# Supplementary Material (ESI) for Journal of Materials Chemistry
# This journal is (C) The Royal Society of Chemistry 2009


data_global
_journal_name_full               J.Mater.Chem.

_journal_coden_Cambridge         1145

_publ_contact_author_name        'M L P Reddy'
_publ_contact_author_email       MLPREDDY55@GMAIL.COM

_publ_section_title              
;
Dual Emission from Stoichiometrically Mixed Lanthanide
Complexes of 3-Phenyl-4-benzoyl-5-isoxazolonate and 2,2'-Bipyridine
;
loop_
_publ_author_name
'M L P Reddy'
'D. B. Ambili Raj'
'Silvanose Biju'
'Alan H. Cowley'
'Michael Findlater'
;
C.K.Jayasankar
;

# Attachment 'eu(pbi)bipy_revised.cif'

data_shelxl
_database_code_depnum_ccdc_archive 'CCDC 689107'

_audit_creation_method           
;
manual editing of the .cif file
created by SHELXTL Ver. 6.10
;

_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C59 H42 Cl2 Eu N5 O10'
_chemical_formula_sum            'C59 H42 Cl2 Eu N5 O10'
_chemical_formula_weight         1203.84

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   p-1
_symmetry_space_group_name_Hall  -p1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.839(3)
_cell_length_b                   13.863(3)
_cell_length_c                   16.379(3)
_cell_angle_alpha                81.66(3)
_cell_angle_beta                 73.32(3)
_cell_angle_gamma                89.26(3)
_cell_volume                     2762.0(10)
_cell_formula_units_Z            2
_cell_measurement_temperature    153(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       needle
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          .30
_exptl_crystal_size_mid          .20
_exptl_crystal_size_min          .15
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.448
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1216
_exptl_absorpt_coefficient_mu    1.295
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
Department of Chemistry
University of Anywhere
Sometown
Somewhere, UK
;

_diffrn_ambient_temperature      153(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Nonius Kappa CCD'
_diffrn_measurement_method       \w-scan
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            18115
_diffrn_reflns_av_R_equivalents  0.0335
_diffrn_reflns_av_sigmaI/netI    0.0886
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         1.49
_diffrn_reflns_theta_max         27.42
_reflns_number_total             12370
_reflns_number_gt                8912
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Collect software, Nonius B.V. 1998'
_computing_cell_refinement       'Collect software, Nonius B.V. 1998'
_computing_data_reduction        
;
DENZO and Scalepack (Otwinoski and Minor, 1997)
;
_computing_structure_solution    
;
SIR97 - Altomare A., Burla M.C., Camalli M., Cascarano G.L., Giacovazzo C.,
Guagliardi A., Moliterni A.G.G., Polidori G.,Spagna R.
;
_computing_structure_refinement  'XL SHELXTL/PC, Siemens Analytical'
_computing_molecular_graphics    'XP SHELXTL/PC, Siemens Analytical'
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
A molecule of what appeared to be disordered methylene chloride was removed
by using the PLATON SQUEEZE program.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.1060P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         12370
_refine_ls_number_parameters     667
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1052
_refine_ls_R_factor_gt           0.0710
_refine_ls_wR_factor_ref         0.1840
_refine_ls_wR_factor_gt          0.1703
_refine_ls_goodness_of_fit_ref   1.108
_refine_ls_restrained_S_all      1.108
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.4048(6) 0.4269(5) 0.7292(4) 0.0383(15) Uani 1 1 d . . .
C2 C 0.4389(5) 0.3334(4) 0.7129(4) 0.0312(13) Uani 1 1 d . . .
C3 C 0.3738(5) 0.2692(4) 0.6850(3) 0.0284(13) Uani 1 1 d . . .
C4 C 0.5425(5) 0.3254(5) 0.7299(4) 0.0386(15) Uani 1 1 d . . .
C5 C 0.6213(5) 0.2472(5) 0.7276(4) 0.0352(14) Uani 1 1 d . . .
C6 C 0.7306(6) 0.2688(5) 0.6892(4) 0.0460(17) Uani 1 1 d . . .
H6 H 0.7528 0.3321 0.6626 0.055 Uiso 1 1 calc R . .
C7 C 0.8085(6) 0.1975(6) 0.6897(5) 0.0510(19) Uani 1 1 d . . .
H7 H 0.8820 0.2130 0.6638 0.061 Uiso 1 1 calc R . .
C8 C 0.7751(6) 0.1044(6) 0.7289(5) 0.0507(19) Uani 1 1 d . . .
H8 H 0.8265 0.0565 0.7291 0.061 Uiso 1 1 calc R . .
C9 C 0.6665(6) 0.0806(6) 0.7679(5) 0.0537(19) Uani 1 1 d . . .
H9 H 0.6445 0.0172 0.7943 0.064 Uiso 1 1 calc R . .
C10 C 0.5901(6) 0.1529(5) 0.7674(4) 0.0433(16) Uani 1 1 d . . .
H10 H 0.5169 0.1374 0.7944 0.052 Uiso 1 1 calc R . .
C11 C 0.4186(5) 0.1784(4) 0.6519(4) 0.0305(13) Uani 1 1 d . . .
C12 C 0.5216(6) 0.1774(5) 0.5948(4) 0.0389(15) Uani 1 1 d . . .
H12 H 0.5637 0.2347 0.5749 0.047 Uiso 1 1 calc R . .
C13 C 0.5616(6) 0.0910(6) 0.5673(4) 0.0493(19) Uani 1 1 d . . .
H13 H 0.6299 0.0907 0.5277 0.059 Uiso 1 1 calc R . .
C14 C 0.5010(7) 0.0055(6) 0.5983(5) 0.055(2) Uani 1 1 d . . .
H14 H 0.5295 -0.0528 0.5811 0.066 Uiso 1 1 calc R . .
C15 C 0.3984(7) 0.0061(5) 0.6544(5) 0.0500(19) Uani 1 1 d . . .
H15 H 0.3578 -0.0519 0.6755 0.060 Uiso 1 1 calc R . .
C16 C 0.3553(6) 0.0929(5) 0.6799(4) 0.0384(15) Uani 1 1 d . . .
H16 H 0.2845 0.0938 0.7156 0.046 Uiso 1 1 calc R . .
C17 C -0.0242(5) 0.4696(4) 0.6229(3) 0.0272(12) Uani 1 1 d . . .
C18 C -0.0300(5) 0.5705(4) 0.6258(3) 0.0276(13) Uani 1 1 d . . .
C19 C 0.0425(5) 0.6214(4) 0.6570(3) 0.0291(13) Uani 1 1 d . . .
C20 C -0.1116(5) 0.6022(4) 0.5858(3) 0.0301(13) Uani 1 1 d . . .
C21 C -0.1584(5) 0.7009(4) 0.5744(4) 0.0342(14) Uani 1 1 d . . .
C22 C -0.1667(6) 0.7419(5) 0.4944(4) 0.0417(16) Uani 1 1 d . . .
H22 H -0.1446 0.7073 0.4481 0.050 Uiso 1 1 calc R . .
C23 C -0.2077(6) 0.8338(5) 0.4831(5) 0.0478(18) Uani 1 1 d . . .
H23 H -0.2129 0.8618 0.4293 0.057 Uiso 1 1 calc R . .
C24 C -0.2412(6) 0.8842(5) 0.5539(6) 0.054(2) Uani 1 1 d . . .
H24 H -0.2681 0.9464 0.5468 0.065 Uiso 1 1 calc R . .
C25 C -0.2349(6) 0.8432(5) 0.6333(5) 0.0506(19) Uani 1 1 d . . .
H25 H -0.2583 0.8774 0.6798 0.061 Uiso 1 1 calc R . .
C26 C -0.1941(6) 0.7514(5) 0.6448(4) 0.0443(17) Uani 1 1 d . . .
H26 H -0.1903 0.7233 0.6989 0.053 Uiso 1 1 calc R . .
C27 C 0.0536(5) 0.7302(4) 0.6395(4) 0.0333(14) Uani 1 1 d . . .
C28 C 0.0685(6) 0.7818(5) 0.5576(4) 0.0405(16) Uani 1 1 d . . .
H28 H 0.0726 0.7486 0.5113 0.049 Uiso 1 1 calc R . .
C29 C 0.0773(7) 0.8826(5) 0.5448(5) 0.053(2) Uani 1 1 d . . .
H29 H 0.0889 0.9170 0.4897 0.064 Uiso 1 1 calc R . .
C30 C 0.0688(8) 0.9318(5) 0.6130(5) 0.060(2) Uani 1 1 d . . .
H30 H 0.0710 0.9996 0.6042 0.072 Uiso 1 1 calc R . .
C31 C 0.0572(8) 0.8817(5) 0.6948(5) 0.059(2) Uani 1 1 d . . .
H31 H 0.0532 0.9156 0.7405 0.071 Uiso 1 1 calc R . .
C32 C 0.0517(6) 0.7807(5) 0.7079(4) 0.0425(16) Uani 1 1 d . . .
H32 H 0.0466 0.7465 0.7621 0.051 Uiso 1 1 calc R . .
C33 C 0.0809(5) 0.1797(4) 0.8165(3) 0.0273(12) Uani 1 1 d . . .
C34 C 0.1479(5) 0.1609(4) 0.8718(4) 0.0276(12) Uani 1 1 d . . .
C35 C 0.1945(5) 0.2390(4) 0.8994(3) 0.0268(12) Uani 1 1 d . . .
C36 C 0.1473(5) 0.0558(4) 0.8909(4) 0.0303(13) Uani 1 1 d . . .
C37 C 0.2117(5) -0.0065(4) 0.9389(4) 0.0306(14) Uani 1 1 d . . .
C38 C 0.3244(6) 0.0027(5) 0.9146(4) 0.0426(16) Uani 1 1 d . . .
H38 H 0.3602 0.0497 0.8688 0.051 Uiso 1 1 calc R . .
C39 C 0.3841(6) -0.0581(6) 0.9586(5) 0.0505(19) Uani 1 1 d . . .
H39 H 0.4596 -0.0522 0.9419 0.061 Uiso 1 1 calc R . .
C40 C 0.3317(7) -0.1261(5) 1.0260(5) 0.0500(19) Uani 1 1 d . . .
H40 H 0.3716 -0.1659 1.0558 0.060 Uiso 1 1 calc R . .
C41 C 0.2203(7) -0.1365(5) 1.0505(5) 0.0499(19) Uani 1 1 d . . .
H41 H 0.1854 -0.1834 1.0966 0.060 Uiso 1 1 calc R . .
C42 C 0.1598(6) -0.0775(5) 1.0070(4) 0.0411(15) Uani 1 1 d . . .
H42 H 0.0845 -0.0854 1.0234 0.049 Uiso 1 1 calc R . .
C43 C 0.2448(5) 0.2203(4) 0.9721(4) 0.0319(14) Uani 1 1 d . . .
C44 C 0.3435(5) 0.2668(5) 0.9640(4) 0.0350(14) Uani 1 1 d . . .
H44 H 0.3794 0.3056 0.9125 0.042 Uiso 1 1 calc R . .
C45 C 0.3881(6) 0.2560(5) 1.0309(4) 0.0444(17) Uani 1 1 d . . .
H45 H 0.4555 0.2851 1.0241 0.053 Uiso 1 1 calc R . .
C46 C 0.3326(7) 0.2015(5) 1.1093(4) 0.051(2) Uani 1 1 d . . .
H46 H 0.3620 0.1955 1.1554 0.061 Uiso 1 1 calc R . .
C47 C 0.2336(7) 0.1563(5) 1.1185(4) 0.0484(19) Uani 1 1 d . . .
H47 H 0.1963 0.1205 1.1712 0.058 Uiso 1 1 calc R . .
C48 C 0.1902(6) 0.1639(4) 1.0507(4) 0.0370(15) Uani 1 1 d . . .
H48 H 0.1247 0.1317 1.0568 0.044 Uiso 1 1 calc R . .
C49 C -0.1348(6) 0.3964(5) 0.8218(4) 0.0385(15) Uani 1 1 d . . .
H49 H -0.1217 0.3407 0.7953 0.046 Uiso 1 1 calc R . .
C50 C -0.2406(6) 0.4282(6) 0.8450(5) 0.0512(18) Uani 1 1 d . . .
H50 H -0.2974 0.3944 0.8359 0.061 Uiso 1 1 calc R . .
C51 C -0.2575(7) 0.5121(6) 0.8820(6) 0.065(2) Uani 1 1 d . . .
H51 H -0.3266 0.5375 0.8964 0.078 Uiso 1 1 calc R . .
C52 C -0.1734(6) 0.5583(6) 0.8979(5) 0.056(2) Uani 1 1 d . . .
H52 H -0.1859 0.6145 0.9237 0.067 Uiso 1 1 calc R . .
C53 C -0.0693(6) 0.5215(5) 0.8753(4) 0.0385(15) Uani 1 1 d . . .
C54 C 0.0239(6) 0.5629(4) 0.8949(4) 0.0351(15) Uani 1 1 d . . .
C55 C 0.0104(6) 0.6361(5) 0.9460(4) 0.0471(18) Uani 1 1 d . . .
H55 H -0.0586 0.6594 0.9689 0.057 Uiso 1 1 calc R . .
C56 C 0.0988(7) 0.6742(5) 0.9629(5) 0.055(2) Uani 1 1 d . . .
H56 H 0.0904 0.7239 0.9966 0.066 Uiso 1 1 calc R . .
C57 C 0.1986(7) 0.6387(6) 0.9299(5) 0.056(2) Uani 1 1 d . . .
H57 H 0.2599 0.6634 0.9402 0.067 Uiso 1 1 calc R . .
C58 C 0.2063(6) 0.5636(5) 0.8799(5) 0.0505(19) Uani 1 1 d . . .
H58 H 0.2743 0.5381 0.8582 0.061 Uiso 1 1 calc R . .
N1 N 0.5691(5) 0.4056(4) 0.7546(4) 0.0511(15) Uani 1 1 d . . .
N2 N -0.1514(4) 0.5308(4) 0.5579(3) 0.0306(11) Uani 1 1 d . . .
N3 N 0.0882(5) 0.0149(4) 0.8539(3) 0.0380(13) Uani 1 1 d . . .
N4 N -0.0502(4) 0.4407(4) 0.8349(3) 0.0328(12) Uani 1 1 d . . .
N5 N 0.1222(4) 0.5269(4) 0.8620(3) 0.0350(12) Uani 1 1 d . . .
O1 O 0.3218(4) 0.4742(3) 0.7260(3) 0.0361(10) Uani 1 1 d . . .
O2 O 0.2764(3) 0.2861(3) 0.6893(2) 0.0327(9) Uani 1 1 d . . .
O3 O 0.4821(4) 0.4716(3) 0.7537(3) 0.0486(12) Uani 1 1 d . . .
O4 O 0.0292(3) 0.4034(3) 0.6494(2) 0.0287(9) Uani 1 1 d . . .
O5 O 0.1009(4) 0.5775(3) 0.6987(3) 0.0357(10) Uani 1 1 d . . .
O6 O -0.0947(3) 0.4456(3) 0.5795(2) 0.0286(9) Uani 1 1 d . . .
O7 O 0.0521(3) 0.2549(3) 0.7797(2) 0.0308(9) Uani 1 1 d . . .
O8 O 0.1952(3) 0.3247(3) 0.8647(2) 0.0306(9) Uani 1 1 d . . .
O9 O 0.0422(4) 0.0918(3) 0.8078(3) 0.0378(10) Uani 1 1 d . . .
OW O 0.2471(4) 0.4642(3) 0.5834(3) 0.0405(11) Uani 1 1 d . . .
Eu1 Eu 0.14714(3) 0.41231(2) 0.739185(18) 0.02825(13) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
C1 0.043(4) 0.040(4) 0.034(3) -0.004(3) -0.016(3) -0.003(3)
C2 0.038(4) 0.030(3) 0.027(3) -0.006(2) -0.011(3) 0.004(3)
C3 0.040(4) 0.025(3) 0.026(3) -0.005(2) -0.019(3) 0.012(3)
C4 0.034(4) 0.037(4) 0.047(4) -0.001(3) -0.018(3) 0.001(3)
C5 0.039(4) 0.038(4) 0.032(3) -0.007(3) -0.015(3) 0.005(3)
C6 0.041(4) 0.047(4) 0.046(4) -0.006(3) -0.007(3) -0.007(3)
C7 0.031(4) 0.063(5) 0.055(4) -0.016(4) -0.004(3) 0.002(4)
C8 0.047(5) 0.051(5) 0.058(4) -0.010(4) -0.020(4) 0.021(4)
C9 0.046(5) 0.045(4) 0.071(5) 0.008(4) -0.026(4) -0.002(4)
C10 0.029(4) 0.055(5) 0.044(4) 0.008(3) -0.014(3) -0.003(3)
C11 0.035(4) 0.032(3) 0.032(3) -0.010(3) -0.018(3) 0.010(3)
C12 0.041(4) 0.042(4) 0.039(3) -0.011(3) -0.018(3) 0.008(3)
C13 0.052(5) 0.054(5) 0.041(4) -0.016(3) -0.009(3) 0.016(4)
C14 0.070(6) 0.041(4) 0.060(5) -0.018(4) -0.023(4) 0.020(4)
C15 0.068(5) 0.027(4) 0.059(4) -0.015(3) -0.019(4) 0.008(3)
C16 0.041(4) 0.037(4) 0.040(3) -0.013(3) -0.014(3) 0.011(3)
C17 0.030(3) 0.029(3) 0.025(3) -0.003(2) -0.013(2) 0.002(3)
C18 0.042(4) 0.018(3) 0.028(3) -0.005(2) -0.017(3) 0.007(2)
C19 0.044(4) 0.019(3) 0.024(3) 0.000(2) -0.011(3) 0.002(3)
C20 0.041(4) 0.030(3) 0.021(3) -0.001(2) -0.012(3) 0.002(3)
C21 0.044(4) 0.027(3) 0.038(3) -0.004(3) -0.023(3) 0.009(3)
C22 0.053(4) 0.033(4) 0.048(4) -0.004(3) -0.031(3) 0.004(3)
C23 0.067(5) 0.025(3) 0.061(4) 0.003(3) -0.040(4) 0.008(3)
C24 0.047(5) 0.030(4) 0.090(6) -0.009(4) -0.027(4) 0.014(3)
C25 0.058(5) 0.044(4) 0.058(4) -0.021(4) -0.024(4) 0.016(4)
C26 0.054(4) 0.039(4) 0.045(4) -0.010(3) -0.020(3) 0.019(3)
C27 0.045(4) 0.023(3) 0.037(3) -0.006(3) -0.020(3) 0.007(3)
C28 0.055(4) 0.033(4) 0.042(3) -0.010(3) -0.025(3) 0.005(3)
C29 0.079(6) 0.032(4) 0.049(4) 0.006(3) -0.024(4) 0.002(4)
C30 0.097(7) 0.020(3) 0.071(5) -0.004(3) -0.037(5) 0.000(4)
C31 0.096(7) 0.029(4) 0.065(5) -0.019(4) -0.037(5) 0.002(4)
C32 0.067(5) 0.026(3) 0.039(3) -0.003(3) -0.022(3) -0.004(3)
C33 0.028(3) 0.024(3) 0.030(3) -0.002(2) -0.009(2) 0.001(2)
C34 0.034(3) 0.022(3) 0.032(3) -0.005(2) -0.017(3) 0.007(2)
C35 0.028(3) 0.028(3) 0.026(3) -0.006(2) -0.010(2) 0.007(2)
C36 0.035(4) 0.027(3) 0.030(3) -0.007(2) -0.011(3) 0.004(3)
C37 0.042(4) 0.023(3) 0.029(3) -0.008(2) -0.013(3) 0.006(3)
C38 0.041(4) 0.039(4) 0.047(4) 0.006(3) -0.017(3) 0.002(3)
C39 0.043(4) 0.056(5) 0.057(4) -0.010(4) -0.022(4) 0.016(4)
C40 0.070(6) 0.042(4) 0.052(4) -0.008(3) -0.040(4) 0.022(4)
C41 0.072(6) 0.033(4) 0.051(4) 0.004(3) -0.033(4) 0.004(4)
C42 0.046(4) 0.034(4) 0.044(4) 0.000(3) -0.018(3) 0.001(3)
C43 0.047(4) 0.025(3) 0.035(3) -0.014(2) -0.025(3) 0.017(3)
C44 0.035(4) 0.037(4) 0.035(3) -0.006(3) -0.014(3) 0.005(3)
C45 0.049(4) 0.048(4) 0.050(4) -0.018(3) -0.031(3) 0.012(3)
C46 0.075(6) 0.051(4) 0.044(4) -0.014(3) -0.042(4) 0.022(4)
C47 0.072(6) 0.045(4) 0.031(3) -0.002(3) -0.022(3) 0.014(4)
C48 0.054(4) 0.030(3) 0.032(3) -0.003(3) -0.020(3) 0.009(3)
C49 0.048(4) 0.036(4) 0.038(3) -0.006(3) -0.023(3) 0.011(3)
C50 0.043(4) 0.055(5) 0.058(4) -0.012(4) -0.016(4) 0.008(4)
C51 0.045(5) 0.068(6) 0.095(6) -0.037(5) -0.029(4) 0.027(4)
C52 0.052(5) 0.055(5) 0.071(5) -0.032(4) -0.023(4) 0.026(4)
C53 0.051(4) 0.034(4) 0.035(3) -0.010(3) -0.018(3) 0.012(3)
C54 0.057(4) 0.029(3) 0.025(3) -0.003(2) -0.021(3) 0.009(3)
C55 0.063(5) 0.045(4) 0.040(4) -0.019(3) -0.020(3) 0.022(4)
C56 0.095(7) 0.042(4) 0.045(4) -0.025(3) -0.038(4) 0.014(4)
C57 0.074(6) 0.052(5) 0.063(5) -0.031(4) -0.043(4) 0.009(4)
C58 0.058(5) 0.058(5) 0.053(4) -0.031(4) -0.033(4) 0.020(4)
N1 0.043(4) 0.045(4) 0.080(4) -0.021(3) -0.034(3) 0.007(3)
N2 0.037(3) 0.029(3) 0.030(2) -0.002(2) -0.017(2) 0.013(2)
N3 0.051(3) 0.027(3) 0.045(3) -0.007(2) -0.026(3) 0.007(2)
N4 0.043(3) 0.027(3) 0.034(3) -0.004(2) -0.020(2) 0.004(2)
N5 0.050(3) 0.030(3) 0.036(3) -0.010(2) -0.029(3) 0.011(2)
O1 0.051(3) 0.023(2) 0.043(2) -0.0031(18) -0.029(2) 0.006(2)
O2 0.039(3) 0.030(2) 0.035(2) -0.0120(18) -0.0176(19) 0.0091(19)
O3 0.045(3) 0.041(3) 0.071(3) -0.013(2) -0.033(3) 0.001(2)
O4 0.045(3) 0.020(2) 0.0270(19) -0.0030(16) -0.0200(18) 0.0026(18)
O5 0.056(3) 0.022(2) 0.042(2) -0.0069(18) -0.034(2) 0.006(2)
O6 0.041(2) 0.021(2) 0.030(2) -0.0040(16) -0.0207(18) 0.0027(17)
O7 0.038(2) 0.024(2) 0.037(2) -0.0049(17) -0.0211(19) 0.0064(18)
O8 0.047(3) 0.019(2) 0.033(2) -0.0033(17) -0.0244(19) 0.0055(18)
O9 0.051(3) 0.023(2) 0.048(2) -0.0036(19) -0.029(2) 0.0048(19)
OW 0.049(3) 0.044(3) 0.034(2) -0.0030(19) -0.023(2) -0.001(2)
Eu1 0.0410(2) 0.02093(17) 0.03067(17) -0.00630(11) -0.02178(14) 0.00740(12)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O1 1.254(8) . ?
C1 O3 1.358(8) . ?
C1 C2 1.402(8) . ?
C2 C3 1.433(8) . ?
C2 C4 1.435(9) . ?
C3 O2 1.253(7) . ?
C3 C11 1.486(8) . ?
C4 N1 1.318(9) . ?
C4 C5 1.471(9) . ?
C5 C6 1.380(10) . ?
C5 C10 1.382(9) . ?
C6 C7 1.399(10) . ?
C6 H6 0.9300 . ?
C7 C8 1.370(11) . ?
C7 H7 0.9300 . ?
C8 C9 1.379(11) . ?
C8 H8 0.9300 . ?
C9 C10 1.394(10) . ?
C9 H9 0.9300 . ?
C10 H10 0.9300 . ?
C11 C12 1.385(9) . ?
C11 C16 1.389(9) . ?
C12 C13 1.380(9) . ?
C12 H12 0.9300 . ?
C13 C14 1.376(11) . ?
C13 H13 0.9300 . ?
C14 C15 1.373(11) . ?
C14 H14 0.9300 . ?
C15 C16 1.387(9) . ?
C15 H15 0.9300 . ?
C16 H16 0.9300 . ?
C17 O4 1.241(7) . ?
C17 O6 1.371(7) . ?
C17 C18 1.407(8) . ?
C18 C19 1.421(8) . ?
C18 C20 1.421(8) . ?
C19 O5 1.250(7) . ?
C19 C27 1.495(8) . ?
C20 N2 1.315(8) . ?
C20 C21 1.495(8) . ?
C21 C22 1.383(8) . ?
C21 C26 1.397(9) . ?
C22 C23 1.380(9) . ?
C22 H22 0.9300 . ?
C23 C24 1.399(11) . ?
C23 H23 0.9300 . ?
C24 C25 1.365(11) . ?
C24 H24 0.9300 . ?
C25 C26 1.378(9) . ?
C25 H25 0.9300 . ?
C26 H26 0.9300 . ?
C27 C28 1.389(9) . ?
C27 C32 1.398(8) . ?
C28 C29 1.384(10) . ?
C28 H28 0.9300 . ?
C29 C30 1.369(10) . ?
C29 H29 0.9300 . ?
C30 C31 1.385(11) . ?
C30 H30 0.9300 . ?
C31 C32 1.385(9) . ?
C31 H31 0.9300 . ?
C32 H32 0.9300 . ?
C33 O7 1.234(6) . ?
C33 O9 1.363(7) . ?
C33 C34 1.415(8) . ?
C34 C35 1.431(8) . ?
C34 C36 1.444(8) . ?
C35 O8 1.240(7) . ?
C35 C43 1.501(8) . ?
C36 N3 1.280(8) . ?
C36 C37 1.485(8) . ?
C37 C38 1.389(10) . ?
C37 C42 1.389(9) . ?
C38 C39 1.393(9) . ?
C38 H38 0.9300 . ?
C39 C40 1.360(11) . ?
C39 H39 0.9300 . ?
C40 C41 1.373(11) . ?
C40 H40 0.9300 . ?
C41 C42 1.383(9) . ?
C41 H41 0.9300 . ?
C42 H42 0.9300 . ?
C43 C44 1.392(9) . ?
C43 C48 1.402(9) . ?
C44 C45 1.364(9) . ?
C44 H44 0.9300 . ?
C45 C46 1.390(10) . ?
C45 H45 0.9300 . ?
C46 C47 1.384(11) . ?
C46 H46 0.9300 . ?
C47 C48 1.369(9) . ?
C47 H47 0.9300 . ?
C48 H48 0.9300 . ?
C49 N4 1.338(8) . ?
C49 C50 1.386(10) . ?
C49 H49 0.9300 . ?
C50 C51 1.374(10) . ?
C50 H50 0.9300 . ?
C51 C52 1.368(11) . ?
C51 H51 0.9300 . ?
C52 C53 1.393(10) . ?
C52 H52 0.9300 . ?
C53 N4 1.367(7) . ?
C53 C54 1.468(10) . ?
C54 N5 1.343(8) . ?
C54 C55 1.385(8) . ?
C55 C56 1.372(11) . ?
C55 H55 0.9300 . ?
C56 C57 1.356(11) . ?
C56 H56 0.9300 . ?
C57 C58 1.401(9) . ?
C57 H57 0.9300 . ?
C58 N5 1.324(9) . ?
C58 H58 0.9300 . ?
N1 O3 1.437(7) . ?
N2 O6 1.434(6) . ?
N3 O9 1.436(6) . ?
N4 Eu1 2.627(5) . ?
N5 Eu1 2.687(5) . ?
O1 Eu1 2.352(5) . ?
O2 Eu1 2.459(4) . ?
O4 Eu1 2.409(4) . ?
O5 Eu1 2.406(4) . ?
O7 Eu1 2.424(4) . ?
O8 Eu1 2.464(4) . ?
OW Eu1 2.508(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C1 O3 117.1(6) . . ?
O1 C1 C2 134.0(6) . . ?
O3 C1 C2 108.9(6) . . ?
C1 C2 C3 121.4(5) . . ?
C1 C2 C4 104.8(5) . . ?
C3 C2 C4 133.8(5) . . ?
O2 C3 C2 121.5(5) . . ?
O2 C3 C11 117.3(5) . . ?
C2 C3 C11 121.2(5) . . ?
N1 C4 C2 111.2(5) . . ?
N1 C4 C5 115.1(6) . . ?
C2 C4 C5 133.7(6) . . ?
C6 C5 C10 118.4(6) . . ?
C6 C5 C4 119.6(6) . . ?
C10 C5 C4 121.9(6) . . ?
C5 C6 C7 121.2(7) . . ?
C5 C6 H6 119.4 . . ?
C7 C6 H6 119.4 . . ?
C8 C7 C6 119.1(7) . . ?
C8 C7 H7 120.5 . . ?
C6 C7 H7 120.5 . . ?
C7 C8 C9 121.0(7) . . ?
C7 C8 H8 119.5 . . ?
C9 C8 H8 119.5 . . ?
C8 C9 C10 119.1(7) . . ?
C8 C9 H9 120.4 . . ?
C10 C9 H9 120.4 . . ?
C5 C10 C9 121.2(7) . . ?
C5 C10 H10 119.4 . . ?
C9 C10 H10 119.4 . . ?
C12 C11 C16 119.7(6) . . ?
C12 C11 C3 121.5(6) . . ?
C16 C11 C3 118.8(5) . . ?
C13 C12 C11 119.8(7) . . ?
C13 C12 H12 120.1 . . ?
C11 C12 H12 120.1 . . ?
C14 C13 C12 120.4(7) . . ?
C14 C13 H13 119.8 . . ?
C12 C13 H13 119.8 . . ?
C15 C14 C13 120.1(7) . . ?
C15 C14 H14 120.0 . . ?
C13 C14 H14 120.0 . . ?
C14 C15 C16 120.2(7) . . ?
C14 C15 H15 119.9 . . ?
C16 C15 H15 119.9 . . ?
C15 C16 C11 119.6(6) . . ?
C15 C16 H16 120.2 . . ?
C11 C16 H16 120.2 . . ?
O4 C17 O6 117.9(5) . . ?
O4 C17 C18 134.2(5) . . ?
O6 C17 C18 107.9(5) . . ?
C17 C18 C19 122.4(5) . . ?
C17 C18 C20 104.8(5) . . ?
C19 C18 C20 132.6(5) . . ?
O5 C19 C18 121.8(5) . . ?
O5 C19 C27 117.1(5) . . ?
C18 C19 C27 121.1(5) . . ?
N2 C20 C18 112.3(5) . . ?
N2 C20 C21 117.9(5) . . ?
C18 C20 C21 129.7(5) . . ?
C22 C21 C26 120.1(6) . . ?
C22 C21 C20 120.1(5) . . ?
C26 C21 C20 119.9(5) . . ?
C23 C22 C21 120.3(6) . . ?
C23 C22 H22 119.8 . . ?
C21 C22 H22 119.8 . . ?
C22 C23 C24 118.9(6) . . ?
C22 C23 H23 120.6 . . ?
C24 C23 H23 120.6 . . ?
C25 C24 C23 120.9(6) . . ?
C25 C24 H24 119.5 . . ?
C23 C24 H24 119.5 . . ?
C24 C25 C26 120.3(6) . . ?
C24 C25 H25 119.8 . . ?
C26 C25 H25 119.8 . . ?
C25 C26 C21 119.5(6) . . ?
C25 C26 H26 120.3 . . ?
C21 C26 H26 120.3 . . ?
C28 C27 C32 119.5(6) . . ?
C28 C27 C19 122.0(5) . . ?
C32 C27 C19 118.5(5) . . ?
C29 C28 C27 119.9(6) . . ?
C29 C28 H28 120.1 . . ?
C27 C28 H28 120.1 . . ?
C30 C29 C28 120.3(7) . . ?
C30 C29 H29 119.9 . . ?
C28 C29 H29 119.9 . . ?
C29 C30 C31 120.7(6) . . ?
C29 C30 H30 119.6 . . ?
C31 C30 H30 119.6 . . ?
C32 C31 C30 119.5(6) . . ?
C32 C31 H31 120.2 . . ?
C30 C31 H31 120.2 . . ?
C31 C32 C27 120.0(6) . . ?
C31 C32 H32 120.0 . . ?
C27 C32 H32 120.0 . . ?
O7 C33 O9 119.1(5) . . ?
O7 C33 C34 133.8(5) . . ?
O9 C33 C34 107.1(5) . . ?
C33 C34 C35 121.0(5) . . ?
C33 C34 C36 104.5(5) . . ?
C35 C34 C36 134.4(5) . . ?
O8 C35 C34 121.9(5) . . ?
O8 C35 C43 117.0(5) . . ?
C34 C35 C43 121.1(5) . . ?
N3 C36 C34 112.0(5) . . ?
N3 C36 C37 118.7(5) . . ?
C34 C36 C37 129.0(5) . . ?
C38 C37 C42 119.1(6) . . ?
C38 C37 C36 120.8(6) . . ?
C42 C37 C36 120.1(6) . . ?
C37 C38 C39 120.2(6) . . ?
C37 C38 H38 119.9 . . ?
C39 C38 H38 119.9 . . ?
C40 C39 C38 119.9(7) . . ?
C40 C39 H39 120.1 . . ?
C38 C39 H39 120.1 . . ?
C39 C40 C41 120.6(6) . . ?
C39 C40 H40 119.7 . . ?
C41 C40 H40 119.7 . . ?
C40 C41 C42 120.3(7) . . ?
C40 C41 H41 119.8 . . ?
C42 C41 H41 119.8 . . ?
C41 C42 C37 119.9(7) . . ?
C41 C42 H42 120.0 . . ?
C37 C42 H42 120.0 . . ?
C44 C43 C48 119.2(5) . . ?
C44 C43 C35 119.2(6) . . ?
C48 C43 C35 121.3(6) . . ?
C45 C44 C43 120.6(6) . . ?
C45 C44 H44 119.7 . . ?
C43 C44 H44 119.7 . . ?
C44 C45 C46 120.0(7) . . ?
C44 C45 H45 120.0 . . ?
C46 C45 H45 120.0 . . ?
C47 C46 C45 119.9(6) . . ?
C47 C46 H46 120.1 . . ?
C45 C46 H46 120.1 . . ?
C48 C47 C46 120.5(7) . . ?
C48 C47 H47 119.8 . . ?
C46 C47 H47 119.8 . . ?
C47 C48 C43 119.8(7) . . ?
C47 C48 H48 120.1 . . ?
C43 C48 H48 120.1 . . ?
N4 C49 C50 124.3(6) . . ?
N4 C49 H49 117.8 . . ?
C50 C49 H49 117.8 . . ?
C51 C50 C49 116.8(7) . . ?
C51 C50 H50 121.6 . . ?
C49 C50 H50 121.6 . . ?
C52 C51 C50 120.6(7) . . ?
C52 C51 H51 119.7 . . ?
C50 C51 H51 119.7 . . ?
C51 C52 C53 120.1(7) . . ?
C51 C52 H52 120.0 . . ?
C53 C52 H52 120.0 . . ?
N4 C53 C52 120.0(6) . . ?
N4 C53 C54 116.4(5) . . ?
C52 C53 C54 123.6(6) . . ?
N5 C54 C55 121.4(6) . . ?
N5 C54 C53 117.6(5) . . ?
C55 C54 C53 121.0(6) . . ?
C56 C55 C54 119.9(7) . . ?
C56 C55 H55 120.1 . . ?
C54 C55 H55 120.1 . . ?
C57 C56 C55 119.4(6) . . ?
C57 C56 H56 120.3 . . ?
C55 C56 H56 120.3 . . ?
C56 C57 C58 117.8(7) . . ?
C56 C57 H57 121.1 . . ?
C58 C57 H57 121.1 . . ?
N5 C58 C57 123.6(7) . . ?
N5 C58 H58 118.2 . . ?
C57 C58 H58 118.2 . . ?
C4 N1 O3 106.5(5) . . ?
C20 N2 O6 105.8(4) . . ?
C36 N3 O9 106.8(5) . . ?
C49 N4 C53 118.1(5) . . ?
C49 N4 Eu1 119.0(4) . . ?
C53 N4 Eu1 119.4(4) . . ?
C58 N5 C54 117.9(5) . . ?
C58 N5 Eu1 122.0(4) . . ?
C54 N5 Eu1 118.9(4) . . ?
C1 O1 Eu1 127.7(4) . . ?
C3 O2 Eu1 136.3(4) . . ?
C1 O3 N1 108.7(5) . . ?
C17 O4 Eu1 128.0(3) . . ?
C19 O5 Eu1 138.1(4) . . ?
C17 O6 N2 109.0(4) . . ?
C33 O7 Eu1 127.0(4) . . ?
C35 O8 Eu1 137.1(3) . . ?
C33 O9 N3 109.5(4) . . ?
O1 Eu1 O5 87.01(14) . . ?
O1 Eu1 O4 138.38(14) . . ?
O5 Eu1 O4 73.89(13) . . ?
O1 Eu1 O7 137.10(13) . . ?
O5 Eu1 O7 135.86(14) . . ?
O4 Eu1 O7 71.38(13) . . ?
O1 Eu1 O2 73.00(14) . . ?
O5 Eu1 O2 142.12(15) . . ?
O4 Eu1 O2 99.97(13) . . ?
O7 Eu1 O2 71.16(14) . . ?
O1 Eu1 O8 75.53(14) . . ?
O5 Eu1 O8 134.46(12) . . ?
O4 Eu1 O8 142.63(13) . . ?
O7 Eu1 O8 71.51(13) . . ?
O2 Eu1 O8 71.84(13) . . ?
O1 Eu1 OW 69.97(14) . . ?
O5 Eu1 OW 71.81(15) . . ?
O4 Eu1 OW 69.02(14) . . ?
O7 Eu1 OW 118.08(14) . . ?
O2 Eu1 OW 71.19(14) . . ?
O8 Eu1 OW 135.07(14) . . ?
O1 Eu1 N4 134.76(15) . . ?
O5 Eu1 N4 71.70(16) . . ?
O4 Eu1 N4 73.88(14) . . ?
O7 Eu1 N4 73.13(15) . . ?
O2 Eu1 N4 143.78(15) . . ?
O8 Eu1 N4 91.35(14) . . ?
OW Eu1 N4 133.49(15) . . ?
O1 Eu1 N5 73.75(16) . . ?
O5 Eu1 N5 65.23(14) . . ?
O4 Eu1 N5 126.07(14) . . ?
O7 Eu1 N5 117.49(15) . . ?
O2 Eu1 N5 133.88(14) . . ?
O8 Eu1 N5 69.55(13) . . ?
OW Eu1 N5 124.15(16) . . ?
N4 Eu1 N5 61.16(16) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 C2 C3 0.8(11) . . . . ?
O3 C1 C2 C3 -179.4(5) . . . . ?
O1 C1 C2 C4 -179.6(7) . . . . ?
O3 C1 C2 C4 0.3(7) . . . . ?
C1 C2 C3 O2 -13.4(9) . . . . ?
C4 C2 C3 O2 167.0(6) . . . . ?
C1 C2 C3 C11 168.3(5) . . . . ?
C4 C2 C3 C11 -11.3(10) . . . . ?
C1 C2 C4 N1 0.3(7) . . . . ?
C3 C2 C4 N1 179.9(7) . . . . ?
C1 C2 C4 C5 178.4(7) . . . . ?
C3 C2 C4 C5 -2.0(12) . . . . ?
N1 C4 C5 C6 -46.9(9) . . . . ?
C2 C4 C5 C6 135.0(8) . . . . ?
N1 C4 C5 C10 129.1(7) . . . . ?
C2 C4 C5 C10 -48.9(11) . . . . ?
C10 C5 C6 C7 0.5(10) . . . . ?
C4 C5 C6 C7 176.7(6) . . . . ?
C5 C6 C7 C8 0.2(11) . . . . ?
C6 C7 C8 C9 -0.4(11) . . . . ?
C7 C8 C9 C10 -0.1(12) . . . . ?
C6 C5 C10 C9 -1.0(10) . . . . ?
C4 C5 C10 C9 -177.1(6) . . . . ?
C8 C9 C10 C5 0.8(11) . . . . ?
O2 C3 C11 C12 137.7(6) . . . . ?
C2 C3 C11 C12 -43.9(8) . . . . ?
O2 C3 C11 C16 -42.8(8) . . . . ?
C2 C3 C11 C16 135.5(6) . . . . ?
C16 C11 C12 C13 -1.3(9) . . . . ?
C3 C11 C12 C13 178.2(6) . . . . ?
C11 C12 C13 C14 -1.8(10) . . . . ?
C12 C13 C14 C15 2.3(11) . . . . ?
C13 C14 C15 C16 0.3(12) . . . . ?
C14 C15 C16 C11 -3.4(11) . . . . ?
C12 C11 C16 C15 3.9(9) . . . . ?
C3 C11 C16 C15 -175.6(6) . . . . ?
O4 C17 C18 C19 7.1(10) . . . . ?
O6 C17 C18 C19 -172.2(5) . . . . ?
O4 C17 C18 C20 -177.7(6) . . . . ?
O6 C17 C18 C20 3.0(6) . . . . ?
C17 C18 C19 O5 -14.1(9) . . . . ?
C20 C18 C19 O5 172.3(6) . . . . ?
C17 C18 C19 C27 164.5(5) . . . . ?
C20 C18 C19 C27 -9.1(10) . . . . ?
C17 C18 C20 N2 -1.8(7) . . . . ?
C19 C18 C20 N2 172.6(6) . . . . ?
C17 C18 C20 C21 176.0(6) . . . . ?
C19 C18 C20 C21 -9.5(11) . . . . ?
N2 C20 C21 C22 -51.2(9) . . . . ?
C18 C20 C21 C22 131.0(7) . . . . ?
N2 C20 C21 C26 128.6(7) . . . . ?
C18 C20 C21 C26 -49.2(10) . . . . ?
C26 C21 C22 C23 1.6(11) . . . . ?
C20 C21 C22 C23 -178.6(7) . . . . ?
C21 C22 C23 C24 -0.5(11) . . . . ?
C22 C23 C24 C25 -0.7(12) . . . . ?
C23 C24 C25 C26 0.7(12) . . . . ?
C24 C25 C26 C21 0.5(12) . . . . ?
C22 C21 C26 C25 -1.6(11) . . . . ?
C20 C21 C26 C25 178.6(7) . . . . ?
O5 C19 C27 C28 130.3(7) . . . . ?
C18 C19 C27 C28 -48.5(9) . . . . ?
O5 C19 C27 C32 -48.1(9) . . . . ?
C18 C19 C27 C32 133.2(6) . . . . ?
C32 C27 C28 C29 -2.4(11) . . . . ?
C19 C27 C28 C29 179.3(7) . . . . ?
C27 C28 C29 C30 -1.4(12) . . . . ?
C28 C29 C30 C31 3.4(13) . . . . ?
C29 C30 C31 C32 -1.4(14) . . . . ?
C30 C31 C32 C27 -2.4(13) . . . . ?
C28 C27 C32 C31 4.3(11) . . . . ?
C19 C27 C32 C31 -177.3(7) . . . . ?
O7 C33 C34 C35 3.2(10) . . . . ?
O9 C33 C34 C35 -175.1(5) . . . . ?
O7 C33 C34 C36 -179.6(6) . . . . ?
O9 C33 C34 C36 2.1(6) . . . . ?
C33 C34 C35 O8 -13.3(9) . . . . ?
C36 C34 C35 O8 170.5(6) . . . . ?
C33 C34 C35 C43 166.6(5) . . . . ?
C36 C34 C35 C43 -9.6(10) . . . . ?
C33 C34 C36 N3 -0.5(7) . . . . ?
C35 C34 C36 N3 176.1(6) . . . . ?
C33 C34 C36 C37 173.4(6) . . . . ?
C35 C34 C36 C37 -10.0(11) . . . . ?
N3 C36 C37 C38 118.9(7) . . . . ?
C34 C36 C37 C38 -54.6(9) . . . . ?
N3 C36 C37 C42 -58.8(8) . . . . ?
C34 C36 C37 C42 127.7(7) . . . . ?
C42 C37 C38 C39 -0.4(10) . . . . ?
C36 C37 C38 C39 -178.2(6) . . . . ?
C37 C38 C39 C40 -0.7(11) . . . . ?
C38 C39 C40 C41 1.0(11) . . . . ?
C39 C40 C41 C42 -0.3(11) . . . . ?
C40 C41 C42 C37 -0.8(10) . . . . ?
C38 C37 C42 C41 1.1(9) . . . . ?
C36 C37 C42 C41 178.9(6) . . . . ?
O8 C35 C43 C44 -43.6(7) . . . . ?
C34 C35 C43 C44 136.5(6) . . . . ?
O8 C35 C43 C48 130.8(6) . . . . ?
C34 C35 C43 C48 -49.1(8) . . . . ?
C48 C43 C44 C45 1.5(8) . . . . ?
C35 C43 C44 C45 176.0(5) . . . . ?
C43 C44 C45 C46 -2.8(9) . . . . ?
C44 C45 C46 C47 1.7(10) . . . . ?
C45 C46 C47 C48 0.7(10) . . . . ?
C46 C47 C48 C43 -2.0(10) . . . . ?
C44 C43 C48 C47 0.9(9) . . . . ?
C35 C43 C48 C47 -173.5(5) . . . . ?
N4 C49 C50 C51 1.5(11) . . . . ?
C49 C50 C51 C52 -2.6(13) . . . . ?
C50 C51 C52 C53 1.0(14) . . . . ?
C51 C52 C53 N4 2.0(12) . . . . ?
C51 C52 C53 C54 -175.9(7) . . . . ?
N4 C53 C54 N5 8.6(8) . . . . ?
C52 C53 C54 N5 -173.3(6) . . . . ?
N4 C53 C54 C55 -171.0(6) . . . . ?
C52 C53 C54 C55 7.0(10) . . . . ?
N5 C54 C55 C56 0.9(10) . . . . ?
C53 C54 C55 C56 -179.5(6) . . . . ?
C54 C55 C56 C57 -0.8(11) . . . . ?
C55 C56 C57 C58 -0.3(12) . . . . ?
C56 C57 C58 N5 1.3(12) . . . . ?
C2 C4 N1 O3 -0.7(8) . . . . ?
C5 C4 N1 O3 -179.2(5) . . . . ?
C18 C20 N2 O6 0.0(6) . . . . ?
C21 C20 N2 O6 -178.2(5) . . . . ?
C34 C36 N3 O9 -1.2(7) . . . . ?
C37 C36 N3 O9 -175.8(5) . . . . ?
C50 C49 N4 C53 1.4(9) . . . . ?
C50 C49 N4 Eu1 -157.4(5) . . . . ?
C52 C53 N4 C49 -3.1(9) . . . . ?
C54 C53 N4 C49 175.0(5) . . . . ?
C52 C53 N4 Eu1 155.6(5) . . . . ?
C54 C53 N4 Eu1 -26.3(7) . . . . ?
C57 C58 N5 C54 -1.2(11) . . . . ?
C57 C58 N5 Eu1 166.3(6) . . . . ?
C55 C54 N5 C58 0.0(9) . . . . ?
C53 C54 N5 C58 -179.6(6) . . . . ?
C55 C54 N5 Eu1 -167.8(5) . . . . ?
C53 C54 N5 Eu1 12.5(7) . . . . ?
O3 C1 O1 Eu1 -154.8(4) . . . . ?
C2 C1 O1 Eu1 25.0(10) . . . . ?
C2 C3 O2 Eu1 -0.8(9) . . . . ?
C11 C3 O2 Eu1 177.6(4) . . . . ?
O1 C1 O3 N1 179.1(5) . . . . ?
C2 C1 O3 N1 -0.7(7) . . . . ?
C4 N1 O3 C1 0.9(7) . . . . ?
O6 C17 O4 Eu1 -173.6(3) . . . . ?
C18 C17 O4 Eu1 7.2(9) . . . . ?
C18 C19 O5 Eu1 7.2(9) . . . . ?
C27 C19 O5 Eu1 -171.5(4) . . . . ?
O4 C17 O6 N2 177.5(5) . . . . ?
C18 C17 O6 N2 -3.1(6) . . . . ?
C20 N2 O6 C17 2.0(6) . . . . ?
O9 C33 O7 Eu1 -156.9(4) . . . . ?
C34 C33 O7 Eu1 25.0(9) . . . . ?
C34 C35 O8 Eu1 -6.8(9) . . . . ?
C43 C35 O8 Eu1 173.3(4) . . . . ?
O7 C33 O9 N3 178.5(5) . . . . ?
C34 C33 O9 N3 -2.9(6) . . . . ?
C36 N3 O9 C33 2.6(7) . . . . ?
C1 O1 Eu1 O5 -171.9(5) . . . . ?
C1 O1 Eu1 O4 -110.4(5) . . . . ?
C1 O1 Eu1 O7 10.0(6) . . . . ?
C1 O1 Eu1 O2 -24.5(5) . . . . ?
C1 O1 Eu1 O8 50.6(5) . . . . ?
C1 O1 Eu1 OW -100.1(5) . . . . ?
C1 O1 Eu1 N4 127.8(5) . . . . ?
C1 O1 Eu1 N5 123.1(5) . . . . ?
C19 O5 Eu1 O1 145.5(6) . . . . ?
C19 O5 Eu1 O4 2.9(6) . . . . ?
C19 O5 Eu1 O7 -36.3(7) . . . . ?
C19 O5 Eu1 O2 88.4(6) . . . . ?
C19 O5 Eu1 O8 -148.2(5) . . . . ?
C19 O5 Eu1 OW 75.6(6) . . . . ?
C19 O5 Eu1 N4 -75.0(6) . . . . ?
C19 O5 Eu1 N5 -141.0(6) . . . . ?
C17 O4 Eu1 O1 -75.4(5) . . . . ?
C17 O4 Eu1 O5 -9.4(4) . . . . ?
C17 O4 Eu1 O7 142.9(5) . . . . ?
C17 O4 Eu1 O2 -151.0(5) . . . . ?
C17 O4 Eu1 O8 135.9(4) . . . . ?
C17 O4 Eu1 OW -85.7(5) . . . . ?
C17 O4 Eu1 N4 65.7(5) . . . . ?
C17 O4 Eu1 N5 32.0(5) . . . . ?
C33 O7 Eu1 O1 14.4(5) . . . . ?
C33 O7 Eu1 O5 -162.9(4) . . . . ?
C33 O7 Eu1 O4 157.2(5) . . . . ?
C33 O7 Eu1 O2 49.3(4) . . . . ?
C33 O7 Eu1 O8 -27.2(4) . . . . ?
C33 O7 Eu1 OW 104.7(4) . . . . ?
C33 O7 Eu1 N4 -124.5(5) . . . . ?
C33 O7 Eu1 N5 -81.1(5) . . . . ?
C3 O2 Eu1 O1 15.1(5) . . . . ?
C3 O2 Eu1 O5 76.3(6) . . . . ?
C3 O2 Eu1 O4 152.8(5) . . . . ?
C3 O2 Eu1 O7 -140.9(5) . . . . ?
C3 O2 Eu1 O8 -64.9(5) . . . . ?
C3 O2 Eu1 OW 89.2(5) . . . . ?
C3 O2 Eu1 N4 -130.9(5) . . . . ?
C3 O2 Eu1 N5 -30.5(6) . . . . ?
C35 O8 Eu1 O1 -130.9(6) . . . . ?
C35 O8 Eu1 O5 158.3(5) . . . . ?
C35 O8 Eu1 O4 28.2(6) . . . . ?
C35 O8 Eu1 O7 21.3(5) . . . . ?
C35 O8 Eu1 O2 -54.3(5) . . . . ?
C35 O8 Eu1 OW -90.3(6) . . . . ?
C35 O8 Eu1 N4 93.0(6) . . . . ?
C35 O8 Eu1 N5 151.4(6) . . . . ?
C49 N4 Eu1 O1 175.9(4) . . . . ?
C53 N4 Eu1 O1 17.4(5) . . . . ?
C49 N4 Eu1 O5 109.8(4) . . . . ?
C53 N4 Eu1 O5 -48.7(4) . . . . ?
C49 N4 Eu1 O4 31.8(4) . . . . ?
C53 N4 Eu1 O4 -126.6(4) . . . . ?
C49 N4 Eu1 O7 -43.1(4) . . . . ?
C53 N4 Eu1 O7 158.4(4) . . . . ?
C49 N4 Eu1 O2 -53.0(5) . . . . ?
C53 N4 Eu1 O2 148.5(4) . . . . ?
C49 N4 Eu1 O8 -113.3(4) . . . . ?
C53 N4 Eu1 O8 88.2(4) . . . . ?
C49 N4 Eu1 OW 69.9(5) . . . . ?
C53 N4 Eu1 OW -88.6(4) . . . . ?
C49 N4 Eu1 N5 -179.0(5) . . . . ?
C53 N4 Eu1 N5 22.5(4) . . . . ?
C58 N5 Eu1 O1 -8.9(5) . . . . ?
C54 N5 Eu1 O1 158.5(5) . . . . ?
C58 N5 Eu1 O5 -103.1(5) . . . . ?
C54 N5 Eu1 O5 64.2(4) . . . . ?
C58 N5 Eu1 O4 -147.6(5) . . . . ?
C54 N5 Eu1 O4 19.8(5) . . . . ?
C58 N5 Eu1 O7 126.2(5) . . . . ?
C54 N5 Eu1 O7 -66.4(5) . . . . ?
C58 N5 Eu1 O2 36.5(6) . . . . ?
C54 N5 Eu1 O2 -156.1(4) . . . . ?
C58 N5 Eu1 O8 71.4(5) . . . . ?
C54 N5 Eu1 O8 -121.2(5) . . . . ?
C58 N5 Eu1 OW -59.9(6) . . . . ?
C54 N5 Eu1 OW 107.4(4) . . . . ?
C58 N5 Eu1 N4 174.9(6) . . . . ?
C54 N5 Eu1 N4 -17.7(4) . . . . ?

_diffrn_measured_fraction_theta_max 0.983
_diffrn_reflns_theta_full        27.42
_diffrn_measured_fraction_theta_full 0.983
_refine_diff_density_max         2.254
_refine_diff_density_min         -1.285
_refine_diff_density_rms         0.197