# Electronic Supplementary Material (ESI) for Polymer Chemistry.
# This journal is © The Royal Society of Chemistry 2014

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_hazh-blau

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C50 H62 Br2 N2 O2'
_chemical_formula_sum            'C50 H62 Br2 N2 O2'
_chemical_formula_weight         882.84

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   5.5633(5)
_cell_length_b                   9.9288(11)
_cell_length_c                   19.482(2)
_cell_angle_alpha                96.408(4)
_cell_angle_beta                 94.570(6)
_cell_angle_gamma                95.403(6)
_cell_volume                     1060.19(19)
_cell_formula_units_Z            1
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    4181
_cell_measurement_theta_min      2.08
_cell_measurement_theta_max      25.00
_exptl_crystal_description       prism
_exptl_crystal_colour            blue
_exptl_crystal_colour_lustre     metallic

_exptl_crystal_size_max          .15
_exptl_crystal_size_mid          .07
_exptl_crystal_size_min          .03
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.383
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             462
_exptl_absorpt_coefficient_mu    1.954
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       Phi/Omega-Scans
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            4181
_diffrn_reflns_av_R_equivalents  0.0634
_diffrn_reflns_av_sigmaI/netI    0.1316
_diffrn_reflns_limit_h_min       -5
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         2.08
_diffrn_reflns_theta_max         25.00
_reflns_number_total             3450
_reflns_number_gt                2271
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Nonius COLLECT'
_computing_cell_refinement       'Nonius DENZO (Otwinowski, Minor 1997)'
_computing_data_reduction        'Nonius DENZO (Otwinowski, Minor 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SCHAKAL99 (E. Keller 1999)'
_computing_publication_material  'PLATON (A. L. Spek 1980-2004)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0826P)²+0.8300P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         3450
_refine_ls_number_parameters     254
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1243
_refine_ls_R_factor_gt           0.0725
_refine_ls_wR_factor_ref         0.1856
_refine_ls_wR_factor_gt          0.1630
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_restrained_S_all      1.041
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Br1 Br 1.68078(13) 0.33753(8) -0.28711(4) 0.0351(3) Uani 1 1 d . . .
O1 O 1.1857(8) 0.4152(5) 0.0340(3) 0.0324(12) Uani 1 1 d . . .
N1 N 0.8495(10) 0.2675(5) 0.0461(3) 0.0260(14) Uani 1 1 d . . .
C1 C 1.4908(12) 0.2962(6) -0.2134(4) 0.0269(17) Uani 1 1 d . . .
C2 C 1.5735(12) 0.3501(7) -0.1466(4) 0.0262(16) Uani 1 1 d . . .
H2 H 1.7255 0.4038 -0.1370 0.031 Uiso 1 1 calc R . .
C3 C 1.4300(12) 0.3241(6) -0.0939(4) 0.0266(16) Uani 1 1 d . . .
H3 H 1.4840 0.3625 -0.0478 0.032 Uiso 1 1 calc R . .
C4 C 1.2067(12) 0.2427(6) -0.1064(4) 0.0270(16) Uani 1 1 d . . .
C5 C 1.0496(12) 0.2180(7) -0.0521(4) 0.0249(16) Uani 1 1 d . . .
C6 C 1.0474(13) 0.3137(7) 0.0119(4) 0.0274(16) Uani 1 1 d . . .
C7 C 0.7364(12) 0.1455(6) 0.0105(4) 0.0235(16) Uani 1 1 d . . .
C8 C 0.8675(12) 0.1149(6) -0.0502(4) 0.0274(17) Uani 1 1 d . . .
C9 C 0.7963(12) -0.0091(7) -0.0943(4) 0.0276(16) Uani 1 1 d . . .
H9 H 0.8869 -0.0333 -0.1324 0.033 Uiso 1 1 calc R . .
C10 C 0.6030(11) -0.0921(6) -0.0828(4) 0.0250(16) Uani 1 1 d . . .
H10 H 0.5566 -0.1729 -0.1138 0.030 Uiso 1 1 calc R . .
C11 C 0.5356(11) 0.0622(6) 0.0250(4) 0.0240(16) Uani 1 1 d . . .
C23 C 1.2727(13) 0.2170(7) -0.2290(4) 0.0288(17) Uani 1 1 d . . .
H23 H 1.2207 0.1803 -0.2755 0.035 Uiso 1 1 calc R . .
C24 C 1.1311(12) 0.1918(6) -0.1761(4) 0.0273(17) Uani 1 1 d . . .
H24 H 0.9786 0.1388 -0.1867 0.033 Uiso 1 1 calc R . .
C25 C 0.7848(13) 0.3494(7) 0.1072(4) 0.0298(17) Uani 1 1 d . . .
H25A H 0.6065 0.3503 0.1039 0.036 Uiso 1 1 calc R . .
H25B H 0.8577 0.4443 0.1074 0.036 Uiso 1 1 calc R . .
C26 C 0.8660(13) 0.2997(7) 0.1753(4) 0.0330(18) Uani 1 1 d . . .
H26A H 1.0454 0.3094 0.1815 0.040 Uiso 1 1 calc R . .
H26B H 0.8095 0.2016 0.1732 0.040 Uiso 1 1 calc R . .
C27 C 0.7708(13) 0.3766(7) 0.2377(4) 0.0322(18) Uani 1 1 d . . .
H27A H 0.8234 0.4750 0.2390 0.039 Uiso 1 1 calc R . .
H27B H 0.5913 0.3646 0.2321 0.039 Uiso 1 1 calc R . .
C28 C 0.8579(13) 0.3294(7) 0.3060(4) 0.0320(17) Uani 1 1 d . . .
H28A H 1.0372 0.3439 0.3119 0.038 Uiso 1 1 calc R . .
H28B H 0.8101 0.2303 0.3038 0.038 Uiso 1 1 calc R . .
C29 C 0.7587(13) 0.4020(7) 0.3694(4) 0.0316(17) Uani 1 1 d . . .
H29A H 0.5806 0.3996 0.3604 0.038 Uiso 1 1 calc R . .
H29B H 0.7918 0.3514 0.4095 0.038 Uiso 1 1 calc R . .
C30 C 0.8655(12) 0.5495(7) 0.3884(4) 0.0299(17) Uani 1 1 d . . .
H30A H 1.0415 0.5509 0.4015 0.036 Uiso 1 1 calc R . .
H30B H 0.8463 0.5976 0.3468 0.036 Uiso 1 1 calc R . .
C31 C 0.7541(13) 0.6280(7) 0.4473(4) 0.0309(17) Uani 1 1 d . . .
H31A H 0.7944 0.5895 0.4910 0.037 Uiso 1 1 calc R . .
H31B H 0.5755 0.6173 0.4377 0.037 Uiso 1 1 calc R . .
C32 C 0.8458(14) 0.7796(7) 0.4563(4) 0.0368(19) Uani 1 1 d . . .
H32A H 1.0208 0.7897 0.4721 0.044 Uiso 1 1 calc R . .
H32B H 0.8289 0.8134 0.4104 0.044 Uiso 1 1 calc R . .
C33 C 0.7179(14) 0.8697(7) 0.5069(4) 0.039(2) Uani 1 1 d . . .
H33A H 0.7629 0.9659 0.5002 0.047 Uiso 1 1 calc R . .
H33B H 0.5408 0.8499 0.4948 0.047 Uiso 1 1 calc R . .
C34 C 0.7700(13) 0.8548(7) 0.5810(4) 0.0358(19) Uani 1 1 d . . .
H34A H 0.9456 0.8793 0.5941 0.043 Uiso 1 1 calc R . .
H34B H 0.7319 0.7579 0.5877 0.043 Uiso 1 1 calc R . .
C47 C 0.6277(14) 0.9427(8) 0.6298(4) 0.0368(19) Uani 1 1 d . . .
H47A H 0.6614 1.0392 0.6220 0.044 Uiso 1 1 calc R . .
H47B H 0.4522 0.9159 0.6177 0.044 Uiso 1 1 calc R . .
C48 C 0.6875(14) 0.9309(8) 0.7058(4) 0.041(2) Uani 1 1 d . . .
H48A H 0.6480 0.8364 0.7145 0.061 Uiso 1 1 calc R . .
H48B H 0.5925 0.9906 0.7337 0.061 Uiso 1 1 calc R . .
H48C H 0.8607 0.9580 0.7184 0.061 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Br1 C1 1.908(7) . ?
O1 C6 1.224(8) . ?
N1 C7 1.394(8) . ?
N1 C6 1.400(9) . ?
N1 C25 1.454(8) . ?
C1 C23 1.375(9) . ?
C1 C2 1.376(10) . ?
C2 C3 1.381(10) . ?
C2 H2 0.9500 . ?
C3 C4 1.405(9) . ?
C3 H3 0.9500 . ?
C4 C24 1.410(10) . ?
C4 C5 1.453(9) . ?
C5 C8 1.376(9) . ?
C5 C6 1.481(9) . ?
C7 C11 1.392(9) . ?
C7 C8 1.456(9) . ?
C8 C9 1.425(9) . ?
C9 C10 1.341(9) . ?
C9 H9 0.9500 . ?
C10 C11 1.435(9) 2_655 ?
C10 H10 0.9500 . ?
C11 C10 1.435(9) 2_655 ?
C11 C11 1.486(13) 2_655 ?
C23 C24 1.378(10) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C26 1.517(10) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 C27 1.520(10) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C27 C28 1.517(10) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 C29 1.529(10) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 C30 1.521(9) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 C31 1.520(10) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 C32 1.530(9) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C32 C33 1.520(10) . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C33 C34 1.477(11) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 C47 1.535(10) . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C47 C48 1.511(11) . ?
C47 H47A 0.9900 . ?
C47 H47B 0.9900 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C7 N1 C6 109.7(5) . . ?
C7 N1 C25 130.4(6) . . ?
C6 N1 C25 119.8(6) . . ?
C23 C1 C2 122.3(7) . . ?
C23 C1 Br1 118.9(6) . . ?
C2 C1 Br1 118.8(5) . . ?
C1 C2 C3 118.4(6) . . ?
C1 C2 H2 120.8 . . ?
C3 C2 H2 120.8 . . ?
C2 C3 C4 122.1(7) . . ?
C2 C3 H3 119.0 . . ?
C4 C3 H3 119.0 . . ?
C3 C4 C24 116.7(6) . . ?
C3 C4 C5 122.9(6) . . ?
C24 C4 C5 120.3(6) . . ?
C8 C5 C4 129.7(6) . . ?
C8 C5 C6 106.7(6) . . ?
C4 C5 C6 123.4(6) . . ?
O1 C6 N1 123.3(6) . . ?
O1 C6 C5 129.6(7) . . ?
N1 C6 C5 107.1(6) . . ?
C11 C7 N1 130.4(6) . . ?
C11 C7 C8 122.7(6) . . ?
N1 C7 C8 107.0(5) . . ?
C5 C8 C9 132.0(7) . . ?
C5 C8 C7 109.3(6) . . ?
C9 C8 C7 118.7(6) . . ?
C10 C9 C8 120.7(7) . . ?
C10 C9 H9 119.6 . . ?
C8 C9 H9 119.6 . . ?
C9 C10 C11 121.8(6) . 2_655 ?
C9 C10 H10 119.1 . . ?
C11 C10 H10 119.1 2_655 . ?
C7 C11 C10 124.0(6) . 2_655 ?
C7 C11 C11 115.8(7) . 2_655 ?
C10 C11 C11 120.2(7) 2_655 2_655 ?
C1 C23 C24 118.9(7) . . ?
C1 C23 H23 120.6 . . ?
C24 C23 H23 120.6 . . ?
C23 C24 C4 121.6(6) . . ?
C23 C24 H24 119.2 . . ?
C4 C24 H24 119.2 . . ?
N1 C25 C26 114.2(6) . . ?
N1 C25 H25A 108.7 . . ?
C26 C25 H25A 108.7 . . ?
N1 C25 H25B 108.7 . . ?
C26 C25 H25B 108.7 . . ?
H25A C25 H25B 107.6 . . ?
C25 C26 C27 113.1(6) . . ?
C25 C26 H26A 109.0 . . ?
C27 C26 H26A 109.0 . . ?
C25 C26 H26B 109.0 . . ?
C27 C26 H26B 109.0 . . ?
H26A C26 H26B 107.8 . . ?
C28 C27 C26 113.0(6) . . ?
C28 C27 H27A 109.0 . . ?
C26 C27 H27A 109.0 . . ?
C28 C27 H27B 109.0 . . ?
C26 C27 H27B 109.0 . . ?
H27A C27 H27B 107.8 . . ?
C27 C28 C29 114.2(6) . . ?
C27 C28 H28A 108.7 . . ?
C29 C28 H28A 108.7 . . ?
C27 C28 H28B 108.7 . . ?
C29 C28 H28B 108.7 . . ?
H28A C28 H28B 107.6 . . ?
C30 C29 C28 114.1(6) . . ?
C30 C29 H29A 108.7 . . ?
C28 C29 H29A 108.7 . . ?
C30 C29 H29B 108.7 . . ?
C28 C29 H29B 108.7 . . ?
H29A C29 H29B 107.6 . . ?
C31 C30 C29 115.2(6) . . ?
C31 C30 H30A 108.5 . . ?
C29 C30 H30A 108.5 . . ?
C31 C30 H30B 108.5 . . ?
C29 C30 H30B 108.5 . . ?
H30A C30 H30B 107.5 . . ?
C30 C31 C32 111.8(6) . . ?
C30 C31 H31A 109.3 . . ?
C32 C31 H31A 109.3 . . ?
C30 C31 H31B 109.3 . . ?
C32 C31 H31B 109.3 . . ?
H31A C31 H31B 107.9 . . ?
C33 C32 C31 115.4(6) . . ?
C33 C32 H32A 108.4 . . ?
C31 C32 H32A 108.4 . . ?
C33 C32 H32B 108.4 . . ?
C31 C32 H32B 108.4 . . ?
H32A C32 H32B 107.5 . . ?
C34 C33 C32 115.9(6) . . ?
C34 C33 H33A 108.3 . . ?
C32 C33 H33A 108.3 . . ?
C34 C33 H33B 108.3 . . ?
C32 C33 H33B 108.3 . . ?
H33A C33 H33B 107.4 . . ?
C33 C34 C47 114.0(6) . . ?
C33 C34 H34A 108.7 . . ?
C47 C34 H34A 108.7 . . ?
C33 C34 H34B 108.7 . . ?
C47 C34 H34B 108.7 . . ?
H34A C34 H34B 107.6 . . ?
C48 C47 C34 114.0(6) . . ?
C48 C47 H47A 108.8 . . ?
C34 C47 H47A 108.8 . . ?
C48 C47 H47B 108.8 . . ?
C34 C47 H47B 108.8 . . ?
H47A C47 H47B 107.7 . . ?
C47 C48 H48A 109.5 . . ?
C47 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C47 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C23 C1 C2 C3 -0.6(10) . . . . ?
Br1 C1 C2 C3 177.4(5) . . . . ?
C1 C2 C3 C4 1.3(10) . . . . ?
C2 C3 C4 C24 -2.0(9) . . . . ?
C2 C3 C4 C5 -177.9(6) . . . . ?
C3 C4 C5 C8 -159.3(7) . . . . ?
C24 C4 C5 C8 25.0(11) . . . . ?
C3 C4 C5 C6 26.6(10) . . . . ?
C24 C4 C5 C6 -149.2(7) . . . . ?
C7 N1 C6 O1 -176.3(6) . . . . ?
C25 N1 C6 O1 6.8(10) . . . . ?
C7 N1 C6 C5 3.5(7) . . . . ?
C25 N1 C6 C5 -173.4(6) . . . . ?
C8 C5 C6 O1 175.2(7) . . . . ?
C4 C5 C6 O1 -9.5(11) . . . . ?
C8 C5 C6 N1 -4.6(7) . . . . ?
C4 C5 C6 N1 170.7(6) . . . . ?
C6 N1 C7 C11 179.6(7) . . . . ?
C25 N1 C7 C11 -3.9(11) . . . . ?
C6 N1 C7 C8 -1.2(7) . . . . ?
C25 N1 C7 C8 175.3(6) . . . . ?
C4 C5 C8 C9 10.5(13) . . . . ?
C6 C5 C8 C9 -174.6(7) . . . . ?
C4 C5 C8 C7 -171.0(6) . . . . ?
C6 C5 C8 C7 3.9(8) . . . . ?
C11 C7 C8 C5 177.5(6) . . . . ?
N1 C7 C8 C5 -1.8(7) . . . . ?
C11 C7 C8 C9 -3.8(10) . . . . ?
N1 C7 C8 C9 176.9(6) . . . . ?
C5 C8 C9 C10 -177.4(7) . . . . ?
C7 C8 C9 C10 4.2(10) . . . . ?
C8 C9 C10 C11 -1.8(10) . . . 2_655 ?
N1 C7 C11 C10 1.6(11) . . . 2_655 ?
C8 C7 C11 C10 -177.5(6) . . . 2_655 ?
N1 C7 C11 C11 -179.9(7) . . . 2_655 ?
C8 C7 C11 C11 1.0(11) . . . 2_655 ?
C2 C1 C23 C24 0.6(10) . . . . ?
Br1 C1 C23 C24 -177.4(5) . . . . ?
C1 C23 C24 C4 -1.4(10) . . . . ?
C3 C4 C24 C23 2.0(9) . . . . ?
C5 C4 C24 C23 178.0(6) . . . . ?
C7 N1 C25 C26 81.8(9) . . . . ?
C6 N1 C25 C26 -102.0(7) . . . . ?
N1 C25 C26 C27 -173.2(6) . . . . ?
C25 C26 C27 C28 -178.4(6) . . . . ?
C26 C27 C28 C29 -178.2(6) . . . . ?
C27 C28 C29 C30 -71.6(8) . . . . ?
C28 C29 C30 C31 174.8(6) . . . . ?
C29 C30 C31 C32 -171.9(6) . . . . ?
C30 C31 C32 C33 171.6(7) . . . . ?
C31 C32 C33 C34 71.5(9) . . . . ?
C32 C33 C34 C47 -177.3(6) . . . . ?
C33 C34 C47 C48 -178.1(6) . . . . ?

_diffrn_measured_fraction_theta_max 0.925
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.925
_refine_diff_density_max         1.191
_refine_diff_density_min         -0.929
_refine_diff_density_rms         0.118
_database_code_depnum_ccdc_archive 'CCDC 990639'
