# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2014

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_NJP21overc120114
_database_code_depnum_ccdc_archive 'CCDC 1024660'
_audit_update_record             
;
2014-12-09 deposited with the CCDC.
2014-12-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C48 H42 Eu2 I6 N2 O16'
_chemical_formula_weight         1968.15

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   8.3983(8)
_cell_length_b                   25.310(3)
_cell_length_c                   14.1228(16)
_cell_angle_alpha                90
_cell_angle_beta                 105.357(2)
_cell_angle_gamma                90
_cell_volume                     2894.8(5)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    8109
_cell_measurement_theta_min      2.20
_cell_measurement_theta_max      32.40

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.258
_exptl_crystal_F_000             1832
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.090
_exptl_crystal_size_mid          0.040
_exptl_crystal_size_min          0.030
_exptl_absorpt_coefficient_mu    5.411
_shelx_estimated_absorpt_T_min   0.642
_shelx_estimated_absorpt_T_max   0.855
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6338
_exptl_absorpt_correction_T_max  0.7465
_exptl_absorpt_process_details   'SADABS SHELXL-97 (Sheldrick, 2001)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            42747
_diffrn_reflns_av_unetI/netI     0.0544
_diffrn_reflns_av_R_equivalents  0.0534
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -38
_diffrn_reflns_limit_k_max       38
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_theta_min         1.609
_diffrn_reflns_theta_max         33.153
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             10938
_reflns_number_gt                8289
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker SMART (Bruker, 2001)'
_computing_cell_refinement       'Bruker SMART (Bruker, 2001)'
_computing_data_reduction        'Bruker SAINT (Bruker, 2001)'
_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 1999)'
_computing_publication_material  'Bruker SHELXTL (Bruker, 2001)'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0161P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         10938
_refine_ls_number_parameters     344
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0560
_refine_ls_R_factor_gt           0.0331
_refine_ls_wR_factor_ref         0.0539
_refine_ls_wR_factor_gt          0.0492
_refine_ls_goodness_of_fit_ref   1.010
_refine_ls_restrained_S_all      1.010
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.87050(2) 0.50966(2) 0.61490(2) 0.00752(3) Uani 1 1 d . . . . .
C1 C 1.1683(3) 0.52796(11) 0.7611(2) 0.0105(5) Uani 1 1 d . . . . .
C2 C 1.3322(3) 0.53591(12) 0.8340(2) 0.0113(5) Uani 1 1 d . . . . .
C3 C 1.3450(4) 0.56394(12) 0.9203(2) 0.0130(6) Uani 1 1 d . . . . .
H3 H 1.2482 0.5771 0.9349 0.016 Uiso 1 1 calc R U . . .
C4 C 1.4978(4) 0.57275(12) 0.9851(2) 0.0162(6) Uani 1 1 d . . . . .
H4 H 1.5061 0.5916 1.0443 0.019 Uiso 1 1 calc R U . . .
C5 C 1.6386(4) 0.55395(13) 0.9631(2) 0.0161(6) Uani 1 1 d . . . . .
C6 C 1.6289(4) 0.52442(13) 0.8793(2) 0.0163(6) Uani 1 1 d . . . . .
H6 H 1.7258 0.5104 0.8662 0.020 Uiso 1 1 calc R U . . .
C7 C 1.4756(3) 0.51565(13) 0.8150(2) 0.0139(6) Uani 1 1 d . . . . .
H7 H 1.4675 0.4956 0.7570 0.017 Uiso 1 1 calc R U . . .
C8 C 0.7021(3) 0.42930(11) 0.6944(2) 0.0113(5) Uani 1 1 d . . . . .
C9 C 0.6231(3) 0.38667(12) 0.7407(2) 0.0125(6) Uani 1 1 d . . . . .
C10 C 0.7034(4) 0.36761(13) 0.8324(2) 0.0168(6) Uani 1 1 d . . . . .
H16 H 0.8103 0.3806 0.8642 0.020 Uiso 1 1 calc R U . . .
C11 C 0.6313(4) 0.32990(13) 0.8791(2) 0.0192(6) Uani 1 1 d . . . . .
H17 H 0.6883 0.3166 0.9418 0.023 Uiso 1 1 calc R U . . .
C12 C 0.4746(4) 0.31204(12) 0.8324(2) 0.0164(6) Uani 1 1 d . . . . .
C13 C 0.3951(4) 0.32943(14) 0.7393(3) 0.0294(9) Uani 1 1 d . . . . .
H20 H 0.2890 0.3160 0.7070 0.035 Uiso 1 1 calc R U . . .
C14 C 0.4694(4) 0.36642(14) 0.6931(3) 0.0244(8) Uani 1 1 d . . . . .
H24 H 0.4151 0.3780 0.6286 0.029 Uiso 1 1 calc R U . . .
C15 C 0.9968(3) 0.59935(12) 0.5087(2) 0.0103(5) Uani 1 1 d . . . . .
C16 C 1.0117(3) 0.65158(11) 0.4613(2) 0.0112(5) Uani 1 1 d . . . . .
C17 C 1.0426(4) 0.65455(12) 0.3699(2) 0.0138(6) Uani 1 1 d . . . . .
H13 H 1.0531 0.6230 0.3355 0.017 Uiso 1 1 calc R U . . .
C18 C 1.0585(4) 0.70336(12) 0.3281(2) 0.0163(6) Uani 1 1 d . . . . .
H21 H 1.0812 0.7053 0.2658 0.020 Uiso 1 1 calc R U . . .
C19 C 1.0408(4) 0.74920(12) 0.3785(2) 0.0143(6) Uani 1 1 d . . . . .
C20 C 1.0080(4) 0.74690(12) 0.4696(2) 0.0153(6) Uani 1 1 d . . . . .
H23 H 0.9957 0.7785 0.5034 0.018 Uiso 1 1 calc R U . . .
C21 C 0.9933(4) 0.69781(12) 0.5110(2) 0.0143(6) Uani 1 1 d . . . . .
H14 H 0.9706 0.6958 0.5734 0.017 Uiso 1 1 calc R U . . .
C22 C 0.6677(4) 0.59735(12) 0.7136(2) 0.0139(6) Uani 1 1 d . . . . .
H15 H 0.7664 0.6013 0.7648 0.017 Uiso 1 1 calc R U . . .
C23 C 0.3910(4) 0.62745(14) 0.6354(3) 0.0219(7) Uani 1 1 d . . . . .
H19A H 0.4015 0.6016 0.5857 0.033 Uiso 1 1 calc R U . . .
H19B H 0.3656 0.6622 0.6047 0.033 Uiso 1 1 calc R U . . .
H19C H 0.3019 0.6166 0.6641 0.033 Uiso 1 1 calc R U . . .
C24 C 0.5543(4) 0.66738(13) 0.7916(3) 0.0225(7) Uani 1 1 d . . . . .
H22A H 0.4767 0.6567 0.8291 0.034 Uiso 1 1 calc R U . . .
H22B H 0.5256 0.7028 0.7646 0.034 Uiso 1 1 calc R U . . .
H22C H 0.6667 0.6677 0.8349 0.034 Uiso 1 1 calc R U . . .
I1 I 1.86856(2) 0.56854(2) 1.06167(2) 0.02255(5) Uani 1 1 d . . . . .
I2 I 0.35559(3) 0.26046(2) 0.90844(2) 0.02795(6) Uani 1 1 d . . . . .
I3 I 1.06398(2) 0.82317(2) 0.31672(2) 0.01870(5) Uani 1 1 d . . . . .
N1 N 0.5450(3) 0.63020(10) 0.7118(2) 0.0163(5) Uani 1 1 d . . . . .
O1 O 1.1619(2) 0.49959(8) 0.68545(15) 0.0128(4) Uani 1 1 d . . . . .
O2 O 1.0403(2) 0.54940(8) 0.77356(15) 0.0119(4) Uani 1 1 d . . . . .
O3 O 0.8402(2) 0.44807(8) 0.74274(15) 0.0123(4) Uani 1 1 d . . . . .
O4 O 0.6338(2) 0.44589(8) 0.60929(15) 0.0140(4) Uani 1 1 d . . . . .
O5 O 1.0410(2) 0.55745(8) 0.47230(15) 0.0134(4) Uani 1 1 d . . . . .
O6 O 0.9410(3) 0.59880(8) 0.58243(15) 0.0142(4) Uani 1 1 d . . . . .
O7 O 0.6627(2) 0.56153(8) 0.65257(16) 0.0146(4) Uani 1 1 d . . . . .
O8 O 0.6892(3) 0.52298(9) 0.45618(16) 0.0143(4) Uani 1 1 d . . . . .
H8A H 0.596(5) 0.5331(14) 0.442(3) 0.019(10) Uiso 1 1 d . . . . .
H8B H 0.724(5) 0.5196(16) 0.412(3) 0.032(12) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O5 2.332(2) 3_766 ?
Eu1 O7 2.355(2) . ?
Eu1 O8 2.377(2) . ?
Eu1 O1 2.399(2) . ?
Eu1 O6 2.407(2) . ?
Eu1 O3 2.449(2) . ?
Eu1 O2 2.525(2) . ?
Eu1 O4 2.545(2) . ?
Eu1 C1 2.828(3) . ?
Eu1 C8 2.870(3) . ?
Eu1 O5 3.016(2) . ?
Eu1 C15 3.061(3) . ?
Eu1 H8B 2.82(4) . ?
C1 O2 1.257(3) . ?
C1 O1 1.277(3) . ?
C1 C2 1.498(4) . ?
C2 C3 1.390(4) . ?
C2 C7 1.399(4) . ?
C3 C4 1.382(4) . ?
C3 H3 0.9500 . ?
C4 C5 1.384(4) . ?
C4 H4 0.9500 . ?
C5 C6 1.384(4) . ?
C5 I1 2.093(3) . ?
C6 C7 1.383(4) . ?
C6 H6 0.9500 . ?
C7 H7 0.9500 . ?
C8 O4 1.259(3) . ?
C8 O3 1.272(3) . ?
C8 C9 1.503(4) . ?
C9 C10 1.380(4) . ?
C9 C14 1.386(4) . ?
C10 C11 1.387(4) . ?
C10 H16 0.9500 . ?
C11 C12 1.382(4) . ?
C11 H17 0.9500 . ?
C12 C13 1.379(5) . ?
C12 I2 2.104(3) . ?
C13 C14 1.381(5) . ?
C13 H20 0.9500 . ?
C14 H24 0.9500 . ?
C15 O6 1.250(3) . ?
C15 O5 1.276(3) . ?
C15 C16 1.502(4) . ?
C16 C17 1.384(4) . ?
C16 C21 1.394(4) . ?
C17 C18 1.391(4) . ?
C17 H13 0.9500 . ?
C18 C19 1.389(4) . ?
C18 H21 0.9500 . ?
C19 C20 1.387(4) . ?
C19 I3 2.096(3) . ?
C20 C21 1.393(4) . ?
C20 H23 0.9500 . ?
C21 H14 0.9500 . ?
C22 O7 1.244(4) . ?
C22 N1 1.319(4) . ?
C22 H15 0.9500 . ?
C23 N1 1.450(4) . ?
C23 H19A 0.9800 . ?
C23 H19B 0.9800 . ?
C23 H19C 0.9800 . ?
C24 N1 1.454(4) . ?
C24 H22A 0.9800 . ?
C24 H22B 0.9800 . ?
C24 H22C 0.9800 . ?
O5 Eu1 2.332(2) 3_766 ?
O8 H8A 0.80(4) . ?
O8 H8B 0.77(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Eu1 O7 152.17(7) 3_766 . ?
O5 Eu1 O8 79.60(8) 3_766 . ?
O7 Eu1 O8 78.81(8) . . ?
O5 Eu1 O1 73.09(7) 3_766 . ?
O7 Eu1 O1 134.51(7) . . ?
O8 Eu1 O1 137.31(7) . . ?
O5 Eu1 O6 116.95(7) 3_766 . ?
O7 Eu1 O6 75.81(7) . . ?
O8 Eu1 O6 79.39(8) . . ?
O1 Eu1 O6 84.45(7) . . ?
O5 Eu1 O3 92.03(7) 3_766 . ?
O7 Eu1 O3 87.74(7) . . ?
O8 Eu1 O3 128.31(7) . . ?
O1 Eu1 O3 85.40(7) . . ?
O6 Eu1 O3 144.67(7) . . ?
O5 Eu1 O2 125.08(7) 3_766 . ?
O7 Eu1 O2 81.70(7) . . ?
O8 Eu1 O2 148.30(7) . . ?
O1 Eu1 O2 53.08(6) . . ?
O6 Eu1 O2 71.70(7) . . ?
O3 Eu1 O2 75.15(7) . . ?
O5 Eu1 O4 82.94(7) 3_766 . ?
O7 Eu1 O4 75.00(7) . . ?
O8 Eu1 O4 76.15(7) . . ?
O1 Eu1 O4 130.38(7) . . ?
O6 Eu1 O4 144.87(7) . . ?
O3 Eu1 O4 52.17(7) . . ?
O2 Eu1 O4 122.22(7) . . ?
O5 Eu1 C1 99.26(8) 3_766 . ?
O7 Eu1 C1 107.99(8) . . ?
O8 Eu1 C1 152.53(8) . . ?
O1 Eu1 C1 26.69(7) . . ?
O6 Eu1 C1 76.77(8) . . ?
O3 Eu1 C1 79.06(7) . . ?
O2 Eu1 C1 26.39(7) . . ?
O4 Eu1 C1 131.21(7) . . ?
O5 Eu1 C8 87.10(8) 3_766 . ?
O7 Eu1 C8 80.52(8) . . ?
O8 Eu1 C8 102.14(8) . . ?
O1 Eu1 C8 108.45(7) . . ?
O6 Eu1 C8 155.53(7) . . ?
O3 Eu1 C8 26.17(7) . . ?
O2 Eu1 C8 98.99(7) . . ?
O4 Eu1 C8 26.00(7) . . ?
C1 Eu1 C8 105.22(8) . . ?
O5 Eu1 O5 70.45(7) 3_766 . ?
O7 Eu1 O5 116.02(6) . . ?
O8 Eu1 O5 67.18(7) . . ?
O1 Eu1 O5 72.99(6) . . ?
O6 Eu1 O5 46.58(6) . . ?
O3 Eu1 O5 155.21(6) . . ?
O2 Eu1 O5 100.16(6) . . ?
O4 Eu1 O5 137.60(6) . . ?
C1 Eu1 O5 86.42(7) . . ?
C8 Eu1 O5 156.29(7) . . ?
O5 Eu1 C15 94.65(8) 3_766 . ?
O7 Eu1 C15 94.07(7) . . ?
O8 Eu1 C15 69.59(8) . . ?
O1 Eu1 C15 80.47(7) . . ?
O6 Eu1 C15 22.64(7) . . ?
O3 Eu1 C15 161.87(7) . . ?
O2 Eu1 C15 87.24(7) . . ?
O4 Eu1 C15 145.49(7) . . ?
C1 Eu1 C15 83.24(8) . . ?
C8 Eu1 C15 171.00(8) . . ?
O5 Eu1 C15 24.22(6) . . ?
O5 Eu1 H8B 68.9(8) 3_766 . ?
O7 Eu1 H8B 91.8(8) . . ?
O8 Eu1 H8B 13.9(8) . . ?
O1 Eu1 H8B 123.6(8) . . ?
O6 Eu1 H8B 77.6(8) . . ?
O3 Eu1 H8B 134.9(8) . . ?
O2 Eu1 H8B 149.3(8) . . ?
O4 Eu1 H8B 84.2(8) . . ?
C1 Eu1 H8B 142.3(8) . . ?
C8 Eu1 H8B 109.6(8) . . ?
O5 Eu1 H8B 55.9(8) . . ?
C15 Eu1 H8B 63.2(8) . . ?
O2 C1 O1 120.8(3) . . ?
O2 C1 C2 120.7(3) . . ?
O1 C1 C2 118.6(2) . . ?
O2 C1 Eu1 63.20(15) . . ?
O1 C1 Eu1 57.56(14) . . ?
C2 C1 Eu1 176.1(2) . . ?
C3 C2 C7 119.0(3) . . ?
C3 C2 C1 121.0(3) . . ?
C7 C2 C1 120.0(3) . . ?
C4 C3 C2 120.3(3) . . ?
C4 C3 H3 119.8 . . ?
C2 C3 H3 119.8 . . ?
C3 C4 C5 119.7(3) . . ?
C3 C4 H4 120.2 . . ?
C5 C4 H4 120.2 . . ?
C6 C5 C4 121.1(3) . . ?
C6 C5 I1 120.0(2) . . ?
C4 C5 I1 118.9(2) . . ?
C7 C6 C5 118.8(3) . . ?
C7 C6 H6 120.6 . . ?
C5 C6 H6 120.6 . . ?
C6 C7 C2 120.9(3) . . ?
C6 C7 H7 119.5 . . ?
C2 C7 H7 119.5 . . ?
O4 C8 O3 120.5(3) . . ?
O4 C8 C9 120.9(3) . . ?
O3 C8 C9 118.6(3) . . ?
O4 C8 Eu1 62.42(15) . . ?
O3 C8 Eu1 58.09(14) . . ?
C9 C8 Eu1 176.6(2) . . ?
C10 C9 C14 119.1(3) . . ?
C10 C9 C8 119.8(3) . . ?
C14 C9 C8 121.1(3) . . ?
C9 C10 C11 121.4(3) . . ?
C9 C10 H16 119.3 . . ?
C11 C10 H16 119.3 . . ?
C12 C11 C10 118.6(3) . . ?
C12 C11 H17 120.7 . . ?
C10 C11 H17 120.7 . . ?
C13 C12 C11 120.7(3) . . ?
C13 C12 I2 120.6(2) . . ?
C11 C12 I2 118.7(2) . . ?
C12 C13 C14 120.1(3) . . ?
C12 C13 H20 120.0 . . ?
C14 C13 H20 120.0 . . ?
C13 C14 C9 120.1(3) . . ?
C13 C14 H24 120.0 . . ?
C9 C14 H24 120.0 . . ?
O6 C15 O5 122.6(3) . . ?
O6 C15 C16 118.4(3) . . ?
O5 C15 C16 119.0(3) . . ?
O6 C15 Eu1 47.81(14) . . ?
O5 C15 Eu1 75.91(16) . . ?
C16 C15 Eu1 162.10(18) . . ?
C17 C16 C21 119.8(3) . . ?
C17 C16 C15 121.4(3) . . ?
C21 C16 C15 118.7(3) . . ?
C16 C17 C18 120.5(3) . . ?
C16 C17 H13 119.8 . . ?
C18 C17 H13 119.8 . . ?
C19 C18 C17 119.3(3) . . ?
C19 C18 H21 120.3 . . ?
C17 C18 H21 120.3 . . ?
C20 C19 C18 120.9(3) . . ?
C20 C19 I3 119.1(2) . . ?
C18 C19 I3 119.9(2) . . ?
C19 C20 C21 119.3(3) . . ?
C19 C20 H23 120.4 . . ?
C21 C20 H23 120.4 . . ?
C20 C21 C16 120.2(3) . . ?
C20 C21 H14 119.9 . . ?
C16 C21 H14 119.9 . . ?
O7 C22 N1 124.3(3) . . ?
O7 C22 H15 117.9 . . ?
N1 C22 H15 117.8 . . ?
N1 C23 H19A 109.5 . . ?
N1 C23 H19B 109.5 . . ?
H19A C23 H19B 109.5 . . ?
N1 C23 H19C 109.5 . . ?
H19A C23 H19C 109.5 . . ?
H19B C23 H19C 109.5 . . ?
N1 C24 H22A 109.5 . . ?
N1 C24 H22B 109.5 . . ?
H22A C24 H22B 109.5 . . ?
N1 C24 H22C 109.5 . . ?
H22A C24 H22C 109.5 . . ?
H22B C24 H22C 109.5 . . ?
C22 N1 C23 121.4(3) . . ?
C22 N1 C24 120.8(3) . . ?
C23 N1 C24 117.5(3) . . ?
C1 O1 Eu1 95.75(16) . . ?
C1 O2 Eu1 90.41(17) . . ?
C8 O3 Eu1 95.73(17) . . ?
C8 O4 Eu1 91.59(17) . . ?
C15 O5 Eu1 170.3(2) . 3_766 ?
C15 O5 Eu1 79.87(16) . . ?
Eu1 O5 Eu1 109.54(7) 3_766 . ?
C15 O6 Eu1 109.55(18) . . ?
C22 O7 Eu1 132.21(19) . . ?
Eu1 O8 H8A 128(3) . . ?
Eu1 O8 H8B 118(3) . . ?
H8A O8 H8B 114(4) . . ?

_refine_diff_density_max         1.229
_refine_diff_density_min         -0.900
_refine_diff_density_rms         0.192

_shelxl_version_number           2013-4




