# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2014

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#
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#                                CCDC 
# 
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# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
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#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
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data_1

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C28 H52 Cd2 Eu2 N6 O24,4(O)'
_chemical_formula_sum            'C28 H52 Cd2 Eu2 N6 O28'
_chemical_formula_weight         1449.48

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.804(3)
_cell_length_b                   10.912(4)
_cell_length_c                   20.446(6)
_cell_angle_alpha                100.683(12)
_cell_angle_beta                 92.766(9)
_cell_angle_gamma                91.801(11)
_cell_volume                     2145.1(12)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    8910
_cell_measurement_theta_min      5.97
_cell_measurement_theta_max      55.02

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.244
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1416
_exptl_absorpt_coefficient_mu    3.966
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Saturn724 (2x2 bin mode)'
_diffrn_measurement_method       dtprofit.ref
_diffrn_detector_area_resol_mean 28.5714
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            14537
_diffrn_reflns_av_R_equivalents  0.0299
_diffrn_reflns_av_sigmaI/netI    0.0255
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         2.99
_diffrn_reflns_theta_max         25.00
_reflns_number_total             6950
_reflns_number_gt                6255
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'CrystalClear (Rigaku Corp., 2000)'
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2000)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0368P)²+5.4160P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6950
_refine_ls_number_parameters     595
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0315
_refine_ls_R_factor_gt           0.0267
_refine_ls_wR_factor_ref         0.0680
_refine_ls_wR_factor_gt          0.0661
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_restrained_S_all      1.007
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.19500(2) 0.30912(2) 0.857953(9) 0.01661(7) Uani 1 1 d . . .
Eu2 Eu 0.62458(2) 0.29579(2) 0.337863(10) 0.01645(7) Uani 1 1 d . . .
Cd1 Cd 0.36062(3) 0.27256(3) 0.681545(14) 0.01576(8) Uani 1 1 d . . .
Cd2 Cd 0.79760(3) 0.26359(3) 0.163440(14) 0.01584(8) Uani 1 1 d . . .
O1 O 0.5997(3) 0.2160(3) 0.44739(15) 0.0309(8) Uani 1 1 d . . .
O1W O 0.3257(3) 0.1756(3) 0.91962(15) 0.0273(7) Uani 1 1 d . . .
H1WA H 0.3136 0.1961 0.9617 0.041 Uiso 1 1 d R . .
H1WB H 0.2990 0.0986 0.9061 0.041 Uiso 1 1 d R . .
O2 O 0.4814(3) 0.3760(3) 0.43012(15) 0.0276(7) Uani 1 1 d . . .
O2W O -0.0237(3) 0.4027(4) 0.84425(16) 0.0344(8) Uani 1 1 d . . .
H2WA H -0.0522 0.3931 0.8009 0.052 Uiso 1 1 d R . .
H2WB H -0.0901 0.3687 0.8651 0.052 Uiso 1 1 d R . .
O3 O 0.4176(3) 0.4865(3) 0.68685(15) 0.0222(7) Uani 1 1 d . . .
O3W O 0.4481(3) 0.1265(3) 0.32170(16) 0.0272(7) Uani 1 1 d . . .
H3WA H 0.4844 0.0530 0.3237 0.041 Uiso 1 1 d R . .
H3WB H 0.3865 0.1398 0.3530 0.041 Uiso 1 1 d R . .
O4 O 0.5880(3) 0.6269(3) 0.71002(16) 0.0278(7) Uani 1 1 d . . .
O4W O 0.7773(3) 0.4297(4) 0.41939(16) 0.0353(8) Uani 1 1 d . . .
H4WA H 0.8605 0.4139 0.4109 0.053 Uiso 1 1 d R . .
H4WB H 0.7754 0.4526 0.4614 0.053 Uiso 1 1 d R . .
O5 O 0.3665(3) 0.0519(3) 0.67560(15) 0.0242(7) Uani 1 1 d . . .
O5W O 0.1820(6) 0.1394(6) 0.3823(3) 0.0966(19) Uiso 1 1 d . . .
O6 O 0.2314(3) -0.1205(3) 0.66309(15) 0.0247(7) Uani 1 1 d . . .
O6W O 0.2337(4) 0.4911(4) 0.44523(19) 0.0501(11) Uani 1 1 d G . .
H6WA H 0.1648 0.4563 0.4213 0.075 Uiso 1 1 d G . .
H6WB H 0.3111 0.4588 0.4395 0.075 Uiso 1 1 d G . .
O7 O 0.1611(3) 0.3249(3) 0.73729(13) 0.0196(6) Uani 1 1 d . . .
O7W O 0.2611(4) 0.5436(4) 0.0882(2) 0.0487(10) Uani 1 1 d G . .
H7WA H 0.3422 0.5726 0.0868 0.073 Uiso 1 1 d G . .
H7WB H 0.2371 0.4968 0.0511 0.073 Uiso 1 1 d G . .
O8 O -0.0533(3) 0.3736(4) 0.71489(17) 0.0420(10) Uani 1 1 d . . .
O8W O 0.905(3) 0.207(3) 0.4823(14) 0.506(16) Uiso 1 1 d . . .
O9 O 0.4028(3) 0.2621(3) 0.79497(14) 0.0237(7) Uani 1 1 d . . .
O10 O 0.5599(3) 0.2017(4) 0.86393(16) 0.0381(9) Uani 1 1 d . . .
O11 O 0.8397(3) 0.3373(3) 0.28056(14) 0.0206(6) Uani 1 1 d . . .
O12 O 1.0076(3) 0.3790(4) 0.36056(17) 0.0460(11) Uani 1 1 d . . .
O13 O 0.7972(3) 0.0392(3) 0.15228(15) 0.0244(7) Uani 1 1 d . . .
O14 O 0.8872(3) -0.1085(3) 0.20137(14) 0.0246(7) Uani 1 1 d . . .
O15 O 1.1336(3) 0.3950(3) -0.02753(15) 0.0287(7) Uani 1 1 d . . .
O16 O 1.0316(3) 0.2145(3) -0.07136(15) 0.0305(8) Uani 1 1 d . . .
O17 O 0.4026(3) 0.1022(4) 0.19353(16) 0.0337(8) Uani 1 1 d . . .
O18 O 0.5976(3) 0.2178(3) 0.21503(14) 0.0217(7) Uani 1 1 d . . .
O19 O 0.7415(3) 0.4622(3) 0.14016(15) 0.0233(7) Uani 1 1 d . . .
O20 O 0.5995(3) 0.5607(3) 0.08319(16) 0.0301(7) Uani 1 1 d . . .
N1 N 0.4545(3) 0.2152(3) 0.57102(16) 0.0177(7) Uani 1 1 d . . .
N2 N 0.1720(3) 0.1779(3) 0.61241(16) 0.0173(7) Uani 1 1 d . . .
N3 N 0.5984(3) 0.2949(3) 0.70650(16) 0.0174(7) Uani 1 1 d . . .
N4 N 0.9077(4) 0.2113(3) 0.05697(17) 0.0198(8) Uani 1 1 d . . .
N5 N 0.6107(3) 0.2332(3) 0.08230(16) 0.0184(7) Uani 1 1 d . . .
N6 N 1.0187(3) 0.2064(3) 0.19498(16) 0.0176(7) Uani 1 1 d . . .
C1 C 0.4662(4) 0.3221(4) 0.5369(2) 0.0199(9) Uani 1 1 d . . .
H1A H 0.5259 0.3855 0.5647 0.024 Uiso 1 1 calc R . .
H1B H 0.3766 0.3567 0.5344 0.024 Uiso 1 1 calc R . .
C2 C 0.5192(4) 0.2994(4) 0.4670(2) 0.0225(10) Uani 1 1 d . . .
C3 C 0.5885(4) 0.1653(4) 0.5900(2) 0.0206(9) Uani 1 1 d . . .
H3A H 0.6415 0.1464 0.5507 0.025 Uiso 1 1 calc R . .
H3B H 0.5718 0.0882 0.6060 0.025 Uiso 1 1 calc R . .
C4 C 0.3578(4) 0.1171(4) 0.5333(2) 0.0206(9) Uani 1 1 d . . .
H4A H 0.3709 0.0395 0.5490 0.025 Uiso 1 1 calc R . .
H4B H 0.3767 0.1034 0.4864 0.025 Uiso 1 1 calc R . .
C5 C 0.2098(4) 0.1543(5) 0.5415(2) 0.0226(10) Uani 1 1 d . . .
H5A H 0.1959 0.2292 0.5232 0.027 Uiso 1 1 calc R . .
H5B H 0.1495 0.0884 0.5162 0.027 Uiso 1 1 calc R . .
C6 C 0.6707(4) 0.2574(5) 0.6436(2) 0.0242(10) Uani 1 1 d . . .
H6A H 0.7557 0.2204 0.6540 0.029 Uiso 1 1 calc R . .
H6B H 0.6932 0.3316 0.6259 0.029 Uiso 1 1 calc R . .
C7 C 0.6278(4) 0.2160(4) 0.7559(2) 0.0201(9) Uani 1 1 d . . .
H7A H 0.7180 0.2392 0.7769 0.024 Uiso 1 1 calc R . .
H7B H 0.6285 0.1297 0.7332 0.024 Uiso 1 1 calc R . .
C8 C 0.5231(4) 0.2274(4) 0.8098(2) 0.0214(9) Uani 1 1 d . . .
C9 C 0.6298(4) 0.4281(4) 0.7367(2) 0.0236(10) Uani 1 1 d . . .
H9A H 0.7245 0.4482 0.7298 0.028 Uiso 1 1 calc R . .
H9B H 0.6197 0.4391 0.7843 0.028 Uiso 1 1 calc R . .
C10 C 0.5401(4) 0.5193(4) 0.70872(19) 0.0185(9) Uani 1 1 d . . .
C11 C 0.1336(4) 0.0606(4) 0.6349(2) 0.0210(9) Uani 1 1 d . . .
H11A H 0.0844 0.0050 0.5982 0.025 Uiso 1 1 calc R . .
H11B H 0.0717 0.0797 0.6707 0.025 Uiso 1 1 calc R . .
C12 C 0.2542(4) -0.0080(4) 0.65947(19) 0.0193(9) Uani 1 1 d . . .
C13 C 0.0632(4) 0.2686(5) 0.6244(2) 0.0245(10) Uani 1 1 d . . .
H13A H -0.0240 0.2270 0.6079 0.029 Uiso 1 1 calc R . .
H13B H 0.0797 0.3345 0.5994 0.029 Uiso 1 1 calc R . .
C14 C 0.0551(4) 0.3263(4) 0.6980(2) 0.0219(9) Uani 1 1 d . . .
C15 C 0.7986(4) 0.1365(4) 0.0127(2) 0.0227(10) Uani 1 1 d . . .
H15A H 0.7862 0.0563 0.0261 0.027 Uiso 1 1 calc R . .
H15B H 0.8277 0.1212 -0.0327 0.027 Uiso 1 1 calc R . .
C16 C 0.6625(4) 0.1998(5) 0.0143(2) 0.0244(10) Uani 1 1 d . . .
H16A H 0.6726 0.2751 -0.0041 0.029 Uiso 1 1 calc R . .
H16B H 0.5953 0.1447 -0.0140 0.029 Uiso 1 1 calc R . .
C17 C 1.0253(4) 0.1365(4) 0.0718(2) 0.0226(9) Uani 1 1 d . . .
H17A H 1.0858 0.1278 0.0352 0.027 Uiso 1 1 calc R . .
H17B H 0.9922 0.0536 0.0758 0.027 Uiso 1 1 calc R . .
C18 C 1.1049(4) 0.1973(5) 0.1361(2) 0.0247(10) Uani 1 1 d . . .
H18A H 1.1837 0.1486 0.1430 0.030 Uiso 1 1 calc R . .
H18B H 1.1377 0.2802 0.1322 0.030 Uiso 1 1 calc R . .
C19 C 0.9561(4) 0.3251(4) 0.0341(2) 0.0218(9) Uani 1 1 d . . .
H19A H 1.0062 0.3784 0.0714 0.026 Uiso 1 1 calc R . .
H19B H 0.8766 0.3693 0.0230 0.026 Uiso 1 1 calc R . .
C20 C 1.0465(4) 0.3085(4) -0.0253(2) 0.0231(10) Uani 1 1 d . . .
C21 C 0.5215(4) 0.1355(4) 0.1001(2) 0.0201(9) Uani 1 1 d . . .
H21A H 0.5595 0.0548 0.0849 0.024 Uiso 1 1 calc R . .
H21B H 0.4324 0.1357 0.0774 0.024 Uiso 1 1 calc R . .
C22 C 0.5045(4) 0.1533(4) 0.1754(2) 0.0204(9) Uani 1 1 d . . .
C23 C 0.5359(4) 0.3505(4) 0.0882(2) 0.0245(10) Uani 1 1 d . . .
H23A H 0.4719 0.3535 0.1232 0.029 Uiso 1 1 calc R . .
H23B H 0.4838 0.3510 0.0467 0.029 Uiso 1 1 calc R . .
C24 C 0.6319(4) 0.4649(4) 0.1040(2) 0.0199(9) Uani 1 1 d . . .
C25 C 1.0078(4) 0.0863(4) 0.2192(2) 0.0239(10) Uani 1 1 d . . .
H25A H 0.9998 0.1044 0.2671 0.029 Uiso 1 1 calc R . .
H25B H 1.0919 0.0430 0.2106 0.029 Uiso 1 1 calc R . .
C26 C 0.8879(4) -0.0008(4) 0.1877(2) 0.0187(9) Uani 1 1 d . . .
C27 C 1.0717(4) 0.3072(4) 0.2501(2) 0.0230(10) Uani 1 1 d . . .
H27A H 1.0984 0.3799 0.2319 0.028 Uiso 1 1 calc R . .
H27B H 1.1523 0.2796 0.2716 0.028 Uiso 1 1 calc R . .
C28 C 0.9657(4) 0.3435(4) 0.3016(2) 0.0218(9) Uani 1 1 d . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O14 2.392(3) 2_656 ?
Eu1 O2W 2.430(3) . ?
Eu1 O1W 2.449(3) . ?
Eu1 O15 2.466(3) 1_456 ?
Eu1 O9 2.479(3) . ?
Eu1 O7 2.512(3) . ?
Eu1 O16 2.529(3) 1_456 ?
Eu1 O19 2.545(3) 2_666 ?
Eu1 O20 2.545(3) 2_666 ?
Eu1 C20 2.857(4) 1_456 ?
Eu1 C24 2.910(5) 2_666 ?
Eu1 Cd1 3.9847(11) . ?
Eu2 O6 2.410(3) 2_656 ?
Eu2 O4W 2.424(3) . ?
Eu2 O2 2.453(3) . ?
Eu2 O3W 2.456(3) . ?
Eu2 O4 2.496(3) 2_666 ?
Eu2 O18 2.496(3) . ?
Eu2 O11 2.530(3) . ?
Eu2 O3 2.560(3) 2_666 ?
Eu2 O1 2.568(3) . ?
Eu2 C2 2.875(4) . ?
Eu2 C10 2.890(4) 2_666 ?
Eu2 Cd2 3.9844(11) . ?
Cd1 O7 2.344(3) . ?
Cd1 N3 2.358(3) . ?
Cd1 O9 2.360(3) . ?
Cd1 N2 2.360(4) . ?
Cd1 O3 2.365(3) . ?
Cd1 O5 2.391(3) . ?
Cd1 N1 2.461(3) . ?
Cd2 O18 2.354(3) . ?
Cd2 N6 2.367(3) . ?
Cd2 O19 2.379(3) . ?
Cd2 N5 2.384(3) . ?
Cd2 O11 2.392(3) . ?
Cd2 O13 2.417(3) . ?
Cd2 N4 2.456(3) . ?
O1 C2 1.246(5) . ?
O1W H1WA 0.8625 . ?
O1W H1WB 0.8624 . ?
O2 C2 1.277(5) . ?
O2W H2WA 0.9019 . ?
O2W H2WB 0.9026 . ?
O3 C10 1.278(5) . ?
O3 Eu2 2.560(3) 2_666 ?
O3W H3WA 0.8953 . ?
O3W H3WB 0.8964 . ?
O4 C10 1.246(6) . ?
O4 Eu2 2.496(3) 2_666 ?
O4W H4WA 0.8581 . ?
O4W H4WB 0.8508 . ?
O5 C12 1.260(5) . ?
O6 C12 1.257(5) . ?
O6 Eu2 2.410(3) 2_656 ?
O6W H6WA 0.8501 . ?
O6W H6WB 0.8504 . ?
O7 C14 1.284(5) . ?
O7W H7WA 0.8501 . ?
O7W H7WB 0.8500 . ?
O8 C14 1.232(5) . ?
O9 C8 1.290(5) . ?
O10 C8 1.231(5) . ?
O11 C28 1.285(5) . ?
O12 C28 1.241(5) . ?
O13 C26 1.259(5) . ?
O14 C26 1.258(5) . ?
O14 Eu1 2.392(3) 2_656 ?
O15 C20 1.261(6) . ?
O15 Eu1 2.466(3) 1_654 ?
O16 C20 1.257(6) . ?
O16 Eu1 2.529(3) 1_654 ?
O17 C22 1.235(5) . ?
O18 C22 1.289(5) . ?
O19 C24 1.280(5) . ?
O19 Eu1 2.545(3) 2_666 ?
O20 C24 1.244(5) . ?
O20 Eu1 2.545(3) 2_666 ?
N1 C1 1.470(5) . ?
N1 C4 1.483(6) . ?
N1 C3 1.499(5) . ?
N2 C13 1.476(5) . ?
N2 C11 1.482(6) . ?
N2 C5 1.491(5) . ?
N3 C7 1.467(5) . ?
N3 C9 1.485(6) . ?
N3 C6 1.495(5) . ?
N4 C19 1.477(6) . ?
N4 C15 1.486(6) . ?
N4 C17 1.486(5) . ?
N5 C21 1.467(5) . ?
N5 C23 1.484(5) . ?
N5 C16 1.488(5) . ?
N6 C27 1.481(5) . ?
N6 C25 1.487(6) . ?
N6 C18 1.493(5) . ?
C1 C2 1.525(5) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C3 C6 1.521(6) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C4 C5 1.528(6) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.534(6) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C9 C10 1.519(6) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 Eu2 2.890(4) 2_666 ?
C11 C12 1.532(6) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C13 C14 1.528(6) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C15 C16 1.521(6) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C17 C18 1.524(6) . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C19 C20 1.525(6) . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C20 Eu1 2.857(4) 1_654 ?
C21 C22 1.533(6) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C23 C24 1.516(6) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C24 Eu1 2.910(5) 2_666 ?
C25 C26 1.527(6) . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C27 C28 1.525(6) . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O14 Eu1 O2W 93.05(12) 2_656 . ?
O14 Eu1 O1W 80.31(11) 2_656 . ?
O2W Eu1 O1W 145.33(11) . . ?
O14 Eu1 O15 122.92(11) 2_656 1_456 ?
O2W Eu1 O15 75.36(11) . 1_456 ?
O1W Eu1 O15 79.93(11) . 1_456 ?
O14 Eu1 O9 84.18(11) 2_656 . ?
O2W Eu1 O9 138.61(10) . . ?
O1W Eu1 O9 74.96(10) . . ?
O15 Eu1 O9 139.01(10) 1_456 . ?
O14 Eu1 O7 72.71(10) 2_656 . ?
O2W Eu1 O7 72.67(10) . . ?
O1W Eu1 O7 134.93(10) . . ?
O15 Eu1 O7 145.14(10) 1_456 . ?
O9 Eu1 O7 67.09(9) . . ?
O14 Eu1 O16 70.90(10) 2_656 1_456 ?
O2W Eu1 O16 73.38(12) . 1_456 ?
O1W Eu1 O16 72.29(11) . 1_456 ?
O15 Eu1 O16 52.11(11) 1_456 1_456 ?
O9 Eu1 O16 141.49(11) . 1_456 ?
O7 Eu1 O16 127.88(10) . 1_456 ?
O14 Eu1 O19 150.31(10) 2_656 2_666 ?
O2W Eu1 O19 76.11(11) . 2_666 ?
O1W Eu1 O19 123.87(10) . 2_666 ?
O15 Eu1 O19 81.55(10) 1_456 2_666 ?
O9 Eu1 O19 86.16(10) . 2_666 ?
O7 Eu1 O19 77.66(10) . 2_666 ?
O16 Eu1 O19 129.27(10) 1_456 2_666 ?
O14 Eu1 O20 145.97(11) 2_656 2_666 ?
O2W Eu1 O20 120.93(12) . 2_666 ?
O1W Eu1 O20 72.63(11) . 2_666 ?
O15 Eu1 O20 72.53(11) 1_456 2_666 ?
O9 Eu1 O20 69.33(11) . 2_666 ?
O7 Eu1 O20 113.21(10) . 2_666 ?
O16 Eu1 O20 117.94(11) 1_456 2_666 ?
O19 Eu1 O20 51.28(10) 2_666 2_666 ?
O14 Eu1 C20 97.00(12) 2_656 1_456 ?
O2W Eu1 C20 70.95(12) . 1_456 ?
O1W Eu1 C20 76.13(12) . 1_456 ?
O15 Eu1 C20 26.10(12) 1_456 1_456 ?
O9 Eu1 C20 150.43(11) . 1_456 ?
O7 Eu1 C20 141.50(11) . 1_456 ?
O16 Eu1 C20 26.10(12) 1_456 1_456 ?
O19 Eu1 C20 105.07(12) 2_666 1_456 ?
O20 Eu1 C20 96.14(12) 2_666 1_456 ?
O14 Eu1 C24 159.78(10) 2_656 2_666 ?
O2W Eu1 C24 99.31(13) . 2_666 ?
O1W Eu1 C24 97.87(12) . 2_666 ?
O15 Eu1 C24 76.02(11) 1_456 2_666 ?
O9 Eu1 C24 75.96(11) . 2_666 ?
O7 Eu1 C24 95.70(11) . 2_666 ?
O16 Eu1 C24 128.01(11) 1_456 2_666 ?
O19 Eu1 C24 26.05(11) 2_666 2_666 ?
O20 Eu1 C24 25.24(11) 2_666 2_666 ?
C20 Eu1 C24 102.12(13) 1_456 2_666 ?
O14 Eu1 Cd1 75.15(7) 2_656 . ?
O2W Eu1 Cd1 105.86(8) . . ?
O1W Eu1 Cd1 105.17(7) . . ?
O15 Eu1 Cd1 161.93(8) 1_456 . ?
O9 Eu1 Cd1 33.61(7) . . ?
O7 Eu1 Cd1 33.50(6) . . ?
O16 Eu1 Cd1 145.92(7) 1_456 . ?
O19 Eu1 Cd1 81.31(7) 2_666 . ?
O20 Eu1 Cd1 92.19(8) 2_666 . ?
C20 Eu1 Cd1 171.54(10) 1_456 . ?
C24 Eu1 Cd1 86.05(8) 2_666 . ?
O6 Eu2 O4W 91.99(12) 2_656 . ?
O6 Eu2 O2 123.62(10) 2_656 . ?
O4W Eu2 O2 74.99(11) . . ?
O6 Eu2 O3W 80.57(11) 2_656 . ?
O4W Eu2 O3W 144.58(11) . . ?
O2 Eu2 O3W 80.54(11) . . ?
O6 Eu2 O4 145.82(11) 2_656 2_666 ?
O4W Eu2 O4 122.18(12) . 2_666 ?
O2 Eu2 O4 71.94(11) . 2_666 ?
O3W Eu2 O4 71.96(11) . 2_666 ?
O6 Eu2 O18 84.26(10) 2_656 . ?
O4W Eu2 O18 139.89(10) . . ?
O2 Eu2 O18 138.46(10) . . ?
O3W Eu2 O18 74.19(10) . . ?
O4 Eu2 O18 69.16(10) 2_666 . ?
O6 Eu2 O11 71.77(10) 2_656 . ?
O4W Eu2 O11 72.52(10) . . ?
O2 Eu2 O11 144.49(11) . . ?
O3W Eu2 O11 134.95(10) . . ?
O4 Eu2 O11 114.75(10) 2_666 . ?
O18 Eu2 O11 68.38(9) . . ?
O6 Eu2 O3 150.74(10) 2_656 2_666 ?
O4W Eu2 O3 77.07(11) . 2_666 ?
O2 Eu2 O3 80.12(10) . 2_666 ?
O3W Eu2 O3 123.55(10) . 2_666 ?
O4 Eu2 O3 51.65(10) 2_666 2_666 ?
O18 Eu2 O3 86.99(10) . 2_666 ?
O11 Eu2 O3 79.04(9) . 2_666 ?
O6 Eu2 O1 71.74(10) 2_656 . ?
O4W Eu2 O1 74.45(12) . . ?
O2 Eu2 O1 51.88(10) . . ?
O3W Eu2 O1 70.31(11) . . ?
O4 Eu2 O1 115.53(11) 2_666 . ?
O18 Eu2 O1 139.66(11) . . ?
O11 Eu2 O1 129.02(10) . . ?
O3 Eu2 O1 128.81(10) 2_666 . ?
O6 Eu2 C2 97.41(12) 2_656 . ?
O4W Eu2 C2 72.27(12) . . ?
O2 Eu2 C2 26.23(11) . . ?
O3W Eu2 C2 74.43(12) . . ?
O4 Eu2 C2 94.45(12) 2_666 . ?
O18 Eu2 C2 147.84(11) . . ?
O11 Eu2 C2 142.65(11) . . ?
O3 Eu2 C2 104.69(11) 2_666 . ?
O1 Eu2 C2 25.67(12) . . ?
O6 Eu2 C10 160.66(11) 2_656 2_666 ?
O4W Eu2 C10 100.25(13) . 2_666 ?
O2 Eu2 C10 74.45(10) . 2_666 ?
O3W Eu2 C10 97.35(12) . 2_666 ?
O4 Eu2 C10 25.42(11) 2_666 2_666 ?
O18 Eu2 C10 76.72(11) . 2_666 ?
O11 Eu2 C10 97.56(11) . 2_666 ?
O3 Eu2 C10 26.23(11) 2_666 2_666 ?
O1 Eu2 C10 125.90(10) . 2_666 ?
C2 Eu2 C10 100.55(12) . 2_666 ?
O6 Eu2 Cd2 76.56(7) 2_656 . ?
O4W Eu2 Cd2 106.75(8) . . ?
O2 Eu2 Cd2 159.82(7) . . ?
O3W Eu2 Cd2 105.06(7) . . ?
O4 Eu2 Cd2 91.11(8) 2_666 . ?
O18 Eu2 Cd2 33.60(7) . . ?
O11 Eu2 Cd2 34.80(6) . . ?
O3 Eu2 Cd2 80.74(7) 2_666 . ?
O1 Eu2 Cd2 148.30(7) . . ?
C2 Eu2 Cd2 173.91(9) . . ?
C10 Eu2 Cd2 85.54(8) 2_666 . ?
O7 Cd1 N3 137.14(11) . . ?
O7 Cd1 O9 71.78(10) . . ?
N3 Cd1 O9 71.58(11) . . ?
O7 Cd1 N2 71.87(11) . . ?
N3 Cd1 N2 150.19(11) . . ?
O9 Cd1 N2 125.92(11) . . ?
O7 Cd1 O3 90.27(10) . . ?
N3 Cd1 O3 74.39(11) . . ?
O9 Cd1 O3 99.05(11) . . ?
N2 Cd1 O3 119.68(11) . . ?
O7 Cd1 O5 103.08(11) . . ?
N3 Cd1 O5 90.97(11) . . ?
O9 Cd1 O5 79.00(11) . . ?
N2 Cd1 O5 71.89(11) . . ?
O3 Cd1 O5 164.96(10) . . ?
O7 Cd1 N1 144.21(11) . . ?
N3 Cd1 N1 77.35(11) . . ?
O9 Cd1 N1 142.60(11) . . ?
N2 Cd1 N1 76.09(11) . . ?
O3 Cd1 N1 91.98(11) . . ?
O5 Cd1 N1 81.27(11) . . ?
O7 Cd1 Eu1 36.26(7) . . ?
N3 Cd1 Eu1 105.00(8) . . ?
O9 Cd1 Eu1 35.55(7) . . ?
N2 Cd1 Eu1 99.37(8) . . ?
O3 Cd1 Eu1 96.89(7) . . ?
O5 Cd1 Eu1 90.10(7) . . ?
N1 Cd1 Eu1 171.13(9) . . ?
O18 Cd2 N6 124.19(11) . . ?
O18 Cd2 O19 98.90(10) . . ?
N6 Cd2 O19 125.33(11) . . ?
O18 Cd2 N5 71.22(11) . . ?
N6 Cd2 N5 147.69(11) . . ?
O19 Cd2 N5 72.05(11) . . ?
O18 Cd2 O11 73.05(10) . . ?
N6 Cd2 O11 71.39(10) . . ?
O19 Cd2 O11 94.58(11) . . ?
N5 Cd2 O11 139.03(10) . . ?
O18 Cd2 O13 77.05(10) . . ?
N6 Cd2 O13 71.36(11) . . ?
O19 Cd2 O13 159.06(10) . . ?
N5 Cd2 O13 87.32(11) . . ?
O11 Cd2 O13 103.61(11) . . ?
O18 Cd2 N4 141.06(11) . . ?
N6 Cd2 N4 76.45(12) . . ?
O19 Cd2 N4 90.84(11) . . ?
N5 Cd2 N4 76.31(12) . . ?
O11 Cd2 N4 143.94(11) . . ?
O13 Cd2 N4 80.59(11) . . ?
O18 Cd2 Eu2 35.94(7) . . ?
N6 Cd2 Eu2 99.79(8) . . ?
O19 Cd2 Eu2 97.44(7) . . ?
N5 Cd2 Eu2 104.73(8) . . ?
O11 Cd2 Eu2 37.13(7) . . ?
O13 Cd2 Eu2 91.08(7) . . ?
N4 Cd2 Eu2 171.58(9) . . ?
C2 O1 Eu2 91.1(3) . . ?
Eu1 O1W H1WA 110.1 . . ?
Eu1 O1W H1WB 109.8 . . ?
H1WA O1W H1WB 109.0 . . ?
C2 O2 Eu2 95.7(2) . . ?
Eu1 O2W H2WA 111.7 . . ?
Eu1 O2W H2WB 112.2 . . ?
H2WA O2W H2WB 107.0 . . ?
C10 O3 Cd1 114.3(3) . . ?
C10 O3 Eu2 91.4(3) . 2_666 ?
Cd1 O3 Eu2 153.85(13) . 2_666 ?
Eu2 O3W H3WA 111.4 . . ?
Eu2 O3W H3WB 111.6 . . ?
H3WA O3W H3WB 107.3 . . ?
C10 O4 Eu2 95.3(3) . 2_666 ?
Eu2 O4W H4WA 109.6 . . ?
Eu2 O4W H4WB 132.3 . . ?
H4WA O4W H4WB 107.0 . . ?
C12 O5 Cd1 115.6(3) . . ?
C12 O6 Eu2 133.6(3) . 2_656 ?
H6WA O6W H6WB 118.6 . . ?
C14 O7 Cd1 113.7(2) . . ?
C14 O7 Eu1 133.7(3) . . ?
Cd1 O7 Eu1 110.23(11) . . ?
H7WA O7W H7WB 109.5 . . ?
C8 O9 Cd1 114.8(2) . . ?
C8 O9 Eu1 134.3(3) . . ?
Cd1 O9 Eu1 110.85(11) . . ?
C28 O11 Cd2 115.4(2) . . ?
C28 O11 Eu2 130.6(3) . . ?
Cd2 O11 Eu2 108.07(11) . . ?
C26 O13 Cd2 115.1(3) . . ?
C26 O14 Eu1 133.5(3) . 2_656 ?
C20 O15 Eu1 94.5(3) . 1_654 ?
C20 O16 Eu1 91.7(3) . 1_654 ?
C22 O18 Cd2 114.6(2) . . ?
C22 O18 Eu2 134.8(3) . . ?
Cd2 O18 Eu2 110.46(11) . . ?
C24 O19 Cd2 116.0(3) . . ?
C24 O19 Eu1 93.1(3) . 2_666 ?
Cd2 O19 Eu1 150.46(13) . 2_666 ?
C24 O20 Eu1 94.0(3) . 2_666 ?
C1 N1 C4 111.0(3) . . ?
C1 N1 C3 114.4(3) . . ?
C4 N1 C3 113.0(3) . . ?
C1 N1 Cd1 112.3(2) . . ?
C4 N1 Cd1 105.0(2) . . ?
C3 N1 Cd1 100.3(2) . . ?
C13 N2 C11 110.9(3) . . ?
C13 N2 C5 112.0(3) . . ?
C11 N2 C5 111.8(3) . . ?
C13 N2 Cd1 104.7(3) . . ?
C11 N2 Cd1 107.5(2) . . ?
C5 N2 Cd1 109.5(2) . . ?
C7 N3 C9 109.9(3) . . ?
C7 N3 C6 113.2(3) . . ?
C9 N3 C6 111.3(3) . . ?
C7 N3 Cd1 106.0(2) . . ?
C9 N3 Cd1 107.2(2) . . ?
C6 N3 Cd1 108.9(2) . . ?
C19 N4 C15 114.5(3) . . ?
C19 N4 C17 110.3(3) . . ?
C15 N4 C17 113.1(4) . . ?
C19 N4 Cd2 111.2(2) . . ?
C15 N4 Cd2 102.6(2) . . ?
C17 N4 Cd2 104.4(2) . . ?
C21 N5 C23 109.1(3) . . ?
C21 N5 C16 113.6(3) . . ?
C23 N5 C16 109.8(3) . . ?
C21 N5 Cd2 105.6(2) . . ?
C23 N5 Cd2 108.8(2) . . ?
C16 N5 Cd2 109.8(2) . . ?
C27 N6 C25 109.8(3) . . ?
C27 N6 C18 111.3(3) . . ?
C25 N6 C18 111.9(3) . . ?
C27 N6 Cd2 106.0(2) . . ?
C25 N6 Cd2 109.2(2) . . ?
C18 N6 Cd2 108.4(2) . . ?
N1 C1 C2 118.0(3) . . ?
N1 C1 H1A 107.8 . . ?
C2 C1 H1A 107.8 . . ?
N1 C1 H1B 107.8 . . ?
C2 C1 H1B 107.8 . . ?
H1A C1 H1B 107.1 . . ?
O1 C2 O2 121.3(4) . . ?
O1 C2 C1 123.0(4) . . ?
O2 C2 C1 115.6(4) . . ?
O1 C2 Eu2 63.3(2) . . ?
O2 C2 Eu2 58.1(2) . . ?
C1 C2 Eu2 171.6(3) . . ?
N1 C3 C6 112.2(3) . . ?
N1 C3 H3A 109.2 . . ?
C6 C3 H3A 109.2 . . ?
N1 C3 H3B 109.2 . . ?
C6 C3 H3B 109.2 . . ?
H3A C3 H3B 107.9 . . ?
N1 C4 C5 111.2(3) . . ?
N1 C4 H4A 109.4 . . ?
C5 C4 H4A 109.4 . . ?
N1 C4 H4B 109.4 . . ?
C5 C4 H4B 109.4 . . ?
H4A C4 H4B 108.0 . . ?
N2 C5 C4 113.0(3) . . ?
N2 C5 H5A 109.0 . . ?
C4 C5 H5A 109.0 . . ?
N2 C5 H5B 109.0 . . ?
C4 C5 H5B 109.0 . . ?
H5A C5 H5B 107.8 . . ?
N3 C6 C3 114.1(3) . . ?
N3 C6 H6A 108.7 . . ?
C3 C6 H6A 108.7 . . ?
N3 C6 H6B 108.7 . . ?
C3 C6 H6B 108.7 . . ?
H6A C6 H6B 107.6 . . ?
N3 C7 C8 112.7(3) . . ?
N3 C7 H7A 109.0 . . ?
C8 C7 H7A 109.0 . . ?
N3 C7 H7B 109.0 . . ?
C8 C7 H7B 109.0 . . ?
H7A C7 H7B 107.8 . . ?
O10 C8 O9 124.9(4) . . ?
O10 C8 C7 117.5(4) . . ?
O9 C8 C7 117.6(4) . . ?
N3 C9 C10 114.3(3) . . ?
N3 C9 H9A 108.7 . . ?
C10 C9 H9A 108.7 . . ?
N3 C9 H9B 108.7 . . ?
C10 C9 H9B 108.7 . . ?
H9A C9 H9B 107.6 . . ?
O4 C10 O3 121.6(4) . . ?
O4 C10 C9 118.2(4) . . ?
O3 C10 C9 120.1(4) . . ?
O4 C10 Eu2 59.3(2) . 2_666 ?
O3 C10 Eu2 62.3(2) . 2_666 ?
C9 C10 Eu2 176.6(3) . 2_666 ?
N2 C11 C12 114.7(3) . . ?
N2 C11 H11A 108.6 . . ?
C12 C11 H11A 108.6 . . ?
N2 C11 H11B 108.6 . . ?
C12 C11 H11B 108.6 . . ?
H11A C11 H11B 107.6 . . ?
O6 C12 O5 125.1(4) . . ?
O6 C12 C11 116.5(4) . . ?
O5 C12 C11 118.4(4) . . ?
N2 C13 C14 112.8(3) . . ?
N2 C13 H13A 109.0 . . ?
C14 C13 H13A 109.0 . . ?
N2 C13 H13B 109.0 . . ?
C14 C13 H13B 109.0 . . ?
H13A C13 H13B 107.8 . . ?
O8 C14 O7 124.9(4) . . ?
O8 C14 C13 116.6(4) . . ?
O7 C14 C13 118.4(4) . . ?
N4 C15 C16 113.1(4) . . ?
N4 C15 H15A 109.0 . . ?
C16 C15 H15A 109.0 . . ?
N4 C15 H15B 109.0 . . ?
C16 C15 H15B 109.0 . . ?
H15A C15 H15B 107.8 . . ?
N5 C16 C15 113.7(3) . . ?
N5 C16 H16A 108.8 . . ?
C15 C16 H16A 108.8 . . ?
N5 C16 H16B 108.8 . . ?
C15 C16 H16B 108.8 . . ?
H16A C16 H16B 107.7 . . ?
N4 C17 C18 111.5(3) . . ?
N4 C17 H17A 109.3 . . ?
C18 C17 H17A 109.3 . . ?
N4 C17 H17B 109.3 . . ?
C18 C17 H17B 109.3 . . ?
H17A C17 H17B 108.0 . . ?
N6 C18 C17 111.7(3) . . ?
N6 C18 H18A 109.3 . . ?
C17 C18 H18A 109.3 . . ?
N6 C18 H18B 109.3 . . ?
C17 C18 H18B 109.3 . . ?
H18A C18 H18B 107.9 . . ?
N4 C19 C20 117.6(3) . . ?
N4 C19 H19A 107.9 . . ?
C20 C19 H19A 107.9 . . ?
N4 C19 H19B 107.9 . . ?
C20 C19 H19B 107.9 . . ?
H19A C19 H19B 107.2 . . ?
O16 C20 O15 121.3(4) . . ?
O16 C20 C19 121.3(4) . . ?
O15 C20 C19 117.3(4) . . ?
O16 C20 Eu1 62.2(2) . 1_654 ?
O15 C20 Eu1 59.4(2) . 1_654 ?
C19 C20 Eu1 171.2(3) . 1_654 ?
N5 C21 C22 112.4(3) . . ?
N5 C21 H21A 109.1 . . ?
C22 C21 H21A 109.1 . . ?
N5 C21 H21B 109.1 . . ?
C22 C21 H21B 109.1 . . ?
H21A C21 H21B 107.9 . . ?
O17 C22 O18 124.8(4) . . ?
O17 C22 C21 116.8(4) . . ?
O18 C22 C21 118.4(4) . . ?
N5 C23 C24 111.9(3) . . ?
N5 C23 H23A 109.2 . . ?
C24 C23 H23A 109.2 . . ?
N5 C23 H23B 109.2 . . ?
C24 C23 H23B 109.2 . . ?
H23A C23 H23B 107.9 . . ?
O20 C24 O19 121.6(4) . . ?
O20 C24 C23 118.9(4) . . ?
O19 C24 C23 119.4(4) . . ?
O20 C24 Eu1 60.7(2) . 2_666 ?
O19 C24 Eu1 60.9(2) . 2_666 ?
C23 C24 Eu1 176.0(3) . 2_666 ?
N6 C25 C26 114.9(4) . . ?
N6 C25 H25A 108.5 . . ?
C26 C25 H25A 108.5 . . ?
N6 C25 H25B 108.5 . . ?
C26 C25 H25B 108.5 . . ?
H25A C25 H25B 107.5 . . ?
O14 C26 O13 125.1(4) . . ?
O14 C26 C25 115.5(4) . . ?
O13 C26 C25 119.3(4) . . ?
N6 C27 C28 112.0(3) . . ?
N6 C27 H27A 109.2 . . ?
C28 C27 H27A 109.2 . . ?
N6 C27 H27B 109.2 . . ?
C28 C27 H27B 109.2 . . ?
H27A C27 H27B 107.9 . . ?
O12 C28 O11 124.8(4) . . ?
O12 C28 C27 117.8(4) . . ?
O11 C28 C27 117.4(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O14 Eu1 Cd1 O7 80.99(15) 2_656 . . . ?
O2W Eu1 Cd1 O7 -7.97(16) . . . . ?
O1W Eu1 Cd1 O7 156.37(15) . . . . ?
O15 Eu1 Cd1 O7 -99.4(3) 1_456 . . . ?
O9 Eu1 Cd1 O7 -176.94(19) . . . . ?
O16 Eu1 Cd1 O7 75.7(2) 1_456 . . . ?
O19 Eu1 Cd1 O7 -80.76(15) 2_666 . . . ?
O20 Eu1 Cd1 O7 -131.04(15) 2_666 . . . ?
C20 Eu1 Cd1 O7 58.7(6) 1_456 . . . ?
C24 Eu1 Cd1 O7 -106.54(15) 2_666 . . . ?
O14 Eu1 Cd1 N3 -122.40(12) 2_656 . . . ?
O2W Eu1 Cd1 N3 148.64(13) . . . . ?
O1W Eu1 Cd1 N3 -47.02(12) . . . . ?
O15 Eu1 Cd1 N3 57.3(3) 1_456 . . . ?
O9 Eu1 Cd1 N3 -20.33(17) . . . . ?
O7 Eu1 Cd1 N3 156.61(16) . . . . ?
O16 Eu1 Cd1 N3 -127.71(17) 1_456 . . . ?
O19 Eu1 Cd1 N3 75.85(11) 2_666 . . . ?
O20 Eu1 Cd1 N3 25.57(12) 2_666 . . . ?
C20 Eu1 Cd1 N3 -144.7(6) 1_456 . . . ?
C24 Eu1 Cd1 N3 50.07(12) 2_666 . . . ?
O14 Eu1 Cd1 O9 -102.08(16) 2_656 . . . ?
O2W Eu1 Cd1 O9 168.96(17) . . . . ?
O1W Eu1 Cd1 O9 -26.69(16) . . . . ?
O15 Eu1 Cd1 O9 77.6(3) 1_456 . . . ?
O7 Eu1 Cd1 O9 176.94(19) . . . . ?
O16 Eu1 Cd1 O9 -107.4(2) 1_456 . . . ?
O19 Eu1 Cd1 O9 96.18(16) 2_666 . . . ?
O20 Eu1 Cd1 O9 45.90(16) 2_666 . . . ?
C20 Eu1 Cd1 O9 -124.4(6) 1_456 . . . ?
C24 Eu1 Cd1 O9 70.40(17) 2_666 . . . ?
O14 Eu1 Cd1 N2 40.28(12) 2_656 . . . ?
O2W Eu1 Cd1 N2 -48.68(13) . . . . ?
O1W Eu1 Cd1 N2 115.66(12) . . . . ?
O15 Eu1 Cd1 N2 -140.1(3) 1_456 . . . ?
O9 Eu1 Cd1 N2 142.36(17) . . . . ?
O7 Eu1 Cd1 N2 -40.71(16) . . . . ?
O16 Eu1 Cd1 N2 34.97(17) 1_456 . . . ?
O19 Eu1 Cd1 N2 -121.47(11) 2_666 . . . ?
O20 Eu1 Cd1 N2 -171.75(11) 2_666 . . . ?
C20 Eu1 Cd1 N2 18.0(6) 1_456 . . . ?
C24 Eu1 Cd1 N2 -147.25(12) 2_666 . . . ?
O14 Eu1 Cd1 O3 161.97(10) 2_656 . . . ?
O2W Eu1 Cd1 O3 73.01(12) . . . . ?
O1W Eu1 Cd1 O3 -122.64(11) . . . . ?
O15 Eu1 Cd1 O3 -18.4(3) 1_456 . . . ?
O9 Eu1 Cd1 O3 -95.95(16) . . . . ?
O7 Eu1 Cd1 O3 80.99(15) . . . . ?
O16 Eu1 Cd1 O3 156.66(16) 1_456 . . . ?
O19 Eu1 Cd1 O3 0.23(9) 2_666 . . . ?
O20 Eu1 Cd1 O3 -50.05(10) 2_666 . . . ?
C20 Eu1 Cd1 O3 139.7(6) 1_456 . . . ?
C24 Eu1 Cd1 O3 -25.55(11) 2_666 . . . ?
O14 Eu1 Cd1 O5 -31.38(11) 2_656 . . . ?
O2W Eu1 Cd1 O5 -120.34(12) . . . . ?
O1W Eu1 Cd1 O5 44.01(11) . . . . ?
O15 Eu1 Cd1 O5 148.3(3) 1_456 . . . ?
O9 Eu1 Cd1 O5 70.70(16) . . . . ?
O7 Eu1 Cd1 O5 -112.36(15) . . . . ?
O16 Eu1 Cd1 O5 -36.69(17) 1_456 . . . ?
O19 Eu1 Cd1 O5 166.88(10) 2_666 . . . ?
O20 Eu1 Cd1 O5 116.60(11) 2_666 . . . ?
C20 Eu1 Cd1 O5 -53.7(6) 1_456 . . . ?
C24 Eu1 Cd1 O5 141.10(11) 2_666 . . . ?
O14 Eu1 Cd1 N1 -18.2(5) 2_656 . . . ?
O2W Eu1 Cd1 N1 -107.1(5) . . . . ?
O1W Eu1 Cd1 N1 57.2(5) . . . . ?
O15 Eu1 Cd1 N1 161.5(6) 1_456 . . . ?
O9 Eu1 Cd1 N1 83.9(5) . . . . ?
O7 Eu1 Cd1 N1 -99.2(5) . . . . ?
O16 Eu1 Cd1 N1 -23.5(5) 1_456 . . . ?
O19 Eu1 Cd1 N1 -179.9(5) 2_666 . . . ?
O20 Eu1 Cd1 N1 129.8(5) 2_666 . . . ?
C20 Eu1 Cd1 N1 -40.5(8) 1_456 . . . ?
C24 Eu1 Cd1 N1 154.3(5) 2_666 . . . ?
O6 Eu2 Cd2 O18 100.01(15) 2_656 . . . ?
O4W Eu2 Cd2 O18 -171.97(16) . . . . ?
O2 Eu2 Cd2 O18 -80.0(3) . . . . ?
O3W Eu2 Cd2 O18 23.83(15) . . . . ?
O4 Eu2 Cd2 O18 -47.77(15) 2_666 . . . ?
O11 Eu2 Cd2 O18 177.33(18) . . . . ?
O3 Eu2 Cd2 O18 -98.58(15) 2_666 . . . ?
O1 Eu2 Cd2 O18 100.6(2) . . . . ?
C2 Eu2 Cd2 O18 108.2(9) . . . . ?
C10 Eu2 Cd2 O18 -72.60(16) 2_666 . . . ?
O6 Eu2 Cd2 N6 -37.17(12) 2_656 . . . ?
O4W Eu2 Cd2 N6 50.84(13) . . . . ?
O2 Eu2 Cd2 N6 142.8(3) . . . . ?
O3W Eu2 Cd2 N6 -113.36(12) . . . . ?
O4 Eu2 Cd2 N6 175.04(12) 2_666 . . . ?
O18 Eu2 Cd2 N6 -137.18(16) . . . . ?
O11 Eu2 Cd2 N6 40.14(15) . . . . ?
O3 Eu2 Cd2 N6 124.23(11) 2_666 . . . ?
O1 Eu2 Cd2 N6 -36.56(18) . . . . ?
C2 Eu2 Cd2 N6 -29.0(9) . . . . ?
C10 Eu2 Cd2 N6 150.22(13) 2_666 . . . ?
O6 Eu2 Cd2 O19 -165.08(11) 2_656 . . . ?
O4W Eu2 Cd2 O19 -77.06(12) . . . . ?
O2 Eu2 Cd2 O19 14.9(2) . . . . ?
O3W Eu2 Cd2 O19 118.74(11) . . . . ?
O4 Eu2 Cd2 O19 47.14(11) 2_666 . . . ?
O18 Eu2 Cd2 O19 94.91(15) . . . . ?
O11 Eu2 Cd2 O19 -87.76(14) . . . . ?
O3 Eu2 Cd2 O19 -3.67(9) 2_666 . . . ?
O1 Eu2 Cd2 O19 -164.46(17) . . . . ?
C2 Eu2 Cd2 O19 -156.9(9) . . . . ?
C10 Eu2 Cd2 O19 22.31(11) 2_666 . . . ?
O6 Eu2 Cd2 N5 121.61(12) 2_656 . . . ?
O4W Eu2 Cd2 N5 -150.38(13) . . . . ?
O2 Eu2 Cd2 N5 -58.4(3) . . . . ?
O3W Eu2 Cd2 N5 45.42(12) . . . . ?
O4 Eu2 Cd2 N5 -26.18(12) 2_666 . . . ?
O18 Eu2 Cd2 N5 21.59(16) . . . . ?
O11 Eu2 Cd2 N5 -161.08(15) . . . . ?
O3 Eu2 Cd2 N5 -76.99(11) 2_666 . . . ?
O1 Eu2 Cd2 N5 122.22(18) . . . . ?
C2 Eu2 Cd2 N5 129.8(9) . . . . ?
C10 Eu2 Cd2 N5 -51.00(13) 2_666 . . . ?
O6 Eu2 Cd2 O11 -77.32(15) 2_656 . . . ?
O4W Eu2 Cd2 O11 10.70(15) . . . . ?
O2 Eu2 Cd2 O11 102.7(3) . . . . ?
O3W Eu2 Cd2 O11 -153.50(15) . . . . ?
O4 Eu2 Cd2 O11 134.90(15) 2_666 . . . ?
O18 Eu2 Cd2 O11 -177.33(18) . . . . ?
O3 Eu2 Cd2 O11 84.09(14) 2_666 . . . ?
O1 Eu2 Cd2 O11 -76.7(2) . . . . ?
C2 Eu2 Cd2 O11 -69.1(9) . . . . ?
C10 Eu2 Cd2 O11 110.08(15) 2_666 . . . ?
O6 Eu2 Cd2 O13 34.09(10) 2_656 . . . ?
O4W Eu2 Cd2 O13 122.11(12) . . . . ?
O2 Eu2 Cd2 O13 -145.9(2) . . . . ?
O3W Eu2 Cd2 O13 -42.09(11) . . . . ?
O4 Eu2 Cd2 O13 -113.69(10) 2_666 . . . ?
O18 Eu2 Cd2 O13 -65.92(15) . . . . ?
O11 Eu2 Cd2 O13 111.41(14) . . . . ?
O3 Eu2 Cd2 O13 -164.50(10) 2_666 . . . ?
O1 Eu2 Cd2 O13 34.71(17) . . . . ?
C2 Eu2 Cd2 O13 42.3(9) . . . . ?
C10 Eu2 Cd2 O13 -138.52(11) 2_666 . . . ?
O6 Eu2 Cd2 N4 25.6(6) 2_656 . . . ?
O4W Eu2 Cd2 N4 113.6(6) . . . . ?
O2 Eu2 Cd2 N4 -154.4(6) . . . . ?
O3W Eu2 Cd2 N4 -50.6(6) . . . . ?
O4 Eu2 Cd2 N4 -122.2(6) 2_666 . . . ?
O18 Eu2 Cd2 N4 -74.4(6) . . . . ?
O11 Eu2 Cd2 N4 102.9(6) . . . . ?
O3 Eu2 Cd2 N4 -173.0(6) 2_666 . . . ?
O1 Eu2 Cd2 N4 26.2(6) . . . . ?
C2 Eu2 Cd2 N4 33.7(10) . . . . ?
C10 Eu2 Cd2 N4 -147.0(6) 2_666 . . . ?
O6 Eu2 O1 C2 178.8(3) 2_656 . . . ?
O4W Eu2 O1 C2 81.3(3) . . . . ?
O2 Eu2 O1 C2 -1.6(3) . . . . ?
O3W Eu2 O1 C2 -95.0(3) . . . . ?
O4 Eu2 O1 C2 -37.3(3) 2_666 . . . ?
O18 Eu2 O1 C2 -124.7(3) . . . . ?
O11 Eu2 O1 C2 132.5(3) . . . . ?
O3 Eu2 O1 C2 22.8(3) 2_666 . . . ?
C10 Eu2 O1 C2 -10.2(3) 2_666 . . . ?
Cd2 Eu2 O1 C2 178.2(2) . . . . ?
O6 Eu2 O2 C2 2.0(3) 2_656 . . . ?
O4W Eu2 O2 C2 -80.3(3) . . . . ?
O3W Eu2 O2 C2 73.9(3) . . . . ?
O4 Eu2 O2 C2 147.9(3) 2_666 . . . ?
O18 Eu2 O2 C2 126.7(3) . . . . ?
O11 Eu2 O2 C2 -104.6(3) . . . . ?
O3 Eu2 O2 C2 -159.4(3) 2_666 . . . ?
O1 Eu2 O2 C2 1.6(3) . . . . ?
C10 Eu2 O2 C2 174.3(3) 2_666 . . . ?
Cd2 Eu2 O2 C2 -178.0(2) . . . . ?
O7 Cd1 O3 C10 130.6(3) . . . . ?
N3 Cd1 O3 C10 -8.9(3) . . . . ?
O9 Cd1 O3 C10 59.0(3) . . . . ?
N2 Cd1 O3 C10 -160.3(3) . . . . ?
O5 Cd1 O3 C10 -22.3(6) . . . . ?
N1 Cd1 O3 C10 -85.2(3) . . . . ?
Eu1 Cd1 O3 C10 94.8(3) . . . . ?
O7 Cd1 O3 Eu2 -60.6(3) . . . 2_666 ?
N3 Cd1 O3 Eu2 159.9(3) . . . 2_666 ?
O9 Cd1 O3 Eu2 -132.2(3) . . . 2_666 ?
N2 Cd1 O3 Eu2 8.5(3) . . . 2_666 ?
O5 Cd1 O3 Eu2 146.5(3) . . . 2_666 ?
N1 Cd1 O3 Eu2 83.6(3) . . . 2_666 ?
Eu1 Cd1 O3 Eu2 -96.4(3) . . . 2_666 ?
O7 Cd1 O5 C12 43.7(3) . . . . ?
N3 Cd1 O5 C12 -177.1(3) . . . . ?
O9 Cd1 O5 C12 111.9(3) . . . . ?
N2 Cd1 O5 C12 -21.9(3) . . . . ?
O3 Cd1 O5 C12 -164.2(3) . . . . ?
N1 Cd1 O5 C12 -100.0(3) . . . . ?
Eu1 Cd1 O5 C12 77.9(3) . . . . ?
N3 Cd1 O7 C14 160.6(3) . . . . ?
O9 Cd1 O7 C14 -166.9(3) . . . . ?
N2 Cd1 O7 C14 -27.7(3) . . . . ?
O3 Cd1 O7 C14 93.6(3) . . . . ?
O5 Cd1 O7 C14 -93.3(3) . . . . ?
N1 Cd1 O7 C14 -0.1(4) . . . . ?
Eu1 Cd1 O7 C14 -165.0(4) . . . . ?
N3 Cd1 O7 Eu1 -34.3(2) . . . . ?
O9 Cd1 O7 Eu1 -1.87(11) . . . . ?
N2 Cd1 O7 Eu1 137.38(15) . . . . ?
O3 Cd1 O7 Eu1 -101.32(13) . . . . ?
O5 Cd1 O7 Eu1 71.70(13) . . . . ?
N1 Cd1 O7 Eu1 164.91(15) . . . . ?
O14 Eu1 O7 C14 71.8(4) 2_656 . . . ?
O2W Eu1 O7 C14 -27.1(4) . . . . ?
O1W Eu1 O7 C14 127.8(4) . . . . ?
O15 Eu1 O7 C14 -51.5(5) 1_456 . . . ?
O9 Eu1 O7 C14 162.8(4) . . . . ?
O16 Eu1 O7 C14 24.4(4) 1_456 . . . ?
O19 Eu1 O7 C14 -106.2(4) 2_666 . . . ?
O20 Eu1 O7 C14 -144.0(4) 2_666 . . . ?
C20 Eu1 O7 C14 -7.4(5) 1_456 . . . ?
C24 Eu1 O7 C14 -125.1(4) 2_666 . . . ?
Cd1 Eu1 O7 C14 160.9(5) . . . . ?
O14 Eu1 O7 Cd1 -89.09(13) 2_656 . . . ?
O2W Eu1 O7 Cd1 171.96(16) . . . . ?
O1W Eu1 O7 Cd1 -33.1(2) . . . . ?
O15 Eu1 O7 Cd1 147.62(14) 1_456 . . . ?
O9 Eu1 O7 Cd1 1.84(11) . . . . ?
O16 Eu1 O7 Cd1 -136.53(12) 1_456 . . . ?
O19 Eu1 O7 Cd1 92.87(13) 2_666 . . . ?
O20 Eu1 O7 Cd1 55.09(15) 2_666 . . . ?
C20 Eu1 O7 Cd1 -168.36(16) 1_456 . . . ?
C24 Eu1 O7 Cd1 73.96(14) 2_666 . . . ?
O7 Cd1 O9 C8 178.4(3) . . . . ?
N3 Cd1 O9 C8 -24.3(3) . . . . ?
N2 Cd1 O9 C8 128.4(3) . . . . ?
O3 Cd1 O9 C8 -94.4(3) . . . . ?
O5 Cd1 O9 C8 70.5(3) . . . . ?
N1 Cd1 O9 C8 11.1(4) . . . . ?
Eu1 Cd1 O9 C8 176.4(4) . . . . ?
O7 Cd1 O9 Eu1 1.91(12) . . . . ?
N3 Cd1 O9 Eu1 159.29(17) . . . . ?
N2 Cd1 O9 Eu1 -48.08(19) . . . . ?
O3 Cd1 O9 Eu1 89.19(13) . . . . ?
O5 Cd1 O9 Eu1 -105.96(14) . . . . ?
N1 Cd1 O9 Eu1 -165.38(14) . . . . ?
O14 Eu1 O9 C8 -103.7(4) 2_656 . . . ?
O2W Eu1 O9 C8 168.3(4) . . . . ?
O1W Eu1 O9 C8 -22.2(4) . . . . ?
O15 Eu1 O9 C8 32.0(5) 1_456 . . . ?
O7 Eu1 O9 C8 -177.3(4) . . . . ?
O16 Eu1 O9 C8 -54.7(5) 1_456 . . . ?
O19 Eu1 O9 C8 104.5(4) 2_666 . . . ?
O20 Eu1 O9 C8 54.6(4) 2_666 . . . ?
C20 Eu1 O9 C8 -9.7(6) 1_456 . . . ?
C24 Eu1 O9 C8 80.1(4) 2_666 . . . ?
Cd1 Eu1 O9 C8 -175.5(5) . . . . ?
O14 Eu1 O9 Cd1 71.83(14) 2_656 . . . ?
O2W Eu1 O9 Cd1 -16.2(2) . . . . ?
O1W Eu1 O9 Cd1 153.32(16) . . . . ?
O15 Eu1 O9 Cd1 -152.49(13) 1_456 . . . ?
O7 Eu1 O9 Cd1 -1.84(11) . . . . ?
O16 Eu1 O9 Cd1 120.81(16) 1_456 . . . ?
O19 Eu1 O9 Cd1 -80.06(14) 2_666 . . . ?
O20 Eu1 O9 Cd1 -129.92(16) 2_666 . . . ?
C20 Eu1 O9 Cd1 165.8(2) 1_456 . . . ?
C24 Eu1 O9 Cd1 -104.36(15) 2_666 . . . ?
O18 Cd2 O11 C28 154.2(3) . . . . ?
N6 Cd2 O11 C28 17.9(3) . . . . ?
O19 Cd2 O11 C28 -107.9(3) . . . . ?
N5 Cd2 O11 C28 -175.6(3) . . . . ?
O13 Cd2 O11 C28 82.5(3) . . . . ?
N4 Cd2 O11 C28 -10.1(4) . . . . ?
Eu2 Cd2 O11 C28 155.8(4) . . . . ?
O18 Cd2 O11 Eu2 -1.64(11) . . . . ?
N6 Cd2 O11 Eu2 -137.90(15) . . . . ?
O19 Cd2 O11 Eu2 96.28(12) . . . . ?
N5 Cd2 O11 Eu2 28.6(2) . . . . ?
O13 Cd2 O11 Eu2 -73.28(13) . . . . ?
N4 Cd2 O11 Eu2 -165.96(15) . . . . ?
O6 Eu2 O11 C28 -58.3(4) 2_656 . . . ?
O4W Eu2 O11 C28 39.9(4) . . . . ?
O2 Eu2 O11 C28 64.6(4) . . . . ?
O3W Eu2 O11 C28 -113.3(4) . . . . ?
O4 Eu2 O11 C28 157.9(3) 2_666 . . . ?
O18 Eu2 O11 C28 -149.3(4) . . . . ?
O3 Eu2 O11 C28 119.6(4) 2_666 . . . ?
O1 Eu2 O11 C28 -12.0(4) . . . . ?
C2 Eu2 O11 C28 19.7(5) . . . . ?
C10 Eu2 O11 C28 138.3(4) 2_666 . . . ?
Cd2 Eu2 O11 C28 -150.9(4) . . . . ?
O6 Eu2 O11 Cd2 92.58(13) 2_656 . . . ?
O4W Eu2 O11 Cd2 -169.26(15) . . . . ?
O2 Eu2 O11 Cd2 -144.59(14) . . . . ?
O3W Eu2 O11 Cd2 37.51(19) . . . . ?
O4 Eu2 O11 Cd2 -51.25(15) 2_666 . . . ?
O18 Eu2 O11 Cd2 1.59(11) . . . . ?
O3 Eu2 O11 Cd2 -89.51(12) 2_666 . . . ?
O1 Eu2 O11 Cd2 138.83(12) . . . . ?
C2 Eu2 O11 Cd2 170.59(16) . . . . ?
C10 Eu2 O11 Cd2 -70.84(13) 2_666 . . . ?
O18 Cd2 O13 C26 -109.7(3) . . . . ?
N6 Cd2 O13 C26 23.7(3) . . . . ?
O19 Cd2 O13 C26 169.4(3) . . . . ?
N5 Cd2 O13 C26 179.0(3) . . . . ?
O11 Cd2 O13 C26 -41.0(3) . . . . ?
N4 Cd2 O13 C26 102.4(3) . . . . ?
Eu2 Cd2 O13 C26 -76.3(3) . . . . ?
N6 Cd2 O18 C22 -122.0(3) . . . . ?
O19 Cd2 O18 C22 93.5(3) . . . . ?
N5 Cd2 O18 C22 26.0(3) . . . . ?
O11 Cd2 O18 C22 -174.4(3) . . . . ?
O13 Cd2 O18 C22 -65.5(3) . . . . ?
N4 Cd2 O18 C22 -9.0(4) . . . . ?
Eu2 Cd2 O18 C22 -176.0(4) . . . . ?
N6 Cd2 O18 Eu2 54.06(18) . . . . ?
O19 Cd2 O18 Eu2 -90.42(13) . . . . ?
N5 Cd2 O18 Eu2 -157.92(16) . . . . ?
O11 Cd2 O18 Eu2 1.69(11) . . . . ?
O13 Cd2 O18 Eu2 110.51(13) . . . . ?
N4 Cd2 O18 Eu2 167.02(14) . . . . ?
O6 Eu2 O18 C22 100.6(4) 2_656 . . . ?
O4W Eu2 O18 C22 -173.1(4) . . . . ?
O2 Eu2 O18 C22 -35.9(5) . . . . ?
O3W Eu2 O18 C22 18.8(4) . . . . ?
O4 Eu2 O18 C22 -57.5(4) 2_666 . . . ?
O11 Eu2 O18 C22 173.3(4) . . . . ?
O3 Eu2 O18 C22 -107.3(4) 2_666 . . . ?
O1 Eu2 O18 C22 47.9(5) . . . . ?
C2 Eu2 O18 C22 5.8(5) . . . . ?
C10 Eu2 O18 C22 -82.9(4) 2_666 . . . ?
Cd2 Eu2 O18 C22 174.9(5) . . . . ?
O6 Eu2 O18 Cd2 -74.29(13) 2_656 . . . ?
O4W Eu2 O18 Cd2 12.0(2) . . . . ?
O2 Eu2 O18 Cd2 149.18(13) . . . . ?
O3W Eu2 O18 Cd2 -156.08(15) . . . . ?
O4 Eu2 O18 Cd2 127.61(15) 2_666 . . . ?
O11 Eu2 O18 Cd2 -1.64(11) . . . . ?
O3 Eu2 O18 Cd2 77.75(13) 2_666 . . . ?
O1 Eu2 O18 Cd2 -127.07(14) . . . . ?
C2 Eu2 O18 Cd2 -169.08(17) . . . . ?
C10 Eu2 O18 Cd2 102.18(14) 2_666 . . . ?
O18 Cd2 O19 C24 -58.1(3) . . . . ?
N6 Cd2 O19 C24 158.0(3) . . . . ?
N5 Cd2 O19 C24 8.7(3) . . . . ?
O11 Cd2 O19 C24 -131.7(3) . . . . ?
O13 Cd2 O19 C24 18.8(4) . . . . ?
N4 Cd2 O19 C24 84.0(3) . . . . ?
Eu2 Cd2 O19 C24 -94.4(3) . . . . ?
O18 Cd2 O19 Eu1 132.4(3) . . . 2_666 ?
N6 Cd2 O19 Eu1 -11.5(3) . . . 2_666 ?
N5 Cd2 O19 Eu1 -160.7(3) . . . 2_666 ?
O11 Cd2 O19 Eu1 58.9(3) . . . 2_666 ?
O13 Cd2 O19 Eu1 -150.6(2) . . . 2_666 ?
N4 Cd2 O19 Eu1 -85.4(3) . . . 2_666 ?
Eu2 Cd2 O19 Eu1 96.1(3) . . . 2_666 ?
O7 Cd1 N1 C1 73.4(3) . . . . ?
N3 Cd1 N1 C1 -93.3(3) . . . . ?
O9 Cd1 N1 C1 -127.5(3) . . . . ?
N2 Cd1 N1 C1 100.3(3) . . . . ?
O3 Cd1 N1 C1 -19.8(3) . . . . ?
O5 Cd1 N1 C1 173.7(3) . . . . ?
Eu1 Cd1 N1 C1 160.4(4) . . . . ?
O7 Cd1 N1 C4 -47.3(3) . . . . ?
N3 Cd1 N1 C4 146.0(3) . . . . ?
O9 Cd1 N1 C4 111.8(3) . . . . ?
N2 Cd1 N1 C4 -20.4(2) . . . . ?
O3 Cd1 N1 C4 -140.5(3) . . . . ?
O5 Cd1 N1 C4 53.0(3) . . . . ?
Eu1 Cd1 N1 C4 39.7(7) . . . . ?
O7 Cd1 N1 C3 -164.6(2) . . . . ?
N3 Cd1 N1 C3 28.6(3) . . . . ?
O9 Cd1 N1 C3 -5.6(4) . . . . ?
N2 Cd1 N1 C3 -137.7(3) . . . . ?
O3 Cd1 N1 C3 102.2(3) . . . . ?
O5 Cd1 N1 C3 -64.3(3) . . . . ?
Eu1 Cd1 N1 C3 -77.7(6) . . . . ?
O7 Cd1 N2 C13 35.7(2) . . . . ?
N3 Cd1 N2 C13 -155.7(3) . . . . ?
O9 Cd1 N2 C13 85.6(3) . . . . ?
O3 Cd1 N2 C13 -43.9(3) . . . . ?
O5 Cd1 N2 C13 146.6(3) . . . . ?
N1 Cd1 N2 C13 -128.2(3) . . . . ?
Eu1 Cd1 N2 C13 59.6(3) . . . . ?
O7 Cd1 N2 C11 -82.4(2) . . . . ?
N3 Cd1 N2 C11 86.2(3) . . . . ?
O9 Cd1 N2 C11 -32.4(3) . . . . ?
O3 Cd1 N2 C11 -161.9(2) . . . . ?
O5 Cd1 N2 C11 28.6(2) . . . . ?
N1 Cd1 N2 C11 113.8(3) . . . . ?
Eu1 Cd1 N2 C11 -58.4(2) . . . . ?
O7 Cd1 N2 C5 155.9(3) . . . . ?
N3 Cd1 N2 C5 -35.5(4) . . . . ?
O9 Cd1 N2 C5 -154.1(2) . . . . ?
O3 Cd1 N2 C5 76.4(3) . . . . ?
O5 Cd1 N2 C5 -93.1(3) . . . . ?
N1 Cd1 N2 C5 -7.9(3) . . . . ?
Eu1 Cd1 N2 C5 179.9(3) . . . . ?
O7 Cd1 N3 C7 66.8(3) . . . . ?
O9 Cd1 N3 C7 34.3(2) . . . . ?
N2 Cd1 N3 C7 -97.1(3) . . . . ?
O3 Cd1 N3 C7 139.7(3) . . . . ?
O5 Cd1 N3 C7 -43.7(2) . . . . ?
N1 Cd1 N3 C7 -124.6(3) . . . . ?
Eu1 Cd1 N3 C7 46.6(2) . . . . ?
O7 Cd1 N3 C9 -50.5(3) . . . . ?
O9 Cd1 N3 C9 -83.0(3) . . . . ?
N2 Cd1 N3 C9 145.5(3) . . . . ?
O3 Cd1 N3 C9 22.4(2) . . . . ?
O5 Cd1 N3 C9 -161.1(3) . . . . ?
N1 Cd1 N3 C9 118.1(3) . . . . ?
Eu1 Cd1 N3 C9 -70.7(3) . . . . ?
O7 Cd1 N3 C6 -171.1(2) . . . . ?
O9 Cd1 N3 C6 156.4(3) . . . . ?
N2 Cd1 N3 C6 24.9(4) . . . . ?
O3 Cd1 N3 C6 -98.2(3) . . . . ?
O5 Cd1 N3 C6 78.4(3) . . . . ?
N1 Cd1 N3 C6 -2.5(3) . . . . ?
Eu1 Cd1 N3 C6 168.7(3) . . . . ?
O18 Cd2 N4 C19 130.9(3) . . . . ?
N6 Cd2 N4 C19 -100.7(3) . . . . ?
O19 Cd2 N4 C19 25.6(3) . . . . ?
N5 Cd2 N4 C19 96.9(3) . . . . ?
O11 Cd2 N4 C19 -73.4(3) . . . . ?
O13 Cd2 N4 C19 -173.6(3) . . . . ?
Eu2 Cd2 N4 C19 -164.9(4) . . . . ?
O18 Cd2 N4 C15 8.0(4) . . . . ?
N6 Cd2 N4 C15 136.4(3) . . . . ?
O19 Cd2 N4 C15 -97.3(3) . . . . ?
N5 Cd2 N4 C15 -26.0(3) . . . . ?
O11 Cd2 N4 C15 163.7(2) . . . . ?
O13 Cd2 N4 C15 63.5(3) . . . . ?
Eu2 Cd2 N4 C15 72.1(7) . . . . ?
O18 Cd2 N4 C17 -110.1(3) . . . . ?
N6 Cd2 N4 C17 18.3(3) . . . . ?
O19 Cd2 N4 C17 144.6(3) . . . . ?
N5 Cd2 N4 C17 -144.2(3) . . . . ?
O11 Cd2 N4 C17 45.6(4) . . . . ?
O13 Cd2 N4 C17 -54.6(3) . . . . ?
Eu2 Cd2 N4 C17 -46.0(7) . . . . ?
O18 Cd2 N5 C21 -35.1(2) . . . . ?
N6 Cd2 N5 C21 89.8(3) . . . . ?
O19 Cd2 N5 C21 -141.5(3) . . . . ?
O11 Cd2 N5 C21 -65.7(3) . . . . ?
O13 Cd2 N5 C21 42.1(2) . . . . ?
N4 Cd2 N5 C21 123.1(3) . . . . ?
Eu2 Cd2 N5 C21 -48.3(2) . . . . ?
O18 Cd2 N5 C23 81.9(3) . . . . ?
N6 Cd2 N5 C23 -153.2(3) . . . . ?
O19 Cd2 N5 C23 -24.5(3) . . . . ?
O11 Cd2 N5 C23 51.3(3) . . . . ?
O13 Cd2 N5 C23 159.1(3) . . . . ?
N4 Cd2 N5 C23 -119.9(3) . . . . ?
Eu2 Cd2 N5 C23 68.7(3) . . . . ?
O18 Cd2 N5 C16 -157.9(3) . . . . ?
N6 Cd2 N5 C16 -33.0(4) . . . . ?
O19 Cd2 N5 C16 95.7(3) . . . . ?
O11 Cd2 N5 C16 171.5(2) . . . . ?
O13 Cd2 N5 C16 -80.7(3) . . . . ?
N4 Cd2 N5 C16 0.3(3) . . . . ?
Eu2 Cd2 N5 C16 -171.1(3) . . . . ?
O18 Cd2 N6 C27 -85.7(3) . . . . ?
O19 Cd2 N6 C27 49.6(3) . . . . ?
N5 Cd2 N6 C27 164.0(3) . . . . ?
O11 Cd2 N6 C27 -32.7(2) . . . . ?
O13 Cd2 N6 C27 -144.7(3) . . . . ?
N4 Cd2 N6 C27 130.8(3) . . . . ?
Eu2 Cd2 N6 C27 -56.9(3) . . . . ?
O18 Cd2 N6 C25 32.5(3) . . . . ?
O19 Cd2 N6 C25 167.8(2) . . . . ?
N5 Cd2 N6 C25 -77.7(3) . . . . ?
O11 Cd2 N6 C25 85.6(3) . . . . ?
O13 Cd2 N6 C25 -26.5(2) . . . . ?
N4 Cd2 N6 C25 -110.9(3) . . . . ?
Eu2 Cd2 N6 C25 61.4(3) . . . . ?
O18 Cd2 N6 C18 154.7(3) . . . . ?
O19 Cd2 N6 C18 -70.0(3) . . . . ?
N5 Cd2 N6 C18 44.5(4) . . . . ?
O11 Cd2 N6 C18 -152.2(3) . . . . ?
O13 Cd2 N6 C18 95.7(3) . . . . ?
N4 Cd2 N6 C18 11.2(3) . . . . ?
Eu2 Cd2 N6 C18 -176.5(3) . . . . ?
C4 N1 C1 C2 -61.1(5) . . . . ?
C3 N1 C1 C2 68.2(5) . . . . ?
Cd1 N1 C1 C2 -178.3(3) . . . . ?
Eu2 O1 C2 O2 2.8(5) . . . . ?
Eu2 O1 C2 C1 -173.5(4) . . . . ?
Eu2 O2 C2 O1 -3.0(5) . . . . ?
Eu2 O2 C2 C1 173.6(3) . . . . ?
N1 C1 C2 O1 -28.9(6) . . . . ?
N1 C1 C2 O2 154.6(4) . . . . ?
N1 C1 C2 Eu2 -165.1(18) . . . . ?
O6 Eu2 C2 O1 -1.2(3) 2_656 . . . ?
O4W Eu2 C2 O1 -90.9(3) . . . . ?
O2 Eu2 C2 O1 177.2(5) . . . . ?
O3W Eu2 C2 O1 76.8(3) . . . . ?
O4 Eu2 C2 O1 146.7(3) 2_666 . . . ?
O18 Eu2 C2 O1 89.8(3) . . . . ?
O11 Eu2 C2 O1 -70.7(3) . . . . ?
O3 Eu2 C2 O1 -161.8(3) 2_666 . . . ?
C10 Eu2 C2 O1 171.6(3) 2_666 . . . ?
Cd2 Eu2 C2 O1 -9.2(11) . . . . ?
O6 Eu2 C2 O2 -178.3(3) 2_656 . . . ?
O4W Eu2 C2 O2 91.9(3) . . . . ?
O3W Eu2 C2 O2 -100.3(3) . . . . ?
O4 Eu2 C2 O2 -30.5(3) 2_666 . . . ?
O18 Eu2 C2 O2 -87.4(3) . . . . ?
O11 Eu2 C2 O2 112.1(3) . . . . ?
O3 Eu2 C2 O2 21.0(3) 2_666 . . . ?
O1 Eu2 C2 O2 -177.2(5) . . . . ?
C10 Eu2 C2 O2 -5.6(3) 2_666 . . . ?
Cd2 Eu2 C2 O2 173.6(7) . . . . ?
O6 Eu2 C2 C1 138(2) 2_656 . . . ?
O4W Eu2 C2 C1 49(2) . . . . ?
O2 Eu2 C2 C1 -43(2) . . . . ?
O3W Eu2 C2 C1 -144(2) . . . . ?
O4 Eu2 C2 C1 -74(2) 2_666 . . . ?
O18 Eu2 C2 C1 -131(2) . . . . ?
O11 Eu2 C2 C1 69(2) . . . . ?
O3 Eu2 C2 C1 -22(2) 2_666 . . . ?
O1 Eu2 C2 C1 140(2) . . . . ?
C10 Eu2 C2 C1 -49(2) 2_666 . . . ?
Cd2 Eu2 C2 C1 130.3(18) . . . . ?
C1 N1 C3 C6 67.2(4) . . . . ?
C4 N1 C3 C6 -164.5(3) . . . . ?
Cd1 N1 C3 C6 -53.2(4) . . . . ?
C1 N1 C4 C5 -75.3(4) . . . . ?
C3 N1 C4 C5 154.6(3) . . . . ?
Cd1 N1 C4 C5 46.3(4) . . . . ?
C13 N2 C5 C4 151.8(4) . . . . ?
C11 N2 C5 C4 -83.0(4) . . . . ?
Cd1 N2 C5 C4 36.1(4) . . . . ?
N1 C4 C5 N2 -58.8(5) . . . . ?
C7 N3 C6 C3 91.8(4) . . . . ?
C9 N3 C6 C3 -143.8(4) . . . . ?
Cd1 N3 C6 C3 -25.8(4) . . . . ?
N1 C3 C6 N3 58.2(5) . . . . ?
C9 N3 C7 C8 72.5(4) . . . . ?
C6 N3 C7 C8 -162.3(4) . . . . ?
Cd1 N3 C7 C8 -43.0(4) . . . . ?
Cd1 O9 C8 O10 -170.8(4) . . . . ?
Eu1 O9 C8 O10 4.5(8) . . . . ?
Cd1 O9 C8 C7 8.5(5) . . . . ?
Eu1 O9 C8 C7 -176.2(3) . . . . ?
N3 C7 C8 O10 -155.8(4) . . . . ?
N3 C7 C8 O9 24.8(6) . . . . ?
C7 N3 C9 C10 -148.8(3) . . . . ?
C6 N3 C9 C10 84.9(4) . . . . ?
Cd1 N3 C9 C10 -34.1(4) . . . . ?
Eu2 O4 C10 O3 0.1(4) 2_666 . . . ?
Eu2 O4 C10 C9 -177.4(3) 2_666 . . . ?
Cd1 O3 C10 O4 175.0(3) . . . . ?
Eu2 O3 C10 O4 -0.1(4) 2_666 . . . ?
Cd1 O3 C10 C9 -7.6(4) . . . . ?
Eu2 O3 C10 C9 177.4(3) 2_666 . . . ?
Cd1 O3 C10 Eu2 175.1(2) . . . 2_666 ?
N3 C9 C10 O4 -152.5(4) . . . . ?
N3 C9 C10 O3 30.0(5) . . . . ?
N3 C9 C10 Eu2 166(5) . . . 2_666 ?
C13 N2 C11 C12 -149.3(3) . . . . ?
C5 N2 C11 C12 84.9(4) . . . . ?
Cd1 N2 C11 C12 -35.4(4) . . . . ?
Eu2 O6 C12 O5 -24.6(6) 2_656 . . . ?
Eu2 O6 C12 C11 156.9(3) 2_656 . . . ?
Cd1 O5 C12 O6 -169.0(3) . . . . ?
Cd1 O5 C12 C11 9.6(4) . . . . ?
N2 C11 C12 O6 -162.8(3) . . . . ?
N2 C11 C12 O5 18.6(5) . . . . ?
C11 N2 C13 C14 73.1(5) . . . . ?
C5 N2 C13 C14 -161.1(4) . . . . ?
Cd1 N2 C13 C14 -42.5(4) . . . . ?
Cd1 O7 C14 O8 -165.3(4) . . . . ?
Eu1 O7 C14 O8 34.2(7) . . . . ?
Cd1 O7 C14 C13 13.0(5) . . . . ?
Eu1 O7 C14 C13 -147.4(3) . . . . ?
N2 C13 C14 O8 -159.8(4) . . . . ?
N2 C13 C14 O7 21.8(6) . . . . ?
C19 N4 C15 C16 -70.2(4) . . . . ?
C17 N4 C15 C16 162.3(4) . . . . ?
Cd2 N4 C15 C16 50.5(4) . . . . ?
C21 N5 C16 C15 -91.3(4) . . . . ?
C23 N5 C16 C15 146.2(4) . . . . ?
Cd2 N5 C16 C15 26.7(4) . . . . ?
N4 C15 C16 N5 -56.0(5) . . . . ?
C19 N4 C17 C18 73.2(4) . . . . ?
C15 N4 C17 C18 -157.1(4) . . . . ?
Cd2 N4 C17 C18 -46.4(4) . . . . ?
C27 N6 C18 C17 -156.5(4) . . . . ?
C25 N6 C18 C17 80.2(4) . . . . ?
Cd2 N6 C18 C17 -40.3(4) . . . . ?
N4 C17 C18 N6 62.2(5) . . . . ?
C15 N4 C19 C20 -73.7(5) . . . . ?
C17 N4 C19 C20 55.2(5) . . . . ?
Cd2 N4 C19 C20 170.5(3) . . . . ?
Eu1 O16 C20 O15 -6.6(5) 1_654 . . . ?
Eu1 O16 C20 C19 170.8(4) 1_654 . . . ?
Eu1 O15 C20 O16 6.8(5) 1_654 . . . ?
Eu1 O15 C20 C19 -170.7(3) 1_654 . . . ?
N4 C19 C20 O16 32.8(6) . . . . ?
N4 C19 C20 O15 -149.7(4) . . . . ?
N4 C19 C20 Eu1 144.4(19) . . . 1_654 ?
C23 N5 C21 C22 -74.2(4) . . . . ?
C16 N5 C21 C22 162.8(3) . . . . ?
Cd2 N5 C21 C22 42.5(4) . . . . ?
Cd2 O18 C22 O17 167.5(4) . . . . ?
Eu2 O18 C22 O17 -7.3(7) . . . . ?
Cd2 O18 C22 C21 -11.1(5) . . . . ?
Eu2 O18 C22 C21 174.1(3) . . . . ?
N5 C21 C22 O17 158.3(4) . . . . ?
N5 C21 C22 O18 -23.0(5) . . . . ?
C21 N5 C23 C24 152.2(3) . . . . ?
C16 N5 C23 C24 -82.6(4) . . . . ?
Cd2 N5 C23 C24 37.5(4) . . . . ?
Eu1 O20 C24 O19 -2.0(4) 2_666 . . . ?
Eu1 O20 C24 C23 175.5(3) 2_666 . . . ?
Cd2 O19 C24 O20 -172.8(3) . . . . ?
Eu1 O19 C24 O20 2.0(4) 2_666 . . . ?
Cd2 O19 C24 C23 9.7(5) . . . . ?
Eu1 O19 C24 C23 -175.4(3) 2_666 . . . ?
Cd2 O19 C24 Eu1 -174.8(2) . . . 2_666 ?
N5 C23 C24 O20 149.3(4) . . . . ?
N5 C23 C24 O19 -33.2(5) . . . . ?
N5 C23 C24 Eu1 -126(4) . . . 2_666 ?
C27 N6 C25 C26 145.6(3) . . . . ?
C18 N6 C25 C26 -90.3(4) . . . . ?
Cd2 N6 C25 C26 29.7(4) . . . . ?
Eu1 O14 C26 O13 32.7(6) 2_656 . . . ?
Eu1 O14 C26 C25 -149.2(3) 2_656 . . . ?
Cd2 O13 C26 O14 162.8(3) . . . . ?
Cd2 O13 C26 C25 -15.3(5) . . . . ?
N6 C25 C26 O14 171.5(3) . . . . ?
N6 C25 C26 O13 -10.3(6) . . . . ?
C25 N6 C27 C28 -72.0(4) . . . . ?
C18 N6 C27 C28 163.4(4) . . . . ?
Cd2 N6 C27 C28 45.8(4) . . . . ?
Cd2 O11 C28 O12 -179.8(4) . . . . ?
Eu2 O11 C28 O12 -30.7(7) . . . . ?
Cd2 O11 C28 C27 1.7(5) . . . . ?
Eu2 O11 C28 C27 150.8(3) . . . . ?
N6 C27 C28 O12 147.8(4) . . . . ?
N6 C27 C28 O11 -33.6(6) . . . . ?

_diffrn_measured_fraction_theta_max 0.920
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.920
_refine_diff_density_max         1.126
_refine_diff_density_min         -0.627
_refine_diff_density_rms         0.115
_database_code_depnum_ccdc_archive 'CCDC 975527'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_2

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C28 H52 Cd2 Gd2 N6 O24,4(O)'
_chemical_formula_sum            'C28 H52 Cd2 Gd2 N6 O28'
_chemical_formula_weight         1460.06

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.779(2)
_cell_length_b                   10.868(2)
_cell_length_c                   20.395(4)
_cell_angle_alpha                100.77(3)
_cell_angle_beta                 92.74(3)
_cell_angle_gamma                91.79(3)
_cell_volume                     2125.2(7)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    9532
_cell_measurement_theta_min      5.99
_cell_measurement_theta_max      54.92

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.282
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1420
_exptl_absorpt_coefficient_mu    4.173
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Saturn724 (2x2 bin mode)'
_diffrn_measurement_method       dtprofit.ref
_diffrn_detector_area_resol_mean 28.5714
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            19740
_diffrn_reflns_av_R_equivalents  0.0532
_diffrn_reflns_av_sigmaI/netI    0.0713
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         2.99
_diffrn_reflns_theta_max         27.47
_reflns_number_total             9524
_reflns_number_gt                7188
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'CrystalClear (Rigaku Corp., 2000)'
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2000)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0721P)²+1.4582P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         9524
_refine_ls_number_parameters     594
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0630
_refine_ls_R_factor_gt           0.0433
_refine_ls_wR_factor_ref         0.1237
_refine_ls_wR_factor_gt          0.1109
_refine_ls_goodness_of_fit_ref   0.946
_refine_ls_restrained_S_all      0.946
_refine_ls_shift/su_max          0.011
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Gd1 Gd 0.87548(3) 0.20441(2) 0.161924(14) 0.01857(9) Uani 1 1 d . . .
Gd2 Gd 0.69483(3) -0.19095(2) 0.358096(14) 0.01882(9) Uani 1 1 d . . .
Cd1 Cd 0.70233(4) 0.23606(4) 0.33624(2) 0.01867(11) Uani 1 1 d . . .
Cd2 Cd 0.86014(4) -0.22702(4) 0.18168(2) 0.01823(11) Uani 1 1 d . . .
O1 O 0.3655(5) 0.1037(4) 0.5278(2) 0.0311(11) Uani 1 1 d . . .
O1W O 0.7230(5) 0.0722(5) 0.0797(2) 0.0381(12) Uani 1 1 d . . .
H1WA H 0.7346 -0.0044 0.0819 0.057 Uiso 1 1 d R . .
H1WB H 0.6403 0.0899 0.0875 0.057 Uiso 1 1 d R . .
O2 O 0.4679(5) 0.2855(4) 0.5717(2) 0.0314(11) Uani 1 1 d . . .
O2W O 1.0508(4) 0.3724(4) 0.1777(2) 0.0277(10) Uani 1 1 d . . .
H2WA H 1.0982 0.3655 0.1431 0.042 Uiso 1 1 d R . .
H2WB H 1.0127 0.4430 0.1837 0.042 Uiso 1 1 d R . .
O3 O 0.7029(4) 0.4613(4) 0.3473(2) 0.0254(9) Uani 1 1 d . . .
O3W O 0.4764(5) -0.0968(5) 0.3442(3) 0.0392(12) Uani 1 1 d . . .
H3WA H 0.4350 -0.1335 0.3072 0.059 Uiso 1 1 d R . .
H3WB H 0.4259 -0.1051 0.3767 0.059 Uiso 1 1 d R . .
O4 O 0.6127(5) 0.6093(4) 0.2986(2) 0.0280(10) Uani 1 1 d . . .
O4W O 0.8232(5) -0.3232(4) 0.4202(2) 0.0302(10) Uani 1 1 d . . .
H4WA H 0.7977 -0.4036 0.4067 0.045 Uiso 1 1 d R . .
H4WB H 0.9125 -0.3157 0.4145 0.045 Uiso 1 1 d R . .
O5 O 0.9024(4) 0.2812(4) 0.2845(2) 0.0242(9) Uani 1 1 d . . .
O5W O 0.7345(5) -0.0097(5) -0.0553(3) 0.0498(15) Uani 1 1 d . . .
O6 O 1.0967(5) 0.3979(5) 0.3056(2) 0.0367(12) Uani 1 1 d . . .
O6W O 1.425(5) -0.297(4) -0.018(2) 0.63(3) Uiso 1 1 d . . .
O7 O 0.4928(5) 0.1214(6) 0.1388(2) 0.0482(15) Uani 1 1 d . . .
O7W O 0.2378(6) -0.0444(5) 0.4124(3) 0.0485(14) Uani 1 1 d . . .
O8 O 0.6613(4) 0.1633(4) 0.2186(2) 0.0209(9) Uani 1 1 d . . .
O8W O 1.3189(9) 0.3601(10) 0.1172(4) 0.111(3) Uani 1 1 d . . .
O9 O 0.7582(4) 0.0369(4) 0.3594(2) 0.0261(10) Uani 1 1 d . . .
O10 O 0.8996(5) -0.0619(4) 0.4175(2) 0.0318(11) Uani 1 1 d . . .
O11 O 1.0587(5) -0.2970(5) 0.3644(2) 0.0408(13) Uani 1 1 d . . .
O12 O 0.9024(4) -0.2372(4) 0.2954(2) 0.0237(9) Uani 1 1 d . . .
O13 O 0.6600(4) -0.1756(4) 0.2377(2) 0.0224(9) Uani 1 1 d . . .
O14 O 0.4463(5) -0.1259(5) 0.2157(3) 0.0445(14) Uani 1 1 d . . .
O15 O 0.7314(5) -0.6213(4) 0.1631(2) 0.0276(10) Uani 1 1 d . . .
O16 O 0.8677(4) -0.4480(4) 0.1758(2) 0.0258(10) Uani 1 1 d . . .
O17 O 0.9170(4) -0.0126(4) 0.1872(2) 0.0250(9) Uani 1 1 d . . .
O18 O 1.0870(4) 0.1277(4) 0.2097(2) 0.0295(10) Uani 1 1 d . . .
O19 O 0.9825(5) -0.1239(4) -0.0700(2) 0.0293(10) Uani 1 1 d . . .
O20 O 1.0993(5) -0.2843(4) -0.0526(2) 0.0311(11) Uani 1 1 d . . .
N1 N 0.8891(5) 0.2647(4) 0.4172(2) 0.0199(10) Uani 1 1 d . . .
N2 N 0.5922(5) 0.2893(4) 0.4428(2) 0.0195(10) Uani 1 1 d . . .
N3 N 0.4811(5) 0.2934(4) 0.3048(2) 0.0200(10) Uani 1 1 d . . .
N4 N 1.0971(5) -0.2041(4) 0.2064(2) 0.0197(10) Uani 1 1 d . . .
N5 N 0.9538(5) -0.2854(4) 0.0711(2) 0.0191(10) Uani 1 1 d . . .
N6 N 0.6717(5) -0.3225(4) 0.1125(2) 0.0214(11) Uani 1 1 d . . .
C1 C 0.8665(7) 0.0342(5) 0.3958(3) 0.0228(13) Uani 1 1 d . . .
C2 C 0.9629(6) 0.1488(5) 0.4113(3) 0.0265(14) Uani 1 1 d . . .
H2A H 1.0155 0.1485 0.4528 0.032 Uiso 1 1 calc R . .
H2B H 1.0266 0.1454 0.3760 0.032 Uiso 1 1 calc R . .
C3 C 0.8380(7) 0.2992(6) 0.4855(3) 0.0280(14) Uani 1 1 d . . .
H3A H 0.9060 0.3543 0.5137 0.034 Uiso 1 1 calc R . .
H3B H 0.8274 0.2238 0.5042 0.034 Uiso 1 1 calc R . .
C4 C 0.7010(7) 0.3643(5) 0.4872(3) 0.0244(13) Uani 1 1 d . . .
H4A H 0.6716 0.3798 0.5327 0.029 Uiso 1 1 calc R . .
H4B H 0.7139 0.4447 0.4738 0.029 Uiso 1 1 calc R . .
C5 C 0.5429(7) 0.1753(5) 0.4662(3) 0.0234(14) Uani 1 1 d . . .
H5A H 0.6225 0.1304 0.4771 0.028 Uiso 1 1 calc R . .
H5B H 0.4921 0.1218 0.4290 0.028 Uiso 1 1 calc R . .
C6 C 0.4537(7) 0.1922(5) 0.5256(3) 0.0264(14) Uani 1 1 d . . .
C7 C 0.4750(7) 0.3633(6) 0.4275(3) 0.0251(13) Uani 1 1 d . . .
H7A H 0.5083 0.4465 0.4235 0.030 Uiso 1 1 calc R . .
H7B H 0.4143 0.3723 0.4642 0.030 Uiso 1 1 calc R . .
C8 C 0.3954(7) 0.3031(6) 0.3635(3) 0.0274(14) Uani 1 1 d . . .
H8A H 0.3619 0.2200 0.3674 0.033 Uiso 1 1 calc R . .
H8B H 0.3168 0.3525 0.3568 0.033 Uiso 1 1 calc R . .
C9 C 0.4274(6) 0.1928(5) 0.2494(3) 0.0231(13) Uani 1 1 d . . .
H9A H 0.3471 0.2211 0.2277 0.028 Uiso 1 1 calc R . .
H9B H 0.3999 0.1198 0.2674 0.028 Uiso 1 1 calc R . .
C10 C 0.5347(7) 0.1560(6) 0.1977(3) 0.0277(14) Uani 1 1 d . . .
C11 C 0.4913(7) 0.4148(6) 0.2809(3) 0.0271(14) Uani 1 1 d . . .
H11A H 0.4078 0.4589 0.2905 0.033 Uiso 1 1 calc R . .
H11B H 0.4979 0.3973 0.2328 0.033 Uiso 1 1 calc R . .
C12 C 0.6124(6) 0.4999(5) 0.3120(3) 0.0213(12) Uani 1 1 d . . .
C13 C 0.9790(6) 0.3644(5) 0.3994(3) 0.0223(12) Uani 1 1 d . . .
H13A H 1.0687 0.3638 0.4218 0.027 Uiso 1 1 calc R . .
H13B H 0.9410 0.4453 0.4153 0.027 Uiso 1 1 calc R . .
C14 C 0.9946(6) 0.3474(5) 0.3235(3) 0.0226(13) Uani 1 1 d . . .
C15 C 1.0225(6) -0.2719(5) 0.3099(3) 0.0225(13) Uani 1 1 d . . .
C16 C 1.1272(6) -0.2834(6) 0.2562(3) 0.0258(13) Uani 1 1 d . . .
H16A H 1.2176 -0.2597 0.2773 0.031 Uiso 1 1 calc R . .
H16B H 1.1283 -0.3702 0.2336 0.031 Uiso 1 1 calc R . .
C17 C 1.1301(6) -0.0709(5) 0.2371(3) 0.0247(13) Uani 1 1 d . . .
H17A H 1.2250 -0.0509 0.2302 0.030 Uiso 1 1 calc R . .
H17B H 1.1199 -0.0597 0.2849 0.030 Uiso 1 1 calc R . .
C18 C 1.0400(6) 0.0193(5) 0.2088(3) 0.0192(12) Uani 1 1 d . . .
C19 C 1.1699(6) -0.2421(6) 0.1436(3) 0.0278(14) Uani 1 1 d . . .
H19A H 1.2549 -0.2797 0.1542 0.033 Uiso 1 1 calc R . .
H19B H 1.1932 -0.1677 0.1260 0.033 Uiso 1 1 calc R . .
C20 C 1.0881(6) -0.3330(6) 0.0907(3) 0.0261(14) Uani 1 1 d . . .
H20A H 1.1415 -0.3522 0.0515 0.031 Uiso 1 1 calc R . .
H20B H 1.0719 -0.4103 0.1069 0.031 Uiso 1 1 calc R . .
C21 C 0.8579(7) -0.3832(6) 0.0339(3) 0.0260(14) Uani 1 1 d . . .
H21A H 0.8708 -0.4606 0.0501 0.031 Uiso 1 1 calc R . .
H21B H 0.8774 -0.3980 -0.0131 0.031 Uiso 1 1 calc R . .
C22 C 0.7096(7) -0.3464(6) 0.0413(3) 0.0259(13) Uani 1 1 d . . .
H22A H 0.6956 -0.2715 0.0228 0.031 Uiso 1 1 calc R . .
H22B H 0.6497 -0.4131 0.0159 0.031 Uiso 1 1 calc R . .
C23 C 0.5634(6) -0.2320(6) 0.1242(3) 0.0260(13) Uani 1 1 d . . .
H23A H 0.4762 -0.2737 0.1072 0.031 Uiso 1 1 calc R . .
H23B H 0.5805 -0.1657 0.0994 0.031 Uiso 1 1 calc R . .
C24 C 0.5533(6) -0.1732(5) 0.1987(3) 0.0227(13) Uani 1 1 d . . .
C25 C 0.9663(6) -0.1771(5) 0.0374(3) 0.0234(13) Uani 1 1 d . . .
H25A H 1.0275 -0.1145 0.0652 0.028 Uiso 1 1 calc R . .
H25B H 0.8769 -0.1411 0.0356 0.028 Uiso 1 1 calc R . .
C26 C 1.0179(7) -0.2004(6) -0.0334(3) 0.0261(14) Uani 1 1 d . . .
C27 C 0.7541(6) -0.5070(5) 0.1595(3) 0.0213(13) Uani 1 1 d . . .
C28 C 0.6344(6) -0.4400(5) 0.1344(3) 0.0245(13) Uani 1 1 d . . .
H28A H 0.5865 -0.4963 0.0973 0.029 Uiso 1 1 calc R . .
H28B H 0.5711 -0.4217 0.1699 0.029 Uiso 1 1 calc R . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Gd1 O15 2.394(4) 1_565 ?
Gd1 O1W 2.414(5) . ?
Gd1 O2W 2.431(4) . ?
Gd1 O19 2.434(4) 2_755 ?
Gd1 O18 2.478(5) . ?
Gd1 O5 2.482(4) . ?
Gd1 O8 2.508(4) . ?
Gd1 O17 2.547(4) . ?
Gd1 O20 2.560(4) 2_755 ?
Gd1 C26 2.860(6) 2_755 ?
Gd1 C18 2.885(6) . ?
Gd2 O4 2.375(4) 1_545 ?
Gd2 O4W 2.426(5) . ?
Gd2 O3W 2.424(5) . ?
Gd2 O1 2.450(4) 2_656 ?
Gd2 O12 2.466(4) . ?
Gd2 O13 2.501(4) . ?
Gd2 O2 2.511(4) 2_656 ?
Gd2 O9 2.529(4) . ?
Gd2 O10 2.530(5) . ?
Gd2 C6 2.841(6) 2_656 ?
Gd2 C1 2.884(6) . ?
Cd1 O5 2.348(4) . ?
Cd1 N3 2.363(5) . ?
Cd1 N1 2.375(5) . ?
Cd1 O9 2.374(4) . ?
Cd1 O8 2.392(4) . ?
Cd1 O3 2.416(4) . ?
Cd1 N2 2.452(5) . ?
Cd2 O13 2.343(4) . ?
Cd2 N4 2.344(5) . ?
Cd2 N6 2.356(5) . ?
Cd2 O12 2.360(4) . ?
Cd2 O17 2.360(4) . ?
Cd2 O16 2.385(4) . ?
Cd2 N5 2.456(5) . ?
O1 C6 1.280(8) . ?
O1 Gd2 2.450(4) 2_656 ?
O2 C6 1.247(7) . ?
O2 Gd2 2.511(4) 2_656 ?
O3 C12 1.245(8) . ?
O4 C12 1.269(7) . ?
O4 Gd2 2.375(4) 1_565 ?
O5 C14 1.280(8) . ?
O6 C14 1.227(7) . ?
O7 C10 1.235(8) . ?
O8 C10 1.284(8) . ?
O9 C1 1.268(8) . ?
O10 C1 1.253(7) . ?
O11 C15 1.233(8) . ?
O12 C15 1.283(7) . ?
O13 C24 1.284(8) . ?
O14 C24 1.217(7) . ?
O15 C27 1.272(7) . ?
O15 Gd1 2.394(4) 1_545 ?
O16 C27 1.263(8) . ?
O17 C18 1.276(7) . ?
O18 C18 1.248(7) . ?
O19 C26 1.261(8) . ?
O19 Gd1 2.434(4) 2_755 ?
O20 C26 1.249(7) . ?
O20 Gd1 2.560(4) 2_755 ?
N1 C2 1.460(7) . ?
N1 C13 1.482(7) . ?
N1 C3 1.489(7) . ?
N2 C7 1.475(8) . ?
N2 C4 1.481(8) . ?
N2 C5 1.483(7) . ?
N3 C9 1.481(7) . ?
N3 C8 1.483(7) . ?
N3 C11 1.491(7) . ?
N4 C16 1.475(7) . ?
N4 C17 1.485(7) . ?
N4 C19 1.491(7) . ?
N5 C21 1.467(8) . ?
N5 C25 1.475(7) . ?
N5 C20 1.491(8) . ?
N6 C23 1.466(7) . ?
N6 C28 1.472(7) . ?
N6 C22 1.492(7) . ?
C1 C2 1.514(8) . ?
C3 C4 1.533(9) . ?
C5 C6 1.514(8) . ?
C6 Gd2 2.841(6) 2_656 ?
C7 C8 1.514(9) . ?
C9 C10 1.532(8) . ?
C11 C12 1.517(9) . ?
C13 C14 1.541(8) . ?
C15 C16 1.525(8) . ?
C17 C18 1.512(8) . ?
C19 C20 1.500(9) . ?
C21 C22 1.523(9) . ?
C23 C24 1.543(8) . ?
C25 C26 1.531(8) . ?
C26 Gd1 2.860(6) 2_755 ?
C27 C28 1.515(9) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O15 Gd1 O1W 91.48(17) 1_565 . ?
O15 Gd1 O2W 80.84(15) 1_565 . ?
O1W Gd1 O2W 143.86(16) . . ?
O15 Gd1 O19 123.80(15) 1_565 2_755 ?
O1W Gd1 O19 74.67(16) . 2_755 ?
O2W Gd1 O19 80.52(15) . 2_755 ?
O15 Gd1 O18 145.84(15) 1_565 . ?
O1W Gd1 O18 122.66(16) . . ?
O2W Gd1 O18 71.90(14) . . ?
O19 Gd1 O18 72.07(16) 2_755 . ?
O15 Gd1 O5 84.48(15) 1_565 . ?
O1W Gd1 O5 140.20(14) . . ?
O2W Gd1 O5 74.54(14) . . ?
O19 Gd1 O5 138.48(16) 2_755 . ?
O18 Gd1 O5 68.90(15) . . ?
O15 Gd1 O8 71.44(13) 1_565 . ?
O1W Gd1 O8 72.73(14) . . ?
O2W Gd1 O8 135.17(14) . . ?
O19 Gd1 O8 144.29(15) 2_755 . ?
O18 Gd1 O8 114.90(14) . . ?
O5 Gd1 O8 68.45(14) . . ?
O15 Gd1 O17 150.27(13) 1_565 . ?
O1W Gd1 O17 77.81(17) . . ?
O2W Gd1 O17 123.56(15) . . ?
O19 Gd1 O17 80.39(14) 2_755 . ?
O18 Gd1 O17 51.71(14) . . ?
O5 Gd1 O17 86.37(14) . . ?
O8 Gd1 O17 78.88(13) . . ?
O15 Gd1 O20 71.91(14) 1_565 2_755 ?
O1W Gd1 O20 73.93(16) . 2_755 ?
O2W Gd1 O20 70.11(16) . 2_755 ?
O19 Gd1 O20 51.89(14) 2_755 2_755 ?
O18 Gd1 O20 115.51(15) . 2_755 ?
O5 Gd1 O20 139.89(14) . 2_755 ?
O8 Gd1 O20 128.92(15) . 2_755 ?
O17 Gd1 O20 129.17(14) . 2_755 ?
O15 Gd1 C26 97.80(16) 1_565 2_755 ?
O1W Gd1 C26 72.05(17) . 2_755 ?
O2W Gd1 C26 74.10(17) . 2_755 ?
O19 Gd1 C26 26.01(16) 2_755 2_755 ?
O18 Gd1 C26 94.19(17) . 2_755 ?
O5 Gd1 C26 147.74(16) . 2_755 ?
O8 Gd1 C26 142.78(17) . 2_755 ?
O17 Gd1 C26 104.89(16) . 2_755 ?
O20 Gd1 C26 25.89(16) 2_755 2_755 ?
O15 Gd1 C18 160.41(15) 1_565 . ?
O1W Gd1 C18 100.83(17) . . ?
O2W Gd1 C18 97.36(16) . . ?
O19 Gd1 C18 74.61(15) 2_755 . ?
O18 Gd1 C18 25.48(15) . . ?
O5 Gd1 C18 76.29(15) . . ?
O8 Gd1 C18 97.57(15) . . ?
O17 Gd1 C18 26.23(15) . . ?
O20 Gd1 C18 126.04(14) 2_755 . ?
C26 Gd1 C18 100.46(17) 2_755 . ?
O4 Gd2 O4W 80.66(16) 1_545 . ?
O4 Gd2 O3W 92.98(17) 1_545 . ?
O4W Gd2 O3W 145.00(15) . . ?
O4 Gd2 O1 123.46(14) 1_545 2_656 ?
O4W Gd2 O1 79.58(15) . 2_656 ?
O3W Gd2 O1 75.47(17) . 2_656 ?
O4 Gd2 O12 84.39(15) 1_545 . ?
O4W Gd2 O12 75.57(14) . . ?
O3W Gd2 O12 138.43(15) . . ?
O1 Gd2 O12 138.66(16) 2_656 . ?
O4 Gd2 O13 72.37(14) 1_545 . ?
O4W Gd2 O13 135.54(14) . . ?
O3W Gd2 O13 72.35(15) . . ?
O1 Gd2 O13 144.88(14) 2_656 . ?
O12 Gd2 O13 67.33(14) . . ?
O4 Gd2 O2 70.90(14) 1_545 2_656 ?
O4W Gd2 O2 71.83(16) . 2_656 ?
O3W Gd2 O2 73.56(17) . 2_656 ?
O1 Gd2 O2 52.64(14) 2_656 2_656 ?
O12 Gd2 O2 141.59(14) . 2_656 ?
O13 Gd2 O2 127.55(15) . 2_656 ?
O4 Gd2 O9 149.85(15) 1_545 . ?
O4W Gd2 O9 124.03(16) . . ?
O3W Gd2 O9 76.00(16) . . ?
O1 Gd2 O9 81.42(14) 2_656 . ?
O12 Gd2 O9 85.76(14) . . ?
O13 Gd2 O9 77.53(14) . . ?
O2 Gd2 O9 129.61(14) 2_656 . ?
O4 Gd2 O10 145.93(15) 1_545 . ?
O4W Gd2 O10 72.31(15) . . ?
O3W Gd2 O10 121.04(16) . . ?
O1 Gd2 O10 71.96(16) 2_656 . ?
O12 Gd2 O10 69.27(15) . . ?
O13 Gd2 O10 113.84(14) . . ?
O2 Gd2 O10 117.66(16) 2_656 . ?
O9 Gd2 O10 51.76(15) . . ?
O4 Gd2 C6 96.92(16) 1_545 2_656 ?
O4W Gd2 C6 75.56(17) . 2_656 ?
O3W Gd2 C6 71.09(18) . 2_656 ?
O1 Gd2 C6 26.71(16) 2_656 2_656 ?
O12 Gd2 C6 150.47(17) . 2_656 ?
O13 Gd2 C6 141.19(17) . 2_656 ?
O2 Gd2 C6 26.02(16) 2_656 2_656 ?
O9 Gd2 C6 105.51(15) . 2_656 ?
O10 Gd2 C6 96.01(18) . 2_656 ?
O4 Gd2 C1 159.72(15) 1_545 . ?
O4W Gd2 C1 98.01(17) . . ?
O3W Gd2 C1 99.13(18) . . ?
O1 Gd2 C1 75.65(15) 2_656 . ?
O12 Gd2 C1 75.74(15) . . ?
O13 Gd2 C1 95.81(16) . . ?
O2 Gd2 C1 128.17(15) 2_656 . ?
O9 Gd2 C1 26.06(16) . . ?
O10 Gd2 C1 25.71(16) . . ?
C6 Gd2 C1 102.36(18) 2_656 . ?
O5 Cd1 N3 124.27(16) . . ?
O5 Cd1 N1 71.32(16) . . ?
N3 Cd1 N1 147.99(16) . . ?
O5 Cd1 O9 98.82(15) . . ?
N3 Cd1 O9 125.29(16) . . ?
N1 Cd1 O9 71.62(16) . . ?
O5 Cd1 O8 72.59(15) . . ?
N3 Cd1 O8 71.51(15) . . ?
N1 Cd1 O8 138.66(15) . . ?
O9 Cd1 O8 94.90(15) . . ?
O5 Cd1 O3 77.10(14) . . ?
N3 Cd1 O3 71.35(16) . . ?
N1 Cd1 O3 87.83(16) . . ?
O9 Cd1 O3 159.15(16) . . ?
O8 Cd1 O3 103.13(15) . . ?
O5 Cd1 N2 141.05(16) . . ?
N3 Cd1 N2 76.38(17) . . ?
N1 Cd1 N2 76.39(17) . . ?
O9 Cd1 N2 90.97(15) . . ?
O8 Cd1 N2 144.28(16) . . ?
O3 Cd1 N2 80.53(15) . . ?
O13 Cd2 N4 137.24(16) . . ?
O13 Cd2 N6 71.82(15) . . ?
N4 Cd2 N6 150.13(16) . . ?
O13 Cd2 O12 71.67(15) . . ?
N4 Cd2 O12 71.66(15) . . ?
N6 Cd2 O12 125.92(16) . . ?
O13 Cd2 O17 90.58(14) . . ?
N4 Cd2 O17 74.23(16) . . ?
N6 Cd2 O17 119.82(16) . . ?
O12 Cd2 O17 98.97(16) . . ?
O13 Cd2 O16 103.05(14) . . ?
N4 Cd2 O16 90.74(16) . . ?
N6 Cd2 O16 72.10(16) . . ?
O12 Cd2 O16 78.94(15) . . ?
O17 Cd2 O16 164.59(15) . . ?
O13 Cd2 N5 144.22(16) . . ?
N4 Cd2 N5 77.37(17) . . ?
N6 Cd2 N5 75.93(16) . . ?
O12 Cd2 N5 142.55(15) . . ?
O17 Cd2 N5 92.24(15) . . ?
O16 Cd2 N5 80.95(15) . . ?
C6 O1 Gd2 93.9(4) . 2_656 ?
C6 O2 Gd2 92.0(4) . 2_656 ?
C12 O3 Cd1 114.5(4) . . ?
C12 O4 Gd2 133.5(4) . 1_565 ?
C14 O5 Cd1 114.8(3) . . ?
C14 O5 Gd1 134.3(3) . . ?
Cd1 O5 Gd1 110.62(17) . . ?
C10 O8 Cd1 115.0(4) . . ?
C10 O8 Gd1 131.2(4) . . ?
Cd1 O8 Gd1 108.30(16) . . ?
C1 O9 Cd1 116.1(4) . . ?
C1 O9 Gd2 92.8(3) . . ?
Cd1 O9 Gd2 150.6(2) . . ?
C1 O10 Gd2 93.1(4) . . ?
C15 O12 Cd2 114.5(3) . . ?
C15 O12 Gd2 134.6(4) . . ?
Cd2 O12 Gd2 110.80(17) . . ?
C24 O13 Cd2 114.1(3) . . ?
C24 O13 Gd2 133.7(4) . . ?
Cd2 O13 Gd2 110.15(17) . . ?
C27 O15 Gd1 133.5(4) . 1_545 ?
C27 O16 Cd2 114.4(4) . . ?
C18 O17 Cd2 113.8(4) . . ?
C18 O17 Gd1 91.9(3) . . ?
Cd2 O17 Gd1 153.8(2) . . ?
C18 O18 Gd1 95.8(4) . . ?
C26 O19 Gd1 96.2(4) . 2_755 ?
C26 O20 Gd1 90.6(4) . 2_755 ?
C2 N1 C13 109.4(4) . . ?
C2 N1 C3 110.0(5) . . ?
C13 N1 C3 112.8(5) . . ?
C2 N1 Cd1 109.2(4) . . ?
C13 N1 Cd1 105.2(4) . . ?
C3 N1 Cd1 110.0(4) . . ?
C7 N2 C4 113.3(5) . . ?
C7 N2 C5 110.1(5) . . ?
C4 N2 C5 114.3(5) . . ?
C7 N2 Cd1 104.1(3) . . ?
C4 N2 Cd1 102.9(3) . . ?
C5 N2 Cd1 111.5(3) . . ?
C9 N3 C8 111.5(5) . . ?
C9 N3 C11 109.8(5) . . ?
C8 N3 C11 111.3(5) . . ?
C9 N3 Cd1 106.3(3) . . ?
C8 N3 Cd1 108.4(4) . . ?
C11 N3 Cd1 109.4(4) . . ?
C16 N4 C17 109.2(5) . . ?
C16 N4 C19 112.9(5) . . ?
C17 N4 C19 111.3(4) . . ?
C16 N4 Cd2 106.0(3) . . ?
C17 N4 Cd2 108.0(3) . . ?
C19 N4 Cd2 109.2(4) . . ?
C21 N5 C25 111.8(5) . . ?
C21 N5 C20 113.9(4) . . ?
C25 N5 C20 113.7(5) . . ?
C21 N5 Cd2 105.0(3) . . ?
C25 N5 Cd2 111.7(3) . . ?
C20 N5 Cd2 99.8(3) . . ?
C23 N6 C28 111.5(5) . . ?
C23 N6 C22 111.9(5) . . ?
C28 N6 C22 111.3(5) . . ?
C23 N6 Cd2 104.6(4) . . ?
C28 N6 Cd2 107.5(4) . . ?
C22 N6 Cd2 109.6(4) . . ?
O10 C1 O9 122.3(6) . . ?
O10 C1 C2 118.5(6) . . ?
O9 C1 C2 119.1(5) . . ?
O10 C1 Gd2 61.2(3) . . ?
O9 C1 Gd2 61.2(3) . . ?
C2 C1 Gd2 175.8(4) . . ?
N1 C2 C1 111.8(5) . . ?
N1 C3 C4 113.6(5) . . ?
N2 C4 C3 112.6(5) . . ?
N2 C5 C6 117.9(5) . . ?
O2 C6 O1 121.1(5) . . ?
O2 C6 C5 122.0(6) . . ?
O1 C6 C5 116.9(5) . . ?
O2 C6 Gd2 62.0(3) . 2_656 ?
O1 C6 Gd2 59.3(3) . 2_656 ?
C5 C6 Gd2 171.3(4) . 2_656 ?
N2 C7 C8 112.2(5) . . ?
N3 C8 C7 111.7(5) . . ?
N3 C9 C10 111.7(5) . . ?
O7 C10 O8 124.8(6) . . ?
O7 C10 C9 117.3(6) . . ?
O8 C10 C9 117.8(6) . . ?
N3 C11 C12 114.3(5) . . ?
O3 C12 O4 124.5(6) . . ?
O3 C12 C11 120.7(5) . . ?
O4 C12 C11 114.8(6) . . ?
N1 C13 C14 112.2(5) . . ?
O6 C14 O5 125.5(6) . . ?
O6 C14 C13 116.4(6) . . ?
O5 C14 C13 118.1(5) . . ?
O11 C15 O12 124.2(5) . . ?
O11 C15 C16 117.8(6) . . ?
O12 C15 C16 118.0(5) . . ?
N4 C16 C15 112.5(5) . . ?
N4 C17 C18 113.1(5) . . ?
O18 C18 O17 120.6(5) . . ?
O18 C18 C17 118.3(5) . . ?
O17 C18 C17 121.0(5) . . ?
O18 C18 Gd1 58.7(3) . . ?
O17 C18 Gd1 61.9(3) . . ?
C17 C18 Gd1 176.2(4) . . ?
N4 C19 C20 113.7(5) . . ?
N5 C20 C19 113.5(5) . . ?
N5 C21 C22 111.7(5) . . ?
N6 C22 C21 112.4(5) . . ?
N6 C23 C24 113.2(5) . . ?
O14 C24 O13 125.1(6) . . ?
O14 C24 C23 117.6(6) . . ?
O13 C24 C23 117.2(5) . . ?
N5 C25 C26 117.7(5) . . ?
O20 C26 O19 121.3(6) . . ?
O20 C26 C25 122.1(6) . . ?
O19 C26 C25 116.4(5) . . ?
O20 C26 Gd1 63.5(3) . 2_755 ?
O19 C26 Gd1 57.8(3) . 2_755 ?
C25 C26 Gd1 171.4(4) . 2_755 ?
O16 C27 O15 124.2(6) . . ?
O16 C27 C28 119.6(5) . . ?
O15 C27 C28 116.2(6) . . ?
N6 C28 C27 114.8(5) . . ?

_diffrn_measured_fraction_theta_max 0.977
_diffrn_reflns_theta_full        27.47
_diffrn_measured_fraction_theta_full 0.977
_refine_diff_density_max         1.882
_refine_diff_density_min         -2.644
_refine_diff_density_rms         0.207
_database_code_depnum_ccdc_archive 'CCDC 975528'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_3

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C28 H48 Cd3 Cl2 Eu2 N6 O26'
_chemical_formula_sum            'C28 H48 Cd3 Cl2 Eu2 N6 O26'
_chemical_formula_weight         1596.74

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.6545(17)
_cell_length_b                   9.0700(18)
_cell_length_c                   15.407(3)
_cell_angle_alpha                98.47(3)
_cell_angle_beta                 101.37(3)
_cell_angle_gamma                103.33(3)
_cell_volume                     1129.9(4)
_cell_formula_units_Z            1
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    4098
_cell_measurement_theta_min      3.1214
_cell_measurement_theta_max      27.4816

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.347
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             770
_exptl_absorpt_coefficient_mu    4.338
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Saturn724 (2x2 bin mode)'
_diffrn_measurement_method       dtprofit.ref
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            9515
_diffrn_reflns_av_R_equivalents  0.0310
_diffrn_reflns_av_sigmaI/netI    0.0356
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         3.19
_diffrn_reflns_theta_max         27.49
_reflns_number_total             4978
_reflns_number_gt                4779
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'CrystalClear (Rigaku Corp., 2000)'
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2000)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0211P)²+1.9696P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4978
_refine_ls_number_parameters     307
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0317
_refine_ls_R_factor_gt           0.0298
_refine_ls_wR_factor_ref         0.0671
_refine_ls_wR_factor_gt          0.0661
_refine_ls_goodness_of_fit_ref   1.111
_refine_ls_restrained_S_all      1.111
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu Eu 0.18670(2) 0.30717(2) 0.224880(12) 0.02022(6) Uani 1 1 d . . .
Cd1 Cd 0.0000 0.0000 0.5000 0.02776(10) Uani 1 2 d S . .
Cd2 Cd 0.07835(4) 0.24960(4) -0.09738(2) 0.03105(8) Uani 1 1 d . . .
O1 O 0.0510(5) 0.2544(4) 0.4844(2) 0.0425(8) Uani 1 1 d . . .
O1W O -0.2662(4) -0.0065(5) 0.5026(3) 0.0495(9) Uani 1 1 d . . .
H1WA H -0.2744 0.0172 0.5584 0.074 Uiso 1 1 d R . .
H1WB H -0.2975 0.0612 0.4733 0.074 Uiso 1 1 d R . .
O2 O 0.0271(4) 0.2537(3) 0.33645(19) 0.0312(7) Uani 1 1 d . . .
O2W O -0.0914(5) -0.0584(4) 0.3496(2) 0.0425(8) Uani 1 1 d . . .
H2WA H -0.1884 -0.1220 0.3344 0.064 Uiso 1 1 d R . .
H2WB H -0.0966 0.0250 0.3293 0.064 Uiso 1 1 d R . .
O3 O -0.0066(4) 0.7283(4) 0.2399(2) 0.0388(8) Uani 1 1 d . . .
O3W O -0.0960(4) 0.2149(4) 0.1341(2) 0.0337(7) Uani 1 1 d . . .
H3WA H -0.1405 0.1188 0.1371 0.051 Uiso 1 1 d R . .
H3WB H -0.1547 0.2731 0.1542 0.051 Uiso 1 1 d R . .
O4 O 0.0782(4) 0.5247(3) 0.19530(19) 0.0284(6) Uani 1 1 d . . .
Cl Cl 0.28858(13) 0.11756(13) -0.12419(8) 0.0349(2) Uani 1 1 d . . .
O5 O 0.3587(4) 0.2489(4) 0.3454(2) 0.0408(8) Uani 1 1 d . . .
O6 O 0.4968(6) 0.0958(6) 0.4021(3) 0.0722(15) Uani 1 1 d . . .
O7 O 0.1382(4) 0.0344(3) 0.1663(2) 0.0352(7) Uani 1 1 d . . .
O8 O 0.1622(4) -0.1556(3) 0.0674(2) 0.0362(7) Uani 1 1 d . . .
O9 O 0.1968(3) 0.3309(3) 0.07274(18) 0.0253(6) Uani 1 1 d . . .
O10 O 0.2417(5) 0.4842(4) -0.0232(2) 0.0436(9) Uani 1 1 d . . .
N1 N 0.2473(4) 0.5299(4) 0.3674(2) 0.0266(7) Uani 1 1 d . . .
N2 N 0.4243(4) 0.5394(4) 0.2178(2) 0.0252(7) Uani 1 1 d . . .
N3 N 0.4473(4) 0.2086(4) 0.1851(2) 0.0245(7) Uani 1 1 d . . .
C1 C 0.0889(6) 0.3111(5) 0.4196(3) 0.0309(9) Uani 1 1 d . . .
C2 C 0.2267(6) 0.4589(5) 0.4458(3) 0.0319(9) Uani 1 1 d . . .
H2A H 0.2039 0.5318 0.4911 0.038 Uiso 1 1 calc R . .
H2B H 0.3278 0.4363 0.4723 0.038 Uiso 1 1 calc R . .
C3 C 0.1292(6) 0.6239(5) 0.3534(3) 0.0299(9) Uani 1 1 d . . .
H3A H 0.1821 0.7294 0.3857 0.036 Uiso 1 1 calc R . .
H3B H 0.0383 0.5839 0.3791 0.036 Uiso 1 1 calc R . .
C4 C 0.0640(5) 0.6250(4) 0.2558(3) 0.0241(8) Uani 1 1 d . . .
C5 C 0.4171(5) 0.6223(5) 0.3788(3) 0.0335(10) Uani 1 1 d . . .
H5A H 0.4913 0.5614 0.3979 0.040 Uiso 1 1 calc R . .
H5B H 0.4403 0.7131 0.4263 0.040 Uiso 1 1 calc R . .
C6 C 0.4487(5) 0.6735(5) 0.2929(3) 0.0309(9) Uani 1 1 d . . .
H6A H 0.3753 0.7353 0.2740 0.037 Uiso 1 1 calc R . .
H6B H 0.5599 0.7381 0.3053 0.037 Uiso 1 1 calc R . .
C7 C 0.5778(5) 0.4900(5) 0.2260(3) 0.0324(9) Uani 1 1 d . . .
H7A H 0.6147 0.4782 0.2876 0.039 Uiso 1 1 calc R . .
H7B H 0.6614 0.5706 0.2140 0.039 Uiso 1 1 calc R . .
C8 C 0.5594(5) 0.3391(5) 0.1620(3) 0.0307(9) Uani 1 1 d . . .
H8A H 0.5167 0.3478 0.1004 0.037 Uiso 1 1 calc R . .
H8B H 0.6657 0.3192 0.1659 0.037 Uiso 1 1 calc R . .
C9 C 0.5315(5) 0.1542(6) 0.2629(3) 0.0318(9) Uani 1 1 d . . .
H9A H 0.6450 0.2144 0.2816 0.038 Uiso 1 1 calc R . .
H9B H 0.5298 0.0471 0.2432 0.038 Uiso 1 1 calc R . .
C10 C 0.4573(6) 0.1663(6) 0.3424(3) 0.0369(10) Uani 1 1 d . . .
C11 C 0.3759(5) 0.0789(5) 0.1071(3) 0.0278(9) Uani 1 1 d . . .
H11A H 0.4523 0.0165 0.1030 0.033 Uiso 1 1 calc R . .
H11B H 0.3582 0.1193 0.0521 0.033 Uiso 1 1 calc R . .
C12 C 0.2155(5) -0.0214(5) 0.1148(3) 0.0265(8) Uani 1 1 d . . .
C13 C 0.3840(5) 0.5844(5) 0.1293(3) 0.0294(9) Uani 1 1 d . . .
H13A H 0.4846 0.6187 0.1104 0.035 Uiso 1 1 calc R . .
H13B H 0.3375 0.6717 0.1369 0.035 Uiso 1 1 calc R . .
C14 C 0.2662(5) 0.4580(5) 0.0550(3) 0.0262(8) Uani 1 1 d . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu O5 2.346(3) . ?
Eu O9 2.402(3) . ?
Eu O7 2.414(3) . ?
Eu O4 2.436(3) . ?
Eu O2 2.444(3) . ?
Eu O3W 2.450(3) . ?
Eu N2 2.615(3) . ?
Eu N1 2.632(3) . ?
Eu N3 2.752(3) . ?
Eu C14 3.245(4) . ?
Cd1 O2W 2.236(3) 2_556 ?
Cd1 O2W 2.236(3) . ?
Cd1 O1W 2.299(3) . ?
Cd1 O1W 2.299(3) 2_556 ?
Cd1 O1 2.305(3) 2_556 ?
Cd1 O1 2.305(3) . ?
Cd2 O3 2.212(3) 2_565 ?
Cd2 O8 2.225(3) 2 ?
Cd2 O10 2.256(3) . ?
Cd2 Cl 2.4639(13) . ?
Cd2 O9 2.547(3) . ?
Cd2 C14 2.738(4) . ?
O1 C1 1.252(5) . ?
O2 C1 1.267(5) . ?
O3 C4 1.259(5) . ?
O3 Cd2 2.212(3) 2_565 ?
O4 C4 1.249(5) . ?
O5 C10 1.262(5) . ?
O6 C10 1.234(6) . ?
O7 C12 1.258(5) . ?
O8 C12 1.254(5) . ?
O8 Cd2 2.225(3) 2 ?
O9 C14 1.266(5) . ?
O10 C14 1.249(5) . ?
N1 C2 1.472(5) . ?
N1 C5 1.476(6) . ?
N1 C3 1.479(5) . ?
N2 C13 1.480(5) . ?
N2 C7 1.485(5) . ?
N2 C6 1.494(5) . ?
N3 C11 1.471(5) . ?
N3 C8 1.483(5) . ?
N3 C9 1.486(5) . ?
C1 C2 1.516(6) . ?
C3 C4 1.500(6) . ?
C5 C6 1.520(6) . ?
C7 C8 1.519(6) . ?
C9 C10 1.493(6) . ?
C11 C12 1.512(6) . ?
C13 C14 1.510(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Eu O9 135.00(10) . . ?
O5 Eu O7 81.56(12) . . ?
O9 Eu O7 83.96(11) . . ?
O5 Eu O4 136.94(11) . . ?
O9 Eu O4 73.23(10) . . ?
O7 Eu O4 140.41(11) . . ?
O5 Eu O2 73.18(11) . . ?
O9 Eu O2 149.68(10) . . ?
O7 Eu O2 91.42(10) . . ?
O4 Eu O2 92.49(10) . . ?
O5 Eu O3W 139.65(12) . . ?
O9 Eu O3W 73.50(10) . . ?
O7 Eu O3W 73.18(11) . . ?
O4 Eu O3W 69.54(10) . . ?
O2 Eu O3W 76.48(11) . . ?
O5 Eu N2 90.29(12) . . ?
O9 Eu N2 67.26(10) . . ?
O7 Eu N2 129.37(11) . . ?
O4 Eu N2 70.43(11) . . ?
O2 Eu N2 133.73(10) . . ?
O3W Eu N2 130.05(11) . . ?
O5 Eu N1 71.66(11) . . ?
O9 Eu N1 128.08(10) . . ?
O7 Eu N1 147.54(11) . . ?
O4 Eu N1 65.66(10) . . ?
O2 Eu N1 63.83(11) . . ?
O3W Eu N1 116.87(11) . . ?
N2 Eu N1 69.99(11) . . ?
O5 Eu N3 64.08(10) . . ?
O9 Eu N3 71.36(10) . . ?
O7 Eu N3 62.90(10) . . ?
O4 Eu N3 133.48(10) . . ?
O2 Eu N3 132.20(10) . . ?
O3W Eu N3 125.47(10) . . ?
N2 Eu N3 68.61(10) . . ?
N1 Eu N3 117.57(11) . . ?
O5 Eu C14 131.12(11) . . ?
O9 Eu C14 19.47(10) . . ?
O7 Eu C14 102.20(11) . . ?
O4 Eu C14 62.42(10) . . ?
O2 Eu C14 153.27(10) . . ?
O3W Eu C14 85.50(10) . . ?
N2 Eu C14 49.51(10) . . ?
N1 Eu C14 109.14(10) . . ?
N3 Eu C14 74.46(10) . . ?
O2W Cd1 O2W 180.0 2_556 . ?
O2W Cd1 O1W 94.52(14) 2_556 . ?
O2W Cd1 O1W 85.48(14) . . ?
O2W Cd1 O1W 85.48(14) 2_556 2_556 ?
O2W Cd1 O1W 94.52(14) . 2_556 ?
O1W Cd1 O1W 180.00(19) . 2_556 ?
O2W Cd1 O1 85.61(13) 2_556 2_556 ?
O2W Cd1 O1 94.39(13) . 2_556 ?
O1W Cd1 O1 89.34(14) . 2_556 ?
O1W Cd1 O1 90.66(14) 2_556 2_556 ?
O2W Cd1 O1 94.39(13) 2_556 . ?
O2W Cd1 O1 85.61(13) . . ?
O1W Cd1 O1 90.66(14) . . ?
O1W Cd1 O1 89.34(14) 2_556 . ?
O1 Cd1 O1 180.000(1) 2_556 . ?
O3 Cd2 O8 102.37(13) 2_565 2 ?
O3 Cd2 O10 105.26(12) 2_565 . ?
O8 Cd2 O10 121.07(13) 2 . ?
O3 Cd2 Cl 93.74(9) 2_565 . ?
O8 Cd2 Cl 129.39(9) 2 . ?
O10 Cd2 Cl 99.46(11) . . ?
O3 Cd2 O9 158.94(11) 2_565 . ?
O8 Cd2 O9 87.32(11) 2 . ?
O10 Cd2 O9 54.17(10) . . ?
Cl Cd2 O9 94.35(7) . . ?
O3 Cd2 C14 132.03(12) 2_565 . ?
O8 Cd2 C14 106.23(12) 2 . ?
O10 Cd2 C14 26.80(11) . . ?
Cl Cd2 C14 96.80(9) . . ?
O9 Cd2 C14 27.40(10) . . ?
C1 O1 Cd1 128.7(3) . . ?
C1 O2 Eu 120.4(3) . . ?
C4 O3 Cd2 117.5(3) . 2_565 ?
C4 O4 Eu 123.8(3) . . ?
C10 O5 Eu 128.5(3) . . ?
C12 O7 Eu 124.4(3) . . ?
C12 O8 Cd2 104.9(3) . 2 ?
C14 O9 Eu 121.3(3) . . ?
C14 O9 Cd2 84.7(2) . . ?
Eu O9 Cd2 151.18(12) . . ?
C14 O10 Cd2 98.6(3) . . ?
C2 N1 C5 111.9(3) . . ?
C2 N1 C3 108.2(3) . . ?
C5 N1 C3 111.9(3) . . ?
C2 N1 Eu 108.4(2) . . ?
C5 N1 Eu 106.3(2) . . ?
C3 N1 Eu 110.1(2) . . ?
C13 N2 C7 108.9(3) . . ?
C13 N2 C6 110.2(3) . . ?
C7 N2 C6 109.1(3) . . ?
C13 N2 Eu 108.7(2) . . ?
C7 N2 Eu 109.1(2) . . ?
C6 N2 Eu 110.8(2) . . ?
C11 N3 C8 111.5(3) . . ?
C11 N3 C9 109.9(3) . . ?
C8 N3 C9 111.4(3) . . ?
C11 N3 Eu 105.4(2) . . ?
C8 N3 Eu 108.1(2) . . ?
C9 N3 Eu 110.4(2) . . ?
O1 C1 O2 126.2(4) . . ?
O1 C1 C2 115.2(4) . . ?
O2 C1 C2 118.5(4) . . ?
N1 C2 C1 111.7(3) . . ?
N1 C3 C4 113.5(3) . . ?
O4 C4 O3 123.3(4) . . ?
O4 C4 C3 120.0(4) . . ?
O3 C4 C3 116.7(3) . . ?
N1 C5 C6 112.9(3) . . ?
N2 C6 C5 112.2(3) . . ?
N2 C7 C8 113.6(3) . . ?
N3 C8 C7 110.7(3) . . ?
N3 C9 C10 114.0(3) . . ?
O6 C10 O5 123.5(4) . . ?
O6 C10 C9 118.1(4) . . ?
O5 C10 C9 118.4(4) . . ?
N3 C11 C12 111.8(3) . . ?
O8 C12 O7 122.5(4) . . ?
O8 C12 C11 118.7(4) . . ?
O7 C12 C11 118.8(4) . . ?
N2 C13 C14 114.8(3) . . ?
O10 C14 O9 122.3(4) . . ?
O10 C14 C13 117.5(4) . . ?
O9 C14 C13 120.2(4) . . ?
O10 C14 Cd2 54.6(2) . . ?
O9 C14 Cd2 67.9(2) . . ?
C13 C14 Cd2 171.2(3) . . ?
O10 C14 Eu 157.7(3) . . ?
O9 C14 Eu 39.25(19) . . ?
C13 C14 Eu 82.4(2) . . ?
Cd2 C14 Eu 106.19(13) . . ?

_diffrn_measured_fraction_theta_max 0.960
_diffrn_reflns_theta_full        27.49
_diffrn_measured_fraction_theta_full 0.960
_refine_diff_density_max         0.617
_refine_diff_density_min         -0.866
_refine_diff_density_rms         0.114
_database_code_depnum_ccdc_archive 'CCDC 975529'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_4

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C28 H48 Cd3 Cl2 N6 O26 Sm2'
_chemical_formula_sum            'C28 H48 Cd3 Cl2 N6 O26 Sm2'
_chemical_formula_weight         1593.52

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sm Sm -0.1638 3.4418 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.6521(17)
_cell_length_b                   9.0758(18)
_cell_length_c                   15.422(3)
_cell_angle_alpha                98.43(3)
_cell_angle_beta                 101.51(3)
_cell_angle_gamma                103.40(3)
_cell_volume                     1130.5(4)
_cell_formula_units_Z            1
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    5128
_cell_measurement_theta_min      3.13
_cell_measurement_theta_max      27.47

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.341
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             768
_exptl_absorpt_coefficient_mu    4.158
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Saturn724 (2x2 bin mode)'
_diffrn_measurement_method       dtprofit.ref
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            11187
_diffrn_reflns_av_R_equivalents  0.0198
_diffrn_reflns_av_sigmaI/netI    0.0253
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         3.13
_diffrn_reflns_theta_max         27.47
_reflns_number_total             5128
_reflns_number_gt                4729
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'CrystalClear (Rigaku Corp., 2000)'
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2000)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0447P)²+1.8823P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5128
_refine_ls_number_parameters     307
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0277
_refine_ls_R_factor_gt           0.0243
_refine_ls_wR_factor_ref         0.0864
_refine_ls_wR_factor_gt          0.0798
_refine_ls_goodness_of_fit_ref   1.223
_refine_ls_restrained_S_all      1.223
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sm Sm 0.81491(2) 0.69353(2) 0.275169(13) 0.01423(7) Uani 1 1 d . . .
Cd1 Cd 1.0000 1.0000 0.0000 0.02164(11) Uani 1 2 d S . .
Cd2 Cd 0.92202(4) 0.74990(4) 0.59750(2) 0.02539(10) Uani 1 1 d . . .
Cl Cl 0.71122(14) 0.88174(14) 0.62335(9) 0.0293(2) Uani 1 1 d . . .
O10 O 0.8046(4) 0.6688(4) 0.4280(2) 0.0204(6) Uani 1 1 d . . .
O8 O 0.9232(4) 0.4749(4) 0.3042(2) 0.0237(7) Uani 1 1 d . . .
O2 O 0.9742(4) 0.7463(4) 0.1624(2) 0.0259(7) Uani 1 1 d . . .
N3 N 0.7534(5) 0.4697(4) 0.1325(2) 0.0194(7) Uani 1 1 d . . .
O5 O 0.8625(4) 0.9676(4) 0.3341(3) 0.0300(8) Uani 1 1 d . . .
O2W O 1.0925(5) 1.0560(5) 0.1506(2) 0.0349(8) Uani 1 1 d . . .
H2WA H 1.1489 0.9950 0.1671 0.052 Uiso 1 1 d R . .
H2WB H 1.1524 1.1488 0.1668 0.052 Uiso 1 1 d R . .
O1W O 0.7352(5) 0.9953(5) 0.0023(3) 0.0411(10) Uani 1 1 d . . .
H1WA H 0.7073 0.9518 0.0455 0.062 Uiso 1 1 d R . .
H1WB H 0.7252 1.0889 0.0114 0.062 Uiso 1 1 d R . .
O6 O 0.8370(5) 1.1571(4) 0.4327(3) 0.0320(8) Uani 1 1 d . . .
O1 O 0.9471(6) 0.7449(4) 0.0148(2) 0.0368(9) Uani 1 1 d . . .
O7 O 1.0062(5) 0.2697(4) 0.2600(2) 0.0348(9) Uani 1 1 d . . .
O3W O 1.0997(4) 0.7871(4) 0.3666(2) 0.0296(7) Uani 1 1 d . . .
H3WA H 1.1188 0.7246 0.4024 0.044 Uiso 1 1 d R . .
H3WB H 1.1678 0.7918 0.3320 0.044 Uiso 1 1 d R . .
O9 O 0.7576(5) 0.5152(4) 0.5233(2) 0.0379(9) Uani 1 1 d . . .
N2 N 0.5762(5) 0.4601(4) 0.2821(3) 0.0206(7) Uani 1 1 d . . .
O3 O 0.6413(5) 0.7519(5) 0.1541(2) 0.0364(9) Uani 1 1 d . . .
N1 N 0.5527(4) 0.7912(4) 0.3149(3) 0.0198(7) Uani 1 1 d . . .
C10 C 0.6234(6) 0.9218(6) 0.3931(3) 0.0261(10) Uani 1 1 d . . .
H10A H 0.6407 0.8820 0.4483 0.031 Uiso 1 1 calc R . .
H10B H 0.5470 0.9843 0.3966 0.031 Uiso 1 1 calc R . .
C3 C 0.8716(6) 0.3745(5) 0.1462(3) 0.0244(9) Uani 1 1 d . . .
H3A H 0.9623 0.4136 0.1203 0.029 Uiso 1 1 calc R . .
H3B H 0.8178 0.2688 0.1145 0.029 Uiso 1 1 calc R . .
C14 C 0.7329(6) 0.5408(5) 0.4447(3) 0.0222(9) Uani 1 1 d . . .
C2 C 0.7733(6) 0.5418(6) 0.0541(3) 0.0258(10) Uani 1 1 d . . .
H2A H 0.6720 0.5647 0.0281 0.031 Uiso 1 1 calc R . .
H2B H 0.7952 0.4692 0.0084 0.031 Uiso 1 1 calc R . .
C13 C 0.6169(6) 0.4145(5) 0.3702(3) 0.0245(9) Uani 1 1 d . . .
H13A H 0.6648 0.3283 0.3625 0.029 Uiso 1 1 calc R . .
H13B H 0.5162 0.3785 0.3887 0.029 Uiso 1 1 calc R . .
C6 C 0.5508(6) 0.3256(5) 0.2077(3) 0.0246(9) Uani 1 1 d . . .
H6A H 0.4394 0.2613 0.1957 0.029 Uiso 1 1 calc R . .
H6B H 0.6242 0.2639 0.2268 0.029 Uiso 1 1 calc R . .
C11 C 0.4409(6) 0.6610(6) 0.3369(4) 0.0266(10) Uani 1 1 d . . .
H11A H 0.3344 0.6807 0.3328 0.032 Uiso 1 1 calc R . .
H11B H 0.4832 0.6517 0.3984 0.032 Uiso 1 1 calc R . .
C1 C 0.9113(6) 0.6892(5) 0.0798(3) 0.0244(10) Uani 1 1 d . . .
O4 O 0.5014(7) 0.9032(7) 0.0973(3) 0.0676(17) Uani 1 1 d . . .
C5 C 0.5815(6) 0.3754(6) 0.1216(3) 0.0273(10) Uani 1 1 d . . .
H5A H 0.5582 0.2841 0.0747 0.033 Uiso 1 1 calc R . .
H5B H 0.5066 0.4355 0.1022 0.033 Uiso 1 1 calc R . .
C7 C 0.5435(6) 0.8350(6) 0.1564(4) 0.0306(11) Uani 1 1 d . . .
C12 C 0.4228(6) 0.5112(6) 0.2728(4) 0.0284(10) Uani 1 1 d . . .
H12A H 0.3375 0.4306 0.2836 0.034 Uiso 1 1 calc R . .
H12B H 0.3878 0.5241 0.2113 0.034 Uiso 1 1 calc R . .
C8 C 0.4679(6) 0.8445(6) 0.2375(3) 0.0287(10) Uani 1 1 d . . .
H8A H 0.4678 0.9510 0.2574 0.034 Uiso 1 1 calc R . .
H8B H 0.3548 0.7828 0.2186 0.034 Uiso 1 1 calc R . .
C4 C 0.9366(5) 0.3754(5) 0.2436(3) 0.0188(8) Uani 1 1 d . . .
C9 C 0.7832(6) 1.0205(5) 0.3852(3) 0.0216(9) Uani 1 1 d . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sm O3 2.358(4) . ?
Sm O10 2.417(3) . ?
Sm O5 2.428(4) . ?
Sm O8 2.443(3) . ?
Sm O2 2.459(3) . ?
Sm O3W 2.464(4) . ?
Sm N2 2.625(4) . ?
Sm N3 2.641(4) . ?
Sm N1 2.764(3) . ?
Cd1 O2W 2.240(3) 2_775 ?
Cd1 O2W 2.240(3) . ?
Cd1 O1W 2.289(4) 2_775 ?
Cd1 O1W 2.289(4) . ?
Cd1 O1 2.308(4) . ?
Cd1 O1 2.308(4) 2_775 ?
Cd2 O7 2.207(4) 2_766 ?
Cd2 O6 2.228(4) 2_776 ?
Cd2 O9 2.259(4) . ?
Cd2 Cl 2.4655(13) . ?
Cd2 O10 2.537(3) . ?
Cd2 C14 2.747(5) . ?
O10 C14 1.273(6) . ?
O8 C4 1.244(5) . ?
O2 C1 1.260(6) . ?
N3 C2 1.477(6) . ?
N3 C3 1.488(6) . ?
N3 C5 1.497(6) . ?
O5 C9 1.257(6) . ?
O6 C9 1.272(6) . ?
O6 Cd2 2.228(4) 2_776 ?
O1 C1 1.247(5) . ?
O7 C4 1.275(5) . ?
O7 Cd2 2.207(4) 2_766 ?
O9 C14 1.253(6) . ?
N2 C13 1.478(6) . ?
N2 C6 1.490(6) . ?
N2 C12 1.492(6) . ?
O3 C7 1.260(6) . ?
N1 C11 1.472(6) . ?
N1 C8 1.476(6) . ?
N1 C10 1.477(6) . ?
C10 C9 1.501(7) . ?
C3 C4 1.493(6) . ?
C14 C13 1.504(6) . ?
C2 C1 1.513(7) . ?
C6 C5 1.516(7) . ?
C11 C12 1.515(7) . ?
O4 C7 1.218(6) . ?
C7 C8 1.523(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Sm O10 134.89(12) . . ?
O3 Sm O5 81.44(14) . . ?
O10 Sm O5 84.00(12) . . ?
O3 Sm O8 136.71(13) . . ?
O10 Sm O8 73.35(11) . . ?
O5 Sm O8 140.82(12) . . ?
O3 Sm O2 73.11(12) . . ?
O10 Sm O2 150.01(11) . . ?
O5 Sm O2 91.90(12) . . ?
O8 Sm O2 92.32(11) . . ?
O3 Sm O3W 139.62(14) . . ?
O10 Sm O3W 73.64(12) . . ?
O5 Sm O3W 73.32(12) . . ?
O8 Sm O3W 69.85(12) . . ?
O2 Sm O3W 76.73(12) . . ?
O3 Sm N2 90.26(14) . . ?
O10 Sm N2 67.11(12) . . ?
O5 Sm N2 129.12(12) . . ?
O8 Sm N2 70.31(12) . . ?
O2 Sm N2 133.39(12) . . ?
O3W Sm N2 130.12(12) . . ?
O3 Sm N3 71.77(13) . . ?
O10 Sm N3 127.82(11) . . ?
O5 Sm N3 147.71(12) . . ?
O8 Sm N3 65.32(11) . . ?
O2 Sm N3 63.62(11) . . ?
O3W Sm N3 116.95(12) . . ?
N2 Sm N3 69.86(12) . . ?
O3 Sm N1 64.03(12) . . ?
O10 Sm N1 71.32(11) . . ?
O5 Sm N1 62.76(12) . . ?
O8 Sm N1 133.38(11) . . ?
O2 Sm N1 132.28(11) . . ?
O3W Sm N1 125.50(12) . . ?
N2 Sm N1 68.49(12) . . ?
N3 Sm N1 117.45(12) . . ?
O2W Cd1 O2W 180.0(2) 2_775 . ?
O2W Cd1 O1W 94.78(15) 2_775 2_775 ?
O2W Cd1 O1W 85.22(15) . 2_775 ?
O2W Cd1 O1W 85.22(15) 2_775 . ?
O2W Cd1 O1W 94.78(15) . . ?
O1W Cd1 O1W 180.0(2) 2_775 . ?
O2W Cd1 O1 94.66(14) 2_775 . ?
O2W Cd1 O1 85.34(14) . . ?
O1W Cd1 O1 90.47(16) 2_775 . ?
O1W Cd1 O1 89.53(16) . . ?
O2W Cd1 O1 85.34(14) 2_775 2_775 ?
O2W Cd1 O1 94.66(14) . 2_775 ?
O1W Cd1 O1 89.53(16) 2_775 2_775 ?
O1W Cd1 O1 90.47(16) . 2_775 ?
O1 Cd1 O1 180.000(1) . 2_775 ?
O7 Cd2 O6 102.40(16) 2_766 2_776 ?
O7 Cd2 O9 105.73(14) 2_766 . ?
O6 Cd2 O9 120.89(14) 2_776 . ?
O7 Cd2 Cl 93.59(10) 2_766 . ?
O6 Cd2 Cl 129.61(10) 2_776 . ?
O9 Cd2 Cl 99.25(12) . . ?
O7 Cd2 O10 159.49(13) 2_766 . ?
O6 Cd2 O10 86.98(12) 2_776 . ?
O9 Cd2 O10 54.26(12) . . ?
Cl Cd2 O10 94.28(8) . . ?
O7 Cd2 C14 132.48(15) 2_766 . ?
O6 Cd2 C14 106.03(13) 2_776 . ?
O9 Cd2 C14 26.79(13) . . ?
Cl Cd2 C14 96.59(10) . . ?
O10 Cd2 C14 27.51(12) . . ?
C14 O10 Sm 120.7(3) . . ?
C14 O10 Cd2 85.5(3) . . ?
Sm O10 Cd2 151.20(14) . . ?
C4 O8 Sm 123.6(3) . . ?
C1 O2 Sm 120.3(3) . . ?
C2 N3 C3 108.6(3) . . ?
C2 N3 C5 112.4(4) . . ?
C3 N3 C5 111.3(4) . . ?
C2 N3 Sm 107.9(3) . . ?
C3 N3 Sm 110.5(3) . . ?
C5 N3 Sm 106.1(3) . . ?
C9 O5 Sm 123.5(3) . . ?
C9 O6 Cd2 104.7(3) . 2_776 ?
C1 O1 Cd1 128.3(3) . . ?
C4 O7 Cd2 117.1(3) . 2_766 ?
C14 O9 Cd2 98.8(3) . . ?
C13 N2 C6 109.6(3) . . ?
C13 N2 C12 109.9(4) . . ?
C6 N2 C12 108.9(4) . . ?
C13 N2 Sm 108.8(3) . . ?
C6 N2 Sm 111.3(3) . . ?
C12 N2 Sm 108.3(3) . . ?
C7 O3 Sm 129.0(3) . . ?
C11 N1 C8 110.8(4) . . ?
C11 N1 C10 111.8(4) . . ?
C8 N1 C10 109.8(4) . . ?
C11 N1 Sm 108.1(3) . . ?
C8 N1 Sm 110.5(3) . . ?
C10 N1 Sm 105.7(3) . . ?
N1 C10 C9 111.1(4) . . ?
N3 C3 C4 112.7(4) . . ?
O9 C14 O10 121.3(4) . . ?
O9 C14 C13 117.9(4) . . ?
O10 C14 C13 120.8(4) . . ?
O9 C14 Cd2 54.4(2) . . ?
O10 C14 Cd2 67.0(2) . . ?
C13 C14 Cd2 171.6(3) . . ?
N3 C2 C1 112.1(4) . . ?
N2 C13 C14 114.8(4) . . ?
N2 C6 C5 112.2(4) . . ?
N1 C11 C12 110.8(4) . . ?
O1 C1 O2 126.5(5) . . ?
O1 C1 C2 114.9(4) . . ?
O2 C1 C2 118.5(4) . . ?
N3 C5 C6 113.1(4) . . ?
O4 C7 O3 124.7(5) . . ?
O4 C7 C8 118.2(4) . . ?
O3 C7 C8 117.0(4) . . ?
N2 C12 C11 113.7(4) . . ?
N1 C8 C7 114.4(4) . . ?
O8 C4 O7 122.9(4) . . ?
O8 C4 C3 121.1(4) . . ?
O7 C4 C3 116.1(4) . . ?
O5 C9 O6 121.3(4) . . ?
O5 C9 C10 120.4(4) . . ?
O6 C9 C10 118.3(4) . . ?

_diffrn_measured_fraction_theta_max 0.991
_diffrn_reflns_theta_full        27.47
_diffrn_measured_fraction_theta_full 0.991
_refine_diff_density_max         0.872
_refine_diff_density_min         -1.005
_refine_diff_density_rms         0.174

_database_code_depnum_ccdc_archive 'CCDC 975530'
