# Electronic Supplementary Material (ESI) for New Journal of Chemistry
# This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique 2013

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
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#  data retrieval see:
#                         www.ccdc.cam.ac.uk
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#  from this site to visualise CIF-encoded structures and 
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data_1

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C26 H20 Ag N6, C F3 O3 S'
_chemical_formula_sum            'C27 H20 Ag F3 N6 O3 S'
_chemical_formula_weight         673.42

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'I 2/a'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x, -y+1/2, z+1/2'

_cell_length_a                   25.592(18)
_cell_length_b                   7.825(3)
_cell_length_c                   26.830(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 92.66(2)
_cell_angle_gamma                90.00
_cell_volume                     5367(4)
_cell_formula_units_Z            8
_cell_measurement_temperature    295(2)
_cell_measurement_reflns_used    3433
_cell_measurement_theta_min      3
_cell_measurement_theta_max      25

_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.05
_exptl_crystal_density_diffrn    1.667
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2704
_exptl_absorpt_coefficient_mu    0.892
_exptl_absorpt_correction_T_min  0.60801
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      295(2)
_diffrn_radiation_wavelength     0.7107
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_detector_area_resol_mean 16.1544
_diffrn_measurement_method       \w-scan
_diffrn_reflns_number            7243
_diffrn_reflns_av_R_equivalents  0.1015
_diffrn_reflns_av_sigmaI/netI    0.2173
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_theta_min         3.04
_diffrn_reflns_theta_max         25.00
_reflns_number_total             4153
_reflns_number_gt                1855
_reflns_threshold_expression     >2\s(I)

_computing_data_collection       'CrysAlis Pro (Agilent Technologies (2011))'
_computing_cell_refinement       'CrysAlis Pro (Agilent Technologies (2011))'
_computing_data_reduction        'CrysAlis Pro (Agilent Technologies (2011))'
_computing_structure_solution    'SIR92 (Altomare et al., 1993)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'Stereochemical Workstation (Siemens, 1989)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 2008)'

_refine_special_details          
;
 Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F^2^, conventional R-factors R are based
 on F, with F set to zero for negative F^2^. The threshold expression of
 F^2^ > 2\s(F^2^) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F^2^ are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0450P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4153
_refine_ls_number_parameters     372
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1957
_refine_ls_R_factor_gt           0.0804
_refine_ls_wR_factor_ref         0.1831
_refine_ls_wR_factor_gt          0.1444
_refine_ls_goodness_of_fit_ref   0.917
_refine_ls_restrained_S_all      0.917
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.60202(3) -0.03624(13) 0.18553(3) 0.0458(3) Uani 1 1 d . . .
N1 N 0.6926(3) -0.0002(12) 0.2129(4) 0.043(3) Uani 1 1 d . . .
C2 C 0.7270(4) 0.0754(16) 0.1839(4) 0.046(3) Uani 1 1 d . . .
C2A C 0.7079(5) 0.1236(18) 0.1325(5) 0.073(4) Uani 1 1 d . . .
H2A1 H 0.7042 0.0226 0.1123 0.109 Uiso 1 1 calc R . .
H2A2 H 0.7326 0.1995 0.1182 0.109 Uiso 1 1 calc R . .
H2A3 H 0.6747 0.1797 0.1339 0.109 Uiso 1 1 calc R . .
C3 C 0.7783(5) 0.1042(18) 0.2017(5) 0.064(4) Uani 1 1 d . . .
H3 H 0.8028 0.1508 0.1811 0.077 Uiso 1 1 calc R . .
C4 C 0.7920(5) 0.0623(17) 0.2507(5) 0.063(4) Uani 1 1 d . . .
H4 H 0.8254 0.0859 0.2641 0.075 Uiso 1 1 calc R . .
C5 C 0.7559(4) -0.0140(17) 0.2789(5) 0.062(4) Uani 1 1 d . . .
H5 H 0.7658 -0.0477 0.3112 0.074 Uiso 1 1 calc R . .
C6 C 0.7047(4) -0.0434(16) 0.2612(5) 0.047(3) Uani 1 1 d . . .
C7 C 0.6663(4) -0.1315(15) 0.2897(4) 0.041(3) Uani 1 1 d . . .
N8 N 0.6150(3) -0.1241(12) 0.2709(3) 0.037(2) Uani 1 1 d . . .
C9 C 0.5795(4) -0.2084(14) 0.2941(4) 0.035(3) Uani 1 1 d . . .
C10 C 0.5890(5) -0.3037(14) 0.3387(4) 0.040(3) Uani 1 1 d . . .
H10 H 0.5627 -0.3616 0.3545 0.048 Uiso 1 1 calc R . .
C11 C 0.6414(5) -0.3031(16) 0.3570(4) 0.058(4) Uani 1 1 d . . .
H11 H 0.6507 -0.3627 0.3860 0.069 Uiso 1 1 calc R . .
C12 C 0.6779(5) -0.2179(16) 0.3331(5) 0.054(4) Uani 1 1 d . . .
H12 H 0.7121 -0.2173 0.3463 0.065 Uiso 1 1 calc R . .
C13 C 0.5243(4) -0.2000(15) 0.2703(4) 0.036(3) Uani 1 1 d . . .
N14 N 0.5241(3) -0.1875(12) 0.2197(3) 0.039(3) Uani 1 1 d . . .
C15 C 0.4767(5) -0.1879(15) 0.1967(4) 0.047(3) Uani 1 1 d . . .
H15 H 0.4743 -0.1749 0.1622 0.057 Uiso 1 1 calc R . .
C16 C 0.4314(4) -0.2065(16) 0.2213(4) 0.050(4) Uani 1 1 d . . .
H16 H 0.3999 -0.2127 0.2026 0.060 Uiso 1 1 calc R . .
N17 N 0.4302(3) -0.2161(13) 0.2697(3) 0.048(3) Uani 1 1 d . . .
C18 C 0.4789(5) -0.2052(14) 0.2938(4) 0.038(3) Uani 1 1 d . . .
C19 C 0.4725(4) -0.2156(17) 0.3497(5) 0.044(3) Uani 1 1 d . . .
N20 N 0.4503(3) -0.3524(12) 0.3672(3) 0.037(2) Uani 1 1 d . . .
C21 C 0.4468(4) -0.3716(16) 0.4160(4) 0.035(3) Uani 1 1 d . . .
C22 C 0.4636(5) -0.2400(18) 0.4492(4) 0.059(4) Uani 1 1 d . . .
H22 H 0.4583 -0.2481 0.4831 0.071 Uiso 1 1 calc R . .
C23 C 0.4879(4) -0.0995(16) 0.4298(4) 0.049(3) Uani 1 1 d . . .
H23 H 0.5002 -0.0133 0.4511 0.059 Uiso 1 1 calc R . .
C24 C 0.4940(5) -0.0852(17) 0.3804(5) 0.058(4) Uani 1 1 d . . .
H24 H 0.5117 0.0068 0.3671 0.070 Uiso 1 1 calc R . .
C25 C 0.4245(4) -0.5331(18) 0.4336(4) 0.040(3) Uani 1 1 d . . .
N26 N 0.4043(4) -0.6355(14) 0.3969(3) 0.047(3) Uani 1 1 d . . .
C27 C 0.3831(5) -0.7871(19) 0.4118(5) 0.057(4) Uani 1 1 d . . .
C27A C 0.3597(5) -0.8953(17) 0.3698(5) 0.075(5) Uani 1 1 d . . .
H27A H 0.3334 -0.8307 0.3513 0.112 Uiso 1 1 calc R . .
H27B H 0.3442 -0.9958 0.3833 0.112 Uiso 1 1 calc R . .
H27C H 0.3867 -0.9281 0.3480 0.112 Uiso 1 1 calc R . .
C28 C 0.3823(5) -0.8372(19) 0.4618(5) 0.065(4) Uani 1 1 d . . .
H28 H 0.3674 -0.9405 0.4709 0.078 Uiso 1 1 calc R . .
C29 C 0.4038(6) -0.731(2) 0.4963(5) 0.071(4) Uani 1 1 d . . .
H29 H 0.4040 -0.7622 0.5297 0.085 Uiso 1 1 calc R . .
C30 C 0.4256(5) -0.5756(19) 0.4838(5) 0.059(4) Uani 1 1 d . . .
H30 H 0.4403 -0.5030 0.5080 0.071 Uiso 1 1 calc R . .
S1A S 0.62028(14) 0.2865(5) -0.08250(12) 0.0566(10) Uani 1 1 d . . .
O1A O 0.5854(4) 0.1458(14) -0.0813(4) 0.102(4) Uani 1 1 d . . .
O2A O 0.6445(3) 0.3101(12) -0.1277(3) 0.077(3) Uani 1 1 d . . .
O3A O 0.5980(5) 0.4308(15) -0.0603(4) 0.132(5) Uani 1 1 d . . .
C1A C 0.6736(5) 0.238(2) -0.0380(5) 0.062(4) Uani 1 1 d . . .
F1A F 0.6933(3) 0.0863(13) -0.0480(4) 0.115(4) Uani 1 1 d . . .
F2A F 0.6576(3) 0.2244(11) 0.0092(3) 0.082(3) Uani 1 1 d . . .
F3A F 0.7097(3) 0.3581(14) -0.0383(3) 0.117(4) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ag1 0.0449(6) 0.0601(7) 0.0313(5) 0.0049(6) -0.0090(4) 0.0045(5)
N1 0.035(5) 0.049(8) 0.045(6) 0.000(6) -0.009(5) 0.008(5)
C2 0.033(7) 0.070(11) 0.035(7) -0.004(7) 0.011(6) -0.009(7)
C2A 0.064(9) 0.106(13) 0.048(9) 0.012(9) -0.007(7) -0.027(9)
C3 0.042(8) 0.100(13) 0.049(9) -0.004(9) 0.002(7) -0.001(8)
C4 0.032(7) 0.082(12) 0.073(10) 0.010(10) -0.009(7) -0.006(7)
C5 0.029(7) 0.106(13) 0.050(8) -0.006(9) -0.008(6) -0.002(8)
C6 0.041(7) 0.045(8) 0.053(8) -0.006(8) -0.006(6) 0.003(7)
C7 0.040(7) 0.051(9) 0.032(7) 0.010(7) 0.006(6) 0.000(7)
N8 0.032(6) 0.057(7) 0.023(5) 0.005(5) 0.006(4) -0.002(5)
C9 0.051(7) 0.025(7) 0.027(6) -0.002(6) -0.016(6) -0.003(6)
C10 0.075(9) 0.024(7) 0.022(6) 0.001(6) -0.008(6) 0.003(6)
C11 0.089(10) 0.057(10) 0.024(7) 0.014(7) -0.026(7) -0.017(8)
C12 0.063(9) 0.051(9) 0.046(8) 0.012(8) -0.020(7) -0.008(7)
C13 0.037(7) 0.043(8) 0.028(6) 0.013(6) -0.001(6) -0.008(6)
N14 0.040(6) 0.049(7) 0.029(5) -0.001(5) 0.000(5) -0.006(5)
C15 0.052(8) 0.055(10) 0.033(7) 0.006(7) -0.016(6) -0.011(7)
C16 0.034(8) 0.082(11) 0.034(7) 0.001(8) -0.002(6) -0.021(7)
N17 0.045(6) 0.068(8) 0.031(6) -0.006(6) -0.005(5) -0.016(5)
C18 0.047(8) 0.034(8) 0.034(7) 0.013(6) -0.002(6) -0.004(6)
C19 0.033(7) 0.056(9) 0.042(8) 0.011(8) 0.000(6) 0.006(7)
N20 0.045(6) 0.037(7) 0.030(6) 0.013(5) -0.001(4) -0.006(5)
C21 0.025(6) 0.046(8) 0.034(7) -0.009(7) -0.010(5) -0.002(6)
C22 0.059(9) 0.084(12) 0.031(7) -0.008(8) -0.015(6) 0.003(8)
C23 0.058(8) 0.053(10) 0.038(8) -0.003(7) 0.002(6) -0.026(7)
C24 0.071(9) 0.058(10) 0.045(8) 0.012(8) 0.003(7) -0.032(8)
C25 0.024(6) 0.072(10) 0.023(6) 0.004(7) 0.005(5) 0.018(7)
N26 0.048(6) 0.062(8) 0.032(6) -0.011(6) 0.001(5) -0.008(6)
C27 0.049(8) 0.077(12) 0.045(9) -0.002(9) 0.002(7) -0.016(8)
C27A 0.082(10) 0.078(12) 0.062(10) -0.004(9) -0.019(7) -0.044(8)
C28 0.078(10) 0.065(11) 0.051(9) 0.024(9) 0.006(8) -0.026(8)
C29 0.093(12) 0.073(12) 0.046(9) 0.003(10) 0.001(8) 0.005(10)
C30 0.059(9) 0.079(12) 0.040(8) 0.002(9) 0.001(6) 0.009(8)
S1A 0.062(2) 0.070(3) 0.036(2) -0.009(2) -0.0134(17) 0.007(2)
O1A 0.099(8) 0.132(10) 0.071(8) 0.032(7) -0.038(6) -0.046(7)
O2A 0.086(7) 0.118(9) 0.027(5) 0.007(6) -0.001(5) -0.008(6)
O3A 0.176(11) 0.142(11) 0.071(8) -0.059(8) -0.061(7) 0.104(9)
C1A 0.069(10) 0.081(12) 0.033(8) -0.015(9) -0.025(7) 0.019(9)
F1A 0.106(7) 0.120(9) 0.112(8) -0.025(7) -0.049(5) 0.042(7)
F2A 0.073(5) 0.135(8) 0.037(5) 0.002(5) -0.016(4) -0.001(5)
F3A 0.082(6) 0.177(10) 0.087(7) -0.033(7) -0.033(5) -0.064(6)

_geom_special_details            
;
 All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell s.u.'s are taken
 into account individually in the estimation of s.u.'s in distances, angles
 and torsion angles; correlations between s.u.'s in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N26 2.344(10) 4 ?
Ag1 N20 2.384(9) 4 ?
Ag1 N8 2.401(9) . ?
Ag1 N1 2.416(9) . ?
Ag1 N14 2.529(8) . ?
N1 C2 1.340(13) . ?
N1 C6 1.361(14) . ?
C2 C3 1.393(15) . ?
C2 C2A 1.490(15) . ?
C3 C4 1.383(16) . ?
C4 C5 1.359(15) . ?
C5 C6 1.393(14) . ?
C6 C7 1.446(15) . ?
C7 C12 1.367(15) . ?
C7 N8 1.386(13) . ?
N8 C9 1.303(13) . ?
C9 C10 1.422(14) . ?
C9 C13 1.522(14) . ?
C10 C11 1.407(15) . ?
C11 C12 1.336(15) . ?
C13 C18 1.349(14) . ?
C13 N14 1.361(12) . ?
N14 C15 1.337(13) . ?
C15 C16 1.369(14) . ?
C16 N17 1.302(13) . ?
N17 C18 1.380(13) . ?
C18 C19 1.518(15) . ?
C19 N20 1.309(13) . ?
C19 C24 1.406(15) . ?
N20 C21 1.326(13) . ?
N20 Ag1 2.384(9) 4_545 ?
C21 C22 1.414(15) . ?
C21 C25 1.474(16) . ?
C22 C23 1.377(15) . ?
C23 C24 1.348(15) . ?
C25 N26 1.352(13) . ?
C25 C30 1.387(15) . ?
N26 C27 1.371(15) . ?
N26 Ag1 2.344(10) 4_545 ?
C27 C28 1.399(16) . ?
C27 C27A 1.512(16) . ?
C28 C29 1.345(17) . ?
C29 C30 1.382(17) . ?
S1A O2A 1.399(8) . ?
S1A O3A 1.410(10) . ?
S1A O1A 1.419(10) . ?
S1A C1A 1.812(13) . ?
C1A F3A 1.318(15) . ?
C1A F1A 1.321(15) . ?
C1A F2A 1.353(13) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N26 Ag1 N20 68.1(3) 4 4 ?
N26 Ag1 N8 143.8(3) 4 . ?
N20 Ag1 N8 142.0(3) 4 . ?
N26 Ag1 N1 110.5(3) 4 . ?
N20 Ag1 N1 127.9(3) 4 . ?
N8 Ag1 N1 69.8(3) . . ?
N26 Ag1 N14 99.6(3) 4 . ?
N20 Ag1 N14 93.8(3) 4 . ?
N8 Ag1 N14 66.1(3) . . ?
N1 Ag1 N14 134.9(3) . . ?
C2 N1 C6 122.5(9) . . ?
C2 N1 Ag1 121.5(8) . . ?
C6 N1 Ag1 115.7(7) . . ?
N1 C2 C3 120.4(11) . . ?
N1 C2 C2A 116.9(10) . . ?
C3 C2 C2A 122.7(11) . . ?
C4 C3 C2 118.7(11) . . ?
C5 C4 C3 119.0(11) . . ?
C4 C5 C6 122.4(12) . . ?
N1 C6 C5 116.9(11) . . ?
N1 C6 C7 119.4(10) . . ?
C5 C6 C7 123.4(12) . . ?
C12 C7 N8 119.6(10) . . ?
C12 C7 C6 124.0(11) . . ?
N8 C7 C6 116.4(10) . . ?
C9 N8 C7 118.4(9) . . ?
C9 N8 Ag1 122.1(7) . . ?
C7 N8 Ag1 116.4(7) . . ?
N8 C9 C10 124.8(10) . . ?
N8 C9 C13 115.6(10) . . ?
C10 C9 C13 119.6(10) . . ?
C11 C10 C9 114.5(10) . . ?
C12 C11 C10 120.8(11) . . ?
C11 C12 C7 121.8(12) . . ?
C18 C13 N14 120.3(10) . . ?
C18 C13 C9 127.3(10) . . ?
N14 C13 C9 112.4(9) . . ?
C15 N14 C13 115.1(9) . . ?
C15 N14 Ag1 123.2(8) . . ?
C13 N14 Ag1 115.4(7) . . ?
N14 C15 C16 123.1(11) . . ?
N17 C16 C15 123.2(11) . . ?
C16 N17 C18 113.7(9) . . ?
C13 C18 N17 124.2(11) . . ?
C13 C18 C19 126.7(10) . . ?
N17 C18 C19 108.9(9) . . ?
N20 C19 C24 123.3(11) . . ?
N20 C19 C18 117.7(11) . . ?
C24 C19 C18 118.8(11) . . ?
C19 N20 C21 119.7(11) . . ?
C19 N20 Ag1 121.5(8) . 4_545 ?
C21 N20 Ag1 117.2(7) . 4_545 ?
N20 C21 C22 120.5(11) . . ?
N20 C21 C25 117.3(10) . . ?
C22 C21 C25 122.2(11) . . ?
C23 C22 C21 118.2(11) . . ?
C24 C23 C22 120.8(12) . . ?
C23 C24 C19 117.1(11) . . ?
N26 C25 C30 123.6(13) . . ?
N26 C25 C21 114.6(10) . . ?
C30 C25 C21 121.8(12) . . ?
C25 N26 C27 116.3(11) . . ?
C25 N26 Ag1 119.8(8) . 4_545 ?
C27 N26 Ag1 123.4(8) . 4_545 ?
N26 C27 C28 123.1(13) . . ?
N26 C27 C27A 114.5(11) . . ?
C28 C27 C27A 122.4(13) . . ?
C29 C28 C27 117.5(13) . . ?
C28 C29 C30 122.2(14) . . ?
C29 C30 C25 117.2(14) . . ?
O2A S1A O3A 117.7(7) . . ?
O2A S1A O1A 115.2(6) . . ?
O3A S1A O1A 110.1(8) . . ?
O2A S1A C1A 104.4(6) . . ?
O3A S1A C1A 101.4(7) . . ?
O1A S1A C1A 106.2(7) . . ?
F3A C1A F1A 111.4(12) . . ?
F3A C1A F2A 107.8(11) . . ?
F1A C1A F2A 104.7(13) . . ?
F3A C1A S1A 110.7(11) . . ?
F1A C1A S1A 109.7(10) . . ?
F2A C1A S1A 112.4(9) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N26 Ag1 N1 C2 44.9(10) 4 . . . ?
N20 Ag1 N1 C2 -32.8(10) 4 . . . ?
N8 Ag1 N1 C2 -173.8(10) . . . . ?
N14 Ag1 N1 C2 173.4(8) . . . . ?
N26 Ag1 N1 C6 -142.3(9) 4 . . . ?
N20 Ag1 N1 C6 140.0(8) 4 . . . ?
N8 Ag1 N1 C6 -1.0(8) . . . . ?
N14 Ag1 N1 C6 -13.8(11) . . . . ?
C6 N1 C2 C3 3.6(19) . . . . ?
Ag1 N1 C2 C3 176.0(9) . . . . ?
C6 N1 C2 C2A -177.0(12) . . . . ?
Ag1 N1 C2 C2A -4.7(15) . . . . ?
N1 C2 C3 C4 -4(2) . . . . ?
C2A C2 C3 C4 177.1(14) . . . . ?
C2 C3 C4 C5 4(2) . . . . ?
C3 C4 C5 C6 -4(2) . . . . ?
C2 N1 C6 C5 -3.4(18) . . . . ?
Ag1 N1 C6 C5 -176.2(9) . . . . ?
C2 N1 C6 C7 -177.2(10) . . . . ?
Ag1 N1 C6 C7 10.0(14) . . . . ?
C4 C5 C6 N1 3(2) . . . . ?
C4 C5 C6 C7 176.9(12) . . . . ?
N1 C6 C7 C12 162.8(12) . . . . ?
C5 C6 C7 C12 -11(2) . . . . ?
N1 C6 C7 N8 -17.8(17) . . . . ?
C5 C6 C7 N8 168.8(12) . . . . ?
C12 C7 N8 C9 -3.8(17) . . . . ?
C6 C7 N8 C9 176.8(10) . . . . ?
C12 C7 N8 Ag1 -164.3(9) . . . . ?
C6 C7 N8 Ag1 16.2(13) . . . . ?
N26 Ag1 N8 C9 -70.6(10) 4 . . . ?
N20 Ag1 N8 C9 65.7(10) 4 . . . ?
N1 Ag1 N8 C9 -168.0(9) . . . . ?
N14 Ag1 N8 C9 2.2(8) . . . . ?
N26 Ag1 N8 C7 89.2(9) 4 . . . ?
N20 Ag1 N8 C7 -134.5(8) 4 . . . ?
N1 Ag1 N8 C7 -8.2(8) . . . . ?
N14 Ag1 N8 C7 162.0(9) . . . . ?
C7 N8 C9 C10 2.6(17) . . . . ?
Ag1 N8 C9 C10 162.0(8) . . . . ?
C7 N8 C9 C13 -177.8(10) . . . . ?
Ag1 N8 C9 C13 -18.4(13) . . . . ?
N8 C9 C10 C11 -0.7(17) . . . . ?
C13 C9 C10 C11 179.6(10) . . . . ?
C9 C10 C11 C12 0.1(18) . . . . ?
C10 C11 C12 C7 -1(2) . . . . ?
N8 C7 C12 C11 3(2) . . . . ?
C6 C7 C12 C11 -177.3(12) . . . . ?
N8 C9 C13 C18 -148.4(12) . . . . ?
C10 C9 C13 C18 31.3(18) . . . . ?
N8 C9 C13 N14 32.2(14) . . . . ?
C10 C9 C13 N14 -148.1(10) . . . . ?
C18 C13 N14 C15 -2.5(17) . . . . ?
C9 C13 N14 C15 176.9(10) . . . . ?
C18 C13 N14 Ag1 150.5(9) . . . . ?
C9 C13 N14 Ag1 -30.0(12) . . . . ?
N26 Ag1 N14 C15 -48.1(10) 4 . . . ?
N20 Ag1 N14 C15 20.4(9) 4 . . . ?
N8 Ag1 N14 C15 166.8(10) . . . . ?
N1 Ag1 N14 C15 179.9(8) . . . . ?
N26 Ag1 N14 C13 161.2(8) 4 . . . ?
N20 Ag1 N14 C13 -130.3(8) 4 . . . ?
N8 Ag1 N14 C13 16.1(8) . . . . ?
N1 Ag1 N14 C13 29.2(10) . . . . ?
C13 N14 C15 C16 -2.6(18) . . . . ?
Ag1 N14 C15 C16 -153.3(9) . . . . ?
N14 C15 C16 N17 4(2) . . . . ?
C15 C16 N17 C18 0.2(18) . . . . ?
N14 C13 C18 N17 6.9(19) . . . . ?
C9 C13 C18 N17 -172.5(11) . . . . ?
N14 C13 C18 C19 -178.8(11) . . . . ?
C9 C13 C18 C19 2(2) . . . . ?
C16 N17 C18 C13 -5.5(18) . . . . ?
C16 N17 C18 C19 179.3(11) . . . . ?
C13 C18 C19 N20 -116.1(13) . . . . ?
N17 C18 C19 N20 59.0(14) . . . . ?
C13 C18 C19 C24 59.3(17) . . . . ?
N17 C18 C19 C24 -125.7(11) . . . . ?
C24 C19 N20 C21 0.7(17) . . . . ?
C18 C19 N20 C21 175.8(9) . . . . ?
C24 C19 N20 Ag1 165.9(9) . . . 4_545 ?
C18 C19 N20 Ag1 -19.0(14) . . . 4_545 ?
C19 N20 C21 C22 4.6(16) . . . . ?
Ag1 N20 C21 C22 -161.2(8) 4_545 . . . ?
C19 N20 C21 C25 -176.2(9) . . . . ?
Ag1 N20 C21 C25 18.0(12) 4_545 . . . ?
N20 C21 C22 C23 -6.0(16) . . . . ?
C25 C21 C22 C23 174.8(11) . . . . ?
C21 C22 C23 C24 2.2(18) . . . . ?
C22 C23 C24 C19 2.8(19) . . . . ?
N20 C19 C24 C23 -4.5(18) . . . . ?
C18 C19 C24 C23 -179.5(11) . . . . ?
N20 C21 C25 N26 -7.4(14) . . . . ?
C22 C21 C25 N26 171.8(9) . . . . ?
N20 C21 C25 C30 171.2(10) . . . . ?
C22 C21 C25 C30 -9.6(16) . . . . ?
C30 C25 N26 C27 1.4(16) . . . . ?
C21 C25 N26 C27 180.0(10) . . . . ?
C30 C25 N26 Ag1 174.3(8) . . . 4_545 ?
C21 C25 N26 Ag1 -7.2(11) . . . 4_545 ?
C25 N26 C27 C28 -0.6(18) . . . . ?
Ag1 N26 C27 C28 -173.2(9) 4_545 . . . ?
C25 N26 C27 C27A 178.4(10) . . . . ?
Ag1 N26 C27 C27A 5.9(15) 4_545 . . . ?
N26 C27 C28 C29 0(2) . . . . ?
C27A C27 C28 C29 -179.4(12) . . . . ?
C27 C28 C29 C30 1(2) . . . . ?
C28 C29 C30 C25 0(2) . . . . ?
N26 C25 C30 C29 -1.1(18) . . . . ?
C21 C25 C30 C29 -179.6(11) . . . . ?
O2A S1A C1A F3A 54.5(11) . . . . ?
O3A S1A C1A F3A -68.3(12) . . . . ?
O1A S1A C1A F3A 176.7(10) . . . . ?
O2A S1A C1A F1A -68.9(12) . . . . ?
O3A S1A C1A F1A 168.4(11) . . . . ?
O1A S1A C1A F1A 53.3(12) . . . . ?
O2A S1A C1A F2A 175.1(10) . . . . ?
O3A S1A C1A F2A 52.3(13) . . . . ?
O1A S1A C1A F2A -62.8(13) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C3 H3 O2A 0.93 2.37 3.289(16) 170.2 2_655
C16 H16 O2A 0.93 2.39 3.207(15) 146.8 5_655
C30 H30 O1A 0.93 2.40 3.162(16) 138.6 4_545

_diffrn_measured_fraction_theta_max 0.880
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.880
_refine_diff_density_max         1.054
_refine_diff_density_min         -1.093
_refine_diff_density_rms         0.131
_database_code_depnum_ccdc_archive 'CCDC 940008'