# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ch1jw241_0m
_database_code_depnum_ccdc_archive 'CCDC 1028955'
_audit_update_record             
;
2014-10-13 deposited with the CCDC.
2015-01-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C40 H50 Cl4 N4 O9 Pt2'
_chemical_formula_weight         1262.82

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.6896(8)
_cell_length_b                   14.3617(8)
_cell_length_c                   23.8509(12)
_cell_angle_alpha                90.066(3)
_cell_angle_beta                 91.336(3)
_cell_angle_gamma                104.659(3)
_cell_volume                     4535.2(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    9919
_cell_measurement_theta_min      2.93
_cell_measurement_theta_max      27.35

_exptl_crystal_description       needle
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.43
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.12
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.849
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2456
_exptl_absorpt_coefficient_mu    6.454
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.1679
_exptl_absorpt_correction_T_max  0.5114
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            87085
_diffrn_reflns_av_R_equivalents  0.0785
_diffrn_reflns_av_sigmaI/netI    0.0785
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         0.85
_diffrn_reflns_theta_max         27.66
_reflns_number_total             20800
_reflns_number_gt                15309
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0238P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         20800
_refine_ls_number_parameters     1083
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0660
_refine_ls_R_factor_gt           0.0409
_refine_ls_wR_factor_ref         0.0876
_refine_ls_wR_factor_gt          0.0775
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_restrained_S_all      1.011
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt -0.088365(15) 0.130910(14) 0.507833(8) 0.01631(6) Uani 1 1 d . . .
Pt2 Pt -0.084268(16) 0.328532(14) 1.007242(8) 0.01893(6) Uani 1 1 d . . .
Pt3 Pt 1.081650(15) 0.171610(14) -0.021261(8) 0.01564(6) Uani 1 1 d . . .
Pt4 Pt 1.063547(15) 0.366485(14) 0.479808(8) 0.01521(6) Uani 1 1 d . . .
Cl1 Cl -0.15715(11) 0.25581(9) 1.08709(6) 0.0265(3) Uani 1 1 d . . .
Cl2 Cl -0.23786(10) 0.28154(10) 0.96111(6) 0.0278(3) Uani 1 1 d . . .
Cl3 Cl 1.21954(10) 0.38833(9) 0.52235(5) 0.0209(3) Uani 1 1 d . . .
Cl4 Cl 1.13108(10) 0.32999(9) 0.39806(5) 0.0216(3) Uani 1 1 d . . .
Cl5 Cl -0.24120(10) 0.10487(10) 0.46087(6) 0.0239(3) Uani 1 1 d . . .
Cl6 Cl -0.16292(10) 0.16692(9) 0.58750(5) 0.0232(3) Uani 1 1 d . . .
Cl7 Cl 1.23757(10) 0.22011(9) 0.02213(5) 0.0225(3) Uani 1 1 d . . .
Cl8 Cl 1.15146(10) 0.24196(9) -0.10222(5) 0.0228(3) Uani 1 1 d . . .
N1 N 0.0488(3) 0.1487(3) 0.54412(16) 0.0152(9) Uani 1 1 d . . .
N2 N -0.0138(3) 0.0980(3) 0.44211(16) 0.0154(9) Uani 1 1 d . . .
N3 N 0.0536(3) 0.3769(3) 1.04247(17) 0.0189(10) Uani 1 1 d . . .
N4 N -0.0104(3) 0.3976(3) 0.94115(17) 0.0160(10) Uani 1 1 d . . .
N5 N 1.0117(3) 0.1083(3) 0.04706(17) 0.0146(9) Uani 1 1 d . . .
N6 N 0.9421(3) 0.1203(3) -0.05433(16) 0.0164(10) Uani 1 1 d . . .
N7 N 0.9948(3) 0.3979(3) 0.54851(16) 0.0130(9) Uani 1 1 d . . .
N8 N 0.9234(3) 0.3524(3) 0.44736(16) 0.0156(10) Uani 1 1 d . . .
O1 O 0.4079(3) 0.1502(3) 0.57335(14) 0.0230(9) Uani 1 1 d . . .
O2 O 0.3733(3) 0.2068(3) 0.65635(14) 0.0284(9) Uani 1 1 d . . .
O3 O 0.2620(3) 0.0431(2) 0.32648(13) 0.0196(8) Uani 1 1 d . . .
O4 O 0.1286(3) -0.0027(3) 0.26674(14) 0.0234(9) Uani 1 1 d . . .
O5 O 0.4114(3) 0.5517(3) 1.07183(14) 0.0243(9) Uani 1 1 d . . .
O6 O 0.3791(3) 0.4743(3) 1.15382(14) 0.0294(10) Uani 1 1 d . . .
O7 O 0.2616(3) 0.5904(2) 0.82423(13) 0.0182(8) Uani 1 1 d . . .
O8 O 0.1257(3) 0.5659(3) 0.76529(14) 0.0242(9) Uani 1 1 d . . .
O9 O 0.7432(3) -0.0652(3) 0.17316(14) 0.0210(8) Uani 1 1 d . . .
O10 O 0.8785(3) -0.0238(3) 0.23126(15) 0.0399(12) Uani 1 1 d . . .
O11 O 0.5837(3) -0.0573(3) -0.07568(14) 0.0228(9) Uani 1 1 d . . .
O12 O 0.6088(3) 0.0215(3) -0.15773(14) 0.0270(9) Uani 1 1 d . . .
O13 O 0.7300(3) 0.4276(3) 0.68095(13) 0.0220(9) Uani 1 1 d . . .
O14 O 0.8718(3) 0.4756(3) 0.73312(14) 0.0286(10) Uani 1 1 d . . .
O15 O 0.5663(3) 0.3648(3) 0.42444(14) 0.0222(9) Uani 1 1 d . . .
O16 O 0.5925(3) 0.2967(3) 0.34314(14) 0.0281(10) Uani 1 1 d . . .
C1 C 0.0753(4) 0.1774(4) 0.5974(2) 0.0219(13) Uani 1 1 d . . .
H1 H 0.0254 0.1910 0.6208 0.026 Uiso 1 1 calc R . .
C2 C 0.1708(4) 0.1877(4) 0.6192(2) 0.0201(12) Uani 1 1 d . . .
H2 H 0.1871 0.2101 0.6566 0.024 Uiso 1 1 calc R . .
C3 C 0.2433(4) 0.1650(3) 0.5860(2) 0.0172(12) Uani 1 1 d . . .
C4 C 0.2167(4) 0.1340(3) 0.5305(2) 0.0157(11) Uani 1 1 d . . .
H4 H 0.2648 0.1174 0.5070 0.019 Uiso 1 1 calc R . .
C5 C 0.1211(4) 0.1281(3) 0.5108(2) 0.0146(11) Uani 1 1 d . . .
C6 C 0.0846(4) 0.1001(3) 0.4530(2) 0.0155(11) Uani 1 1 d . . .
C7 C 0.1450(4) 0.0774(3) 0.41159(19) 0.0153(11) Uani 1 1 d . . .
H7 H 0.2136 0.0786 0.4197 0.018 Uiso 1 1 calc R . .
C8 C 0.1039(4) 0.0531(3) 0.3586(2) 0.0157(11) Uani 1 1 d . . .
C9 C 0.0040(4) 0.0505(3) 0.3482(2) 0.0188(12) Uani 1 1 d . . .
H9 H -0.0256 0.0324 0.3121 0.023 Uiso 1 1 calc R . .
C10 C -0.0528(4) 0.0742(3) 0.3901(2) 0.0202(12) Uani 1 1 d . . .
H10 H -0.1213 0.0738 0.3822 0.024 Uiso 1 1 calc R . .
C11 C 0.3483(4) 0.1774(4) 0.6100(2) 0.0181(12) Uani 1 1 d . . .
C12 C 0.5117(4) 0.1556(4) 0.5914(2) 0.0237(13) Uani 1 1 d . . .
H12 H 0.5141 0.1451 0.6328 0.028 Uiso 1 1 calc R . .
C13 C 0.5773(5) 0.2526(4) 0.5782(3) 0.0414(17) Uani 1 1 d . . .
H13A H 0.5755 0.2629 0.5376 0.062 Uiso 1 1 calc R . .
H13B H 0.6468 0.2564 0.5908 0.062 Uiso 1 1 calc R . .
H13C H 0.5525 0.3021 0.5974 0.062 Uiso 1 1 calc R . .
C14 C 0.5411(5) 0.0733(4) 0.5611(3) 0.0422(17) Uani 1 1 d . . .
H14A H 0.4905 0.0128 0.5678 0.063 Uiso 1 1 calc R . .
H14B H 0.6073 0.0680 0.5753 0.063 Uiso 1 1 calc R . .
H14C H 0.5445 0.0862 0.5207 0.063 Uiso 1 1 calc R . .
C15 C 0.1644(4) 0.0263(3) 0.3118(2) 0.0164(11) Uani 1 1 d . . .
C16 C 0.3290(4) 0.0182(4) 0.2842(2) 0.0218(13) Uani 1 1 d . . .
H16 H 0.3073 0.0348 0.2459 0.026 Uiso 1 1 calc R . .
C17 C 0.4326(4) 0.0803(4) 0.2982(2) 0.0313(15) Uani 1 1 d . . .
H17A H 0.4303 0.1479 0.3000 0.047 Uiso 1 1 calc R . .
H17B H 0.4795 0.0723 0.2693 0.047 Uiso 1 1 calc R . .
H17C H 0.4557 0.0612 0.3346 0.047 Uiso 1 1 calc R . .
C18 C 0.3205(4) -0.0889(4) 0.2869(2) 0.0296(14) Uani 1 1 d . . .
H18A H 0.3372 -0.1059 0.3251 0.044 Uiso 1 1 calc R . .
H18B H 0.3674 -0.1058 0.2607 0.044 Uiso 1 1 calc R . .
H18C H 0.2513 -0.1244 0.2768 0.044 Uiso 1 1 calc R . .
C19 C 0.0801(4) 0.3597(4) 1.0955(2) 0.0208(12) Uani 1 1 d . . .
H19 H 0.0306 0.3214 1.1190 0.025 Uiso 1 1 calc R . .
C20 C 0.1769(4) 0.3961(4) 1.1168(2) 0.0232(13) Uani 1 1 d . . .
H20 H 0.1937 0.3817 1.1541 0.028 Uiso 1 1 calc R . .
C21 C 0.2492(4) 0.4532(4) 1.0839(2) 0.0187(12) Uani 1 1 d . . .
C22 C 0.2215(4) 0.4731(3) 1.0291(2) 0.0166(11) Uani 1 1 d . . .
H22 H 0.2690 0.5146 1.0060 0.020 Uiso 1 1 calc R . .
C23 C 0.1243(4) 0.4317(4) 1.0089(2) 0.0161(11) Uani 1 1 d . . .
C24 C 0.0885(4) 0.4437(3) 0.9519(2) 0.0166(12) Uani 1 1 d . . .
C25 C 0.1470(4) 0.4959(3) 0.91036(19) 0.0137(11) Uani 1 1 d . . .
H25 H 0.2156 0.5281 0.9182 0.016 Uiso 1 1 calc R . .
C26 C 0.1050(4) 0.5009(4) 0.8574(2) 0.0172(12) Uani 1 1 d . . .
C27 C 0.0039(4) 0.4538(4) 0.8470(2) 0.0206(12) Uani 1 1 d . . .
H27 H -0.0267 0.4564 0.8111 0.025 Uiso 1 1 calc R . .
C28 C -0.0503(4) 0.4036(4) 0.8900(2) 0.0197(12) Uani 1 1 d . . .
H28 H -0.1192 0.3717 0.8830 0.024 Uiso 1 1 calc R . .
C29 C 0.1637(4) 0.5560(3) 0.8101(2) 0.0161(11) Uani 1 1 d . . .
C30 C 0.3244(4) 0.6484(4) 0.7811(2) 0.0227(13) Uani 1 1 d . . .
H30 H 0.3023 0.6195 0.7433 0.027 Uiso 1 1 calc R . .
C31 C 0.3103(5) 0.7490(4) 0.7831(2) 0.0327(15) Uani 1 1 d . . .
H31A H 0.2394 0.7471 0.7747 0.049 Uiso 1 1 calc R . .
H31B H 0.3532 0.7888 0.7553 0.049 Uiso 1 1 calc R . .
H31C H 0.3291 0.7765 0.8206 0.049 Uiso 1 1 calc R . .
C32 C 0.4296(4) 0.6422(4) 0.7937(2) 0.0349(16) Uani 1 1 d . . .
H32A H 0.4527 0.6733 0.8299 0.052 Uiso 1 1 calc R . .
H32B H 0.4741 0.6746 0.7642 0.052 Uiso 1 1 calc R . .
H32C H 0.4313 0.5744 0.7953 0.052 Uiso 1 1 calc R . .
C33 C 0.3529(4) 0.4931(4) 1.1071(2) 0.0199(12) Uani 1 1 d . . .
C34 C 0.5147(4) 0.5996(4) 1.0913(2) 0.0266(14) Uani 1 1 d . . .
H34 H 0.5157 0.6114 1.1327 0.032 Uiso 1 1 calc R . .
C35 C 0.5407(5) 0.6948(5) 1.0608(3) 0.0490(19) Uani 1 1 d . . .
H35A H 0.5373 0.6829 1.0202 0.073 Uiso 1 1 calc R . .
H35B H 0.6091 0.7310 1.0719 0.073 Uiso 1 1 calc R . .
H35C H 0.4925 0.7320 1.0705 0.073 Uiso 1 1 calc R . .
C36 C 0.5841(5) 0.5374(5) 1.0782(3) 0.0479(19) Uani 1 1 d . . .
H36A H 0.5624 0.4760 1.0979 0.072 Uiso 1 1 calc R . .
H36B H 0.6532 0.5700 1.0904 0.072 Uiso 1 1 calc R . .
H36C H 0.5823 0.5253 1.0377 0.072 Uiso 1 1 calc R . .
C37 C 1.0524(4) 0.1087(4) 0.0985(2) 0.0199(12) Uani 1 1 d . . .
H37 H 1.1215 0.1412 0.1044 0.024 Uiso 1 1 calc R . .
C38 C 0.9993(4) 0.0644(4) 0.1430(2) 0.0170(12) Uani 1 1 d . . .
H38 H 1.0314 0.0652 0.1788 0.020 Uiso 1 1 calc R . .
C39 C 0.8982(4) 0.0183(3) 0.1353(2) 0.0161(11) Uani 1 1 d . . .
C40 C 0.8550(4) 0.0152(3) 0.0821(2) 0.0183(12) Uani 1 1 d . . .
H40 H 0.7864 -0.0183 0.0756 0.022 Uiso 1 1 calc R . .
C41 C 0.9126(4) 0.0616(3) 0.0383(2) 0.0158(11) Uani 1 1 d . . .
C42 C 0.8736(4) 0.0684(3) -0.0189(2) 0.0157(11) Uani 1 1 d . . .
C43 C 0.7747(4) 0.0263(3) -0.03682(19) 0.0155(11) Uani 1 1 d . . .
H43 H 0.7280 -0.0124 -0.0121 0.019 Uiso 1 1 calc R . .
C44 C 0.7455(4) 0.0419(4) -0.0918(2) 0.0182(12) Uani 1 1 d . . .
C45 C 0.8146(4) 0.0946(4) -0.1270(2) 0.0236(13) Uani 1 1 d . . .
H45 H 0.7954 0.1053 -0.1645 0.028 Uiso 1 1 calc R . .
C46 C 0.9135(4) 0.1329(4) -0.1078(2) 0.0192(12) Uani 1 1 d . . .
H46 H 0.9619 0.1684 -0.1328 0.023 Uiso 1 1 calc R . .
C47 C 0.6397(4) 0.0026(4) -0.1128(2) 0.0207(12) Uani 1 1 d . . .
C48 C 0.4797(4) -0.1055(4) -0.0924(2) 0.0254(13) Uani 1 1 d . . .
H48 H 0.4752 -0.1173 -0.1338 0.030 Uiso 1 1 calc R . .
C49 C 0.4121(4) -0.0417(5) -0.0769(3) 0.0402(17) Uani 1 1 d . . .
H49A H 0.4205 -0.0262 -0.0368 0.060 Uiso 1 1 calc R . .
H49B H 0.3416 -0.0753 -0.0854 0.060 Uiso 1 1 calc R . .
H49C H 0.4302 0.0179 -0.0986 0.060 Uiso 1 1 calc R . .
C50 C 0.4547(5) -0.1998(5) -0.0622(2) 0.0414(17) Uani 1 1 d . . .
H50A H 0.5041 -0.2360 -0.0712 0.062 Uiso 1 1 calc R . .
H50B H 0.3869 -0.2371 -0.0739 0.062 Uiso 1 1 calc R . .
H50C H 0.4566 -0.1880 -0.0216 0.062 Uiso 1 1 calc R . .
C51 C 0.8393(4) -0.0263(4) 0.1854(2) 0.0181(12) Uani 1 1 d . . .
C52 C 0.6801(4) -0.1059(4) 0.2210(2) 0.0287(14) Uani 1 1 d . . .
H52 H 0.7225 -0.1285 0.2501 0.034 Uiso 1 1 calc R . .
C53 C 0.6024(5) -0.1915(5) 0.1964(3) 0.062(2) Uani 1 1 d . . .
H53A H 0.5541 -0.1688 0.1726 0.093 Uiso 1 1 calc R . .
H53B H 0.5665 -0.2306 0.2269 0.093 Uiso 1 1 calc R . .
H53C H 0.6363 -0.2306 0.1740 0.093 Uiso 1 1 calc R . .
C54 C 0.6375(5) -0.0307(5) 0.2452(3) 0.062(2) Uani 1 1 d . . .
H54A H 0.6923 0.0213 0.2607 0.093 Uiso 1 1 calc R . .
H54B H 0.5913 -0.0584 0.2751 0.093 Uiso 1 1 calc R . .
H54C H 0.6006 -0.0050 0.2159 0.093 Uiso 1 1 calc R . .
C55 C 1.0384(4) 0.4181(4) 0.5991(2) 0.0198(12) Uani 1 1 d . . .
H55 H 1.1078 0.4191 0.6041 0.024 Uiso 1 1 calc R . .
C56 C 0.9864(4) 0.4375(3) 0.6444(2) 0.0185(12) Uani 1 1 d . . .
H56 H 1.0198 0.4530 0.6799 0.022 Uiso 1 1 calc R . .
C57 C 0.8846(4) 0.4340(4) 0.6378(2) 0.0173(12) Uani 1 1 d . . .
C58 C 0.8390(4) 0.4146(3) 0.58483(19) 0.0158(11) Uani 1 1 d . . .
H58 H 0.7700 0.4140 0.5788 0.019 Uiso 1 1 calc R . .
C59 C 0.8959(4) 0.3962(3) 0.5413(2) 0.0157(11) Uani 1 1 d . . .
C60 C 0.8554(4) 0.3718(4) 0.4835(2) 0.0170(12) Uani 1 1 d . . .
C61 C 0.7578(4) 0.3684(3) 0.4656(2) 0.0178(12) Uani 1 1 d . . .
H61 H 0.7117 0.3848 0.4906 0.021 Uiso 1 1 calc R . .
C62 C 0.7275(4) 0.3407(4) 0.4108(2) 0.0177(12) Uani 1 1 d . . .
C63 C 0.7974(4) 0.3199(4) 0.3751(2) 0.0196(12) Uani 1 1 d . . .
H63 H 0.7783 0.3010 0.3374 0.023 Uiso 1 1 calc R . .
C64 C 0.8938(4) 0.3267(4) 0.3940(2) 0.0220(13) Uani 1 1 d . . .
H64 H 0.9413 0.3129 0.3689 0.026 Uiso 1 1 calc R . .
C65 C 0.6223(4) 0.3308(4) 0.3887(2) 0.0218(13) Uani 1 1 d . . .
C66 C 0.4611(4) 0.3599(4) 0.4065(2) 0.0239(13) Uani 1 1 d . . .
H66 H 0.4564 0.3622 0.3647 0.029 Uiso 1 1 calc R . .
C67 C 0.4371(4) 0.4481(4) 0.4311(2) 0.0319(15) Uani 1 1 d . . .
H67A H 0.4382 0.4441 0.4722 0.048 Uiso 1 1 calc R . .
H67B H 0.3699 0.4517 0.4179 0.048 Uiso 1 1 calc R . .
H67C H 0.4875 0.5057 0.4194 0.048 Uiso 1 1 calc R . .
C68 C 0.3942(4) 0.2672(4) 0.4267(3) 0.0365(16) Uani 1 1 d . . .
H68A H 0.4144 0.2130 0.4097 0.055 Uiso 1 1 calc R . .
H68B H 0.3239 0.2640 0.4160 0.055 Uiso 1 1 calc R . .
H68C H 0.4007 0.2640 0.4676 0.055 Uiso 1 1 calc R . .
C69 C 0.8294(4) 0.4496(4) 0.6889(2) 0.0186(12) Uani 1 1 d . . .
C70 C 0.6707(4) 0.4299(4) 0.7314(2) 0.0256(13) Uani 1 1 d . . .
H70 H 0.7051 0.4865 0.7553 0.031 Uiso 1 1 calc R . .
C71 C 0.6645(5) 0.3381(4) 0.7638(3) 0.0445(18) Uani 1 1 d . . .
H71A H 0.6295 0.2827 0.7407 0.067 Uiso 1 1 calc R . .
H71B H 0.6271 0.3393 0.7982 0.067 Uiso 1 1 calc R . .
H71C H 0.7328 0.3327 0.7735 0.067 Uiso 1 1 calc R . .
C72 C 0.5688(4) 0.4406(5) 0.7122(2) 0.0455(19) Uani 1 1 d . . .
H72A H 0.5767 0.5022 0.6930 0.068 Uiso 1 1 calc R . .
H72B H 0.5260 0.4388 0.7448 0.068 Uiso 1 1 calc R . .
H72C H 0.5373 0.3879 0.6864 0.068 Uiso 1 1 calc R . .
O1S O 0.1606(3) 0.2349(3) 0.21408(15) 0.0312(10) Uani 1 1 d . . .
O2S O 0.1411(3) 0.3397(3) 0.71393(16) 0.0345(10) Uani 1 1 d . . .
C1S C 0.3062(4) 0.1981(4) 0.1753(2) 0.0348(15) Uani 1 1 d . . .
H1AA H 0.2626 0.1335 0.1680 0.052 Uiso 1 1 calc R . .
H1AB H 0.3749 0.1934 0.1846 0.052 Uiso 1 1 calc R . .
H1AC H 0.3072 0.2378 0.1419 0.052 Uiso 1 1 calc R . .
C2S C 0.2659(4) 0.2437(4) 0.2241(2) 0.0330(15) Uani 1 1 d . . .
H2AA H 0.2762 0.2110 0.2594 0.040 Uiso 1 1 calc R . .
H2AB H 0.3023 0.3124 0.2277 0.040 Uiso 1 1 calc R . .
C3S C 0.1177(5) 0.2724(4) 0.2572(2) 0.0393(17) Uani 1 1 d . . .
H3AA H 0.1496 0.3422 0.2609 0.047 Uiso 1 1 calc R . .
H3AB H 0.1296 0.2412 0.2928 0.047 Uiso 1 1 calc R . .
C4S C 0.0039(6) 0.2565(6) 0.2465(3) 0.063(2) Uani 1 1 d . . .
H4AA H -0.0084 0.2766 0.2082 0.095 Uiso 1 1 calc R . .
H4AB H -0.0230 0.2946 0.2734 0.095 Uiso 1 1 calc R . .
H4AC H -0.0296 0.1881 0.2509 0.095 Uiso 1 1 calc R . .
C5S C 0.2939(5) 0.4419(4) 0.6785(2) 0.0392(16) Uani 1 1 d . . .
H5AA H 0.2869 0.4053 0.6433 0.059 Uiso 1 1 calc R . .
H5AB H 0.3657 0.4693 0.6874 0.059 Uiso 1 1 calc R . .
H5AC H 0.2599 0.4940 0.6744 0.059 Uiso 1 1 calc R . .
C6S C 0.2463(5) 0.3755(4) 0.7255(2) 0.0412(17) Uani 1 1 d . . .
H6AA H 0.2785 0.3212 0.7286 0.049 Uiso 1 1 calc R . .
H6AB H 0.2571 0.4111 0.7616 0.049 Uiso 1 1 calc R . .
C7S C 0.0929(6) 0.2756(5) 0.7554(2) 0.048(2) Uani 1 1 d . . .
H7AA H 0.1085 0.3060 0.7929 0.058 Uiso 1 1 calc R . .
H7AB H 0.1178 0.2166 0.7548 0.058 Uiso 1 1 calc R . .
C8S C -0.0212(6) 0.2494(5) 0.7440(2) 0.053(2) Uani 1 1 d . . .
H8AA H -0.0468 0.3066 0.7491 0.080 Uiso 1 1 calc R . .
H8AB H -0.0542 0.1994 0.7702 0.080 Uiso 1 1 calc R . .
H8AC H -0.0358 0.2254 0.7055 0.080 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N1 2.005(4) . ?
Pt1 N2 2.010(4) . ?
Pt1 Cl5 2.2947(13) . ?
Pt1 Cl6 2.2968(12) . ?
Pt2 N3 2.003(4) . ?
Pt2 N4 2.016(4) . ?
Pt2 Cl2 2.2934(14) . ?
Pt2 Cl1 2.2975(13) . ?
Pt3 N6 2.008(4) . ?
Pt3 N5 2.008(4) . ?
Pt3 Cl7 2.2925(13) . ?
Pt3 Cl8 2.2945(12) . ?
Pt4 N8 2.014(4) . ?
Pt4 N7 2.015(4) . ?
Pt4 Cl3 2.2907(13) . ?
Pt4 Cl4 2.2930(12) . ?
N1 C1 1.347(6) . ?
N1 C5 1.373(6) . ?
N2 C10 1.348(6) . ?
N2 C6 1.359(6) . ?
N3 C19 1.349(6) . ?
N3 C23 1.360(6) . ?
N4 C28 1.338(6) . ?
N4 C24 1.366(6) . ?
N5 C37 1.334(6) . ?
N5 C41 1.364(6) . ?
N6 C46 1.351(6) . ?
N6 C42 1.354(6) . ?
N7 C55 1.333(6) . ?
N7 C59 1.355(6) . ?
N8 C64 1.349(6) . ?
N8 C60 1.361(6) . ?
O1 C11 1.332(6) . ?
O1 C12 1.458(6) . ?
O2 C11 1.195(6) . ?
O3 C15 1.335(6) . ?
O3 C16 1.481(5) . ?
O4 C15 1.200(6) . ?
O5 C33 1.322(6) . ?
O5 C34 1.472(6) . ?
O6 C33 1.214(6) . ?
O7 C29 1.340(6) . ?
O7 C30 1.475(6) . ?
O8 C29 1.202(6) . ?
O9 C51 1.318(6) . ?
O9 C52 1.478(6) . ?
O10 C51 1.204(6) . ?
O11 C47 1.345(6) . ?
O11 C48 1.463(6) . ?
O12 C47 1.200(6) . ?
O13 C69 1.326(6) . ?
O13 C70 1.473(6) . ?
O14 C69 1.203(6) . ?
O15 C65 1.332(6) . ?
O15 C66 1.476(6) . ?
O16 C65 1.209(6) . ?
C1 C2 1.369(7) . ?
C1 H1 0.9500 . ?
C2 C3 1.385(7) . ?
C2 H2 0.9500 . ?
C3 C4 1.406(7) . ?
C3 C11 1.502(7) . ?
C4 C5 1.362(7) . ?
C4 H4 0.9500 . ?
C5 C6 1.475(7) . ?
C6 C7 1.392(6) . ?
C7 C8 1.379(7) . ?
C7 H7 0.9500 . ?
C8 C9 1.375(7) . ?
C8 C15 1.511(7) . ?
C9 C10 1.374(7) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C12 C13 1.492(7) . ?
C12 C14 1.528(7) . ?
C12 H12 1.0000 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C16 C17 1.502(7) . ?
C16 C18 1.516(7) . ?
C16 H16 1.0000 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 C20 1.380(7) . ?
C19 H19 0.9500 . ?
C20 C21 1.375(7) . ?
C20 H20 0.9500 . ?
C21 C22 1.402(7) . ?
C21 C33 1.483(7) . ?
C22 C23 1.388(7) . ?
C22 H22 0.9500 . ?
C23 C24 1.460(7) . ?
C24 C25 1.385(7) . ?
C25 C26 1.386(6) . ?
C25 H25 0.9500 . ?
C26 C27 1.394(7) . ?
C26 C29 1.505(7) . ?
C27 C28 1.373(7) . ?
C27 H27 0.9500 . ?
C28 H28 0.9500 . ?
C30 C32 1.490(7) . ?
C30 C31 1.506(7) . ?
C30 H30 1.0000 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C34 C36 1.498(8) . ?
C34 C35 1.514(8) . ?
C34 H34 1.0000 . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 C38 1.366(7) . ?
C37 H37 0.9500 . ?
C38 C39 1.382(7) . ?
C38 H38 0.9500 . ?
C39 C40 1.383(7) . ?
C39 C51 1.506(7) . ?
C40 C41 1.390(7) . ?
C40 H40 0.9500 . ?
C41 C42 1.466(7) . ?
C42 C43 1.393(7) . ?
C43 C44 1.397(6) . ?
C43 H43 0.9500 . ?
C44 C45 1.360(7) . ?
C44 C47 1.490(7) . ?
C45 C46 1.393(7) . ?
C45 H45 0.9500 . ?
C46 H46 0.9500 . ?
C48 C50 1.501(7) . ?
C48 C49 1.508(8) . ?
C48 H48 1.0000 . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C52 C54 1.474(8) . ?
C52 C53 1.515(8) . ?
C52 H52 1.0000 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 C56 1.373(7) . ?
C55 H55 0.9500 . ?
C56 C57 1.388(7) . ?
C56 H56 0.9500 . ?
C57 C58 1.392(6) . ?
C57 C69 1.495(7) . ?
C58 C59 1.378(6) . ?
C58 H58 0.9500 . ?
C59 C60 1.481(6) . ?
C60 C61 1.383(7) . ?
C61 C62 1.390(7) . ?
C61 H61 0.9500 . ?
C62 C63 1.382(7) . ?
C62 C65 1.494(7) . ?
C63 C64 1.365(7) . ?
C63 H63 0.9500 . ?
C64 H64 0.9500 . ?
C66 C68 1.499(7) . ?
C66 C67 1.509(7) . ?
C66 H66 1.0000 . ?
C67 H67A 0.9800 . ?
C67 H67B 0.9800 . ?
C67 H67C 0.9800 . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C70 C72 1.502(7) . ?
C70 C71 1.514(7) . ?
C70 H70 1.0000 . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
O1S C3S 1.372(6) . ?
O1S C2S 1.428(6) . ?
O2S C7S 1.409(7) . ?
O2S C6S 1.422(7) . ?
C1S C2S 1.516(7) . ?
C1S H1AA 0.9800 . ?
C1S H1AB 0.9800 . ?
C1S H1AC 0.9800 . ?
C2S H2AA 0.9900 . ?
C2S H2AB 0.9900 . ?
C3S C4S 1.531(9) . ?
C3S H3AA 0.9900 . ?
C3S H3AB 0.9900 . ?
C4S H4AA 0.9800 . ?
C4S H4AB 0.9800 . ?
C4S H4AC 0.9800 . ?
C5S C6S 1.522(8) . ?
C5S H5AA 0.9800 . ?
C5S H5AB 0.9800 . ?
C5S H5AC 0.9800 . ?
C6S H6AA 0.9900 . ?
C6S H6AB 0.9900 . ?
C7S C8S 1.529(9) . ?
C7S H7AA 0.9900 . ?
C7S H7AB 0.9900 . ?
C8S H8AA 0.9800 . ?
C8S H8AB 0.9800 . ?
C8S H8AC 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pt1 N2 80.76(16) . . ?
N1 Pt1 Cl5 175.73(12) . . ?
N2 Pt1 Cl5 95.08(12) . . ?
N1 Pt1 Cl6 94.77(12) . . ?
N2 Pt1 Cl6 175.35(12) . . ?
Cl5 Pt1 Cl6 89.36(5) . . ?
N3 Pt2 N4 80.41(16) . . ?
N3 Pt2 Cl2 175.39(12) . . ?
N4 Pt2 Cl2 95.12(12) . . ?
N3 Pt2 Cl1 94.98(12) . . ?
N4 Pt2 Cl1 175.30(13) . . ?
Cl2 Pt2 Cl1 89.47(5) . . ?
N6 Pt3 N5 80.72(16) . . ?
N6 Pt3 Cl7 175.13(12) . . ?
N5 Pt3 Cl7 94.84(12) . . ?
N6 Pt3 Cl8 95.59(12) . . ?
N5 Pt3 Cl8 176.27(12) . . ?
Cl7 Pt3 Cl8 88.87(5) . . ?
N8 Pt4 N7 80.42(16) . . ?
N8 Pt4 Cl3 175.70(11) . . ?
N7 Pt4 Cl3 95.42(12) . . ?
N8 Pt4 Cl4 95.44(11) . . ?
N7 Pt4 Cl4 175.86(12) . . ?
Cl3 Pt4 Cl4 88.71(5) . . ?
C1 N1 C5 118.1(4) . . ?
C1 N1 Pt1 126.4(3) . . ?
C5 N1 Pt1 115.5(3) . . ?
C10 N2 C6 119.1(4) . . ?
C10 N2 Pt1 126.0(4) . . ?
C6 N2 Pt1 114.9(3) . . ?
C19 N3 C23 119.1(5) . . ?
C19 N3 Pt2 125.4(3) . . ?
C23 N3 Pt2 115.4(3) . . ?
C28 N4 C24 119.1(4) . . ?
C28 N4 Pt2 126.0(4) . . ?
C24 N4 Pt2 114.9(3) . . ?
C37 N5 C41 118.8(4) . . ?
C37 N5 Pt3 126.6(3) . . ?
C41 N5 Pt3 114.6(3) . . ?
C46 N6 C42 119.4(4) . . ?
C46 N6 Pt3 125.4(3) . . ?
C42 N6 Pt3 115.2(3) . . ?
C55 N7 C59 119.2(4) . . ?
C55 N7 Pt4 125.3(4) . . ?
C59 N7 Pt4 115.5(3) . . ?
C64 N8 C60 119.4(5) . . ?
C64 N8 Pt4 125.3(4) . . ?
C60 N8 Pt4 115.3(3) . . ?
C11 O1 C12 117.6(4) . . ?
C15 O3 C16 116.3(4) . . ?
C33 O5 C34 117.5(4) . . ?
C29 O7 C30 115.5(4) . . ?
C51 O9 C52 115.6(4) . . ?
C47 O11 C48 117.6(4) . . ?
C69 O13 C70 115.7(4) . . ?
C65 O15 C66 116.9(4) . . ?
N1 C1 C2 123.0(5) . . ?
N1 C1 H1 118.5 . . ?
C2 C1 H1 118.5 . . ?
C1 C2 C3 119.0(5) . . ?
C1 C2 H2 120.5 . . ?
C3 C2 H2 120.5 . . ?
C2 C3 C4 118.7(5) . . ?
C2 C3 C11 118.9(5) . . ?
C4 C3 C11 122.4(5) . . ?
C5 C4 C3 119.3(5) . . ?
C5 C4 H4 120.3 . . ?
C3 C4 H4 120.3 . . ?
C4 C5 N1 121.8(5) . . ?
C4 C5 C6 124.8(5) . . ?
N1 C5 C6 113.4(4) . . ?
N2 C6 C7 121.1(4) . . ?
N2 C6 C5 115.3(4) . . ?
C7 C6 C5 123.6(5) . . ?
C8 C7 C6 119.1(5) . . ?
C8 C7 H7 120.5 . . ?
C6 C7 H7 120.5 . . ?
C9 C8 C7 119.2(5) . . ?
C9 C8 C15 118.7(4) . . ?
C7 C8 C15 122.0(5) . . ?
C10 C9 C8 119.9(5) . . ?
C10 C9 H9 120.0 . . ?
C8 C9 H9 120.0 . . ?
N2 C10 C9 121.6(5) . . ?
N2 C10 H10 119.2 . . ?
C9 C10 H10 119.2 . . ?
O2 C11 O1 125.2(5) . . ?
O2 C11 C3 123.4(5) . . ?
O1 C11 C3 111.4(4) . . ?
O1 C12 C13 109.5(5) . . ?
O1 C12 C14 105.8(4) . . ?
C13 C12 C14 113.6(5) . . ?
O1 C12 H12 109.3 . . ?
C13 C12 H12 109.3 . . ?
C14 C12 H12 109.3 . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C12 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C12 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
O4 C15 O3 125.1(5) . . ?
O4 C15 C8 123.5(5) . . ?
O3 C15 C8 111.3(4) . . ?
O3 C16 C17 105.5(4) . . ?
O3 C16 C18 108.6(4) . . ?
C17 C16 C18 114.3(5) . . ?
O3 C16 H16 109.4 . . ?
C17 C16 H16 109.4 . . ?
C18 C16 H16 109.4 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C16 C18 H18A 109.5 . . ?
C16 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C16 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N3 C19 C20 121.9(5) . . ?
N3 C19 H19 119.1 . . ?
C20 C19 H19 119.1 . . ?
C21 C20 C19 120.1(5) . . ?
C21 C20 H20 120.0 . . ?
C19 C20 H20 120.0 . . ?
C20 C21 C22 118.3(5) . . ?
C20 C21 C33 119.9(5) . . ?
C22 C21 C33 121.8(5) . . ?
C23 C22 C21 119.5(5) . . ?
C23 C22 H22 120.2 . . ?
C21 C22 H22 120.2 . . ?
N3 C23 C22 121.0(5) . . ?
N3 C23 C24 114.7(5) . . ?
C22 C23 C24 124.3(5) . . ?
N4 C24 C25 120.6(5) . . ?
N4 C24 C23 114.5(4) . . ?
C25 C24 C23 124.9(5) . . ?
C24 C25 C26 119.7(5) . . ?
C24 C25 H25 120.1 . . ?
C26 C25 H25 120.1 . . ?
C25 C26 C27 119.1(5) . . ?
C25 C26 C29 122.8(5) . . ?
C27 C26 C29 118.1(5) . . ?
C28 C27 C26 118.4(5) . . ?
C28 C27 H27 120.8 . . ?
C26 C27 H27 120.8 . . ?
N4 C28 C27 123.0(5) . . ?
N4 C28 H28 118.5 . . ?
C27 C28 H28 118.5 . . ?
O8 C29 O7 125.4(5) . . ?
O8 C29 C26 122.8(5) . . ?
O7 C29 C26 111.8(4) . . ?
O7 C30 C32 105.8(4) . . ?
O7 C30 C31 108.7(4) . . ?
C32 C30 C31 114.4(5) . . ?
O7 C30 H30 109.3 . . ?
C32 C30 H30 109.3 . . ?
C31 C30 H30 109.3 . . ?
C30 C31 H31A 109.5 . . ?
C30 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C30 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C30 C32 H32A 109.5 . . ?
C30 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C30 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
O6 C33 O5 124.7(5) . . ?
O6 C33 C21 122.7(5) . . ?
O5 C33 C21 112.6(4) . . ?
O5 C34 C36 109.6(5) . . ?
O5 C34 C35 105.0(4) . . ?
C36 C34 C35 113.0(5) . . ?
O5 C34 H34 109.7 . . ?
C36 C34 H34 109.7 . . ?
C35 C34 H34 109.7 . . ?
C34 C35 H35A 109.5 . . ?
C34 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C34 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C34 C36 H36A 109.5 . . ?
C34 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C34 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
N5 C37 C38 123.0(5) . . ?
N5 C37 H37 118.5 . . ?
C38 C37 H37 118.5 . . ?
C37 C38 C39 119.2(5) . . ?
C37 C38 H38 120.4 . . ?
C39 C38 H38 120.4 . . ?
C38 C39 C40 118.8(5) . . ?
C38 C39 C51 118.6(4) . . ?
C40 C39 C51 122.6(5) . . ?
C39 C40 C41 119.6(5) . . ?
C39 C40 H40 120.2 . . ?
C41 C40 H40 120.2 . . ?
N5 C41 C40 120.6(5) . . ?
N5 C41 C42 114.8(4) . . ?
C40 C41 C42 124.5(5) . . ?
N6 C42 C43 121.2(5) . . ?
N6 C42 C41 114.5(4) . . ?
C43 C42 C41 124.2(5) . . ?
C42 C43 C44 118.8(5) . . ?
C42 C43 H43 120.6 . . ?
C44 C43 H43 120.6 . . ?
C45 C44 C43 119.6(5) . . ?
C45 C44 C47 119.0(5) . . ?
C43 C44 C47 121.4(5) . . ?
C44 C45 C46 119.7(5) . . ?
C44 C45 H45 120.1 . . ?
C46 C45 H45 120.1 . . ?
N6 C46 C45 121.3(5) . . ?
N6 C46 H46 119.4 . . ?
C45 C46 H46 119.4 . . ?
O12 C47 O11 124.3(5) . . ?
O12 C47 C44 123.8(5) . . ?
O11 C47 C44 111.9(4) . . ?
O11 C48 C50 106.2(4) . . ?
O11 C48 C49 108.8(5) . . ?
C50 C48 C49 112.8(5) . . ?
O11 C48 H48 109.7 . . ?
C50 C48 H48 109.7 . . ?
C49 C48 H48 109.7 . . ?
C48 C49 H49A 109.5 . . ?
C48 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C48 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
C48 C50 H50A 109.5 . . ?
C48 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
C48 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
O10 C51 O9 125.4(5) . . ?
O10 C51 C39 121.6(5) . . ?
O9 C51 C39 113.0(4) . . ?
C54 C52 O9 108.9(5) . . ?
C54 C52 C53 114.6(6) . . ?
O9 C52 C53 104.5(5) . . ?
C54 C52 H52 109.6 . . ?
O9 C52 H52 109.6 . . ?
C53 C52 H52 109.6 . . ?
C52 C53 H53A 109.5 . . ?
C52 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C52 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C52 C54 H54A 109.5 . . ?
C52 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C52 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
N7 C55 C56 122.2(5) . . ?
N7 C55 H55 118.9 . . ?
C56 C55 H55 118.9 . . ?
C55 C56 C57 119.2(5) . . ?
C55 C56 H56 120.4 . . ?
C57 C56 H56 120.4 . . ?
C56 C57 C58 118.9(4) . . ?
C56 C57 C69 117.4(4) . . ?
C58 C57 C69 123.7(5) . . ?
C59 C58 C57 118.7(5) . . ?
C59 C58 H58 120.6 . . ?
C57 C58 H58 120.6 . . ?
N7 C59 C58 121.8(4) . . ?
N7 C59 C60 114.4(4) . . ?
C58 C59 C60 123.8(5) . . ?
N8 C60 C61 120.8(4) . . ?
N8 C60 C59 114.4(4) . . ?
C61 C60 C59 124.9(5) . . ?
C60 C61 C62 119.5(5) . . ?
C60 C61 H61 120.2 . . ?
C62 C61 H61 120.2 . . ?
C63 C62 C61 118.6(5) . . ?
C63 C62 C65 118.3(5) . . ?
C61 C62 C65 123.1(5) . . ?
C64 C63 C62 120.0(5) . . ?
C64 C63 H63 120.0 . . ?
C62 C63 H63 120.0 . . ?
N8 C64 C63 121.7(5) . . ?
N8 C64 H64 119.2 . . ?
C63 C64 H64 119.2 . . ?
O16 C65 O15 124.3(5) . . ?
O16 C65 C62 123.4(5) . . ?
O15 C65 C62 112.3(4) . . ?
O15 C66 C68 108.8(4) . . ?
O15 C66 C67 105.8(4) . . ?
C68 C66 C67 113.6(5) . . ?
O15 C66 H66 109.5 . . ?
C68 C66 H66 109.5 . . ?
C67 C66 H66 109.5 . . ?
C66 C67 H67A 109.5 . . ?
C66 C67 H67B 109.5 . . ?
H67A C67 H67B 109.5 . . ?
C66 C67 H67C 109.5 . . ?
H67A C67 H67C 109.5 . . ?
H67B C67 H67C 109.5 . . ?
C66 C68 H68A 109.5 . . ?
C66 C68 H68B 109.5 . . ?
H68A C68 H68B 109.5 . . ?
C66 C68 H68C 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
O14 C69 O13 124.2(5) . . ?
O14 C69 C57 122.7(5) . . ?
O13 C69 C57 113.1(4) . . ?
O13 C70 C72 107.4(4) . . ?
O13 C70 C71 108.4(4) . . ?
C72 C70 C71 112.7(5) . . ?
O13 C70 H70 109.5 . . ?
C72 C70 H70 109.5 . . ?
C71 C70 H70 109.5 . . ?
C70 C71 H71A 109.5 . . ?
C70 C71 H71B 109.5 . . ?
H71A C71 H71B 109.5 . . ?
C70 C71 H71C 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
C70 C72 H72A 109.5 . . ?
C70 C72 H72B 109.5 . . ?
H72A C72 H72B 109.5 . . ?
C70 C72 H72C 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
C3S O1S C2S 112.3(4) . . ?
C7S O2S C6S 112.3(5) . . ?
C2S C1S H1AA 109.5 . . ?
C2S C1S H1AB 109.5 . . ?
H1AA C1S H1AB 109.5 . . ?
C2S C1S H1AC 109.5 . . ?
H1AA C1S H1AC 109.5 . . ?
H1AB C1S H1AC 109.5 . . ?
O1S C2S C1S 108.7(4) . . ?
O1S C2S H2AA 110.0 . . ?
C1S C2S H2AA 110.0 . . ?
O1S C2S H2AB 110.0 . . ?
C1S C2S H2AB 110.0 . . ?
H2AA C2S H2AB 108.3 . . ?
O1S C3S C4S 110.7(5) . . ?
O1S C3S H3AA 109.5 . . ?
C4S C3S H3AA 109.5 . . ?
O1S C3S H3AB 109.5 . . ?
C4S C3S H3AB 109.5 . . ?
H3AA C3S H3AB 108.1 . . ?
C3S C4S H4AA 109.5 . . ?
C3S C4S H4AB 109.5 . . ?
H4AA C4S H4AB 109.5 . . ?
C3S C4S H4AC 109.5 . . ?
H4AA C4S H4AC 109.5 . . ?
H4AB C4S H4AC 109.5 . . ?
C6S C5S H5AA 109.5 . . ?
C6S C5S H5AB 109.5 . . ?
H5AA C5S H5AB 109.5 . . ?
C6S C5S H5AC 109.5 . . ?
H5AA C5S H5AC 109.5 . . ?
H5AB C5S H5AC 109.5 . . ?
O2S C6S C5S 109.5(5) . . ?
O2S C6S H6AA 109.8 . . ?
C5S C6S H6AA 109.8 . . ?
O2S C6S H6AB 109.8 . . ?
C5S C6S H6AB 109.8 . . ?
H6AA C6S H6AB 108.2 . . ?
O2S C7S C8S 109.4(5) . . ?
O2S C7S H7AA 109.8 . . ?
C8S C7S H7AA 109.8 . . ?
O2S C7S H7AB 109.8 . . ?
C8S C7S H7AB 109.8 . . ?
H7AA C7S H7AB 108.2 . . ?
C7S C8S H8AA 109.5 . . ?
C7S C8S H8AB 109.5 . . ?
H8AA C8S H8AB 109.5 . . ?
C7S C8S H8AC 109.5 . . ?
H8AA C8S H8AC 109.5 . . ?
H8AB C8S H8AC 109.5 . . ?

_diffrn_measured_fraction_theta_max 0.983
_diffrn_reflns_theta_full        27.66
_diffrn_measured_fraction_theta_full 0.983
_refine_diff_density_max         1.377
_refine_diff_density_min         -2.041
_refine_diff_density_rms         0.207
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ch1jw252p-1
_database_code_depnum_ccdc_archive 'CCDC 1028956'
_audit_update_record             
;
2014-10-13 deposited with the CCDC.
2015-01-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C24 H26 N2 O7 Pt'
_chemical_formula_weight         649.56

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   6.6241(3)
_cell_length_b                   10.9966(4)
_cell_length_c                   17.2394(7)
_cell_angle_alpha                100.0200(10)
_cell_angle_beta                 95.6330(10)
_cell_angle_gamma                101.8470(10)
_cell_volume                     1198.53(8)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9991
_cell_measurement_theta_min      2.42
_cell_measurement_theta_max      27.47

_exptl_crystal_description       plate
_exptl_crystal_colour            black
_exptl_crystal_size_max          0.43
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.11
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.800
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             636
_exptl_absorpt_coefficient_mu    5.900
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.1858
_exptl_absorpt_correction_T_max  0.5630
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            15762
_diffrn_reflns_av_R_equivalents  0.0276
_diffrn_reflns_av_sigmaI/netI    0.0300
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.21
_diffrn_reflns_theta_max         27.47
_reflns_number_total             5273
_reflns_number_gt                5048
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0462P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5273
_refine_ls_number_parameters     311
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0232
_refine_ls_R_factor_gt           0.0213
_refine_ls_wR_factor_ref         0.0699
_refine_ls_wR_factor_gt          0.0633
_refine_ls_goodness_of_fit_ref   1.146
_refine_ls_restrained_S_all      1.146
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.268079(16) 1.028997(10) 0.455839(6) 0.01032(6) Uani 1 1 d . . .
O1 O 0.0855(4) 0.6451(2) 0.72458(14) 0.0170(5) Uani 1 1 d . . .
O2 O -0.1574(4) 0.5201(2) 0.62590(15) 0.0224(6) Uani 1 1 d . . .
O3 O 0.6076(5) 1.4071(3) 0.83817(16) 0.0280(7) Uani 1 1 d . . .
O4 O 0.4240(4) 1.2222(2) 0.85942(14) 0.0201(5) Uani 1 1 d . . .
O5 O 0.1660(4) 0.9254(2) 0.34737(14) 0.0146(5) Uani 1 1 d . . .
O6 O 0.3659(4) 1.1684(2) 0.39788(15) 0.0151(5) Uani 1 1 d . . .
N1 N 0.1746(4) 0.8903(3) 0.51291(17) 0.0101(5) Uani 1 1 d . . .
N2 N 0.3549(4) 1.1256(3) 0.56737(17) 0.0100(5) Uani 1 1 d . . .
C1 C 0.0752(5) 0.7700(3) 0.4768(2) 0.0150(7) Uani 1 1 d . . .
H20 H 0.0526 0.7481 0.4215 0.018 Uiso 1 1 calc R . .
C2 C 0.0074(5) 0.6799(3) 0.5206(2) 0.0152(7) Uani 1 1 d . . .
H19 H -0.0668 0.5991 0.4953 0.018 Uiso 1 1 calc R . .
C3 C 0.0511(5) 0.7113(3) 0.6032(2) 0.0137(6) Uani 1 1 d . . .
C4 C -0.0202(5) 0.6142(3) 0.6514(2) 0.0156(7) Uani 1 1 d . . .
C5 C 0.0165(6) 0.5644(3) 0.7811(2) 0.0195(7) Uani 1 1 d . . .
H7 H -0.1357 0.5467 0.7773 0.023 Uiso 1 1 calc R . .
C6 C 0.0862(8) 0.4414(4) 0.7631(3) 0.0347(10) Uani 1 1 d . . .
H1 H 0.0150 0.3930 0.7125 0.052 Uiso 1 1 calc R . .
H3 H 0.0542 0.3938 0.8038 0.052 Uiso 1 1 calc R . .
H2 H 0.2337 0.4592 0.7616 0.052 Uiso 1 1 calc R . .
C7 C 0.1126(7) 0.6435(4) 0.8618(2) 0.0298(9) Uani 1 1 d . . .
H4 H 0.2616 0.6576 0.8661 0.045 Uiso 1 1 calc R . .
H6 H 0.0646 0.5997 0.9024 0.045 Uiso 1 1 calc R . .
H5 H 0.0729 0.7235 0.8682 0.045 Uiso 1 1 calc R . .
C8 C 0.1561(5) 0.8338(3) 0.6402(2) 0.0135(7) Uani 1 1 d . . .
H18 H 0.1880 0.8559 0.6953 0.016 Uiso 1 1 calc R . .
C9 C 0.2118(5) 0.9216(3) 0.5936(2) 0.0121(7) Uani 1 1 d . . .
C10 C 0.3119(5) 1.0570(3) 0.6240(2) 0.0129(7) Uani 1 1 d . . .
C11 C 0.4488(5) 1.2501(3) 0.5900(2) 0.0156(7) Uani 1 1 d . . .
H8 H 0.4798 1.2975 0.5512 0.019 Uiso 1 1 calc R . .
C12 C 0.4997(5) 1.3086(3) 0.6694(2) 0.0163(7) Uani 1 1 d . . .
H17 H 0.5644 1.3943 0.6837 0.020 Uiso 1 1 calc R . .
C13 C 0.4533(5) 1.2381(3) 0.72763(19) 0.0141(6) Uani 1 1 d . . .
C14 C 0.3587(5) 1.1092(3) 0.7048(2) 0.0131(7) Uani 1 1 d . . .
H9 H 0.3280 1.0597 0.7425 0.016 Uiso 1 1 calc R . .
C15 C 0.5061(5) 1.3005(3) 0.8140(2) 0.0172(7) Uani 1 1 d . . .
C16 C 0.4694(6) 1.2645(4) 0.9459(2) 0.0238(8) Uani 1 1 d . . .
H10 H 0.6094 1.3196 0.9602 0.029 Uiso 1 1 calc R . .
C17 C 0.3112(7) 1.3371(4) 0.9739(2) 0.0334(10) Uani 1 1 d . . .
H11 H 0.3200 1.4098 0.9495 0.050 Uiso 1 1 calc R . .
H12 H 0.3390 1.3644 1.0307 0.050 Uiso 1 1 calc R . .
H13 H 0.1740 1.2834 0.9593 0.050 Uiso 1 1 calc R . .
C18 C 0.4642(7) 1.1447(4) 0.9769(2) 0.0328(10) Uani 1 1 d . . .
H15 H 0.3280 1.0898 0.9617 0.049 Uiso 1 1 calc R . .
H14 H 0.4958 1.1649 1.0339 0.049 Uiso 1 1 calc R . .
H16 H 0.5655 1.1028 0.9550 0.049 Uiso 1 1 calc R . .
C19 C 0.1996(6) 0.9980(4) 0.2926(2) 0.0169(7) Uani 1 1 d . . .
C20 C 0.3068(6) 1.1258(4) 0.3189(2) 0.0173(7) Uani 1 1 d . . .
C21 C 0.3478(6) 1.2036(4) 0.2636(2) 0.0221(8) Uani 1 1 d . . .
H24 H 0.4219 1.2872 0.2805 0.027 Uiso 1 1 calc R . .
C22 C 0.2773(6) 1.1555(4) 0.1828(2) 0.0269(9) Uani 1 1 d . . .
H23 H 0.3029 1.2075 0.1460 0.032 Uiso 1 1 calc R . .
C23 C 0.1695(6) 1.0307(4) 0.1573(2) 0.0274(9) Uani 1 1 d . . .
H22 H 0.1235 0.9995 0.1034 0.033 Uiso 1 1 calc R . .
C24 C 0.1291(6) 0.9517(4) 0.2111(2) 0.0229(8) Uani 1 1 d . . .
H21 H 0.0554 0.8681 0.1933 0.027 Uiso 1 1 calc R . .
O1S O 0.5756(5) 1.4281(3) 0.43253(19) 0.0333(7) Uani 1 1 d . . .
H1S1 H 0.5231 1.3488 0.4221 0.040 Uiso 1 1 d R . .
H2S2 H 0.4759 1.4658 0.4307 0.040 Uiso 1 1 d R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N1 1.983(3) . ?
Pt1 O5 1.986(2) . ?
Pt1 N2 1.994(3) . ?
Pt1 O6 2.005(2) . ?
O1 C4 1.332(4) . ?
O1 C5 1.471(4) . ?
O2 C4 1.212(4) . ?
O3 C15 1.205(4) . ?
O4 C15 1.333(4) . ?
O4 C16 1.464(4) . ?
O5 C19 1.345(4) . ?
O6 C20 1.350(4) . ?
N1 C9 1.358(4) . ?
N1 C1 1.359(4) . ?
N2 C10 1.351(5) . ?
N2 C11 1.353(5) . ?
C1 C2 1.378(5) . ?
C1 H20 0.9300 . ?
C2 C3 1.392(5) . ?
C2 H19 0.9300 . ?
C3 C8 1.391(5) . ?
C3 C4 1.494(5) . ?
C5 C7 1.508(5) . ?
C5 C6 1.509(6) . ?
C5 H7 0.9800 . ?
C6 H1 0.9600 . ?
C6 H3 0.9600 . ?
C6 H2 0.9600 . ?
C7 H4 0.9600 . ?
C7 H6 0.9600 . ?
C7 H5 0.9600 . ?
C8 C9 1.378(5) . ?
C8 H18 0.9300 . ?
C9 C10 1.479(5) . ?
C10 C14 1.389(5) . ?
C11 C12 1.384(5) . ?
C11 H8 0.9300 . ?
C12 C13 1.392(4) . ?
C12 H17 0.9300 . ?
C13 C14 1.396(5) . ?
C13 C15 1.501(5) . ?
C14 H9 0.9300 . ?
C16 C18 1.500(5) . ?
C16 C17 1.509(6) . ?
C16 H10 0.9800 . ?
C17 H11 0.9600 . ?
C17 H12 0.9600 . ?
C17 H13 0.9600 . ?
C18 H15 0.9600 . ?
C18 H14 0.9600 . ?
C18 H16 0.9600 . ?
C19 C24 1.406(5) . ?
C19 C20 1.410(5) . ?
C20 C21 1.399(5) . ?
C21 C22 1.398(5) . ?
C21 H24 0.9300 . ?
C22 C23 1.382(6) . ?
C22 H23 0.9300 . ?
C23 C24 1.386(6) . ?
C23 H22 0.9300 . ?
C24 H21 0.9300 . ?
O1S H1S1 0.8500 . ?
O1S H2S2 0.8501 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pt1 O5 95.68(11) . . ?
N1 Pt1 N2 80.97(12) . . ?
O5 Pt1 N2 176.11(9) . . ?
N1 Pt1 O6 179.28(9) . . ?
O5 Pt1 O6 84.22(10) . . ?
N2 Pt1 O6 99.16(11) . . ?
C4 O1 C5 117.1(3) . . ?
C15 O4 C16 118.3(3) . . ?
C19 O5 Pt1 110.1(2) . . ?
C20 O6 Pt1 109.5(2) . . ?
C9 N1 C1 119.5(3) . . ?
C9 N1 Pt1 116.1(2) . . ?
C1 N1 Pt1 124.5(2) . . ?
C10 N2 C11 118.9(3) . . ?
C10 N2 Pt1 114.9(2) . . ?
C11 N2 Pt1 126.2(2) . . ?
N1 C1 C2 121.1(3) . . ?
N1 C1 H20 119.4 . . ?
C2 C1 H20 119.4 . . ?
C1 C2 C3 119.2(3) . . ?
C1 C2 H19 120.4 . . ?
C3 C2 H19 120.4 . . ?
C8 C3 C2 119.7(3) . . ?
C8 C3 C4 120.5(3) . . ?
C2 C3 C4 119.8(3) . . ?
O2 C4 O1 125.4(3) . . ?
O2 C4 C3 123.2(3) . . ?
O1 C4 C3 111.5(3) . . ?
O1 C5 C7 104.6(3) . . ?
O1 C5 C6 110.2(3) . . ?
C7 C5 C6 113.0(3) . . ?
O1 C5 H7 109.6 . . ?
C7 C5 H7 109.6 . . ?
C6 C5 H7 109.6 . . ?
C5 C6 H1 109.5 . . ?
C5 C6 H3 109.5 . . ?
H1 C6 H3 109.5 . . ?
C5 C6 H2 109.5 . . ?
H1 C6 H2 109.5 . . ?
H3 C6 H2 109.5 . . ?
C5 C7 H4 109.5 . . ?
C5 C7 H6 109.5 . . ?
H4 C7 H6 109.5 . . ?
C5 C7 H5 109.5 . . ?
H4 C7 H5 109.5 . . ?
H6 C7 H5 109.5 . . ?
C9 C8 C3 118.6(3) . . ?
C9 C8 H18 120.7 . . ?
C3 C8 H18 120.7 . . ?
N1 C9 C8 121.8(3) . . ?
N1 C9 C10 113.1(3) . . ?
C8 C9 C10 125.1(3) . . ?
N2 C10 C14 122.7(3) . . ?
N2 C10 C9 115.0(3) . . ?
C14 C10 C9 122.3(3) . . ?
N2 C11 C12 121.6(3) . . ?
N2 C11 H8 119.2 . . ?
C12 C11 H8 119.2 . . ?
C11 C12 C13 119.4(3) . . ?
C11 C12 H17 120.3 . . ?
C13 C12 H17 120.3 . . ?
C12 C13 C14 119.3(3) . . ?
C12 C13 C15 120.0(3) . . ?
C14 C13 C15 120.7(3) . . ?
C10 C14 C13 118.0(3) . . ?
C10 C14 H9 121.0 . . ?
C13 C14 H9 121.0 . . ?
O3 C15 O4 125.2(3) . . ?
O3 C15 C13 124.2(3) . . ?
O4 C15 C13 110.7(3) . . ?
O4 C16 C18 104.4(3) . . ?
O4 C16 C17 109.0(3) . . ?
C18 C16 C17 114.6(3) . . ?
O4 C16 H10 109.6 . . ?
C18 C16 H10 109.6 . . ?
C17 C16 H10 109.6 . . ?
C16 C17 H11 109.5 . . ?
C16 C17 H12 109.5 . . ?
H11 C17 H12 109.5 . . ?
C16 C17 H13 109.5 . . ?
H11 C17 H13 109.5 . . ?
H12 C17 H13 109.5 . . ?
C16 C18 H15 109.5 . . ?
C16 C18 H14 109.5 . . ?
H15 C18 H14 109.5 . . ?
C16 C18 H16 109.5 . . ?
H15 C18 H16 109.5 . . ?
H14 C18 H16 109.5 . . ?
O5 C19 C24 122.4(3) . . ?
O5 C19 C20 118.1(3) . . ?
C24 C19 C20 119.4(3) . . ?
O6 C20 C21 122.3(4) . . ?
O6 C20 C19 117.9(3) . . ?
C21 C20 C19 119.7(3) . . ?
C22 C21 C20 119.9(4) . . ?
C22 C21 H24 120.0 . . ?
C20 C21 H24 120.0 . . ?
C23 C22 C21 120.2(3) . . ?
C23 C22 H23 119.9 . . ?
C21 C22 H23 119.9 . . ?
C22 C23 C24 120.8(3) . . ?
C22 C23 H22 119.6 . . ?
C24 C23 H22 119.6 . . ?
C23 C24 C19 119.9(4) . . ?
C23 C24 H21 120.1 . . ?
C19 C24 H21 120.1 . . ?
H1S1 O1S H2S2 107.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Pt1 O5 C19 177.1(2) . . . . ?
N2 Pt1 O5 C19 146.9(13) . . . . ?
O6 Pt1 O5 C19 -3.6(2) . . . . ?
N1 Pt1 O6 C20 85(7) . . . . ?
O5 Pt1 O6 C20 3.0(2) . . . . ?
N2 Pt1 O6 C20 -175.1(2) . . . . ?
O5 Pt1 N1 C9 -178.9(2) . . . . ?
N2 Pt1 N1 C9 -0.8(2) . . . . ?
O6 Pt1 N1 C9 100(7) . . . . ?
O5 Pt1 N1 C1 0.0(3) . . . . ?
N2 Pt1 N1 C1 178.0(3) . . . . ?
O6 Pt1 N1 C1 -82(7) . . . . ?
N1 Pt1 N2 C10 -0.2(2) . . . . ?
O5 Pt1 N2 C10 30.2(14) . . . . ?
O6 Pt1 N2 C10 -179.5(2) . . . . ?
N1 Pt1 N2 C11 -179.8(3) . . . . ?
O5 Pt1 N2 C11 -149.3(12) . . . . ?
O6 Pt1 N2 C11 0.9(3) . . . . ?
C9 N1 C1 C2 1.5(5) . . . . ?
Pt1 N1 C1 C2 -177.4(3) . . . . ?
N1 C1 C2 C3 -3.3(5) . . . . ?
C1 C2 C3 C8 2.1(5) . . . . ?
C1 C2 C3 C4 -179.6(3) . . . . ?
C5 O1 C4 O2 -6.0(5) . . . . ?
C5 O1 C4 C3 173.9(3) . . . . ?
C8 C3 C4 O2 159.0(4) . . . . ?
C2 C3 C4 O2 -19.2(5) . . . . ?
C8 C3 C4 O1 -20.9(4) . . . . ?
C2 C3 C4 O1 160.9(3) . . . . ?
C4 O1 C5 C7 -162.1(3) . . . . ?
C4 O1 C5 C6 76.2(4) . . . . ?
C2 C3 C8 C9 0.8(5) . . . . ?
C4 C3 C8 C9 -177.5(3) . . . . ?
C1 N1 C9 C8 1.6(5) . . . . ?
Pt1 N1 C9 C8 -179.5(3) . . . . ?
C1 N1 C9 C10 -177.3(3) . . . . ?
Pt1 N1 C9 C10 1.7(4) . . . . ?
C3 C8 C9 N1 -2.7(5) . . . . ?
C3 C8 C9 C10 176.0(3) . . . . ?
C11 N2 C10 C14 0.5(5) . . . . ?
Pt1 N2 C10 C14 -179.1(3) . . . . ?
C11 N2 C10 C9 -179.2(3) . . . . ?
Pt1 N2 C10 C9 1.2(4) . . . . ?
N1 C9 C10 N2 -1.9(4) . . . . ?
C8 C9 C10 N2 179.3(3) . . . . ?
N1 C9 C10 C14 178.4(3) . . . . ?
C8 C9 C10 C14 -0.4(6) . . . . ?
C10 N2 C11 C12 -0.6(5) . . . . ?
Pt1 N2 C11 C12 178.9(3) . . . . ?
N2 C11 C12 C13 -0.1(5) . . . . ?
C11 C12 C13 C14 0.9(5) . . . . ?
C11 C12 C13 C15 -179.5(3) . . . . ?
N2 C10 C14 C13 0.3(5) . . . . ?
C9 C10 C14 C13 180.0(3) . . . . ?
C12 C13 C14 C10 -1.0(5) . . . . ?
C15 C13 C14 C10 179.4(3) . . . . ?
C16 O4 C15 O3 -3.9(6) . . . . ?
C16 O4 C15 C13 176.6(3) . . . . ?
C12 C13 C15 O3 -8.1(6) . . . . ?
C14 C13 C15 O3 171.5(4) . . . . ?
C12 C13 C15 O4 171.4(3) . . . . ?
C14 C13 C15 O4 -9.0(5) . . . . ?
C15 O4 C16 C18 -149.7(3) . . . . ?
C15 O4 C16 C17 87.4(4) . . . . ?
Pt1 O5 C19 C24 -175.2(3) . . . . ?
Pt1 O5 C19 C20 3.7(4) . . . . ?
Pt1 O6 C20 C21 178.0(3) . . . . ?
Pt1 O6 C20 C19 -1.8(4) . . . . ?
O5 C19 C20 O6 -1.3(5) . . . . ?
C24 C19 C20 O6 177.7(3) . . . . ?
O5 C19 C20 C21 178.9(3) . . . . ?
C24 C19 C20 C21 -2.1(6) . . . . ?
O6 C20 C21 C22 -178.0(3) . . . . ?
C19 C20 C21 C22 1.8(6) . . . . ?
C20 C21 C22 C23 -0.9(6) . . . . ?
C21 C22 C23 C24 0.2(6) . . . . ?
C22 C23 C24 C19 -0.5(6) . . . . ?
O5 C19 C24 C23 -179.6(3) . . . . ?
C20 C19 C24 C23 1.5(6) . . . . ?

_diffrn_measured_fraction_theta_max 0.960
_diffrn_reflns_theta_full        27.47
_diffrn_measured_fraction_theta_full 0.960
_refine_diff_density_max         0.973
_refine_diff_density_min         -2.068
_refine_diff_density_rms         0.305
