# Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry
# This journal is © The Royal Society of Chemistry 2012


data_global
_journal_name_full               Org.Biomol.Chem.
_journal_coden_cambridge         0177
loop_
_publ_author_name
'Sandra Medina'
'Alvaro Gonzalez-Gomez'
'Gema Dominguez'
'Javier Perez-Castells'
_publ_contact_author_email       jpercas@ceu.es
_publ_contact_author_name        'Javier Perez-Castells'

data_datat
_database_code_depnum_ccdc_archive 'CCDC 877733'
#TrackingRef '- DATAT.CIF'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C33 H32 N2 O10 S2'
_chemical_formula_weight         680.73

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.135(2)
_cell_length_b                   11.251(2)
_cell_length_c                   14.491(3)
_cell_angle_alpha                106.087(4)
_cell_angle_beta                 90.501(4)
_cell_angle_gamma                114.229(4)
_cell_volume                     1575.1(6)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       prismatic
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.435
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             712
_exptl_absorpt_coefficient_mu    0.232
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       '\w scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            15241
_diffrn_reflns_av_R_equivalents  0.1007
_diffrn_reflns_av_sigmaI/netI    0.3112
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.48
_diffrn_reflns_theta_max         29.05
_reflns_number_total             7511
_reflns_number_gt                2024
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker XSCANS'
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.1044P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7511
_refine_ls_number_parameters     420
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.2642
_refine_ls_R_factor_gt           0.0754
_refine_ls_wR_factor_ref         0.2485
_refine_ls_wR_factor_gt          0.1846
_refine_ls_goodness_of_fit_ref   0.805
_refine_ls_restrained_S_all      0.805
_refine_ls_shift/su_max          0.688
_refine_ls_shift/su_mean         0.044

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
S1 S 0.24684(15) 0.05578(15) 0.05635(10) 0.0434(4) Uani 1 1 d . . .
O1 O 0.3768(3) 0.0887(4) 0.0293(2) 0.0466(10) Uani 1 1 d . . .
O2 O 0.1347(4) -0.0342(4) -0.0154(3) 0.0569(11) Uani 1 1 d . . .
O6 O 0.7781(5) 0.3162(5) 0.0929(4) 0.0890(16) Uani 1 1 d . . .
O5 O 0.6475(4) 0.4201(5) 0.0902(3) 0.0783(14) Uani 1 1 d . . .
O3 O 0.4054(4) 0.3527(4) 0.3570(3) 0.0689(13) Uani 1 1 d . . .
O4 O 0.5767(4) 0.4977(4) 0.3054(3) 0.0697(13) Uani 1 1 d . . .
O9 O 0.8389(6) -0.0350(7) 0.4284(4) 0.124(2) Uani 1 1 d . . .
O10 O 0.9345(5) 0.1117(5) 0.3458(4) 0.0832(15) Uani 1 1 d . . .
N1 N 0.2335(4) -0.0187(4) 0.1436(3) 0.0373(11) Uani 1 1 d . . .
N2 N 0.5341(4) 0.0963(4) 0.3253(3) 0.0394(11) Uani 1 1 d . . .
C8 C 0.3297(5) 0.0203(5) 0.2259(4) 0.0334(12) Uani 1 1 d . . .
C7 C 0.1094(5) -0.1073(5) 0.1635(4) 0.0408(14) Uani 1 1 d . . .
C13 C 0.5968(5) 0.2536(5) 0.1725(4) 0.0381(13) Uani 1 1 d . . .
C28 C 0.3231(6) 0.3279(7) 0.0990(4) 0.0609(17) Uani 1 1 d . . .
H28 H 0.3922 0.3284 0.0632 0.073 Uiso 1 1 calc R . .
C11 C 0.3364(5) -0.0252(6) 0.3856(4) 0.0540(16) Uani 1 1 d . . .
H11A H 0.3485 -0.1069 0.3820 0.065 Uiso 1 1 calc R . .
H11B H 0.2809 -0.0139 0.4354 0.065 Uiso 1 1 calc R . .
C4 C -0.0996(6) -0.2746(6) 0.2371(5) 0.0652(19) Uani 1 1 d . . .
H4 H -0.1708 -0.3319 0.2604 0.078 Uiso 1 1 calc R . .
C21 C 0.7044(6) 0.0085(7) 0.3301(4) 0.0648(19) Uani 1 1 d . . .
H21 H 0.6337 -0.0555 0.3555 0.078 Uiso 1 1 calc R . .
C27 C 0.2329(5) 0.2080(5) 0.1116(4) 0.0392(13) Uani 1 1 d . . .
C14 C 0.5756(5) 0.1089(5) 0.1661(4) 0.0357(13) Uani 1 1 d . . .
H14 H 0.5360 0.0396 0.1027 0.043 Uiso 1 1 calc R . .
C17 C 0.6732(6) 0.3395(6) 0.1155(4) 0.0526(16) Uani 1 1 d . . .
C9 C 0.4768(5) 0.1142(5) 0.2432(3) 0.0336(13) Uani 1 1 d . . .
C2 C 0.1314(5) -0.1225(5) 0.2533(4) 0.0418(14) Uani 1 1 d . . .
C1 C 0.2698(5) -0.0415(5) 0.2910(4) 0.0414(14) Uani 1 1 d . . .
C31 C 0.1178(7) 0.3289(7) 0.2025(5) 0.0680(19) Uani 1 1 d . . .
H31 H 0.0482 0.3286 0.2375 0.082 Uiso 1 1 calc R . .
C12 C 0.5198(5) 0.2632(5) 0.2420(4) 0.0384(13) Uani 1 1 d . . .
C15 C 0.4917(6) 0.3728(6) 0.3069(4) 0.0466(15) Uani 1 1 d . . .
C32 C 0.1286(6) 0.2078(6) 0.1623(4) 0.0547(16) Uani 1 1 d . . .
H32 H 0.0658 0.1265 0.1693 0.066 Uiso 1 1 calc R . .
C29 C 0.3099(7) 0.4482(7) 0.1403(5) 0.079(2) Uani 1 1 d . . .
H29 H 0.3718 0.5296 0.1327 0.094 Uiso 1 1 calc R . .
C3 C 0.0250(6) -0.2079(6) 0.2907(5) 0.0566(17) Uani 1 1 d . . .
H3 H 0.0387 -0.2191 0.3506 0.068 Uiso 1 1 calc R . .
C25 C 0.8361(10) 0.0418(13) 0.3775(6) 0.123(4) Uani 1 1 d . . .
C10 C 0.4692(5) 0.0973(6) 0.4118(4) 0.0455(15) Uani 1 1 d . . .
H10A H 0.4574 0.1809 0.4352 0.055 Uiso 1 1 calc R . .
H10B H 0.5230 0.0929 0.4627 0.055 Uiso 1 1 calc R . .
C20 C 0.6742(5) 0.1338(6) 0.3270(4) 0.0448(14) Uani 1 1 d . . .
C6 C -0.0169(6) -0.1746(6) 0.1101(4) 0.0551(16) Uani 1 1 d . . .
H6 H -0.0317 -0.1642 0.0501 0.066 Uiso 1 1 calc R . .
C19 C 0.6900(5) 0.1026(5) 0.2186(3) 0.0399(14) Uani 1 1 d . . .
H19 H 0.7771 0.1634 0.2068 0.048 Uiso 1 1 calc R . .
C18 C 0.8605(8) 0.3862(8) 0.0309(6) 0.115(3) Uani 1 1 d . . .
H18A H 0.8055 0.3764 -0.0246 0.173 Uiso 1 1 calc R . .
H18B H 0.9215 0.3470 0.0098 0.173 Uiso 1 1 calc R . .
H18C H 0.9095 0.4816 0.0661 0.173 Uiso 1 1 calc R . .
C30 C 0.2083(8) 0.4498(7) 0.1916(5) 0.074(2) Uani 1 1 d . . .
C5 C -0.1190(6) -0.2563(6) 0.1480(5) 0.0622(18) Uani 1 1 d . . .
H5 H -0.2040 -0.3010 0.1131 0.075 Uiso 1 1 calc R . .
C33 C 0.1953(9) 0.5830(7) 0.2405(6) 0.120(3) Uani 1 1 d . . .
H33A H 0.2647 0.6578 0.2256 0.180 Uiso 1 1 calc R . .
H33B H 0.2027 0.6000 0.3094 0.180 Uiso 1 1 calc R . .
H33C H 0.1103 0.5743 0.2168 0.180 Uiso 1 1 calc R . .
C22 C 0.6816(6) -0.0383(6) 0.2173(4) 0.0584(17) Uani 1 1 d . . .
H22A H 0.7522 -0.0578 0.1882 0.070 Uiso 1 1 calc R . .
H22B H 0.5954 -0.1136 0.1892 0.070 Uiso 1 1 calc R . .
C26 C 1.0653(7) 0.1500(7) 0.3965(5) 0.095(2) Uani 1 1 d . . .
H26A H 1.0588 0.1560 0.4635 0.142 Uiso 1 1 calc R . .
H26B H 1.1268 0.2371 0.3918 0.142 Uiso 1 1 calc R . .
H26C H 1.0961 0.0819 0.3675 0.142 Uiso 1 1 calc R . .
C16 C 0.5580(8) 0.6132(6) 0.3714(5) 0.102(3) Uani 1 1 d . . .
H16A H 0.4677 0.5996 0.3587 0.153 Uiso 1 1 calc R . .
H16B H 0.6172 0.6972 0.3609 0.153 Uiso 1 1 calc R . .
H16C H 0.5768 0.6178 0.4374 0.153 Uiso 1 1 calc R . .
C23 C 0.7594(7) 0.2699(9) 0.3960(6) 0.089(3) Uani 1 1 d . . .
O8 O 0.7876(9) 0.3662(6) 0.3780(6) 0.230(6) Uani 1 1 d . . .
O7 O 0.7927(7) 0.2723(6) 0.4844(5) 0.151(3) Uani 1 1 d . . .
C24 C 0.8325(11) 0.5003(9) 0.4531(10) 0.244(8) Uani 1 1 d . . .
H24A H 0.7803 0.4909 0.5052 0.366 Uiso 1 1 calc R . .
H24B H 0.8221 0.5644 0.4255 0.366 Uiso 1 1 calc R . .
H24C H 0.9245 0.5329 0.4775 0.366 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
S1 0.0484(10) 0.0494(9) 0.0367(8) 0.0125(7) 0.0042(7) 0.0258(8)
O1 0.049(2) 0.059(3) 0.038(2) 0.0178(19) 0.0127(18) 0.027(2)
O2 0.056(3) 0.059(3) 0.044(2) 0.005(2) -0.018(2) 0.021(2)
O6 0.095(4) 0.089(4) 0.134(4) 0.075(3) 0.080(3) 0.061(3)
O5 0.064(3) 0.086(3) 0.115(4) 0.070(3) 0.035(3) 0.035(3)
O3 0.074(3) 0.059(3) 0.074(3) 0.015(2) 0.038(3) 0.032(3)
O4 0.078(3) 0.037(2) 0.086(3) 0.010(2) 0.025(3) 0.022(2)
O9 0.121(5) 0.193(6) 0.103(5) 0.060(5) 0.027(4) 0.102(5)
O10 0.070(4) 0.095(4) 0.077(4) 0.038(3) -0.003(3) 0.021(3)
N1 0.039(3) 0.041(3) 0.036(3) 0.017(2) 0.004(2) 0.018(2)
N2 0.036(3) 0.056(3) 0.031(2) 0.019(2) 0.008(2) 0.021(2)
C8 0.033(3) 0.035(3) 0.029(3) 0.006(2) 0.004(2) 0.014(3)
C7 0.032(4) 0.032(3) 0.057(4) 0.014(3) 0.003(3) 0.012(3)
C13 0.038(3) 0.039(3) 0.041(3) 0.017(3) 0.009(3) 0.017(3)
C28 0.059(4) 0.061(4) 0.074(5) 0.029(4) 0.011(3) 0.031(4)
C11 0.047(4) 0.070(4) 0.042(4) 0.022(3) 0.008(3) 0.019(4)
C4 0.042(4) 0.055(4) 0.091(5) 0.025(4) 0.024(4) 0.012(4)
C21 0.063(4) 0.096(5) 0.067(5) 0.043(4) 0.021(4) 0.052(4)
C27 0.042(3) 0.042(3) 0.041(3) 0.016(3) -0.002(3) 0.023(3)
C14 0.037(3) 0.041(3) 0.034(3) 0.011(3) 0.010(2) 0.021(3)
C17 0.052(4) 0.047(4) 0.066(4) 0.025(3) 0.018(3) 0.023(4)
C9 0.033(3) 0.040(3) 0.029(3) 0.009(2) 0.005(2) 0.018(3)
C2 0.041(4) 0.042(3) 0.045(4) 0.015(3) 0.015(3) 0.019(3)
C1 0.039(4) 0.043(3) 0.040(3) 0.016(3) 0.007(3) 0.015(3)
C31 0.069(5) 0.070(5) 0.073(5) 0.009(4) 0.008(4) 0.046(4)
C12 0.036(3) 0.038(3) 0.040(3) 0.011(3) 0.007(3) 0.015(3)
C15 0.052(4) 0.040(4) 0.045(4) 0.008(3) 0.008(3) 0.020(3)
C32 0.055(4) 0.059(4) 0.056(4) 0.018(3) 0.011(3) 0.029(3)
C29 0.075(5) 0.053(5) 0.108(6) 0.030(4) 0.004(5) 0.025(4)
C3 0.052(4) 0.054(4) 0.066(4) 0.027(4) 0.021(4) 0.019(4)
C25 0.145(9) 0.265(13) 0.084(6) 0.112(8) 0.060(6) 0.170(10)
C10 0.054(4) 0.055(4) 0.034(3) 0.013(3) 0.004(3) 0.030(3)
C20 0.034(3) 0.060(4) 0.038(3) 0.012(3) 0.004(3) 0.020(3)
C6 0.051(4) 0.052(4) 0.063(4) 0.020(3) 0.001(4) 0.022(4)
C19 0.042(3) 0.047(4) 0.034(3) 0.012(3) 0.011(3) 0.022(3)
C18 0.125(7) 0.104(6) 0.161(8) 0.086(6) 0.114(7) 0.061(6)
C30 0.081(6) 0.058(5) 0.094(6) 0.016(4) 0.005(4) 0.043(5)
C5 0.039(4) 0.048(4) 0.092(6) 0.018(4) -0.002(4) 0.013(3)
C33 0.179(9) 0.076(5) 0.132(8) 0.013(5) 0.008(7) 0.092(6)
C22 0.072(5) 0.070(5) 0.054(4) 0.023(3) 0.017(3) 0.048(4)
C26 0.088(6) 0.100(6) 0.090(6) -0.005(5) -0.010(5) 0.057(5)
C16 0.128(7) 0.041(4) 0.116(6) -0.011(4) 0.021(5) 0.038(5)
C23 0.055(5) 0.097(7) 0.075(6) -0.037(5) -0.023(4) 0.036(5)
O8 0.349(12) 0.023(3) 0.215(8) 0.009(4) -0.188(8) 0.006(5)
O7 0.171(6) 0.119(5) 0.086(4) 0.003(4) -0.018(4) 0.008(5)
C24 0.226(13) 0.053(6) 0.360(18) 0.015(9) -0.208(13) 0.007(7)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
S1 O2 1.422(4) . ?
S1 O1 1.427(3) . ?
S1 N1 1.676(4) . ?
S1 C27 1.748(5) . ?
O6 C17 1.322(6) . ?
O6 C18 1.444(6) . ?
O5 C17 1.197(6) . ?
O3 C15 1.194(6) . ?
O4 C15 1.340(6) . ?
O4 C16 1.478(7) . ?
O9 C25 1.291(9) . ?
O10 C25 1.237(10) . ?
O10 C26 1.462(7) . ?
N1 C7 1.423(6) . ?
N1 C8 1.437(6) . ?
N2 C20 1.437(6) . ?
N2 C9 1.445(6) . ?
N2 C10 1.452(6) . ?
C8 C1 1.347(6) . ?
C8 C9 1.513(6) . ?
C7 C2 1.391(7) . ?
C7 C6 1.390(7) . ?
C13 C12 1.339(6) . ?
C13 C17 1.456(7) . ?
C13 C14 1.521(7) . ?
C28 C27 1.375(7) . ?
C28 C29 1.388(8) . ?
C11 C1 1.480(7) . ?
C11 C10 1.503(7) . ?
C4 C3 1.377(8) . ?
C4 C5 1.391(8) . ?
C21 C25 1.467(10) . ?
C21 C22 1.555(8) . ?
C21 C20 1.589(8) . ?
C27 C32 1.380(7) . ?
C14 C19 1.515(7) . ?
C14 C9 1.581(6) . ?
C9 C12 1.549(7) . ?
C2 C3 1.410(7) . ?
C2 C1 1.436(7) . ?
C31 C30 1.373(8) . ?
C31 C32 1.380(8) . ?
C12 C15 1.477(7) . ?
C29 C30 1.363(9) . ?
C20 C23 1.480(9) . ?
C20 C19 1.539(7) . ?
C6 C5 1.369(7) . ?
C19 C22 1.543(7) . ?
C30 C33 1.536(9) . ?
C23 O8 1.105(10) . ?
C23 O7 1.320(9) . ?
O8 C24 1.473(12) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 S1 O1 118.8(2) . . ?
O2 S1 N1 105.7(2) . . ?
O1 S1 N1 108.0(2) . . ?
O2 S1 C27 109.6(2) . . ?
O1 S1 C27 108.8(2) . . ?
N1 S1 C27 105.0(2) . . ?
C17 O6 C18 118.1(5) . . ?
C15 O4 C16 115.4(5) . . ?
C25 O10 C26 117.2(6) . . ?
C7 N1 C8 106.5(4) . . ?
C7 N1 S1 123.1(4) . . ?
C8 N1 S1 128.2(3) . . ?
C20 N2 C9 112.7(4) . . ?
C20 N2 C10 123.0(4) . . ?
C9 N2 C10 119.5(4) . . ?
C1 C8 N1 109.5(4) . . ?
C1 C8 C9 121.8(5) . . ?
N1 C8 C9 128.7(4) . . ?
C2 C7 C6 120.8(5) . . ?
C2 C7 N1 107.6(5) . . ?
C6 C7 N1 131.5(5) . . ?
C12 C13 C17 136.5(5) . . ?
C12 C13 C14 94.8(4) . . ?
C17 C13 C14 128.7(4) . . ?
C27 C28 C29 119.2(6) . . ?
C1 C11 C10 110.5(4) . . ?
C3 C4 C5 120.1(6) . . ?
C25 C21 C22 117.2(5) . . ?
C25 C21 C20 116.9(7) . . ?
C22 C21 C20 87.3(4) . . ?
C28 C27 C32 119.8(5) . . ?
C28 C27 S1 119.1(4) . . ?
C32 C27 S1 121.0(5) . . ?
C19 C14 C13 113.9(4) . . ?
C19 C14 C9 104.9(4) . . ?
C13 C14 C9 86.1(3) . . ?
O5 C17 O6 122.8(5) . . ?
O5 C17 C13 126.5(5) . . ?
O6 C17 C13 110.6(5) . . ?
N2 C9 C8 106.9(4) . . ?
N2 C9 C12 116.9(4) . . ?
C8 C9 C12 118.1(4) . . ?
N2 C9 C14 104.1(4) . . ?
C8 C9 C14 124.9(4) . . ?
C12 C9 C14 84.7(3) . . ?
C7 C2 C3 119.9(5) . . ?
C7 C2 C1 108.4(5) . . ?
C3 C2 C1 131.7(5) . . ?
C8 C1 C2 108.0(5) . . ?
C8 C1 C11 125.2(5) . . ?
C2 C1 C11 126.7(5) . . ?
C30 C31 C32 121.0(6) . . ?
C13 C12 C15 136.5(5) . . ?
C13 C12 C9 94.1(4) . . ?
C15 C12 C9 129.0(4) . . ?
O3 C15 O4 123.9(5) . . ?
O3 C15 C12 123.8(5) . . ?
O4 C15 C12 112.2(5) . . ?
C27 C32 C31 119.7(6) . . ?
C30 C29 C28 121.6(7) . . ?
C4 C3 C2 118.8(6) . . ?
O10 C25 O9 123.5(7) . . ?
O10 C25 C21 117.6(7) . . ?
O9 C25 C21 115.7(10) . . ?
N2 C10 C11 107.8(4) . . ?
N2 C20 C23 114.0(5) . . ?
N2 C20 C19 102.8(4) . . ?
C23 C20 C19 120.0(6) . . ?
N2 C20 C21 109.9(4) . . ?
C23 C20 C21 117.5(6) . . ?
C19 C20 C21 89.3(4) . . ?
C5 C6 C7 118.3(6) . . ?
C14 C19 C20 107.4(4) . . ?
C14 C19 C22 119.2(5) . . ?
C20 C19 C22 89.5(4) . . ?
C29 C30 C31 118.6(6) . . ?
C29 C30 C33 122.0(7) . . ?
C31 C30 C33 119.3(7) . . ?
C6 C5 C4 122.1(6) . . ?
C19 C22 C21 90.4(4) . . ?
O8 C23 O7 120.6(8) . . ?
O8 C23 C20 122.9(9) . . ?
O7 C23 C20 116.3(9) . . ?
C23 O8 C24 122.4(9) . . ?

_diffrn_measured_fraction_theta_max 0.892
_diffrn_reflns_theta_full        29.05
_diffrn_measured_fraction_theta_full 0.892
_refine_diff_density_max         1.003
_refine_diff_density_min         -0.487
_refine_diff_density_rms         0.070