# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2014

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#                                CCDC 
# 
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# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
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#  fide research purposes only. It may contain copyright material
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data_926484

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C47 H58 Ag11 F15 O11'
_chemical_formula_weight         2266.47

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.551(4)
_cell_length_b                   14.805(4)
_cell_length_c                   18.520(7)
_cell_angle_alpha                110.957(4)
_cell_angle_beta                 92.602(4)
_cell_angle_gamma                117.093(3)
_cell_volume                     3211.2(17)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    15742
_cell_measurement_theta_min      1.62
_cell_measurement_theta_max      25.00

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.22
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.344
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2152
_exptl_absorpt_coefficient_mu    3.367
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5114
_exptl_absorpt_correction_T_max  0.5246
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            15742
_diffrn_reflns_av_R_equivalents  0.0573
_diffrn_reflns_av_sigmaI/netI    0.1671
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.62
_diffrn_reflns_theta_max         25.00
_reflns_number_total             11016
_reflns_number_gt                4624
_reflns_threshold_expression     >2σ(I)

_computing_data_collection       'SMART (Bruker, 1997)'
_computing_cell_refinement       'SAINT (Bruker, 1999)'
_computing_data_reduction        SAINT
_computing_structure_solution    'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'SHELXTL-PLUS (Sheldrick, 1990)'
_computing_publication_material  SHELXL-97

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2σ(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         11016
_refine_ls_number_parameters     492
_refine_ls_number_restraints     65
_refine_ls_R_factor_all          0.1989
_refine_ls_R_factor_gt           0.0781
_refine_ls_wR_factor_ref         0.2233
_refine_ls_wR_factor_gt          0.1667
_refine_ls_goodness_of_fit_ref   0.950
_refine_ls_restrained_S_all      0.949
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.05956(12) 0.10769(12) 0.42028(9) 0.0511(4) Uani 1 1 d . . .
Ag2 Ag 0.14817(13) 0.07143(12) 0.03929(9) 0.0561(4) Uani 1 1 d . . .
Ag3 Ag 0.04959(11) 0.02823(12) 0.19730(9) 0.0502(4) Uani 1 1 d . . .
Ag4 Ag 0.20934(13) -0.03981(13) 0.13340(9) 0.0591(5) Uani 1 1 d . . .
Ag5 Ag -0.12504(14) -0.08391(13) 0.29644(10) 0.0665(5) Uani 1 1 d . . .
Ag6 Ag 0.21083(13) 0.07116(14) 0.33675(9) 0.0608(5) Uani 1 1 d . . .
Ag7 Ag 0.17590(15) 0.25168(14) 0.20880(10) 0.0691(5) Uani 1 1 d . . .
Ag8 Ag -0.05718(15) 0.13294(13) 0.28589(10) 0.0678(5) Uani 1 1 d . . .
Ag9 Ag -0.12673(14) -0.01230(16) 0.47848(11) 0.0760(6) Uani 1 1 d . . .
Ag10 Ag 0.12842(15) 0.19001(14) -0.06265(9) 0.0698(5) Uani 1 1 d . . .
Ag11 Ag 0.0320(3) -0.1305(3) -0.1035(2) 0.0723(11) Uani 0.50 1 d PU . 1
Ag11 Ag 0.0066(3) -0.1624(3) -0.0622(3) 0.0720(11) Uani 0.50 1 d PU . 2
C1 C 0.1985(16) 0.3632(15) 0.3866(10) 0.053(5) Uiso 1 1 d D . .
C2 C 0.2538(16) 0.4529(14) 0.4728(10) 0.093(8) Uiso 1 1 d D . .
C3 C 0.3115(14) -0.0841(17) 0.2665(14) 0.059(6) Uiso 1 1 d D . .
C4 C 0.3748(15) -0.1372(15) 0.2827(10) 0.089(8) Uiso 1 1 d D . .
C5 C -0.018(2) 0.3341(19) 0.2516(16) 0.081(7) Uiso 1 1 d D . .
C6 C 0.0008(19) 0.454(2) 0.2889(15) 0.144(13) Uiso 1 1 d D . .
C7 C 0.0238(15) -0.1998(13) 0.1944(12) 0.050(5) Uiso 1 1 d D . .
C8 C 0.0194(13) -0.3085(12) 0.1868(10) 0.076(7) Uiso 1 1 d D . .
C9 C -0.2522(15) -0.3370(15) 0.1723(13) 0.055(5) Uiso 1 1 d D . .
C10 C -0.3263(16) -0.4580(14) 0.1603(11) 0.097(8) Uiso 1 1 d D . .
C11 C 0.1676(15) -0.0679(15) 0.0039(11) 0.056(5) Uiso 1 1 d D . .
C12 C 0.2047(16) -0.1334(16) -0.0052(11) 0.060(6) Uiso 1 1 d D . .
C13 C 0.2528(16) -0.2056(16) -0.0273(10) 0.068(6) Uiso 1 1 d D . .
C14 C 0.184(2) -0.302(2) -0.0057(18) 0.143(12) Uiso 1 1 d D . .
H14A H 0.1117 -0.3424 -0.0375 0.215 Uiso 1 1 calc R . .
H14B H 0.1845 -0.2727 0.0498 0.215 Uiso 1 1 calc R . .
H14C H 0.2113 -0.3522 -0.0160 0.215 Uiso 1 1 calc R . .
C15 C 0.241(2) -0.253(2) -0.1178(11) 0.123(10) Uiso 1 1 d D . .
H15A H 0.1680 -0.2895 -0.1453 0.185 Uiso 1 1 calc R . .
H15B H 0.2659 -0.3054 -0.1327 0.185 Uiso 1 1 calc R . .
H15C H 0.2834 -0.1924 -0.1319 0.185 Uiso 1 1 calc R . .
C16 C 0.362(2) -0.142(3) 0.0216(17) 0.134(11) Uiso 1 1 d . . .
H16A H 0.3621 -0.1150 0.0771 0.201 Uiso 1 1 calc R . .
H16B H 0.4039 -0.0799 0.0094 0.201 Uiso 1 1 calc R . .
H16C H 0.3922 -0.1900 0.0105 0.201 Uiso 1 1 calc R . .
C17 C 0.1107(12) 0.0268(14) -0.1650(10) 0.046(5) Uiso 1 1 d D . .
C18 C 0.2121(11) 0.0699(13) -0.1492(9) 0.034(4) Uiso 1 1 d D . .
C19 C 0.3273(14) 0.1130(12) -0.1286(8) 0.061(6) Uiso 1 1 d D . .
C20 C 0.346(2) 0.0155(18) -0.1406(16) 0.116(10) Uiso 1 1 d D . .
H20A H 0.4217 0.0435 -0.1268 0.174 Uiso 1 1 calc R . .
H20B H 0.3166 -0.0383 -0.1955 0.174 Uiso 1 1 calc R . .
H20C H 0.3131 -0.0197 -0.1070 0.174 Uiso 1 1 calc R . .
C21 C 0.380(2) 0.164(2) -0.1851(14) 0.114(10) Uiso 1 1 d D . .
H21A H 0.4549 0.1923 -0.1712 0.171 Uiso 1 1 calc R . .
H21B H 0.3674 0.2242 -0.1801 0.171 Uiso 1 1 calc R . .
H21C H 0.3493 0.1075 -0.2391 0.171 Uiso 1 1 calc R . .
C22 C 0.379(2) 0.2051(18) -0.0428(9) 0.105(9) Uiso 1 1 d D . .
H22A H 0.4541 0.2320 -0.0304 0.158 Uiso 1 1 calc R . .
H22B H 0.3474 0.1749 -0.0064 0.158 Uiso 1 1 calc R . .
H22C H 0.3677 0.2658 -0.0380 0.158 Uiso 1 1 calc R . .
C23 C 0.1591(17) 0.2260(18) 0.0720(12) 0.066(6) Uiso 1 1 d . . .
C24 C 0.1985(16) 0.3255(18) 0.0931(12) 0.061(6) Uiso 1 1 d . . .
C25 C 0.2503(13) 0.4504(16) 0.1180(9) 0.086(7) Uiso 1 1 d D . .
C26 C 0.3498(17) 0.487(2) 0.0853(16) 0.125(10) Uiso 1 1 d D . .
H26A H 0.4006 0.4757 0.1105 0.188 Uiso 1 1 calc R . .
H26B H 0.3810 0.5643 0.0961 0.188 Uiso 1 1 calc R . .
H26C H 0.3301 0.4423 0.0286 0.188 Uiso 1 1 calc R . .
C27 C 0.1699(18) 0.472(2) 0.0817(14) 0.104(9) Uiso 1 1 d D . .
H27A H 0.2009 0.5513 0.0972 0.156 Uiso 1 1 calc R . .
H27B H 0.1068 0.4457 0.1007 0.156 Uiso 1 1 calc R . .
H27C H 0.1517 0.4336 0.0245 0.156 Uiso 1 1 calc R . .
C28 C 0.280(2) 0.508(2) 0.2096(10) 0.105(9) Uiso 1 1 d D . .
H28A H 0.3295 0.4926 0.2306 0.158 Uiso 1 1 calc R . .
H28B H 0.2165 0.4804 0.2284 0.158 Uiso 1 1 calc R . .
H28C H 0.3113 0.5876 0.2272 0.158 Uiso 1 1 calc R . .
C29 C 0.2051(13) 0.1294(16) 0.4645(10) 0.057(5) Uiso 1 1 d D . .
C30 C 0.2946(13) 0.1675(15) 0.5112(10) 0.049(5) Uiso 1 1 d D . .
C31 C 0.4003(14) 0.2263(14) 0.5593(10) 0.068(6) Uiso 1 1 d D . .
C32 C 0.459(3) 0.3519(15) 0.579(2) 0.171(15) Uiso 1 1 d D . .
H32A H 0.4589 0.3617 0.5309 0.257 Uiso 1 1 calc R . .
H32B H 0.5310 0.3865 0.6090 0.257 Uiso 1 1 calc R . .
H32C H 0.4232 0.3862 0.6110 0.257 Uiso 1 1 calc R . .
C33 C 0.466(2) 0.180(3) 0.5136(17) 0.154(13) Uiso 1 1 d D . .
H33A H 0.4731 0.1956 0.4677 0.232 Uiso 1 1 calc R . .
H33B H 0.4300 0.0999 0.4968 0.232 Uiso 1 1 calc R . .
H33C H 0.5350 0.2139 0.5479 0.232 Uiso 1 1 calc R . .
C34 C 0.400(2) 0.199(2) 0.6319(13) 0.121(10) Uiso 1 1 d D . .
H34A H 0.4723 0.2378 0.6633 0.181 Uiso 1 1 calc R . .
H34B H 0.3706 0.1198 0.6140 0.181 Uiso 1 1 calc R . .
H34C H 0.3585 0.2228 0.6637 0.181 Uiso 1 1 calc R . .
C35 C -0.1022(16) 0.0684(17) 0.3911(11) 0.059(5) Uiso 1 1 d . . .
C36 C -0.1421(16) 0.1236(17) 0.4206(11) 0.058(5) Uiso 1 1 d . . .
C37 C -0.1872(13) 0.1994(13) 0.4538(9) 0.074(6) Uiso 1 1 d D . .
C38 C -0.215(2) 0.191(2) 0.5310(12) 0.119(10) Uiso 1 1 d D . .
H38A H -0.2702 0.1156 0.5185 0.179 Uiso 1 1 calc R . .
H38B H -0.2388 0.2420 0.5562 0.179 Uiso 1 1 calc R . .
H38C H -0.1525 0.2089 0.5665 0.179 Uiso 1 1 calc R . .
C39 C -0.2761(17) 0.178(2) 0.3910(13) 0.107(9) Uiso 1 1 d D . .
H39A H -0.3344 0.1029 0.3730 0.160 Uiso 1 1 calc R . .
H39B H -0.2490 0.1885 0.3465 0.160 Uiso 1 1 calc R . .
H39C H -0.3003 0.2300 0.4142 0.160 Uiso 1 1 calc R . .
C40 C -0.0988(16) 0.3208(14) 0.4777(13) 0.088(7) Uiso 1 1 d D . .
H40A H -0.1271 0.3699 0.4962 0.132 Uiso 1 1 calc R . .
H40B H -0.0721 0.3271 0.4322 0.132 Uiso 1 1 calc R . .
H40C H -0.0418 0.3414 0.5195 0.132 Uiso 1 1 calc R . .
C41 C 0.2188(15) 0.1220(15) 0.2330(10) 0.047(5) Uiso 1 1 d . . .
C42 C 0.3139(14) 0.1752(14) 0.2422(10) 0.040(4) Uiso 1 1 d . . .
C43 C 0.4293(16) 0.2455(17) 0.2538(11) 0.055(5) Uiso 1 1 d . . .
C44 C 0.471(3) 0.350(3) 0.321(2) 0.172(15) Uiso 1 1 d . . .
H44A H 0.5464 0.3939 0.3276 0.258 Uiso 1 1 calc R . .
H44B H 0.4585 0.3371 0.3679 0.258 Uiso 1 1 calc R . .
H44C H 0.4368 0.3887 0.3132 0.258 Uiso 1 1 calc R . .
C45 C 0.494(3) 0.187(3) 0.267(2) 0.167(14) Uiso 1 1 d . . .
H45A H 0.5686 0.2354 0.2743 0.250 Uiso 1 1 calc R . .
H45B H 0.4694 0.1174 0.2204 0.250 Uiso 1 1 calc R . .
H45C H 0.4823 0.1717 0.3128 0.250 Uiso 1 1 calc R . .
C46 C 0.447(3) 0.249(3) 0.1775(19) 0.160(14) Uiso 1 1 d . . .
H46A H 0.5221 0.2960 0.1836 0.239 Uiso 1 1 calc R . .
H46B H 0.4086 0.2795 0.1611 0.239 Uiso 1 1 calc R . .
H46C H 0.4231 0.1749 0.1378 0.239 Uiso 1 1 calc R . .
C47 C 0.088(2) 0.270(2) 0.6134(14) 0.100(8) Uiso 1 1 d . . .
H47A H 0.1302 0.3138 0.6677 0.150 Uiso 1 1 calc R . .
H47B H 0.0504 0.3031 0.6010 0.150 Uiso 1 1 calc R . .
H47C H 0.1344 0.2663 0.5782 0.150 Uiso 1 1 calc R . .
O1 O 0.2382(12) 0.3828(11) 0.3359(8) 0.077(4) Uani 1 1 d . . .
O2 O 0.1152(11) 0.2746(11) 0.3806(9) 0.074(4) Uani 1 1 d . . .
O3 O 0.2897(16) -0.0949(15) 0.2013(9) 0.106(6) Uani 1 1 d . . .
O4 O 0.2963(13) -0.0281(14) 0.3257(9) 0.090(5) Uani 1 1 d . . .
O5 O -0.0827(15) 0.2701(14) 0.2819(9) 0.097(5) Uani 1 1 d . . .
O6 O 0.0216(13) 0.3050(12) 0.1988(9) 0.084(5) Uani 1 1 d . . .
O7 O 0.0244(10) -0.1366(10) 0.2602(7) 0.056(3) Uani 1 1 d . . .
O8 O 0.0247(11) -0.1899(11) 0.1285(8) 0.064(4) Uani 1 1 d . . .
O9 O -0.2260(11) -0.2687(11) 0.2430(8) 0.069(4) Uani 1 1 d . . .
O10 O -0.2265(13) -0.3222(13) 0.1125(9) 0.093(5) Uani 1 1 d . . .
O11 O 0.0132(12) 0.1578(13) 0.6031(8) 0.079(4) Uiso 1 1 d . . .
F1 F 0.267(3) 0.5464(19) 0.4740(17) 0.109(4) Uiso 0.550(13) 1 d PD A 1
F2 F 0.3482(18) 0.464(2) 0.4862(17) 0.109(4) Uiso 0.550(13) 1 d PD A 1
F3 F 0.221(2) 0.421(2) 0.5282(14) 0.109(4) Uiso 0.550(13) 1 d PD A 1
F1' F 0.184(2) 0.469(3) 0.5099(18) 0.109(4) Uiso 0.450(13) 1 d PD A 2
F2' F 0.327(2) 0.5542(19) 0.488(2) 0.109(4) Uiso 0.450(13) 1 d PD A 2
F3' F 0.295(3) 0.423(3) 0.5168(18) 0.109(4) Uiso 0.450(13) 1 d PD A 2
F4 F 0.360(3) -0.2268(19) 0.2227(14) 0.100(4) Uiso 0.524(15) 1 d PD B 1
F5 F 0.368(3) -0.144(3) 0.3506(13) 0.100(4) Uiso 0.524(15) 1 d PD B 1
F6 F 0.4751(17) -0.073(2) 0.2896(18) 0.100(4) Uiso 0.524(15) 1 d PD B 1
F4' F 0.389(3) -0.187(3) 0.2139(13) 0.100(4) Uiso 0.476(15) 1 d PD B 2
F5' F 0.319(2) -0.215(2) 0.306(2) 0.100(4) Uiso 0.476(15) 1 d PD B 2
F6' F 0.453(2) -0.069(2) 0.3468(15) 0.100(4) Uiso 0.476(15) 1 d PD B 2
F7 F 0.101(2) 0.533(3) 0.320(3) 0.147(6) Uiso 0.46(3) 1 d PD C 1
F8 F -0.058(3) 0.467(4) 0.338(3) 0.147(6) Uiso 0.46(3) 1 d PD C 1
F9 F -0.023(5) 0.476(4) 0.231(2) 0.147(6) Uiso 0.46(3) 1 d PD C 1
F7' F 0.045(4) 0.499(3) 0.242(2) 0.147(6) Uiso 0.54(3) 1 d PD C 2
F8' F 0.074(3) 0.493(3) 0.3529(18) 0.147(6) Uiso 0.54(3) 1 d PD C 2
F9' F -0.088(2) 0.453(3) 0.297(3) 0.147(6) Uiso 0.54(3) 1 d PD C 2
F10 F 0.0751(18) -0.2870(18) 0.2544(11) 0.086(3) Uiso 0.586(11) 1 d PD D 1
F11 F 0.055(2) -0.3544(19) 0.1299(12) 0.086(3) Uiso 0.586(11) 1 d PD D 1
F12 F -0.0762(14) -0.3887(17) 0.1760(15) 0.086(3) Uiso 0.586(11) 1 d PD D 1
F10' F -0.047(2) -0.355(3) 0.2245(19) 0.086(3) Uiso 0.414(11) 1 d PD D 2
F11' F 0.1107(17) -0.303(3) 0.198(2) 0.086(3) Uiso 0.414(11) 1 d PD D 2
F12' F -0.035(3) -0.391(2) 0.1160(12) 0.086(3) Uiso 0.414(11) 1 d PD D 2
F13 F -0.348(3) -0.532(2) 0.0878(12) 0.111(4) Uiso 0.560(16) 1 d PD E 1
F14 F -0.409(2) -0.465(2) 0.1887(17) 0.111(4) Uiso 0.560(16) 1 d PD E 1
F15 F -0.280(2) -0.488(2) 0.2024(16) 0.111(4) Uiso 0.560(16) 1 d PD E 1
F13' F -0.300(3) -0.528(3) 0.114(2) 0.111(4) Uiso 0.440(16) 1 d PD E 2
F14' F -0.421(2) -0.496(3) 0.120(2) 0.111(4) Uiso 0.440(16) 1 d PD E 2
F15' F -0.323(3) -0.473(3) 0.2254(15) 0.111(4) Uiso 0.440(16) 1 d PD E 2


_geom_special_details            
;
 All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell s.u.'s are taken
 into account individually in the estimation of s.u.'s in distances, angles
 and torsion angles; correlations between s.u.'s in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C29 2.072(16) . ?
Ag1 C35 2.14(2) . ?
Ag1 Ag6 2.885(2) . ?
Ag1 Ag5 2.893(2) . ?
Ag1 Ag9 2.986(2) . ?
Ag1 Ag9 3.074(2) 2_556 ?
Ag1 Ag8 3.175(2) . ?
Ag2 C23 2.07(2) . ?
Ag2 C11 2.085(16) . ?
Ag2 Ag11 2.850(4) . ?
Ag2 Ag11 2.874(4) . ?
Ag2 Ag11 3.083(4) 2 ?
Ag2 Ag10 3.084(2) . ?
Ag2 Ag4 3.129(2) . ?
Ag2 Ag7 3.170(2) . ?
Ag2 Ag11 3.268(5) 2 ?
Ag3 C17 2.063(15) 2 ?
Ag3 C41 2.124(19) . ?
Ag3 Ag8 2.849(2) . ?
Ag3 Ag7 2.879(2) . ?
Ag3 Ag4 3.058(2) . ?
Ag3 Ag10 3.065(2) 2 ?
Ag3 Ag6 3.082(2) . ?
Ag3 Ag11 3.170(4) 2 ?
Ag3 Ag5 3.368(2) . ?
Ag4 O3 2.255(15) . ?
Ag4 C11 2.285(18) . ?
Ag4 C41 2.382(17) . ?
Ag4 C12 2.423(19) . ?
Ag4 O8 2.561(13) . ?
Ag4 C42 2.689(17) . ?
Ag5 C35 2.17(2) . ?
Ag5 O9 2.212(13) . ?
Ag5 Ag8 2.983(2) . ?
Ag5 Ag9 3.157(3) . ?
Ag6 C29 2.230(18) . ?
Ag6 O4 2.285(14) . ?
Ag6 C41 2.291(17) . ?
Ag7 O1 2.250(13) . ?
Ag7 C23 2.41(2) . ?
Ag7 C41 2.441(17) . ?
Ag7 C24 2.70(2) . ?
Ag7 Ag11 2.862(4) 2 ?
Ag7 Ag11 3.122(5) 2 ?
Ag8 O5 2.250(14) . ?
Ag8 C17 2.364(17) 2 ?
Ag8 O2 2.438(14) . ?
Ag8 C35 2.453(19) . ?
Ag9 C29 2.245(19) 2_556 ?
Ag9 C35 2.284(19) . ?
Ag9 C30 2.555(18) 2_556 ?
Ag9 O11 2.561(15) . ?
Ag9 C36 2.679(19) . ?
Ag9 Ag1 3.074(2) 2_556 ?
Ag10 C23 2.33(2) . ?
Ag10 O10 2.364(17) 2 ?
Ag10 C17 2.369(17) . ?
Ag10 O8 2.490(13) 2 ?
Ag10 C24 2.67(2) . ?
Ag10 C18 2.707(15) . ?
Ag10 Ag3 3.065(2) 2 ?
Ag10 Ag11 3.119(5) 2 ?
Ag11 O6 2.274(15) 2 ?
Ag11 C11 2.317(19) . ?
Ag11 C23 2.69(2) 2 ?
Ag11 Ag7 2.862(4) 2 ?
Ag11 Ag3 3.170(4) 2 ?
Ag11 Ag2 3.268(5) 2 ?
Ag11 C11 2.115(19) . ?
Ag11 C23 2.12(2) 2 ?
Ag11 O6 2.513(16) 2 ?
Ag11 Ag2 3.083(4) 2 ?
Ag11 Ag10 3.119(5) 2 ?
Ag11 Ag7 3.122(5) 2 ?
C1 O1 1.18(2) . ?
C1 O2 1.28(2) . ?
C1 C2 1.5350(11) . ?
C2 F2' 1.298(10) . ?
C2 F3' 1.299(10) . ?
C2 F3 1.300(10) . ?
C2 F1 1.302(10) . ?
C2 F2 1.306(10) . ?
C2 F1' 1.312(10) . ?
C3 O3 1.17(2) . ?
C3 O4 1.22(2) . ?
C3 C4 1.5350(11) . ?
C4 F6 1.298(10) . ?
C4 F5' 1.302(10) . ?
C4 F5 1.302(10) . ?
C4 F6' 1.302(10) . ?
C4 F4 1.305(10) . ?
C4 F4' 1.306(10) . ?
C5 O6 1.20(3) . ?
C5 O5 1.31(3) . ?
C5 C6 1.5352(11) . ?
C6 F9' 1.299(10) . ?
C6 F7 1.303(10) . ?
C6 F7' 1.304(10) . ?
C6 F9 1.306(10) . ?
C6 F8 1.306(10) . ?
C6 F8' 1.307(10) . ?
C7 O7 1.239(19) . ?
C7 O8 1.28(2) . ?
C7 C8 1.5350(11) . ?
C8 F11' 1.296(10) . ?
C8 F12 1.298(10) . ?
C8 F10' 1.301(10) . ?
C8 F11 1.306(10) . ?
C8 F12' 1.310(10) . ?
C8 F10 1.310(10) . ?
C9 O9 1.24(2) . ?
C9 O10 1.25(2) . ?
C9 C10 1.5351(11) . ?
C10 F14' 1.301(10) . ?
C10 F15' 1.302(10) . ?
C10 F13 1.303(10) . ?
C10 F13' 1.305(10) . ?
C10 F14 1.305(10) . ?
C10 F15 1.307(10) . ?
C11 C12 1.276(9) . ?
C12 C13 1.48(2) . ?
C13 C16 1.46(3) . ?
C13 C14 1.5350(8) . ?
C13 C15 1.5350(12) . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 C18 1.281(9) . ?
C17 Ag3 2.063(15) 2 ?
C17 Ag8 2.364(17) 2 ?
C18 C19 1.47(2) . ?
C19 C21 1.5349(11) . ?
C19 C22 1.5350(11) . ?
C19 C20 1.5350(11) . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 C24 1.20(3) . ?
C23 Ag11 2.12(2) 2 ?
C23 Ag11 2.69(2) 2 ?
C24 C25 1.51(3) . ?
C25 C27 1.5350(11) . ?
C25 C28 1.5350(12) . ?
C25 C26 1.5350(11) . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 C30 1.281(9) . ?
C29 Ag9 2.245(19) 2_556 ?
C30 C31 1.42(2) . ?
C30 Ag9 2.555(18) 2_556 ?
C31 C34 1.5348(11) . ?
C31 C33 1.5349(11) . ?
C31 C32 1.5350(12) . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
C34 H34A 0.9600 . ?
C34 H34B 0.9600 . ?
C34 H34C 0.9600 . ?
C35 C36 1.20(2) . ?
C36 C37 1.51(3) . ?
C37 C40 1.5349(11) . ?
C37 C38 1.5350(12) . ?
C37 C39 1.5350(11) . ?
C38 H38A 0.9600 . ?
C38 H38B 0.9600 . ?
C38 H38C 0.9600 . ?
C39 H39A 0.9600 . ?
C39 H39B 0.9600 . ?
C39 H39C 0.9600 . ?
C40 H40A 0.9600 . ?
C40 H40B 0.9600 . ?
C40 H40C 0.9600 . ?
C41 C42 1.20(2) . ?
C42 C43 1.47(2) . ?
C43 C44 1.42(3) . ?
C43 C46 1.47(3) . ?
C43 C45 1.60(3) . ?
C44 H44A 0.9600 . ?
C44 H44B 0.9600 . ?
C44 H44C 0.9600 . ?
C45 H45A 0.9600 . ?
C45 H45B 0.9600 . ?
C45 H45C 0.9600 . ?
C46 H46A 0.9600 . ?
C46 H46B 0.9600 . ?
C46 H46C 0.9600 . ?
C47 O11 1.44(3) . ?
C47 H47A 0.9600 . ?
C47 H47B 0.9600 . ?
C47 H47C 0.9600 . ?
O6 Ag11 2.274(15) 2 ?
O6 Ag11 2.513(16) 2 ?
O8 Ag10 2.490(13) 2 ?
O10 Ag10 2.364(17) 2 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C29 Ag1 C35 167.9(7) . . ?
C29 Ag1 Ag6 50.2(5) . . ?
C35 Ag1 Ag6 137.7(5) . . ?
C29 Ag1 Ag5 131.0(5) . . ?
C35 Ag1 Ag5 48.3(5) . . ?
Ag6 Ag1 Ag5 94.26(7) . . ?
C29 Ag1 Ag9 118.2(5) . . ?
C35 Ag1 Ag9 49.6(5) . . ?
Ag6 Ag1 Ag9 140.34(7) . . ?
Ag5 Ag1 Ag9 64.94(6) . . ?
C29 Ag1 Ag9 46.9(5) . 2_556 ?
C35 Ag1 Ag9 121.2(5) . 2_556 ?
Ag6 Ag1 Ag9 82.66(6) . 2_556 ?
Ag5 Ag1 Ag9 105.06(7) . 2_556 ?
Ag9 Ag1 Ag9 71.93(7) . 2_556 ?
C29 Ag1 Ag8 141.5(5) . . ?
C35 Ag1 Ag8 50.5(5) . . ?
Ag6 Ag1 Ag8 96.45(6) . . ?
Ag5 Ag1 Ag8 58.68(6) . . ?
Ag9 Ag1 Ag8 99.74(7) . . ?
Ag9 Ag1 Ag8 163.68(7) 2_556 . ?
C23 Ag2 C11 168.7(8) . . ?
C23 Ag2 Ag11 130.7(6) . . ?
C11 Ag2 Ag11 53.3(5) . . ?
C23 Ag2 Ag11 141.0(6) . . ?
C11 Ag2 Ag11 47.3(5) . . ?
Ag11 Ag2 Ag11 20.82(9) . . ?
C23 Ag2 Ag11 43.3(6) . 2 ?
C11 Ag2 Ag11 147.6(5) . 2 ?
Ag11 Ag2 Ag11 102.38(12) . 2 ?
Ag11 Ag2 Ag11 101.93(11) . 2 ?
C23 Ag2 Ag10 49.1(6) . . ?
C11 Ag2 Ag10 127.6(5) . . ?
Ag11 Ag2 Ag10 85.74(10) . . ?
Ag11 Ag2 Ag10 103.72(11) . . ?
Ag11 Ag2 Ag10 60.77(10) 2 . ?
C23 Ag2 Ag4 133.8(6) . . ?
C11 Ag2 Ag4 46.9(5) . . ?
Ag11 Ag2 Ag4 94.50(10) . . ?
Ag11 Ag2 Ag4 78.84(10) . . ?
Ag11 Ag2 Ag4 129.59(11) 2 . ?
Ag10 Ag2 Ag4 169.01(7) . . ?
C23 Ag2 Ag7 49.4(6) . . ?
C11 Ag2 Ag7 132.9(5) . . ?
Ag11 Ag2 Ag7 154.99(12) . . ?
Ag11 Ag2 Ag7 138.48(11) . . ?
Ag11 Ag2 Ag7 59.89(9) 2 . ?
Ag10 Ag2 Ag7 98.38(6) . . ?
Ag4 Ag2 Ag7 86.05(6) . . ?
C23 Ag2 Ag11 55.1(6) . 2 ?
C11 Ag2 Ag11 136.1(6) . 2 ?
Ag11 Ag2 Ag11 104.62(11) . 2 ?
Ag11 Ag2 Ag11 97.51(11) . 2 ?
Ag11 Ag2 Ag11 18.46(8) 2 2 ?
Ag10 Ag2 Ag11 79.20(9) . 2 ?
Ag4 Ag2 Ag11 111.26(10) . 2 ?
Ag7 Ag2 Ag11 52.76(8) . 2 ?
C17 Ag3 C41 166.2(7) 2 . ?
C17 Ag3 Ag8 54.8(5) 2 . ?
C41 Ag3 Ag8 116.1(5) . . ?
C17 Ag3 Ag7 110.4(5) 2 . ?
C41 Ag3 Ag7 56.0(5) . . ?
Ag8 Ag3 Ag7 79.57(6) . . ?
C17 Ag3 Ag4 138.5(5) 2 . ?
C41 Ag3 Ag4 50.9(5) . . ?
Ag8 Ag3 Ag4 166.75(7) . . ?
Ag7 Ag3 Ag4 92.73(6) . . ?
C17 Ag3 Ag10 50.5(5) 2 2 ?
C41 Ag3 Ag10 138.7(5) . 2 ?
Ag8 Ag3 Ag10 104.85(7) . 2 ?
Ag7 Ag3 Ag10 132.34(7) . 2 ?
Ag4 Ag3 Ag10 88.32(6) . 2 ?
C17 Ag3 Ag6 138.5(5) 2 . ?
C41 Ag3 Ag6 48.0(5) . . ?
Ag8 Ag3 Ag6 99.35(7) . . ?
Ag7 Ag3 Ag6 92.87(6) . . ?
Ag4 Ag3 Ag6 70.06(5) . . ?
Ag10 Ag3 Ag6 131.41(7) 2 . ?
C17 Ag3 Ag11 59.3(5) 2 2 ?
C41 Ag3 Ag11 108.9(5) . 2 ?
Ag8 Ag3 Ag11 68.61(9) . 2 ?
Ag7 Ag3 Ag11 56.23(9) . 2 ?
Ag4 Ag3 Ag11 115.97(10) . 2 ?
Ag10 Ag3 Ag11 80.77(9) 2 2 ?
Ag6 Ag3 Ag11 147.76(9) . 2 ?
C17 Ag3 Ag5 57.0(5) 2 . ?
C41 Ag3 Ag5 129.3(5) . . ?
Ag8 Ag3 Ag5 56.61(5) . . ?
Ag7 Ag3 Ag5 133.93(7) . . ?
Ag4 Ag3 Ag5 126.92(6) . . ?
Ag10 Ag3 Ag5 77.47(6) 2 . ?
Ag6 Ag3 Ag5 81.95(6) . . ?
Ag11 Ag3 Ag5 111.75(10) 2 . ?
O3 Ag4 C11 136.6(6) . . ?
O3 Ag4 C41 104.5(6) . . ?
C11 Ag4 C41 116.4(6) . . ?
O3 Ag4 C12 105.4(5) . . ?
C11 Ag4 C12 31.3(3) . . ?
C41 Ag4 C12 145.7(6) . . ?
O3 Ag4 O8 91.2(6) . . ?
C11 Ag4 O8 95.6(6) . . ?
C41 Ag4 O8 99.6(5) . . ?
C12 Ag4 O8 96.2(6) . . ?
O3 Ag4 C42 94.3(6) . . ?
C11 Ag4 C42 115.7(6) . . ?
C41 Ag4 C42 26.6(5) . . ?
C12 Ag4 C42 134.0(6) . . ?
O8 Ag4 C42 125.0(5) . . ?
O3 Ag4 Ag3 120.4(4) . . ?
C11 Ag4 Ag3 99.8(4) . . ?
C41 Ag4 Ag3 43.8(5) . . ?
C12 Ag4 Ag3 127.1(4) . . ?
O8 Ag4 Ag3 60.2(3) . . ?
C42 Ag4 Ag3 70.2(4) . . ?
O3 Ag4 Ag2 167.6(5) . . ?
C11 Ag4 Ag2 41.8(4) . . ?
C41 Ag4 Ag2 74.7(4) . . ?
C12 Ag4 Ag2 72.5(4) . . ?
O8 Ag4 Ag2 101.1(3) . . ?
C42 Ag4 Ag2 79.6(3) . . ?
Ag3 Ag4 Ag2 67.81(5) . . ?
C35 Ag5 O9 142.9(7) . . ?
C35 Ag5 Ag1 47.4(5) . . ?
O9 Ag5 Ag1 144.5(4) . . ?
C35 Ag5 Ag8 54.1(5) . . ?
O9 Ag5 Ag8 149.5(4) . . ?
Ag1 Ag5 Ag8 65.39(6) . . ?
C35 Ag5 Ag9 46.4(5) . . ?
O9 Ag5 Ag9 103.5(4) . . ?
Ag1 Ag5 Ag9 58.95(5) . . ?
Ag8 Ag5 Ag9 100.21(6) . . ?
C35 Ag5 Ag3 99.7(5) . . ?
O9 Ag5 Ag3 117.1(4) . . ?
Ag1 Ag5 Ag3 75.32(6) . . ?
Ag8 Ag5 Ag3 52.87(5) . . ?
Ag9 Ag5 Ag3 134.08(7) . . ?
C29 Ag6 O4 103.9(6) . . ?
C29 Ag6 C41 141.3(7) . . ?
O4 Ag6 C41 109.7(6) . . ?
C29 Ag6 Ag1 45.6(4) . . ?
O4 Ag6 Ag1 137.8(4) . . ?
C41 Ag6 Ag1 110.7(4) . . ?
C29 Ag6 Ag3 125.5(4) . . ?
O4 Ag6 Ag3 124.1(4) . . ?
C41 Ag6 Ag3 43.5(5) . . ?
Ag1 Ag6 Ag3 80.13(6) . . ?
O1 Ag7 C23 143.2(6) . . ?
O1 Ag7 C41 96.8(5) . . ?
C23 Ag7 C41 112.6(6) . . ?
O1 Ag7 C24 116.8(6) . . ?
C23 Ag7 C24 26.5(6) . . ?
C41 Ag7 C24 132.6(6) . . ?
O1 Ag7 Ag11 129.9(4) . 2 ?
C23 Ag7 Ag11 60.7(5) . 2 ?
C41 Ag7 Ag11 110.0(5) . 2 ?
C24 Ag7 Ag11 74.1(5) . 2 ?
O1 Ag7 Ag3 112.3(4) . . ?
C23 Ag7 Ag3 104.0(5) . . ?
C41 Ag7 Ag3 46.1(4) . . ?
C24 Ag7 Ag3 129.8(5) . . ?
Ag11 Ag7 Ag3 67.04(10) 2 . ?
O1 Ag7 Ag11 136.3(4) . 2 ?
C23 Ag7 Ag11 42.7(5) . 2 ?
C41 Ag7 Ag11 119.9(4) . 2 ?
C24 Ag7 Ag11 54.9(5) . 2 ?
Ag11 Ag7 Ag11 19.29(10) 2 2 ?
Ag3 Ag7 Ag11 82.60(10) . 2 ?
O1 Ag7 Ag2 164.6(4) . . ?
C23 Ag7 Ag2 40.8(5) . . ?
C41 Ag7 Ag2 73.2(4) . . ?
C24 Ag7 Ag2 66.1(4) . . ?
Ag11 Ag7 Ag2 65.38(10) 2 . ?
Ag3 Ag7 Ag2 69.39(6) . . ?
Ag11 Ag7 Ag2 58.67(8) 2 . ?
O5 Ag8 C17 118.1(6) . 2 ?
O5 Ag8 O2 89.4(6) . . ?
C17 Ag8 O2 132.8(5) 2 . ?
O5 Ag8 C35 120.6(6) . . ?
C17 Ag8 C35 107.6(6) 2 . ?
O2 Ag8 C35 85.6(6) . . ?
O5 Ag8 Ag3 130.7(4) . . ?
C17 Ag8 Ag3 45.5(4) 2 . ?
O2 Ag8 Ag3 87.4(4) . . ?
C35 Ag8 Ag3 108.3(5) . . ?
O5 Ag8 Ag5 153.9(5) . . ?
C17 Ag8 Ag5 62.8(4) 2 . ?
O2 Ag8 Ag5 108.7(3) . . ?
C35 Ag8 Ag5 45.8(5) . . ?
Ag3 Ag8 Ag5 70.52(6) . . ?
O5 Ag8 Ag1 134.2(4) . . ?
C17 Ag8 Ag1 107.4(4) 2 . ?
O2 Ag8 Ag1 53.6(3) . . ?
C35 Ag8 Ag1 42.3(5) . . ?
Ag3 Ag8 Ag1 79.10(6) . . ?
Ag5 Ag8 Ag1 55.93(5) . . ?
C29 Ag9 C35 160.7(7) 2_556 . ?
C29 Ag9 C30 30.1(3) 2_556 2_556 ?
C35 Ag9 C30 130.9(6) . 2_556 ?
C29 Ag9 O11 98.4(5) 2_556 . ?
C35 Ag9 O11 99.1(6) . . ?
C30 Ag9 O11 121.6(5) 2_556 . ?
C29 Ag9 C36 145.6(6) 2_556 . ?
C35 Ag9 C36 26.5(6) . . ?
C30 Ag9 C36 119.9(6) 2_556 . ?
O11 Ag9 C36 90.3(5) . . ?
C29 Ag9 Ag1 149.4(4) 2_556 . ?
C35 Ag9 Ag1 45.6(5) . . ?
C30 Ag9 Ag1 161.8(4) 2_556 . ?
O11 Ag9 Ag1 74.3(3) . . ?
C36 Ag9 Ag1 64.9(4) . . ?
C29 Ag9 Ag1 42.4(4) 2_556 2_556 ?
C35 Ag9 Ag1 152.9(5) . 2_556 ?
C30 Ag9 Ag1 71.4(4) 2_556 2_556 ?
O11 Ag9 Ag1 74.2(3) . 2_556 ?
C36 Ag9 Ag1 164.4(4) . 2_556 ?
Ag1 Ag9 Ag1 108.07(7) . 2_556 ?
C29 Ag9 Ag5 125.8(5) 2_556 . ?
C35 Ag9 Ag5 43.4(5) . . ?
C30 Ag9 Ag5 108.0(4) 2_556 . ?
O11 Ag9 Ag5 130.2(3) . . ?
C36 Ag9 Ag5 66.8(4) . . ?
Ag1 Ag9 Ag5 56.11(5) . . ?
Ag1 Ag9 Ag5 122.10(8) 2_556 . ?
C23 Ag10 O10 124.0(7) . 2 ?
C23 Ag10 C17 122.8(7) . . ?
O10 Ag10 C17 99.3(5) 2 . ?
C23 Ag10 O8 121.0(6) . 2 ?
O10 Ag10 O8 82.5(5) 2 2 ?
C17 Ag10 O8 98.0(5) . 2 ?
C23 Ag10 C24 26.8(6) . . ?
O10 Ag10 C24 99.1(6) 2 . ?
C17 Ag10 C24 146.1(6) . . ?
O8 Ag10 C24 112.4(5) 2 . ?
C23 Ag10 C18 113.8(6) . . ?
O10 Ag10 C18 85.5(5) 2 . ?
C17 Ag10 C18 28.2(3) . . ?
O8 Ag10 C18 120.6(4) 2 . ?
C24 Ag10 C18 126.9(5) . . ?
C23 Ag10 Ag3 125.1(6) . 2 ?
O10 Ag10 Ag3 110.8(4) 2 2 ?
C17 Ag10 Ag3 42.2(4) . 2 ?
O8 Ag10 Ag3 60.7(3) 2 2 ?
C24 Ag10 Ag3 147.2(5) . 2 ?
C18 Ag10 Ag3 70.3(3) . 2 ?
C23 Ag10 Ag2 42.2(5) . . ?
O10 Ag10 Ag2 144.0(4) 2 . ?
C17 Ag10 Ag2 80.7(4) . . ?
O8 Ag10 Ag2 133.4(3) 2 . ?
C24 Ag10 Ag2 67.9(4) . . ?
C18 Ag10 Ag2 77.8(3) . . ?
Ag3 Ag10 Ag2 93.38(7) 2 . ?
C23 Ag10 Ag11 42.9(5) . 2 ?
O10 Ag10 Ag11 140.7(4) 2 2 ?
C17 Ag10 Ag11 118.5(4) . 2 ?
O8 Ag10 Ag11 81.9(3) 2 2 ?
C24 Ag10 Ag11 55.2(5) . 2 ?
C18 Ag10 Ag11 133.1(3) . 2 ?
Ag3 Ag10 Ag11 92.24(9) 2 2 ?
Ag2 Ag10 Ag11 59.61(9) . 2 ?
O6 Ag11 C11 114.0(6) 2 . ?
O6 Ag11 C23 85.7(6) 2 2 ?
C11 Ag11 C23 110.5(7) . 2 ?
O6 Ag11 Ag2 160.1(4) 2 . ?
C11 Ag11 Ag2 46.2(4) . . ?
C23 Ag11 Ag2 101.3(5) 2 . ?
O6 Ag11 Ag7 62.6(4) 2 2 ?
C11 Ag11 Ag7 160.5(5) . 2 ?
C23 Ag11 Ag7 51.3(4) 2 2 ?
Ag2 Ag11 Ag7 135.69(15) . 2 ?
O6 Ag11 Ag3 102.7(4) 2 2 ?
C11 Ag11 Ag3 138.4(5) . 2 ?
C23 Ag11 Ag3 90.5(4) 2 2 ?
Ag2 Ag11 Ag3 95.85(12) . 2 ?
Ag7 Ag11 Ag3 56.74(8) 2 2 ?
O6 Ag11 Ag2 119.0(5) 2 2 ?
C11 Ag11 Ag2 109.8(5) . 2 ?
C23 Ag11 Ag2 39.2(5) 2 2 ?
Ag2 Ag11 Ag2 75.38(11) . 2 ?
Ag7 Ag11 Ag2 61.86(9) 2 2 ?
Ag3 Ag11 Ag2 64.81(8) 2 2 ?
C11 Ag11 C23 152.8(8) . 2 ?
C11 Ag11 O6 112.3(6) . 2 ?
C23 Ag11 O6 93.5(7) 2 2 ?
C11 Ag11 Ag2 46.4(4) . . ?
C23 Ag11 Ag2 117.3(6) 2 . ?
O6 Ag11 Ag2 139.1(4) 2 . ?
C11 Ag11 Ag2 123.5(5) . 2 ?
C23 Ag11 Ag2 42.1(6) 2 2 ?
O6 Ag11 Ag2 117.8(4) 2 2 ?
Ag2 Ag11 Ag2 78.07(11) . 2 ?
C11 Ag11 Ag10 105.6(5) . 2 ?
C23 Ag11 Ag10 48.3(5) 2 2 ?
O6 Ag11 Ag10 129.2(4) 2 2 ?
Ag2 Ag11 Ag10 91.73(12) . 2 ?
Ag2 Ag11 Ag10 59.62(9) 2 2 ?
C11 Ag11 Ag7 153.6(5) . 2 ?
C23 Ag11 Ag7 50.3(5) 2 2 ?
O6 Ag11 Ag7 56.4(4) 2 2 ?
Ag2 Ag11 Ag7 123.78(15) . 2 ?
Ag2 Ag11 Ag7 61.44(9) 2 2 ?
Ag10 Ag11 Ag7 98.65(12) 2 2 ?
O1 C1 O2 129.0(17) . . ?
O1 C1 C2 117.4(19) . . ?
O2 C1 C2 113.5(17) . . ?
F2' C2 F3' 105(3) . . ?
F2' C2 F3 123(2) . . ?
F3' C2 F3 49.8(18) . . ?
F2' C2 F1 38.1(17) . . ?
F3' C2 F1 137(3) . . ?
F3 C2 F1 122(2) . . ?
F2' C2 F2 70(2) . . ?
F3' C2 F2 48.7(19) . . ?
F3 C2 F2 97(2) . . ?
F1 C2 F2 108(2) . . ?
F2' C2 F1' 103(3) . . ?
F3' C2 F1' 103(2) . . ?
F3 C2 F1' 54.3(17) . . ?
F1 C2 F1' 76(2) . . ?
F2 C2 F1' 142(2) . . ?
F2' C2 C1 121(2) . . ?
F3' C2 C1 113(2) . . ?
F3 C2 C1 116(2) . . ?
F1 C2 C1 107.1(19) . . ?
F2 C2 C1 104.7(19) . . ?
F1' C2 C1 111(2) . . ?
O3 C3 O4 127.2(18) . . ?
O3 C3 C4 117.9(19) . . ?
O4 C3 C4 114.6(18) . . ?
F6 C4 F5' 137(2) . . ?
F6 C4 F5 106(2) . . ?
F5' C4 F5 43.9(16) . . ?
F6 C4 F6' 50.6(16) . . ?
F5' C4 F6' 99(2) . . ?
F5 C4 F6' 57.6(18) . . ?
F6 C4 F4 98(2) . . ?
F5' C4 F4 79(2) . . ?
F5 C4 F4 116(2) . . ?
F6' C4 F4 129(2) . . ?
F6 C4 F4' 77(2) . . ?
F5' C4 F4' 107(2) . . ?
F5 C4 F4' 140(2) . . ?
F6' C4 F4' 122(3) . . ?
F4 C4 F4' 28.1(19) . . ?
F6 C4 C3 109.7(19) . . ?
F5' C4 C3 111(2) . . ?
F5 C4 C3 110.0(19) . . ?
F6' C4 C3 112.4(19) . . ?
F4 C4 C3 116(2) . . ?
F4' C4 C3 106(2) . . ?
O6 C5 O5 126(2) . . ?
O6 C5 C6 122(2) . . ?
O5 C5 C6 112(2) . . ?
F9' C6 F7 132(3) . . ?
F9' C6 F7' 113(3) . . ?
F7 C6 F7' 65(2) . . ?
F9' C6 F9 77(3) . . ?
F7 C6 F9 100(3) . . ?
F7' C6 F9 39(2) . . ?
F9' C6 F8 34(2) . . ?
F7 C6 F8 112(3) . . ?
F7' C6 F8 137(3) . . ?
F9 C6 F8 108(3) . . ?
F9' C6 F8' 119(3) . . ?
F7 C6 F8' 44(2) . . ?
F7' C6 F8' 109(3) . . ?
F9 C6 F8' 143(3) . . ?
F8 C6 F8' 85(3) . . ?
F9' C6 C5 111(3) . . ?
F7 C6 C5 115(3) . . ?
F7' C6 C5 106(3) . . ?
F9 C6 C5 108(3) . . ?
F8 C6 C5 113(3) . . ?
F8' C6 C5 98(2) . . ?
O7 C7 O8 129.6(15) . . ?
O7 C7 C8 118.0(16) . . ?
O8 C7 C8 112.4(16) . . ?
F11' C8 F12 131(2) . . ?
F11' C8 F10' 116(2) . . ?
F12 C8 F10' 37.2(15) . . ?
F11' C8 F11 56.0(16) . . ?
F12 C8 F11 104.2(18) . . ?
F10' C8 F11 129(2) . . ?
F11' C8 F12' 105(2) . . ?
F12 C8 F12' 58.9(17) . . ?
F10' C8 F12' 95(2) . . ?
F11 C8 F12' 52.0(16) . . ?
F11' C8 F10 53.8(16) . . ?
F12 C8 F10 106.2(18) . . ?
F10' C8 F10 72.2(19) . . ?
F11 C8 F10 107.1(17) . . ?
F12' C8 F10 140(2) . . ?
F11' C8 C7 115.7(19) . . ?
F12 C8 C7 113.4(16) . . ?
F10' C8 C7 110.5(19) . . ?
F11 C8 C7 117.7(17) . . ?
F12' C8 C7 112.1(19) . . ?
F10 C8 C7 107.6(16) . . ?
O9 C9 O10 130.4(18) . . ?
O9 C9 C10 112.2(17) . . ?
O10 C9 C10 117.4(19) . . ?
F14' C10 F15' 115(3) . . ?
F14' C10 F13 68(2) . . ?
F15' C10 F13 127(3) . . ?
F14' C10 F13' 101(3) . . ?
F15' C10 F13' 103(3) . . ?
F13 C10 F13' 35.4(18) . . ?
F14' C10 F14 53.3(17) . . ?
F15' C10 F14 68(2) . . ?
F13 C10 F14 116(2) . . ?
F13' C10 F14 137(3) . . ?
F14' C10 F15 138(3) . . ?
F15' C10 F15 37.5(18) . . ?
F13 C10 F15 102(2) . . ?
F13' C10 F15 70(2) . . ?
F14 C10 F15 104(2) . . ?
F14' C10 C9 110(2) . . ?
F15' C10 C9 114(2) . . ?
F13 C10 C9 113(2) . . ?
F13' C10 C9 113(2) . . ?
F14 C10 C9 109.7(19) . . ?
F15 C10 C9 111(2) . . ?
C12 C11 Ag2 164.4(17) . . ?
C12 C11 Ag11 109.2(15) . . ?
Ag2 C11 Ag11 86.4(6) . . ?
C12 C11 Ag4 80.3(12) . . ?
Ag2 C11 Ag4 91.4(7) . . ?
Ag11 C11 Ag4 120.3(9) . . ?
C12 C11 Ag11 113.7(14) . . ?
Ag2 C11 Ag11 80.5(6) . . ?
Ag11 C11 Ag11 26.5(3) . . ?
Ag4 C11 Ag11 145.5(9) . . ?
C11 C12 C13 170(2) . . ?
C11 C12 Ag4 68.4(12) . . ?
C13 C12 Ag4 119.9(12) . . ?
C16 C13 C12 108.9(19) . . ?
C16 C13 C14 110(2) . . ?
C12 C13 C14 103.7(18) . . ?
C16 C13 C15 115(2) . . ?
C12 C13 C15 109.6(18) . . ?
C14 C13 C15 109(2) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C13 C16 H16A 109.5 . . ?
C13 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C13 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 Ag3 172.4(14) . 2 ?
C18 C17 Ag8 101.0(12) . 2 ?
Ag3 C17 Ag8 79.8(5) 2 2 ?
C18 C17 Ag10 90.7(11) . . ?
Ag3 C17 Ag10 87.2(6) 2 . ?
Ag8 C17 Ag10 164.4(7) 2 . ?
C17 C18 C19 175.6(16) . . ?
C17 C18 Ag10 61.0(10) . . ?
C19 C18 Ag10 120.3(10) . . ?
C18 C19 C21 109.8(16) . . ?
C18 C19 C22 110.7(15) . . ?
C21 C19 C22 108.0(17) . . ?
C18 C19 C20 109.2(16) . . ?
C21 C19 C20 107.3(17) . . ?
C22 C19 C20 111.7(17) . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C19 C21 H21A 109.5 . . ?
C19 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C19 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C19 C22 H22A 109.5 . . ?
C19 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C19 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C24 C23 Ag2 159.5(19) . . ?
C24 C23 Ag11 105.9(17) . 2 ?
Ag2 C23 Ag11 94.6(9) . 2 ?
C24 C23 Ag10 92.3(15) . . ?
Ag2 C23 Ag10 88.7(8) . . ?
Ag11 C23 Ag10 88.8(8) 2 . ?
C24 C23 Ag7 90.6(15) . . ?
Ag2 C23 Ag7 89.8(7) . . ?
Ag11 C23 Ag7 86.9(7) 2 . ?
Ag10 C23 Ag7 175.3(11) . . ?
C24 C23 Ag11 113.5(16) . 2 ?
Ag2 C23 Ag11 85.7(7) . 2 ?
Ag11 C23 Ag11 20.9(3) 2 2 ?
Ag10 C23 Ag11 107.4(8) . 2 ?
Ag7 C23 Ag11 68.1(5) . 2 ?
C23 C24 C25 178(2) . . ?
C23 C24 Ag10 60.8(13) . . ?
C25 C24 Ag10 118.2(12) . . ?
C23 C24 Ag7 62.9(13) . . ?
C25 C24 Ag7 118.2(12) . . ?
Ag10 C24 Ag7 123.6(8) . . ?
C24 C25 C27 108.1(16) . . ?
C24 C25 C28 107.6(17) . . ?
C27 C25 C28 111.4(17) . . ?
C24 C25 C26 107.5(17) . . ?
C27 C25 C26 110.6(18) . . ?
C28 C25 C26 111.4(17) . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C25 C27 H27A 109.5 . . ?
C25 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C25 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C25 C28 H28A 109.5 . . ?
C25 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C25 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C30 C29 Ag1 161.4(16) . . ?
C30 C29 Ag6 111.7(14) . . ?
Ag1 C29 Ag6 84.2(6) . . ?
C30 C29 Ag9 88.5(13) . 2_556 ?
Ag1 C29 Ag9 90.7(7) . 2_556 ?
Ag6 C29 Ag9 123.3(8) . 2_556 ?
C29 C30 C31 170(2) . . ?
C29 C30 Ag9 61.5(11) . 2_556 ?
C31 C30 Ag9 128.3(12) . 2_556 ?
C30 C31 C34 110.1(17) . . ?
C30 C31 C33 109.3(18) . . ?
C34 C31 C33 102.9(19) . . ?
C30 C31 C32 113.0(19) . . ?
C34 C31 C32 114.7(19) . . ?
C33 C31 C32 106(2) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C31 C34 H34A 109.5 . . ?
C31 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C31 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C36 C35 Ag1 129.4(17) . . ?
C36 C35 Ag5 146.1(18) . . ?
Ag1 C35 Ag5 84.3(7) . . ?
C36 C35 Ag9 95.4(15) . . ?
Ag1 C35 Ag9 84.8(7) . . ?
Ag5 C35 Ag9 90.2(7) . . ?
C36 C35 Ag8 96.6(15) . . ?
Ag1 C35 Ag8 87.1(7) . . ?
Ag5 C35 Ag8 80.1(6) . . ?
Ag9 C35 Ag8 168.0(10) . . ?
C35 C36 C37 175(2) . . ?
C35 C36 Ag9 58.1(12) . . ?
C37 C36 Ag9 126.8(12) . . ?
C36 C37 C40 108.3(16) . . ?
C36 C37 C38 106.8(16) . . ?
C40 C37 C38 107.0(16) . . ?
C36 C37 C39 112.5(16) . . ?
C40 C37 C39 104.9(17) . . ?
C38 C37 C39 117.0(18) . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C37 C39 H39A 109.5 . . ?
C37 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C37 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C37 C40 H40A 109.5 . . ?
C37 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C37 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C42 C41 Ag3 170.3(15) . . ?
C42 C41 Ag6 100.9(13) . . ?
Ag3 C41 Ag6 88.4(7) . . ?
C42 C41 Ag4 91.0(13) . . ?
Ag3 C41 Ag4 85.3(6) . . ?
Ag6 C41 Ag4 97.9(6) . . ?
C42 C41 Ag7 97.3(13) . . ?
Ag3 C41 Ag7 77.9(6) . . ?
Ag6 C41 Ag7 131.9(8) . . ?
Ag4 C41 Ag7 126.0(7) . . ?
C41 C42 C43 176.8(18) . . ?
C41 C42 Ag4 62.3(11) . . ?
C43 C42 Ag4 120.1(11) . . ?
C44 C43 C46 117(2) . . ?
C44 C43 C42 111(2) . . ?
C46 C43 C42 107.6(19) . . ?
C44 C43 C45 108(2) . . ?
C46 C43 C45 101(2) . . ?
C42 C43 C45 112.3(19) . . ?
C43 C44 H44A 109.5 . . ?
C43 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C43 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C43 C45 H45A 109.5 . . ?
C43 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C43 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C43 C46 H46A 109.5 . . ?
C43 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C43 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
O11 C47 H47A 109.5 . . ?
O11 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
O11 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C1 O1 Ag7 121.0(13) . . ?
C1 O2 Ag8 137.9(12) . . ?
C3 O3 Ag4 139.0(14) . . ?
C3 O4 Ag6 129.4(13) . . ?
C5 O5 Ag8 116.8(15) . . ?
C5 O6 Ag11 129.7(16) . 2 ?
C5 O6 Ag11 147.1(17) . 2 ?
Ag11 O6 Ag11 24.31(19) 2 2 ?
C7 O8 Ag10 119.1(11) . 2 ?
C7 O8 Ag4 111.0(11) . . ?
Ag10 O8 Ag4 115.2(5) 2 . ?
C9 O9 Ag5 129.0(12) . . ?
C9 O10 Ag10 146.2(14) . 2 ?
C47 O11 Ag9 130.1(13) . . ?

_diffrn_measured_fraction_theta_max 0.973
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.973
_refine_diff_density_max         1.596
_refine_diff_density_min         -0.899
_refine_diff_density_rms         0.200

_database_code_depnum_ccdc_archive 'CCDC 926484'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_926485

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C50 H75 Ag11 O8'
_chemical_formula_weight         1990.67

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.983(5)
_cell_length_b                   14.005(5)
_cell_length_c                   18.653(5)
_cell_angle_alpha                99.434(5)
_cell_angle_beta                 99.090(5)
_cell_angle_gamma                116.326(5)
_cell_volume                     3117.9(18)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    15420
_cell_measurement_theta_min      1.15
_cell_measurement_theta_max      24.80

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.22
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.120
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1912
_exptl_absorpt_coefficient_mu    3.415
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5072
_exptl_absorpt_correction_T_max  0.5204
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71069
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            15420
_diffrn_reflns_av_R_equivalents  0.0523
_diffrn_reflns_av_sigmaI/netI    0.1306
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.15
_diffrn_reflns_theta_max         24.80
_reflns_number_total             10520
_reflns_number_gt                5005
_reflns_threshold_expression     >2σ(I)

_computing_data_collection       'SMART (Bruker, 1997)'
_computing_cell_refinement       'SAINT (Bruker, 1999)'
_computing_data_reduction        SAINT
_computing_structure_solution    'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'SHELXTL-PLUS (Sheldrick, 1990)'
_computing_publication_material  SHELXL-97

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2σ(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0627P)²+11.8652P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10520
_refine_ls_number_parameters     404
_refine_ls_number_restraints     25
_refine_ls_R_factor_all          0.1556
_refine_ls_R_factor_gt           0.0639
_refine_ls_wR_factor_ref         0.1799
_refine_ls_wR_factor_gt          0.1314
_refine_ls_goodness_of_fit_ref   0.993
_refine_ls_restrained_S_all      0.992
_refine_ls_shift/su_max          0.117
_refine_ls_shift/su_mean         0.002

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.58015(10) -0.04026(10) 0.44761(7) 0.0462(3) Uani 1 1 d . . .
Ag2 Ag 0.44228(10) -0.04364(10) 0.30531(7) 0.0447(3) Uani 1 1 d . . .
Ag3 Ag 0.54015(10) -0.08013(10) 1.05300(7) 0.0470(4) Uani 1 1 d . . .
Ag4 Ag 0.45615(10) -0.05782(10) 0.80542(7) 0.0443(3) Uani 1 1 d . . .
Ag5 Ag 0.36457(11) -0.17727(11) 0.91357(7) 0.0544(4) Uani 1 1 d . . .
Ag6 Ag 0.32285(11) -0.13548(11) 0.41333(7) 0.0539(4) Uani 1 1 d . . .
Ag7 Ag 0.61360(14) -0.11400(13) 0.75009(8) 0.0686(5) Uani 1 1 d . . .
Ag8 Ag 0.66412(13) 0.02181(12) 0.94148(8) 0.0706(5) Uani 1 1 d . . .
Ag9 Ag 0.47835(13) -0.16406(12) 0.55886(8) 0.0699(5) Uani 1 1 d . . .
Ag10 Ag 0.35903(14) -0.19155(13) 0.14138(8) 0.0765(5) Uani 1 1 d . . .
Ag11 Ag 0.30865(13) -0.14099(14) 0.64129(8) 0.0758(5) Uani 1 1 d . . .
O1 O 0.2933(10) -0.2370(9) 0.2402(7) 0.070(4) Uani 1 1 d . . .
O2 O 0.1770(10) -0.2661(10) 0.3171(6) 0.075(4) Uani 1 1 d . . .
O3 O 0.3528(11) -0.3016(11) 0.6065(7) 0.081(4) Uani 1 1 d . . .
O4 O 0.5007(12) -0.3011(11) 0.6662(8) 0.088(4) Uani 1 1 d . . .
O5 O 0.2619(9) -0.2077(9) 0.7424(6) 0.065(3) Uani 1 1 d . . .
O6 O 0.2323(10) -0.3206(9) 0.8160(6) 0.072(4) Uani 1 1 d . . .
O7 O 0.8007(12) -0.0016(12) 0.8363(9) 0.103(5) Uani 1 1 d . . .
O8 O 0.8029(11) 0.1471(12) 0.8944(8) 0.092(4) Uani 1 1 d . . .
C1 C 0.1974(15) -0.2845(14) 0.2572(10) 0.050(4) Uiso 1 1 d . . .
C2 C 0.101(2) -0.384(2) 0.1963(14) 0.129(10) Uiso 1 1 d . . .
H2A H 0.1242 -0.3936 0.1509 0.194 Uiso 1 1 calc R . .
H2B H 0.0390 -0.3718 0.1864 0.194 Uiso 1 1 calc R . .
H2C H 0.0811 -0.4498 0.2137 0.194 Uiso 1 1 calc R . .
C3 C 0.4020(18) -0.3414(16) 0.6384(11) 0.060(5) Uiso 1 1 d . . .
C4 C 0.335(2) -0.459(2) 0.6499(15) 0.144(11) Uiso 1 1 d . . .
H4A H 0.3851 -0.4786 0.6764 0.216 Uiso 1 1 calc R . .
H4B H 0.2952 -0.5112 0.6018 0.216 Uiso 1 1 calc R . .
H4C H 0.2841 -0.4579 0.6786 0.216 Uiso 1 1 calc R . .
C5 C 0.2141(15) -0.3018(15) 0.7546(11) 0.058(5) Uiso 1 1 d . . .
C6 C 0.1156(19) -0.3919(19) 0.6930(13) 0.117(9) Uiso 1 1 d . . .
H6A H 0.1100 -0.3664 0.6486 0.175 Uiso 1 1 calc R . .
H6B H 0.0494 -0.4102 0.7095 0.175 Uiso 1 1 calc R . .
H6C H 0.1248 -0.4562 0.6819 0.175 Uiso 1 1 calc R . .
C7 C 0.8410(18) 0.0958(19) 0.8645(12) 0.070(6) Uiso 1 1 d . . .
C8 C 0.957(2) 0.168(2) 0.8522(17) 0.176(13) Uiso 1 1 d . . .
H8A H 0.9832 0.2444 0.8756 0.265 Uiso 1 1 calc R . .
H8B H 0.9518 0.1578 0.7992 0.265 Uiso 1 1 calc R . .
H8C H 1.0086 0.1458 0.8741 0.265 Uiso 1 1 calc R . .
C9 C 0.7039(13) 0.0481(12) 1.0692(8) 0.042(4) Uiso 1 1 d . . .
C10 C 0.8012(13) 0.0921(12) 1.0845(8) 0.043(4) Uiso 1 1 d . . .
C11 C 0.9244(16) 0.1519(16) 1.1108(11) 0.071(6) Uiso 1 1 d . . .
C12 C 0.3946(12) -0.2273(12) 1.0316(8) 0.042(4) Uiso 1 1 d . . .
C13 C 0.3275(13) -0.3219(13) 1.0159(9) 0.046(4) Uiso 1 1 d . . .
C14 C 0.2428(10) -0.4478(12) 0.9930(7) 0.059(5) Uiso 1 1 d D . .
C15 C 0.5304(13) -0.1422(12) 0.8544(9) 0.047(4) Uiso 1 1 d . . .
C16 C 0.5667(13) -0.2022(13) 0.8699(9) 0.050(4) Uiso 1 1 d . B .
C17 C 0.6116(11) -0.2812(12) 0.8863(7) 0.058(5) Uiso 1 1 d D . .
C18 C 0.2729(12) -0.1037(12) 0.5291(9) 0.055(5) Uiso 1 1 d D . .
C19 C 0.1711(12) -0.1756(12) 0.5140(9) 0.048(4) Uiso 1 1 d D . .
C20 C 0.0545(14) -0.2543(14) 0.4958(10) 0.058(5) Uiso 1 1 d . . .
C21 C 0.4557(13) -0.1986(13) 0.4278(9) 0.044(4) Uiso 1 1 d . . .
C22 C 0.4084(13) -0.2972(13) 0.4124(9) 0.045(4) Uiso 1 1 d . . .
C23 C 0.3519(18) -0.4204(17) 0.3864(12) 0.081(6) Uiso 1 1 d . . .
C24 C 0.3541(12) 0.0277(12) 0.3569(8) 0.039(4) Uiso 1 1 d . . .
C25 C 0.2977(13) 0.0700(12) 0.3670(8) 0.044(4) Uiso 1 1 d . . .
C26 C 0.2183(12) 0.1111(11) 0.3880(7) 0.064(5) Uiso 1 1 d D . .
C27 C 0.5603(13) -0.0611(12) 0.2512(9) 0.046(4) Uiso 1 1 d . . .
C28 C 0.6124(13) -0.1102(13) 0.2513(9) 0.047(4) Uiso 1 1 d . D .
C29 C 0.6766(12) -0.1739(11) 0.2486(7) 0.056(5) Uiso 1 1 d D . .
C30 C 0.972(2) 0.2649(18) 1.0942(13) 0.116(9) Uiso 1 1 d . . .
H30A H 1.0508 0.3019 1.1111 0.174 Uiso 1 1 calc R . .
H30B H 0.9441 0.3084 1.1200 0.174 Uiso 1 1 calc R . .
H30C H 0.9496 0.2555 1.0410 0.174 Uiso 1 1 calc R . .
C31 C 0.964(2) 0.083(2) 1.0682(15) 0.139(10) Uiso 1 1 d . . .
H31A H 1.0431 0.1187 1.0831 0.208 Uiso 1 1 calc R . .
H31B H 0.9389 0.0728 1.0152 0.208 Uiso 1 1 calc R . .
H31C H 0.9347 0.0119 1.0790 0.208 Uiso 1 1 calc R . .
C32 C 0.959(2) 0.171(2) 1.2037(14) 0.127(9) Uiso 1 1 d . . .
H32A H 1.0381 0.2095 1.2222 0.191 Uiso 1 1 calc R . .
H32B H 0.9300 0.1005 1.2150 0.191 Uiso 1 1 calc R . .
H32C H 0.9291 0.2135 1.2274 0.191 Uiso 1 1 calc R . .
C33 C 0.125(2) -0.465(5) 0.986(4) 0.080(5) Uiso 0.42(4) 1 d PD A 1
H33A H 0.1129 -0.4195 0.9564 0.119 Uiso 0.42(4) 1 calc PR A 1
H33B H 0.1158 -0.4453 1.0351 0.119 Uiso 0.42(4) 1 calc PR A 1
H33C H 0.0727 -0.5412 0.9618 0.119 Uiso 0.42(4) 1 calc PR A 1
C34 C 0.288(4) -0.509(4) 1.037(3) 0.080(5) Uiso 0.42(4) 1 d PD A 1
H34A H 0.3628 -0.4865 1.0353 0.119 Uiso 0.42(4) 1 calc PR A 1
H34B H 0.2434 -0.5871 1.0153 0.119 Uiso 0.42(4) 1 calc PR A 1
H34C H 0.2856 -0.4914 1.0887 0.119 Uiso 0.42(4) 1 calc PR A 1
C35 C 0.239(4) -0.495(4) 0.9117(14) 0.080(5) Uiso 0.42(4) 1 d PD A 1
H35A H 0.2107 -0.4627 0.8787 0.119 Uiso 0.42(4) 1 calc PR A 1
H35B H 0.1919 -0.5739 0.8973 0.119 Uiso 0.42(4) 1 calc PR A 1
H35C H 0.3123 -0.4790 0.9084 0.119 Uiso 0.42(4) 1 calc PR A 1
C33' C 0.129(2) -0.455(4) 0.969(3) 0.080(5) Uiso 0.58(4) 1 d PD A 2
H33D H 0.1227 -0.4325 0.9237 0.119 Uiso 0.58(4) 1 calc PR A 2
H33E H 0.1213 -0.4070 1.0084 0.119 Uiso 0.58(4) 1 calc PR A 2
H33F H 0.0722 -0.5295 0.9614 0.119 Uiso 0.58(4) 1 calc PR A 2
C34' C 0.258(3) -0.482(3) 1.0661(14) 0.080(5) Uiso 0.58(4) 1 d PD A 2
H34D H 0.3291 -0.4790 1.0782 0.119 Uiso 0.58(4) 1 calc PR A 2
H34E H 0.2012 -0.5565 1.0596 0.119 Uiso 0.58(4) 1 calc PR A 2
H34F H 0.2539 -0.4332 1.1063 0.119 Uiso 0.58(4) 1 calc PR A 2
C35' C 0.273(3) -0.508(3) 0.9319(19) 0.080(5) Uiso 0.58(4) 1 d PD A 2
H35D H 0.2624 -0.4862 0.8866 0.119 Uiso 0.58(4) 1 calc PR A 2
H35E H 0.2268 -0.5867 0.9221 0.119 Uiso 0.58(4) 1 calc PR A 2
H35F H 0.3491 -0.4903 0.9487 0.119 Uiso 0.58(4) 1 calc PR A 2
C36 C 0.526(3) -0.374(3) 0.912(3) 0.084(6) Uiso 0.408(18) 1 d PD B 1
H36A H 0.4952 -0.3438 0.9455 0.127 Uiso 0.408(18) 1 calc PR B 1
H36B H 0.5614 -0.4088 0.9376 0.127 Uiso 0.408(18) 1 calc PR B 1
H36C H 0.4684 -0.4278 0.8689 0.127 Uiso 0.408(18) 1 calc PR B 1
C37 C 0.703(3) -0.216(4) 0.9599(17) 0.084(6) Uiso 0.408(18) 1 d PD B 1
H37A H 0.7643 -0.1559 0.9509 0.127 Uiso 0.408(18) 1 calc PR B 1
H37B H 0.7279 -0.2641 0.9779 0.127 Uiso 0.408(18) 1 calc PR B 1
H37C H 0.6752 -0.1881 0.9970 0.127 Uiso 0.408(18) 1 calc PR B 1
C38 C 0.682(2) -0.288(3) 0.8323(16) 0.084(6) Uiso 0.592(18) 1 d PD B 1
H38A H 0.7276 -0.2161 0.8272 0.127 Uiso 0.592(18) 1 calc PR B 1
H38B H 0.6341 -0.3360 0.7839 0.127 Uiso 0.592(18) 1 calc PR B 1
H38C H 0.7275 -0.3179 0.8519 0.127 Uiso 0.592(18) 1 calc PR B 1
C36' C 0.523(2) -0.3998(14) 0.8433(19) 0.084(6) Uiso 0.592(18) 1 d PD B 2
H36D H 0.5114 -0.4068 0.7902 0.127 Uiso 0.592(18) 1 calc PR B 2
H36E H 0.4555 -0.4162 0.8571 0.127 Uiso 0.592(18) 1 calc PR B 2
H36F H 0.5480 -0.4505 0.8558 0.127 Uiso 0.592(18) 1 calc PR B 2
C37' C 0.625(3) -0.279(3) 0.9699(9) 0.084(6) Uiso 0.592(18) 1 d PD B 2
H37D H 0.5543 -0.3072 0.9805 0.127 Uiso 0.592(18) 1 calc PR B 2
H37E H 0.6727 -0.2050 1.0003 0.127 Uiso 0.592(18) 1 calc PR B 2
H37F H 0.6574 -0.3250 0.9811 0.127 Uiso 0.592(18) 1 calc PR B 2
C38' C 0.723(2) -0.238(4) 0.866(3) 0.084(6) Uiso 0.408(18) 1 d PD B 2
H38D H 0.7120 -0.2404 0.8139 0.127 Uiso 0.408(18) 1 calc PR B 2
H38E H 0.7561 -0.2829 0.8772 0.127 Uiso 0.408(18) 1 calc PR B 2
H38F H 0.7713 -0.1629 0.8958 0.127 Uiso 0.408(18) 1 calc PR B 2
C39 C 0.0393(17) -0.3719(16) 0.4795(12) 0.095(7) Uiso 1 1 d . . .
H39A H -0.0379 -0.4242 0.4678 0.142 Uiso 1 1 calc R . .
H39B H 0.0782 -0.3806 0.5230 0.142 Uiso 1 1 calc R . .
H39C H 0.0680 -0.3844 0.4376 0.142 Uiso 1 1 calc R . .
C40 C -0.005(2) -0.240(2) 0.4243(14) 0.134(10) Uiso 1 1 d . . .
H40A H -0.0825 -0.2916 0.4113 0.201 Uiso 1 1 calc R . .
H40B H 0.0255 -0.2527 0.3834 0.201 Uiso 1 1 calc R . .
H40C H 0.0051 -0.1660 0.4339 0.201 Uiso 1 1 calc R . .
C41 C 0.0088(18) -0.2359(18) 0.5633(12) 0.102(8) Uiso 1 1 d . . .
H41A H -0.0683 -0.2884 0.5515 0.153 Uiso 1 1 calc R . .
H41B H 0.0181 -0.1624 0.5743 0.153 Uiso 1 1 calc R . .
H41C H 0.0480 -0.2452 0.6064 0.153 Uiso 1 1 calc R . .
C42 C 0.2367(19) -0.4678(19) 0.4036(14) 0.118(9) Uiso 1 1 d . . .
H42A H 0.2458 -0.4417 0.4564 0.176 Uiso 1 1 calc R . .
H42B H 0.2014 -0.5471 0.3896 0.176 Uiso 1 1 calc R . .
H42C H 0.1918 -0.4440 0.3753 0.176 Uiso 1 1 calc R . .
C43 C 0.424(2) -0.463(2) 0.4254(17) 0.174(13) Uiso 1 1 d . . .
H43A H 0.4418 -0.4337 0.4790 0.261 Uiso 1 1 calc R . .
H43B H 0.4903 -0.4392 0.4091 0.261 Uiso 1 1 calc R . .
H43C H 0.3839 -0.5420 0.4129 0.261 Uiso 1 1 calc R . .
C44 C 0.326(2) -0.466(2) 0.3107(16) 0.151(11) Uiso 1 1 d . . .
H44A H 0.2900 -0.5449 0.3005 0.227 Uiso 1 1 calc R . .
H44B H 0.3924 -0.4405 0.2940 0.227 Uiso 1 1 calc R . .
H44C H 0.2774 -0.4439 0.2846 0.227 Uiso 1 1 calc R . .
C45 C 0.1108(18) 0.033(2) 0.3265(17) 0.079(5) Uiso 0.546(18) 1 d PD C 1
H45A H 0.1239 0.0380 0.2779 0.118 Uiso 0.546(18) 1 calc PR C 1
H45B H 0.0551 0.0534 0.3332 0.118 Uiso 0.546(18) 1 calc PR C 1
H45C H 0.0863 -0.0416 0.3299 0.118 Uiso 0.546(18) 1 calc PR C 1
C46 C 0.253(3) 0.213(2) 0.357(2) 0.079(5) Uiso 0.546(18) 1 d PD C 1
H46A H 0.2514 0.1929 0.3050 0.118 Uiso 0.546(18) 1 calc PR C 1
H46B H 0.3268 0.2684 0.3851 0.118 Uiso 0.546(18) 1 calc PR C 1
H46C H 0.2032 0.2423 0.3620 0.118 Uiso 0.546(18) 1 calc PR C 1
C47 C 0.207(3) 0.112(3) 0.4686(11) 0.079(5) Uiso 0.546(18) 1 d PD C 1
H47A H 0.1830 0.0396 0.4754 0.118 Uiso 0.546(18) 1 calc PR C 1
H47B H 0.1539 0.1358 0.4772 0.118 Uiso 0.546(18) 1 calc PR C 1
H47C H 0.2774 0.1627 0.5037 0.118 Uiso 0.546(18) 1 calc PR C 1
C45' C 0.1042(19) 0.015(2) 0.381(3) 0.079(5) Uiso 0.454(18) 1 d PD C 2
H45D H 0.0752 -0.0335 0.3311 0.118 Uiso 0.454(18) 1 calc PR C 2
H45E H 0.0550 0.0427 0.3914 0.118 Uiso 0.454(18) 1 calc PR C 2
H45F H 0.1110 -0.0260 0.4167 0.118 Uiso 0.454(18) 1 calc PR C 2
C46' C 0.202(4) 0.173(3) 0.331(2) 0.079(5) Uiso 0.454(18) 1 d PD C 2
H46D H 0.2712 0.2358 0.3344 0.118 Uiso 0.454(18) 1 calc PR C 2
H46E H 0.1500 0.1976 0.3410 0.118 Uiso 0.454(18) 1 calc PR C 2
H46F H 0.1737 0.1247 0.2808 0.118 Uiso 0.454(18) 1 calc PR C 2
C47' C 0.278(3) 0.199(3) 0.4639(14) 0.079(5) Uiso 0.454(18) 1 d PD C 2
H47D H 0.3477 0.2545 0.4609 0.118 Uiso 0.454(18) 1 calc PR C 2
H47E H 0.2898 0.1646 0.5025 0.118 Uiso 0.454(18) 1 calc PR C 2
H47F H 0.2332 0.2320 0.4757 0.118 Uiso 0.454(18) 1 calc PR C 2
C48 C 0.7809(19) -0.099(3) 0.3134(15) 0.082(5) Uiso 0.523(14) 1 d PD D 1
H48A H 0.8273 -0.1332 0.3177 0.123 Uiso 0.523(14) 1 calc PR D 1
H48B H 0.7602 -0.0892 0.3596 0.123 Uiso 0.523(14) 1 calc PR D 1
H48C H 0.8204 -0.0289 0.3035 0.123 Uiso 0.523(14) 1 calc PR D 1
C49 C 0.685(3) -0.210(3) 0.1688(11) 0.082(5) Uiso 0.523(14) 1 d PD D 1
H49A H 0.7265 -0.2495 0.1695 0.123 Uiso 0.523(14) 1 calc PR D 1
H49B H 0.7227 -0.1458 0.1511 0.123 Uiso 0.523(14) 1 calc PR D 1
H49C H 0.6127 -0.2568 0.1358 0.123 Uiso 0.523(14) 1 calc PR D 1
C50 C 0.616(3) -0.268(2) 0.284(2) 0.082(5) Uiso 0.523(14) 1 d PD D 1
H50A H 0.6520 -0.3125 0.2850 0.123 Uiso 0.523(14) 1 calc PR D 1
H50B H 0.5409 -0.3125 0.2549 0.123 Uiso 0.523(14) 1 calc PR D 1
H50C H 0.6182 -0.2371 0.3346 0.123 Uiso 0.523(14) 1 calc PR D 1
C49' C 0.770(3) -0.118(3) 0.212(2) 0.082(5) Uiso 0.477(14) 1 d PD D 2
H49D H 0.8121 -0.1571 0.2099 0.123 Uiso 0.477(14) 1 calc PR D 2
H49E H 0.8182 -0.0429 0.2409 0.123 Uiso 0.477(14) 1 calc PR D 2
H49F H 0.7398 -0.1192 0.1617 0.123 Uiso 0.477(14) 1 calc PR D 2
C48' C 0.706(4) -0.195(4) 0.3252(13) 0.082(5) Uiso 0.477(14) 1 d PD D 2
H48D H 0.7472 -0.2346 0.3219 0.123 Uiso 0.477(14) 1 calc PR D 2
H48E H 0.6399 -0.2373 0.3391 0.123 Uiso 0.477(14) 1 calc PR D 2
H48F H 0.7508 -0.1254 0.3626 0.123 Uiso 0.477(14) 1 calc PR D 2
C50' C 0.604(3) -0.2872(19) 0.1917(19) 0.082(5) Uiso 0.477(14) 1 d PD D 2
H50D H 0.6432 -0.3282 0.1897 0.123 Uiso 0.477(14) 1 calc PR D 2
H50E H 0.5840 -0.2772 0.1428 0.123 Uiso 0.477(14) 1 calc PR D 2
H50F H 0.5376 -0.3270 0.2070 0.123 Uiso 0.477(14) 1 calc PR D 2


_geom_special_details            
;
 All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell s.u.'s are taken
 into account individually in the estimation of s.u.'s in distances, angles
 and torsion angles; correlations between s.u.'s in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C21 2.046(15) . ?
Ag1 C18 2.057(14) 2_656 ?
Ag1 Ag6 2.9086(19) 2_656 ?
Ag1 Ag2 3.0042(19) . ?
Ag1 Ag9 3.043(2) . ?
Ag1 Ag6 3.142(2) . ?
Ag1 Ag11 3.210(2) 2_656 ?
Ag1 Ag9 3.321(2) 2_656 ?
Ag2 C24 2.145(15) . ?
Ag2 C27 2.146(16) . ?
Ag2 O1 2.503(11) . ?
Ag2 Ag4 2.8986(18) 2_656 ?
Ag2 Ag6 2.9173(19) . ?
Ag2 Ag7 2.928(2) 2_656 ?
Ag2 Ag10 3.107(2) . ?
Ag2 Ag11 3.143(2) 2_656 ?
Ag2 Ag9 3.154(2) 2_656 ?
Ag3 C12 2.075(15) . ?
Ag3 C9 2.125(16) . ?
Ag3 Ag5 2.9159(19) . ?
Ag3 Ag4 2.9841(18) 2_657 ?
Ag3 Ag8 3.048(2) . ?
Ag3 Ag5 3.146(2) 2_657 ?
Ag3 Ag10 3.198(2) 1_556 ?
Ag3 Ag8 3.312(2) 2_657 ?
Ag4 C15 2.109(16) . ?
Ag4 C27 2.186(16) 2_656 ?
Ag4 O5 2.509(11) . ?
Ag4 Ag2 2.8986(18) 2_656 ?
Ag4 Ag7 2.919(2) . ?
Ag4 Ag5 2.9207(19) . ?
Ag4 Ag3 2.9841(18) 2_657 ?
Ag4 Ag11 3.113(2) . ?
Ag4 Ag10 3.148(2) 2_656 ?
Ag4 Ag8 3.163(2) . ?
Ag5 O6 2.282(11) . ?
Ag5 C9 2.395(15) 2_657 ?
Ag5 C12 2.447(15) . ?
Ag5 C15 2.611(16) . ?
Ag5 Ag3 3.146(2) 2_657 ?
Ag5 Ag8 3.376(2) 2_657 ?
Ag6 O2 2.277(11) . ?
Ag6 C21 2.384(15) . ?
Ag6 C18 2.406(16) . ?
Ag6 C24 2.563(14) . ?
Ag6 Ag1 2.9086(18) 2_656 ?
Ag7 C15 2.419(15) . ?
Ag7 O4 2.452(14) . ?
Ag7 O7 2.469(15) . ?
Ag7 C24 2.499(14) 2_656 ?
Ag7 C25 2.703(15) 2_656 ?
Ag7 Ag2 2.928(2) 2_656 ?
Ag8 C9 2.287(15) . ?
Ag8 C15 2.328(15) . ?
Ag8 O8 2.374(14) . ?
Ag8 Ag10 3.142(2) 2_656 ?
Ag8 Ag3 3.312(2) 2_657 ?
Ag8 Ag5 3.376(2) 2_657 ?
Ag9 C24 2.343(15) 2_656 ?
Ag9 C21 2.353(15) . ?
Ag9 O3 2.374(13) . ?
Ag9 Ag11 3.126(2) . ?
Ag9 Ag2 3.154(2) 2_656 ?
Ag9 Ag1 3.321(2) 2_656 ?
Ag10 C12 2.213(15) 1_554 ?
Ag10 O1 2.247(13) . ?
Ag10 C13 2.562(15) 1_554 ?
Ag10 Ag8 3.142(2) 2_656 ?
Ag10 Ag4 3.148(2) 2_656 ?
Ag10 Ag3 3.198(2) 1_554 ?
Ag11 C18 2.272(17) . ?
Ag11 O5 2.299(11) . ?
Ag11 O3 2.596(14) . ?
Ag11 C19 2.631(16) . ?
Ag11 Ag2 3.143(2) 2_656 ?
Ag11 Ag1 3.210(2) 2_656 ?
O1 C1 1.323(19) . ?
O2 C1 1.212(18) . ?
O3 C3 1.21(2) . ?
O4 C3 1.22(2) . ?
O5 C5 1.264(19) . ?
O6 C5 1.23(2) . ?
O7 C7 1.20(2) . ?
O8 C7 1.19(2) . ?
C1 C2 1.54(3) . ?
C3 C4 1.56(3) . ?
C5 C6 1.51(3) . ?
C7 C8 1.57(3) . ?
C9 C10 1.178(19) . ?
C9 Ag5 2.395(15) 2_657 ?
C10 C11 1.49(2) . ?
C11 C31 1.50(3) . ?
C11 C30 1.53(3) . ?
C11 C32 1.67(3) . ?
C12 C13 1.184(18) . ?
C12 Ag10 2.213(15) 1_556 ?
C13 C14 1.56(2) . ?
C13 Ag10 2.562(15) 1_556 ?
C14 C34' 1.5350(11) . ?
C14 C34 1.5349(11) . ?
C14 C33 1.5350(12) . ?
C14 C33' 1.5350(12) . ?
C14 C35' 1.5351(11) . ?
C14 C35 1.5351(11) . ?
C15 C16 1.207(19) . ?
C16 C17 1.54(2) . ?
C17 C36 1.5350(11) . ?
C17 C37' 1.5350(11) . ?
C17 C38' 1.5350(12) . ?
C17 C38 1.5350(11) . ?
C17 C37 1.5351(12) . ?
C17 C36' 1.5351(11) . ?
C18 C19 1.276(9) . ?
C18 Ag1 2.057(14) 2_656 ?
C19 C20 1.45(2) . ?
C20 C39 1.53(2) . ?
C20 C41 1.53(2) . ?
C20 C40 1.55(3) . ?
C21 C22 1.195(18) . ?
C22 C23 1.49(2) . ?
C23 C44 1.37(3) . ?
C23 C43 1.52(3) . ?
C23 C42 1.56(3) . ?
C24 C25 1.197(18) . ?
C24 Ag9 2.343(14) 2_656 ?
C24 Ag7 2.499(14) 2_656 ?
C25 C26 1.53(2) . ?
C25 Ag7 2.703(15) 2_656 ?
C26 C45' 1.5350(11) . ?
C26 C47' 1.5350(11) . ?
C26 C46' 1.5350(11) . ?
C26 C47 1.5350(11) . ?
C26 C46 1.5351(11) . ?
C26 C45 1.5351(11) . ?
C27 C28 1.205(19) . ?
C27 Ag4 2.186(16) 2_656 ?
C28 C29 1.52(2) . ?
C29 C49 1.5349(11) . ?
C29 C48' 1.5350(11) . ?
C29 C50' 1.5350(11) . ?
C29 C48 1.5350(11) . ?
C29 C49' 1.5351(11) . ?
C29 C50 1.5351(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C21 Ag1 C18 167.6(6) . 2_656 ?
C21 Ag1 Ag6 127.9(4) . 2_656 ?
C18 Ag1 Ag6 54.8(5) 2_656 2_656 ?
C21 Ag1 Ag2 83.5(4) . . ?
C18 Ag1 Ag2 104.7(5) 2_656 . ?
Ag6 Ag1 Ag2 125.18(6) 2_656 . ?
C21 Ag1 Ag9 50.6(4) . . ?
C18 Ag1 Ag9 127.4(5) 2_656 . ?
Ag6 Ag1 Ag9 78.14(5) 2_656 . ?
Ag2 Ag1 Ag9 122.39(6) . . ?
C21 Ag1 Ag6 49.4(4) . . ?
C18 Ag1 Ag6 143.1(5) 2_656 . ?
Ag6 Ag1 Ag6 106.89(5) 2_656 . ?
Ag2 Ag1 Ag6 56.62(4) . . ?
Ag9 Ag1 Ag6 66.54(5) . . ?
C21 Ag1 Ag11 140.2(4) . 2_656 ?
C18 Ag1 Ag11 44.8(5) 2_656 2_656 ?
Ag6 Ag1 Ag11 89.15(6) 2_656 2_656 ?
Ag2 Ag1 Ag11 60.66(5) . 2_656 ?
Ag9 Ag1 Ag11 165.89(6) . 2_656 ?
Ag6 Ag1 Ag11 112.33(5) . 2_656 ?
C21 Ag1 Ag9 120.3(4) . 2_656 ?
C18 Ag1 Ag9 72.2(5) 2_656 2_656 ?
Ag6 Ag1 Ag9 65.64(5) 2_656 2_656 ?
Ag2 Ag1 Ag9 59.56(4) . 2_656 ?
Ag9 Ag1 Ag9 111.09(5) . 2_656 ?
Ag6 Ag1 Ag9 70.93(5) . 2_656 ?
Ag11 Ag1 Ag9 57.15(5) 2_656 2_656 ?
C24 Ag2 C27 161.3(6) . . ?
C24 Ag2 O1 102.4(5) . . ?
C27 Ag2 O1 93.3(5) . . ?
C24 Ag2 Ag4 115.5(4) . 2_656 ?
C27 Ag2 Ag4 48.6(4) . 2_656 ?
O1 Ag2 Ag4 108.7(3) . 2_656 ?
C24 Ag2 Ag6 58.5(4) . . ?
C27 Ag2 Ag6 137.8(4) . . ?
O1 Ag2 Ag6 71.6(3) . . ?
Ag4 Ag2 Ag6 173.44(6) 2_656 . ?
C24 Ag2 Ag7 56.5(4) . 2_656 ?
C27 Ag2 Ag7 108.7(4) . 2_656 ?
O1 Ag2 Ag7 110.0(3) . 2_656 ?
Ag4 Ag2 Ag7 60.12(5) 2_656 2_656 ?
Ag6 Ag2 Ag7 113.44(6) . 2_656 ?
C24 Ag2 Ag1 97.3(4) . . ?
C27 Ag2 Ag1 86.5(4) . . ?
O1 Ag2 Ag1 110.0(3) . . ?
Ag4 Ag2 Ag1 121.05(6) 2_656 . ?
Ag6 Ag2 Ag1 64.06(5) . . ?
Ag7 Ag2 Ag1 135.98(6) 2_656 . ?
C24 Ag2 Ag10 124.6(4) . . ?
C27 Ag2 Ag10 61.2(4) . . ?
O1 Ag2 Ag10 45.7(3) . . ?
Ag4 Ag2 Ag10 63.10(5) 2_656 . ?
Ag6 Ag2 Ag10 117.23(6) . . ?
Ag7 Ag2 Ag10 89.33(6) 2_656 . ?
Ag1 Ag2 Ag10 132.60(6) . . ?
C24 Ag2 Ag11 105.4(4) . 2_656 ?
C27 Ag2 Ag11 60.1(4) . 2_656 ?
O1 Ag2 Ag11 151.9(3) . 2_656 ?
Ag4 Ag2 Ag11 61.86(5) 2_656 2_656 ?
Ag6 Ag2 Ag11 121.00(6) . 2_656 ?
Ag7 Ag2 Ag11 88.67(6) 2_656 2_656 ?
Ag1 Ag2 Ag11 62.91(5) . 2_656 ?
Ag10 Ag2 Ag11 116.92(6) . 2_656 ?
C24 Ag2 Ag9 48.0(4) . 2_656 ?
C27 Ag2 Ag9 119.6(4) . 2_656 ?
O1 Ag2 Ag9 145.4(3) . 2_656 ?
Ag4 Ag2 Ag9 101.78(6) 2_656 2_656 ?
Ag6 Ag2 Ag9 76.25(5) . 2_656 ?
Ag7 Ag2 Ag9 71.52(6) 2_656 2_656 ?
Ag1 Ag2 Ag9 65.23(5) . 2_656 ?
Ag10 Ag2 Ag9 160.26(6) . 2_656 ?
Ag11 Ag2 Ag9 59.52(5) 2_656 2_656 ?
C12 Ag3 C9 167.7(6) . . ?
C12 Ag3 Ag5 55.7(4) . . ?
C9 Ag3 Ag5 125.8(4) . . ?
C12 Ag3 Ag4 103.8(4) . 2_657 ?
C9 Ag3 Ag4 85.0(4) . 2_657 ?
Ag5 Ag3 Ag4 125.32(6) . 2_657 ?
C12 Ag3 Ag8 128.5(4) . . ?
C9 Ag3 Ag8 48.6(4) . . ?
Ag5 Ag3 Ag8 77.90(5) . . ?
Ag4 Ag3 Ag8 122.07(6) 2_657 . ?
C12 Ag3 Ag5 142.6(4) . 2_657 ?
C9 Ag3 Ag5 49.5(4) . 2_657 ?
Ag5 Ag3 Ag5 106.48(5) . 2_657 ?
Ag4 Ag3 Ag5 56.83(4) 2_657 2_657 ?
Ag8 Ag3 Ag5 66.04(5) . 2_657 ?
C12 Ag3 Ag10 43.5(4) . 1_556 ?
C9 Ag3 Ag10 142.4(4) . 1_556 ?
Ag5 Ag3 Ag10 89.22(6) . 1_556 ?
Ag4 Ag3 Ag10 61.11(5) 2_657 1_556 ?
Ag8 Ag3 Ag10 165.77(6) . 1_556 ?
Ag5 Ag3 Ag10 112.89(5) 2_657 1_556 ?
C12 Ag3 Ag8 71.7(4) . 2_657 ?
C9 Ag3 Ag8 120.5(4) . 2_657 ?
Ag5 Ag3 Ag8 65.29(5) . 2_657 ?
Ag4 Ag3 Ag8 60.04(4) 2_657 2_657 ?
Ag8 Ag3 Ag8 110.48(5) . 2_657 ?
Ag5 Ag3 Ag8 70.95(5) 2_657 2_657 ?
Ag10 Ag3 Ag8 57.69(5) 1_556 2_657 ?
C15 Ag4 C27 159.0(6) . 2_656 ?
C15 Ag4 O5 103.1(5) . . ?
C27 Ag4 O5 93.9(5) 2_656 . ?
C15 Ag4 Ag2 113.9(4) . 2_656 ?
C27 Ag4 Ag2 47.4(4) 2_656 2_656 ?
O5 Ag4 Ag2 109.6(3) . 2_656 ?
C15 Ag4 Ag7 54.7(4) . . ?
C27 Ag4 Ag7 107.9(4) 2_656 . ?
O5 Ag4 Ag7 110.4(3) . . ?
Ag2 Ag4 Ag7 60.45(5) 2_656 . ?
C15 Ag4 Ag5 60.0(4) . . ?
C27 Ag4 Ag5 139.1(4) 2_656 . ?
O5 Ag4 Ag5 70.8(3) . . ?
Ag2 Ag4 Ag5 173.34(6) 2_656 . ?
Ag7 Ag4 Ag5 113.01(6) . . ?
C15 Ag4 Ag3 98.2(4) . 2_657 ?
C27 Ag4 Ag3 87.4(4) 2_656 2_657 ?
O5 Ag4 Ag3 109.5(3) . 2_657 ?
Ag2 Ag4 Ag3 120.75(6) 2_656 2_657 ?
Ag7 Ag4 Ag3 135.79(6) . 2_657 ?
Ag5 Ag4 Ag3 64.39(5) . 2_657 ?
C15 Ag4 Ag11 124.5(4) . . ?
C27 Ag4 Ag11 60.5(4) 2_656 . ?
O5 Ag4 Ag11 46.8(3) . . ?
Ag2 Ag4 Ag11 62.93(5) 2_656 . ?
Ag7 Ag4 Ag11 89.43(6) . . ?
Ag5 Ag4 Ag11 117.47(6) . . ?
Ag3 Ag4 Ag11 132.62(6) 2_657 . ?
C15 Ag4 Ag10 104.5(4) . 2_656 ?
C27 Ag4 Ag10 60.2(4) 2_656 2_656 ?
O5 Ag4 Ag10 152.2(3) . 2_656 ?
Ag2 Ag4 Ag10 61.69(5) 2_656 2_656 ?
Ag7 Ag4 Ag10 88.73(6) . 2_656 ?
Ag5 Ag4 Ag10 121.15(6) . 2_656 ?
Ag3 Ag4 Ag10 62.79(5) 2_657 2_656 ?
Ag11 Ag4 Ag10 116.63(6) . 2_656 ?
C15 Ag4 Ag8 47.4(4) . . ?
C27 Ag4 Ag8 119.9(4) 2_656 . ?
O5 Ag4 Ag8 144.5(3) . . ?
Ag2 Ag4 Ag8 101.94(6) 2_656 . ?
Ag7 Ag4 Ag8 71.44(6) . . ?
Ag5 Ag4 Ag8 76.00(5) . . ?
Ag3 Ag4 Ag8 65.13(5) 2_657 . ?
Ag11 Ag4 Ag8 160.25(6) . . ?
Ag10 Ag4 Ag8 59.72(5) 2_656 . ?
O6 Ag5 C9 104.3(5) . 2_657 ?
O6 Ag5 C12 114.3(5) . . ?
C9 Ag5 C12 108.9(5) 2_657 . ?
O6 Ag5 C15 96.5(5) . . ?
C9 Ag5 C15 122.1(5) 2_657 . ?
C12 Ag5 C15 110.3(5) . . ?
O6 Ag5 Ag3 153.9(3) . . ?
C9 Ag5 Ag3 98.4(4) 2_657 . ?
C12 Ag5 Ag3 44.5(4) . . ?
C15 Ag5 Ag3 81.9(3) . . ?
O6 Ag5 Ag4 89.4(3) . . ?
C9 Ag5 Ag4 82.0(4) 2_657 . ?
C12 Ag5 Ag4 149.2(4) . . ?
C15 Ag5 Ag4 44.4(4) . . ?
Ag3 Ag5 Ag4 106.56(6) . . ?
O6 Ag5 Ag3 132.4(3) . 2_657 ?
C9 Ag5 Ag3 42.5(4) 2_657 2_657 ?
C12 Ag5 Ag3 109.6(3) . 2_657 ?
C15 Ag5 Ag3 84.5(3) . 2_657 ?
Ag3 Ag5 Ag3 73.52(5) . 2_657 ?
Ag4 Ag5 Ag3 58.78(4) . 2_657 ?
O6 Ag5 Ag8 129.5(3) . 2_657 ?
C9 Ag5 Ag8 42.6(4) 2_657 2_657 ?
C12 Ag5 Ag8 67.1(3) . 2_657 ?
C15 Ag5 Ag8 131.9(3) . 2_657 ?
Ag3 Ag5 Ag8 63.03(5) . 2_657 ?
Ag4 Ag5 Ag8 113.68(6) . 2_657 ?
Ag3 Ag5 Ag8 55.58(4) 2_657 2_657 ?
O2 Ag6 C21 106.2(5) . . ?
O2 Ag6 C18 113.1(5) . . ?
C21 Ag6 C18 111.0(5) . . ?
O2 Ag6 C24 96.1(5) . . ?
C21 Ag6 C24 121.3(5) . . ?
C18 Ag6 C24 108.3(5) . . ?
O2 Ag6 Ag1 152.5(3) . 2_656 ?
C21 Ag6 Ag1 98.3(4) . 2_656 ?
C18 Ag6 Ag1 44.3(3) . 2_656 ?
C24 Ag6 Ag1 81.2(3) . 2_656 ?
O2 Ag6 Ag2 90.2(3) . . ?
C21 Ag6 Ag2 80.2(4) . . ?
C18 Ag6 Ag2 148.4(4) . . ?
C24 Ag6 Ag2 45.5(3) . . ?
Ag1 Ag6 Ag2 106.28(6) 2_656 . ?
O2 Ag6 Ag1 134.2(3) . . ?
C21 Ag6 Ag1 40.6(4) . . ?
C18 Ag6 Ag1 109.4(4) . . ?
C24 Ag6 Ag1 85.8(3) . . ?
Ag1 Ag6 Ag1 73.11(5) 2_656 . ?
Ag2 Ag6 Ag1 59.31(4) . . ?
C15 Ag7 O4 98.4(5) . . ?
C15 Ag7 O7 91.7(5) . . ?
O4 Ag7 O7 137.8(5) . . ?
C15 Ag7 C24 149.4(5) . 2_656 ?
O4 Ag7 C24 93.0(5) . 2_656 ?
O7 Ag7 C24 98.7(5) . 2_656 ?
C15 Ag7 C25 175.6(5) . 2_656 ?
O4 Ag7 C25 84.0(5) . 2_656 ?
O7 Ag7 C25 89.0(5) . 2_656 ?
C24 Ag7 C25 26.2(4) 2_656 2_656 ?
C15 Ag7 Ag4 45.4(4) . . ?
O4 Ag7 Ag4 105.0(3) . . ?
O7 Ag7 Ag4 111.0(4) . . ?
C24 Ag7 Ag4 104.3(3) 2_656 . ?
C25 Ag7 Ag4 130.4(3) 2_656 . ?
C15 Ag7 Ag2 103.8(4) . 2_656 ?
O4 Ag7 Ag2 111.5(4) . 2_656 ?
O7 Ag7 Ag2 105.5(4) . 2_656 ?
C24 Ag7 Ag2 45.7(3) 2_656 2_656 ?
C25 Ag7 Ag2 71.8(3) 2_656 2_656 ?
Ag4 Ag7 Ag2 59.43(4) . 2_656 ?
C9 Ag8 C15 124.9(5) . . ?
C9 Ag8 O8 116.2(5) . . ?
C15 Ag8 O8 116.0(5) . . ?
C9 Ag8 Ag3 44.1(4) . . ?
C15 Ag8 Ag3 83.8(4) . . ?
O8 Ag8 Ag3 160.0(4) . . ?
C9 Ag8 Ag10 124.8(4) . 2_656 ?
C15 Ag8 Ag10 99.4(4) . 2_656 ?
O8 Ag8 Ag10 54.6(4) . 2_656 ?
Ag3 Ag8 Ag10 128.14(7) . 2_656 ?
C9 Ag8 Ag4 138.5(4) . . ?
C15 Ag8 Ag4 41.8(4) . . ?
O8 Ag8 Ag4 99.3(3) . . ?
Ag3 Ag8 Ag4 97.74(6) . . ?
Ag10 Ag8 Ag4 59.90(5) 2_656 . ?
C9 Ag8 Ag3 90.3(4) . 2_657 ?
C15 Ag8 Ag3 85.4(4) . 2_657 ?
O8 Ag8 Ag3 112.6(4) . 2_657 ?
Ag3 Ag8 Ag3 69.52(5) . 2_657 ?
Ag10 Ag8 Ag3 59.32(5) 2_656 2_657 ?
Ag4 Ag8 Ag3 54.82(4) . 2_657 ?
C9 Ag8 Ag5 45.1(4) . 2_657 ?
C15 Ag8 Ag5 129.1(4) . 2_657 ?
O8 Ag8 Ag5 106.2(4) . 2_657 ?
Ag3 Ag8 Ag5 58.38(5) . 2_657 ?
Ag10 Ag8 Ag5 82.41(6) 2_656 2_657 ?
Ag4 Ag8 Ag5 106.50(6) . 2_657 ?
Ag3 Ag8 Ag5 51.68(4) 2_657 2_657 ?
C24 Ag9 C21 121.2(5) 2_656 . ?
C24 Ag9 O3 117.7(5) 2_656 . ?
C21 Ag9 O3 118.5(5) . . ?
C24 Ag9 Ag1 82.0(4) 2_656 . ?
C21 Ag9 Ag1 42.2(4) . . ?
O3 Ag9 Ag1 160.2(3) . . ?
C24 Ag9 Ag11 101.0(4) 2_656 . ?
C21 Ag9 Ag11 124.9(4) . . ?
O3 Ag9 Ag11 54.3(3) . . ?
Ag1 Ag9 Ag11 127.86(7) . . ?
C24 Ag9 Ag2 42.8(4) 2_656 2_656 ?
C21 Ag9 Ag2 136.5(4) . 2_656 ?
O3 Ag9 Ag2 98.9(3) . 2_656 ?
Ag1 Ag9 Ag2 97.54(6) . 2_656 ?
Ag11 Ag9 Ag2 60.08(5) . 2_656 ?
C24 Ag9 Ag1 85.4(4) 2_656 2_656 ?
C21 Ag9 Ag1 88.4(4) . 2_656 ?
O3 Ag9 Ag1 112.6(3) . 2_656 ?
Ag1 Ag9 Ag1 68.91(5) . 2_656 ?
Ag11 Ag9 Ag1 59.64(5) . 2_656 ?
Ag2 Ag9 Ag1 55.22(4) 2_656 2_656 ?
C12 Ag10 O1 154.3(5) 1_554 . ?
C12 Ag10 C13 27.5(5) 1_554 1_554 ?
O1 Ag10 C13 127.7(5) . 1_554 ?
C12 Ag10 Ag2 148.1(4) 1_554 . ?
O1 Ag10 Ag2 52.8(3) . . ?
C13 Ag10 Ag2 166.8(4) 1_554 . ?
C12 Ag10 Ag8 74.1(4) 1_554 2_656 ?
O1 Ag10 Ag8 126.5(3) . 2_656 ?
C13 Ag10 Ag8 91.1(3) 1_554 2_656 ?
Ag2 Ag10 Ag8 97.85(6) . 2_656 ?
C12 Ag10 Ag4 95.6(4) 1_554 2_656 ?
O1 Ag10 Ag4 107.9(3) . 2_656 ?
C13 Ag10 Ag4 123.1(3) 1_554 2_656 ?
Ag2 Ag10 Ag4 55.21(4) . 2_656 ?
Ag8 Ag10 Ag4 60.38(5) 2_656 2_656 ?
C12 Ag10 Ag3 40.2(4) 1_554 1_554 ?
O1 Ag10 Ag3 157.3(3) . 1_554 ?
C13 Ag10 Ag3 67.2(3) 1_554 1_554 ?
Ag2 Ag10 Ag3 108.39(6) . 1_554 ?
Ag8 Ag10 Ag3 62.99(5) 2_656 1_554 ?
Ag4 Ag10 Ag3 56.10(4) 2_656 1_554 ?
C18 Ag11 O5 154.5(5) . . ?
C18 Ag11 O3 103.0(5) . . ?
O5 Ag11 O3 86.0(4) . . ?
C18 Ag11 C19 29.0(3) . . ?
O5 Ag11 C19 126.4(4) . . ?
O3 Ag11 C19 100.4(4) . . ?
C18 Ag11 Ag4 147.9(4) . . ?
O5 Ag11 Ag4 52.7(3) . . ?
O3 Ag11 Ag4 93.1(3) . . ?
C19 Ag11 Ag4 166.4(3) . . ?
C18 Ag11 Ag9 74.3(4) . . ?
O5 Ag11 Ag9 126.4(3) . . ?
O3 Ag11 Ag9 47.9(3) . . ?
C19 Ag11 Ag9 92.4(3) . . ?
Ag4 Ag11 Ag9 97.75(6) . . ?
C18 Ag11 Ag2 95.4(4) . 2_656 ?
O5 Ag11 Ag2 107.8(3) . 2_656 ?
O3 Ag11 Ag2 94.5(3) . 2_656 ?
C19 Ag11 Ag2 124.4(3) . 2_656 ?
Ag4 Ag11 Ag2 55.20(4) . 2_656 ?
Ag9 Ag11 Ag2 60.40(5) . 2_656 ?
C18 Ag11 Ag1 39.6(4) . 2_656 ?
O5 Ag11 Ag1 157.3(3) . 2_656 ?
O3 Ag11 Ag1 109.9(3) . 2_656 ?
C19 Ag11 Ag1 68.1(3) . 2_656 ?
Ag4 Ag11 Ag1 108.72(6) . 2_656 ?
Ag9 Ag11 Ag1 63.21(5) . 2_656 ?
Ag2 Ag11 Ag1 56.43(4) 2_656 2_656 ?
C1 O1 Ag10 139.5(11) . . ?
C1 O1 Ag2 123.7(10) . . ?
Ag10 O1 Ag2 81.5(4) . . ?
C1 O2 Ag6 115.8(12) . . ?
C3 O3 Ag9 108.0(13) . . ?
C3 O3 Ag11 137.3(13) . . ?
Ag9 O3 Ag11 77.8(4) . . ?
C3 O4 Ag7 123.2(13) . . ?
C5 O5 Ag11 136.3(11) . . ?
C5 O5 Ag4 126.8(12) . . ?
Ag11 O5 Ag4 80.6(3) . . ?
C5 O6 Ag5 117.8(12) . . ?
C7 O7 Ag7 123.4(15) . . ?
C7 O8 Ag8 105.8(14) . . ?
O2 C1 O1 128.3(16) . . ?
O2 C1 C2 114.6(18) . . ?
O1 C1 C2 116.7(17) . . ?
O3 C3 O4 129(2) . . ?
O3 C3 C4 119(2) . . ?
O4 C3 C4 112(2) . . ?
O6 C5 O5 124.3(17) . . ?
O6 C5 C6 117.8(18) . . ?
O5 C5 C6 117.0(18) . . ?
O8 C7 O7 130(2) . . ?
O8 C7 C8 115(2) . . ?
O7 C7 C8 115(2) . . ?
C10 C9 Ag3 157.7(14) . . ?
C10 C9 Ag8 100.6(12) . . ?
Ag3 C9 Ag8 87.3(6) . . ?
C10 C9 Ag5 112.2(12) . 2_657 ?
Ag3 C9 Ag5 88.0(6) . 2_657 ?
Ag8 C9 Ag5 92.3(5) . 2_657 ?
C9 C10 C11 175.0(18) . . ?
C10 C11 C31 106.8(17) . . ?
C10 C11 C30 110.7(17) . . ?
C31 C11 C30 109.4(19) . . ?
C10 C11 C32 107.7(16) . . ?
C31 C11 C32 113.7(19) . . ?
C30 C11 C32 108.5(17) . . ?
C13 C12 Ag3 164.1(14) . . ?
C13 C12 Ag10 92.9(12) . 1_556 ?
Ag3 C12 Ag10 96.4(6) . 1_556 ?
C13 C12 Ag5 102.7(12) . . ?
Ag3 C12 Ag5 79.9(5) . . ?
Ag10 C12 Ag5 134.5(7) 1_556 . ?
C12 C13 C14 177.2(17) . . ?
C12 C13 Ag10 59.6(10) . 1_556 ?
C14 C13 Ag10 122.8(9) . 1_556 ?
C34' C14 C34 33(2) . . ?
C34' C14 C33 98(3) . . ?
C34 C14 C33 122(3) . . ?
C34' C14 C33' 112(2) . . ?
C34 C14 C33' 135(3) . . ?
C33 C14 C33' 14(4) . . ?
C34' C14 C35' 111(2) . . ?
C34 C14 C35' 79(2) . . ?
C33 C14 C35' 123(3) . . ?
C33' C14 C35' 115(3) . . ?
C34' C14 C35 133(3) . . ?
C34 C14 C35 103(3) . . ?
C33 C14 C35 103(3) . . ?
C33' C14 C35 93(3) . . ?
C35' C14 C35 25(2) . . ?
C34' C14 C13 103.5(17) . . ?
C34 C14 C13 110(2) . . ?
C33 C14 C13 110(3) . . ?
C33' C14 C13 105(2) . . ?
C35' C14 C13 109.3(18) . . ?
C35 C14 C13 108(2) . . ?
C16 C15 Ag4 168.7(14) . . ?
C16 C15 Ag8 98.8(12) . . ?
Ag4 C15 Ag8 90.8(6) . . ?
C16 C15 Ag7 92.8(11) . . ?
Ag4 C15 Ag7 79.9(5) . . ?
Ag8 C15 Ag7 97.0(6) . . ?
C16 C15 Ag5 108.6(12) . . ?
Ag4 C15 Ag5 75.6(5) . . ?
Ag8 C15 Ag5 98.7(5) . . ?
Ag7 C15 Ag5 151.0(7) . . ?
C15 C16 C17 177.7(17) . . ?
C36 C17 C37' 59(2) . . ?
C36 C17 C38' 145(3) . . ?
C37' C17 C38' 111(3) . . ?
C36 C17 C38 129(3) . . ?
C37' C17 C38 132(2) . . ?
C38' C17 C38 30(2) . . ?
C36 C17 C37 101(3) . . ?
C37' C17 C37 43.1(19) . . ?
C38' C17 C37 72(3) . . ?
C38 C17 C37 100(3) . . ?
C36 C17 C36' 49(2) . . ?
C37' C17 C36' 105(2) . . ?
C38' C17 C36' 117(3) . . ?
C38 C17 C36' 88(2) . . ?
C37 C17 C36' 141(3) . . ?
C36 C17 C16 109(2) . . ?
C37' C17 C16 109.1(17) . . ?
C38' C17 C16 106(2) . . ?
C38 C17 C16 109.9(17) . . ?
C37 C17 C16 105(2) . . ?
C36' C17 C16 108.5(16) . . ?
C19 C18 Ag1 164.8(14) . 2_656 ?
C19 C18 Ag11 91.3(11) . . ?
Ag1 C18 Ag11 95.6(6) 2_656 . ?
C19 C18 Ag6 104.0(12) . . ?
Ag1 C18 Ag6 80.9(5) 2_656 . ?
Ag11 C18 Ag6 133.6(7) . . ?
C18 C19 C20 177.8(18) . . ?
C18 C19 Ag11 59.7(10) . . ?
C20 C19 Ag11 122.0(11) . . ?
C19 C20 C39 109.3(15) . . ?
C19 C20 C41 109.3(15) . . ?
C39 C20 C41 108.6(16) . . ?
C19 C20 C40 108.4(16) . . ?
C39 C20 C40 109.0(17) . . ?
C41 C20 C40 112.1(17) . . ?
C22 C21 Ag1 160.0(14) . . ?
C22 C21 Ag9 98.2(12) . . ?
Ag1 C21 Ag9 87.2(6) . . ?
C22 C21 Ag6 109.0(12) . . ?
Ag1 C21 Ag6 90.0(6) . . ?
Ag9 C21 Ag6 91.5(5) . . ?
C21 C22 C23 174.8(18) . . ?
C44 C23 C22 117(2) . . ?
C44 C23 C43 107(2) . . ?
C22 C23 C43 110(2) . . ?
C44 C23 C42 103(2) . . ?
C22 C23 C42 108.9(17) . . ?
C43 C23 C42 112(2) . . ?
C25 C24 Ag2 162.7(13) . . ?
C25 C24 Ag9 99.3(11) . 2_656 ?
Ag2 C24 Ag9 89.2(5) . 2_656 ?
C25 C24 Ag7 86.5(11) . 2_656 ?
Ag2 C24 Ag7 77.8(5) . 2_656 ?
Ag9 C24 Ag7 94.6(5) 2_656 2_656 ?
C25 C24 Ag6 116.9(12) . . ?
Ag2 C24 Ag6 76.0(4) . . ?
Ag9 C24 Ag6 99.7(5) 2_656 . ?
Ag7 C24 Ag6 149.8(6) 2_656 . ?
C24 C25 C26 170.5(16) . . ?
C24 C25 Ag7 67.3(10) . 2_656 ?
C26 C25 Ag7 121.9(9) . 2_656 ?
C45' C26 C47' 117(2) . . ?
C45' C26 C46' 107(3) . . ?
C47' C26 C46' 105(2) . . ?
C45' C26 C47 74(2) . . ?
C47' C26 C47 46.2(18) . . ?
C46' C26 C47 135(3) . . ?
C45' C26 C46 132(2) . . ?
C47' C26 C46 83(2) . . ?
C46' C26 C46 27(2) . . ?
C47 C26 C46 124(2) . . ?
C45' C26 C45 41.9(18) . . ?
C47' C26 C45 149(2) . . ?
C46' C26 C45 71(2) . . ?
C47 C26 C45 114(2) . . ?
C46 C26 C45 98(2) . . ?
C45' C26 C25 111.5(19) . . ?
C47' C26 C25 107.7(19) . . ?
C46' C26 C25 107(2) . . ?
C47 C26 C25 113.9(17) . . ?
C46 C26 C25 101.4(18) . . ?
C45 C26 C25 102.4(16) . . ?
C28 C27 Ag2 139.1(14) . . ?
C28 C27 Ag4 136.9(13) . 2_656 ?
Ag2 C27 Ag4 84.0(6) . 2_656 ?
C27 C28 C29 178.0(17) . . ?
C28 C29 C49 112.0(17) . . ?
C28 C29 C48' 111.4(19) . . ?
C49 C29 C48' 136(2) . . ?
C28 C29 C50' 108.8(19) . . ?
C49 C29 C50' 53.0(19) . . ?
C48' C29 C50' 107(2) . . ?
C28 C29 C48 102.5(17) . . ?
C49 C29 C48 121(2) . . ?
C48' C29 C48 52.6(19) . . ?
C50' C29 C48 148(2) . . ?
C28 C29 C49' 108.4(19) . . ?
C49 C29 C49' 50.5(18) . . ?
C48' C29 C49' 118(2) . . ?
C50' C29 C49' 102(2) . . ?
C48 C29 C49' 74(2) . . ?
C28 C29 C50 103.8(17) . . ?
C49 C29 C50 116(2) . . ?
C48' C29 C50 47.3(19) . . ?
C50' C29 C50 66(2) . . ?
C48 C29 C50 100(2) . . ?
C49' C29 C50 148(2) . . ?

_diffrn_measured_fraction_theta_max 0.977
_diffrn_reflns_theta_full        24.80
_diffrn_measured_fraction_theta_full 0.977
_refine_diff_density_max         1.085
_refine_diff_density_min         -1.074
_refine_diff_density_rms         0.217

_database_code_depnum_ccdc_archive 'CCDC 926485'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_926482

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C52 H65 Ag12 F15 O11'
_chemical_formula_weight         2445.48

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P21

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   11.490(5)
_cell_length_b                   23.129(5)
_cell_length_c                   14.609(5)
_cell_angle_alpha                90.000(5)
_cell_angle_beta                 106.035(5)
_cell_angle_gamma                90.000(5)
_cell_volume                     3731(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    18864
_cell_measurement_theta_min      1.70
_cell_measurement_theta_max      25.00

_exptl_crystal_description       rectangle
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.22
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.177
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2328
_exptl_absorpt_coefficient_mu    3.156
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5180
_exptl_absorpt_correction_T_max  0.5435
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71069
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            18864
_diffrn_reflns_av_R_equivalents  0.0385
_diffrn_reflns_av_sigmaI/netI    0.0628
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         1.70
_diffrn_reflns_theta_max         25.00
_reflns_number_total             9684
_reflns_number_gt                6599
_reflns_threshold_expression     >2σ(I)

_computing_data_collection       'SMART (Bruker, 1997)'
_computing_cell_refinement       'SAINT (Bruker, 1999)'
_computing_data_reduction        SAINT
_computing_structure_solution    'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'SHELXTL-PLUS (Sheldrick, 1990)'
_computing_publication_material  SHELXL-97

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2σ(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0936P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.36(9)
_refine_ls_number_reflns         9684
_refine_ls_number_parameters     470
_refine_ls_number_restraints     63
_refine_ls_R_factor_all          0.0943
_refine_ls_R_factor_gt           0.0607
_refine_ls_wR_factor_ref         0.1663
_refine_ls_wR_factor_gt          0.1453
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_restrained_S_all      1.033
_refine_ls_shift/su_max          0.054
_refine_ls_shift/su_mean         0.003

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag -0.02387(11) 0.2166(2) 0.75386(8) 0.0577(3) Uani 1 1 d . . .
Ag2 Ag 0.50295(11) 0.2206(2) 0.76783(11) 0.0683(4) Uani 1 1 d . . .
Ag3 Ag 0.34566(11) 0.3166(2) 0.77833(10) 0.0632(4) Uani 1 1 d . . .
Ag4 Ag -0.08472(14) 0.3063(2) 0.60655(13) 0.0881(5) Uani 1 1 d . . .
Ag5 Ag 0.19600(13) 0.2586(2) 0.88515(10) 0.0772(4) Uani 1 1 d . . .
Ag6 Ag 0.44543(16) 0.3227(2) 0.62409(11) 0.0817(5) Uani 1 1 d . . .
Ag7 Ag 0.16414(12) 0.2406(2) 0.63595(11) 0.0798(5) Uani 1 1 d . . .
Ag8 Ag 0.78993(15) 0.3487(2) 0.77575(10) 0.0754(4) Uani 1 1 d . . .
Ag9 Ag 0.68189(13) 0.2553(2) 0.66341(9) 0.0705(4) Uani 1 1 d . . .
Ag10 Ag -0.02332(14) 0.3016(2) 0.94360(13) 0.0911(5) Uani 1 1 d . . .
Ag11 Ag -0.20397(14) 0.2123(2) 0.86072(11) 0.1038(7) Uani 1 1 d . . .
Ag12 Ag 0.60509(14) 0.3489(2) 0.87369(15) 0.1070(7) Uani 1 1 d . . .
C1 C 0.1172(19) 0.3646(8) 0.5297(14) 0.079(5) Uiso 1 1 d D A .
C2 C 0.1558(17) 0.4132(9) 0.4745(14) 0.137(5) Uiso 1 1 d D . .
C3 C 0.393(2) 0.2166(11) 0.5052(15) 0.092(6) Uiso 1 1 d D A .
C4 C 0.404(2) 0.1727(11) 0.4307(17) 0.137(5) Uiso 1 1 d D . .
C5 C 0.244(2) 0.3263(11) 1.0799(16) 0.099(7) Uiso 1 1 d D C .
C6 C 0.331(2) 0.3517(12) 1.1688(16) 0.137(5) Uiso 1 1 d D . .
C7 C 0.1107(18) 0.3896(8) 0.7942(14) 0.077(5) Uiso 1 1 d D D .
C8 C 0.059(2) 0.4504(8) 0.7874(19) 0.137(5) Uiso 1 1 d D . .
C9 C 0.655(2) 0.2143(12) 1.0059(15) 0.097(7) Uiso 1 1 d D E .
C10 C 0.612(2) 0.2021(12) 1.0937(16) 0.154(12) Uiso 1 1 d D . .
C11 C 0.810(2) 0.3534(11) 0.9131(11) 0.090(6) Uiso 1 1 d D . .
C12 C 0.8291(16) 0.3732(9) 1.0165(11) 0.070(5) Uiso 1 1 d D . .
C13 C 0.8517(12) 0.3902(6) 1.1075(11) 0.057(4) Uiso 1 1 d D . .
C14 C 0.734(2) 0.4150(15) 1.121(2) 0.156(5) Uiso 1 1 d D . .
H14A H 0.7470 0.4270 1.1863 0.234 Uiso 1 1 calc R . .
H14B H 0.6718 0.3860 1.1061 0.234 Uiso 1 1 calc R . .
H14C H 0.7090 0.4477 1.0800 0.234 Uiso 1 1 calc R . .
C15 C 0.897(3) 0.3392(11) 1.175(2) 0.156(5) Uiso 1 1 d D . .
H15A H 0.9140 0.3522 1.2399 0.234 Uiso 1 1 calc R . .
H15B H 0.9694 0.3237 1.1642 0.234 Uiso 1 1 calc R . .
H15C H 0.8359 0.3097 1.1639 0.234 Uiso 1 1 calc R . .
C16 C 0.952(2) 0.4361(12) 1.123(2) 0.156(5) Uiso 1 1 d D . .
H16A H 0.9733 0.4485 1.1886 0.234 Uiso 1 1 calc R . .
H16B H 0.9228 0.4687 1.0825 0.234 Uiso 1 1 calc R . .
H16C H 1.0214 0.4200 1.1087 0.234 Uiso 1 1 calc R . .
C17 C 0.7358(17) 0.3353(8) 0.6354(11) 0.072(5) Uiso 1 1 d D . .
C18 C 0.7084(18) 0.3658(9) 0.5385(11) 0.080(6) Uiso 1 1 d D . .
C19 C 0.6657(15) 0.3834(7) 0.4504(14) 0.085(6) Uiso 1 1 d D . .
C20 C 0.5324(17) 0.4020(16) 0.426(2) 0.157(5) Uiso 1 1 d D . .
H20A H 0.5077 0.4165 0.3617 0.236 Uiso 1 1 calc R . .
H20B H 0.5229 0.4318 0.4688 0.236 Uiso 1 1 calc R . .
H20C H 0.4831 0.3694 0.4312 0.236 Uiso 1 1 calc R . .
C21 C 0.686(3) 0.3375(12) 0.380(2) 0.157(5) Uiso 1 1 d D . .
H21A H 0.6586 0.3522 0.3167 0.236 Uiso 1 1 calc R . .
H21B H 0.6404 0.3033 0.3858 0.236 Uiso 1 1 calc R . .
H21C H 0.7701 0.3281 0.3953 0.236 Uiso 1 1 calc R . .
C22 C 0.739(3) 0.4387(10) 0.449(2) 0.157(5) Uiso 1 1 d D . .
H22A H 0.7160 0.4550 0.3860 0.236 Uiso 1 1 calc R . .
H22B H 0.8239 0.4295 0.4663 0.236 Uiso 1 1 calc R . .
H22C H 0.7235 0.4661 0.4933 0.236 Uiso 1 1 calc R . .
C23 C 0.4590(19) 0.3738(7) 0.7363(15) 0.083(6) Uiso 1 1 d D . .
C24 C 0.4972(17) 0.4374(7) 0.7528(14) 0.080(6) Uiso 1 1 d D . .
C25 C 0.5171(16) 0.4896(10) 0.7518(13) 0.103(7) Uiso 1 1 d D . .
C26 C 0.536(3) 0.5138(17) 0.8527(16) 0.166(6) Uiso 1 1 d D . .
H26A H 0.5547 0.5543 0.8532 0.249 Uiso 1 1 calc R . .
H26B H 0.6017 0.4937 0.8960 0.249 Uiso 1 1 calc R . .
H26C H 0.4634 0.5085 0.8721 0.249 Uiso 1 1 calc R . .
C27 C 0.422(3) 0.5298(14) 0.689(2) 0.166(6) Uiso 1 1 d D . .
H27A H 0.4517 0.5687 0.6946 0.249 Uiso 1 1 calc R . .
H27B H 0.3487 0.5281 0.7087 0.249 Uiso 1 1 calc R . .
H27C H 0.4045 0.5176 0.6236 0.249 Uiso 1 1 calc R . .
C28 C 0.639(2) 0.5032(18) 0.732(2) 0.166(6) Uiso 1 1 d D . .
H28A H 0.6553 0.5438 0.7406 0.249 Uiso 1 1 calc R . .
H28B H 0.6357 0.4922 0.6684 0.249 Uiso 1 1 calc R . .
H28C H 0.7022 0.4819 0.7762 0.249 Uiso 1 1 calc R . .
C29 C 0.3065(15) 0.2307(5) 0.7876(12) 0.063(4) Uiso 1 1 d D . .
C30 C 0.3026(17) 0.1644(5) 0.7835(13) 0.070(5) Uiso 1 1 d D . .
C31 C 0.3039(13) 0.1094(8) 0.7867(11) 0.069(5) Uiso 1 1 d D . .
C32 C 0.1791(19) 0.0903(17) 0.795(2) 0.166(6) Uiso 1 1 d D . .
H32A H 0.1749 0.0489 0.7943 0.249 Uiso 1 1 calc R . .
H32B H 0.1172 0.1054 0.7417 0.249 Uiso 1 1 calc R . .
H32C H 0.1671 0.1048 0.8530 0.249 Uiso 1 1 calc R . .
C33 C 0.326(3) 0.0890(17) 0.6930(16) 0.166(6) Uiso 1 1 d D . .
H33A H 0.3251 0.0476 0.6907 0.249 Uiso 1 1 calc R . .
H33B H 0.4037 0.1028 0.6894 0.249 Uiso 1 1 calc R . .
H33C H 0.2640 0.1040 0.6402 0.249 Uiso 1 1 calc R . .
C34 C 0.412(2) 0.0873(17) 0.866(2) 0.166(6) Uiso 1 1 d D . .
H34A H 0.4119 0.0458 0.8663 0.249 Uiso 1 1 calc R . .
H34B H 0.4057 0.1012 0.9266 0.249 Uiso 1 1 calc R . .
H34C H 0.4859 0.1011 0.8555 0.249 Uiso 1 1 calc R . .
C35 C -0.0373(15) 0.2111(8) 0.6127(12) 0.063(4) Uiso 1 1 d . . .
C36 C -0.0416(17) 0.1921(9) 0.5301(14) 0.072(5) Uiso 1 1 d . . .
C37 C -0.0630(16) 0.1699(8) 0.4363(18) 0.103(7) Uiso 1 1 d D . .
C38 C -0.189(2) 0.1420(16) 0.404(3) 0.171(14) Uiso 1 1 d D . .
H38A H -0.2037 0.1292 0.3388 0.257 Uiso 1 1 calc R . .
H38B H -0.2492 0.1699 0.4076 0.257 Uiso 1 1 calc R . .
H38C H -0.1925 0.1096 0.4436 0.257 Uiso 1 1 calc R . .
C39 C 0.017(3) 0.1159(11) 0.443(2) 0.156(12) Uiso 1 1 d D . .
H39A H 0.0099 0.1013 0.3806 0.234 Uiso 1 1 calc R . .
H39B H -0.0096 0.0868 0.4802 0.234 Uiso 1 1 calc R . .
H39C H 0.0995 0.1258 0.4737 0.234 Uiso 1 1 calc R . .
C40 C -0.041(3) 0.2172(19) 0.373(3) 0.178(14) Uiso 1 1 d . . .
H40A H -0.0525 0.2026 0.3099 0.267 Uiso 1 1 calc R . .
H40B H 0.0408 0.2311 0.3974 0.267 Uiso 1 1 calc R . .
H40C H -0.0963 0.2484 0.3723 0.267 Uiso 1 1 calc R . .
C41 C 0.0153(14) 0.2137(8) 0.8950(10) 0.061(4) Uiso 1 1 d D . .
C42 C 0.0398(18) 0.1789(8) 0.9878(11) 0.078(5) Uiso 1 1 d D . .
C43 C 0.0824(16) 0.1547(7) 1.0716(15) 0.092(6) Uiso 1 1 d D . .
C44 C 0.040(3) 0.1879(15) 1.1477(19) 0.157(5) Uiso 1 1 d D . .
H44A H 0.0657 0.2275 1.1488 0.236 Uiso 1 1 calc R . .
H44B H 0.0750 0.1707 1.2089 0.236 Uiso 1 1 calc R . .
H44C H -0.0465 0.1863 1.1328 0.236 Uiso 1 1 calc R . .
C45 C 0.060(3) 0.0894(8) 1.057(2) 0.157(5) Uiso 1 1 d D . .
H45A H 0.1017 0.0753 1.0129 0.236 Uiso 1 1 calc R . .
H45B H -0.0248 0.0823 1.0328 0.236 Uiso 1 1 calc R . .
H45C H 0.0907 0.0699 1.1171 0.236 Uiso 1 1 calc R . .
C46 C 0.2213(16) 0.1528(16) 1.104(2) 0.157(5) Uiso 1 1 d D . .
H46A H 0.2505 0.1313 1.0588 0.236 Uiso 1 1 calc R . .
H46B H 0.2476 0.1345 1.1654 0.236 Uiso 1 1 calc R . .
H46C H 0.2527 0.1915 1.1084 0.236 Uiso 1 1 calc R . .
C47 C 0.6493(15) 0.1786(7) 0.7318(12) 0.059(4) Uiso 1 1 d D . .
C48 C 0.6885(16) 0.1276(7) 0.7240(13) 0.065(5) Uiso 1 1 d D . .
C49 C 0.7292(17) 0.0715(9) 0.7181(14) 0.107(8) Uiso 1 1 d D . .
C50 C 0.857(2) 0.0661(17) 0.706(2) 0.156(5) Uiso 1 1 d D . .
H50A H 0.8770 0.0260 0.7024 0.234 Uiso 1 1 calc R . .
H50B H 0.9143 0.0838 0.7590 0.234 Uiso 1 1 calc R . .
H50C H 0.8601 0.0852 0.6481 0.234 Uiso 1 1 calc R . .
C51 C 0.722(3) 0.0301(13) 0.798(2) 0.156(5) Uiso 1 1 d D . .
H51A H 0.7495 -0.0075 0.7864 0.234 Uiso 1 1 calc R . .
H51B H 0.6392 0.0276 0.8011 0.234 Uiso 1 1 calc R . .
H51C H 0.7716 0.0444 0.8581 0.234 Uiso 1 1 calc R . .
C52 C 0.640(3) 0.0320(14) 0.648(2) 0.156(5) Uiso 1 1 d D . .
H52A H 0.6723 -0.0065 0.6520 0.234 Uiso 1 1 calc R . .
H52B H 0.6272 0.0464 0.5844 0.234 Uiso 1 1 calc R . .
H52C H 0.5641 0.0313 0.6638 0.234 Uiso 1 1 calc R . .
O1 O 0.0117(12) 0.3643(9) 0.5256(13) 0.121(7) Uani 1 1 d . . .
O2 O 0.1952(14) 0.3261(8) 0.5631(13) 0.114(2) Uani 1 1 d . . .
O3 O 0.3162(17) 0.2029(8) 0.5485(12) 0.118(6) Uani 1 1 d . . .
O4 O 0.4581(15) 0.2590(8) 0.5222(11) 0.107(5) Uani 1 1 d . . .
O5 O 0.2936(12) 0.3008(8) 1.0233(10) 0.099(5) Uani 1 1 d . . .
O6 O 0.1361(14) 0.3321(8) 1.0720(13) 0.114(2) Uani 1 1 d . . .
O7 O 0.2229(14) 0.3883(8) 0.8135(13) 0.114(2) Uani 1 1 d . . .
O8 O 0.0439(14) 0.3477(9) 0.7867(13) 0.114(2) Uani 1 1 d . . .
O9 O 0.5797(14) 0.2474(8) 0.9517(13) 0.114(2) Uani 1 1 d . . .
O10 O 0.7424(15) 0.1997(10) 0.9989(12) 0.129(7) Uani 1 1 d . . .
O11W O 0.465(2) 0.3760(13) 0.9724(18) 0.176(9) Uiso 1 1 d . . .
F1 F 0.260(2) 0.4042(14) 0.458(2) 0.122(4) Uiso 0.535(13) 1 d PD A 1
F2 F 0.161(3) 0.4616(11) 0.5216(19) 0.122(4) Uiso 0.535(13) 1 d PD A 1
F3 F 0.084(2) 0.4201(15) 0.3888(17) 0.122(4) Uiso 0.535(13) 1 d PD A 1
F1' F 0.166(3) 0.3940(15) 0.3931(18) 0.122(4) Uiso 0.465(13) 1 d PD A 2
F2' F 0.268(2) 0.4300(16) 0.506(2) 0.122(4) Uiso 0.465(13) 1 d PD A 2
F3' F 0.073(2) 0.4527(13) 0.449(2) 0.122(4) Uiso 0.465(13) 1 d PD A 2
F4 F 0.309(3) 0.1410(19) 0.396(3) 0.166(6) Uiso 0.497(16) 1 d PD B 1
F5 F 0.505(3) 0.1437(19) 0.463(3) 0.166(6) Uiso 0.497(16) 1 d PD B 1
F6 F 0.431(4) 0.1966(19) 0.358(2) 0.166(6) Uiso 0.497(16) 1 d PD B 1
F4' F 0.317(3) 0.186(2) 0.355(2) 0.166(6) Uiso 0.503(16) 1 d PD B 2
F5' F 0.388(4) 0.1190(13) 0.452(3) 0.166(6) Uiso 0.503(16) 1 d PD B 2
F6' F 0.501(3) 0.178(2) 0.402(3) 0.166(6) Uiso 0.503(16) 1 d PD B 2
F7 F 0.369(4) 0.4008(15) 1.142(3) 0.163(6) Uiso 0.519(18) 1 d PD C 1
F8 F 0.432(3) 0.3228(19) 1.197(3) 0.163(6) Uiso 0.519(18) 1 d PD C 1
F9 F 0.276(3) 0.365(2) 1.233(2) 0.163(6) Uiso 0.519(18) 1 d PD C 1
F7' F 0.285(4) 0.3964(16) 1.200(3) 0.163(6) Uiso 0.481(18) 1 d PD C 2
F8' F 0.436(3) 0.366(2) 1.159(3) 0.163(6) Uiso 0.481(18) 1 d PD C 2
F9' F 0.344(4) 0.3075(15) 1.227(3) 0.163(6) Uiso 0.481(18) 1 d PD C 2
F10 F -0.030(3) 0.454(2) 0.710(2) 0.156(6) Uiso 0.460(17) 1 d PD D 1
F11 F 0.127(3) 0.4964(14) 0.803(3) 0.156(6) Uiso 0.460(17) 1 d PD D 1
F12 F -0.014(4) 0.461(2) 0.839(3) 0.156(6) Uiso 0.460(17) 1 d PD D 1
F10' F -0.058(2) 0.4549(19) 0.765(3) 0.156(6) Uiso 0.540(17) 1 d PD D 2
F11' F 0.103(3) 0.4838(17) 0.734(3) 0.156(6) Uiso 0.540(17) 1 d PD D 2
F12' F 0.098(3) 0.4683(17) 0.8756(19) 0.156(6) Uiso 0.540(17) 1 d PD D 2
F13 F 0.600(3) 0.2457(14) 1.147(2) 0.155(5) Uiso 0.545(16) 1 d PD E 1
F14 F 0.690(3) 0.1665(18) 1.146(3) 0.155(5) Uiso 0.545(16) 1 d PD E 1
F15 F 0.527(3) 0.1633(17) 1.081(3) 0.155(5) Uiso 0.545(16) 1 d PD E 1
F13' F 0.499(2) 0.206(2) 1.092(3) 0.155(5) Uiso 0.455(16) 1 d PD E 2
F14' F 0.695(3) 0.214(2) 1.172(2) 0.155(5) Uiso 0.455(16) 1 d PD E 2
F15' F 0.616(5) 0.1461(12) 1.102(3) 0.155(5) Uiso 0.455(16) 1 d PD E 2


_geom_special_details            
;
 All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell s.u.'s are taken
 into account individually in the estimation of s.u.'s in distances, angles
 and torsion angles; correlations between s.u.'s in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C41 1.986(14) . ?
Ag1 C35 2.028(17) . ?
Ag1 Ag5 2.886(2) . ?
Ag1 Ag11 2.918(2) . ?
Ag1 Ag4 2.931(2) . ?
Ag1 Ag7 3.162(2) . ?
Ag2 C47 2.130(16) . ?
Ag2 C29 2.365(17) . ?
Ag2 C30 2.708(18) . ?
Ag2 Ag3 2.894(2) . ?
Ag2 Ag9 2.988(2) . ?
Ag2 Ag6 3.108(2) . ?
Ag2 Ag11 3.270(2) 1_655 ?
Ag3 C29 2.049(14) . ?
Ag3 C23 2.066(19) . ?
Ag3 O7 2.325(18) . ?
Ag3 Ag6 2.800(2) . ?
Ag3 Ag5 2.945(2) . ?
Ag3 Ag12 3.015(2) . ?
Ag3 Ag7 3.061(2) . ?
Ag4 C35 2.264(19) . ?
Ag4 O1 2.270(14) . ?
Ag4 C17 2.316(19) 1_455 ?
Ag4 C18 2.69(2) 1_455 ?
Ag4 Ag7 3.160(2) . ?
Ag4 Ag9 3.241(2) 1_455 ?
Ag4 Ag8 3.334(2) 1_455 ?
Ag5 O5 2.243(13) . ?
Ag5 C29 2.249(17) . ?
Ag5 C41 2.361(16) . ?
Ag5 Ag10 3.043(2) . ?
Ag6 C23 1.991(19) . ?
Ag6 O4 2.128(16) . ?
Ag6 Ag9 3.046(2) . ?
Ag7 O2 2.320(19) . ?
Ag7 C35 2.346(17) . ?
Ag7 C29 2.373(16) . ?
Ag7 O3 2.584(17) . ?
Ag7 C36 2.687(19) . ?
Ag8 C11 1.959(15) . ?
Ag8 C17 1.996(16) . ?
Ag8 Ag9 2.788(2) . ?
Ag8 Ag12 2.870(3) . ?
Ag8 Ag10 2.983(2) 1_655 ?
Ag8 Ag4 3.334(2) 1_655 ?
Ag9 C17 2.029(18) . ?
Ag9 C47 2.119(17) . ?
Ag9 Ag11 2.988(2) 1_655 ?
Ag9 Ag4 3.241(2) 1_655 ?
Ag10 C11 2.20(2) 1_455 ?
Ag10 C41 2.239(18) . ?
Ag10 O6 2.340(17) . ?
Ag10 Ag11 2.941(3) . ?
Ag10 Ag8 2.983(2) 1_455 ?
Ag11 O10 2.287(17) 1_455 ?
Ag11 C47 2.290(16) 1_455 ?
Ag11 C41 2.430(16) . ?
Ag11 Ag9 2.988(2) 1_455 ?
Ag11 Ag2 3.270(2) 1_455 ?
Ag12 C11 2.26(2) . ?
Ag12 C23 2.31(2) . ?
Ag12 O11W 2.52(3) . ?
C1 O1 1.20(2) . ?
C1 O2 1.26(2) . ?
C1 C2 1.5200(11) . ?
C2 F3' 1.296(10) . ?
C2 F2' 1.297(10) . ?
C2 F1 1.298(10) . ?
C2 F3 1.304(10) . ?
C2 F1' 1.306(10) . ?
C2 F2 1.307(10) . ?
C3 O4 1.22(3) . ?
C3 O3 1.26(3) . ?
C3 C4 1.5201(11) . ?
C4 F6' 1.294(10) . ?
C4 F4 1.296(10) . ?
C4 F6 1.304(10) . ?
C4 F5' 1.303(10) . ?
C4 F5 1.306(10) . ?
C4 F4' 1.306(10) . ?
C5 O6 1.22(3) . ?
C5 O5 1.27(3) . ?
C5 C6 1.5201(11) . ?
C6 F7' 1.300(10) . ?
C6 F8' 1.303(10) . ?
C6 F9 1.305(10) . ?
C6 F8 1.307(10) . ?
C6 F9' 1.309(10) . ?
C6 F7 1.312(10) . ?
C7 O8 1.22(2) . ?
C7 O7 1.24(2) . ?
C7 C8 1.5200(11) . ?
C8 F12 1.298(10) . ?
C8 F11' 1.298(10) . ?
C8 F10' 1.301(10) . ?
C8 F11 1.303(10) . ?
C8 F10 1.304(10) . ?
C8 F12' 1.309(10) . ?
C9 O10 1.09(3) . ?
C9 O9 1.26(3) . ?
C9 C10 1.5201(11) . ?
C10 F13' 1.296(10) . ?
C10 F14' 1.300(10) . ?
C10 F15' 1.302(10) . ?
C10 F14 1.300(10) . ?
C10 F15 1.305(10) . ?
C10 F13 1.310(10) . ?
C11 C12 1.5345(11) . ?
C11 Ag10 2.20(2) 1_655 ?
C12 C13 1.34(2) . ?
C13 C14 1.5350(12) . ?
C13 C16 1.5350(11) . ?
C13 C15 1.5350(11) . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 C18 1.5345(11) . ?
C17 Ag4 2.316(19) 1_655 ?
C18 C19 1.31(2) . ?
C18 Ag4 2.69(2) 1_655 ?
C19 C22 1.5349(11) . ?
C19 C20 1.5349(12) . ?
C19 C21 1.5350(11) . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 C24 1.5347(11) . ?
C24 C25 1.23(3) . ?
C25 C27 1.5348(11) . ?
C25 C26 1.5350(11) . ?
C25 C28 1.5351(12) . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 C30 1.5345(11) . ?
C30 C31 1.27(2) . ?
C31 C32 1.5350(12) . ?
C31 C34 1.5350(11) . ?
C31 C33 1.5351(11) . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
C34 H34A 0.9600 . ?
C34 H34B 0.9600 . ?
C34 H34C 0.9600 . ?
C35 C36 1.27(2) . ?
C36 C37 1.42(3) . ?
C37 C40 1.50(4) . ?
C37 C38 1.5350(9) . ?
C37 C39 1.5350(11) . ?
C38 H38A 0.9600 . ?
C38 H38B 0.9600 . ?
C38 H38C 0.9600 . ?
C39 H39A 0.9600 . ?
C39 H39B 0.9600 . ?
C39 H39C 0.9600 . ?
C40 H40A 0.9600 . ?
C40 H40B 0.9600 . ?
C40 H40C 0.9600 . ?
C41 C42 1.5345(11) . ?
C42 C43 1.31(2) . ?
C43 C44 1.5349(11) . ?
C43 C45 1.5349(11) . ?
C43 C46 1.5350(13) . ?
C44 H44A 0.9600 . ?
C44 H44B 0.9600 . ?
C44 H44C 0.9600 . ?
C45 H45A 0.9600 . ?
C45 H45B 0.9600 . ?
C45 H45C 0.9600 . ?
C46 H46A 0.9600 . ?
C46 H46B 0.9600 . ?
C46 H46C 0.9600 . ?
C47 C48 1.280(9) . ?
C47 Ag11 2.290(16) 1_655 ?
C48 C49 1.39(3) . ?
C49 C52 1.5349(11) . ?
C49 C50 1.5349(12) . ?
C49 C51 1.5349(11) . ?
C50 H50A 0.9600 . ?
C50 H50B 0.9600 . ?
C50 H50C 0.9600 . ?
C51 H51A 0.9600 . ?
C51 H51B 0.9600 . ?
C51 H51C 0.9600 . ?
C52 H52A 0.9600 . ?
C52 H52B 0.9600 . ?
C52 H52C 0.9600 . ?
O10 Ag11 2.287(17) 1_655 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C41 Ag1 C35 169.9(7) . . ?
C41 Ag1 Ag5 54.2(5) . . ?
C35 Ag1 Ag5 120.2(5) . . ?
C41 Ag1 Ag11 55.6(5) . . ?
C35 Ag1 Ag11 132.5(5) . . ?
Ag5 Ag1 Ag11 106.01(6) . . ?
C41 Ag1 Ag4 136.5(5) . . ?
C35 Ag1 Ag4 50.4(5) . . ?
Ag5 Ag1 Ag4 103.72(7) . . ?
Ag11 Ag1 Ag4 110.86(7) . . ?
C41 Ag1 Ag7 125.3(5) . . ?
C35 Ag1 Ag7 47.8(5) . . ?
Ag5 Ag1 Ag7 72.45(6) . . ?
Ag11 Ag1 Ag7 171.73(8) . . ?
Ag4 Ag1 Ag7 62.35(5) . . ?
C47 Ag2 C29 157.0(6) . . ?
C47 Ag2 C30 123.4(6) . . ?
C29 Ag2 C30 34.4(2) . . ?
C47 Ag2 Ag3 155.5(5) . . ?
C29 Ag2 Ag3 44.5(3) . . ?
C30 Ag2 Ag3 78.8(3) . . ?
C47 Ag2 Ag9 45.2(5) . . ?
C29 Ag2 Ag9 148.2(4) . . ?
C30 Ag2 Ag9 153.2(4) . . ?
Ag3 Ag2 Ag9 110.42(7) . . ?
C47 Ag2 Ag6 102.4(5) . . ?
C29 Ag2 Ag6 88.6(4) . . ?
C30 Ag2 Ag6 113.2(4) . . ?
Ag3 Ag2 Ag6 55.48(5) . . ?
Ag9 Ag2 Ag6 59.93(5) . . ?
C47 Ag2 Ag11 44.2(4) . 1_655 ?
C29 Ag2 Ag11 149.7(4) . 1_655 ?
C30 Ag2 Ag11 137.6(4) . 1_655 ?
Ag3 Ag2 Ag11 127.57(8) . 1_655 ?
Ag9 Ag2 Ag11 56.82(5) . 1_655 ?
Ag6 Ag2 Ag11 109.11(7) . 1_655 ?
C29 Ag3 C23 144.0(7) . . ?
C29 Ag3 O7 121.3(6) . . ?
C23 Ag3 O7 94.5(7) . . ?
C29 Ag3 Ag6 104.4(5) . . ?
C23 Ag3 Ag6 45.3(5) . . ?
O7 Ag3 Ag6 123.4(5) . . ?
C29 Ag3 Ag2 53.9(5) . . ?
C23 Ag3 Ag2 91.2(6) . . ?
O7 Ag3 Ag2 170.1(5) . . ?
Ag6 Ag3 Ag2 66.14(5) . . ?
C29 Ag3 Ag5 49.7(5) . . ?
C23 Ag3 Ag5 163.3(5) . . ?
O7 Ag3 Ag5 74.3(5) . . ?
Ag6 Ag3 Ag5 151.43(7) . . ?
Ag2 Ag3 Ag5 98.23(6) . . ?
C29 Ag3 Ag12 114.7(5) . . ?
C23 Ag3 Ag12 49.8(6) . . ?
O7 Ag3 Ag12 107.7(4) . . ?
Ag6 Ag3 Ag12 77.70(7) . . ?
Ag2 Ag3 Ag12 70.28(7) . . ?
Ag5 Ag3 Ag12 121.04(7) . . ?
C29 Ag3 Ag7 50.8(5) . . ?
C23 Ag3 Ag7 122.2(6) . . ?
O7 Ag3 Ag7 102.7(4) . . ?
Ag6 Ag3 Ag7 80.54(7) . . ?
Ag2 Ag3 Ag7 80.89(6) . . ?
Ag5 Ag3 Ag7 73.17(6) . . ?
Ag12 Ag3 Ag7 149.04(7) . . ?
C35 Ag4 O1 116.7(7) . . ?
C35 Ag4 C17 119.4(6) . 1_455 ?
O1 Ag4 C17 120.7(6) . 1_455 ?
C35 Ag4 C18 133.7(6) . 1_455 ?
O1 Ag4 C18 90.8(5) . 1_455 ?
C17 Ag4 C18 34.7(3) 1_455 1_455 ?
C35 Ag4 Ag1 43.6(4) . . ?
O1 Ag4 Ag1 138.5(3) . . ?
C17 Ag4 Ag1 96.6(4) 1_455 . ?
C18 Ag4 Ag1 129.9(4) 1_455 . ?
C35 Ag4 Ag7 47.8(4) . . ?
O1 Ag4 Ag7 78.5(4) . . ?
C17 Ag4 Ag7 158.8(4) 1_455 . ?
C18 Ag4 Ag7 166.1(4) 1_455 . ?
Ag1 Ag4 Ag7 62.40(5) . . ?
C35 Ag4 Ag9 81.0(4) . 1_455 ?
O1 Ag4 Ag9 155.0(3) . 1_455 ?
C17 Ag4 Ag9 38.5(4) 1_455 1_455 ?
C18 Ag4 Ag9 64.6(4) 1_455 1_455 ?
Ag1 Ag4 Ag9 66.47(5) . 1_455 ?
Ag7 Ag4 Ag9 124.89(7) . 1_455 ?
C35 Ag4 Ag8 113.9(4) . 1_455 ?
O1 Ag4 Ag8 125.9(6) . 1_455 ?
C17 Ag4 Ag8 36.0(4) 1_455 1_455 ?
C18 Ag4 Ag8 66.7(4) 1_455 1_455 ?
Ag1 Ag4 Ag8 74.22(6) . 1_455 ?
Ag7 Ag4 Ag8 126.91(7) . 1_455 ?
Ag9 Ag4 Ag8 50.16(5) 1_455 1_455 ?
O5 Ag5 C29 117.7(5) . . ?
O5 Ag5 C41 111.5(5) . . ?
C29 Ag5 C41 124.9(6) . . ?
O5 Ag5 Ag1 150.8(4) . . ?
C29 Ag5 Ag1 91.5(4) . . ?
C41 Ag5 Ag1 43.0(3) . . ?
O5 Ag5 Ag3 93.3(4) . . ?
C29 Ag5 Ag3 44.0(4) . . ?
C41 Ag5 Ag3 152.2(3) . . ?
Ag1 Ag5 Ag3 109.46(6) . . ?
O5 Ag5 Ag10 81.5(4) . . ?
C29 Ag5 Ag10 158.1(4) . . ?
C41 Ag5 Ag10 46.9(4) . . ?
Ag1 Ag5 Ag10 69.86(6) . . ?
Ag3 Ag5 Ag10 130.52(8) . . ?
C23 Ag6 O4 169.0(8) . . ?
C23 Ag6 Ag3 47.5(6) . . ?
O4 Ag6 Ag3 130.5(5) . . ?
C23 Ag6 Ag9 106.6(6) . . ?
O4 Ag6 Ag9 63.1(5) . . ?
Ag3 Ag6 Ag9 111.38(6) . . ?
C23 Ag6 Ag2 86.6(6) . . ?
O4 Ag6 Ag2 84.4(5) . . ?
Ag3 Ag6 Ag2 58.38(5) . . ?
Ag9 Ag6 Ag2 58.10(5) . . ?
O2 Ag7 C35 116.9(6) . . ?
O2 Ag7 C29 110.9(5) . . ?
C35 Ag7 C29 120.3(6) . . ?
O2 Ag7 O3 81.4(6) . . ?
C35 Ag7 O3 127.2(6) . . ?
C29 Ag7 O3 92.5(6) . . ?
O2 Ag7 C36 108.4(6) . . ?
C35 Ag7 C36 28.3(6) . . ?
C29 Ag7 C36 140.1(6) . . ?
O3 Ag7 C36 100.5(6) . . ?
O2 Ag7 Ag3 70.1(4) . . ?
C35 Ag7 Ag3 136.5(4) . . ?
C29 Ag7 Ag3 42.0(3) . . ?
O3 Ag7 Ag3 95.9(4) . . ?
C36 Ag7 Ag3 163.1(4) . . ?
O2 Ag7 Ag4 77.1(4) . . ?
C35 Ag7 Ag4 45.6(5) . . ?
C29 Ag7 Ag4 122.5(4) . . ?
O3 Ag7 Ag4 143.6(4) . . ?
C36 Ag7 Ag4 60.2(4) . . ?
Ag3 Ag7 Ag4 103.74(7) . . ?
O2 Ag7 Ag1 127.9(5) . . ?
C35 Ag7 Ag1 39.9(4) . . ?
C29 Ag7 Ag1 82.7(4) . . ?
O3 Ag7 Ag1 150.1(4) . . ?
C36 Ag7 Ag1 67.4(4) . . ?
Ag3 Ag7 Ag1 99.82(7) . . ?
Ag4 Ag7 Ag1 55.25(5) . . ?
C11 Ag8 C17 167.4(9) . . ?
C11 Ag8 Ag9 123.6(7) . . ?
C17 Ag8 Ag9 46.7(5) . . ?
C11 Ag8 Ag12 51.8(6) . . ?
C17 Ag8 Ag12 116.7(6) . . ?
Ag9 Ag8 Ag12 91.41(8) . . ?
C11 Ag8 Ag10 47.6(7) . 1_655 ?
C17 Ag8 Ag10 137.5(5) . 1_655 ?
Ag9 Ag8 Ag10 107.67(7) . 1_655 ?
Ag12 Ag8 Ag10 93.11(7) . 1_655 ?
C11 Ag8 Ag4 145.6(7) . 1_655 ?
C17 Ag8 Ag4 43.0(5) . 1_655 ?
Ag9 Ag8 Ag4 63.19(6) . 1_655 ?
Ag12 Ag8 Ag4 154.30(8) . 1_655 ?
Ag10 Ag8 Ag4 98.18(7) 1_655 1_655 ?
C17 Ag9 C47 164.2(6) . . ?
C17 Ag9 Ag8 45.7(5) . . ?
C47 Ag9 Ag8 118.6(4) . . ?
C17 Ag9 Ag2 129.7(5) . . ?
C47 Ag9 Ag2 45.5(4) . . ?
Ag8 Ag9 Ag2 99.48(7) . . ?
C17 Ag9 Ag11 114.9(5) . 1_655 ?
C47 Ag9 Ag11 49.8(4) . 1_655 ?
Ag8 Ag9 Ag11 71.61(7) . 1_655 ?
Ag2 Ag9 Ag11 66.34(5) . 1_655 ?
C17 Ag9 Ag6 78.5(5) . . ?
C47 Ag9 Ag6 104.6(4) . . ?
Ag8 Ag9 Ag6 86.76(7) . . ?
Ag2 Ag9 Ag6 61.98(5) . . ?
Ag11 Ag9 Ag6 118.89(7) 1_655 . ?
C17 Ag9 Ag4 45.3(5) . 1_655 ?
C47 Ag9 Ag4 133.8(4) . 1_655 ?
Ag8 Ag9 Ag4 66.65(6) . 1_655 ?
Ag2 Ag9 Ag4 164.41(7) . 1_655 ?
Ag11 Ag9 Ag4 101.22(6) 1_655 1_655 ?
Ag6 Ag9 Ag4 121.57(7) . 1_655 ?
C11 Ag10 C41 132.0(7) 1_455 . ?
C11 Ag10 O6 116.3(6) 1_455 . ?
C41 Ag10 O6 110.4(6) . . ?
C11 Ag10 Ag11 79.8(6) 1_455 . ?
C41 Ag10 Ag11 53.9(4) . . ?
O6 Ag10 Ag11 148.1(5) . . ?
C11 Ag10 Ag8 41.0(4) 1_455 1_455 ?
C41 Ag10 Ag8 103.4(4) . 1_455 ?
O6 Ag10 Ag8 140.8(5) . 1_455 ?
Ag11 Ag10 Ag8 69.65(6) . 1_455 ?
C11 Ag10 Ag5 149.8(5) 1_455 . ?
C41 Ag10 Ag5 50.3(4) . . ?
O6 Ag10 Ag5 78.3(5) . . ?
Ag11 Ag10 Ag5 101.53(7) . . ?
Ag8 Ag10 Ag5 110.62(8) 1_455 . ?
O10 Ag11 C47 111.5(7) 1_455 1_455 ?
O10 Ag11 C41 109.7(5) 1_455 . ?
C47 Ag11 C41 131.3(6) 1_455 . ?
O10 Ag11 Ag1 151.7(4) 1_455 . ?
C47 Ag11 Ag1 92.4(4) 1_455 . ?
C41 Ag11 Ag1 42.4(3) . . ?
O10 Ag11 Ag10 93.3(6) 1_455 . ?
C47 Ag11 Ag10 148.6(4) 1_455 . ?
C41 Ag11 Ag10 48.1(4) . . ?
Ag1 Ag11 Ag10 70.87(6) . . ?
O10 Ag11 Ag9 137.8(4) 1_455 1_455 ?
C47 Ag11 Ag9 45.0(4) 1_455 1_455 ?
C41 Ag11 Ag9 110.4(3) . 1_455 ?
Ag1 Ag11 Ag9 70.11(6) . 1_455 ?
Ag10 Ag11 Ag9 103.61(8) . 1_455 ?
O10 Ag11 Ag2 82.9(4) 1_455 1_455 ?
C47 Ag11 Ag2 40.4(4) 1_455 1_455 ?
C41 Ag11 Ag2 167.2(3) . 1_455 ?
Ag1 Ag11 Ag2 125.26(7) . 1_455 ?
Ag10 Ag11 Ag2 131.17(10) . 1_455 ?
Ag9 Ag11 Ag2 56.83(5) 1_455 1_455 ?
C11 Ag12 C23 131.7(7) . . ?
C11 Ag12 O11W 128.8(7) . . ?
C23 Ag12 O11W 90.5(8) . . ?
C11 Ag12 Ag8 42.9(4) . . ?
C23 Ag12 Ag8 91.6(6) . . ?
O11W Ag12 Ag8 164.6(6) . . ?
C11 Ag12 Ag3 162.5(5) . . ?
C23 Ag12 Ag3 43.2(5) . . ?
O11W Ag12 Ag3 67.6(6) . . ?
Ag8 Ag12 Ag3 122.85(9) . . ?
O1 C1 O2 128.1(18) . . ?
O1 C1 C2 114.7(18) . . ?
O2 C1 C2 116.6(19) . . ?
F3' C2 F2' 118(3) . . ?
F3' C2 F1 134(2) . . ?
F2' C2 F1 40.8(18) . . ?
F3' C2 F3 54.7(19) . . ?
F2' C2 F3 127(2) . . ?
F1 C2 F3 102(2) . . ?
F3' C2 F1' 103(2) . . ?
F2' C2 F1' 95(2) . . ?
F1 C2 F1' 56.9(19) . . ?
F3 C2 F1' 50.1(18) . . ?
F3' C2 F2 57.8(18) . . ?
F2' C2 F2 70(2) . . ?
F1 C2 F2 109(2) . . ?
F3 C2 F2 109(2) . . ?
F1' C2 F2 140(3) . . ?
F3' C2 C1 112(2) . . ?
F2' C2 C1 116(2) . . ?
F1 C2 C1 113(2) . . ?
F3 C2 C1 114(2) . . ?
F1' C2 C1 110(2) . . ?
F2 C2 C1 109(2) . . ?
O4 C3 O3 125(2) . . ?
O4 C3 C4 121(2) . . ?
O3 C3 C4 114(2) . . ?
F6' C4 F4 130(3) . . ?
F6' C4 F6 44(2) . . ?
F4 C4 F6 107(3) . . ?
F6' C4 F5' 111(3) . . ?
F4 C4 F5' 53(2) . . ?
F6 C4 F5' 132(3) . . ?
F6' C4 F5 54(3) . . ?
F4 C4 F5 115(3) . . ?
F6 C4 F5 97(3) . . ?
F5' C4 F5 66(3) . . ?
F6' C4 F4' 103(3) . . ?
F4 C4 F4' 56(3) . . ?
F6 C4 F4' 61(3) . . ?
F5' C4 F4' 107(3) . . ?
F5 C4 F4' 145(3) . . ?
F6' C4 C3 114(3) . . ?
F4 C4 C3 115(3) . . ?
F6 C4 C3 113(3) . . ?
F5' C4 C3 115(3) . . ?
F5 C4 C3 109(3) . . ?
F4' C4 C3 105(3) . . ?
O6 C5 O5 128(2) . . ?
O6 C5 C6 117(2) . . ?
O5 C5 C6 115(2) . . ?
F7' C6 F8' 108(4) . . ?
F7' C6 F9 40(3) . . ?
F8' C6 F9 131(3) . . ?
F7' C6 F8 135(3) . . ?
F8' C6 F8 53(3) . . ?
F9 C6 F8 117(3) . . ?
F7' C6 F9' 112(3) . . ?
F8' C6 F9' 109(3) . . ?
F9 C6 F9' 73(3) . . ?
F8 C6 F9' 58(3) . . ?
F7' C6 F7 67(3) . . ?
F8' C6 F7 49(3) . . ?
F9 C6 F7 106(3) . . ?
F8 C6 F7 101(3) . . ?
F9' C6 F7 151(3) . . ?
F7' C6 C5 112(3) . . ?
F8' C6 C5 115(3) . . ?
F9 C6 C5 112(3) . . ?
F8 C6 C5 113(3) . . ?
F9' C6 C5 100(3) . . ?
F7 C6 C5 106(3) . . ?
O8 C7 O7 126(2) . . ?
O8 C7 C8 120(2) . . ?
O7 C7 C8 113.4(19) . . ?
F12 C8 F11' 131(3) . . ?
F12 C8 F10' 49(2) . . ?
F11' C8 F10' 110(3) . . ?
F12 C8 F11 102(3) . . ?
F11' C8 F11 46(2) . . ?
F10' C8 F11 121(3) . . ?
F12 C8 F10 91(3) . . ?
F11' C8 F10 77(3) . . ?
F10' C8 F10 43(2) . . ?
F11 C8 F10 113(3) . . ?
F12 C8 F12' 58(2) . . ?
F11' C8 F12' 109(3) . . ?
F10' C8 F12' 106(3) . . ?
F11 C8 F12' 63(3) . . ?
F10 C8 F12' 144(3) . . ?
F12 C8 C7 116(3) . . ?
F11' C8 C7 112(3) . . ?
F10' C8 C7 117(3) . . ?
F11 C8 C7 123(3) . . ?
F10 C8 C7 108(3) . . ?
F12' C8 C7 102(2) . . ?
O10 C9 O9 128(2) . . ?
O10 C9 C10 123(2) . . ?
O9 C9 C10 109(2) . . ?
F13' C10 F14' 119(3) . . ?
F13' C10 F15' 94(3) . . ?
F14' C10 F15' 97(3) . . ?
F13' C10 F14 125(3) . . ?
F14' C10 F14 53(3) . . ?
F15' C10 F14 46(2) . . ?
F13' C10 F15 48(2) . . ?
F14' C10 F15 128(3) . . ?
F15' C10 F15 48(2) . . ?
F14 C10 F15 91(3) . . ?
F13' C10 F13 72(3) . . ?
F14' C10 F13 59(3) . . ?
F15' C10 F13 135(3) . . ?
F14 C10 F13 108(3) . . ?
F15 C10 F13 114(3) . . ?
F13' C10 C9 122(3) . . ?
F14' C10 C9 112(3) . . ?
F15' C10 C9 105(3) . . ?
F14 C10 C9 106(3) . . ?
F15 C10 C9 115(3) . . ?
F13 C10 C9 119(3) . . ?
C12 C11 Ag8 165.7(18) . . ?
C12 C11 Ag10 94.6(12) . 1_655 ?
Ag8 C11 Ag10 91.4(8) . 1_655 ?
C12 C11 Ag12 97.1(12) . . ?
Ag8 C11 Ag12 85.4(7) . . ?
Ag10 C11 Ag12 144.4(12) 1_655 . ?
C13 C12 C11 177.4(18) . . ?
C12 C13 C14 107.6(17) . . ?
C12 C13 C16 106.5(18) . . ?
C14 C13 C16 112(2) . . ?
C12 C13 C15 110.6(19) . . ?
C14 C13 C15 111(2) . . ?
C16 C13 C15 109(2) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C13 C16 H16A 109.5 . . ?
C13 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C13 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 Ag8 143.5(14) . . ?
C18 C17 Ag9 127.5(13) . . ?
Ag8 C17 Ag9 87.7(6) . . ?
C18 C17 Ag4 86.1(11) . 1_655 ?
Ag8 C17 Ag4 101.0(7) . 1_655 ?
Ag9 C17 Ag4 96.2(7) . 1_655 ?
C19 C18 C17 167(2) . . ?
C19 C18 Ag4 125.2(14) . 1_655 ?
C17 C18 Ag4 59.2(9) . 1_655 ?
C18 C19 C22 102.5(19) . . ?
C18 C19 C20 113(2) . . ?
C22 C19 C20 106(2) . . ?
C18 C19 C21 111(2) . . ?
C22 C19 C21 113(2) . . ?
C20 C19 C21 111(2) . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C19 C21 H21A 109.5 . . ?
C19 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C19 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C19 C22 H22A 109.5 . . ?
C19 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C19 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C24 C23 Ag6 130.7(15) . . ?
C24 C23 Ag3 138.0(15) . . ?
Ag6 C23 Ag3 87.3(7) . . ?
C24 C23 Ag12 89.7(11) . . ?
Ag6 C23 Ag12 116.2(9) . . ?
Ag3 C23 Ag12 87.0(7) . . ?
C25 C24 C23 170(2) . . ?
C24 C25 C27 120(2) . . ?
C24 C25 C26 109(2) . . ?
C27 C25 C26 104(2) . . ?
C24 C25 C28 113(2) . . ?
C27 C25 C28 108(2) . . ?
C26 C25 C28 102(2) . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.4 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C25 C27 H27A 109.5 . . ?
C25 C27 H27B 109.4 . . ?
H27A C27 H27B 109.5 . . ?
C25 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C25 C28 H28A 109.5 . . ?
C25 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C25 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C30 C29 Ag3 166.0(14) . . ?
C30 C29 Ag5 107.2(11) . . ?
Ag3 C29 Ag5 86.4(5) . . ?
C30 C29 Ag2 85.1(10) . . ?
Ag3 C29 Ag2 81.6(6) . . ?
Ag5 C29 Ag2 146.1(8) . . ?
C30 C29 Ag7 93.2(10) . . ?
Ag3 C29 Ag7 87.3(5) . . ?
Ag5 C29 Ag7 101.5(6) . . ?
Ag2 C29 Ag7 109.3(7) . . ?
C31 C30 C29 175.7(18) . . ?
C31 C30 Ag2 118.8(13) . . ?
C29 C30 Ag2 60.5(9) . . ?
C30 C31 C32 107(2) . . ?
C30 C31 C34 111(2) . . ?
C32 C31 C34 115(2) . . ?
C30 C31 C33 106(2) . . ?
C32 C31 C33 112(2) . . ?
C34 C31 C33 106(2) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C31 C34 H34A 109.5 . . ?
C31 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C31 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C36 C35 Ag1 163.3(16) . . ?
C36 C35 Ag4 110.6(14) . . ?
Ag1 C35 Ag4 86.0(7) . . ?
C36 C35 Ag7 90.9(12) . . ?
Ag1 C35 Ag7 92.3(6) . . ?
Ag4 C35 Ag7 86.5(6) . . ?
C35 C36 C37 172.5(19) . . ?
C35 C36 Ag7 60.8(11) . . ?
C37 C36 Ag7 126.6(13) . . ?
C36 C37 C40 108(2) . . ?
C36 C37 C38 110(2) . . ?
C40 C37 C38 115(2) . . ?
C36 C37 C39 107(2) . . ?
C40 C37 C39 116(3) . . ?
C38 C37 C39 100(2) . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C37 C39 H39A 109.5 . . ?
C37 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C37 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C37 C40 H40A 109.5 . . ?
C37 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C37 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C42 C41 Ag1 150.3(14) . . ?
C42 C41 Ag10 101.5(11) . . ?
Ag1 C41 Ag10 106.9(7) . . ?
C42 C41 Ag5 109.6(11) . . ?
Ag1 C41 Ag5 82.7(5) . . ?
Ag10 C41 Ag5 82.8(6) . . ?
C42 C41 Ag11 95.8(10) . . ?
Ag1 C41 Ag11 82.0(5) . . ?
Ag10 C41 Ag11 78.0(5) . . ?
Ag5 C41 Ag11 150.7(7) . . ?
C43 C42 C41 168.1(19) . . ?
C42 C43 C44 111(2) . . ?
C42 C43 C45 107(2) . . ?
C44 C43 C45 121(2) . . ?
C42 C43 C46 113(2) . . ?
C44 C43 C46 107(2) . . ?
C45 C43 C46 98(2) . . ?
C43 C44 H44A 109.5 . . ?
C43 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C43 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C43 C45 H45A 109.5 . . ?
C43 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C43 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C43 C46 H46A 109.5 . . ?
C43 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C43 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C48 C47 Ag9 128.1(14) . . ?
C48 C47 Ag2 139.8(15) . . ?
Ag9 C47 Ag2 89.4(6) . . ?
C48 C47 Ag11 100.9(12) . 1_655 ?
Ag9 C47 Ag11 85.2(6) . 1_655 ?
Ag2 C47 Ag11 95.4(6) . 1_655 ?
C47 C48 C49 178(2) . . ?
C48 C49 C52 115(2) . . ?
C48 C49 C50 116(2) . . ?
C52 C49 C50 111(2) . . ?
C48 C49 C51 116(2) . . ?
C52 C49 C51 88(2) . . ?
C50 C49 C51 107(2) . . ?
C49 C50 H50A 109.5 . . ?
C49 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
C49 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C49 C51 H51A 109.5 . . ?
C49 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C49 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C49 C52 H52A 109.5 . . ?
C49 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C49 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C1 O1 Ag4 127.6(13) . . ?
C1 O2 Ag7 126.6(13) . . ?
C3 O3 Ag7 145.8(17) . . ?
C3 O4 Ag6 122.9(15) . . ?
C5 O5 Ag5 125.7(12) . . ?
C5 O6 Ag10 126.3(16) . . ?
C7 O7 Ag3 128.4(14) . . ?
C9 O10 Ag11 121.5(17) . 1_655 ?

_diffrn_measured_fraction_theta_max 0.995
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.995
_refine_diff_density_max         1.141
_refine_diff_density_min         -1.063
_refine_diff_density_rms         0.172

_database_code_depnum_ccdc_archive 'CCDC 926482'
