# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_CCDC
_database_code_depnum_ccdc_archive 'CCDC 1017739'
_audit_update_record             
;
2014-08-03 deposited with the CCDC.
2015-01-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
'C70 H54 Eu3 N6 O34, 2(C2 H3 N), 2(C H4 N0.50), 2(C2 H8 N), 4(H2 O)'
_chemical_formula_sum            'C80 H92 Eu3 N11 O38'
_chemical_formula_weight         2271.53

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P2(1)/n  '
_symmetry_space_group_name_Hall  '-P 2yn'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   15.4724(19)
_cell_length_b                   14.1459(17)
_cell_length_c                   24.040(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.188(2)
_cell_angle_gamma                90.00
_cell_volume                     5261.6(10)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9849
_cell_measurement_theta_min      2.58
_cell_measurement_theta_max      28.00

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.434
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2284
_exptl_absorpt_coefficient_mu    1.848
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7
_exptl_absorpt_correction_T_max  0.8
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Smart Apex CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            42035
_diffrn_reflns_av_R_equivalents  0.0130
_diffrn_reflns_av_sigmaI/netI    0.0707
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_theta_min         1.57
_diffrn_reflns_theta_max         26.00
_reflns_number_total             10337
_reflns_number_gt                7676
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'SMART (Bruker, 2000)'
_computing_cell_refinement       SMART
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_computing_structure_refinement  SHELXTL
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.08P)²+1.88P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10337
_refine_ls_number_parameters     647
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0584
_refine_ls_R_factor_gt           0.0543
_refine_ls_wR_factor_ref         0.1371
_refine_ls_wR_factor_gt          0.1365
_refine_ls_goodness_of_fit_ref   1.001
_refine_ls_restrained_S_all      1.001
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3716(7) 1.0084(6) 0.4250(3) 0.042(2) Uani 1 1 d . . .
C2 C 0.3357(5) 1.0533(6) 0.3730(3) 0.0352(18) Uani 1 1 d . . .
C3 C 0.3685(6) 1.1394(6) 0.3542(4) 0.044(2) Uani 1 1 d . . .
H3 H 0.4125 1.1702 0.3751 0.053 Uiso 1 1 calc R . .
C4 C 0.3398(5) 1.1787(6) 0.3082(4) 0.039(2) Uani 1 1 d . . .
H4 H 0.3624 1.2380 0.2967 0.047 Uiso 1 1 calc R . .
C5 C 0.2754(5) 1.1338(6) 0.2754(4) 0.040(2) Uani 1 1 d . . .
C6 C 0.2425(5) 1.0479(6) 0.2952(3) 0.0344(19) Uani 1 1 d . . .
C7 C 0.2724(5) 1.0043(6) 0.3439(3) 0.0356(19) Uani 1 1 d . . .
H7 H 0.2507 0.9451 0.3562 0.043 Uiso 1 1 calc R . .
C8 C 0.0740(6) 1.1751(7) 0.0778(3) 0.040(2) Uani 1 1 d . . .
C9 C 0.1308(5) 1.1653(6) 0.1277(3) 0.0320(18) Uani 1 1 d . . .
C10 C 0.1891(6) 1.2337(6) 0.1413(3) 0.043(2) Uani 1 1 d . . .
H10 H 0.1942 1.2866 0.1172 0.052 Uiso 1 1 calc R . .
C11 C 0.2435(6) 1.2306(6) 0.1899(3) 0.045(2) Uani 1 1 d . . .
H11 H 0.2854 1.2777 0.1979 0.054 Uiso 1 1 calc R . .
C12 C 0.2303(5) 1.1572(6) 0.2221(3) 0.0363(19) Uani 1 1 d . . .
C13 C 0.1724(6) 1.0846(6) 0.2095(3) 0.037(2) Uani 1 1 d . . .
C14 C 0.1214(6) 1.0872(6) 0.1646(3) 0.041(2) Uani 1 1 d . . .
H14 H 0.0803 1.0387 0.1575 0.049 Uiso 1 1 calc R . .
C15 C 0.1761(6) 1.0026(5) 0.2551(3) 0.036(2) Uani 1 1 d . . .
C16 C 0.0908(6) 0.9982(7) 0.2826(4) 0.047(2) Uani 1 1 d . . .
H16D H 0.0966 1.0189 0.3214 0.071 Uiso 1 1 calc R . .
H16E H 0.0692 0.9331 0.2817 0.071 Uiso 1 1 calc R . .
H16F H 0.0501 1.0397 0.2631 0.071 Uiso 1 1 calc R . .
C17 C 0.4643(5) 0.6819(6) 0.5915(3) 0.0338(19) Uani 1 1 d . . .
C18 C 0.4165(5) 0.6868(6) 0.6448(3) 0.0341(19) Uani 1 1 d . . .
C19 C 0.3951(5) 0.7711(6) 0.6683(3) 0.041(2) Uani 1 1 d . . .
H19 H 0.4116 0.8279 0.6501 0.050 Uiso 1 1 calc R . .
C20 C 0.3499(6) 0.7766(6) 0.7179(3) 0.040(2) Uani 1 1 d . . .
H20 H 0.3431 0.8357 0.7361 0.048 Uiso 1 1 calc R . .
C21 C 0.3158(5) 0.6976(6) 0.7402(3) 0.0365(18) Uani 1 1 d . . .
C22 C 0.3415(5) 0.6072(6) 0.7182(3) 0.0336(19) Uani 1 1 d . . .
C23 C 0.3896(5) 0.6044(6) 0.6712(3) 0.0330(19) Uani 1 1 d . . .
H23 H 0.4053 0.5449 0.6559 0.040 Uiso 1 1 calc R . .
C24 C 0.1057(6) 0.5725(6) 0.9193(3) 0.0362(19) Uani 1 1 d . . .
C25 C 0.1615(5) 0.6081(6) 0.8727(3) 0.0326(18) Uani 1 1 d . . .
C26 C 0.1672(6) 0.7068(6) 0.8655(4) 0.047(2) Uani 1 1 d . . .
H26 H 0.1356 0.7483 0.8889 0.056 Uiso 1 1 calc R . .
C27 C 0.2199(6) 0.7428(6) 0.8236(3) 0.0374(19) Uani 1 1 d . . .
H27 H 0.2246 0.8090 0.8179 0.045 Uiso 1 1 calc R . .
C28 C 0.2656(5) 0.6795(6) 0.7898(3) 0.0332(19) Uani 1 1 d . . .
C29 C 0.2536(5) 0.5837(6) 0.7948(3) 0.0346(19) Uani 1 1 d . . .
C30 C 0.2022(5) 0.5483(6) 0.8387(3) 0.0360(18) Uani 1 1 d . . .
H30 H 0.1967 0.4820 0.8440 0.043 Uiso 1 1 calc R . .
C31 C 0.2973(6) 0.5304(6) 0.7516(3) 0.037(2) Uani 1 1 d . . .
C32 C 0.3636(6) 0.4543(7) 0.7700(3) 0.047(2) Uani 1 1 d . . .
H32A H 0.3329 0.3998 0.7854 0.070 Uiso 1 1 calc R . .
H32B H 0.4022 0.4809 0.7983 0.070 Uiso 1 1 calc R . .
H32C H 0.3976 0.4342 0.7378 0.070 Uiso 1 1 calc R . .
C33 C 0.7000(6) 0.6749(8) 0.5632(4) 0.057(3) Uani 1 1 d . . .
H33 H 0.7002 0.6706 0.6026 0.068 Uiso 1 1 calc R . .
C34 C 0.7735(8) 0.7086(7) 0.4818(4) 0.064(3) Uani 1 1 d . . .
H34A H 0.8025 0.6474 0.4859 0.076 Uiso 1 1 calc R . .
H34C H 0.8139 0.7546 0.4660 0.076 Uiso 1 1 calc R . .
H34B H 0.7235 0.7017 0.4570 0.076 Uiso 1 1 calc R . .
C35 C 0.7803(6) 0.8321(6) 0.5606(4) 0.052(2) Uani 1 1 d . . .
H35A H 0.7362 0.8816 0.5584 0.078 Uiso 1 1 calc R . .
H35B H 0.8317 0.8520 0.5398 0.078 Uiso 1 1 calc R . .
H35C H 0.7960 0.8212 0.5996 0.078 Uiso 1 1 calc R . .
C36 C 0.3935(6) 0.8135(6) 0.1290(4) 0.053(2) Uani 1 1 d . . .
C37 C 0.4691(6) 0.7854(7) 0.0997(4) 0.053(2) Uani 1 1 d . . .
H82B H 0.4940 0.7292 0.1174 0.063 Uiso 1 1 calc R . .
H82C H 0.5115 0.8368 0.1005 0.063 Uiso 1 1 calc R . .
H82A H 0.4540 0.7707 0.0610 0.063 Uiso 1 1 calc R . .
C38 C 0.9287(10) 0.5292(12) 0.4599(6) 0.041(4) Uani 0.50 1 d P . .
H39A H 0.9697 0.4781 0.4523 0.061 Uiso 0.50 1 calc PR . .
H39B H 0.8755 0.5025 0.4755 0.061 Uiso 0.50 1 calc PR . .
H39C H 0.9543 0.5734 0.4867 0.061 Uiso 0.50 1 calc PR . .
C39 C 0.9637(13) 0.6758(13) 0.4111(14) 0.096(10) Uani 0.50 1 d P . .
H38A H 0.9800 0.6861 0.4501 0.144 Uiso 0.50 1 calc PR . .
H38B H 0.9294 0.7296 0.3978 0.144 Uiso 0.50 1 calc PR . .
H38C H 1.0159 0.6697 0.3885 0.144 Uiso 0.50 1 calc PR . .
C40 C 0.4995(6) 0.7374(6) 0.2519(4) 0.052(2) Uani 1 1 d . . .
H36 H 0.5163 0.7437 0.2128 0.077 Uiso 1 1 calc R . .
H36B H 0.4495 0.6953 0.2548 0.077 Uiso 1 1 calc R . .
H36C H 0.5479 0.7110 0.2733 0.077 Uiso 1 1 calc R . .
C41 C 0.5415(6) 0.9042(7) 0.2638(4) 0.056(3) Uani 1 1 d . . .
H37A H 0.5899 0.8962 0.2898 0.084 Uiso 1 1 calc R . .
H37B H 0.5161 0.9671 0.2689 0.084 Uiso 1 1 calc R . .
H37C H 0.5623 0.8978 0.2256 0.084 Uiso 1 1 calc R . .
Eu1 Eu 0.44398(3) 0.87368(3) 0.508454(17) 0.03693(13) Uani 1 1 d . . .
Eu2 Eu 0.5000 0.5000 0.5000 0.04369(16) Uani 1 2 d S . .
N1 N 0.2931(4) 0.5067(6) 0.5532(3) 0.0437(18) Uani 1 1 d . . .
N2 N 0.2564(5) 0.7509(6) 0.5225(3) 0.050(2) Uani 1 1 d . . .
N3 N 0.7450(4) 0.7412(6) 0.5355(3) 0.051(2) Uani 1 1 d . . .
N4 N 0.3293(6) 0.8373(7) 0.1516(4) 0.070(3) Uani 1 1 d . . .
N5 N 0.9077(11) 0.5813(10) 0.4061(8) 0.080(6) Uani 0.50 1 d P . .
H5A H 0.8496 0.5948 0.4036 0.096 Uiso 0.50 1 calc PR . .
H5B H 0.9238 0.5464 0.3756 0.096 Uiso 0.50 1 calc PR . .
N6 N 0.4766(5) 0.8327(5) 0.2747(3) 0.048(2) Uani 1 1 d . . .
H4A H 0.4250 0.8519 0.2592 0.057 Uiso 1 1 calc R . .
H4B H 0.4688 0.8278 0.3125 0.057 Uiso 1 1 calc R . .
O1 O 0.3390(4) 0.9320(4) 0.4436(2) 0.0373(13) Uani 1 1 d . . .
O2 O 0.4374(4) 1.0420(4) 0.4512(2) 0.0395(13) Uani 1 1 d . . .
O3 O 0.0857(3) 1.2434(4) 0.0468(2) 0.0419(14) Uani 1 1 d . . .
O4 O 0.0225(5) 1.1122(5) 0.0657(2) 0.0470(17) Uani 1 1 d . . .
O5 O 0.2027(4) 0.9217(4) 0.2327(2) 0.0411(14) Uani 1 1 d . . .
H5F H 0.2642 0.9111 0.2250 0.049 Uiso 1 1 d R . .
O6 O 0.4891(3) 0.7576(4) 0.5700(2) 0.0352(12) Uani 1 1 d . . .
O7 O 0.4768(4) 0.6025(4) 0.5685(2) 0.0302(13) Uani 1 1 d . . .
O8 O 0.0502(4) 0.6278(4) 0.9401(2) 0.0401(13) Uani 1 1 d . . .
O9 O 0.1165(4) 0.4848(4) 0.9317(2) 0.0341(13) Uani 1 1 d . . .
O10 O 0.2364(4) 0.4905(4) 0.7174(2) 0.0403(14) Uani 1 1 d . . .
H10B H 0.2626 0.4579 0.6868 0.048 Uiso 1 1 d R . .
O11 O 0.3032(4) 0.4178(5) 0.5485(2) 0.0425(14) Uani 1 1 d . . .
O12 O 0.3169(4) 0.5596(4) 0.5172(2) 0.0458(14) Uani 1 1 d . . .
O13 O 0.2527(3) 0.5379(4) 0.5991(2) 0.0417(14) Uani 1 1 d . . .
O14 O 0.3072(3) 0.8087(4) 0.5420(2) 0.0344(13) Uani 1 1 d . . .
O15 O 0.2034(4) 0.7143(4) 0.5553(2) 0.0475(15) Uani 1 1 d . . .
O16 O 0.6537(4) 0.6140(4) 0.5302(2) 0.0415(14) Uani 1 1 d . . .
O17 O 0.2532(4) 0.7335(4) 0.4729(2) 0.0411(15) Uani 1 1 d . . .
O1W O 0.2055(11) 0.6155(10) 0.4602(7) 0.054(5) Uani 0.40 1 d P . .
H1X H 0.1692 0.6603 0.4572 0.065 Uiso 0.40 1 d PR . .
H1Y H 0.2204 0.6094 0.4941 0.065 Uiso 0.40 1 d PR . .
O2W O 0.8648(11) 0.8827(10) 0.4485(6) 0.048(4) Uani 0.40 1 d P . .
H2X H 0.9160 0.8643 0.4416 0.058 Uiso 0.40 1 d PR . .
H2Y H 0.8657 0.9408 0.4577 0.058 Uiso 0.40 1 d PR . .
O3W O -0.0026(9) 0.9018(12) 0.5623(6) 0.052(4) Uani 0.40 1 d P . .
H3X H 0.0014 0.9562 0.5771 0.063 Uiso 0.40 1 d PR . .
H3Y H 0.0167 0.9040 0.5293 0.063 Uiso 0.40 1 d PR . .
O4W O 0.9210(11) 0.3680(13) 0.6812(7) 0.066(5) Uani 0.40 1 d P . .
H4X H 0.8994 0.4232 0.6817 0.079 Uiso 0.40 1 d PR . .
H4Y H 0.8876 0.3310 0.6635 0.079 Uiso 0.40 1 d PR . .
O5W O 0.9910(12) 0.1439(13) 0.5592(8) 0.077(6) Uani 0.40 1 d P . .
H5X H 0.9751 0.0899 0.5707 0.093 Uiso 0.40 1 d PR . .
H5Y H 0.9823 0.1478 0.5243 0.093 Uiso 0.40 1 d PR . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O1 1.274(9) . ?
C1 O2 1.286(11) . ?
C1 C2 1.506(11) . ?
C1 Eu1 2.983(9) . ?
C2 C7 1.388(12) . ?
C2 C3 1.395(11) . ?
C3 C4 1.316(12) . ?
C3 H3 0.9500 . ?
C4 C5 1.418(12) . ?
C4 H4 0.9500 . ?
C5 C6 1.400(11) . ?
C5 C12 1.495(12) . ?
C6 C7 1.401(10) . ?
C6 C15 1.545(11) . ?
C7 H7 0.9500 . ?
C8 O4 1.228(10) . ?
C8 O3 1.233(10) . ?
C8 C9 1.492(11) . ?
C9 C10 1.362(11) . ?
C9 C14 1.425(12) . ?
C10 C11 1.437(12) . ?
C10 H10 0.9500 . ?
C11 C12 1.312(12) . ?
C11 H11 0.9500 . ?
C12 C13 1.395(12) . ?
C13 C14 1.336(11) . ?
C13 C15 1.596(11) . ?
C14 H14 0.9500 . ?
C15 O5 1.330(9) . ?
C15 C16 1.481(12) . ?
C16 H16D 0.9800 . ?
C16 H16E 0.9800 . ?
C16 H16F 0.9800 . ?
C17 O6 1.250(9) . ?
C17 O7 1.267(9) . ?
C17 C18 1.482(10) . ?
C18 C19 1.361(11) . ?
C18 C23 1.391(11) . ?
C19 C20 1.386(11) . ?
C19 H19 0.9500 . ?
C20 C21 1.348(11) . ?
C20 H20 0.9500 . ?
C21 C22 1.441(11) . ?
C21 C28 1.448(10) . ?
C22 C23 1.356(10) . ?
C22 C31 1.514(11) . ?
C23 H23 0.9500 . ?
C24 O8 1.266(10) . ?
C24 O9 1.286(9) . ?
C24 C25 1.504(10) . ?
C25 C30 1.335(10) . ?
C25 C26 1.410(11) . ?
C26 C27 1.394(12) . ?
C26 H26 0.9500 . ?
C27 C28 1.401(11) . ?
C27 H27 0.9500 . ?
C28 C29 1.373(12) . ?
C29 C30 1.415(11) . ?
C29 C31 1.452(10) . ?
C30 H30 0.9500 . ?
C31 O10 1.370(10) . ?
C31 C32 1.551(12) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 N3 1.345(12) . ?
C33 O16 1.371(10) . ?
C33 H33 0.9500 . ?
C34 N3 1.442(11) . ?
C34 H34A 0.9800 . ?
C34 H34C 0.9800 . ?
C34 H34B 0.9800 . ?
C35 N3 1.521(11) . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 N4 1.183(12) . ?
C36 C37 1.425(12) . ?
C37 H82B 0.9800 . ?
C37 H82C 0.9800 . ?
C37 H82A 0.9800 . ?
C38 N5 1.52(2) . ?
C38 H39A 0.9800 . ?
C38 H39B 0.9800 . ?
C38 H39C 0.9800 . ?
C39 N5 1.60(2) . ?
C39 H38A 0.9800 . ?
C39 H38B 0.9800 . ?
C39 H38C 0.9800 . ?
C40 N6 1.498(11) . ?
C40 H36 0.9800 . ?
C40 H36B 0.9800 . ?
C40 H36C 0.9800 . ?
C41 N6 1.449(12) . ?
C41 H37A 0.9800 . ?
C41 H37B 0.9800 . ?
C41 H37C 0.9800 . ?
Eu1 O6 2.317(6) . ?
Eu1 O3 2.317(6) 2_545 ?
Eu1 O8 2.328(6) 4_675 ?
Eu1 O9 2.329(5) 2_556 ?
Eu1 O2 2.392(6) 3_676 ?
Eu1 O1 2.394(6) . ?
Eu1 O14 2.447(5) . ?
Eu1 O2 2.752(6) . ?
Eu1 Eu1 3.9933(9) 3_676 ?
Eu2 O7 2.224(5) 3_666 ?
Eu2 O7 2.225(5) . ?
Eu2 O4 2.265(6) 4_676 ?
Eu2 O4 2.265(6) 2_545 ?
Eu2 O16 2.962(6) 3_666 ?
Eu2 O16 2.962(6) . ?
Eu2 O12 2.986(6) . ?
Eu2 O12 2.986(6) 3_666 ?
N1 O12 1.203(8) . ?
N1 O11 1.272(9) . ?
N1 O13 1.344(8) . ?
N2 O17 1.220(8) . ?
N2 O14 1.225(9) . ?
N2 O15 1.250(9) . ?
N5 H5A 0.9200 . ?
N5 H5B 0.9200 . ?
N6 H4A 0.9200 . ?
N6 H4B 0.9200 . ?
O2 Eu1 2.392(6) 3_676 ?
O3 Eu1 2.317(6) 2 ?
O4 Eu2 2.265(6) 2 ?
O5 H5F 0.9799 . ?
O8 Eu1 2.328(6) 4_576 ?
O9 Eu1 2.329(5) 2_546 ?
O10 H10B 0.9599 . ?
O1W H1X 0.8500 . ?
O1W H1Y 0.8499 . ?
O2W H2X 0.8499 . ?
O2W H2Y 0.8501 . ?
O3W H3X 0.8500 . ?
O3W H3Y 0.8499 . ?
O4W H4X 0.8500 . ?
O4W H4Y 0.8500 . ?
O5W H5X 0.8500 . ?
O5W H5Y 0.8501 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C1 O2 117.1(8) . . ?
O1 C1 C2 120.2(8) . . ?
O2 C1 C2 122.6(8) . . ?
O1 C1 Eu1 51.0(4) . . ?
O2 C1 Eu1 67.2(5) . . ?
C2 C1 Eu1 164.6(6) . . ?
C7 C2 C3 122.0(8) . . ?
C7 C2 C1 117.8(7) . . ?
C3 C2 C1 120.2(8) . . ?
C4 C3 C2 121.3(9) . . ?
C4 C3 H3 119.4 . . ?
C2 C3 H3 119.4 . . ?
C3 C4 C5 120.9(8) . . ?
C3 C4 H4 119.6 . . ?
C5 C4 H4 119.6 . . ?
C6 C5 C4 117.1(8) . . ?
C6 C5 C12 108.3(7) . . ?
C4 C5 C12 134.6(8) . . ?
C5 C6 C7 123.1(8) . . ?
C5 C6 C15 112.9(7) . . ?
C7 C6 C15 123.7(8) . . ?
C2 C7 C6 115.6(8) . . ?
C2 C7 H7 122.2 . . ?
C6 C7 H7 122.2 . . ?
O4 C8 O3 121.5(8) . . ?
O4 C8 C9 120.1(8) . . ?
O3 C8 C9 118.1(9) . . ?
C10 C9 C14 118.0(7) . . ?
C10 C9 C8 121.0(8) . . ?
C14 C9 C8 120.8(8) . . ?
C9 C10 C11 124.0(8) . . ?
C9 C10 H10 118.0 . . ?
C11 C10 H10 118.0 . . ?
C12 C11 C10 114.3(9) . . ?
C12 C11 H11 122.8 . . ?
C10 C11 H11 122.8 . . ?
C11 C12 C13 123.8(8) . . ?
C11 C12 C5 127.5(8) . . ?
C13 C12 C5 108.6(7) . . ?
C14 C13 C12 122.1(8) . . ?
C14 C13 C15 126.5(8) . . ?
C12 C13 C15 111.4(7) . . ?
C13 C14 C9 117.6(9) . . ?
C13 C14 H14 121.2 . . ?
C9 C14 H14 121.2 . . ?
O5 C15 C16 115.0(7) . . ?
O5 C15 C6 113.8(7) . . ?
C16 C15 C6 109.3(6) . . ?
O5 C15 C13 110.9(7) . . ?
C16 C15 C13 107.9(7) . . ?
C6 C15 C13 98.6(6) . . ?
C15 C16 H16D 109.5 . . ?
C15 C16 H16E 109.5 . . ?
H16D C16 H16E 109.5 . . ?
C15 C16 H16F 109.5 . . ?
H16D C16 H16F 109.5 . . ?
H16E C16 H16F 109.5 . . ?
O6 C17 O7 122.1(7) . . ?
O6 C17 C18 118.2(7) . . ?
O7 C17 C18 119.7(7) . . ?
C19 C18 C23 118.1(7) . . ?
C19 C18 C17 121.5(8) . . ?
C23 C18 C17 120.4(7) . . ?
C18 C19 C20 122.1(8) . . ?
C18 C19 H19 119.0 . . ?
C20 C19 H19 119.0 . . ?
C21 C20 C19 119.6(8) . . ?
C21 C20 H20 120.2 . . ?
C19 C20 H20 120.2 . . ?
C20 C21 C22 118.8(7) . . ?
C20 C21 C28 133.3(8) . . ?
C22 C21 C28 107.2(7) . . ?
C23 C22 C21 119.0(7) . . ?
C23 C22 C31 132.2(7) . . ?
C21 C22 C31 108.4(6) . . ?
C22 C23 C18 121.5(7) . . ?
C22 C23 H23 119.3 . . ?
C18 C23 H23 119.3 . . ?
O8 C24 O9 126.4(7) . . ?
O8 C24 C25 118.6(7) . . ?
O9 C24 C25 114.9(7) . . ?
C30 C25 C26 121.4(7) . . ?
C30 C25 C24 121.2(7) . . ?
C26 C25 C24 117.4(7) . . ?
C27 C26 C25 119.2(7) . . ?
C27 C26 H26 120.4 . . ?
C25 C26 H26 120.4 . . ?
C26 C27 C28 118.8(7) . . ?
C26 C27 H27 120.6 . . ?
C28 C27 H27 120.6 . . ?
C29 C28 C27 120.7(7) . . ?
C29 C28 C21 108.6(7) . . ?
C27 C28 C21 129.6(8) . . ?
C28 C29 C30 119.4(7) . . ?
C28 C29 C31 112.7(7) . . ?
C30 C29 C31 127.9(8) . . ?
C25 C30 C29 120.0(8) . . ?
C25 C30 H30 120.0 . . ?
C29 C30 H30 120.0 . . ?
O10 C31 C29 108.7(7) . . ?
O10 C31 C22 106.8(7) . . ?
C29 C31 C22 102.7(7) . . ?
O10 C31 C32 109.8(7) . . ?
C29 C31 C32 117.7(7) . . ?
C22 C31 C32 110.4(7) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
N3 C33 O16 115.0(8) . . ?
N3 C33 H33 122.5 . . ?
O16 C33 H33 122.5 . . ?
N3 C34 H34A 109.5 . . ?
N3 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
N3 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
H34C C34 H34B 109.5 . . ?
N3 C35 H35A 109.5 . . ?
N3 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
N3 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
N4 C36 C37 177.7(11) . . ?
C36 C37 H82B 109.5 . . ?
C36 C37 H82C 109.5 . . ?
H82B C37 H82C 109.5 . . ?
C36 C37 H82A 109.5 . . ?
H82B C37 H82A 109.5 . . ?
H82C C37 H82A 109.5 . . ?
N5 C38 H39A 109.5 . . ?
N5 C38 H39B 109.5 . . ?
H39A C38 H39B 109.5 . . ?
N5 C38 H39C 109.5 . . ?
H39A C38 H39C 109.5 . . ?
H39B C38 H39C 109.5 . . ?
N5 C39 H38A 109.5 . . ?
N5 C39 H38B 109.5 . . ?
H38A C39 H38B 109.5 . . ?
N5 C39 H38C 109.5 . . ?
H38A C39 H38C 109.5 . . ?
H38B C39 H38C 109.5 . . ?
N6 C40 H36 109.5 . . ?
N6 C40 H36B 109.5 . . ?
H36 C40 H36B 109.5 . . ?
N6 C40 H36C 109.5 . . ?
H36 C40 H36C 109.5 . . ?
H36B C40 H36C 109.5 . . ?
N6 C41 H37A 109.5 . . ?
N6 C41 H37B 109.5 . . ?
H37A C41 H37B 109.5 . . ?
N6 C41 H37C 109.5 . . ?
H37A C41 H37C 109.5 . . ?
H37B C41 H37C 109.5 . . ?
O6 Eu1 O3 82.03(18) . 2_545 ?
O6 Eu1 O8 103.45(17) . 4_675 ?
O3 Eu1 O8 74.16(19) 2_545 4_675 ?
O6 Eu1 O9 101.77(16) . 2_556 ?
O3 Eu1 O9 144.3(2) 2_545 2_556 ?
O8 Eu1 O9 136.73(18) 4_675 2_556 ?
O6 Eu1 O2 82.23(19) . 3_676 ?
O3 Eu1 O2 141.22(18) 2_545 3_676 ?
O8 Eu1 O2 75.43(19) 4_675 3_676 ?
O9 Eu1 O2 73.85(19) 2_556 3_676 ?
O6 Eu1 O1 149.61(19) . . ?
O3 Eu1 O1 76.57(19) 2_545 . ?
O8 Eu1 O1 91.27(19) 4_675 . ?
O9 Eu1 O1 84.12(18) 2_556 . ?
O2 Eu1 O1 127.6(2) 3_676 . ?
O6 Eu1 O14 77.45(18) . . ?
O3 Eu1 O14 73.72(18) 2_545 . ?
O8 Eu1 O14 147.40(19) 4_675 . ?
O9 Eu1 O14 72.59(18) 2_556 . ?
O2 Eu1 O14 135.84(17) 3_676 . ?
O1 Eu1 O14 76.00(18) . . ?
O6 Eu1 O2 160.62(18) . . ?
O3 Eu1 O2 113.22(18) 2_545 . ?
O8 Eu1 O2 71.32(17) 4_675 . ?
O9 Eu1 O2 73.22(16) 2_556 . ?
O2 Eu1 O2 78.4(2) 3_676 . ?
O1 Eu1 O2 49.63(18) . . ?
O14 Eu1 O2 117.34(17) . . ?
O6 Eu1 C1 173.9(2) . . ?
O3 Eu1 C1 92.8(2) 2_545 . ?
O8 Eu1 C1 78.2(2) 4_675 . ?
O9 Eu1 C1 80.45(19) 2_556 . ?
O2 Eu1 C1 103.9(2) 3_676 . ?
O1 Eu1 C1 24.4(2) . . ?
O14 Eu1 C1 97.9(2) . . ?
O2 Eu1 C1 25.5(2) . . ?
O6 Eu1 Eu1 124.69(13) . 3_676 ?
O3 Eu1 Eu1 137.62(13) 2_545 3_676 ?
O8 Eu1 Eu1 68.19(13) 4_675 3_676 ?
O9 Eu1 Eu1 68.55(13) 2_556 3_676 ?
O2 Eu1 Eu1 42.47(14) 3_676 3_676 ?
O1 Eu1 Eu1 85.37(13) . 3_676 ?
O14 Eu1 Eu1 138.27(13) . 3_676 ?
O2 Eu1 Eu1 35.93(12) . 3_676 ?
C1 Eu1 Eu1 61.44(18) . 3_676 ?
O7 Eu2 O7 180.000(1) 3_666 . ?
O7 Eu2 O4 92.02(19) 3_666 4_676 ?
O7 Eu2 O4 87.98(19) . 4_676 ?
O7 Eu2 O4 87.98(19) 3_666 2_545 ?
O7 Eu2 O4 92.02(19) . 2_545 ?
O4 Eu2 O4 180.0(2) 4_676 2_545 ?
O7 Eu2 O16 66.10(18) 3_666 3_666 ?
O7 Eu2 O16 113.90(18) . 3_666 ?
O4 Eu2 O16 84.93(19) 4_676 3_666 ?
O4 Eu2 O16 95.07(19) 2_545 3_666 ?
O7 Eu2 O16 113.90(18) 3_666 . ?
O7 Eu2 O16 66.10(18) . . ?
O4 Eu2 O16 95.07(19) 4_676 . ?
O4 Eu2 O16 84.93(19) 2_545 . ?
O16 Eu2 O16 180.0 3_666 . ?
O7 Eu2 O12 116.22(18) 3_666 . ?
O7 Eu2 O12 63.78(18) . . ?
O4 Eu2 O12 104.2(2) 4_676 . ?
O4 Eu2 O12 75.8(2) 2_545 . ?
O16 Eu2 O12 54.97(17) 3_666 . ?
O16 Eu2 O12 125.03(17) . . ?
O7 Eu2 O12 63.78(18) 3_666 3_666 ?
O7 Eu2 O12 116.22(18) . 3_666 ?
O4 Eu2 O12 75.8(2) 4_676 3_666 ?
O4 Eu2 O12 104.2(2) 2_545 3_666 ?
O16 Eu2 O12 125.03(17) 3_666 3_666 ?
O16 Eu2 O12 54.97(17) . 3_666 ?
O12 Eu2 O12 179.999(1) . 3_666 ?
O12 N1 O11 120.8(7) . . ?
O12 N1 O13 122.1(7) . . ?
O11 N1 O13 117.1(6) . . ?
O17 N2 O14 122.1(7) . . ?
O17 N2 O15 120.5(8) . . ?
O14 N2 O15 117.2(8) . . ?
C33 N3 C34 112.4(8) . . ?
C33 N3 C35 125.5(7) . . ?
C34 N3 C35 120.9(8) . . ?
C38 N5 C39 103.2(19) . . ?
C38 N5 H5A 111.1 . . ?
C39 N5 H5A 111.1 . . ?
C38 N5 H5B 111.1 . . ?
C39 N5 H5B 111.1 . . ?
H5A N5 H5B 109.1 . . ?
C41 N6 C40 113.4(7) . . ?
C41 N6 H4A 108.9 . . ?
C40 N6 H4A 108.9 . . ?
C41 N6 H4B 108.9 . . ?
C40 N6 H4B 108.9 . . ?
H4A N6 H4B 107.7 . . ?
C1 O1 Eu1 104.6(5) . . ?
C1 O2 Eu1 171.1(6) . 3_676 ?
C1 O2 Eu1 87.3(5) . . ?
Eu1 O2 Eu1 101.6(2) 3_676 . ?
C8 O3 Eu1 160.0(6) . 2 ?
C8 O4 Eu2 140.4(6) . 2 ?
C15 O5 H5F 120.6 . . ?
C17 O6 Eu1 141.2(5) . . ?
C17 O7 Eu2 157.9(5) . . ?
C24 O8 Eu1 139.0(5) . 4_576 ?
C24 O9 Eu1 137.8(5) . 2_546 ?
C31 O10 H10B 111.4 . . ?
N1 O12 Eu2 102.5(4) . . ?
N2 O14 Eu1 132.8(5) . . ?
C33 O16 Eu2 154.3(5) . . ?
H1X O1W H1Y 109.5 . . ?
H2X O2W H2Y 109.5 . . ?
H3X O3W H3Y 109.5 . . ?
H4X O4W H4Y 109.5 . . ?
H5X O5W H5Y 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 C2 C7 -5.9(12) . . . . ?
O2 C1 C2 C7 171.3(7) . . . . ?
Eu1 C1 C2 C7 45(3) . . . . ?
O1 C1 C2 C3 176.8(8) . . . . ?
O2 C1 C2 C3 -6.0(12) . . . . ?
Eu1 C1 C2 C3 -132(2) . . . . ?
C7 C2 C3 C4 1.0(13) . . . . ?
C1 C2 C3 C4 178.2(8) . . . . ?
C2 C3 C4 C5 -1.2(13) . . . . ?
C3 C4 C5 C6 1.8(12) . . . . ?
C3 C4 C5 C12 -179.1(9) . . . . ?
C4 C5 C6 C7 -2.3(12) . . . . ?
C12 C5 C6 C7 178.4(8) . . . . ?
C4 C5 C6 C15 -177.2(7) . . . . ?
C12 C5 C6 C15 3.5(10) . . . . ?
C3 C2 C7 C6 -1.3(11) . . . . ?
C1 C2 C7 C6 -178.6(7) . . . . ?
C5 C6 C7 C2 2.0(12) . . . . ?
C15 C6 C7 C2 176.3(7) . . . . ?
O4 C8 C9 C10 179.0(8) . . . . ?
O3 C8 C9 C10 5.3(11) . . . . ?
O4 C8 C9 C14 -5.3(12) . . . . ?
O3 C8 C9 C14 -179.0(7) . . . . ?
C14 C9 C10 C11 1.7(12) . . . . ?
C8 C9 C10 C11 177.5(7) . . . . ?
C9 C10 C11 C12 -2.5(12) . . . . ?
C10 C11 C12 C13 3.7(13) . . . . ?
C10 C11 C12 C5 -179.6(8) . . . . ?
C6 C5 C12 C11 -178.6(9) . . . . ?
C4 C5 C12 C11 2.3(16) . . . . ?
C6 C5 C12 C13 -1.4(10) . . . . ?
C4 C5 C12 C13 179.4(9) . . . . ?
C11 C12 C13 C14 -4.3(14) . . . . ?
C5 C12 C13 C14 178.5(8) . . . . ?
C11 C12 C13 C15 176.1(8) . . . . ?
C5 C12 C13 C15 -1.1(9) . . . . ?
C12 C13 C14 C9 3.1(13) . . . . ?
C15 C13 C14 C9 -177.4(8) . . . . ?
C10 C9 C14 C13 -1.9(12) . . . . ?
C8 C9 C14 C13 -177.8(8) . . . . ?
C5 C6 C15 O5 113.6(8) . . . . ?
C7 C6 C15 O5 -61.2(11) . . . . ?
C5 C6 C15 C16 -116.3(9) . . . . ?
C7 C6 C15 C16 68.8(10) . . . . ?
C5 C6 C15 C13 -3.8(9) . . . . ?
C7 C6 C15 C13 -178.7(8) . . . . ?
C14 C13 C15 O5 63.7(11) . . . . ?
C12 C13 C15 O5 -116.8(8) . . . . ?
C14 C13 C15 C16 -63.1(11) . . . . ?
C12 C13 C15 C16 116.4(8) . . . . ?
C14 C13 C15 C6 -176.7(9) . . . . ?
C12 C13 C15 C6 2.9(9) . . . . ?
O6 C17 C18 C19 4.0(11) . . . . ?
O7 C17 C18 C19 -174.1(7) . . . . ?
O6 C17 C18 C23 -178.2(7) . . . . ?
O7 C17 C18 C23 3.7(11) . . . . ?
C23 C18 C19 C20 1.8(12) . . . . ?
C17 C18 C19 C20 179.7(7) . . . . ?
C18 C19 C20 C21 -9.1(13) . . . . ?
C19 C20 C21 C22 12.4(12) . . . . ?
C19 C20 C21 C28 -179.3(8) . . . . ?
C20 C21 C22 C23 -9.0(12) . . . . ?
C28 C21 C22 C23 179.9(8) . . . . ?
C20 C21 C22 C31 177.8(8) . . . . ?
C28 C21 C22 C31 6.6(9) . . . . ?
C21 C22 C23 C18 1.8(13) . . . . ?
C31 C22 C23 C18 173.2(9) . . . . ?
C19 C18 C23 C22 1.7(12) . . . . ?
C17 C18 C23 C22 -176.2(8) . . . . ?
O8 C24 C25 C30 -160.3(8) . . . . ?
O9 C24 C25 C30 15.5(12) . . . . ?
O8 C24 C25 C26 18.1(12) . . . . ?
O9 C24 C25 C26 -166.1(8) . . . . ?
C30 C25 C26 C27 -3.1(13) . . . . ?
C24 C25 C26 C27 178.5(8) . . . . ?
C25 C26 C27 C28 -0.1(12) . . . . ?
C26 C27 C28 C29 5.4(12) . . . . ?
C26 C27 C28 C21 172.0(8) . . . . ?
C20 C21 C28 C29 -175.2(9) . . . . ?
C22 C21 C28 C29 -5.9(9) . . . . ?
C20 C21 C28 C27 16.8(15) . . . . ?
C22 C21 C28 C27 -173.8(8) . . . . ?
C27 C28 C29 C30 -7.5(12) . . . . ?
C21 C28 C29 C30 -176.7(7) . . . . ?
C27 C28 C29 C31 172.1(7) . . . . ?
C21 C28 C29 C31 2.9(10) . . . . ?
C26 C25 C30 C29 1.0(13) . . . . ?
C24 C25 C30 C29 179.3(8) . . . . ?
C28 C29 C30 C25 4.3(12) . . . . ?
C31 C29 C30 C25 -175.2(8) . . . . ?
C28 C29 C31 O10 -111.8(8) . . . . ?
C30 C29 C31 O10 67.7(11) . . . . ?
C28 C29 C31 C22 1.1(9) . . . . ?
C30 C29 C31 C22 -179.3(8) . . . . ?
C28 C29 C31 C32 122.6(8) . . . . ?
C30 C29 C31 C32 -57.8(12) . . . . ?
C23 C22 C31 O10 -62.5(12) . . . . ?
C21 C22 C31 O10 109.5(7) . . . . ?
C23 C22 C31 C29 -176.8(9) . . . . ?
C21 C22 C31 C29 -4.8(9) . . . . ?
C23 C22 C31 C32 56.8(13) . . . . ?
C21 C22 C31 C32 -131.1(7) . . . . ?
O1 C1 Eu1 O3 47.9(5) . . . 2_545 ?
O2 C1 Eu1 O3 -144.4(4) . . . 2_545 ?
C2 C1 Eu1 O3 -12(2) . . . 2_545 ?
O1 C1 Eu1 O8 121.0(5) . . . 4_675 ?
O2 C1 Eu1 O8 -71.3(4) . . . 4_675 ?
C2 C1 Eu1 O8 61(2) . . . 4_675 ?
O1 C1 Eu1 O9 -96.8(5) . . . 2_556 ?
O2 C1 Eu1 O9 70.9(4) . . . 2_556 ?
C2 C1 Eu1 O9 -157(2) . . . 2_556 ?
O1 C1 Eu1 O2 -167.4(4) . . . 3_676 ?
O2 C1 Eu1 O2 0.3(5) . . . 3_676 ?
C2 C1 Eu1 O2 133(2) . . . 3_676 ?
O2 C1 Eu1 O1 167.7(8) . . . . ?
C2 C1 Eu1 O1 -60(2) . . . . ?
O1 C1 Eu1 O14 -26.1(5) . . . . ?
O2 C1 Eu1 O14 141.6(4) . . . . ?
C2 C1 Eu1 O14 -86(2) . . . . ?
O1 C1 Eu1 O2 -167.7(8) . . . . ?
C2 C1 Eu1 O2 132(3) . . . . ?
O1 C1 Eu1 Eu1 -167.5(5) . . . 3_676 ?
O2 C1 Eu1 Eu1 0.2(4) . . . 3_676 ?
C2 C1 Eu1 Eu1 133(2) . . . 3_676 ?
O16 C33 N3 C34 -31.0(11) . . . . ?
O16 C33 N3 C35 161.9(8) . . . . ?
O2 C1 O1 Eu1 -12.7(9) . . . . ?
C2 C1 O1 Eu1 164.6(6) . . . . ?
O6 Eu1 O1 C1 -176.9(5) . . . . ?
O3 Eu1 O1 C1 -130.4(5) 2_545 . . . ?
O8 Eu1 O1 C1 -57.0(5) 4_675 . . . ?
O9 Eu1 O1 C1 79.8(5) 2_556 . . . ?
O2 Eu1 O1 C1 15.5(6) 3_676 . . . ?
O14 Eu1 O1 C1 153.3(5) . . . . ?
O2 Eu1 O1 C1 6.9(4) . . . . ?
Eu1 Eu1 O1 C1 11.0(5) 3_676 . . . ?
O1 C1 O2 Eu1 10.7(7) . . . . ?
C2 C1 O2 Eu1 -166.6(8) . . . . ?
O6 Eu1 O2 C1 179.1(5) . . . . ?
O3 Eu1 O2 C1 39.2(5) 2_545 . . . ?
O8 Eu1 O2 C1 101.9(5) 4_675 . . . ?
O9 Eu1 O2 C1 -103.3(4) 2_556 . . . ?
O2 Eu1 O2 C1 -179.7(5) 3_676 . . . ?
O1 Eu1 O2 C1 -6.6(4) . . . . ?
O14 Eu1 O2 C1 -43.8(5) . . . . ?
Eu1 Eu1 O2 C1 -179.7(5) 3_676 . . . ?
O6 Eu1 O2 Eu1 -1.1(5) . . . 3_676 ?
O3 Eu1 O2 Eu1 -141.07(18) 2_545 . . 3_676 ?
O8 Eu1 O2 Eu1 -78.4(2) 4_675 . . 3_676 ?
O9 Eu1 O2 Eu1 76.4(2) 2_556 . . 3_676 ?
O2 Eu1 O2 Eu1 0.0 3_676 . . 3_676 ?
O1 Eu1 O2 Eu1 173.1(3) . . . 3_676 ?
O14 Eu1 O2 Eu1 135.92(19) . . . 3_676 ?
C1 Eu1 O2 Eu1 179.7(5) . . . 3_676 ?
O4 C8 O3 Eu1 53(2) . . . 2 ?
C9 C8 O3 Eu1 -133.6(14) . . . 2 ?
O3 C8 O4 Eu2 62.4(12) . . . 2 ?
C9 C8 O4 Eu2 -111.1(9) . . . 2 ?
O7 C17 O6 Eu1 88.0(9) . . . . ?
C18 C17 O6 Eu1 -90.0(8) . . . . ?
O3 Eu1 O6 C17 -50.3(7) 2_545 . . . ?
O8 Eu1 O6 C17 -121.8(7) 4_675 . . . ?
O9 Eu1 O6 C17 93.6(7) 2_556 . . . ?
O2 Eu1 O6 C17 165.3(7) 3_676 . . . ?
O1 Eu1 O6 C17 -4.9(9) . . . . ?
O14 Eu1 O6 C17 24.7(7) . . . . ?
O2 Eu1 O6 C17 166.4(7) . . . . ?
Eu1 Eu1 O6 C17 165.6(7) 3_676 . . . ?
O6 C17 O7 Eu2 -24.6(17) . . . . ?
C18 C17 O7 Eu2 153.4(10) . . . . ?
O4 Eu2 O7 C17 171.2(13) 4_676 . . . ?
O4 Eu2 O7 C17 -8.8(13) 2_545 . . . ?
O16 Eu2 O7 C17 -105.2(13) 3_666 . . . ?
O16 Eu2 O7 C17 74.8(13) . . . . ?
O12 Eu2 O7 C17 -81.9(13) . . . . ?
O12 Eu2 O7 C17 98.1(13) 3_666 . . . ?
O9 C24 O8 Eu1 3.8(14) . . . 4_576 ?
C25 C24 O8 Eu1 179.0(5) . . . 4_576 ?
O8 C24 O9 Eu1 -0.6(14) . . . 2_546 ?
C25 C24 O9 Eu1 -176.0(5) . . . 2_546 ?
O11 N1 O12 Eu2 -51.7(8) . . . . ?
O13 N1 O12 Eu2 130.3(6) . . . . ?
O7 Eu2 O12 N1 95.4(5) 3_666 . . . ?
O7 Eu2 O12 N1 -84.6(5) . . . . ?
O4 Eu2 O12 N1 -4.1(5) 4_676 . . . ?
O4 Eu2 O12 N1 175.9(5) 2_545 . . . ?
O16 Eu2 O12 N1 69.1(5) 3_666 . . . ?
O16 Eu2 O12 N1 -110.9(5) . . . . ?
O17 N2 O14 Eu1 -22.2(13) . . . . ?
O15 N2 O14 Eu1 162.4(5) . . . . ?
O6 Eu1 O14 N2 -98.8(7) . . . . ?
O3 Eu1 O14 N2 -13.6(7) 2_545 . . . ?
O8 Eu1 O14 N2 -3.4(8) 4_675 . . . ?
O9 Eu1 O14 N2 154.4(7) 2_556 . . . ?
O2 Eu1 O14 N2 -163.5(6) 3_676 . . . ?
O1 Eu1 O14 N2 66.2(7) . . . . ?
O2 Eu1 O14 N2 94.6(7) . . . . ?
C1 Eu1 O14 N2 77.0(7) . . . . ?
Eu1 Eu1 O14 N2 132.4(6) 3_676 . . . ?
N3 C33 O16 Eu2 -138.4(10) . . . . ?
O7 Eu2 O16 C33 -168.1(13) 3_666 . . . ?
O7 Eu2 O16 C33 11.9(13) . . . . ?
O4 Eu2 O16 C33 -73.7(13) 4_676 . . . ?
O4 Eu2 O16 C33 106.3(13) 2_545 . . . ?
O12 Eu2 O16 C33 37.6(13) . . . . ?
O12 Eu2 O16 C33 -142.4(13) 3_666 . . . ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        26.00
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         0.814
_refine_diff_density_min         -0.690
_refine_diff_density_rms         0.154
