Ag5 Ag4 Ag2 57.754(14) . . ?
C41 Ag4 Ag3 110.79(17) . 7 ?
C31 Ag4 Ag3 47.56(16) . 7 ?
O1 Ag4 Ag3 145.02(10) . 7 ?
Ag1 Ag4 Ag3 72.542(15) . 7 ?
Ag6 Ag4 Ag3 112.753(19) . 7 ?
Ag5 Ag4 Ag3 59.592(15) . 7 ?
Ag2 Ag4 Ag3 56.102(14) . 7 ?
C41 Ag5 O4 119.2(2) . 7 ?
C41 Ag5 C21 134.1(2) . . ?
O4 Ag5 C21 105.2(2) 7 . ?
C41 Ag5 C42 28.31(19) . . ?
O4 Ag5 C42 102.15(19) 7 . ?
C21 Ag5 C42 150.2(2) . . ?
C41 Ag5 Ag4 46.42(16) . . ?
O4 Ag5 Ag4 114.16(15) 7 . ?
C21 Ag5 Ag4 105.97(15) . . ?
C42 Ag5 Ag4 72.74(14) . . ?
C41 Ag5 Ag2 90.14(15) . . ?
O4 Ag5 Ag2 140.50(13) 7 . ?
C21 Ag5 Ag2 45.03(14) . . ?
C42 Ag5 Ag2 114.32(13) . . ?
Ag4 Ag5 Ag2 66.043(15) . . ?
C41 Ag5 Ag3 111.71(16) . 7 ?
O4 Ag5 Ag3 83.36(13) 7 7 ?
C21 Ag5 Ag3 60.15(16) . 7 ?
C42 Ag5 Ag3 135.78(15) . 7 ?
Ag4 Ag5 Ag3 65.317(16) . 7 ?
Ag2 Ag5 Ag3 60.197(15) . 7 ?
N1 Ag6 C41 92.44(19) . . ?
N1 Ag6 N2 70.08(19) . . ?
C41 Ag6 N2 102.9(2) . . ?
N1 Ag6 C11 135.31(19) . . ?
C41 Ag6 C11 125.7(2) . . ?
N2 Ag6 C11 115.36(19) . . ?
N1 Ag6 Ag4 115.65(13) . . ?
C41 Ag6 Ag4 46.92(15) . . ?
N2 Ag6 Ag4 147.58(15) . . ?
C11 Ag6 Ag4 83.80(14) . . ?
N1 Ag6 Ag2 177.08(14) . . ?
C41 Ag6 Ag2 88.96(14) . . ?
N2 Ag6 Ag2 107.11(13) . . ?
C11 Ag6 Ag2 44.79(14) . . ?
Ag4 Ag6 Ag2 67.111(16) . . ?
C12 C11 Ag2 167.5(5) . . ?
C12 C11 Ag6 91.1(4) . . ?
Ag2 C11 Ag6 80.66(18) . . ?
C12 C11 Ag3 108.1(4) . . ?
Ag2 C11 Ag3 79.16(17) . . ?
Ag6 C11 Ag3 159.4(3) . . ?
C12 C11 Ag1 108.2(4) . . ?
Ag2 C11 Ag1 83.0(2) . . ?
Ag6 C11 Ag1 103.5(2) . . ?
Ag3 C11 Ag1 78.15(15) . . ?
C11 C12 C13 176.8(7) . . ?
C14 C13 C12 112.3(8) . . ?
C14 C13 C15 121.2(10) . . ?
C12 C13 C15 113.8(7) . . ?
C14 C13 C16 100.2(9) . . ?
C12 C13 C16 106.5(7) . . ?
C15 C13 C16 99.6(8) . . ?
C22 C21 Ag2 155.5(6) . . ?
C22 C21 Ag5 98.3(4) . . ?
Ag2 C21 Ag5 83.8(2) . . ?
C22 C21 Ag1 106.8(4) . 7 ?
Ag2 C21 Ag1 81.53(19) . 7 ?
Ag5 C21 Ag1 148.1(3) . 7 ?
C21 C22 C23 177.0(7) . . ?
C25 C23 C22 111.4(7) . . ?
C25 C23 C24 111.1(8) . . ?
C22 C23 C24 109.6(7) . . ?
C25 C23 C26 107.5(9) . . ?
C22 C23 C26 108.3(6) . . ?
C24 C23 C26 108.7(8) . . ?
C32 C31 Ag4 150.1(5) . . ?
C32 C31 Ag3 98.1(5) . 7 ?
Ag4 C31 Ag3 91.1(2) . 7 ?
C32 C31 Ag1 128.5(5) . . ?
Ag4 C31 Ag1 77.6(2) . . ?
Ag3 C31 Ag1 98.1(2) 7 . ?
C31 C32 C33 174.7(7) . . ?
C34 C33 C36 122.4(10) . . ?
C34 C33 C32 115.3(8) . . ?
C36 C33 C32 112.9(7) . . ?
C34 C33 C35 94.1(9) . . ?
C36 C33 C35 102.2(10) . . ?
C32 C33 C35 105.2(8) . . ?
C42 C41 Ag4 153.4(6) . . ?
C42 C41 Ag5 89.6(5) . . ?
Ag4 C41 Ag5 82.4(2) . . ?
C42 C41 Ag6 128.3(5) . . ?
Ag4 C41 Ag6 78.22(19) . . ?
Ag5 C41 Ag6 100.0(2) . . ?
C41 C42 C43 172.2(7) . . ?
C41 C42 Ag5 62.1(4) . . ?
C43 C42 Ag5 125.6(5) . . ?
C42 C43 C46 110.3(6) . . ?
C42 C43 C45 110.1(6) . . ?
C46 C43 C45 110.4(7) . . ?
C42 C43 C44 107.4(7) . . ?
C46 C43 C44 108.8(7) . . ?
C45 C43 C44 109.7(8) . . ?
C105 N1 C101 118.9(6) . . ?
C105 N1 Ag6 117.0(4) . . ?
C101 N1 Ag6 121.2(4) . . ?
C201 N2 C205 119.6(6) . . ?
C201 N2 Ag6 124.3(5) . . ?
C205 N2 Ag6 116.1(4) . . ?
N1 C101 C102 122.1(7) . . ?
C103 C102 C101 119.8(7) . . ?
C102 C103 C104 118.0(7) . . ?
C103 C104 C105 120.6(7) . . ?
N1 C105 C104 120.5(6) . . ?
N1 C105 C205 116.7(6) . . ?
C104 C105 C205 122.7(6) . . ?
N2 C201 C202 123.6(7) . . ?
C203 C202 C201 117.5(7) . . ?
C202 C203 C204 120.0(7) . . ?
C203 C204 C205 119.4(7) . . ?
N2 C205 C204 120.0(6) . . ?
N2 C205 C105 117.9(5) . . ?
C204 C205 C105 122.0(6) . . ?
C1 O1 Ag4 119.8(4) . . ?
C1 O2 Ag1 119.6(4) . . ?
O1 C1 O2 131.1(6) . . ?
O1 C1 C2 115.2(6) . . ?
O2 C1 C2 113.6(6) . . ?
F1 C2 F2 106.6(6) . . ?
F1 C2 C3 106.9(8) . . ?
F2 C2 C3 105.6(8) . . ?
F1 C2 C1 111.7(6) . . ?
F2 C2 C1 111.7(7) . . ?
C3 C2 C1 113.8(7) . . ?
F4 C3 F3 110.8(11) . . ?
F4 C3 F5 106.5(10) . . ?
F3 C3 F5 110.0(10) . . ?
F4 C3 C2 109.6(9) . . ?
F3 C3 C2 109.0(10) . . ?
F5 C3 C2 111.0(10) . . ?
C4 O3 Ag3 128.7(5) . . ?
C4 O4 Ag5 120.2(4) . 7 ?
O3 C4 O4 130.7(6) . . ?
O3 C4 C5 114.4(7) . . ?
O4 C4 C5 114.9(6) . . ?
F7 C5 F6 106.1(6) . . ?
F7 C5 C6 104.1(7) . . ?
F6 C5 C6 107.7(7) . . ?
F7 C5 C4 110.5(6) . . ?
F6 C5 C4 110.7(6) . . ?
C6 C5 C4 116.9(7) . . ?
F8 C6 F9 107.5(9) . . ?
F8 C6 F10 107.1(9) . . ?
F9 C6 F10 108.0(8) . . ?
F8 C6 C5 112.6(8) . . ?
F9 C6 C5 111.5(8) . . ?
F10 C6 C5 110.0(8) . . ?

_diffrn_measured_fraction_theta_max 0.983
_diffrn_reflns_theta_full        26.00
_diffrn_measured_fraction_theta_full 0.983
_refine_diff_density_max         1.421
_refine_diff_density_min         -0.660
_refine_diff_density_rms         0.111
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_9
_database_code_depnum_ccdc_archive 'CCDC 1032354'
_audit_update_record             
;
2014-11-03 deposited with the CCDC.
2014-12-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C100 H98 Ag12 F18 N8 O14'
_chemical_formula_weight         3272.30

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P2(1)/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   16.7828(3)
_cell_length_b                   26.6720(5)
_cell_length_c                   25.7056(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 108.236(2)
_cell_angle_gamma                90.00
_cell_volume                     10928.7(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    15850
_cell_measurement_theta_min      3.9850
_cell_measurement_theta_max      62.2930

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.989
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             6368
_exptl_absorpt_coefficient_mu    17.644
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.66162
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET)
(compiled Dec  3 2012,18:21:49)
;
_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'Enhance Ultra (Cu) X-ray Source'
_diffrn_radiation_monochromator  mirror
_diffrn_measurement_device_type  'Xcalibur, Sapphire3, Gemini ultra'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean 16.1903
_diffrn_standards_number         37541
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            36080
_diffrn_reflns_av_R_equivalents  0.0834
_diffrn_reflns_av_sigmaI/netI    0.0867
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         3.23
_diffrn_reflns_theta_max         62.20
_reflns_number_total             16726
_reflns_number_gt                13689
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1585P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         16726
_refine_ls_number_parameters     1349
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0908
_refine_ls_R_factor_gt           0.0802
_refine_ls_wR_factor_ref         0.2276
_refine_ls_wR_factor_gt          0.2066
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_restrained_S_all      1.020
_refine_ls_shift/su_max          0.085
_refine_ls_shift/su_mean         0.012

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.28141(4) 0.68931(2) 0.21021(2) 0.02384(18) Uani 1 1 d . . .
Ag2 Ag 0.30936(4) 0.58488(2) 0.20245(2) 0.02389(18) Uani 1 1 d . . .
Ag3 Ag 0.20906(4) 0.55468(2) 0.29129(2) 0.02628(18) Uani 1 1 d . . .
Ag4 Ag 0.18104(4) 0.66068(2) 0.29725(2) 0.02386(18) Uani 1 1 d . . .
Ag5 Ag 0.22309(4) 0.76210(2) 0.26832(2) 0.02857(18) Uani 1 1 d . . .
Ag6 Ag 0.26997(4) 0.48509(2) 0.23120(2) 0.02927(19) Uani 1 1 d . . .
Ag7 Ag 0.45907(4) 0.68672(2) 0.26795(3) 0.02954(19) Uani 1 1 d . . .
Ag8 Ag 0.37104(4) 0.66004(3) 0.13115(3) 0.0376(2) Uani 1 1 d . . .
Ag9 Ag 0.12089(4) 0.58868(3) 0.37168(3) 0.0392(2) Uani 1 1 d . . .
Ag10 Ag 0.35701(4) 0.62677(2) 0.31371(2) 0.02470(18) Uani 1 1 d . . .
Ag11 Ag 0.13388(4) 0.61828(2) 0.18470(2) 0.02665(18) Uani 1 1 d . . .
Ag12 Ag 0.03298(4) 0.56193(2) 0.23689(2) 0.02871(18) Uani 1 1 d . . .
C1 C 0.4472(8) 0.7706(4) 0.1341(7) 0.073(4) Uani 1 1 d . . .
H1A H 0.4098 0.7779 0.1532 0.087 Uiso 1 1 calc R . .
C2 C 0.4969(10) 0.8082(6) 0.1251(9) 0.097(7) Uani 1 1 d . . .
H2A H 0.4912 0.8406 0.1368 0.117 Uiso 1 1 calc R . .
C3 C 0.5539(12) 0.7987(6) 0.0994(8) 0.106(8) Uani 1 1 d . . .
H3A H 0.5868 0.8245 0.0927 0.127 Uiso 1 1 calc R . .
C4 C 0.5629(7) 0.7496(7) 0.0828(6) 0.080(6) Uani 1 1 d . . .
C5 C 0.6227(12) 0.7386(7) 0.0578(7) 0.088(5) Uiso 1 1 d U . .
H5A H 0.6580 0.7637 0.0527 0.106 Uiso 1 1 calc R . .
C6 C 0.6294(9) 0.6947(5) 0.0420(6) 0.065(3) Uiso 1 1 d U . .
H6A H 0.6699 0.6884 0.0251 0.078 Uiso 1 1 calc R . .
C7 C 0.5733(7) 0.6501(9) 0.0493(5) 0.082(6) Uani 1 1 d . . .
C8 C 0.5783(11) 0.5988(11) 0.0332(6) 0.113(9) Uani 1 1 d . . .
H8A H 0.6184 0.5887 0.0173 0.136 Uiso 1 1 calc R . .
C9 C 0.5217(12) 0.5652(9) 0.0422(6) 0.104(8) Uani 1 1 d . . .
H9A H 0.5235 0.5320 0.0317 0.125 Uiso 1 1 calc R . .
C10 C 0.4615(11) 0.5798(6) 0.0668(5) 0.071(4) Uani 1 1 d . . .
H10A H 0.4239 0.5564 0.0725 0.085 Uiso 1 1 calc R . .
C11 C 0.5114(6) 0.6616(5) 0.0734(4) 0.048(3) Uani 1 1 d . . .
C12 C 0.5083(7) 0.7130(5) 0.0913(5) 0.055(3) Uani 1 1 d . . .
C13 C 0.5619(8) 0.7948(4) 0.2730(5) 0.053(3) Uani 1 1 d . . .
H13A H 0.5232 0.8073 0.2888 0.063 Uiso 1 1 calc R . .
C14 C 0.6239(9) 0.8273(4) 0.2676(5) 0.059(3) Uani 1 1 d . . .
H14A H 0.6257 0.8604 0.2792 0.070 Uiso 1 1 calc R . .
C15 C 0.6814(8) 0.8096(5) 0.2452(5) 0.056(3) Uani 1 1 d . . .
H15A H 0.7224 0.8308 0.2403 0.067 Uiso 1 1 calc R . .
C16 C 0.6791(6) 0.7586(4) 0.2291(4) 0.038(2) Uani 1 1 d . . .
C17 C 0.7369(7) 0.7378(5) 0.2065(5) 0.055(3) Uani 1 1 d . . .
H17A H 0.7795 0.7576 0.2014 0.066 Uiso 1 1 calc R . .
C18 C 0.7316(6) 0.6892(5) 0.1919(4) 0.044(3) Uani 1 1 d . . .
H18A H 0.7713 0.6761 0.1773 0.052 Uiso 1 1 calc R . .
C19 C 0.6667(6) 0.6564(4) 0.1981(3) 0.033(2) Uani 1 1 d . . .
C20 C 0.6638(7) 0.6048(5) 0.1858(4) 0.050(3) Uani 1 1 d . . .
H20A H 0.7038 0.5901 0.1725 0.060 Uiso 1 1 calc R . .
C21 C 0.6009(7) 0.5774(4) 0.1940(4) 0.041(2) Uani 1 1 d . . .
H21A H 0.5962 0.5435 0.1849 0.049 Uiso 1 1 calc R . .
C22 C 0.5430(6) 0.5996(4) 0.2158(4) 0.037(2) Uani 1 1 d . . .
H22A H 0.5008 0.5798 0.2214 0.044 Uiso 1 1 calc R . .
C23 C 0.6075(5) 0.6760(4) 0.2209(3) 0.0281(18) Uani 1 1 d . . .
C24 C 0.6137(6) 0.7295(4) 0.2371(4) 0.035(2) Uani 1 1 d . . .
C25 C 0.0497(8) 0.6763(4) 0.4385(4) 0.044(2) Uani 1 1 d . . .
H25A H 0.0903 0.6965 0.4315 0.052 Uiso 1 1 calc R . .
C26 C -0.0060(9) 0.6976(4) 0.4636(4) 0.051(3) Uani 1 1 d . . .
H26A H -0.0028 0.7315 0.4724 0.062 Uiso 1 1 calc R . .
C27 C -0.0651(8) 0.6674(4) 0.4748(4) 0.047(3) Uani 1 1 d . . .
H27A H -0.1029 0.6808 0.4909 0.056 Uiso 1 1 calc R . .
C28 C -0.0679(6) 0.6163(4) 0.4618(3) 0.037(2) Uani 1 1 d . . .
C29 C -0.1245(7) 0.5808(7) 0.4754(4) 0.062(4) Uani 1 1 d . . .
H29A H -0.1598 0.5919 0.4946 0.075 Uiso 1 1 calc R . .
C30 C -0.1265(7) 0.5347(6) 0.4613(4) 0.053(3) Uani 1 1 d . . .
H30A H -0.1663 0.5139 0.4684 0.064 Uiso 1 1 calc R . .
C31 C -0.0702(7) 0.5135(4) 0.4350(4) 0.038(2) Uani 1 1 d . . .
C32 C -0.0669(7) 0.4628(4) 0.4216(4) 0.046(2) Uani 1 1 d . . .
H32A H -0.1020 0.4400 0.4309 0.055 Uiso 1 1 calc R . .
C33 C -0.0130(7) 0.4466(4) 0.3950(4) 0.047(3) Uani 1 1 d . . .
H33A H -0.0116 0.4131 0.3852 0.056 Uiso 1 1 calc R . .
C34 C 0.0391(7) 0.4813(4) 0.3832(4) 0.040(2) Uani 1 1 d . . .
H34A H 0.0748 0.4700 0.3645 0.048 Uiso 1 1 calc R . .
C35 C -0.0105(5) 0.5464(3) 0.4224(3) 0.0252(17) Uani 1 1 d . . .
C36 C -0.0101(5) 0.5986(4) 0.4367(3) 0.0265(18) Uani 1 1 d . . .
C37 C -0.0463(6) 0.6507(4) 0.2910(4) 0.0320(19) Uani 1 1 d . . .
H37A H -0.0050 0.6701 0.2837 0.038 Uiso 1 1 calc R . .
C38 C -0.1041(7) 0.6740(4) 0.3131(4) 0.040(2) Uani 1 1 d . . .
H38A H -0.1003 0.7082 0.3204 0.048 Uiso 1 1 calc R . .
C39 C -0.1652(6) 0.6464(4) 0.3236(4) 0.037(2) Uani 1 1 d . . .
H39A H -0.2028 0.6613 0.3388 0.044 Uiso 1 1 calc R . .
C40 C -0.1708(5) 0.5948(4) 0.3111(3) 0.0294(19) Uani 1 1 d . . .
C41 C -0.2348(6) 0.5636(5) 0.3198(4) 0.043(3) Uani 1 1 d . . .
H41A H -0.2738 0.5772 0.3348 0.052 Uiso 1 1 calc R . .
C42 C -0.2389(6) 0.5138(5) 0.3060(4) 0.043(3) Uani 1 1 d . . .
H42A H -0.2813 0.4943 0.3119 0.051 Uiso 1 1 calc R . .
C43 C -0.1821(6) 0.4910(4) 0.2836(3) 0.037(2) Uani 1 1 d . . .
C44 C -0.1852(8) 0.4412(4) 0.2679(4) 0.053(3) Uani 1 1 d . . .
H44A H -0.2271 0.4207 0.2726 0.063 Uiso 1 1 calc R . .
C45 C -0.1289(9) 0.4218(4) 0.2460(5) 0.054(3) Uani 1 1 d . . .
H45A H -0.1315 0.3884 0.2352 0.065 Uiso 1 1 calc R . .
C46 C -0.0665(7) 0.4539(4) 0.2401(4) 0.042(2) Uani 1 1 d . . .
H46A H -0.0271 0.4405 0.2254 0.051 Uiso 1 1 calc R . .
C47 C -0.1171(6) 0.5214(4) 0.2743(3) 0.0302(19) Uani 1 1 d . . .
C48 C -0.1112(5) 0.5743(3) 0.2892(3) 0.0241(17) Uani 1 1 d . . .
C49 C 0.2451(5) 0.6134(3) 0.3630(3) 0.0182(15) Uani 1 1 d . . .
C50 C 0.2798(6) 0.5967(3) 0.4081(4) 0.0298(19) Uani 1 1 d . . .
C51 C 0.3300(6) 0.5786(5) 0.4636(3) 0.045(3) Uani 1 1 d . . .
C52 C 0.3782(9) 0.6229(6) 0.4957(5) 0.068(4) Uani 1 1 d . . .
H52A H 0.4166 0.6355 0.4779 0.102 Uiso 1 1 calc R . .
H52B H 0.4089 0.6124 0.5322 0.102 Uiso 1 1 calc R . .
H52C H 0.3395 0.6490 0.4973 0.102 Uiso 1 1 calc R . .
C53 C 0.2666(9) 0.5564(7) 0.4911(5) 0.084(6) Uani 1 1 d . . .
H53A H 0.2296 0.5824 0.4953 0.125 Uiso 1 1 calc R . .
H53B H 0.2970 0.5430 0.5264 0.125 Uiso 1 1 calc R . .
H53C H 0.2345 0.5302 0.4685 0.125 Uiso 1 1 calc R . .
C54 C 0.3896(8) 0.5358(5) 0.4567(5) 0.059(3) Uani 1 1 d . . .
H54A H 0.4286 0.5491 0.4398 0.088 Uiso 1 1 calc R . .
H54B H 0.3571 0.5098 0.4341 0.088 Uiso 1 1 calc R . .
H54C H 0.4198 0.5224 0.4920 0.088 Uiso 1 1 calc R . .
C55 C 0.3713(6) 0.5488(3) 0.2790(4) 0.0298(19) Uani 1 1 d . . .
C56 C 0.4245(6) 0.5174(3) 0.3008(3) 0.0263(18) Uani 1 1 d . . .
C57 C 0.4937(6) 0.4836(4) 0.3274(4) 0.039(2) Uani 1 1 d . . .
C58 C 0.4655(8) 0.4456(4) 0.3630(5) 0.053(3) Uani 1 1 d . . .
H58A H 0.4203 0.4257 0.3403 0.080 Uiso 1 1 calc R . .
H58B H 0.4470 0.4632 0.3897 0.080 Uiso 1 1 calc R . .
H58C H 0.5117 0.4241 0.3813 0.080 Uiso 1 1 calc R . .
C59 C 0.5663(7) 0.5146(4) 0.3656(5) 0.051(3) Uani 1 1 d . . .
H59A H 0.5477 0.5305 0.3932 0.077 Uiso 1 1 calc R . .
H59B H 0.5836 0.5396 0.3445 0.077 Uiso 1 1 calc R . .
H59C H 0.6126 0.4929 0.3827 0.077 Uiso 1 1 calc R . .
C60 C 0.5237(8) 0.4575(4) 0.2834(5) 0.056(3) Uani 1 1 d . . .
H60A H 0.4785 0.4382 0.2597 0.084 Uiso 1 1 calc R . .
H60B H 0.5699 0.4357 0.3007 0.084 Uiso 1 1 calc R . .
H60C H 0.5413 0.4824 0.2622 0.084 Uiso 1 1 calc R . .
C61 C 0.3574(5) 0.7158(3) 0.2949(3) 0.0228(17) Uani 1 1 d . . .
C62 C 0.3652(5) 0.7462(3) 0.3325(3) 0.0280(18) Uani 1 1 d . . .
C63 C 0.3866(7) 0.7770(4) 0.3829(5) 0.050(3) Uani 1 1 d . . .
C64 C 0.3353(14) 0.7576(9) 0.4198(6) 0.113(8) Uani 1 1 d . . .
H64A H 0.2764 0.7609 0.4006 0.170 Uiso 1 1 calc R . .
H64B H 0.3494 0.7768 0.4530 0.170 Uiso 1 1 calc R . .
H64C H 0.3484 0.7229 0.4285 0.170 Uiso 1 1 calc R . .
C65 C 0.3697(11) 0.8309(6) 0.3686(8) 0.101(7) Uani 1 1 d . . .
H65A H 0.4026 0.8415 0.3461 0.151 Uiso 1 1 calc R . .
H65B H 0.3844 0.8505 0.4016 0.151 Uiso 1 1 calc R . .
H65C H 0.3112 0.8353 0.3490 0.151 Uiso 1 1 calc R . .
C66 C 0.4811(10) 0.7732(6) 0.4101(6) 0.084(5) Uani 1 1 d . . .
H66A H 0.5094 0.7857 0.3856 0.126 Uiso 1 1 calc R . .
H66B H 0.4963 0.7388 0.4187 0.126 Uiso 1 1 calc R . .
H66C H 0.4970 0.7927 0.4432 0.126 Uiso 1 1 calc R . .
C67 C 0.1224(6) 0.6979(3) 0.2221(3) 0.0273(18) Uani 1 1 d . . .
C68 C 0.0725(5) 0.7257(3) 0.1919(3) 0.0267(18) Uani 1 1 d . . .
C69 C 0.0061(6) 0.7557(4) 0.1543(4) 0.033(2) Uani 1 1 d . . .
C70 C -0.0785(7) 0.7391(5) 0.1598(4) 0.047(3) Uani 1 1 d . . .
H70A H -0.0882 0.7045 0.1496 0.071 Uiso 1 1 calc R . .
H70B H -0.1226 0.7592 0.1363 0.071 Uiso 1 1 calc R . .
H70C H -0.0777 0.7432 0.1971 0.071 Uiso 1 1 calc R . .
C71 C 0.0207(7) 0.8114(4) 0.1704(5) 0.056(3) Uani 1 1 d . . .
H71A H 0.0736 0.8220 0.1672 0.084 Uiso 1 1 calc R . .
H71B H 0.0211 0.8157 0.2076 0.084 Uiso 1 1 calc R . .
H71C H -0.0235 0.8312 0.1466 0.084 Uiso 1 1 calc R . .
C72 C 0.0070(9) 0.7488(5) 0.0956(4) 0.062(3) Uani 1 1 d . . .
H72A H -0.0022 0.7141 0.0855 0.093 Uiso 1 1 calc R . .
H72B H 0.0603 0.7591 0.0930 0.093 Uiso 1 1 calc R . .
H72C H -0.0367 0.7687 0.0714 0.093 Uiso 1 1 calc R . .
C73 C 0.2455(5) 0.6340(3) 0.1368(3) 0.0228(17) Uani 1 1 d . . .
C74 C 0.2181(5) 0.6427(3) 0.0875(4) 0.0251(18) Uani 1 1 d . . .
C75 C 0.1818(6) 0.6524(4) 0.0289(3) 0.034(2) Uani 1 1 d . . .
C76 C 0.0864(7) 0.6454(5) 0.0109(4) 0.048(3) Uani 1 1 d . . .
H76A H 0.0626 0.6681 0.0310 0.072 Uiso 1 1 calc R . .
H76B H 0.0736 0.6115 0.0181 0.072 Uiso 1 1 calc R . .
H76C H 0.0634 0.6522 -0.0276 0.072 Uiso 1 1 calc R . .
C77 C 0.2008(9) 0.7059(5) 0.0167(4) 0.063(4) Uani 1 1 d . . .
H77A H 0.1775 0.7286 0.0370 0.094 Uiso 1 1 calc R . .
H77B H 0.1766 0.7124 -0.0218 0.094 Uiso 1 1 calc R . .
H77C H 0.2605 0.7106 0.0271 0.094 Uiso 1 1 calc R . .
C78 C 0.2190(9) 0.6161(6) -0.0041(4) 0.069(4) Uani 1 1 d . . .
H78A H 0.2787 0.6203 0.0068 0.103 Uiso 1 1 calc R . .
H78B H 0.1953 0.6232 -0.0425 0.103 Uiso 1 1 calc R . .
H78C H 0.2060 0.5822 0.0030 0.103 Uiso 1 1 calc R . .
C79 C 0.1323(5) 0.5298(3) 0.2076(3) 0.0227(17) Uani 1 1 d . . .
C80 C 0.1218(5) 0.5017(3) 0.1689(3) 0.0247(17) Uani 1 1 d . . .
C81 C 0.0939(7) 0.4724(4) 0.1166(4) 0.039(2) Uani 1 1 d . . .
C82 C -0.0010(9) 0.4731(5) 0.0941(6) 0.064(4) Uani 1 1 d . . .
H82A H -0.0240 0.4571 0.1197 0.096 Uiso 1 1 calc R . .
H82B H -0.0190 0.4554 0.0599 0.096 Uiso 1 1 calc R . .
H82C H -0.0203 0.5072 0.0886 0.096 Uiso 1 1 calc R . .
C83 C 0.1330(11) 0.4974(6) 0.0761(5) 0.070(4) Uani 1 1 d . . .
H83A H 0.1135 0.5314 0.0696 0.105 Uiso 1 1 calc R . .
H83B H 0.1166 0.4792 0.0422 0.105 Uiso 1 1 calc R . .
H83C H 0.1930 0.4972 0.0914 0.105 Uiso 1 1 calc R . .
C84 C 0.1245(7) 0.4181(4) 0.1272(5) 0.048(3) Uani 1 1 d . . .
H84A H 0.0997 0.4027 0.1521 0.072 Uiso 1 1 calc R . .
H84B H 0.1845 0.4178 0.1429 0.072 Uiso 1 1 calc R . .
H84C H 0.1086 0.3999 0.0933 0.072 Uiso 1 1 calc R . .
C85 C 0.2490(6) 0.8051(4) 0.1629(4) 0.039(2) Uani 1 1 d . . .
C86 C 0.2455(7) 0.8449(4) 0.1181(5) 0.045(3) Uani 1 1 d . . .
C87 C 0.1026(6) 0.7783(3) 0.3325(3) 0.0307(19) Uani 1 1 d . . .
C88 C 0.0297(7) 0.8067(4) 0.3430(4) 0.042(2) Uani 1 1 d . . .
C89 C -0.0588(7) 0.6052(4) 0.1111(4) 0.036(2) Uani 1 1 d . . .
C90 C -0.1309(7) 0.6140(5) 0.0586(4) 0.047(3) Uani 1 1 d . . .
C91 C 0.3669(7) 0.4752(4) 0.1501(4) 0.045(2) Uani 1 1 d . . .
C92 C 0.4177(14) 0.4462(5) 0.1189(7) 0.089(6) Uani 1 1 d . . .
C93 C 0.2324(5) 0.4357(4) 0.3296(4) 0.033(2) Uani 1 1 d . . .
C94 C 0.2251(8) 0.3940(4) 0.3688(5) 0.049(3) Uani 1 1 d . . .
C95 C 0.5437(6) 0.6410(3) 0.3954(4) 0.034(2) Uani 1 1 d . . .
C96 C 0.6108(7) 0.6320(5) 0.4499(4) 0.049(3) Uani 1 1 d . . .
C97 C 0.7632(10) 0.4892(6) 0.1050(7) 0.078(4) Uani 1 1 d . . .
H97A H 0.8119 0.4674 0.1143 0.093 Uiso 1 1 calc R . .
H97B H 0.7550 0.5027 0.0687 0.093 Uiso 1 1 calc R . .
C98 C 0.6892(11) 0.4605(6) 0.1055(8) 0.089(5) Uani 1 1 d . . .
H98A H 0.6805 0.4335 0.0796 0.133 Uiso 1 1 calc R . .
H98B H 0.6409 0.4820 0.0956 0.133 Uiso 1 1 calc R . .
H98C H 0.6976 0.4471 0.1415 0.133 Uiso 1 1 calc R . .
C99 C 0.7260(10) 0.7579(6) 0.4070(6) 0.075(4) Uani 1 1 d . . .
H99A H 0.7362 0.7469 0.4445 0.090 Uiso 1 1 calc R . .
H99B H 0.6752 0.7779 0.3963 0.090 Uiso 1 1 calc R . .
C100 C 0.7970(13) 0.7880(7) 0.4031(8) 0.100(6) Uani 1 1 d . . .
H10B H 0.8039 0.8167 0.4267 0.151 Uiso 1 1 calc R . .
H10C H 0.7863 0.7990 0.3659 0.151 Uiso 1 1 calc R . .
H10D H 0.8471 0.7681 0.4140 0.151 Uiso 1 1 calc R . .
F1 F -0.0364(5) 0.8053(5) 0.2995(3) 0.097(4) Uani 1 1 d . . .
F2 F 0.0079(5) 0.7875(3) 0.3845(3) 0.0604(18) Uani 1 1 d . . .
F3 F 0.0493(6) 0.8543(3) 0.3576(4) 0.086(3) Uani 1 1 d . . .
F4 F 0.1634(9) 0.8543(6) 0.0908(5) 0.143(6) Uani 1 1 d . . .
F5 F 0.2724(13) 0.8859(5) 0.1322(4) 0.189(10) Uani 1 1 d . . .
F6 F 0.2668(10) 0.8283(4) 0.0777(4) 0.131(6) Uani 1 1 d . . .
F7 F -0.1689(8) 0.5734(5) 0.0359(4) 0.128(5) Uani 1 1 d . . .
F8 F -0.1868(10) 0.6399(8) 0.0662(6) 0.233(13) Uani 1 1 d . . .
F9 F -0.1094(8) 0.6327(8) 0.0189(5) 0.193(10) Uani 1 1 d . . .
F10 F 0.4123(11) 0.3998(6) 0.1181(6) 0.149(5) Uiso 1 1 d . . .
F11 F 0.3823(11) 0.4581(6) 0.0642(6) 0.150(5) Uiso 1 1 d . . .
F12 F 0.4877(10) 0.4619(6) 0.1246(9) 0.199(10) Uani 1 1 d . . .
F13 F 0.5893(7) 0.6016(6) 0.4836(4) 0.136(6) Uani 1 1 d . . .
F14 F 0.6761(6) 0.6094(5) 0.4425(4) 0.109(4) Uani 1 1 d . . .
F15 F 0.6404(8) 0.6736(4) 0.4753(4) 0.115(5) Uani 1 1 d . . .
F16 F 0.2930(15) 0.3923(8) 0.4098(7) 0.246(14) Uani 1 1 d . . .
F17 F 0.1746(12) 0.3966(5) 0.3930(8) 0.199(10) Uani 1 1 d . . .
F18 F 0.2303(14) 0.3500(4) 0.3539(6) 0.174(8) Uani 1 1 d . . .
N1 N 0.5462(5) 0.6474(3) 0.2288(3) 0.0296(16) Uani 1 1 d . . .
N2 N 0.5545(5) 0.7476(3) 0.2572(3) 0.0370(18) Uani 1 1 d . . .
N3 N 0.4506(5) 0.7239(3) 0.1166(4) 0.043(2) Uani 1 1 d . . .
N4 N 0.4584(6) 0.6275(4) 0.0820(3) 0.044(2) Uani 1 1 d . . .
N5 N -0.0491(5) 0.6026(3) 0.2803(3) 0.0291(16) Uani 1 1 d . . .
N6 N -0.0593(5) 0.5018(3) 0.2538(3) 0.0331(17) Uani 1 1 d . . .
N7 N 0.0457(5) 0.6282(3) 0.4247(3) 0.0283(16) Uani 1 1 d . . .
N8 N 0.0430(5) 0.5287(3) 0.3960(3) 0.0293(16) Uani 1 1 d . . .
O1 O 0.4716(4) 0.6275(3) 0.3941(2) 0.0366(15) Uani 1 1 d . . .
O2 O 0.5655(4) 0.6601(3) 0.3591(3) 0.0413(16) Uani 1 1 d . . .
O3 O 0.1104(4) 0.7337(2) 0.3456(3) 0.0370(15) Uani 1 1 d . . .
O4 O 0.1439(4) 0.8059(2) 0.3095(3) 0.0377(15) Uani 1 1 d . . .
O5 O 0.2393(5) 0.8233(3) 0.2052(3) 0.0439(17) Uani 1 1 d . . .
O6 O 0.2637(6) 0.7627(3) 0.1524(3) 0.050(2) Uani 1 1 d . . .
O7 O -0.0780(4) 0.5859(3) 0.1496(3) 0.0426(17) Uani 1 1 d . . .
O8 O 0.0107(5) 0.6178(3) 0.1091(3) 0.0432(17) Uani 1 1 d . . .
O9 O 0.3360(5) 0.4464(3) 0.1774(3) 0.0431(17) Uani 1 1 d . . .
O10 O 0.3677(5) 0.5208(3) 0.1466(3) 0.0477(18) Uani 1 1 d . . .
O11 O 0.2158(5) 0.4780(2) 0.3435(3) 0.0364(15) Uani 1 1 d . . .
O12 O 0.2529(5) 0.4222(3) 0.2901(3) 0.0414(16) Uani 1 1 d . . .
O13 O 0.7163(6) 0.7158(4) 0.3722(5) 0.082(3) Uani 1 1 d . . .
H13B H 0.6722 0.7015 0.3702 0.123 Uiso 1 1 calc R . .
O14 O 0.7763(6) 0.5279(4) 0.1426(4) 0.067(2) Uani 1 1 d . . .
H14B H 0.8188 0.5434 0.1432 0.100 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C61 2.263(8) . ?
Ag1 C73 2.322(7) . ?
Ag1 O6 2.420(6) . ?
Ag1 Ag5 2.8059(8) . ?
Ag1 Ag2 2.8420(8) . ?
Ag1 Ag7 2.8858(9) . ?
Ag1 Ag8 2.9859(9) . ?
Ag1 Ag11 3.0221(9) . ?
Ag1 Ag10 3.0591(8) . ?
Ag1 Ag4 3.2840(8) . ?
Ag2 C73 2.141(7) . ?
Ag2 C55 2.143(8) . ?
Ag2 Ag6 2.8934(8) . ?
Ag2 Ag10 2.9388(8) . ?
Ag2 Ag11 2.9721(8) . ?
Ag2 Ag8 3.1044(8) . ?
Ag2 Ag3 3.3321(8) . ?
Ag3 C79 2.236(8) . ?
Ag3 C49 2.350(7) . ?
Ag3 O11 2.429(6) . ?
Ag3 Ag6 2.8043(8) . ?
Ag3 Ag12 2.8530(9) . ?
Ag3 Ag4 2.8780(8) . ?
Ag3 Ag9 3.0325(9) . ?
Ag3 Ag10 3.0494(9) . ?
Ag3 Ag11 3.1328(8) . ?
Ag4 C49 2.114(7) . ?
Ag4 C67 2.121(8) . ?
Ag4 Ag5 2.9490(8) . ?
Ag4 Ag11 2.9737(8) . ?
Ag4 Ag10 2.9894(8) . ?
Ag4 Ag9 3.0946(8) . ?
Ag5 O4 2.264(6) . ?
Ag5 O5 2.377(7) . ?
Ag5 C67 2.438(9) . ?
Ag5 C61 2.472(8) . ?
Ag5 C62 2.475(8) . ?
Ag6 O9 2.272(7) . ?
Ag6 O12 2.337(6) . ?
Ag6 C55 2.446(9) . ?
Ag6 C79 2.500(8) . ?
Ag6 C80 2.539(8) . ?
Ag7 C61 2.174(8) . ?
Ag7 N1 2.274(7) . ?
Ag7 N2 2.356(8) . ?
Ag7 O2 2.562(7) . ?
Ag7 Ag10 2.8523(8) . ?
Ag8 C73 2.265(9) . ?
Ag8 N3 2.266(8) . ?
Ag8 N4 2.380(9) . ?
Ag8 C74 2.501(9) . ?
Ag9 C49 2.262(8) . ?
Ag9 N8 2.273(8) . ?
Ag9 N7 2.374(7) . ?
Ag9 C50 2.544(9) . ?
Ag10 C55 2.304(9) . ?
Ag10 O1 2.342(6) . ?
Ag10 C61 2.423(8) . ?
Ag10 C49 2.599(7) . ?
Ag11 O8 2.354(6) . ?
Ag11 C67 2.364(8) . ?
Ag11 C79 2.435(8) . ?
Ag11 C73 2.579(8) . ?
Ag11 Ag12 2.8895(8) . ?
Ag12 C79 2.206(8) . ?
Ag12 N5 2.298(7) . ?
Ag12 N6 2.362(8) . ?
Ag12 O7 2.509(7) . ?
C1 N3 1.332(17) . ?
C1 C2 1.37(2) . ?
C2 C3 1.34(3) . ?
C3 C4 1.40(3) . ?
C4 C5 1.38(2) . ?
C4 C12 1.401(18) . ?
C5 C6 1.25(2) . ?
C6 C7 1.56(2) . ?
C7 C11 1.399(16) . ?
C7 C8 1.44(3) . ?
C8 C9 1.38(3) . ?
C9 C10 1.41(2) . ?
C10 N4 1.335(17) . ?
C11 N4 1.339(16) . ?
C11 C12 1.45(2) . ?
C12 N3 1.356(16) . ?
C13 N2 1.317(15) . ?
C13 C14 1.393(18) . ?
C14 C15 1.356(19) . ?
C15 C16 1.418(17) . ?
C16 C17 1.393(17) . ?
C16 C24 1.411(15) . ?
C17 C18 1.344(19) . ?
C18 C19 1.442(16) . ?
C19 C23 1.403(13) . ?
C19 C20 1.410(17) . ?
C20 C21 1.354(18) . ?
C21 C22 1.397(15) . ?
C22 N1 1.316(13) . ?
C23 N1 1.345(12) . ?
C23 C24 1.481(14) . ?
C24 N2 1.345(13) . ?
C25 N7 1.326(13) . ?
C25 C26 1.410(17) . ?
C26 C27 1.376(18) . ?
C27 C28 1.402(16) . ?
C28 C36 1.403(13) . ?
C28 C29 1.459(18) . ?
C29 C30 1.28(2) . ?
C30 C31 1.439(16) . ?
C31 C32 1.401(16) . ?
C31 C35 1.441(13) . ?
C32 C33 1.364(17) . ?
C33 C34 1.372(16) . ?
C34 N8 1.303(13) . ?
C35 N8 1.367(11) . ?
C35 C36 1.439(13) . ?
C36 N7 1.335(12) . ?
C37 N5 1.310(13) . ?
C37 C38 1.413(14) . ?
C38 C39 1.355(16) . ?
C39 C40 1.409(15) . ?
C40 C48 1.403(12) . ?
C40 C41 1.431(15) . ?
C41 C42 1.371(17) . ?
C42 C43 1.399(16) . ?
C43 C44 1.385(16) . ?
C43 C47 1.437(13) . ?
C44 C45 1.345(19) . ?
C45 C46 1.397(18) . ?
C46 N6 1.322(13) . ?
C47 N6 1.346(12) . ?
C47 C48 1.458(13) . ?
C48 N5 1.361(12) . ?
C49 C50 1.208(13) . ?
C50 C51 1.491(13) . ?
C51 C52 1.523(18) . ?
C51 C54 1.563(18) . ?
C51 C53 1.566(16) . ?
C55 C56 1.225(13) . ?
C56 C57 1.461(13) . ?
C57 C58 1.536(15) . ?
C57 C60 1.540(15) . ?
C57 C59 1.544(15) . ?
C61 C62 1.237(13) . ?
C62 C63 1.481(13) . ?
C63 C65 1.49(2) . ?
C63 C66 1.522(19) . ?
C63 C64 1.56(2) . ?
C67 C68 1.202(13) . ?
C68 C69 1.463(13) . ?
C69 C72 1.525(14) . ?
C69 C70 1.536(14) . ?
C69 C71 1.541(16) . ?
C73 C74 1.226(12) . ?
C74 C75 1.462(12) . ?
C75 C77 1.516(16) . ?
C75 C76 1.531(15) . ?
C75 C78 1.542(13) . ?
C79 C80 1.213(12) . ?
C80 C81 1.499(12) . ?
C81 C82 1.516(18) . ?
C81 C84 1.531(15) . ?
C81 C83 1.543(15) . ?
C85 O6 1.205(13) . ?
C85 O5 1.246(12) . ?
C85 C86 1.554(13) . ?
C86 F5 1.195(16) . ?
C86 F6 1.279(15) . ?
C86 F4 1.360(18) . ?
C87 O3 1.232(12) . ?
C87 O4 1.278(11) . ?
C87 C88 1.533(14) . ?
C88 F1 1.307(14) . ?
C88 F2 1.334(12) . ?
C88 F3 1.336(13) . ?
C89 O8 1.229(13) . ?
C89 O7 1.244(12) . ?
C89 C90 1.524(15) . ?
C90 F8 1.228(17) . ?
C90 F9 1.283(17) . ?
C90 F7 1.300(17) . ?
C91 O10 1.220(14) . ?
C91 O9 1.258(13) . ?
C91 C92 1.548(17) . ?
C92 F12 1.21(2) . ?
C92 F10 1.24(2) . ?
C92 F11 1.38(2) . ?
C93 O12 1.224(12) . ?
C93 O11 1.241(12) . ?
C93 C94 1.531(13) . ?
C94 F17 1.201(15) . ?
C94 F18 1.248(17) . ?
C94 F16 1.29(2) . ?
C95 O2 1.216(12) . ?
C95 O1 1.253(12) . ?
C95 C96 1.517(15) . ?
C96 F15 1.304(15) . ?
C96 F14 1.315(16) . ?
C96 F13 1.317(16) . ?
C97 O14 1.385(17) . ?
C97 C98 1.46(2) . ?
C99 O13 1.412(17) . ?
C99 C100 1.47(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C61 Ag1 C73 154.7(3) . . ?
C61 Ag1 O6 105.2(3) . . ?
C73 Ag1 O6 93.7(3) . . ?
C61 Ag1 Ag5 57.2(2) . . ?
C73 Ag1 Ag5 145.8(2) . . ?
O6 Ag1 Ag5 76.75(16) . . ?
C61 Ag1 Ag2 108.5(2) . . ?
C73 Ag1 Ag2 47.68(19) . . ?
O6 Ag1 Ag2 137.84(16) . . ?
Ag5 Ag1 Ag2 143.92(3) . . ?
C61 Ag1 Ag7 48.1(2) . . ?
C73 Ag1 Ag7 111.5(2) . . ?
O6 Ag1 Ag7 104.1(2) . . ?
Ag5 Ag1 Ag7 102.66(2) . . ?
Ag2 Ag1 Ag7 81.14(2) . . ?
C61 Ag1 Ag8 118.9(2) . . ?
C73 Ag1 Ag8 48.6(2) . . ?
O6 Ag1 Ag8 77.56(16) . . ?
Ag5 Ag1 Ag8 151.30(3) . . ?
Ag2 Ag1 Ag8 64.32(2) . . ?
Ag7 Ag1 Ag8 71.59(2) . . ?
C61 Ag1 Ag11 125.5(2) . . ?
C73 Ag1 Ag11 55.9(2) . . ?
O6 Ag1 Ag11 116.1(2) . . ?
Ag5 Ag1 Ag11 98.67(2) . . ?
Ag2 Ag1 Ag11 60.81(2) . . ?
Ag7 Ag1 Ag11 137.82(3) . . ?
Ag8 Ag1 Ag11 103.97(2) . . ?
C61 Ag1 Ag10 51.6(2) . . ?
C73 Ag1 Ag10 106.98(19) . . ?
O6 Ag1 Ag10 156.0(2) . . ?
Ag5 Ag1 Ag10 91.90(2) . . ?
Ag2 Ag1 Ag10 59.600(19) . . ?
Ag7 Ag1 Ag10 57.254(19) . . ?
Ag8 Ag1 Ag10 106.81(2) . . ?
Ag11 Ag1 Ag10 86.31(2) . . ?
C61 Ag1 Ag4 70.9(2) . . ?
C73 Ag1 Ag4 110.4(2) . . ?
O6 Ag1 Ag4 128.03(17) . . ?
Ag5 Ag1 Ag4 57.281(19) . . ?
Ag2 Ag1 Ag4 87.19(2) . . ?
Ag7 Ag1 Ag4 108.16(2) . . ?
Ag8 Ag1 Ag4 151.40(3) . . ?
Ag11 Ag1 Ag4 56.087(18) . . ?
Ag10 Ag1 Ag4 56.101(17) . . ?
C73 Ag2 C55 167.8(3) . . ?
C73 Ag2 Ag1 53.3(2) . . ?
C55 Ag2 Ag1 114.7(2) . . ?
C73 Ag2 Ag6 131.8(2) . . ?
C55 Ag2 Ag6 55.7(2) . . ?
Ag1 Ag2 Ag6 145.86(3) . . ?
C73 Ag2 Ag10 116.8(2) . . ?
C55 Ag2 Ag10 51.0(2) . . ?
Ag1 Ag2 Ag10 63.87(2) . . ?
Ag6 Ag2 Ag10 96.63(2) . . ?
C73 Ag2 Ag11 57.9(2) . . ?
C55 Ag2 Ag11 116.6(3) . . ?
Ag1 Ag2 Ag11 62.59(2) . . ?
Ag6 Ag2 Ag11 91.17(2) . . ?
Ag10 Ag2 Ag11 89.44(2) . . ?
C73 Ag2 Ag8 46.8(2) . . ?
C55 Ag2 Ag8 132.5(3) . . ?
Ag1 Ag2 Ag8 60.09(2) . . ?
Ag6 Ag2 Ag8 152.85(3) . . ?
Ag10 Ag2 Ag8 106.83(3) . . ?
Ag11 Ag2 Ag8 102.31(2) . . ?
C73 Ag2 Ag3 116.9(2) . . ?
C55 Ag2 Ag3 57.7(3) . . ?
Ag1 Ag2 Ag3 93.38(2) . . ?
Ag6 Ag2 Ag3 52.976(18) . . ?
Ag10 Ag2 Ag3 57.784(18) . . ?
Ag11 Ag2 Ag3 59.266(18) . . ?
Ag8 Ag2 Ag3 153.38(3) . . ?
C79 Ag3 C49 152.0(3) . . ?
C79 Ag3 O11 101.2(3) . . ?
C49 Ag3 O11 99.9(2) . . ?
C79 Ag3 Ag6 58.2(2) . . ?
C49 Ag3 Ag6 145.58(19) . . ?
O11 Ag3 Ag6 77.58(14) . . ?
C79 Ag3 Ag12 49.6(2) . . ?
C49 Ag3 Ag12 108.18(19) . . ?
O11 Ag3 Ag12 100.96(18) . . ?
Ag6 Ag3 Ag12 105.96(3) . . ?
C79 Ag3 Ag4 106.8(2) . . ?
C49 Ag3 Ag4 46.34(18) . . ?
O11 Ag3 Ag4 141.06(14) . . ?
Ag6 Ag3 Ag4 140.65(3) . . ?
Ag12 Ag3 Ag4 78.35(2) . . ?
C79 Ag3 Ag9 119.2(2) . . ?
C49 Ag3 Ag9 47.65(19) . . ?
O11 Ag3 Ag9 79.85(15) . . ?
Ag6 Ag3 Ag9 155.92(3) . . ?
Ag12 Ag3 Ag9 70.26(2) . . ?
Ag4 Ag3 Ag9 63.08(2) . . ?
C79 Ag3 Ag10 124.0(2) . . ?
C49 Ag3 Ag10 55.75(19) . . ?
O11 Ag3 Ag10 122.13(18) . . ?
Ag6 Ag3 Ag10 96.07(2) . . ?
Ag12 Ag3 Ag10 135.01(3) . . ?
Ag4 Ag3 Ag10 60.49(2) . . ?
Ag9 Ag3 Ag10 102.99(2) . . ?
C79 Ag3 Ag11 50.6(2) . . ?
C49 Ag3 Ag11 105.06(18) . . ?
O11 Ag3 Ag11 151.11(17) . . ?
Ag6 Ag3 Ag11 89.60(2) . . ?
Ag12 Ag3 Ag11 57.50(2) . . ?
Ag4 Ag3 Ag11 59.123(19) . . ?
Ag9 Ag3 Ag11 106.57(3) . . ?
Ag10 Ag3 Ag11 84.56(2) . . ?
C79 Ag3 Ag2 71.0(2) . . ?
C49 Ag3 Ag2 108.41(18) . . ?
O11 Ag3 Ag2 129.47(15) . . ?
Ag6 Ag3 Ag2 55.463(19) . . ?
Ag12 Ag3 Ag2 108.40(2) . . ?
Ag4 Ag3 Ag2 85.70(2) . . ?
Ag9 Ag3 Ag2 148.61(3) . . ?
Ag10 Ag3 Ag2 54.623(18) . . ?
Ag11 Ag3 Ag2 54.634(17) . . ?
C49 Ag4 C67 169.4(3) . . ?
C49 Ag4 Ag3 53.6(2) . . ?
C67 Ag4 Ag3 116.6(2) . . ?
C49 Ag4 Ag5 130.3(2) . . ?
C67 Ag4 Ag5 54.6(2) . . ?
Ag3 Ag4 Ag5 146.27(3) . . ?
C49 Ag4 Ag11 117.7(2) . . ?
C67 Ag4 Ag11 52.1(2) . . ?
Ag3 Ag4 Ag11 64.71(2) . . ?
Ag5 Ag4 Ag11 96.62(2) . . ?
C49 Ag4 Ag10 58.3(2) . . ?
C67 Ag4 Ag10 115.3(3) . . ?
Ag3 Ag4 Ag10 62.59(2) . . ?
Ag5 Ag4 Ag10 90.54(2) . . ?
Ag11 Ag4 Ag10 88.45(2) . . ?
C49 Ag4 Ag9 47.0(2) . . ?
C67 Ag4 Ag9 134.9(3) . . ?
Ag3 Ag4 Ag9 60.90(2) . . ?
Ag5 Ag4 Ag9 151.07(3) . . ?
Ag11 Ag4 Ag9 109.06(3) . . ?
Ag10 Ag4 Ag9 102.93(2) . . ?
C49 Ag4 Ag1 116.3(2) . . ?
C67 Ag4 Ag1 57.4(3) . . ?
Ag3 Ag4 Ag1 93.73(2) . . ?
Ag5 Ag4 Ag1 53.179(17) . . ?
Ag11 Ag4 Ag1 57.498(18) . . ?
Ag10 Ag4 Ag1 58.143(18) . . ?
Ag9 Ag4 Ag1 154.37(3) . . ?
O4 Ag5 O5 100.0(2) . . ?
O4 Ag5 C67 99.9(3) . . ?
O5 Ag5 C67 111.0(3) . . ?
O4 Ag5 C61 138.3(3) . . ?
O5 Ag5 C61 104.0(3) . . ?
C67 Ag5 C61 102.5(3) . . ?
O4 Ag5 C62 111.2(3) . . ?
O5 Ag5 C62 106.3(3) . . ?
C67 Ag5 C62 125.5(3) . . ?
C61 Ag5 C62 29.0(3) . . ?
O4 Ag5 Ag1 163.52(17) . . ?
O5 Ag5 Ag1 88.74(17) . . ?
C67 Ag5 Ag1 63.8(2) . . ?
C61 Ag5 Ag1 50.30(18) . . ?
C62 Ag5 Ag1 79.2(2) . . ?
O4 Ag5 Ag4 97.68(17) . . ?
O5 Ag5 Ag4 152.82(18) . . ?
C67 Ag5 Ag4 45.16(19) . . ?
C61 Ag5 Ag4 75.03(19) . . ?
C62 Ag5 Ag4 86.1(2) . . ?
Ag1 Ag5 Ag4 69.54(2) . . ?
O9 Ag6 O12 104.5(3) . . ?
O9 Ag6 C55 103.1(3) . . ?
O12 Ag6 C55 112.4(3) . . ?
O9 Ag6 C79 131.2(2) . . ?
O12 Ag6 C79 102.0(3) . . ?
C55 Ag6 C79 103.6(3) . . ?
O9 Ag6 C80 105.3(3) . . ?
O12 Ag6 C80 103.8(3) . . ?
C55 Ag6 C80 125.8(3) . . ?
C79 Ag6 C80 27.8(3) . . ?
O9 Ag6 Ag3 165.3(2) . . ?
O12 Ag6 Ag3 88.78(16) . . ?
C55 Ag6 Ag3 65.1(2) . . ?
C79 Ag6 Ag3 49.44(17) . . ?
C80 Ag6 Ag3 77.19(19) . . ?
O9 Ag6 Ag2 93.9(2) . . ?
O12 Ag6 Ag2 155.52(18) . . ?
C55 Ag6 Ag2 46.40(19) . . ?
C79 Ag6 Ag2 76.54(19) . . ?
C80 Ag6 Ag2 86.3(2) . . ?
Ag3 Ag6 Ag2 71.56(2) . . ?
C61 Ag7 N1 169.2(3) . . ?
C61 Ag7 N2 114.9(3) . . ?
N1 Ag7 N2 73.2(3) . . ?
C61 Ag7 O2 101.5(3) . . ?
N1 Ag7 O2 85.2(2) . . ?
N2 Ag7 O2 89.6(3) . . ?
C61 Ag7 Ag10 55.7(2) . . ?
N1 Ag7 Ag10 118.5(2) . . ?
N2 Ag7 Ag10 162.22(19) . . ?
O2 Ag7 Ag10 78.73(16) . . ?
C61 Ag7 Ag1 50.8(2) . . ?
N1 Ag7 Ag1 119.16(19) . . ?
N2 Ag7 Ag1 123.7(2) . . ?
O2 Ag7 Ag1 142.14(15) . . ?
Ag10 Ag7 Ag1 64.43(2) . . ?
C73 Ag8 N3 148.1(3) . . ?
C73 Ag8 N4 131.4(3) . . ?
N3 Ag8 N4 72.2(3) . . ?
C73 Ag8 C74 29.3(3) . . ?
N3 Ag8 C74 129.7(3) . . ?
N4 Ag8 C74 114.2(3) . . ?
C73 Ag8 Ag1 50.23(18) . . ?
N3 Ag8 Ag1 111.4(3) . . ?
N4 Ag8 Ag1 169.2(2) . . ?
C74 Ag8 Ag1 71.86(18) . . ?
C73 Ag8 Ag2 43.60(19) . . ?
N3 Ag8 Ag2 154.9(2) . . ?
N4 Ag8 Ag2 116.9(2) . . ?
C74 Ag8 Ag2 70.16(19) . . ?
Ag1 Ag8 Ag2 55.594(18) . . ?
C49 Ag9 N8 149.2(3) . . ?
C49 Ag9 N7 126.7(3) . . ?
N8 Ag9 N7 72.5(3) . . ?
C49 Ag9 C50 28.3(3) . . ?
N8 Ag9 C50 125.8(3) . . ?
N7 Ag9 C50 115.8(3) . . ?
C49 Ag9 Ag3 50.16(18) . . ?
N8 Ag9 Ag3 114.98(19) . . ?
N7 Ag9 Ag3 169.79(17) . . ?
C50 Ag9 Ag3 66.2(2) . . ?
C49 Ag9 Ag4 43.08(19) . . ?
N8 Ag9 Ag4 158.97(17) . . ?
N7 Ag9 Ag4 114.44(17) . . ?
C50 Ag9 Ag4 70.6(2) . . ?
Ag3 Ag9 Ag4 56.021(18) . . ?
C55 Ag10 O1 101.1(3) . . ?
C55 Ag10 C61 143.0(3) . . ?
O1 Ag10 C61 96.6(3) . . ?
C55 Ag10 C49 104.1(3) . . ?
O1 Ag10 C49 95.2(2) . . ?
C61 Ag10 C49 106.2(3) . . ?
C55 Ag10 Ag7 101.4(2) . . ?
O1 Ag10 Ag7 85.76(16) . . ?
C61 Ag10 Ag7 47.82(19) . . ?
C49 Ag10 Ag7 153.78(17) . . ?
C55 Ag10 Ag2 46.3(2) . . ?
O1 Ag10 Ag2 139.49(18) . . ?
C61 Ag10 Ag2 101.23(18) . . ?
C49 Ag10 Ag2 113.87(16) . . ?
Ag7 Ag10 Ag2 80.06(2) . . ?
C55 Ag10 Ag4 115.8(2) . . ?
O1 Ag10 Ag4 128.66(17) . . ?
C61 Ag10 Ag4 74.93(19) . . ?
C49 Ag10 Ag4 43.75(17) . . ?
Ag7 Ag10 Ag4 117.78(3) . . ?
Ag2 Ag10 Ag4 91.22(2) . . ?
C55 Ag10 Ag3 62.3(2) . . ?
O1 Ag10 Ag3 124.56(16) . . ?
C61 Ag10 Ag3 129.28(19) . . ?
C49 Ag10 Ag3 48.37(16) . . ?
Ag7 Ag10 Ag3 146.52(3) . . ?
Ag2 Ag10 Ag3 67.593(19) . . ?
Ag4 Ag10 Ag3 56.914(19) . . ?
C55 Ag10 Ag1 102.7(2) . . ?
O1 Ag10 Ag1 139.97(17) . . ?
C61 Ag10 Ag1 47.02(18) . . ?
C49 Ag10 Ag1 109.43(17) . . ?
Ag7 Ag10 Ag1 58.32(2) . . ?
Ag2 Ag10 Ag1 56.525(18) . . ?
Ag4 Ag10 Ag1 65.756(19) . . ?
Ag3 Ag10 Ag1 95.04(2) . . ?
O8 Ag11 C67 100.3(3) . . ?
O8 Ag11 C79 96.9(3) . . ?
C67 Ag11 C79 139.9(3) . . ?
O8 Ag11 C73 100.9(2) . . ?
C67 Ag11 C73 102.2(3) . . ?
C79 Ag11 C73 109.7(3) . . ?
O8 Ag11 Ag12 83.65(18) . . ?
C67 Ag11 Ag12 98.3(2) . . ?
C79 Ag11 Ag12 48.01(19) . . ?
C73 Ag11 Ag12 157.74(18) . . ?
O8 Ag11 Ag2 134.22(19) . . ?
C67 Ag11 Ag2 114.2(2) . . ?
C79 Ag11 Ag2 76.0(2) . . ?
C73 Ag11 Ag2 44.67(17) . . ?
Ag12 Ag11 Ag2 117.99(3) . . ?
O8 Ag11 Ag4 134.69(19) . . ?
C67 Ag11 Ag4 45.1(2) . . ?
C79 Ag11 Ag4 98.82(17) . . ?
C73 Ag11 Ag4 113.02(17) . . ?
Ag12 Ag11 Ag4 76.25(2) . . ?
Ag2 Ag11 Ag4 90.88(2) . . ?
O8 Ag11 Ag1 129.14(18) . . ?
C67 Ag11 Ag1 60.9(2) . . ?
C79 Ag11 Ag1 128.7(2) . . ?
C73 Ag11 Ag1 48.19(18) . . ?
Ag12 Ag11 Ag1 141.69(3) . . ?
Ag2 Ag11 Ag1 56.599(19) . . ?
Ag4 Ag11 Ag1 66.416(19) . . ?
O8 Ag11 Ag3 136.77(18) . . ?
C67 Ag11 Ag3 101.1(2) . . ?
C79 Ag11 Ag3 45.22(18) . . ?
C73 Ag11 Ag3 110.61(17) . . ?
Ag12 Ag11 Ag3 56.38(2) . . ?
Ag2 Ag11 Ag3 66.100(19) . . ?
Ag4 Ag11 Ag3 56.165(18) . . ?
Ag1 Ag11 Ag3 94.09(2) . . ?
C79 Ag12 N5 168.8(3) . . ?
C79 Ag12 N6 114.1(3) . . ?
N5 Ag12 N6 72.7(3) . . ?
C79 Ag12 O7 102.8(3) . . ?
N5 Ag12 O7 85.7(2) . . ?
N6 Ag12 O7 89.5(3) . . ?
C79 Ag12 Ag3 50.5(2) . . ?
N5 Ag12 Ag3 118.71(19) . . ?
N6 Ag12 Ag3 120.1(2) . . ?
O7 Ag12 Ag3 145.15(16) . . ?
C79 Ag12 Ag11 55.1(2) . . ?
N5 Ag12 Ag11 120.53(19) . . ?
N6 Ag12 Ag11 162.17(17) . . ?
O7 Ag12 Ag11 80.28(16) . . ?
Ag3 Ag12 Ag11 66.12(2) . . ?
N3 C1 C2 122.2(18) . . ?
C3 C2 C1 120.7(18) . . ?
C2 C3 C4 119.1(14) . . ?
C5 C4 C12 122.1(19) . . ?
C5 C4 C3 120.3(16) . . ?
C12 C4 C3 117.6(16) . . ?
C6 C5 C4 119.9(19) . . ?
C5 C6 C7 123.6(16) . . ?
C11 C7 C8 117.0(16) . . ?
C11 C7 C6 116.3(17) . . ?
C8 C7 C6 126.7(13) . . ?
C9 C8 C7 117.7(15) . . ?
C8 C9 C10 121.8(19) . . ?
N4 C10 C9 119.6(18) . . ?
N4 C11 C7 123.2(15) . . ?
N4 C11 C12 119.9(9) . . ?
C7 C11 C12 116.9(14) . . ?
N3 C12 C4 121.8(15) . . ?
N3 C12 C11 117.1(10) . . ?
C4 C12 C11 121.1(13) . . ?
N2 C13 C14 124.5(11) . . ?
C15 C14 C13 118.6(11) . . ?
C14 C15 C16 120.0(10) . . ?
C17 C16 C24 121.2(10) . . ?
C17 C16 C15 123.0(10) . . ?
C24 C16 C15 115.9(10) . . ?
C18 C17 C16 120.4(10) . . ?
C17 C18 C19 122.7(10) . . ?
C23 C19 C20 118.5(9) . . ?
C23 C19 C18 118.6(9) . . ?
C20 C19 C18 122.8(9) . . ?
C21 C20 C19 117.9(9) . . ?
C20 C21 C22 120.5(10) . . ?
N1 C22 C21 122.3(10) . . ?
N1 C23 C19 121.8(9) . . ?
N1 C23 C24 119.5(8) . . ?
C19 C23 C24 118.6(8) . . ?
N2 C24 C16 124.1(9) . . ?
N2 C24 C23 117.3(9) . . ?
C16 C24 C23 118.5(9) . . ?
N7 C25 C26 121.8(10) . . ?
C27 C26 C25 119.0(10) . . ?
C26 C27 C28 119.4(10) . . ?
C27 C28 C36 117.5(10) . . ?
C27 C28 C29 123.3(10) . . ?
C36 C28 C29 119.2(10) . . ?
C30 C29 C28 121.1(10) . . ?
C29 C30 C31 123.2(10) . . ?
C32 C31 C30 125.2(10) . . ?
C32 C31 C35 116.6(9) . . ?
C30 C31 C35 118.1(10) . . ?
C33 C32 C31 120.9(10) . . ?
C32 C33 C34 117.6(10) . . ?
N8 C34 C33 125.8(10) . . ?
N8 C35 C36 120.6(8) . . ?
N8 C35 C31 120.8(9) . . ?
C36 C35 C31 118.6(8) . . ?
N7 C36 C28 122.9(9) . . ?
N7 C36 C35 117.4(7) . . ?
C28 C36 C35 119.6(8) . . ?
N5 C37 C38 122.0(9) . . ?
C39 C38 C37 119.9(10) . . ?
C38 C39 C40 119.0(9) . . ?
C48 C40 C39 117.9(9) . . ?
C48 C40 C41 120.0(9) . . ?
C39 C40 C41 122.2(8) . . ?
C42 C41 C40 120.3(9) . . ?
C41 C42 C43 122.8(9) . . ?
C44 C43 C42 124.7(10) . . ?
C44 C43 C47 117.0(10) . . ?
C42 C43 C47 118.3(9) . . ?
C45 C44 C43 121.7(11) . . ?
C44 C45 C46 117.2(11) . . ?
N6 C46 C45 124.9(11) . . ?
N6 C47 C43 121.6(9) . . ?
N6 C47 C48 118.7(8) . . ?
C43 C47 C48 119.7(8) . . ?
N5 C48 C40 122.0(8) . . ?
N5 C48 C47 119.0(7) . . ?
C40 C48 C47 119.0(8) . . ?
C50 C49 Ag4 163.7(7) . . ?
C50 C49 Ag9 88.9(6) . . ?
Ag4 C49 Ag9 89.9(3) . . ?
C50 C49 Ag3 115.8(7) . . ?
Ag4 C49 Ag3 80.1(2) . . ?
Ag9 C49 Ag3 82.2(2) . . ?
C50 C49 Ag10 108.2(6) . . ?
Ag4 C49 Ag10 78.0(2) . . ?
Ag9 C49 Ag10 156.4(3) . . ?
Ag3 C49 Ag10 75.9(2) . . ?
C49 C50 C51 174.6(9) . . ?
C49 C50 Ag9 62.7(5) . . ?
C51 C50 Ag9 122.5(6) . . ?
C50 C51 C52 108.2(10) . . ?
C50 C51 C54 108.6(8) . . ?
C52 C51 C54 112.2(10) . . ?
C50 C51 C53 107.1(8) . . ?
C52 C51 C53 111.6(10) . . ?
C54 C51 C53 109.0(11) . . ?
C56 C55 Ag2 143.2(7) . . ?
C56 C55 Ag10 126.1(7) . . ?
Ag2 C55 Ag10 82.6(3) . . ?
C56 C55 Ag6 92.7(6) . . ?
Ag2 C55 Ag6 77.9(3) . . ?
Ag10 C55 Ag6 133.0(4) . . ?
C55 C56 C57 174.7(9) . . ?
C56 C57 C58 109.8(9) . . ?
C56 C57 C60 109.2(8) . . ?
C58 C57 C60 111.9(9) . . ?
C56 C57 C59 108.7(8) . . ?
C58 C57 C59 107.6(9) . . ?
C60 C57 C59 109.5(9) . . ?
C62 C61 Ag7 125.5(7) . . ?
C62 C61 Ag1 147.7(7) . . ?
Ag7 C61 Ag1 81.1(3) . . ?
C62 C61 Ag10 119.5(7) . . ?
Ag7 C61 Ag10 76.5(3) . . ?
Ag1 C61 Ag10 81.4(2) . . ?
C62 C61 Ag5 75.6(5) . . ?
Ag7 C61 Ag5 146.0(4) . . ?
Ag1 C61 Ag5 72.5(2) . . ?
Ag10 C61 Ag5 119.0(3) . . ?
C61 C62 C63 170.1(9) . . ?
C61 C62 Ag5 75.4(5) . . ?
C63 C62 Ag5 114.0(6) . . ?
C62 C63 C65 110.2(11) . . ?
C62 C63 C66 107.3(9) . . ?
C65 C63 C66 105.6(12) . . ?
C62 C63 C64 108.6(11) . . ?
C65 C63 C64 111.9(14) . . ?
C66 C63 C64 113.1(14) . . ?
C68 C67 Ag4 155.1(8) . . ?
C68 C67 Ag11 114.9(7) . . ?
Ag4 C67 Ag11 82.9(3) . . ?
C68 C67 Ag5 96.8(6) . . ?
Ag4 C67 Ag5 80.3(3) . . ?
Ag11 C67 Ag5 134.2(4) . . ?
C67 C68 C69 174.7(10) . . ?
C68 C69 C72 110.2(8) . . ?
C68 C69 C70 108.5(8) . . ?
C72 C69 C70 110.6(10) . . ?
C68 C69 C71 109.0(8) . . ?
C72 C69 C71 109.4(9) . . ?
C70 C69 C71 109.1(8) . . ?
C74 C73 Ag2 149.8(6) . . ?
C74 C73 Ag8 86.1(6) . . ?
Ag2 C73 Ag8 89.6(3) . . ?
C74 C73 Ag1 129.5(6) . . ?
Ag2 C73 Ag1 79.0(2) . . ?
Ag8 C73 Ag1 81.2(3) . . ?
C74 C73 Ag11 115.5(6) . . ?
Ag2 C73 Ag11 77.4(2) . . ?
Ag8 C73 Ag11 155.4(3) . . ?
Ag1 C73 Ag11 75.9(2) . . ?
C73 C74 C75 177.5(9) . . ?
C73 C74 Ag8 64.6(5) . . ?
C75 C74 Ag8 117.9(6) . . ?
C74 C75 C77 109.5(8) . . ?
C74 C75 C76 110.4(7) . . ?
C77 C75 C76 108.7(9) . . ?
C74 C75 C78 110.2(8) . . ?
C77 C75 C78 109.2(10) . . ?
C76 C75 C78 108.8(9) . . ?
C80 C79 Ag12 126.1(7) . . ?
C80 C79 Ag3 149.8(7) . . ?
Ag12 C79 Ag3 79.9(3) . . ?
C80 C79 Ag11 114.2(6) . . ?
Ag12 C79 Ag11 76.8(3) . . ?
Ag3 C79 Ag11 84.1(3) . . ?
C80 C79 Ag6 77.9(5) . . ?
Ag12 C79 Ag6 147.4(3) . . ?
Ag3 C79 Ag6 72.4(2) . . ?
Ag11 C79 Ag6 116.2(3) . . ?
C79 C80 C81 169.2(9) . . ?
C79 C80 Ag6 74.3(5) . . ?
C81 C80 Ag6 116.4(6) . . ?
C80 C81 C82 109.3(8) . . ?
C80 C81 C84 109.8(8) . . ?
C82 C81 C84 109.5(9) . . ?
C80 C81 C83 107.5(8) . . ?
C82 C81 C83 110.8(11) . . ?
C84 C81 C83 109.9(10) . . ?
O6 C85 O5 130.7(9) . . ?
O6 C85 C86 115.9(9) . . ?
O5 C85 C86 113.3(9) . . ?
F5 C86 F6 112.8(13) . . ?
F5 C86 F4 102.3(14) . . ?
F6 C86 F4 98.2(12) . . ?
F5 C86 C85 118.5(11) . . ?
F6 C86 C85 114.3(9) . . ?
F4 C86 C85 107.8(9) . . ?
O3 C87 O4 131.1(9) . . ?
O3 C87 C88 116.9(8) . . ?
O4 C87 C88 112.0(8) . . ?
F1 C88 F2 107.5(10) . . ?
F1 C88 F3 109.7(10) . . ?
F2 C88 F3 104.1(8) . . ?
F1 C88 C87 110.3(8) . . ?
F2 C88 C87 112.6(9) . . ?
F3 C88 C87 112.4(9) . . ?
O8 C89 O7 129.2(9) . . ?
O8 C89 C90 114.8(9) . . ?
O7 C89 C90 115.9(9) . . ?
F8 C90 F9 109.1(16) . . ?
F8 C90 F7 104.3(15) . . ?
F9 C90 F7 100.7(12) . . ?
F8 C90 C89 112.4(10) . . ?
F9 C90 C89 115.0(10) . . ?
F7 C90 C89 114.2(11) . . ?
O10 C91 O9 131.8(10) . . ?
O10 C91 C92 116.0(9) . . ?
O9 C91 C92 112.0(9) . . ?
F12 C92 F10 114(2) . . ?
F12 C92 F11 97.9(15) . . ?
F10 C92 F11 102.0(16) . . ?
F12 C92 C91 115.8(14) . . ?
F10 C92 C91 117.2(14) . . ?
F11 C92 C91 106.3(15) . . ?
O12 C93 O11 130.8(9) . . ?
O12 C93 C94 115.7(9) . . ?
O11 C93 C94 113.5(8) . . ?
F17 C94 F18 109.9(14) . . ?
F17 C94 F16 99.5(16) . . ?
F18 C94 F16 95.1(15) . . ?
F17 C94 C93 121.1(9) . . ?
F18 C94 C93 117.0(9) . . ?
F16 C94 C93 109.4(12) . . ?
O2 C95 O1 128.3(9) . . ?
O2 C95 C96 117.4(9) . . ?
O1 C95 C96 114.2(9) . . ?
F15 C96 F14 105.0(12) . . ?
F15 C96 F13 109.5(11) . . ?
F14 C96 F13 102.9(12) . . ?
F15 C96 C95 112.7(10) . . ?
F14 C96 C95 110.5(10) . . ?
F13 C96 C95 115.3(10) . . ?
O14 C97 C98 109.5(13) . . ?
O13 C99 C100 109.1(14) . . ?
C22 N1 C23 118.9(8) . . ?
C22 N1 Ag7 125.3(7) . . ?
C23 N1 Ag7 115.7(6) . . ?
C13 N2 C24 116.8(9) . . ?
C13 N2 Ag7 128.7(7) . . ?
C24 N2 Ag7 114.1(6) . . ?
C1 N3 C12 118.3(12) . . ?
C1 N3 Ag8 123.8(10) . . ?
C12 N3 Ag8 117.7(8) . . ?
C10 N4 C11 120.7(11) . . ?
C10 N4 Ag8 126.1(10) . . ?
C11 N4 Ag8 113.0(8) . . ?
C37 N5 C48 119.1(8) . . ?
C37 N5 Ag12 125.1(6) . . ?
C48 N5 Ag12 115.3(6) . . ?
C46 N6 C47 117.5(9) . . ?
C46 N6 Ag12 128.2(7) . . ?
C47 N6 Ag12 113.8(6) . . ?
C25 N7 C36 119.3(8) . . ?
C25 N7 Ag9 126.3(6) . . ?
C36 N7 Ag9 114.1(6) . . ?
C34 N8 C35 118.1(8) . . ?
C34 N8 Ag9 126.9(7) . . ?
C35 N8 Ag9 114.7(6) . . ?
C95 O1 Ag10 123.1(6) . . ?
C95 O2 Ag7 121.8(6) . . ?
C87 O4 Ag5 113.7(5) . . ?
C85 O5 Ag5 113.7(6) . . ?
C85 O6 Ag1 128.0(6) . . ?
C89 O7 Ag12 120.8(6) . . ?
C89 O8 Ag11 124.4(6) . . ?
C91 O9 Ag6 115.3(7) . . ?
C93 O11 Ag3 125.6(6) . . ?
C93 O12 Ag6 116.7(6) . . ?

_diffrn_measured_fraction_theta_max 0.967
_diffrn_reflns_theta_full        62.20
_diffrn_measured_fraction_theta_full 0.967
_refine_diff_density_max         2.637
_refine_diff_density_min         -4.004
_refine_diff_density_rms         0.346
