{"text_format":"2","workbook":"xls","n_sheets":2,"sheets":["Final results","Raw"],"not_rendered":{"charts":4,"images":0,"macros":0,"external_links":2,"defined_names":0,"comments":0,"pivot_tables":0},"unopened":[],"bounds":{"document_bytes":16777216,"sheet_cells":100000,"run_cost":"one","rows_first":2000,"rows_last":500,"rows_between":2000,"halvings":0,"cell_chars":16384,"cell_head_chars":4096},"cells_cut":0,"cells_raw":0,"read":"whole","date_system":"1900","formulas":"cached_only"}

{"sheet":"Final results","index":0,"n_rows":58,"n_cols":9,"rows_kept":58,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
["April. 2010"]
[]
[null,"Cl precipitation"]
[null,"δ Ag (‰)","1SD","Measured 107Ag, V","Initial Ag, ng in 5 ml","% loss of Ag"]
[]
[]
[]
[]
["sample-1",-0.1888552369979868,0.020964975337946792,0.8,6000,96.49122807017544]
["sample-2",-0.18837213623439375,0.0418922637497753,0.7,6000,96.9298245614035]
["sample-3",-0.14710418253762736,0.033827044265084594,0.9,6000,96.05263157894737]
[0,-0.1747771852566693,0.02396674062535461,null,6000,96.49122807017545]
["Sample-4",-0.10769430870125607,0.015260368151824525,4,6000,82.45614035087719]
["Sample-5",-0.07768631895792577,0.028957848249394444,4.8,6000,78.94736842105263]
["Sample-6",-0.07302253850862694,0.03276259017246245,9,6000,60.52631578947369]
["Sample-7",0.0023411806240991595,0.02756951625298139,12.1,6000,46.92982456140351]
["Sample-8",-0.008658652148763046,0.025695756482764065,17.1,6000,25]
[]
[null,0,null,null,null,0]
[]
[]
[]
[]
[null,"PACS2+Ag supplement",{"$nulls":4},"Ag atomic weight in PACS-2≈Ag atomic weight in supplement"]
[null,"δ Ag (‰), measured","1SD","20ppm Ag supplement added (mg)","PACS-2 weight (g)","Theoretical R107/109","107Ag abundance","109Ag abundance","Theoretical δ Ag (‰)"]
["PACS-2",-0.025,0.019,0,0.25,1.0763530904999998,0.5183863454749918,0.48161365452500826,-0.025000000000052758]
["Sample2",0.2436128504804458,0.026641214220966453,6,0.25,1.0766128586672703,null,null,0.2163349999724229]
["Sample3",0.332790092718279,0.01927886573138583,10,0.25,1.076717470145795,null,null,0.3135232406725752]
["Sample4",0.4097251899887411,0.017246319517425238,15,0.25,1.0768093380899262,null,null,0.39887222906997977]
["Sample5",0.45168063323375307,0.03179607095619868,20,0.25,1.0768751492024,null,null,0.46001338040491113]
["Sample7",0.5341050558353988,0.027092785987312646,30,0.25,1.0769631462671356,null,null,0.5417661672790786]
["Sample8",0.629,0.02,46,0.25,1.0770441819958334,null,null,0.6170515950068012]
[]
["Ag supplement",0.83,0.04,80,0,1.0772733954,0.5185997171992665,0.4814002828007336,0.8300000000001084]
[]
[null,"PACS-2 Ag concentration: 1.22 ppm"]
[null,"Ag supplement concentration: 20 ppm"]
{"$rows_empty":11}
["UV photolysis"]
["Jan. 05, 2010"]
["Time (min)","δ Ag","1 sigma","Total loss  "]
[]
[25,0.04483546702842567,0.023682738508696222,12.857142857142856]
[60,0.022687155094036626,0.014086279766915963,19.999999999999986]
[120,0.028001263494448203,0.029887057161074693,25.357142857142854]
[210,-0.00284286218610319,0.025872602813315337,24.99999999999999]
[390,0.011018413571539654,0.024594706934711198,24.642857142857146]
[720,0.022742897489891334,0.02456756465579914,24.642857142857146]

{"sheet":"Raw","index":1,"n_rows":102,"n_cols":15,"rows_kept":102,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
[{"$nulls":8},"Cl precipitation"]
[null,"Data calculation can be done conveniently with use of Neptune software"]
["Note: ","1. Use 1.07638 for Ag107/Ag109 in method , choose exponential for mass bias correction to get corrected Pd104/Pd105 ratio in two adjacent standards"]
[null,"2. Input average value of corrected Pd104/Pd105 ratio, choose exponential for mass bias correction through saving the method file to get corrected Ag 107/Ag109 ratio in the sample"]
[]
["2010-04-27",{"$nulls":4},"Certified","Corrected ratio","Average","NIST 978a",{"$nulls":4},"Corrected ratio"]
["NIST 978a","Ag107 intensity","Ag109 intensity","Pd104 intensity","Pd105 intensity","Ag107/Ag109","Pd104/Pd105","Pd104/Pd105",null,"Ag107 intensity","Ag109 intensity","Pd104 intensity","Pd105 intensity","Ag107/Ag109","δ Ag"]
["Std1-1",1.2250782,2.5203272,0.51948977,0.50246167,1.07638,0.4963091,0.49631648,"Sample1-1",1.2933469,2.6616152,0.56777622,0.54960062,1.0762125,-0.15561418829768137]
["Std1-2",1.2048518,2.478942,0.50985756,0.49324151,1.07638,0.49632386,0.49631981999999997,"Sample1-2",1.3063352,2.6886371,0.57477444,0.55649949,1.076184,-0.18209182630657406]
["Std1-3",1.2210384,2.5125871,0.51716592,0.50043684,1.07638,0.49631578,0.496320255,"Sample1-3",1.3152606,2.7072641,0.5795581,0.5612477,1.0761678,-0.19714227317491062]
["Std1-4",1.2199944,2.5105836,0.51694096,0.50028507,1.07638,0.49632473,0.49631997,"Sample1-4",1.3172792,2.7115967,0.58015863,0.56189708,1.0761642,-0.2004868169233065]
["Std1-5",1.2343128,2.5401858,0.52332714,0.50650671,1.07638,0.49631521,0.496323355,"Sample1-5",1.3233525,2.7240589,0.58287524,0.56453741,1.0761551,-0.2089410802874614]
["Std1-6",1.2329106,2.5373748,0.5227722,0.50602618,1.07638,0.4963315]
[]
[{"$nulls":8},0,{"$nulls":4},1.0761767199999999,-0.1888552369979868]
[{"$nulls":8},"Si ",{"$nulls":4},2.256628230203342e-05,0.020964975337946792]
[]
[{"$nulls":5},"Certified","Corrected ratio","Average",{"$nulls":5},"Corrected ratio"]
["NIST 978a",{"$nulls":4},"Ag107/Ag109","Pd104/Pd105","Pd104/Pd105",{"$nulls":5},"Ag107/Ag109","δ Ag"]
["Std2-1",1.2329106,2.5373748,0.5227722,0.50602618,1.07638,0.4963315,0.496332015,"Sample2-1",1.1767174,2.421287,0.48072631,0.46522823,1.0762413,-0.1288578383098482]
["Std2-2",1.2274425,2.5256326,0.51997625,0.50313368,1.07638,0.49633253,0.49632326,"Sample2-2",1.1422101,2.3497953,0.46800559,0.45274924,1.0761735,-0.1918467455731543]
["Std2-3",1.1977776,2.4643878,0.50697865,0.49045236,1.07638,0.49631399,0.49630501,"Sample2-3",1.1242394,2.3127125,0.46274254,0.44760497,1.0761375,-0.22529218305800125]
["Std2-4",1.1964573,2.4615755,0.50622936,0.48966163,1.07638,0.49629603,0.496308845,"Sample2-4",1.1365165,2.3379857,0.46961602,0.45425572,1.0761336,-0.22891543878555964]
["Std2-5",1.2080477,2.4853212,0.51115259,0.49441513,1.07638,0.49632166,0.496316705,"Sample2-5",1.1545173,2.3748405,0.47728033,0.46159709,1.0762003,-0.16694847544540536]
["Std2-6",1.2148455,2.4993479,0.51411705,0.49729202,1.07638,0.49631175]
[]
[{"$nulls":8},0,{"$nulls":4},1.0761772399999998,-0.18837213623439375]
[{"$nulls":8},"Si ",{"$nulls":4},4.509199712224646e-05,0.0418922637497753]
[]
[{"$nulls":5},"Certified","Corrected ratio","Average",{"$nulls":5},"Corrected ratio"]
["NIST 978a",{"$nulls":4},"Ag107/Ag109","Pd104/Pd105","Pd104/Pd105",{"$nulls":5},"Ag107/Ag109","δ Ag"]
["Std3-1",1.2148455,2.4993479,0.51411705,0.49729202,1.07638,0.49631175,0.496324275,"Sample3-1",1.2953968,2.6647243,0.68582704,0.66332202,1.076259,-0.11241383154625417]
["Std3-2",1.2333329,2.537454,0.52239787,0.50538235,1.07638,0.4963368,0.49632594,"Sample3-2",1.3181896,2.711762,0.6987162,0.67589236,1.0762182,-0.15031866069592503]
["Std3-3",1.2576314,2.5876052,0.53316229,0.51581121,1.07638,0.49631508,0.496312785,"Sample3-3",1.3410631,2.7588627,0.71156178,0.68829699,1.0762423,-0.12792879837952853]
["Std3-4",1.2710105,2.6150502,0.53890119,0.52133179,1.07638,0.49631049,0.49631153,"Sample3-4",1.3539358,2.7852086,0.71828394,0.6947707,1.0761629,-0.20169456883256665]
["Std3-5",1.2735779,2.6202678,0.53970782,0.52208746,1.07638,0.49631257,0.496315195,"Sample3-5",1.3458089,2.7684496,0.713451,0.69004361,1.0762259,-0.14316505323386242]
["Std3-6",1.2634268,2.5993326,0.53510496,0.51761881,1.07638,0.49631782]
[]
[{"$nulls":8},0,{"$nulls":4},1.07622166,-0.14710418253762736]
[{"$nulls":8},"Si ",{"$nulls":4},3.64107548792808e-05,0.033827044265084594]
[]
[]
[{"$nulls":5},"Certified","Corrected ratio","Average",{"$nulls":5},"Corrected ratio"]
["NIST 978a",{"$nulls":4},"Ag107/Ag109","Pd104/Pd105","Pd104/Pd105",{"$nulls":5},"Ag107/Ag109","δ Ag"]
["Std4-1",1.3235034,2.724332,2.8804787,2.7892912,1.07638,0.49633393,0.496330815,"Sample4-1",1.3670435,2.8141504,2.9669092,2.8736305,1.0762573,-0.11399319942761998]
["Std4-2",1.3257,2.7291858,2.8875784,2.7967224,1.07638,0.4963277,0.49632981499999995,"Sample4-2",1.3745652,2.829777,2.9856406,2.8920435,1.0762551,-0.11603708727392359]
["Std4-3",1.3389631,2.7565185,2.9182424,2.8265595,1.07638,0.49633193,0.4963311,"Sample4-3",1.3887644,2.8592103,3.0195049,2.9252328,1.0762727,-0.09968598450338373]
["Std4-4",1.3506124,2.7805689,2.945177,2.8527672,1.07638,0.49633027,0.49633170000000004,"Sample4-4",1.4046569,2.8916028,3.0523684,2.9564951,1.076247,-0.12356231070809187]
["Std4-5",1.3605263,2.8007182,2.9651889,2.8716287,1.07638,0.49633313,0.49633403,"Sample4-5",1.4162118,2.9154133,3.0774867,2.9807568,1.0762883,-0.08519296159326117]
["Std4-6",1.3640805,2.8079681,2.9722407,2.8783626,1.07638,0.49633493]
[]
[{"$nulls":8},0,{"$nulls":4},1.07626408,-0.10769430870125607]
[{"$nulls":8},"Si ",{"$nulls":4},1.642596032517227e-05,0.015260368151824525]
[]
[{"$nulls":5},"Certified","Corrected ratio","Average",{"$nulls":5},"Corrected ratio"]
["NIST 978a",{"$nulls":4},"Ag107/Ag109","Pd104/Pd105","Pd104/Pd105",{"$nulls":5},"Ag107/Ag109","δ Ag"]
["Std5-1",1.3640805,2.8079681,2.9722407,2.8783626,1.07638,0.49633493,0.49633456,"Sample5-1",1.3443049,2.7672595,2.76524,2.6781129,1.0762947,-0.0792471060404587]
["Std5-2",1.3637249,2.8072722,2.9716257,2.8778271,1.07638,0.49633419,0.49633409500000003,"Sample5-2",1.3605149,2.8007404,2.7994168,2.7113275,1.0763382,-0.03883386907965747]
["Std5-3",1.3622098,2.8041209,2.9672778,2.8735534,1.07638,0.496334,0.49633209,"Sample5-3",1.338416,2.7552688,2.7535885,2.666978,1.0763135,-0.061781155354045936]
["Std5-4",1.3589643,2.7974975,2.9604372,2.8669995,1.07638,0.49633018,0.49633409,"Sample5-4",1.3674658,2.8149438,2.8134391,2.724819,1.0762778,-0.0949478808598414]
["Std5-5",1.3626138,2.8048505,2.9674522,2.8735853,1.07638,0.496338,0.496331305,"Sample5-5",1.3635988,2.8068464,2.8047797,2.7162485,1.0762577,-0.11362158345562534]
["Std5-6",1.3661495,2.8121798,2.975162,2.8809864,1.07638,0.49632461]
[]
[{"$nulls":8},0,{"$nulls":4},1.07629638,-0.07768631895792577]
[{"$nulls":8},"Si ",{"$nulls":4},3.116964617983444e-05,0.028957848249394444]
[]
[]
[{"$nulls":5},"Certified","Corrected ratio","Average",{"$nulls":5},"Corrected ratio"]
["NIST 978a",{"$nulls":4},"Ag107/Ag109","Pd104/Pd105","Pd104/Pd105",{"$nulls":5},"Ag107/Ag109","δ Ag"]
["Std6-1",1.3139256,2.7044395,2.8562991,2.7653242,1.07638,0.49631668,0.49631736000000004,"Sample6-1",1.297242,2.6700892,2.6456658,2.5616736,1.0762581,-0.11324996748351968]
["Std6-2",1.3258307,2.7289425,2.8832322,2.7914299,1.07638,0.49631804,0.49632506,"Sample6-2",1.3005164,2.6769412,2.6535636,2.5694478,1.0763056,-0.06912057080210587]
["Std6-3",1.3093951,2.6952872,2.848904,2.7586589,1.07638,0.49633208,0.49632191999999997,"Sample6-3",1.2990847,2.6739785,2.6505583,2.5664616,1.0763329,-0.04375778070941916]
["Std6-4",1.3122757,2.7011279,2.854163,2.7633907,1.07638,0.49631176,0.49631661,"Sample6-4",1.3007973,2.6775185,2.6548507,2.5707466,1.0762731,-0.09931436853138909]
["Std6-5",1.3252707,2.727818,2.882751,2.7910454,1.07638,0.49632146,0.49632769499999996,"Sample6-5",1.3155974,2.7078993,2.6848882,2.599617,1.0763373,-0.03967000501670093]
["Std6-6",1.3235034,2.724332,2.8804787,2.7892912,1.07638,0.49633393]
[]
[{"$nulls":8},0,{"$nulls":4},1.0763013999999997,-0.07302253850862694]
[{"$nulls":8},"Si ",{"$nulls":4},3.526500761273089e-05,0.03276259017246245]
[]
[{"$nulls":5},"Certified","Corrected ratio","Average",{"$nulls":5},"Corrected ratio"]
["NIST 978a",{"$nulls":4},"Ag107/Ag109","Pd104/Pd105","Pd104/Pd105",{"$nulls":5},"Ag107/Ag109","δ Ag"]
["Std7-1",1.3074654,2.6903203,2.8381655,2.7461799,1.07638,0.4963225,0.496318535,"Sample7-1",1.2338722,2.5388825,2.4859098,2.4053147,1.0763905,0.009754919266580231]
["Std7-2",1.3146737,2.705413,2.8546415,2.7625799,1.07638,0.49631457,0.496320765,"Sample7-2",1.233975,2.5393157,2.4864996,2.4062262,1.0764191,0.03632546126852709]
["Std7-3",1.3045301,2.6846894,2.8333933,2.7424455,1.07638,0.49632696,0.496323185,"Sample7-3",1.2341749,2.5398971,2.4880958,2.4082137,1.0763643,-0.014585926902954682]
["Std7-4",1.3192418,2.7151106,2.866097,2.7743187,1.07638,0.49631941,0.496319895,"Sample7-4",1.2410133,2.5539963,2.5022218,2.4219346,1.0763425,-0.03483899737999341]
["Std7-5",1.3141738,2.7047305,2.8553849,2.7640457,1.07638,0.49632038,0.49631853000000004,"Sample7-5",1.2506024,2.5738608,2.5225674,2.4418007,1.0763962,0.015050446868336564]
["Std7-6",1.3139256,2.7044395,2.8562991,2.7653242,1.07638,0.49631668]
[]
[{"$nulls":8},0,{"$nulls":4},1.07638252,0.0023411806240991595]
[{"$nulls":8},"Si ",{"$nulls":4},2.967527623712914e-05,0.02756951625298139]
[]
["2010-04-29",{"$nulls":4},"Certified","Corrected ratio","Average",{"$nulls":5},"Corrected ratio"]
["NIST 978a",{"$nulls":4},"Ag107/Ag109","Pd104/Pd105","Pd104/Pd105",{"$nulls":5},"Ag107/Ag109","δ Ag"]
["Std8-1",0.94435868,1.9414204,2.0765667,2.0059157,1.07638,0.49633585,0.49633071500000003,"Sample8-1",0.80643537,1.6579435,1.7501562,1.6906751,1.0763646,-0.014307214924014211]
["Std8-2",0.92104297,1.8936259,2.0239935,1.9553254,1.07638,0.49632558,0.496329695,"Sample8-2",0.79628954,1.6370135,1.7256946,1.6669867,1.0763314,-0.045151340604565604]
["Std8-3",0.9136293,1.8782259,2.0079787,1.9395888,1.07638,0.49633381,0.49633656,"Sample8-3",0.77560124,1.5944893,1.6808169,1.6236356,1.0763749,-0.004738103643542324]
["Std8-4",0.8891839,1.8280424,1.9544736,1.8880694,1.07638,0.49633931,0.49633671999999995,"Sample8-4",0.75580655,1.5540301,1.6404732,1.5850744,1.0764088,0.026756349988055206]
["Std8-5",0.87519707,1.7993953,1.9261524,1.8609034,1.07638,0.49633413,0.49633367,"Sample8-5",0.75355673,1.549377,1.6359288,1.5806779,1.0763737,-0.005852951559748298]
["Std8-6",0.87357886,1.7960178,1.9221937,1.8569631,1.07638,0.49633321]
[]
[{"$nulls":8},0,{"$nulls":4},1.0763706800000001,-0.008658652148763046]
[{"$nulls":8},"Si ",{"$nulls":4},2.76583896598389e-05,0.025695756482764065]