Supplementary Material (ESI) for Journal of Materials Chemistry This journal is © The Royal Society of Chemistry 2002 data_seon03_2 _database_code_CSD 175836 _journal_coden_Cambridge 1145 _publ_requested_journal 'Journal of Materials Chemistry' loop_ _publ_author_name 'Kim, Sung-Jin' 'Choi, Eun Sang' 'Kang, Woun' 'Park, Seon-Mi' _publ_contact_author_name 'Prof Sung-Jin Kim' _publ_contact_author_address ; Chemistry Ewha Womans University 11-1 Daehyun-dong Seodaemun-ku Seoul 120-750 KOREA ; _publ_contact_author_email 'SJKIM@MM.EWHA.AC.KR' _publ_section_title ; Eu5In2Sb6,Eu5In2-xZnxSb6 : Rare Earth Zintl Phases with Narrow Band Gaps ; _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_formula_moiety ? _chemical_formula_sum 'Eu5 In2 Sb6' _chemical_formula_weight 1719.94 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'In' 'In' -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Sb' 'Sb' -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Eu' 'Eu' -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting ? _symmetry_space_group_name_H-M ? loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, z' '-x+1/2, y+1/2, -z' 'x+1/2, -y+1/2, -z' '-x, -y, -z' 'x, y, -z' 'x-1/2, -y-1/2, z' '-x-1/2, y-1/2, z' _cell_length_a 12.510(3) _cell_length_b 14.584(3) _cell_length_c 4.6243(9) _cell_angle_alpha 90.00 _cell_angle_beta 90.00 _cell_angle_gamma 90.00 _cell_volume 843.7(3) _cell_formula_units_Z 2 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description ? _exptl_crystal_colour ? _exptl_crystal_size_max ? _exptl_crystal_size_mid ? _exptl_crystal_size_min ? _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 6.770 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1438 _exptl_absorpt_coefficient_mu 30.338 _exptl_absorpt_correction_type ? _exptl_absorpt_correction_T_min ? _exptl_absorpt_correction_T_max ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type ? _diffrn_measurement_method ? _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 881 _diffrn_reflns_av_R_equivalents 0.0052 _diffrn_reflns_av_sigmaI/netI 0.0382 _diffrn_reflns_limit_h_min 0 _diffrn_reflns_limit_h_max 14 _diffrn_reflns_limit_k_min 0 _diffrn_reflns_limit_k_max 17 _diffrn_reflns_limit_l_min 0 _diffrn_reflns_limit_l_max 5 _diffrn_reflns_theta_min 2.14 _diffrn_reflns_theta_max 24.96 _reflns_number_total 845 _reflns_number_gt 663 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme 'calc w=1/[\s^2^(Fo^2^)+(0.1021P)^2^+96.6276P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method SHELXL _refine_ls_extinction_coef 0.0025(3) _refine_ls_extinction_expression 'Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^' _refine_ls_number_reflns 845 _refine_ls_number_parameters 42 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0544 _refine_ls_R_factor_gt 0.0350 _refine_ls_wR_factor_ref 0.1439 _refine_ls_wR_factor_gt 0.1291 _refine_ls_goodness_of_fit_ref 0.877 _refine_ls_restrained_S_all 0.877 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Eu1 Eu 0.32749(11) 0.01894(10) 0.0000 0.0139(5) Uani 1 d S . . Eu2 Eu 0.0000 0.0000 0.0000 0.0123(5) Uani 1 d S . . Eu3 Eu -0.08720(10) -0.24950(9) 0.0000 0.0125(5) Uani 1 d S . . Sb1 Sb 0.16526(13) -0.17325(12) 0.0000 0.0125(5) Uani 1 d S . . Sb2 Sb 0.15289(13) 0.09404(12) -0.5000 0.0113(5) Uani 1 d S . . Sb3 Sb 0.52581(14) 0.09556(12) -0.5000 0.0120(5) Uani 1 d S . . In1 In 0.32991(15) 0.21489(14) -0.5000 0.0127(5) Uani 1 d S . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Eu1 0.0150(8) 0.0125(8) 0.0141(8) 0.000 0.000 0.0035(5) Eu2 0.0125(9) 0.0068(9) 0.0176(11) 0.000 0.000 -0.0028(7) Eu3 0.0161(8) 0.0056(7) 0.0158(8) 0.000 0.000 -0.0011(5) Sb1 0.0142(10) 0.0066(10) 0.0168(10) 0.000 0.000 0.0001(6) Sb2 0.0151(9) 0.0101(10) 0.0086(10) 0.000 0.000 -0.0028(7) Sb3 0.0184(10) 0.0066(9) 0.0109(10) 0.000 0.000 0.0013(6) In1 0.0202(10) 0.0084(10) 0.0095(10) 0.000 0.000 -0.0001(7) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Eu1 Sb2 3.3641(16) 1_556 ? Eu1 Sb2 3.3641(16) . ? Eu1 Sb3 3.3915(16) 5_655 ? Eu1 Sb3 3.3915(16) 5_654 ? Eu1 Sb1 3.461(2) . ? Eu1 Sb3 3.5708(18) 1_556 ? Eu1 Sb3 3.5708(18) . ? Eu1 In1 3.676(2) 1_556 ? Eu1 In1 3.676(2) . ? Eu1 Eu3 4.072(2) 7_655 ? Eu1 Eu2 4.1063(16) . ? Eu1 Eu1 4.351(3) 5_655 ? Eu2 Sb1 3.2647(18) 5 ? Eu2 Sb1 3.2647(18) . ? Eu2 Sb2 3.2992(13) 5_554 ? Eu2 Sb2 3.2992(13) 1_556 ? Eu2 Sb2 3.2992(13) 5 ? Eu2 Sb2 3.2992(13) . ? Eu2 Eu3 3.7987(15) . ? Eu2 Eu3 3.7987(15) 5 ? Eu2 Eu1 4.1063(16) 5 ? Eu3 Sb1 3.295(2) 7 ? Eu3 Sb3 3.3228(16) 3_544 ? Eu3 Sb3 3.3228(16) 3_545 ? Eu3 Sb2 3.3410(17) 5 ? Eu3 Sb2 3.3410(17) 5_554 ? Eu3 Sb1 3.348(2) . ? Eu3 In1 3.8498(18) 5_554 ? Eu3 In1 3.8498(18) 5 ? Eu3 Eu1 4.072(2) 7 ? Sb1 In1 2.8304(16) 3_544 ? Sb1 In1 2.8304(16) 3_545 ? Sb1 Eu3 3.295(2) 7_655 ? Sb2 In1 2.830(3) . ? Sb2 Eu2 3.2992(13) 1_554 ? Sb2 Eu3 3.3410(17) 5 ? Sb2 Eu3 3.3410(17) 5_554 ? Sb2 Eu1 3.3641(16) 1_554 ? Sb3 Sb3 2.861(4) 5_654 ? Sb3 In1 3.006(3) . ? Sb3 Eu3 3.3228(16) 3 ? Sb3 Eu3 3.3228(16) 3_554 ? Sb3 Eu1 3.3915(16) 5_655 ? Sb3 Eu1 3.3915(16) 5_654 ? Sb3 Eu1 3.5708(18) 1_554 ? In1 Sb1 2.8304(16) 3 ? In1 Sb1 2.8304(16) 3_554 ? In1 Eu1 3.676(2) 1_554 ? In1 Eu3 3.8498(18) 5_554 ? In1 Eu3 3.8498(18) 5 ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag Sb2 Eu1 Sb2 86.84(5) 1_556 . ? Sb2 Eu1 Sb3 92.47(3) 1_556 5_655 ? Sb2 Eu1 Sb3 168.59(6) . 5_655 ? Sb2 Eu1 Sb3 168.59(6) 1_556 5_654 ? Sb2 Eu1 Sb3 92.47(3) . 5_654 ? Sb3 Eu1 Sb3 85.96(5) 5_655 5_654 ? Sb2 Eu1 Sb1 83.27(5) 1_556 . ? Sb2 Eu1 Sb1 83.27(5) . . ? Sb3 Eu1 Sb1 85.33(5) 5_655 . ? Sb3 Eu1 Sb1 85.33(5) 5_654 . ? Sb2 Eu1 Sb3 84.50(4) 1_556 1_556 ? Sb2 Eu1 Sb3 142.59(6) . 1_556 ? Sb3 Eu1 Sb3 48.45(6) 5_655 1_556 ? Sb3 Eu1 Sb3 102.68(4) 5_654 1_556 ? Sb1 Eu1 Sb3 131.38(4) . 1_556 ? Sb2 Eu1 Sb3 142.59(6) 1_556 . ? Sb2 Eu1 Sb3 84.50(4) . . ? Sb3 Eu1 Sb3 102.68(4) 5_655 . ? Sb3 Eu1 Sb3 48.45(6) 5_654 . ? Sb1 Eu1 Sb3 131.38(4) . . ? Sb3 Eu1 Sb3 80.71(5) 1_556 . ? Sb2 Eu1 In1 47.15(4) 1_556 1_556 ? Sb2 Eu1 In1 100.64(5) . 1_556 ? Sb3 Eu1 In1 87.11(4) 5_655 1_556 ? Sb3 Eu1 In1 143.81(6) 5_654 1_556 ? Sb1 Eu1 In1 129.38(4) . 1_556 ? Sb3 Eu1 In1 48.98(4) 1_556 1_556 ? Sb3 Eu1 In1 99.11(5) . 1_556 ? Sb2 Eu1 In1 100.64(5) 1_556 . ? Sb2 Eu1 In1 47.15(4) . . ? Sb3 Eu1 In1 143.81(6) 5_655 . ? Sb3 Eu1 In1 87.11(4) 5_654 . ? Sb1 Eu1 In1 129.38(4) . . ? Sb3 Eu1 In1 99.11(5) 1_556 . ? Sb3 Eu1 In1 48.98(4) . . ? In1 Eu1 In1 77.95(5) 1_556 . ? Sb2 Eu1 Eu3 118.97(4) 1_556 7_655 ? Sb2 Eu1 Eu3 118.97(4) . 7_655 ? Sb3 Eu1 Eu3 51.90(3) 5_655 7_655 ? Sb3 Eu1 Eu3 51.90(3) 5_654 7_655 ? Sb1 Eu1 Eu3 51.10(4) . 7_655 ? Sb3 Eu1 Eu3 96.89(4) 1_556 7_655 ? Sb3 Eu1 Eu3 96.89(4) . 7_655 ? In1 Eu1 Eu3 138.42(3) 1_556 7_655 ? In1 Eu1 Eu3 138.42(3) . 7_655 ? Sb2 Eu1 Eu2 51.25(3) 1_556 . ? Sb2 Eu1 Eu2 51.25(3) . . ? Sb3 Eu1 Eu2 120.45(4) 5_655 . ? Sb3 Eu1 Eu2 120.45(4) 5_654 . ? Sb1 Eu1 Eu2 50.24(3) . . ? Sb3 Eu1 Eu2 135.59(3) 1_556 . ? Sb3 Eu1 Eu2 135.59(3) . . ? In1 Eu1 Eu2 93.47(4) 1_556 . ? In1 Eu1 Eu2 93.47(4) . . ? Eu3 Eu1 Eu2 101.34(4) 7_655 . ? Sb2 Eu1 Eu1 133.27(3) 1_556 5_655 ? Sb2 Eu1 Eu1 133.27(3) . 5_655 ? Sb3 Eu1 Eu1 53.19(3) 5_655 5_655 ? Sb3 Eu1 Eu1 53.19(3) 5_654 5_655 ? Sb1 Eu1 Eu1 118.62(6) . 5_655 ? Sb3 Eu1 Eu1 49.50(3) 1_556 5_655 ? Sb3 Eu1 Eu1 49.50(3) . 5_655 ? In1 Eu1 Eu1 95.19(5) 1_556 5_655 ? In1 Eu1 Eu1 95.19(5) . 5_655 ? Eu3 Eu1 Eu1 67.51(4) 7_655 5_655 ? Eu2 Eu1 Eu1 168.85(6) . 5_655 ? Sb1 Eu2 Sb1 180.0 5 . ? Sb1 Eu2 Sb2 87.40(4) 5 5_554 ? Sb1 Eu2 Sb2 92.60(4) . 5_554 ? Sb1 Eu2 Sb2 92.60(4) 5 1_556 ? Sb1 Eu2 Sb2 87.40(4) . 1_556 ? Sb2 Eu2 Sb2 180.0 5_554 1_556 ? Sb1 Eu2 Sb2 87.40(4) 5 5 ? Sb1 Eu2 Sb2 92.60(4) . 5 ? Sb2 Eu2 Sb2 88.98(4) 5_554 5 ? Sb2 Eu2 Sb2 91.02(4) 1_556 5 ? Sb1 Eu2 Sb2 92.60(4) 5 . ? Sb1 Eu2 Sb2 87.40(4) . . ? Sb2 Eu2 Sb2 91.02(4) 5_554 . ? Sb2 Eu2 Sb2 88.98(4) 1_556 . ? Sb2 Eu2 Sb2 180.0 5 . ? Sb1 Eu2 Eu3 124.02(4) 5 . ? Sb1 Eu2 Eu3 55.98(4) . . ? Sb2 Eu2 Eu3 55.62(3) 5_554 . ? Sb2 Eu2 Eu3 124.38(3) 1_556 . ? Sb2 Eu2 Eu3 55.62(3) 5 . ? Sb2 Eu2 Eu3 124.38(3) . . ? Sb1 Eu2 Eu3 55.98(4) 5 5 ? Sb1 Eu2 Eu3 124.02(4) . 5 ? Sb2 Eu2 Eu3 124.38(3) 5_554 5 ? Sb2 Eu2 Eu3 55.62(3) 1_556 5 ? Sb2 Eu2 Eu3 124.38(3) 5 5 ? Sb2 Eu2 Eu3 55.62(3) . 5 ? Eu3 Eu2 Eu3 180.0 . 5 ? Sb1 Eu2 Eu1 54.57(4) 5 5 ? Sb1 Eu2 Eu1 125.43(4) . 5 ? Sb2 Eu2 Eu1 52.67(3) 5_554 5 ? Sb2 Eu2 Eu1 127.33(3) 1_556 5 ? Sb2 Eu2 Eu1 52.67(3) 5 5 ? Sb2 Eu2 Eu1 127.33(3) . 5 ? Eu3 Eu2 Eu1 69.46(3) . 5 ? Eu3 Eu2 Eu1 110.54(3) 5 5 ? Sb1 Eu2 Eu1 125.43(4) 5 . ? Sb1 Eu2 Eu1 54.57(4) . . ? Sb2 Eu2 Eu1 127.33(3) 5_554 . ? Sb2 Eu2 Eu1 52.67(3) 1_556 . ? Sb2 Eu2 Eu1 127.33(3) 5 . ? Sb2 Eu2 Eu1 52.67(3) . . ? Eu3 Eu2 Eu1 110.54(3) . . ? Eu3 Eu2 Eu1 69.46(3) 5 . ? Eu1 Eu2 Eu1 180.0 5 . ? Sb1 Eu3 Sb3 89.12(5) 7 3_544 ? Sb1 Eu3 Sb3 89.12(5) 7 3_545 ? Sb3 Eu3 Sb3 88.19(6) 3_544 3_545 ? Sb1 Eu3 Sb2 90.05(5) 7 5 ? Sb3 Eu3 Sb2 179.12(5) 3_544 5 ? Sb3 Eu3 Sb2 92.11(3) 3_545 5 ? Sb1 Eu3 Sb2 90.05(5) 7 5_554 ? Sb3 Eu3 Sb2 92.11(3) 3_544 5_554 ? Sb3 Eu3 Sb2 179.12(5) 3_545 5_554 ? Sb2 Eu3 Sb2 87.59(6) 5 5_554 ? Sb1 Eu3 Sb1 179.41(5) 7 . ? Sb3 Eu3 Sb1 90.45(5) 3_544 . ? Sb3 Eu3 Sb1 90.45(5) 3_545 . ? Sb2 Eu3 Sb1 90.38(4) 5 . ? Sb2 Eu3 Sb1 90.38(4) 5_554 . ? Sb1 Eu3 Eu2 126.68(5) 7 . ? Sb3 Eu3 Eu2 125.80(4) 3_544 . ? Sb3 Eu3 Eu2 125.80(4) 3_545 . ? Sb2 Eu3 Eu2 54.59(3) 5 . ? Sb2 Eu3 Eu2 54.59(3) 5_554 . ? Sb1 Eu3 Eu2 53.92(4) . . ? Sb1 Eu3 In1 45.86(3) 7 5_554 ? Sb3 Eu3 In1 81.58(4) 3_544 5_554 ? Sb3 Eu3 In1 133.58(5) 3_545 5_554 ? Sb2 Eu3 In1 97.62(5) 5 5_554 ? Sb2 Eu3 In1 45.68(4) 5_554 5_554 ? Sb1 Eu3 In1 134.46(4) . 5_554 ? Eu2 Eu3 In1 95.79(4) . 5_554 ? Sb1 Eu3 In1 45.86(3) 7 5 ? Sb3 Eu3 In1 133.58(5) 3_544 5 ? Sb3 Eu3 In1 81.58(4) 3_545 5 ? Sb2 Eu3 In1 45.68(4) 5 5 ? Sb2 Eu3 In1 97.62(5) 5_554 5 ? Sb1 Eu3 In1 134.46(4) . 5 ? Eu2 Eu3 In1 95.79(4) . 5 ? In1 Eu3 In1 73.82(4) 5_554 5 ? Sb1 Eu3 Eu1 54.81(4) 7 7 ? Sb3 Eu3 Eu1 53.44(3) 3_544 7 ? Sb3 Eu3 Eu1 53.44(3) 3_545 7 ? Sb2 Eu3 Eu1 126.19(4) 5 7 ? Sb2 Eu3 Eu1 126.19(4) 5_554 7 ? Sb1 Eu3 Eu1 124.59(5) . 7 ? Eu2 Eu3 Eu1 178.51(4) . 7 ? In1 Eu3 Eu1 85.40(4) 5_554 7 ? In1 Eu3 Eu1 85.40(4) 5 7 ? In1 Sb1 In1 109.55(9) 3_544 3_545 ? In1 Sb1 Eu2 117.36(5) 3_544 . ? In1 Sb1 Eu2 117.36(5) 3_545 . ? In1 Sb1 Eu3 77.46(5) 3_544 7_655 ? In1 Sb1 Eu3 77.46(5) 3_545 7_655 ? Eu2 Sb1 Eu3 149.28(6) . 7_655 ? In1 Sb1 Eu3 80.14(5) 3_544 . ? In1 Sb1 Eu3 80.14(5) 3_545 . ? Eu2 Sb1 Eu3 70.11(4) . . ? Eu3 Sb1 Eu3 140.61(6) 7_655 . ? In1 Sb1 Eu1 117.02(5) 3_544 . ? In1 Sb1 Eu1 117.02(5) 3_545 . ? Eu2 Sb1 Eu1 75.20(5) . . ? Eu3 Sb1 Eu1 74.08(5) 7_655 . ? Eu3 Sb1 Eu1 145.30(6) . . ? In1 Sb2 Eu2 135.43(2) . 1_554 ? In1 Sb2 Eu2 135.43(2) . . ? Eu2 Sb2 Eu2 88.98(4) 1_554 . ? In1 Sb2 Eu3 76.70(5) . 5 ? Eu2 Sb2 Eu3 128.65(6) 1_554 5 ? Eu2 Sb2 Eu3 69.79(3) . 5 ? In1 Sb2 Eu3 76.70(5) . 5_554 ? Eu2 Sb2 Eu3 69.79(3) 1_554 5_554 ? Eu2 Sb2 Eu3 128.65(6) . 5_554 ? Eu3 Sb2 Eu3 87.59(6) 5 5_554 ? In1 Sb2 Eu1 72.22(5) . . ? Eu2 Sb2 Eu1 136.28(6) 1_554 . ? Eu2 Sb2 Eu1 76.08(3) . . ? Eu3 Sb2 Eu1 84.55(3) 5 . ? Eu3 Sb2 Eu1 148.91(6) 5_554 . ? In1 Sb2 Eu1 72.22(5) . 1_554 ? Eu2 Sb2 Eu1 76.08(3) 1_554 1_554 ? Eu2 Sb2 Eu1 136.28(6) . 1_554 ? Eu3 Sb2 Eu1 148.91(6) 5 1_554 ? Eu3 Sb2 Eu1 84.55(3) 5_554 1_554 ? Eu1 Sb2 Eu1 86.84(5) . 1_554 ? Sb3 Sb3 In1 112.33(10) 5_654 . ? Sb3 Sb3 Eu3 135.61(3) 5_654 3 ? In1 Sb3 Eu3 78.16(5) . 3 ? Sb3 Sb3 Eu3 135.61(3) 5_654 3_554 ? In1 Sb3 Eu3 78.16(5) . 3_554 ? Eu3 Sb3 Eu3 88.19(6) 3 3_554 ? Sb3 Sb3 Eu1 69.05(5) 5_654 5_655 ? In1 Sb3 Eu1 136.57(3) . 5_655 ? Eu3 Sb3 Eu1 74.66(4) 3 5_655 ? Eu3 Sb3 Eu1 133.17(6) 3_554 5_655 ? Sb3 Sb3 Eu1 69.05(5) 5_654 5_654 ? In1 Sb3 Eu1 136.57(3) . 5_654 ? Eu3 Sb3 Eu1 133.17(6) 3 5_654 ? Eu3 Sb3 Eu1 74.66(4) 3_554 5_654 ? Eu1 Sb3 Eu1 85.96(5) 5_655 5_654 ? Sb3 Sb3 Eu1 62.50(5) 5_654 1_554 ? In1 Sb3 Eu1 67.34(5) . 1_554 ? Eu3 Sb3 Eu1 145.48(6) 3 1_554 ? Eu3 Sb3 Eu1 85.57(3) 3_554 1_554 ? Eu1 Sb3 Eu1 131.55(6) 5_655 1_554 ? Eu1 Sb3 Eu1 77.32(4) 5_654 1_554 ? Sb3 Sb3 Eu1 62.50(5) 5_654 . ? In1 Sb3 Eu1 67.34(5) . . ? Eu3 Sb3 Eu1 85.57(3) 3 . ? Eu3 Sb3 Eu1 145.48(6) 3_554 . ? Eu1 Sb3 Eu1 77.32(4) 5_655 . ? Eu1 Sb3 Eu1 131.55(6) 5_654 . ? Eu1 Sb3 Eu1 80.71(5) 1_554 . ? Sb2 In1 Sb1 112.06(6) . 3 ? Sb2 In1 Sb1 112.06(6) . 3_554 ? Sb1 In1 Sb1 109.55(9) 3 3_554 ? Sb2 In1 Sb3 106.11(9) . . ? Sb1 In1 Sb3 108.44(6) 3 . ? Sb1 In1 Sb3 108.44(6) 3_554 . ? Sb2 In1 Eu1 60.62(5) . 1_554 ? Sb1 In1 Eu1 164.16(6) 3 1_554 ? Sb1 In1 Eu1 86.24(4) 3_554 1_554 ? Sb3 In1 Eu1 63.68(5) . 1_554 ? Sb2 In1 Eu1 60.62(5) . . ? Sb1 In1 Eu1 86.24(4) 3 . ? Sb1 In1 Eu1 164.16(6) 3_554 . ? Sb3 In1 Eu1 63.68(5) . . ? Eu1 In1 Eu1 77.95(5) 1_554 . ? Sb2 In1 Eu3 57.62(4) . 5_554 ? Sb1 In1 Eu3 115.59(7) 3 5_554 ? Sb1 In1 Eu3 56.68(4) 3_554 5_554 ? Sb3 In1 Eu3 135.97(4) . 5_554 ? Eu1 In1 Eu3 73.60(3) 1_554 5_554 ? Eu1 In1 Eu3 118.24(6) . 5_554 ? Sb2 In1 Eu3 57.62(4) . 5 ? Sb1 In1 Eu3 56.68(4) 3 5 ? Sb1 In1 Eu3 115.59(7) 3_554 5 ? Sb3 In1 Eu3 135.97(4) . 5 ? Eu1 In1 Eu3 118.24(6) 1_554 5 ? Eu1 In1 Eu3 73.60(3) . 5 ? Eu3 In1 Eu3 73.82(4) 5_554 5 ? _diffrn_measured_fraction_theta_max 0.932 _diffrn_reflns_theta_full 24.96 _diffrn_measured_fraction_theta_full 0.932 _refine_diff_density_max 2.094 _refine_diff_density_min -2.667 _refine_diff_density_rms 0.558