# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_cu_dyl109048_0m
_database_code_depnum_ccdc_archive 'CCDC 1027340'
_audit_update_record             
;
2014-10-02 deposited with the CCDC.
2015-06-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C21 H45 Dy O24'
_chemical_formula_weight         844.07
_chemical_absolute_configuration rmad

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -9.8046 9.8477 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P21

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   6.0848(2)
_cell_length_b                   25.2704(10)
_cell_length_c                   10.5635(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 105.602(2)
_cell_angle_gamma                90.00
_cell_volume                     1564.45(10)
_cell_formula_units_Z            2
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       needlike
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.254
_exptl_crystal_size_mid          0.075
_exptl_crystal_size_min          0.070
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.792
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             858
_exptl_absorpt_coefficient_mu    13.668
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.336
_exptl_absorpt_correction_T_max  0.384
_exptl_absorpt_process_details   
;
G. M. Sheldrick, (1996). SADABS. Program for Empirical Absorption Correction. University of Gottingen, Germany.
;

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            23323
_diffrn_reflns_av_R_equivalents  0.0390
_diffrn_reflns_av_sigmaI/netI    0.0548
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_theta_min         3.50
_diffrn_reflns_theta_max         68.32
_reflns_number_total             5284
_reflns_number_gt                5124
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.014(2)
_refine_ls_number_reflns         5284
_refine_ls_number_parameters     415
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0225
_refine_ls_R_factor_gt           0.0218
_refine_ls_wR_factor_ref         0.0467
_refine_ls_wR_factor_gt          0.0465
_refine_ls_goodness_of_fit_ref   0.926
_refine_ls_restrained_S_all      0.926
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 1.09716(2) 0.253060(10) 0.113686(13) 0.00842(5) Uani 1 1 d . . .
O1 O 1.0388(3) 0.16015(8) 0.1001(2) 0.0135(4) Uani 1 1 d . . .
H1 H 1.0720 0.1480 0.1775 0.020 Uiso 1 1 d R . .
O2 O 1.1581(3) 0.21462(8) -0.0728(2) 0.0136(4) Uani 1 1 d . . .
O3 O 1.2332(4) 0.14590(9) -0.1862(2) 0.0183(4) Uani 1 1 d . . .
O4 O 0.6889(4) 0.01662(8) -0.0497(2) 0.0192(4) Uani 1 1 d . . .
H4 H 0.7040 -0.0119 -0.0210 0.029 Uiso 1 1 d R . .
O5 O 0.9988(4) -0.01269(9) 0.2003(2) 0.0203(5) Uani 1 1 d . . .
H5 H 0.8561 -0.0116 0.1850 0.030 Uiso 1 1 d R . .
O6 O 1.1935(4) 0.08765(9) 0.2746(2) 0.0215(5) Uani 1 1 d . . .
H6 H 1.1551 0.0675 0.3282 0.032 Uiso 1 1 d R . .
O7 O 0.3222(3) 0.22080(8) 0.32055(19) 0.0115(4) Uani 1 1 d . . .
H7 H 0.2970 0.2249 0.3920 0.017 Uiso 1 1 d R . .
O8 O 0.8574(3) 0.23939(7) 0.2533(2) 0.0118(4) Uani 1 1 d . . .
O9 O 0.4956(3) 0.25463(14) 0.14459(17) 0.0169(3) Uani 1 1 d . . .
O10 O 0.7081(4) 0.10658(9) 0.5907(2) 0.0185(4) Uani 1 1 d . . .
H10 H 0.6228 0.0886 0.6248 0.028 Uiso 1 1 d R . .
O11 O 0.6158(4) 0.18707(9) 0.7669(2) 0.0160(4) Uani 1 1 d . . .
H11 H 0.4781 0.1781 0.7502 0.024 Uiso 1 1 d R . .
O12 O 0.3206(3) 0.24713(11) 0.5542(2) 0.0177(5) Uani 1 1 d . . .
H12 H 0.2640 0.2571 0.6130 0.027 Uiso 1 1 d R . .
O13 O 1.1268(4) 0.33053(8) 0.2428(2) 0.0151(4) Uani 1 1 d . . .
H13 H 1.0760 0.3373 0.3080 0.023 Uiso 1 1 d R . .
O14 O 1.1489(4) 0.32956(8) 0.0067(2) 0.0169(4) Uani 1 1 d . . .
O15 O 1.2891(4) 0.41081(9) 0.0094(2) 0.0207(5) Uani 1 1 d . . .
O16 O 0.9561(4) 0.38339(9) 0.4027(2) 0.0197(5) Uani 1 1 d . . .
H16 H 0.8755 0.3894 0.4543 0.030 Uiso 1 1 d R . .
O17 O 1.6456(4) 0.42348(10) 0.5066(2) 0.0226(5) Uani 1 1 d . . .
H17 H 1.6740 0.4114 0.5834 0.034 Uiso 1 1 d R . .
O18 O 1.2405(4) 0.45902(9) 0.5683(2) 0.0214(5) Uani 1 1 d . . .
H18 H 1.1612 0.4858 0.5724 0.032 Uiso 1 1 d R . .
O19 O 0.7343(3) 0.25969(12) -0.03721(18) 0.0164(4) Uani 1 1 d . . .
H19A H 0.6250 0.2612 0.0038 0.025 Uiso 1 1 d R . .
H19B H 0.7020 0.2377 -0.0960 0.025 Uiso 1 1 d R . .
C1 C 1.1125(5) 0.12724(12) 0.0070(3) 0.0120(6) Uani 1 1 d . . .
C2 C 0.9223(5) 0.09033(11) -0.0629(3) 0.0133(5) Uani 1 1 d . . .
H2A H 0.9695 0.0712 -0.1332 0.016 Uiso 1 1 calc R . .
H2B H 0.7851 0.1115 -0.1049 0.016 Uiso 1 1 calc R . .
C3 C 0.8622(5) 0.05025(12) 0.0301(3) 0.0142(6) Uani 1 1 d . . .
H3 H 0.7960 0.0696 0.0937 0.017 Uiso 1 1 calc R . .
C4 C 1.0686(5) 0.01927(12) 0.1069(3) 0.0159(6) Uani 1 1 d . . .
H4A H 1.1242 -0.0040 0.0454 0.019 Uiso 1 1 calc R . .
C5 C 1.2604(5) 0.05658(13) 0.1775(3) 0.0179(6) Uani 1 1 d . . .
H5A H 1.3981 0.0352 0.2213 0.022 Uiso 1 1 calc R . .
C6 C 1.3225(5) 0.09530(12) 0.0808(3) 0.0144(6) Uani 1 1 d . . .
H6A H 1.3833 0.0754 0.0169 0.017 Uiso 1 1 calc R . .
H6B H 1.4430 0.1198 0.1294 0.017 Uiso 1 1 calc R . .
C7 C 1.1736(4) 0.16525(12) -0.0926(3) 0.0115(5) Uani 1 1 d . . .
C8 C 0.5694(4) 0.22381(11) 0.3662(3) 0.0100(5) Uani 1 1 d . . .
C9 C 0.6682(5) 0.17013(11) 0.4200(3) 0.0120(5) Uani 1 1 d . . .
H9A H 0.6125 0.1426 0.3523 0.014 Uiso 1 1 calc R . .
H9B H 0.8366 0.1714 0.4399 0.014 Uiso 1 1 calc R . .
C10 C 0.5995(5) 0.15559(11) 0.5443(3) 0.0118(5) Uani 1 1 d . . .
H10A H 0.4302 0.1510 0.5223 0.014 Uiso 1 1 calc R . .
C11 C 0.6716(5) 0.19934(12) 0.6468(3) 0.0129(6) Uani 1 1 d . . .
H11A H 0.8411 0.2032 0.6672 0.015 Uiso 1 1 calc R . .
C12 C 0.5644(4) 0.25194(19) 0.5922(2) 0.0132(5) Uani 1 1 d . . .
H12A H 0.6118 0.2802 0.6604 0.016 Uiso 1 1 calc R . .
C13 C 0.6399(5) 0.26693(10) 0.4698(3) 0.0128(6) Uani 1 1 d . . .
H13A H 0.5687 0.3009 0.4340 0.015 Uiso 1 1 calc R . .
H13B H 0.8076 0.2715 0.4936 0.015 Uiso 1 1 calc R . .
C14 C 0.6478(5) 0.24006(10) 0.2451(3) 0.0108(6) Uani 1 1 d . . .
C15 C 1.1951(5) 0.38134(11) 0.2030(3) 0.0134(6) Uani 1 1 d . . .
C16 C 1.4283(5) 0.39732(12) 0.2932(3) 0.0151(6) Uani 1 1 d . . .
H16A H 1.5396 0.3687 0.2933 0.018 Uiso 1 1 calc R . .
H16B H 1.4822 0.4296 0.2577 0.018 Uiso 1 1 calc R . .
C17 C 1.4206(5) 0.40784(12) 0.4343(3) 0.0157(6) Uani 1 1 d . . .
H17A H 1.3772 0.3746 0.4730 0.019 Uiso 1 1 calc R . .
C18 C 1.2462(5) 0.45083(12) 0.4358(3) 0.0169(6) Uani 1 1 d . . .
H18A H 1.2913 0.4844 0.3993 0.020 Uiso 1 1 calc R . .
C19 C 1.0130(5) 0.43264(12) 0.3510(3) 0.0163(6) Uani 1 1 d . . .
H19 H 0.8950 0.4599 0.3536 0.020 Uiso 1 1 calc R . .
C20 C 1.0172(5) 0.42314(12) 0.2086(3) 0.0164(6) Uani 1 1 d . . .
H20A H 0.8648 0.4112 0.1563 0.020 Uiso 1 1 calc R . .
H20B H 1.0538 0.4566 0.1701 0.020 Uiso 1 1 calc R . .
C21 C 1.2131(5) 0.37366(12) 0.0608(3) 0.0145(6) Uani 1 1 d . . .
O20 O 1.0258(4) 0.05199(9) 0.4858(2) 0.0225(5) Uani 1 1 d . . .
H20C H 0.9326 0.0712 0.5126 0.034 Uiso 1 1 d R . .
H20D H 1.1485 0.0488 0.5470 0.034 Uiso 1 1 d R . .
O21 O 1.4003(4) 0.05720(9) 0.7187(2) 0.0209(4) Uani 1 1 d . . .
H21A H 1.3277 0.0824 0.7420 0.031 Uiso 1 1 d R . .
H21B H 1.4890 0.0441 0.7870 0.031 Uiso 1 1 d R . .
O22 O 1.1251(4) 0.28954(10) 0.7211(2) 0.0225(5) Uani 1 1 d . . .
H22A H 1.1910 0.3190 0.7453 0.034 Uiso 1 1 d R . .
H22B H 1.1491 0.2745 0.7860 0.034 Uiso 1 1 d R . .
O23 O 0.7799(4) 0.38979(11) -0.2262(3) 0.0301(6) Uani 1 1 d . . .
H23A H 0.8736 0.3648 -0.1973 0.045 Uiso 1 1 d R . .
H23B H 0.6539 0.3831 -0.2091 0.045 Uiso 1 1 d R . .
O24 O 1.3372(4) 0.38604(10) -0.2298(2) 0.0235(5) Uani 1 1 d . . .
H24A H 1.2750 0.4077 -0.2901 0.035 Uiso 1 1 d R . .
H24B H 1.3286 0.3979 -0.1560 0.035 Uiso 1 1 d R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O14 2.303(2) . ?
Dy1 O2 2.314(2) . ?
Dy1 O19 2.3559(18) . ?
Dy1 O9 2.3578(15) 1_655 ?
Dy1 O8 2.3623(17) . ?
Dy1 O13 2.365(2) . ?
Dy1 O1 2.373(2) . ?
Dy1 O7 2.389(2) 1_655 ?
O1 C1 1.448(3) . ?
O1 H1 0.8453 . ?
O2 C7 1.273(4) . ?
O3 C7 1.241(4) . ?
O4 C3 1.438(3) . ?
O4 H4 0.7775 . ?
O5 C4 1.426(4) . ?
O5 H5 0.8398 . ?
O6 C5 1.435(4) . ?
O6 H6 0.8398 . ?
O7 C8 1.453(3) . ?
O7 Dy1 2.389(2) 1_455 ?
O7 H7 0.8168 . ?
O8 C14 1.255(4) . ?
O9 C14 1.262(4) . ?
O9 Dy1 2.3578(15) 1_455 ?
O10 C10 1.427(3) . ?
O10 H10 0.8399 . ?
O11 C11 1.433(3) . ?
O11 H11 0.8396 . ?
O12 C12 1.434(3) . ?
O12 H12 0.8264 . ?
O13 C15 1.446(3) . ?
O13 H13 0.8448 . ?
O14 C21 1.265(4) . ?
O15 C21 1.235(4) . ?
O16 C19 1.438(4) . ?
O16 H16 0.8396 . ?
O17 C17 1.432(4) . ?
O17 H17 0.8401 . ?
O18 C18 1.425(4) . ?
O18 H18 0.8396 . ?
O19 H19A 0.8866 . ?
O19 H19B 0.8174 . ?
C1 C2 1.515(4) . ?
C1 C6 1.535(4) . ?
C1 C7 1.543(4) . ?
C2 C3 1.522(4) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 C4 1.517(4) . ?
C3 H3 1.0000 . ?
C4 C5 1.529(4) . ?
C4 H4A 1.0000 . ?
C5 C6 1.533(4) . ?
C5 H5A 1.0000 . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C8 C13 1.522(4) . ?
C8 C9 1.530(4) . ?
C8 C14 1.537(3) . ?
C9 C10 1.527(4) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C10 C11 1.527(4) . ?
C10 H10A 1.0000 . ?
C11 C12 1.524(5) . ?
C11 H11A 1.0000 . ?
C12 C13 1.532(3) . ?
C12 H12A 1.0000 . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C15 C20 1.525(4) . ?
C15 C16 1.536(4) . ?
C15 C21 1.547(4) . ?
C16 C17 1.527(4) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 C18 1.522(4) . ?
C17 H17A 1.0000 . ?
C18 C19 1.531(4) . ?
C18 H18A 1.0000 . ?
C19 C20 1.530(4) . ?
C19 H19 1.0000 . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
O20 H20C 0.8514 . ?
O20 H20D 0.8500 . ?
O21 H21A 0.8488 . ?
O21 H21B 0.8435 . ?
O22 H22A 0.8520 . ?
O22 H22B 0.7629 . ?
O23 H23A 0.8498 . ?
O23 H23B 0.8504 . ?
O24 H24A 0.8481 . ?
O24 H24B 0.8502 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O14 Dy1 O2 81.98(7) . . ?
O14 Dy1 O19 80.52(9) . . ?
O2 Dy1 O19 77.84(7) . . ?
O14 Dy1 O9 77.45(9) . 1_655 ?
O2 Dy1 O9 74.38(7) . 1_655 ?
O19 Dy1 O9 146.51(6) . 1_655 ?
O14 Dy1 O8 128.16(7) . . ?
O2 Dy1 O8 137.51(7) . . ?
O19 Dy1 O8 78.99(7) . . ?
O9 Dy1 O8 134.48(7) 1_655 . ?
O14 Dy1 O13 65.72(7) . . ?
O2 Dy1 O13 146.47(7) . . ?
O19 Dy1 O13 104.10(9) . . ?
O9 Dy1 O13 89.43(9) 1_655 . ?
O8 Dy1 O13 74.04(7) . . ?
O14 Dy1 O1 147.02(7) . . ?
O2 Dy1 O1 65.73(7) . . ?
O19 Dy1 O1 86.09(9) . . ?
O9 Dy1 O1 99.01(10) 1_655 . ?
O8 Dy1 O1 77.62(6) . . ?
O13 Dy1 O1 147.22(7) . . ?
O14 Dy1 O7 127.95(7) . 1_655 ?
O2 Dy1 O7 116.86(7) . 1_655 ?
O19 Dy1 O7 147.74(7) . 1_655 ?
O9 Dy1 O7 64.15(6) 1_655 1_655 ?
O8 Dy1 O7 71.18(7) . 1_655 ?
O13 Dy1 O7 79.57(7) . 1_655 ?
O1 Dy1 O7 75.95(7) . 1_655 ?
C1 O1 Dy1 122.71(16) . . ?
C1 O1 H1 114.3 . . ?
Dy1 O1 H1 107.9 . . ?
C7 O2 Dy1 126.02(18) . . ?
C3 O4 H4 109.1 . . ?
C4 O5 H5 109.5 . . ?
C5 O6 H6 109.5 . . ?
C8 O7 Dy1 124.99(15) . 1_455 ?
C8 O7 H7 97.0 . . ?
Dy1 O7 H7 126.7 1_455 . ?
C14 O8 Dy1 137.88(19) . . ?
C14 O9 Dy1 127.34(17) . 1_455 ?
C10 O10 H10 109.5 . . ?
C11 O11 H11 109.5 . . ?
C12 O12 H12 111.9 . . ?
C15 O13 Dy1 123.39(16) . . ?
C15 O13 H13 104.7 . . ?
Dy1 O13 H13 130.6 . . ?
C21 O14 Dy1 125.7(2) . . ?
C19 O16 H16 109.4 . . ?
C17 O17 H17 109.5 . . ?
C18 O18 H18 109.5 . . ?
Dy1 O19 H19A 111.2 . . ?
Dy1 O19 H19B 117.1 . . ?
H19A O19 H19B 110.0 . . ?
O1 C1 C2 110.4(2) . . ?
O1 C1 C6 108.9(2) . . ?
C2 C1 C6 110.3(2) . . ?
O1 C1 C7 106.3(2) . . ?
C2 C1 C7 110.1(2) . . ?
C6 C1 C7 110.7(2) . . ?
C1 C2 C3 112.3(2) . . ?
C1 C2 H2A 109.1 . . ?
C3 C2 H2A 109.1 . . ?
C1 C2 H2B 109.1 . . ?
C3 C2 H2B 109.1 . . ?
H2A C2 H2B 107.9 . . ?
O4 C3 C4 112.3(2) . . ?
O4 C3 C2 106.3(2) . . ?
C4 C3 C2 112.4(2) . . ?
O4 C3 H3 108.6 . . ?
C4 C3 H3 108.6 . . ?
C2 C3 H3 108.6 . . ?
O5 C4 C3 107.7(2) . . ?
O5 C4 C5 110.0(2) . . ?
C3 C4 C5 110.9(2) . . ?
O5 C4 H4A 109.4 . . ?
C3 C4 H4A 109.4 . . ?
C5 C4 H4A 109.4 . . ?
O6 C5 C4 111.1(2) . . ?
O6 C5 C6 107.2(3) . . ?
C4 C5 C6 111.2(3) . . ?
O6 C5 H5A 109.1 . . ?
C4 C5 H5A 109.1 . . ?
C6 C5 H5A 109.1 . . ?
C5 C6 C1 110.7(2) . . ?
C5 C6 H6A 109.5 . . ?
C1 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
C1 C6 H6B 109.5 . . ?
H6A C6 H6B 108.1 . . ?
O3 C7 O2 124.6(3) . . ?
O3 C7 C1 118.3(3) . . ?
O2 C7 C1 117.1(2) . . ?
O7 C8 C13 110.0(2) . . ?
O7 C8 C9 110.2(2) . . ?
C13 C8 C9 111.2(2) . . ?
O7 C8 C14 105.3(2) . . ?
C13 C8 C14 108.5(2) . . ?
C9 C8 C14 111.5(2) . . ?
C10 C9 C8 111.2(2) . . ?
C10 C9 H9A 109.4 . . ?
C8 C9 H9A 109.4 . . ?
C10 C9 H9B 109.4 . . ?
C8 C9 H9B 109.4 . . ?
H9A C9 H9B 108.0 . . ?
O10 C10 C11 111.5(2) . . ?
O10 C10 C9 107.2(2) . . ?
C11 C10 C9 110.0(2) . . ?
O10 C10 H10A 109.4 . . ?
C11 C10 H10A 109.4 . . ?
C9 C10 H10A 109.4 . . ?
O11 C11 C12 110.2(2) . . ?
O11 C11 C10 112.3(2) . . ?
C12 C11 C10 110.5(2) . . ?
O11 C11 H11A 107.9 . . ?
C12 C11 H11A 107.9 . . ?
C10 C11 H11A 107.9 . . ?
O12 C12 C11 109.7(3) . . ?
O12 C12 C13 107.9(2) . . ?
C11 C12 C13 109.9(2) . . ?
O12 C12 H12A 109.8 . . ?
C11 C12 H12A 109.8 . . ?
C13 C12 H12A 109.8 . . ?
C8 C13 C12 109.9(2) . . ?
C8 C13 H13A 109.7 . . ?
C12 C13 H13A 109.7 . . ?
C8 C13 H13B 109.7 . . ?
C12 C13 H13B 109.7 . . ?
H13A C13 H13B 108.2 . . ?
O8 C14 O9 124.4(3) . . ?
O8 C14 C8 118.4(3) . . ?
O9 C14 C8 117.2(2) . . ?
O13 C15 C20 109.9(2) . . ?
O13 C15 C16 110.1(2) . . ?
C20 C15 C16 109.9(2) . . ?
O13 C15 C21 105.8(2) . . ?
C20 C15 C21 111.2(3) . . ?
C16 C15 C21 109.9(2) . . ?
C17 C16 C15 112.7(2) . . ?
C17 C16 H16A 109.1 . . ?
C15 C16 H16A 109.1 . . ?
C17 C16 H16B 109.1 . . ?
C15 C16 H16B 109.1 . . ?
H16A C16 H16B 107.8 . . ?
O17 C17 C18 111.5(2) . . ?
O17 C17 C16 107.0(2) . . ?
C18 C17 C16 109.8(3) . . ?
O17 C17 H17A 109.5 . . ?
C18 C17 H17A 109.5 . . ?
C16 C17 H17A 109.5 . . ?
O18 C18 C17 108.3(2) . . ?
O18 C18 C19 110.8(2) . . ?
C17 C18 C19 108.6(2) . . ?
O18 C18 H18A 109.7 . . ?
C17 C18 H18A 109.7 . . ?
C19 C18 H18A 109.7 . . ?
O16 C19 C20 107.9(2) . . ?
O16 C19 C18 108.5(2) . . ?
C20 C19 C18 111.4(2) . . ?
O16 C19 H19 109.7 . . ?
C20 C19 H19 109.7 . . ?
C18 C19 H19 109.7 . . ?
C15 C20 C19 110.3(2) . . ?
C15 C20 H20A 109.6 . . ?
C19 C20 H20A 109.6 . . ?
C15 C20 H20B 109.6 . . ?
C19 C20 H20B 109.6 . . ?
H20A C20 H20B 108.1 . . ?
O15 C21 O14 125.3(3) . . ?
O15 C21 C15 117.7(3) . . ?
O14 C21 C15 117.1(3) . . ?
H20C O20 H20D 109.2 . . ?
H21A O21 H21B 108.0 . . ?
H22A O22 H22B 101.8 . . ?
H23A O23 H23B 109.5 . . ?
H24A O24 H24B 109.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O14 Dy1 O1 C1 25.7(3) . . . . ?
O2 Dy1 O1 C1 13.16(19) . . . . ?
O19 Dy1 O1 C1 91.6(2) . . . . ?
O9 Dy1 O1 C1 -55.1(2) 1_655 . . . ?
O8 Dy1 O1 C1 171.2(2) . . . . ?
O13 Dy1 O1 C1 -158.25(19) . . . . ?
O7 Dy1 O1 C1 -115.4(2) 1_655 . . . ?
O14 Dy1 O2 C7 174.9(2) . . . . ?
O19 Dy1 O2 C7 -103.1(2) . . . . ?
O9 Dy1 O2 C7 95.8(2) 1_655 . . . ?
O8 Dy1 O2 C7 -44.8(3) . . . . ?
O13 Dy1 O2 C7 159.6(2) . . . . ?
O1 Dy1 O2 C7 -12.0(2) . . . . ?
O7 Dy1 O2 C7 46.2(2) 1_655 . . . ?
O14 Dy1 O8 C14 63.8(3) . . . . ?
O2 Dy1 O8 C14 -62.7(3) . . . . ?
O19 Dy1 O8 C14 -4.7(3) . . . . ?
O9 Dy1 O8 C14 176.4(3) 1_655 . . . ?
O13 Dy1 O8 C14 103.6(3) . . . . ?
O1 Dy1 O8 C14 -93.1(3) . . . . ?
O7 Dy1 O8 C14 -172.3(3) 1_655 . . . ?
O14 Dy1 O13 C15 -10.07(19) . . . . ?
O2 Dy1 O13 C15 6.6(3) . . . . ?
O19 Dy1 O13 C15 -82.6(2) . . . . ?
O9 Dy1 O13 C15 66.4(2) 1_655 . . . ?
O8 Dy1 O13 C15 -156.6(2) . . . . ?
O1 Dy1 O13 C15 172.29(18) . . . . ?
O7 Dy1 O13 C15 130.2(2) 1_655 . . . ?
O2 Dy1 O14 C21 -156.1(2) . . . . ?
O19 Dy1 O14 C21 124.9(2) . . . . ?
O9 Dy1 O14 C21 -80.4(2) 1_655 . . . ?
O8 Dy1 O14 C21 57.1(3) . . . . ?
O13 Dy1 O14 C21 14.7(2) . . . . ?
O1 Dy1 O14 C21 -167.7(2) . . . . ?
O7 Dy1 O14 C21 -38.2(3) 1_655 . . . ?
Dy1 O1 C1 C2 -132.4(2) . . . . ?
Dy1 O1 C1 C6 106.3(2) . . . . ?
Dy1 O1 C1 C7 -13.0(3) . . . . ?
O1 C1 C2 C3 -65.4(3) . . . . ?
C6 C1 C2 C3 55.0(3) . . . . ?
C7 C1 C2 C3 177.5(2) . . . . ?
C1 C2 C3 O4 -177.4(2) . . . . ?
C1 C2 C3 C4 -54.1(3) . . . . ?
O4 C3 C4 O5 -66.4(3) . . . . ?
C2 C3 C4 O5 173.8(2) . . . . ?
O4 C3 C4 C5 173.2(2) . . . . ?
C2 C3 C4 C5 53.4(3) . . . . ?
O5 C4 C5 O6 -55.0(3) . . . . ?
C3 C4 C5 O6 64.0(3) . . . . ?
O5 C4 C5 C6 -174.3(2) . . . . ?
C3 C4 C5 C6 -55.2(3) . . . . ?
O6 C5 C6 C1 -64.4(3) . . . . ?
C4 C5 C6 C1 57.2(3) . . . . ?
O1 C1 C6 C5 64.8(3) . . . . ?
C2 C1 C6 C5 -56.6(3) . . . . ?
C7 C1 C6 C5 -178.6(2) . . . . ?
Dy1 O2 C7 O3 -171.0(2) . . . . ?
Dy1 O2 C7 C1 9.4(3) . . . . ?
O1 C1 C7 O3 -177.1(2) . . . . ?
C2 C1 C7 O3 -57.4(3) . . . . ?
C6 C1 C7 O3 64.7(4) . . . . ?
O1 C1 C7 O2 2.6(3) . . . . ?
C2 C1 C7 O2 122.3(3) . . . . ?
C6 C1 C7 O2 -115.6(3) . . . . ?
Dy1 O7 C8 C13 104.9(2) 1_455 . . . ?
Dy1 O7 C8 C9 -132.13(18) 1_455 . . . ?
Dy1 O7 C8 C14 -11.8(3) 1_455 . . . ?
O7 C8 C9 C10 -66.4(3) . . . . ?
C13 C8 C9 C10 55.9(3) . . . . ?
C14 C8 C9 C10 177.1(2) . . . . ?
C8 C9 C10 O10 -177.1(2) . . . . ?
C8 C9 C10 C11 -55.7(3) . . . . ?
O10 C10 C11 O11 -59.8(3) . . . . ?
C9 C10 C11 O11 -178.6(2) . . . . ?
O10 C10 C11 C12 176.7(2) . . . . ?
C9 C10 C11 C12 57.9(3) . . . . ?
O11 C11 C12 O12 -65.9(3) . . . . ?
C10 C11 C12 O12 58.8(3) . . . . ?
O11 C11 C12 C13 175.6(2) . . . . ?
C10 C11 C12 C13 -59.7(3) . . . . ?
O7 C8 C13 C12 65.4(3) . . . . ?
C9 C8 C13 C12 -56.9(3) . . . . ?
C14 C8 C13 C12 -179.9(2) . . . . ?
O12 C12 C13 C8 -60.8(4) . . . . ?
C11 C12 C13 C8 58.8(3) . . . . ?
Dy1 O8 C14 O9 -6.7(5) . . . . ?
Dy1 O8 C14 C8 175.34(17) . . . . ?
Dy1 O9 C14 O8 176.3(2) 1_455 . . . ?
Dy1 O9 C14 C8 -5.7(4) 1_455 . . . ?
O7 C8 C14 O8 -171.5(2) . . . . ?
C13 C8 C14 O8 70.7(3) . . . . ?
C9 C8 C14 O8 -52.1(3) . . . . ?
O7 C8 C14 O9 10.3(3) . . . . ?
C13 C8 C14 O9 -107.4(3) . . . . ?
C9 C8 C14 O9 129.8(3) . . . . ?
Dy1 O13 C15 C20 126.2(2) . . . . ?
Dy1 O13 C15 C16 -112.6(2) . . . . ?
Dy1 O13 C15 C21 6.1(3) . . . . ?
O13 C15 C16 C17 -66.3(3) . . . . ?
C20 C15 C16 C17 54.9(3) . . . . ?
C21 C15 C16 C17 177.6(2) . . . . ?
C15 C16 C17 O17 -178.6(2) . . . . ?
C15 C16 C17 C18 -57.4(3) . . . . ?
O17 C17 C18 O18 -62.5(3) . . . . ?
C16 C17 C18 O18 179.0(2) . . . . ?
O17 C17 C18 C19 177.0(2) . . . . ?
C16 C17 C18 C19 58.6(3) . . . . ?
O18 C18 C19 O16 -60.8(3) . . . . ?
C17 C18 C19 O16 58.1(3) . . . . ?
O18 C18 C19 C20 -179.4(2) . . . . ?
C17 C18 C19 C20 -60.5(3) . . . . ?
O13 C15 C20 C19 66.8(3) . . . . ?
C16 C15 C20 C19 -54.5(3) . . . . ?
C21 C15 C20 C19 -176.4(2) . . . . ?
O16 C19 C20 C15 -60.1(3) . . . . ?
C18 C19 C20 C15 58.9(3) . . . . ?
Dy1 O14 C21 O15 162.9(3) . . . . ?
Dy1 O14 C21 C15 -17.0(4) . . . . ?
O13 C15 C21 O15 -173.7(3) . . . . ?
C20 C15 C21 O15 66.9(4) . . . . ?
C16 C15 C21 O15 -55.0(4) . . . . ?
O13 C15 C21 O14 6.1(4) . . . . ?
C20 C15 C21 O14 -113.2(3) . . . . ?
C16 C15 C21 O14 124.9(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.993
_diffrn_reflns_theta_full        68.32
_diffrn_measured_fraction_theta_full 0.993
_refine_diff_density_max         0.506
_refine_diff_density_min         -0.849
_refine_diff_density_rms         0.073
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mo_dyyl1_0m
_audit_block_doi                 10.5517/cc13l7rp
_database_code_depnum_ccdc_archive 'CCDC 1030432'
_audit_update_record             
;
2014-10-22 deposited with the CCDC.
2015-06-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C42 H90 Dy O48 Y'
_chemical_formula_weight         1614.55
_chemical_absolute_configuration rmad

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Y Y -2.7962 3.5667 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P21

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   6.0796(2)
_cell_length_b                   25.2483(7)
_cell_length_c                   10.5544(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 105.6740(10)
_cell_angle_gamma                90.00
_cell_volume                     1559.85(8)
_cell_formula_units_Z            1
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.719
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             831
_exptl_absorpt_coefficient_mu    2.231
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  0.646
_exptl_absorpt_correction_T_max  0.640
_exptl_absorpt_process_details   
;
G. M. Sheldrick, (1996). SADABS. Program for Empirical Absorption Correction. University of Gottingen, Germany.
;

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            17422
_diffrn_reflns_av_R_equivalents  0.0198
_diffrn_reflns_av_sigmaI/netI    0.0190
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_theta_min         1.61
_diffrn_reflns_theta_max         25.01
_reflns_number_total             5479
_reflns_number_gt                5432
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0180P)²+0.5580P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.016(3)
_refine_ls_number_reflns         5479
_refine_ls_number_parameters     415
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0144
_refine_ls_R_factor_gt           0.0142
_refine_ls_wR_factor_ref         0.0362
_refine_ls_wR_factor_gt          0.0361
_refine_ls_goodness_of_fit_ref   1.064
_refine_ls_restrained_S_all      1.064
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 1.097685(16) 0.253050(5) 0.113251(9) 0.00742(4) Uani 0.50 1 d P . .
Y1 Y 1.097685(16) 0.253050(5) 0.113251(9) 0.00742(4) Uani 0.50 1 d P . .
O1 O 1.0389(3) 0.16056(5) 0.10007(14) 0.0123(3) Uani 1 1 d . . .
H1 H 1.0720 0.1484 0.1775 0.018 Uiso 1 1 d R . .
O2 O 1.1588(2) 0.21487(5) -0.07267(14) 0.0124(3) Uani 1 1 d . . .
O3 O 1.2342(3) 0.14623(6) -0.18641(14) 0.0160(3) Uani 1 1 d . . .
O4 O 0.6895(3) 0.01671(6) -0.05005(15) 0.0173(3) Uani 1 1 d . . .
H4 H 0.7046 -0.0118 -0.0213 0.026 Uiso 1 1 d R . .
O5 O 1.0006(3) -0.01266(6) 0.20072(15) 0.0188(3) Uani 1 1 d . . .
H5 H 0.8579 -0.0115 0.1854 0.028 Uiso 1 1 d R . .
O6 O 1.1943(3) 0.08790(6) 0.27470(14) 0.0199(3) Uani 1 1 d . . .
H6 H 1.1559 0.0677 0.3283 0.030 Uiso 1 1 d R . .
O7 O 0.3237(2) 0.22099(5) 0.32006(13) 0.0103(3) Uani 1 1 d . . .
H7 H 0.2985 0.2251 0.3916 0.015 Uiso 1 1 d R . .
O8 O 0.8579(2) 0.23943(5) 0.25280(13) 0.0117(3) Uani 1 1 d . . .
O9 O 0.4955(2) 0.25461(9) 0.14382(11) 0.0158(3) Uani 1 1 d . . .
O10 O 0.7086(3) 0.10652(6) 0.58995(15) 0.0171(3) Uani 1 1 d . . .
H10 H 0.6233 0.0886 0.6240 0.026 Uiso 1 1 d R . .
O11 O 0.6170(3) 0.18733(6) 0.76642(13) 0.0144(3) Uani 1 1 d . . .
H11 H 0.4793 0.1784 0.7497 0.022 Uiso 1 1 d R . .
O12 O 0.3210(2) 0.24718(8) 0.55359(12) 0.0162(3) Uani 1 1 d . . .
H12 H 0.2644 0.2572 0.6124 0.024 Uiso 1 1 d R . .
O13 O 1.1274(3) 0.33029(5) 0.24273(14) 0.0127(3) Uani 1 1 d . . .
H13 H 1.0766 0.3371 0.3079 0.019 Uiso 1 1 d R . .
O14 O 1.1490(3) 0.32937(6) 0.00629(14) 0.0147(3) Uani 1 1 d . . .
O15 O 1.2885(3) 0.41081(6) 0.00903(16) 0.0190(4) Uani 1 1 d . . .
O16 O 0.9561(3) 0.38317(6) 0.40217(15) 0.0167(3) Uani 1 1 d . . .
H16 H 0.8755 0.3892 0.4538 0.025 Uiso 1 1 d R . .
O17 O 1.6451(3) 0.42342(7) 0.50666(15) 0.0195(3) Uani 1 1 d . . .
H17 H 1.6735 0.4113 0.5835 0.029 Uiso 1 1 d R . .
O18 O 1.2407(3) 0.45904(6) 0.56816(14) 0.0185(3) Uani 1 1 d . . .
H18 H 1.1614 0.4859 0.5723 0.028 Uiso 1 1 d R . .
O19 O 0.7358(2) 0.25988(7) -0.03680(12) 0.0142(3) Uani 1 1 d . . .
H19A H 0.6266 0.2614 0.0042 0.021 Uiso 1 1 d R . .
H19B H 0.7035 0.2379 -0.0956 0.021 Uiso 1 1 d R . .
C1 C 1.1137(4) 0.12749(8) 0.0070(2) 0.0107(4) Uani 1 1 d . . .
C2 C 0.9229(4) 0.09052(8) -0.0630(2) 0.0120(4) Uani 1 1 d . . .
H2A H 0.9690 0.0718 -0.1319 0.014 Uiso 1 1 calc R . .
H2B H 0.7884 0.1113 -0.1043 0.014 Uiso 1 1 calc R . .
C3 C 0.8617(4) 0.05034(8) 0.0297(2) 0.0128(4) Uani 1 1 d . . .
H3 H 0.7962 0.0693 0.0919 0.015 Uiso 1 1 calc R . .
C4 C 1.0684(4) 0.01935(8) 0.1070(2) 0.0139(4) Uani 1 1 d . . .
H4A H 1.1228 -0.0035 0.0467 0.017 Uiso 1 1 calc R . .
C5 C 1.2615(4) 0.05669(8) 0.1777(2) 0.0159(4) Uani 1 1 d . . .
H5A H 1.3965 0.0357 0.2209 0.019 Uiso 1 1 calc R . .
C6 C 1.3235(4) 0.09528(8) 0.0811(2) 0.0144(4) Uani 1 1 d . . .
H6A H 1.3827 0.0757 0.0184 0.017 Uiso 1 1 calc R . .
H6B H 1.4421 0.1192 0.1287 0.017 Uiso 1 1 calc R . .
C7 C 1.1753(3) 0.16552(8) -0.09274(19) 0.0108(4) Uani 1 1 d . . .
C8 C 0.5700(3) 0.22380(7) 0.36441(19) 0.0089(4) Uani 1 1 d . . .
C9 C 0.6691(3) 0.17026(8) 0.41956(19) 0.0109(4) Uani 1 1 d . . .
H9A H 0.6157 0.1431 0.3534 0.013 Uiso 1 1 calc R . .
H9B H 0.8344 0.1716 0.4397 0.013 Uiso 1 1 calc R . .
C10 C 0.5998(3) 0.15558(8) 0.54366(19) 0.0110(4) Uani 1 1 d . . .
H10A H 0.4337 0.1510 0.5217 0.013 Uiso 1 1 calc R . .
C11 C 0.6713(3) 0.19931(8) 0.64634(19) 0.0108(4) Uani 1 1 d . . .
H11A H 0.8376 0.2031 0.6663 0.013 Uiso 1 1 calc R . .
C12 C 0.5653(3) 0.25171(14) 0.59123(16) 0.0118(3) Uani 1 1 d . . .
H12A H 0.6121 0.2793 0.6583 0.014 Uiso 1 1 calc R . .
C13 C 0.6409(3) 0.26694(7) 0.47002(19) 0.0116(4) Uani 1 1 d . . .
H13A H 0.8055 0.2713 0.4938 0.014 Uiso 1 1 calc R . .
H13B H 0.5715 0.3004 0.4355 0.014 Uiso 1 1 calc R . .
C14 C 0.6480(3) 0.24024(6) 0.24404(19) 0.0093(4) Uani 1 1 d . . .
C15 C 1.1953(4) 0.38136(8) 0.2024(2) 0.0112(4) Uani 1 1 d . . .
C16 C 1.4272(4) 0.39717(8) 0.29261(19) 0.0121(4) Uani 1 1 d . . .
H16A H 1.4803 0.4288 0.2577 0.015 Uiso 1 1 calc R . .
H16B H 1.5361 0.3691 0.2928 0.015 Uiso 1 1 calc R . .
C17 C 1.4207(4) 0.40787(8) 0.4343(2) 0.0138(4) Uani 1 1 d . . .
H17A H 1.3784 0.3753 0.4723 0.017 Uiso 1 1 calc R . .
C18 C 1.2457(4) 0.45059(8) 0.4357(2) 0.0134(4) Uani 1 1 d . . .
H18A H 1.2895 0.4835 0.3998 0.016 Uiso 1 1 calc R . .
C19 C 1.0132(4) 0.43237(8) 0.3508(2) 0.0144(4) Uani 1 1 d . . .
H19 H 0.8973 0.4590 0.3533 0.017 Uiso 1 1 calc R . .
C20 C 1.0174(4) 0.42298(8) 0.2080(2) 0.0139(4) Uani 1 1 d . . .
H20A H 0.8680 0.4113 0.1566 0.017 Uiso 1 1 calc R . .
H20B H 1.0531 0.4559 0.1703 0.017 Uiso 1 1 calc R . .
C21 C 1.2129(4) 0.37362(8) 0.0606(2) 0.0122(4) Uani 1 1 d . . .
O20 O 1.0260(3) 0.05185(6) 0.48545(15) 0.0194(3) Uani 1 1 d . . .
H20C H 0.9328 0.0711 0.5123 0.029 Uiso 1 1 d R . .
H20D H 1.1487 0.0486 0.5467 0.029 Uiso 1 1 d R . .
O21 O 1.4006(3) 0.05724(6) 0.71850(15) 0.0183(3) Uani 1 1 d . . .
H21A H 1.3280 0.0825 0.7418 0.027 Uiso 1 1 d R . .
H21B H 1.4893 0.0442 0.7868 0.027 Uiso 1 1 d R . .
O22 O 1.1257(3) 0.28935(6) 0.72062(14) 0.0199(3) Uani 1 1 d . . .
H22A H 1.1916 0.3188 0.7448 0.030 Uiso 1 1 d R . .
H22B H 1.1496 0.2743 0.7855 0.030 Uiso 1 1 d R . .
O23 O 0.7793(3) 0.38990(7) -0.22649(17) 0.0260(4) Uani 1 1 d . . .
H23A H 0.8730 0.3650 -0.1976 0.039 Uiso 1 1 d R . .
H23B H 0.6533 0.3833 -0.2094 0.039 Uiso 1 1 d R . .
O24 O 1.3373(3) 0.38584(6) -0.22996(15) 0.0211(3) Uani 1 1 d . . .
H24A H 1.2751 0.4075 -0.2902 0.032 Uiso 1 1 d R . .
H24B H 1.3287 0.3977 -0.1561 0.032 Uiso 1 1 d R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O14 2.2968(14) . ?
Dy1 O2 2.3047(14) . ?
Dy1 O19 2.3441(13) . ?
Dy1 O9 2.3523(12) 1_655 ?
Dy1 O13 2.3600(13) . ?
Dy1 O8 2.3606(13) . ?
Dy1 O1 2.3607(14) . ?
Dy1 O7 2.3848(13) 1_655 ?
O1 C1 1.453(2) . ?
O1 H1 0.8444 . ?
O2 C7 1.272(2) . ?
O3 C7 1.239(3) . ?
O4 C3 1.432(2) . ?
O4 H4 0.7767 . ?
O5 C4 1.422(2) . ?
O5 H5 0.8389 . ?
O6 C5 1.436(3) . ?
O6 H6 0.8394 . ?
O7 C8 1.445(2) . ?
O7 Y1 2.3848(13) 1_455 ?
O7 Dy1 2.3848(13) 1_455 ?
O7 H7 0.8163 . ?
O8 C14 1.255(2) . ?
O9 C14 1.257(2) . ?
O9 Y1 2.3523(12) 1_455 ?
O9 Dy1 2.3523(12) 1_455 ?
O10 C10 1.427(2) . ?
O10 H10 0.8395 . ?
O11 C11 1.426(2) . ?
O11 H11 0.8386 . ?
O12 C12 1.435(2) . ?
O12 H12 0.8260 . ?
O13 C15 1.452(2) . ?
O13 H13 0.8444 . ?
O14 C21 1.268(3) . ?
O15 C21 1.234(3) . ?
O16 C19 1.435(3) . ?
O16 H16 0.8392 . ?
O17 C17 1.427(3) . ?
O17 H17 0.8391 . ?
O18 C18 1.422(2) . ?
O18 H18 0.8388 . ?
O19 H19A 0.8862 . ?
O19 H19B 0.8165 . ?
C1 C2 1.516(3) . ?
C1 C6 1.537(3) . ?
C1 C7 1.544(3) . ?
C2 C3 1.523(3) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C4 1.518(3) . ?
C3 H3 0.9800 . ?
C4 C5 1.533(3) . ?
C4 H4A 0.9800 . ?
C5 C6 1.529(3) . ?
C5 H5A 0.9800 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C8 C14 1.528(3) . ?
C8 C9 1.530(3) . ?
C8 C13 1.534(3) . ?
C9 C10 1.526(3) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C11 1.526(3) . ?
C10 H10A 0.9800 . ?
C11 C12 1.517(4) . ?
C11 H11A 0.9800 . ?
C12 C13 1.521(3) . ?
C12 H12A 0.9800 . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C15 C20 1.521(3) . ?
C15 C16 1.526(3) . ?
C15 C21 1.542(3) . ?
C16 C17 1.530(3) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C17 C18 1.518(3) . ?
C17 H17A 0.9800 . ?
C18 C19 1.526(3) . ?
C18 H18A 0.9800 . ?
C19 C20 1.533(3) . ?
C19 H19 0.9800 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
O20 H20C 0.8508 . ?
O20 H20D 0.8485 . ?
O21 H21A 0.8483 . ?
O21 H21B 0.8422 . ?
O22 H22A 0.8511 . ?
O22 H22B 0.7620 . ?
O23 H23A 0.8488 . ?
O23 H23B 0.8499 . ?
O24 H24A 0.8470 . ?
O24 H24B 0.8495 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O14 Dy1 O2 81.83(5) . . ?
O14 Dy1 O19 80.42(6) . . ?
O2 Dy1 O19 78.07(5) . . ?
O14 Dy1 O9 77.42(6) . 1_655 ?
O2 Dy1 O9 74.19(5) . 1_655 ?
O19 Dy1 O9 146.50(4) . 1_655 ?
O14 Dy1 O13 65.92(5) . . ?
O2 Dy1 O13 146.50(5) . . ?
O19 Dy1 O13 103.98(6) . . ?
O9 Dy1 O13 89.52(6) 1_655 . ?
O14 Dy1 O8 128.15(5) . . ?
O2 Dy1 O8 137.65(5) . . ?
O19 Dy1 O8 78.89(5) . . ?
O9 Dy1 O8 134.60(4) 1_655 . ?
O13 Dy1 O8 73.90(5) . . ?
O14 Dy1 O1 147.08(5) . . ?
O2 Dy1 O1 65.97(5) . . ?
O19 Dy1 O1 86.18(6) . . ?
O9 Dy1 O1 99.12(7) 1_655 . ?
O13 Dy1 O1 146.95(5) . . ?
O8 Dy1 O1 77.49(4) . . ?
O14 Dy1 O7 127.84(5) . 1_655 ?
O2 Dy1 O7 116.86(5) . 1_655 ?
O19 Dy1 O7 147.87(5) . 1_655 ?
O9 Dy1 O7 64.11(4) 1_655 1_655 ?
O13 Dy1 O7 79.36(5) . 1_655 ?
O8 Dy1 O7 71.32(5) . 1_655 ?
O1 Dy1 O7 76.04(5) . 1_655 ?
C1 O1 Dy1 122.57(11) . . ?
C1 O1 H1 114.1 . . ?
Dy1 O1 H1 108.0 . . ?
C7 O2 Dy1 126.12(13) . . ?
C3 O4 H4 109.3 . . ?
C4 O5 H5 109.0 . . ?
C5 O6 H6 109.4 . . ?
C8 O7 Y1 124.77(11) . 1_455 ?
C8 O7 Dy1 124.77(11) . 1_455 ?
Y1 O7 Dy1 0.000(7) 1_455 1_455 ?
C8 O7 H7 97.5 . . ?
Y1 O7 H7 126.7 1_455 . ?
Dy1 O7 H7 126.7 1_455 . ?
C14 O8 Dy1 137.64(13) . . ?
C14 O9 Y1 127.43(12) . 1_455 ?
C14 O9 Dy1 127.43(12) . 1_455 ?
Y1 O9 Dy1 0.000(8) 1_455 1_455 ?
C10 O10 H10 109.4 . . ?
C11 O11 H11 109.2 . . ?
C12 O12 H12 112.2 . . ?
C15 O13 Dy1 123.18(11) . . ?
C15 O13 H13 104.7 . . ?
Dy1 O13 H13 130.7 . . ?
C21 O14 Dy1 125.66(13) . . ?
C19 O16 H16 109.3 . . ?
C17 O17 H17 109.6 . . ?
C18 O18 H18 109.7 . . ?
Dy1 O19 H19A 111.3 . . ?
Dy1 O19 H19B 116.9 . . ?
H19A O19 H19B 110.1 . . ?
O1 C1 C2 110.18(17) . . ?
O1 C1 C6 109.19(17) . . ?
C2 C1 C6 110.04(17) . . ?
O1 C1 C7 106.35(15) . . ?
C2 C1 C7 110.21(17) . . ?
C6 C1 C7 110.80(17) . . ?
C1 C2 C3 112.61(17) . . ?
C1 C2 H2A 109.1 . . ?
C3 C2 H2A 109.1 . . ?
C1 C2 H2B 109.1 . . ?
C3 C2 H2B 109.1 . . ?
H2A C2 H2B 107.8 . . ?
O4 C3 C4 112.22(16) . . ?
O4 C3 C2 106.51(16) . . ?
C4 C3 C2 112.24(17) . . ?
O4 C3 H3 108.6 . . ?
C4 C3 H3 108.6 . . ?
C2 C3 H3 108.6 . . ?
O5 C4 C3 108.28(17) . . ?
O5 C4 C5 109.83(16) . . ?
C3 C4 C5 111.00(17) . . ?
O5 C4 H4A 109.2 . . ?
C3 C4 H4A 109.2 . . ?
C5 C4 H4A 109.2 . . ?
O6 C5 C6 107.13(17) . . ?
O6 C5 C4 110.88(17) . . ?
C6 C5 C4 111.22(17) . . ?
O6 C5 H5A 109.2 . . ?
C6 C5 H5A 109.2 . . ?
C4 C5 H5A 109.2 . . ?
C5 C6 C1 110.87(18) . . ?
C5 C6 H6A 109.5 . . ?
C1 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
C1 C6 H6B 109.5 . . ?
H6A C6 H6B 108.1 . . ?
O3 C7 O2 124.80(18) . . ?
O3 C7 C1 118.38(17) . . ?
O2 C7 C1 116.81(17) . . ?
O7 C8 C14 105.72(15) . . ?
O7 C8 C9 110.29(15) . . ?
C14 C8 C9 112.20(15) . . ?
O7 C8 C13 109.48(15) . . ?
C14 C8 C13 108.77(15) . . ?
C9 C8 C13 110.27(16) . . ?
C10 C9 C8 111.70(16) . . ?
C10 C9 H9A 109.3 . . ?
C8 C9 H9A 109.3 . . ?
C10 C9 H9B 109.3 . . ?
C8 C9 H9B 109.3 . . ?
H9A C9 H9B 107.9 . . ?
O10 C10 C11 111.60(16) . . ?
O10 C10 C9 107.14(15) . . ?
C11 C10 C9 110.00(16) . . ?
O10 C10 H10A 109.4 . . ?
C11 C10 H10A 109.4 . . ?
C9 C10 H10A 109.4 . . ?
O11 C11 C12 110.44(15) . . ?
O11 C11 C10 112.82(16) . . ?
C12 C11 C10 110.41(16) . . ?
O11 C11 H11A 107.7 . . ?
C12 C11 H11A 107.7 . . ?
C10 C11 H11A 107.7 . . ?
O12 C12 C11 109.7(2) . . ?
O12 C12 C13 108.23(15) . . ?
C11 C12 C13 110.44(18) . . ?
O12 C12 H12A 109.5 . . ?
C11 C12 H12A 109.5 . . ?
C13 C12 H12A 109.5 . . ?
C12 C13 C8 110.01(17) . . ?
C12 C13 H13A 109.7 . . ?
C8 C13 H13A 109.7 . . ?
C12 C13 H13B 109.7 . . ?
C8 C13 H13B 109.7 . . ?
H13A C13 H13B 108.2 . . ?
O8 C14 O9 124.82(17) . . ?
O8 C14 C8 118.16(17) . . ?
O9 C14 C8 117.01(16) . . ?
O13 C15 C20 109.93(16) . . ?
O13 C15 C16 109.70(16) . . ?
C20 C15 C16 109.99(16) . . ?
O13 C15 C21 105.78(15) . . ?
C20 C15 C21 111.23(17) . . ?
C16 C15 C21 110.13(17) . . ?
C15 C16 C17 113.12(17) . . ?
C15 C16 H16A 109.0 . . ?
C17 C16 H16A 109.0 . . ?
C15 C16 H16B 109.0 . . ?
C17 C16 H16B 109.0 . . ?
H16A C16 H16B 107.8 . . ?
O17 C17 C18 111.75(17) . . ?
O17 C17 C16 107.38(16) . . ?
C18 C17 C16 109.79(17) . . ?
O17 C17 H17A 109.3 . . ?
C18 C17 H17A 109.3 . . ?
C16 C17 H17A 109.3 . . ?
O18 C18 C17 108.53(16) . . ?
O18 C18 C19 111.11(17) . . ?
C17 C18 C19 108.69(16) . . ?
O18 C18 H18A 109.5 . . ?
C17 C18 H18A 109.5 . . ?
C19 C18 H18A 109.5 . . ?
O16 C19 C18 108.62(17) . . ?
O16 C19 C20 107.90(16) . . ?
C18 C19 C20 111.43(17) . . ?
O16 C19 H19 109.6 . . ?
C18 C19 H19 109.6 . . ?
C20 C19 H19 109.6 . . ?
C15 C20 C19 110.25(17) . . ?
C15 C20 H20A 109.6 . . ?
C19 C20 H20A 109.6 . . ?
C15 C20 H20B 109.6 . . ?
C19 C20 H20B 109.6 . . ?
H20A C20 H20B 108.1 . . ?
O15 C21 O14 125.2(2) . . ?
O15 C21 C15 117.60(18) . . ?
O14 C21 C15 117.21(18) . . ?
H20C O20 H20D 109.2 . . ?
H21A O21 H21B 108.0 . . ?
H22A O22 H22B 101.9 . . ?
H23A O23 H23B 109.5 . . ?
H24A O24 H24B 109.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O14 Dy1 O1 C1 26.2(2) . . . . ?
O2 Dy1 O1 C1 13.37(14) . . . . ?
O19 Dy1 O1 C1 92.01(15) . . . . ?
O9 Dy1 O1 C1 -54.69(15) 1_655 . . . ?
O13 Dy1 O1 C1 -158.04(13) . . . . ?
O8 Dy1 O1 C1 171.46(15) . . . . ?
O7 Dy1 O1 C1 -114.98(15) 1_655 . . . ?
O14 Dy1 O2 C7 174.73(16) . . . . ?
O19 Dy1 O2 C7 -103.41(16) . . . . ?
O9 Dy1 O2 C7 95.57(16) 1_655 . . . ?
O13 Dy1 O2 C7 159.24(14) . . . . ?
O8 Dy1 O2 C7 -45.02(19) . . . . ?
O1 Dy1 O2 C7 -12.28(15) . . . . ?
O7 Dy1 O2 C7 46.27(17) 1_655 . . . ?
O14 Dy1 O8 C14 63.57(18) . . . . ?
O2 Dy1 O8 C14 -62.83(18) . . . . ?
O19 Dy1 O8 C14 -4.72(16) . . . . ?
O9 Dy1 O8 C14 176.25(16) 1_655 . . . ?
O13 Dy1 O8 C14 103.52(17) . . . . ?
O1 Dy1 O8 C14 -93.23(16) . . . . ?
O7 Dy1 O8 C14 -172.52(17) 1_655 . . . ?
O14 Dy1 O13 C15 -9.87(13) . . . . ?
O2 Dy1 O13 C15 6.96(19) . . . . ?
O19 Dy1 O13 C15 -82.47(14) . . . . ?
O9 Dy1 O13 C15 66.55(14) 1_655 . . . ?
O8 Dy1 O13 C15 -156.29(15) . . . . ?
O1 Dy1 O13 C15 172.66(13) . . . . ?
O7 Dy1 O13 C15 130.27(15) 1_655 . . . ?
O2 Dy1 O14 C21 -156.24(18) . . . . ?
O19 Dy1 O14 C21 124.57(18) . . . . ?
O9 Dy1 O14 C21 -80.71(17) 1_655 . . . ?
O13 Dy1 O14 C21 14.47(16) . . . . ?
O8 Dy1 O14 C21 56.98(19) . . . . ?
O1 Dy1 O14 C21 -168.07(15) . . . . ?
O7 Dy1 O14 C21 -38.44(19) 1_655 . . . ?
Dy1 O1 C1 C2 -132.62(14) . . . . ?
Dy1 O1 C1 C6 106.41(16) . . . . ?
Dy1 O1 C1 C7 -13.2(2) . . . . ?
O1 C1 C2 C3 -65.5(2) . . . . ?
C6 C1 C2 C3 55.0(2) . . . . ?
C7 C1 C2 C3 177.45(17) . . . . ?
C1 C2 C3 O4 -177.09(16) . . . . ?
C1 C2 C3 C4 -53.9(2) . . . . ?
O4 C3 C4 O5 -66.5(2) . . . . ?
C2 C3 C4 O5 173.57(16) . . . . ?
O4 C3 C4 C5 172.86(17) . . . . ?
C2 C3 C4 C5 53.0(2) . . . . ?
O5 C4 C5 O6 -55.6(2) . . . . ?
C3 C4 C5 O6 64.1(2) . . . . ?
O5 C4 C5 C6 -174.68(17) . . . . ?
C3 C4 C5 C6 -55.0(2) . . . . ?
O6 C5 C6 C1 -64.1(2) . . . . ?
C4 C5 C6 C1 57.2(2) . . . . ?
O1 C1 C6 C5 64.5(2) . . . . ?
C2 C1 C6 C5 -56.6(2) . . . . ?
C7 C1 C6 C5 -178.71(17) . . . . ?
Dy1 O2 C7 O3 -171.19(15) . . . . ?
Dy1 O2 C7 C1 9.6(2) . . . . ?
O1 C1 C7 O3 -176.65(17) . . . . ?
C2 C1 C7 O3 -57.2(2) . . . . ?
C6 C1 C7 O3 64.8(2) . . . . ?
O1 C1 C7 O2 2.6(2) . . . . ?
C2 C1 C7 O2 121.99(19) . . . . ?
C6 C1 C7 O2 -116.0(2) . . . . ?
Y1 O7 C8 C14 -11.03(18) 1_455 . . . ?
Dy1 O7 C8 C14 -11.03(18) 1_455 . . . ?
Y1 O7 C8 C9 -132.53(13) 1_455 . . . ?
Dy1 O7 C8 C9 -132.53(13) 1_455 . . . ?
Y1 O7 C8 C13 105.97(15) 1_455 . . . ?
Dy1 O7 C8 C13 105.97(15) 1_455 . . . ?
O7 C8 C9 C10 -65.3(2) . . . . ?
C14 C8 C9 C10 177.14(16) . . . . ?
C13 C8 C9 C10 55.7(2) . . . . ?
C8 C9 C10 O10 -177.47(16) . . . . ?
C8 C9 C10 C11 -56.0(2) . . . . ?
O10 C10 C11 O11 -59.6(2) . . . . ?
C9 C10 C11 O11 -178.37(16) . . . . ?
O10 C10 C11 C12 176.30(15) . . . . ?
C9 C10 C11 C12 57.5(2) . . . . ?
O11 C11 C12 O12 -65.93(19) . . . . ?
C10 C11 C12 O12 59.54(19) . . . . ?
O11 C11 C12 C13 174.85(16) . . . . ?
C10 C11 C12 C13 -59.7(2) . . . . ?
O12 C12 C13 C8 -61.1(3) . . . . ?
C11 C12 C13 C8 59.0(2) . . . . ?
O7 C8 C13 C12 64.9(2) . . . . ?
C14 C8 C13 C12 179.93(16) . . . . ?
C9 C8 C13 C12 -56.6(2) . . . . ?
Dy1 O8 C14 O9 -6.3(3) . . . . ?
Dy1 O8 C14 C8 175.08(11) . . . . ?
Y1 O9 C14 O8 176.24(14) 1_455 . . . ?
Dy1 O9 C14 O8 176.24(14) 1_455 . . . ?
Y1 O9 C14 C8 -5.2(3) 1_455 . . . ?
Dy1 O9 C14 C8 -5.2(3) 1_455 . . . ?
O7 C8 C14 O8 -171.70(14) . . . . ?
C9 C8 C14 O8 -51.4(2) . . . . ?
C13 C8 C14 O8 70.8(2) . . . . ?
O7 C8 C14 O9 9.6(2) . . . . ?
C9 C8 C14 O9 129.9(2) . . . . ?
C13 C8 C14 O9 -107.9(2) . . . . ?
Dy1 O13 C15 C20 126.05(14) . . . . ?
Dy1 O13 C15 C16 -112.89(15) . . . . ?
Dy1 O13 C15 C21 5.9(2) . . . . ?
O13 C15 C16 C17 -66.4(2) . . . . ?
C20 C15 C16 C17 54.6(2) . . . . ?
C21 C15 C16 C17 177.55(16) . . . . ?
C15 C16 C17 O17 -178.57(16) . . . . ?
C15 C16 C17 C18 -56.9(2) . . . . ?
O17 C17 C18 O18 -61.9(2) . . . . ?
C16 C17 C18 O18 179.03(16) . . . . ?
O17 C17 C18 C19 177.10(16) . . . . ?
C16 C17 C18 C19 58.1(2) . . . . ?
O18 C18 C19 O16 -61.1(2) . . . . ?
C17 C18 C19 O16 58.3(2) . . . . ?
O18 C18 C19 C20 -179.80(16) . . . . ?
C17 C18 C19 C20 -60.4(2) . . . . ?
O13 C15 C20 C19 66.6(2) . . . . ?
C16 C15 C20 C19 -54.3(2) . . . . ?
C21 C15 C20 C19 -176.60(17) . . . . ?
O16 C19 C20 C15 -60.2(2) . . . . ?
C18 C19 C20 C15 58.9(2) . . . . ?
Dy1 O14 C21 O15 163.01(17) . . . . ?
Dy1 O14 C21 C15 -16.8(3) . . . . ?
O13 C15 C21 O15 -173.70(19) . . . . ?
C20 C15 C21 O15 67.0(3) . . . . ?
C16 C15 C21 O15 -55.2(3) . . . . ?
O13 C15 C21 O14 6.1(3) . . . . ?
C20 C15 C21 O14 -113.2(2) . . . . ?
C16 C15 C21 O14 124.6(2) . . . . ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        25.01
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         0.342
_refine_diff_density_min         -0.372
_refine_diff_density_rms         0.044
