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# This journal is © The Royal Society of Chemistry 2014

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#                                CCDC 
# 
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# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
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#  fide research purposes only. It may contain copyright material
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data_mo_dm13137_0m

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C27 H29 N3 O3'
_chemical_formula_weight         443.53

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   6.6657(12)
_cell_length_b                   8.9418(16)
_cell_length_c                   19.201(4)
_cell_angle_alpha                87.395(3)
_cell_angle_beta                 87.173(4)
_cell_angle_gamma                88.605(4)
_cell_volume                     1141.6(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    140(2)
_cell_measurement_reflns_used    1589
_cell_measurement_theta_min      2.47
_cell_measurement_theta_max      32.01

_exptl_crystal_description       prism
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.04
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.290
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             472
_exptl_absorpt_coefficient_mu    0.085
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.9750
_exptl_absorpt_correction_T_max  0.9966
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      140(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            11107
_diffrn_reflns_av_R_equivalents  0.0373
_diffrn_reflns_av_sigmaI/netI    0.0770
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         1.06
_diffrn_reflns_theta_max         30.00
_reflns_number_total             6601
_reflns_number_gt                3598
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1230P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6601
_refine_ls_number_parameters     345
_refine_ls_number_restraints     138
_refine_ls_R_factor_all          0.1325
_refine_ls_R_factor_gt           0.0703
_refine_ls_wR_factor_ref         0.2464
_refine_ls_wR_factor_gt          0.1944
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_restrained_S_all      1.098
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
N1 N 0.7331(3) 0.7276(2) -0.11684(9) 0.0198(4) Uani 1 1 d . . .
N2 N 0.9533(4) 0.9598(3) -0.26856(11) 0.0348(6) Uani 1 1 d . . .
N3 N 0.6799(3) 0.7104(3) 0.46234(11) 0.0343(6) Uani 1 1 d D . .
O1 O 0.7907(3) 0.51435(19) -0.17503(8) 0.0260(4) Uani 1 1 d . . .
O2 O 0.6950(3) 0.94403(19) -0.05964(9) 0.0313(5) Uani 1 1 d . . .
O3 O 0.7091(3) 0.46478(18) 0.19841(8) 0.0254(4) Uani 1 1 d . . .
C1 C 0.7635(3) 0.5730(3) -0.11910(11) 0.0185(5) Uani 1 1 d . . .
C2 C 0.7637(3) 0.4869(2) -0.05142(11) 0.0170(4) Uani 1 1 d . . .
C3 C 0.7837(3) 0.3336(3) -0.05096(12) 0.0208(5) Uani 1 1 d . . .
H3 H 0.8009 0.2843 -0.0937 0.025 Uiso 1 1 calc R . .
C4 C 0.7788(4) 0.2496(3) 0.01270(12) 0.0214(5) Uani 1 1 d . . .
H4 H 0.7931 0.1436 0.0128 0.026 Uiso 1 1 calc R . .
C5 C 0.7535(3) 0.3197(3) 0.07507(12) 0.0201(5) Uani 1 1 d . . .
H5 H 0.7485 0.2615 0.1178 0.024 Uiso 1 1 calc R . .
C6 C 0.7349(3) 0.4771(2) 0.07603(11) 0.0163(4) Uani 1 1 d . . .
C7 C 0.7110(3) 0.5562(3) 0.13886(11) 0.0203(5) Uani 1 1 d . . .
C8 C 0.6932(4) 0.7089(3) 0.13770(11) 0.0224(5) Uani 1 1 d . . .
H8 H 0.6805 0.7596 0.1802 0.027 Uiso 1 1 calc R . .
C9 C 0.6940(4) 0.7906(3) 0.07340(12) 0.0220(5) Uani 1 1 d . . .
H9 H 0.6778 0.8965 0.0729 0.026 Uiso 1 1 calc R . .
C10 C 0.7175(3) 0.7202(2) 0.01126(11) 0.0171(4) Uani 1 1 d . . .
C11 C 0.7387(3) 0.5619(2) 0.01179(11) 0.0162(4) Uani 1 1 d . . .
C12 C 0.7139(4) 0.8075(3) -0.05564(11) 0.0202(5) Uani 1 1 d . . .
C13 C 0.7311(4) 0.8163(3) -0.18313(11) 0.0247(5) Uani 1 1 d . . .
H13A H 0.6398 0.9045 -0.1780 0.030 Uiso 1 1 calc R . .
H13B H 0.6811 0.7550 -0.2200 0.030 Uiso 1 1 calc R . .
C14 C 0.9435(4) 0.8678(3) -0.20402(12) 0.0263(5) Uani 1 1 d . . .
H14A H 0.9939 0.9257 -0.1660 0.032 Uiso 1 1 calc R . .
H14B H 1.0330 0.7787 -0.2096 0.032 Uiso 1 1 calc R . .
C15 C 1.1618(5) 0.9756(4) -0.29296(16) 0.0492(9) Uani 1 1 d . . .
H15A H 1.2363 1.0223 -0.2573 0.074 Uiso 1 1 calc R . .
H15B H 1.1687 1.0384 -0.3361 0.074 Uiso 1 1 calc R . .
H15C H 1.2212 0.8765 -0.3019 0.074 Uiso 1 1 calc R . .
C16 C 0.8601(6) 1.1047(4) -0.2584(2) 0.0622(11) Uani 1 1 d . . .
H16A H 0.9357 1.1586 -0.2254 0.093 Uiso 1 1 calc R . .
H16B H 0.7216 1.0922 -0.2398 0.093 Uiso 1 1 calc R . .
H16C H 0.8595 1.1620 -0.3032 0.093 Uiso 1 1 calc R . .
C17 C 0.7019(4) 0.5309(3) 0.26346(11) 0.0225(5) Uani 1 1 d . . .
C18 C 0.5239(4) 0.5918(3) 0.29048(12) 0.0279(6) Uani 1 1 d . A .
H18 H 0.4060 0.5924 0.2646 0.033 Uiso 1 1 calc R . .
C19 C 0.5192(4) 0.6524(3) 0.35618(12) 0.0293(6) Uani 1 1 d . . .
H19 H 0.3977 0.6964 0.3744 0.035 Uiso 1 1 calc R A .
C20 C 0.6895(4) 0.6496(3) 0.39556(12) 0.0251(5) Uani 1 1 d . A .
C21 C 0.8665(4) 0.5848(3) 0.36714(12) 0.0282(6) Uani 1 1 d . . .
H21 H 0.9840 0.5802 0.3933 0.034 Uiso 1 1 calc R A .
C22 C 0.8723(4) 0.5273(3) 0.30116(12) 0.0258(5) Uani 1 1 d . A .
H22 H 0.9940 0.4854 0.2820 0.031 Uiso 1 1 calc R . .
C23 C 0.5290(10) 0.6558(8) 0.5106(3) 0.0451(13) Uani 0.50 1 d PDU A 1
H23A H 0.5650 0.5515 0.5255 0.054 Uiso 0.50 1 calc PR A 1
H23B H 0.4006 0.6537 0.4869 0.054 Uiso 0.50 1 calc PR A 1
C24 C 0.4983(12) 0.7466(9) 0.5742(4) 0.0492(13) Uani 0.50 1 d PDU A 1
H24A H 0.4078 0.6925 0.6086 0.059 Uiso 0.50 1 calc PR A 1
H24B H 0.4316 0.8431 0.5609 0.059 Uiso 0.50 1 calc PR A 1
C25 C 0.6920(11) 0.7773(9) 0.6080(3) 0.0537(13) Uani 0.50 1 d PDU A 1
H25A H 0.7488 0.6825 0.6281 0.064 Uiso 0.50 1 calc PR A 1
H25B H 0.6646 0.8463 0.6464 0.064 Uiso 0.50 1 calc PR A 1
C26 C 0.8441(14) 0.8471(9) 0.5545(4) 0.0513(13) Uani 0.50 1 d PDU A 1
H26A H 0.8043 0.9530 0.5444 0.062 Uiso 0.50 1 calc PR A 1
H26B H 0.9777 0.8458 0.5749 0.062 Uiso 0.50 1 calc PR A 1
C27 C 0.8600(14) 0.7685(11) 0.4884(5) 0.0506(14) Uani 0.50 1 d PDU A 1
H27A H 0.9189 0.8383 0.4519 0.061 Uiso 0.50 1 calc PR A 1
H27B H 0.9571 0.6838 0.4943 0.061 Uiso 0.50 1 calc PR A 1
C23' C 0.4897(10) 0.7779(10) 0.4866(3) 0.0586(14) Uani 0.50 1 d PDU A 2
H23C H 0.3799 0.7108 0.4764 0.070 Uiso 0.50 1 calc PR A 2
H23D H 0.4685 0.8736 0.4597 0.070 Uiso 0.50 1 calc PR A 2
C24' C 0.4755(14) 0.8076(11) 0.5631(4) 0.0638(16) Uani 0.50 1 d PDU A 2
H24C H 0.3592 0.8760 0.5724 0.077 Uiso 0.50 1 calc PR A 2
H24D H 0.4498 0.7121 0.5898 0.077 Uiso 0.50 1 calc PR A 2
C25' C 0.6601(10) 0.8751(10) 0.5889(4) 0.0575(13) Uani 0.50 1 d PDU A 2
H25C H 0.6513 0.8734 0.6406 0.069 Uiso 0.50 1 calc PR A 2
H25D H 0.6682 0.9808 0.5715 0.069 Uiso 0.50 1 calc PR A 2
C26' C 0.8463(13) 0.7903(10) 0.5645(5) 0.0560(14) Uani 0.50 1 d PDU A 2
H26C H 0.9605 0.8575 0.5689 0.067 Uiso 0.50 1 calc PR A 2
H26D H 0.8648 0.7055 0.5988 0.067 Uiso 0.50 1 calc PR A 2
C27' C 0.8712(13) 0.7275(11) 0.4941(5) 0.0482(14) Uani 0.50 1 d PDU A 2
H27C H 0.9565 0.7945 0.4634 0.058 Uiso 0.50 1 calc PR A 2
H27D H 0.9409 0.6286 0.4980 0.058 Uiso 0.50 1 calc PRU A 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
N1 C1 1.394(3) . ?
N1 C12 1.402(3) . ?
N1 C13 1.469(3) . ?
N2 C16 1.440(4) . ?
N2 C15 1.453(4) . ?
N2 C14 1.456(3) . ?
N3 C23 1.414(5) . ?
N3 C20 1.413(3) . ?
N3 C27 1.441(8) . ?
N3 C23' 1.455(6) . ?
N3 C27' 1.454(8) . ?
O1 C1 1.220(2) . ?
O2 C12 1.223(3) . ?
O3 C7 1.375(3) . ?
O3 C17 1.404(3) . ?
C1 C2 1.480(3) . ?
C2 C3 1.374(3) . ?
C2 C11 1.414(3) . ?
C3 C4 1.404(3) . ?
C3 H3 0.9500 . ?
C4 C5 1.378(3) . ?
C4 H4 0.9500 . ?
C5 C6 1.411(3) . ?
C5 H5 0.9500 . ?
C6 C11 1.418(3) . ?
C6 C7 1.427(3) . ?
C7 C8 1.367(3) . ?
C8 C9 1.406(3) . ?
C8 H8 0.9500 . ?
C9 C10 1.375(3) . ?
C9 H9 0.9500 . ?
C10 C11 1.419(3) . ?
C10 C12 1.474(3) . ?
C13 C14 1.529(3) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C22 1.376(3) . ?
C17 C18 1.381(4) . ?
C18 C19 1.394(3) . ?
C18 H18 0.9500 . ?
C19 C20 1.394(4) . ?
C19 H19 0.9500 . ?
C20 C21 1.399(4) . ?
C21 C22 1.387(3) . ?
C21 H21 0.9500 . ?
C22 H22 0.9500 . ?
C23 C24 1.499(7) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C24 C25 1.509(8) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C25 C26 1.531(8) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 C27 1.476(7) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C23' C24' 1.503(7) . ?
C23' H23C 0.9900 . ?
C23' H23D 0.9900 . ?
C24' C25' 1.499(8) . ?
C24' H24C 0.9900 . ?
C24' H24D 0.9900 . ?
C25' C26' 1.505(8) . ?
C25' H25C 0.9900 . ?
C25' H25D 0.9900 . ?
C26' C27' 1.489(8) . ?
C26' H26C 0.9900 . ?
C26' H26D 0.9900 . ?
C27' H27C 0.9900 . ?
C27' H27D 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 N1 C12 124.98(19) . . ?
C1 N1 C13 118.38(18) . . ?
C12 N1 C13 116.56(19) . . ?
C16 N2 C15 110.4(2) . . ?
C16 N2 C14 110.9(2) . . ?
C15 N2 C14 109.4(2) . . ?
C23 N3 C20 116.9(3) . . ?
C23 N3 C27 118.9(5) . . ?
C20 N3 C27 118.7(5) . . ?
C23 N3 C23' 49.1(4) . . ?
C20 N3 C23' 117.6(3) . . ?
C27 N3 C23' 117.1(5) . . ?
C23 N3 C27' 112.6(5) . . ?
C20 N3 C27' 116.0(5) . . ?
C27 N3 C27' 15.3(7) . . ?
C23' N3 C27' 125.1(5) . . ?
C7 O3 C17 118.70(18) . . ?
O1 C1 N1 120.3(2) . . ?
O1 C1 C2 122.7(2) . . ?
N1 C1 C2 117.00(18) . . ?
C3 C2 C11 120.7(2) . . ?
C3 C2 C1 119.20(19) . . ?
C11 C2 C1 120.1(2) . . ?
C2 C3 C4 120.0(2) . . ?
C2 C3 H3 120.0 . . ?
C4 C3 H3 120.0 . . ?
C5 C4 C3 120.5(2) . . ?
C5 C4 H4 119.7 . . ?
C3 C4 H4 119.7 . . ?
C4 C5 C6 120.5(2) . . ?
C4 C5 H5 119.7 . . ?
C6 C5 H5 119.7 . . ?
C5 C6 C11 119.00(19) . . ?
C5 C6 C7 123.2(2) . . ?
C11 C6 C7 117.83(19) . . ?
C8 C7 O3 124.8(2) . . ?
C8 C7 C6 121.5(2) . . ?
O3 C7 C6 113.67(19) . . ?
C7 C8 C9 119.7(2) . . ?
C7 C8 H8 120.1 . . ?
C9 C8 H8 120.1 . . ?
C10 C9 C8 121.3(2) . . ?
C10 C9 H9 119.4 . . ?
C8 C9 H9 119.4 . . ?
C9 C10 C11 119.5(2) . . ?
C9 C10 C12 120.5(2) . . ?
C11 C10 C12 119.97(19) . . ?
C2 C11 C10 120.6(2) . . ?
C2 C11 C6 119.24(19) . . ?
C10 C11 C6 120.14(18) . . ?
O2 C12 N1 119.7(2) . . ?
O2 C12 C10 123.2(2) . . ?
N1 C12 C10 117.2(2) . . ?
N1 C13 C14 109.63(19) . . ?
N1 C13 H13A 109.7 . . ?
C14 C13 H13A 109.7 . . ?
N1 C13 H13B 109.7 . . ?
C14 C13 H13B 109.7 . . ?
H13A C13 H13B 108.2 . . ?
N2 C14 C13 113.0(2) . . ?
N2 C14 H14A 109.0 . . ?
C13 C14 H14A 109.0 . . ?
N2 C14 H14B 109.0 . . ?
C13 C14 H14B 109.0 . . ?
H14A C14 H14B 107.8 . . ?
N2 C15 H15A 109.5 . . ?
N2 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
N2 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
N2 C16 H16A 109.5 . . ?
N2 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
N2 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C22 C17 C18 120.7(2) . . ?
C22 C17 O3 118.9(2) . . ?
C18 C17 O3 120.4(2) . . ?
C17 C18 C19 119.2(2) . . ?
C17 C18 H18 120.4 . . ?
C19 C18 H18 120.4 . . ?
C20 C19 C18 121.2(2) . . ?
C20 C19 H19 119.4 . . ?
C18 C19 H19 119.4 . . ?
C19 C20 C21 118.1(2) . . ?
C19 C20 N3 120.0(2) . . ?
C21 C20 N3 121.9(2) . . ?
C22 C21 C20 120.7(2) . . ?
C22 C21 H21 119.6 . . ?
C20 C21 H21 119.6 . . ?
C17 C22 C21 120.0(2) . . ?
C17 C22 H22 120.0 . . ?
C21 C22 H22 120.0 . . ?
N3 C23 C24 114.0(5) . . ?
N3 C23 H23A 108.8 . . ?
C24 C23 H23A 108.8 . . ?
N3 C23 H23B 108.8 . . ?
C24 C23 H23B 108.8 . . ?
H23A C23 H23B 107.7 . . ?
C23 C24 C25 113.0(6) . . ?
C23 C24 H24A 109.0 . . ?
C25 C24 H24A 109.0 . . ?
C23 C24 H24B 109.0 . . ?
C25 C24 H24B 109.0 . . ?
H24A C24 H24B 107.8 . . ?
C24 C25 C26 110.6(6) . . ?
C24 C25 H25A 109.5 . . ?
C26 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
C26 C25 H25B 109.5 . . ?
H25A C25 H25B 108.1 . . ?
C27 C26 C25 113.0(7) . . ?
C27 C26 H26A 109.0 . . ?
C25 C26 H26A 109.0 . . ?
C27 C26 H26B 109.0 . . ?
C25 C26 H26B 109.0 . . ?
H26A C26 H26B 107.8 . . ?
N3 C27 C26 118.4(8) . . ?
N3 C27 H27A 107.7 . . ?
C26 C27 H27A 107.7 . . ?
N3 C27 H27B 107.7 . . ?
C26 C27 H27B 107.7 . . ?
H27A C27 H27B 107.1 . . ?
N3 C23' C24' 114.5(6) . . ?
N3 C23' H23C 108.6 . . ?
C24' C23' H23C 108.6 . . ?
N3 C23' H23D 108.6 . . ?
C24' C23' H23D 108.6 . . ?
H23C C23' H23D 107.6 . . ?
C25' C24' C23' 113.9(7) . . ?
C25' C24' H24C 108.8 . . ?
C23' C24' H24C 108.8 . . ?
C25' C24' H24D 108.8 . . ?
C23' C24' H24D 108.8 . . ?
H24C C24' H24D 107.7 . . ?
C24' C25' C26' 110.9(7) . . ?
C24' C25' H25C 109.5 . . ?
C26' C25' H25C 109.5 . . ?
C24' C25' H25D 109.5 . . ?
C26' C25' H25D 109.5 . . ?
H25C C25' H25D 108.0 . . ?
C27' C26' C25' 122.9(8) . . ?
C27' C26' H26C 106.6 . . ?
C25' C26' H26C 106.6 . . ?
C27' C26' H26D 106.6 . . ?
C25' C26' H26D 106.6 . . ?
H26C C26' H26D 106.6 . . ?
N3 C27' C26' 112.3(8) . . ?
N3 C27' H27C 109.2 . . ?
C26' C27' H27C 109.2 . . ?
N3 C27' H27D 109.1 . . ?
C26' C27' H27D 109.1 . . ?
H27C C27' H27D 107.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C12 N1 C1 O1 -175.5(2) . . . . ?
C13 N1 C1 O1 1.1(3) . . . . ?
C12 N1 C1 C2 3.7(3) . . . . ?
C13 N1 C1 C2 -179.72(19) . . . . ?
O1 C1 C2 C3 -3.8(3) . . . . ?
N1 C1 C2 C3 177.0(2) . . . . ?
O1 C1 C2 C11 177.6(2) . . . . ?
N1 C1 C2 C11 -1.5(3) . . . . ?
C11 C2 C3 C4 0.2(3) . . . . ?
C1 C2 C3 C4 -178.3(2) . . . . ?
C2 C3 C4 C5 0.2(3) . . . . ?
C3 C4 C5 C6 -0.9(3) . . . . ?
C4 C5 C6 C11 1.2(3) . . . . ?
C4 C5 C6 C7 -179.1(2) . . . . ?
C17 O3 C7 C8 -4.5(3) . . . . ?
C17 O3 C7 C6 175.2(2) . . . . ?
C5 C6 C7 C8 -179.9(2) . . . . ?
C11 C6 C7 C8 -0.3(3) . . . . ?
C5 C6 C7 O3 0.4(3) . . . . ?
C11 C6 C7 O3 -179.98(19) . . . . ?
O3 C7 C8 C9 -179.0(2) . . . . ?
C6 C7 C8 C9 1.4(4) . . . . ?
C7 C8 C9 C10 -1.7(4) . . . . ?
C8 C9 C10 C11 0.9(3) . . . . ?
C8 C9 C10 C12 178.8(2) . . . . ?
C3 C2 C11 C10 -179.9(2) . . . . ?
C1 C2 C11 C10 -1.4(3) . . . . ?
C3 C2 C11 C6 0.1(3) . . . . ?
C1 C2 C11 C6 178.62(19) . . . . ?
C9 C10 C11 C2 -179.8(2) . . . . ?
C12 C10 C11 C2 2.3(3) . . . . ?
C9 C10 C11 C6 0.2(3) . . . . ?
C12 C10 C11 C6 -177.7(2) . . . . ?
C5 C6 C11 C2 -0.8(3) . . . . ?
C7 C6 C11 C2 179.5(2) . . . . ?
C5 C6 C11 C10 179.2(2) . . . . ?
C7 C6 C11 C10 -0.5(3) . . . . ?
C1 N1 C12 O2 177.3(2) . . . . ?
C13 N1 C12 O2 0.7(3) . . . . ?
C1 N1 C12 C10 -2.8(3) . . . . ?
C13 N1 C12 C10 -179.44(19) . . . . ?
C9 C10 C12 O2 1.7(4) . . . . ?
C11 C10 C12 O2 179.6(2) . . . . ?
C9 C10 C12 N1 -178.2(2) . . . . ?
C11 C10 C12 N1 -0.3(3) . . . . ?
C1 N1 C13 C14 -90.6(2) . . . . ?
C12 N1 C13 C14 86.2(2) . . . . ?
C16 N2 C14 C13 70.8(3) . . . . ?
C15 N2 C14 C13 -167.2(2) . . . . ?
N1 C13 C14 N2 -178.6(2) . . . . ?
C7 O3 C17 C22 -106.5(3) . . . . ?
C7 O3 C17 C18 76.6(3) . . . . ?
C22 C17 C18 C19 1.1(4) . . . . ?
O3 C17 C18 C19 177.9(2) . . . . ?
C17 C18 C19 C20 -1.4(4) . . . . ?
C18 C19 C20 C21 0.4(4) . . . . ?
C18 C19 C20 N3 -179.3(2) . . . . ?
C23 N3 C20 C19 54.3(5) . . . . ?
C27 N3 C20 C19 -152.2(5) . . . . ?
C23' N3 C20 C19 -1.5(5) . . . . ?
C27' N3 C20 C19 -169.2(5) . . . . ?
C23 N3 C20 C21 -125.4(4) . . . . ?
C27 N3 C20 C21 28.1(6) . . . . ?
C23' N3 C20 C21 178.8(5) . . . . ?
C27' N3 C20 C21 11.2(6) . . . . ?
C19 C20 C21 C22 1.0(4) . . . . ?
N3 C20 C21 C22 -179.3(2) . . . . ?
C18 C17 C22 C21 0.2(4) . . . . ?
O3 C17 C22 C21 -176.7(2) . . . . ?
C20 C21 C22 C17 -1.3(4) . . . . ?
C20 N3 C23 C24 -167.6(5) . . . . ?
C27 N3 C23 C24 38.9(9) . . . . ?
C23' N3 C23 C24 -63.2(6) . . . . ?
C27' N3 C23 C24 54.4(8) . . . . ?
N3 C23 C24 C25 -49.4(9) . . . . ?
C23 C24 C25 C26 53.2(9) . . . . ?
C24 C25 C26 C27 -46.5(10) . . . . ?
C23 N3 C27 C26 -33.9(10) . . . . ?
C20 N3 C27 C26 173.2(6) . . . . ?
C23' N3 C27 C26 22.3(10) . . . . ?
C27' N3 C27 C26 -103(3) . . . . ?
C25 C26 C27 N3 37.1(11) . . . . ?
C23 N3 C23' C24' 63.7(7) . . . . ?
C20 N3 C23' C24' 166.5(6) . . . . ?
C27 N3 C23' C24' -42.2(10) . . . . ?
C27' N3 C23' C24' -27.0(11) . . . . ?
N3 C23' C24' C25' 43.9(11) . . . . ?
C23' C24' C25' C26' -48.2(11) . . . . ?
C24' C25' C26' C27' 37.9(12) . . . . ?
C23 N3 C27' C26' -40.8(9) . . . . ?
C20 N3 C27' C26' -179.2(5) . . . . ?
C27 N3 C27' C26' 77(3) . . . . ?
C23' N3 C27' C26' 14.2(10) . . . . ?
C25' C26' C27' N3 -20.1(12) . . . . ?

_diffrn_measured_fraction_theta_max 0.990
_diffrn_reflns_theta_full        30.00
_diffrn_measured_fraction_theta_full 0.990
_refine_diff_density_max         0.636
_refine_diff_density_min         -0.344
_refine_diff_density_rms         0.097
_database_code_depnum_ccdc_archive 'CCDC 990189'
