# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2014

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/. 
# 
# Audit and citation data items have may been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelxl
_database_code_depnum_ccdc_archive 'CCDC 995811'
_audit_update_record             
;
2014-04-07 deposited with the CCDC.
2014-12-05 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C31 H22 N8 O2 Os, 5(O)'
_chemical_formula_sum            'C31 H22 N8 O7 Os'
_chemical_formula_weight         808.77

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -1.2165 7.6030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/c'
_symmetry_space_group_name_Hall  '-P 2ybc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   9.5534(2)
_cell_length_b                   25.7853(5)
_cell_length_c                   12.6272(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 93.470(2)
_cell_angle_gamma                90.00
_cell_volume                     3104.85(12)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      2.90
_cell_measurement_theta_max      25.00

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.14
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.730
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1584
_exptl_absorpt_coefficient_mu    4.168
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5048
_exptl_absorpt_correction_T_max  0.5930
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur Sapphire3'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            40852
_diffrn_reflns_av_R_equivalents  0.0264
_diffrn_reflns_av_sigmaI/netI    0.0149
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         2.87
_diffrn_reflns_theta_max         25.00
_reflns_number_total             5464
_reflns_number_gt                5338
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0254P)²+21.5230P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5464
_refine_ls_number_parameters     439
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0306
_refine_ls_R_factor_gt           0.0298
_refine_ls_wR_factor_ref         0.0697
_refine_ls_wR_factor_gt          0.0692
_refine_ls_goodness_of_fit_ref   0.981
_refine_ls_restrained_S_all      0.981
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C -0.0345(5) 0.35829(18) 0.6383(4) 0.0235(10) Uani 1 1 d . . .
C2 C 0.0125(5) 0.38848(16) 0.7938(4) 0.0202(9) Uani 1 1 d . . .
C3 C -0.0119(5) 0.40798(17) 0.8994(4) 0.0204(9) Uani 1 1 d . . .
C4 C -0.1089(5) 0.43243(18) 1.0406(4) 0.0240(10) Uani 1 1 d . . .
C5 C -0.2023(5) 0.44500(19) 1.1177(4) 0.0286(11) Uani 1 1 d . . .
H5 H -0.2997 0.4378 1.1079 0.034 Uiso 1 1 calc R . .
C6 C -0.1457(6) 0.46855(19) 1.2092(4) 0.0302(11) Uani 1 1 d . . .
H6 H -0.2067 0.4785 1.2624 0.036 Uiso 1 1 calc R . .
C7 C -0.0030(5) 0.47815(18) 1.2262(4) 0.0280(11) Uani 1 1 d . . .
H7 H 0.0311 0.4935 1.2910 0.034 Uiso 1 1 calc R . .
C8 C 0.0909(5) 0.46574(18) 1.1504(4) 0.0267(10) Uani 1 1 d . . .
H8 H 0.1885 0.4725 1.1613 0.032 Uiso 1 1 calc R . .
C9 C 0.0343(5) 0.44280(17) 1.0572(3) 0.0211(9) Uani 1 1 d . . .
C10 C 0.1382(5) 0.38498(17) 0.7426(4) 0.0220(9) Uani 1 1 d . . .
C11 C 0.2882(5) 0.39330(18) 0.7690(4) 0.0240(10) Uani 1 1 d . . .
C12 C 0.3466(5) 0.25846(19) 0.6687(4) 0.0290(11) Uani 1 1 d . . .
H12 H 0.3904 0.2804 0.7213 0.035 Uiso 1 1 calc R . .
C13 C 0.3557(6) 0.2052(2) 0.6816(4) 0.0370(13) Uani 1 1 d . . .
H13 H 0.4062 0.1911 0.7421 0.044 Uiso 1 1 calc R . .
C14 C 0.2919(7) 0.1727(2) 0.6070(5) 0.0445(14) Uani 1 1 d . . .
H14 H 0.2985 0.1361 0.6146 0.053 Uiso 1 1 calc R . .
C15 C 0.2184(7) 0.1944(2) 0.5213(5) 0.0414(13) Uani 1 1 d . . .
H15 H 0.1725 0.1727 0.4693 0.050 Uiso 1 1 calc R . .
C16 C 0.2110(5) 0.24803(18) 0.5103(4) 0.0280(11) Uani 1 1 d . . .
C17 C 0.1392(5) 0.27475(18) 0.4212(4) 0.0274(10) Uani 1 1 d . . .
C18 C 0.0568(6) 0.2507(2) 0.3406(4) 0.0360(12) Uani 1 1 d . . .
H18 H 0.0439 0.2142 0.3419 0.043 Uiso 1 1 calc R . .
C19 C -0.0060(6) 0.2794(2) 0.2593(4) 0.0392(13) Uani 1 1 d . . .
H19 H -0.0634 0.2633 0.2048 0.047 Uiso 1 1 calc R . .
C20 C 0.0164(6) 0.3326(2) 0.2587(4) 0.0327(11) Uani 1 1 d . . .
H20 H -0.0238 0.3534 0.2027 0.039 Uiso 1 1 calc R . .
C21 C 0.0980(5) 0.35491(19) 0.3406(4) 0.0264(10) Uani 1 1 d . . .
H21 H 0.1117 0.3914 0.3397 0.032 Uiso 1 1 calc R . .
C22 C 0.5356(5) 0.3183(2) 0.4520(4) 0.0305(11) Uani 1 1 d . . .
H22 H 0.5255 0.2884 0.4948 0.037 Uiso 1 1 calc R . .
C23 C 0.6424(6) 0.3195(2) 0.3834(5) 0.0389(13) Uani 1 1 d . . .
H23 H 0.7061 0.2913 0.3809 0.047 Uiso 1 1 calc R . .
C24 C 0.6562(6) 0.3621(2) 0.3183(5) 0.0436(14) Uani 1 1 d . . .
H24 H 0.7262 0.3630 0.2681 0.052 Uiso 1 1 calc R . .
C25 C 0.5663(6) 0.4032(2) 0.3280(4) 0.0373(13) Uani 1 1 d . . .
H25 H 0.5747 0.4330 0.2846 0.045 Uiso 1 1 calc R . .
C26 C 0.4634(5) 0.40135(19) 0.4007(4) 0.0263(10) Uani 1 1 d . . .
C27 C 0.3707(5) 0.44456(18) 0.4234(4) 0.0269(10) Uani 1 1 d . . .
C28 C 0.3799(6) 0.4941(2) 0.3805(5) 0.0364(12) Uani 1 1 d . . .
H28 H 0.4450 0.5010 0.3283 0.044 Uiso 1 1 calc R . .
C29 C 0.2936(6) 0.5333(2) 0.4144(5) 0.0392(13) Uani 1 1 d . . .
H29 H 0.2990 0.5674 0.3862 0.047 Uiso 1 1 calc R . .
C30 C 0.1998(6) 0.52177(19) 0.4900(4) 0.0329(12) Uani 1 1 d . . .
H30 H 0.1412 0.5482 0.5155 0.039 Uiso 1 1 calc R . .
C31 C 0.1913(5) 0.47193(18) 0.5284(4) 0.0269(10) Uani 1 1 d . . .
H31 H 0.1251 0.4646 0.5795 0.032 Uiso 1 1 calc R . .
O7 O 0.6335(4) 0.33039(16) 0.7330(4) 0.0466(10) Uani 1 1 d . . .
N1 N 0.1032(4) 0.36583(14) 0.6420(3) 0.0204(8) Uani 1 1 d . . .
N2 N -0.0947(4) 0.37185(15) 0.7276(3) 0.0240(8) Uani 1 1 d . . .
N3 N 0.0930(4) 0.42677(14) 0.9655(3) 0.0215(8) Uani 1 1 d . . .
H3 H 0.1823 0.4285 0.9524 0.026 Uiso 1 1 calc R . .
N4 N -0.1356(4) 0.40996(15) 0.9412(3) 0.0244(8) Uani 1 1 d . . .
N5 N 0.2767(4) 0.28030(14) 0.5830(3) 0.0212(8) Uani 1 1 d . . .
N6 N 0.1588(4) 0.32745(14) 0.4213(3) 0.0219(8) Uani 1 1 d . . .
N7 N 0.2740(4) 0.43292(14) 0.4961(3) 0.0216(8) Uani 1 1 d . . .
N8 N 0.4449(4) 0.35783(15) 0.4605(3) 0.0241(8) Uani 1 1 d . . .
O1 O 0.3687(3) 0.38299(13) 0.6932(3) 0.0264(7) Uani 1 1 d . . .
O2 O 0.3347(3) 0.40846(15) 0.8582(3) 0.0342(8) Uani 1 1 d . . .
O3 O 0.4227(5) 0.05213(17) 0.5799(4) 0.0527(11) Uani 1 1 d . . .
O4 O 0.3988(4) 0.54905(16) 0.1421(4) 0.0575(12) Uani 1 1 d . . .
O5A O 0.5355(11) 0.1921(4) 0.4361(9) 0.055(4) Uani 0.466(17) 1 d P A 1
O5B O 0.678(2) 0.1859(6) 0.4493(11) 0.155(10) Uani 0.534(17) 1 d P A 2
O6 O -0.2728(10) 0.2618(4) 0.1151(9) 0.187(5) Uani 1 1 d . . .
Os1 Os 0.270749(18) 0.357691(6) 0.547504(13) 0.01895(7) Uani 1 1 d . . .
H1 H -0.082(5) 0.3444(18) 0.574(4) 0.016(11) Uiso 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.328(6) . ?
C1 N2 1.342(6) . ?
C1 H1 0.97(5) . ?
C2 N2 1.351(6) . ?
C2 C10 1.402(6) . ?
C2 C3 1.457(6) . ?
C3 N4 1.324(6) . ?
C3 N3 1.354(6) . ?
C4 N4 1.392(6) . ?
C4 C5 1.398(6) . ?
C4 C9 1.397(7) . ?
C5 C6 1.386(7) . ?
C5 H5 0.9500 . ?
C6 C7 1.390(7) . ?
C6 H6 0.9500 . ?
C7 C8 1.388(7) . ?
C7 H7 0.9500 . ?
C8 C9 1.396(7) . ?
C8 H8 0.9500 . ?
C9 N3 1.380(6) . ?
C10 N1 1.384(6) . ?
C10 C11 1.467(6) . ?
C11 O2 1.248(6) . ?
C11 O1 1.291(6) . ?
C12 N5 1.358(6) . ?
C12 C13 1.384(7) . ?
C12 H12 0.9500 . ?
C13 C14 1.377(8) . ?
C13 H13 0.9500 . ?
C14 C15 1.373(8) . ?
C14 H14 0.9500 . ?
C15 C16 1.391(7) . ?
C15 H15 0.9500 . ?
C16 N5 1.364(6) . ?
C16 C17 1.455(7) . ?
C17 N6 1.372(6) . ?
C17 C18 1.394(7) . ?
C18 C19 1.373(8) . ?
C18 H18 0.9500 . ?
C19 C20 1.388(8) . ?
C19 H19 0.9500 . ?
C20 C21 1.382(7) . ?
C20 H20 0.9500 . ?
C21 N6 1.344(6) . ?
C21 H21 0.9500 . ?
C22 N8 1.347(6) . ?
C22 C23 1.378(7) . ?
C22 H22 0.9500 . ?
C23 C24 1.385(8) . ?
C23 H23 0.9500 . ?
C24 C25 1.373(8) . ?
C24 H24 0.9500 . ?
C25 C26 1.387(7) . ?
C25 H25 0.9500 . ?
C26 N8 1.370(6) . ?
C26 C27 1.462(7) . ?
C27 N7 1.375(6) . ?
C27 C28 1.392(7) . ?
C28 C29 1.389(8) . ?
C28 H28 0.9500 . ?
C29 C30 1.381(8) . ?
C29 H29 0.9500 . ?
C30 C31 1.378(7) . ?
C30 H30 0.9500 . ?
C31 N7 1.357(6) . ?
C31 H31 0.9500 . ?
N1 Os1 2.064(4) . ?
N3 H3 0.8800 . ?
N5 Os1 2.045(4) . ?
N6 Os1 2.021(4) . ?
N7 Os1 2.046(4) . ?
N8 Os1 2.048(4) . ?
O1 Os1 2.117(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 N2 114.0(4) . . ?
N1 C1 H1 119(3) . . ?
N2 C1 H1 127(3) . . ?
N2 C2 C10 109.4(4) . . ?
N2 C2 C3 121.2(4) . . ?
C10 C2 C3 129.3(4) . . ?
N4 C3 N3 112.6(4) . . ?
N4 C3 C2 125.0(4) . . ?
N3 C3 C2 122.3(4) . . ?
N4 C4 C5 129.4(4) . . ?
N4 C4 C9 109.9(4) . . ?
C5 C4 C9 120.7(4) . . ?
C6 C5 C4 116.7(4) . . ?
C6 C5 H5 121.7 . . ?
C4 C5 H5 121.7 . . ?
C5 C6 C7 122.4(4) . . ?
C5 C6 H6 118.8 . . ?
C7 C6 H6 118.8 . . ?
C8 C7 C6 121.5(5) . . ?
C8 C7 H7 119.3 . . ?
C6 C7 H7 119.3 . . ?
C7 C8 C9 116.4(4) . . ?
C7 C8 H8 121.8 . . ?
C9 C8 H8 121.8 . . ?
N3 C9 C8 132.6(4) . . ?
N3 C9 C4 105.1(4) . . ?
C8 C9 C4 122.3(4) . . ?
N1 C10 C2 106.3(4) . . ?
N1 C10 C11 116.1(4) . . ?
C2 C10 C11 137.6(4) . . ?
O2 C11 O1 122.6(4) . . ?
O2 C11 C10 122.7(4) . . ?
O1 C11 C10 114.7(4) . . ?
N5 C12 C13 122.0(5) . . ?
N5 C12 H12 119.0 . . ?
C13 C12 H12 119.0 . . ?
C14 C13 C12 120.1(5) . . ?
C14 C13 H13 119.9 . . ?
C12 C13 H13 119.9 . . ?
C15 C14 C13 118.4(5) . . ?
C15 C14 H14 120.8 . . ?
C13 C14 H14 120.8 . . ?
C14 C15 C16 120.3(5) . . ?
C14 C15 H15 119.9 . . ?
C16 C15 H15 119.9 . . ?
N5 C16 C15 121.4(5) . . ?
N5 C16 C17 114.1(4) . . ?
C15 C16 C17 124.5(5) . . ?
N6 C17 C18 120.8(5) . . ?
N6 C17 C16 114.2(4) . . ?
C18 C17 C16 125.0(4) . . ?
C19 C18 C17 120.5(5) . . ?
C19 C18 H18 119.7 . . ?
C17 C18 H18 119.7 . . ?
C18 C19 C20 118.4(5) . . ?
C18 C19 H19 120.8 . . ?
C20 C19 H19 120.8 . . ?
C21 C20 C19 119.2(5) . . ?
C21 C20 H20 120.4 . . ?
C19 C20 H20 120.4 . . ?
N6 C21 C20 123.1(5) . . ?
N6 C21 H21 118.4 . . ?
C20 C21 H21 118.4 . . ?
N8 C22 C23 122.5(5) . . ?
N8 C22 H22 118.7 . . ?
C23 C22 H22 118.7 . . ?
C24 C23 C22 119.5(5) . . ?
C24 C23 H23 120.3 . . ?
C22 C23 H23 120.3 . . ?
C25 C24 C23 118.5(5) . . ?
C25 C24 H24 120.7 . . ?
C23 C24 H24 120.7 . . ?
C24 C25 C26 120.3(5) . . ?
C24 C25 H25 119.8 . . ?
C26 C25 H25 119.8 . . ?
N8 C26 C25 120.9(5) . . ?
N8 C26 C27 114.6(4) . . ?
C25 C26 C27 124.4(5) . . ?
N7 C27 C28 121.4(5) . . ?
N7 C27 C26 113.8(4) . . ?
C28 C27 C26 124.7(5) . . ?
C29 C28 C27 119.7(5) . . ?
C29 C28 H28 120.1 . . ?
C27 C28 H28 120.1 . . ?
C30 C29 C28 118.5(5) . . ?
C30 C29 H29 120.7 . . ?
C28 C29 H29 120.7 . . ?
C29 C30 C31 120.0(5) . . ?
C29 C30 H30 120.0 . . ?
C31 C30 H30 120.0 . . ?
N7 C31 C30 122.6(5) . . ?
N7 C31 H31 118.7 . . ?
C30 C31 H31 118.7 . . ?
C1 N1 C10 105.6(4) . . ?
C1 N1 Os1 140.0(3) . . ?
C10 N1 Os1 114.4(3) . . ?
C1 N2 C2 104.8(4) . . ?
C3 N3 C9 107.6(4) . . ?
C3 N3 H3 126.2 . . ?
C9 N3 H3 126.2 . . ?
C3 N4 C4 104.8(4) . . ?
C12 N5 C16 117.9(4) . . ?
C12 N5 Os1 125.8(3) . . ?
C16 N5 Os1 116.2(3) . . ?
C21 N6 C17 117.9(4) . . ?
C21 N6 Os1 125.4(3) . . ?
C17 N6 Os1 116.7(3) . . ?
C31 N7 C27 117.8(4) . . ?
C31 N7 Os1 126.0(3) . . ?
C27 N7 Os1 116.3(3) . . ?
C22 N8 C26 118.1(4) . . ?
C22 N8 Os1 126.1(3) . . ?
C26 N8 Os1 115.7(3) . . ?
C11 O1 Os1 117.1(3) . . ?
N6 Os1 N5 78.64(15) . . ?
N6 Os1 N8 89.21(15) . . ?
N5 Os1 N8 96.11(15) . . ?
N6 Os1 N7 97.65(15) . . ?
N5 Os1 N7 173.55(14) . . ?
N8 Os1 N7 78.47(15) . . ?
N6 Os1 N1 95.92(15) . . ?
N5 Os1 N1 89.13(14) . . ?
N8 Os1 N1 173.31(15) . . ?
N7 Os1 N1 96.55(14) . . ?
N6 Os1 O1 171.69(14) . . ?
N5 Os1 O1 96.02(14) . . ?
N8 Os1 O1 97.75(14) . . ?
N7 Os1 O1 88.23(14) . . ?
N1 Os1 O1 77.49(13) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 C2 C3 N4 2.0(7) . . . . ?
C10 C2 C3 N4 179.7(5) . . . . ?
N2 C2 C3 N3 -177.3(4) . . . . ?
C10 C2 C3 N3 0.4(7) . . . . ?
N4 C4 C5 C6 -178.4(5) . . . . ?
C9 C4 C5 C6 0.8(7) . . . . ?
C4 C5 C6 C7 -1.8(7) . . . . ?
C5 C6 C7 C8 1.7(8) . . . . ?
C6 C7 C8 C9 -0.5(7) . . . . ?
C7 C8 C9 N3 178.1(5) . . . . ?
C7 C8 C9 C4 -0.4(7) . . . . ?
N4 C4 C9 N3 0.7(5) . . . . ?
C5 C4 C9 N3 -178.6(4) . . . . ?
N4 C4 C9 C8 179.6(4) . . . . ?
C5 C4 C9 C8 0.2(7) . . . . ?
N2 C2 C10 N1 0.4(5) . . . . ?
C3 C2 C10 N1 -177.5(4) . . . . ?
N2 C2 C10 C11 -175.6(5) . . . . ?
C3 C2 C10 C11 6.5(9) . . . . ?
N1 C10 C11 O2 -177.1(4) . . . . ?
C2 C10 C11 O2 -1.4(9) . . . . ?
N1 C10 C11 O1 1.9(6) . . . . ?
C2 C10 C11 O1 177.7(5) . . . . ?
N5 C12 C13 C14 -0.7(8) . . . . ?
C12 C13 C14 C15 -0.8(9) . . . . ?
C13 C14 C15 C16 0.8(9) . . . . ?
C14 C15 C16 N5 0.5(9) . . . . ?
C14 C15 C16 C17 178.3(5) . . . . ?
N5 C16 C17 N6 4.8(6) . . . . ?
C15 C16 C17 N6 -173.1(5) . . . . ?
N5 C16 C17 C18 -175.4(5) . . . . ?
C15 C16 C17 C18 6.7(8) . . . . ?
N6 C17 C18 C19 0.3(8) . . . . ?
C16 C17 C18 C19 -179.5(5) . . . . ?
C17 C18 C19 C20 1.0(8) . . . . ?
C18 C19 C20 C21 -1.5(8) . . . . ?
C19 C20 C21 N6 0.7(8) . . . . ?
N8 C22 C23 C24 -1.8(9) . . . . ?
C22 C23 C24 C25 3.1(9) . . . . ?
C23 C24 C25 C26 -0.7(9) . . . . ?
C24 C25 C26 N8 -3.2(8) . . . . ?
C24 C25 C26 C27 174.6(5) . . . . ?
N8 C26 C27 N7 -4.1(6) . . . . ?
C25 C26 C27 N7 178.0(5) . . . . ?
N8 C26 C27 C28 173.2(5) . . . . ?
C25 C26 C27 C28 -4.7(8) . . . . ?
N7 C27 C28 C29 2.4(8) . . . . ?
C26 C27 C28 C29 -174.7(5) . . . . ?
C27 C28 C29 C30 -0.3(8) . . . . ?
C28 C29 C30 C31 -1.4(8) . . . . ?
C29 C30 C31 N7 1.1(8) . . . . ?
N2 C1 N1 C10 1.3(5) . . . . ?
N2 C1 N1 Os1 -178.9(3) . . . . ?
C2 C10 N1 C1 -1.0(5) . . . . ?
C11 C10 N1 C1 176.1(4) . . . . ?
C2 C10 N1 Os1 179.2(3) . . . . ?
C11 C10 N1 Os1 -3.8(5) . . . . ?
N1 C1 N2 C2 -1.0(5) . . . . ?
C10 C2 N2 C1 0.3(5) . . . . ?
C3 C2 N2 C1 178.4(4) . . . . ?
N4 C3 N3 C9 -0.6(5) . . . . ?
C2 C3 N3 C9 178.8(4) . . . . ?
C8 C9 N3 C3 -178.8(5) . . . . ?
C4 C9 N3 C3 -0.1(5) . . . . ?
N3 C3 N4 C4 1.0(5) . . . . ?
C2 C3 N4 C4 -178.4(4) . . . . ?
C5 C4 N4 C3 178.2(5) . . . . ?
C9 C4 N4 C3 -1.1(5) . . . . ?
C13 C12 N5 C16 2.0(7) . . . . ?
C13 C12 N5 Os1 -173.9(4) . . . . ?
C15 C16 N5 C12 -1.9(7) . . . . ?
C17 C16 N5 C12 -179.9(4) . . . . ?
C15 C16 N5 Os1 174.4(4) . . . . ?
C17 C16 N5 Os1 -3.6(5) . . . . ?
C20 C21 N6 C17 0.6(7) . . . . ?
C20 C21 N6 Os1 -176.6(4) . . . . ?
C18 C17 N6 C21 -1.1(7) . . . . ?
C16 C17 N6 C21 178.8(4) . . . . ?
C18 C17 N6 Os1 176.3(4) . . . . ?
C16 C17 N6 Os1 -3.8(5) . . . . ?
C30 C31 N7 C27 1.0(7) . . . . ?
C30 C31 N7 Os1 180.0(4) . . . . ?
C28 C27 N7 C31 -2.7(7) . . . . ?
C26 C27 N7 C31 174.7(4) . . . . ?
C28 C27 N7 Os1 178.2(4) . . . . ?
C26 C27 N7 Os1 -4.4(5) . . . . ?
C23 C22 N8 C26 -2.0(8) . . . . ?
C23 C22 N8 Os1 173.3(4) . . . . ?
C25 C26 N8 C22 4.5(7) . . . . ?
C27 C26 N8 C22 -173.5(4) . . . . ?
C25 C26 N8 Os1 -171.3(4) . . . . ?
C27 C26 N8 Os1 10.7(5) . . . . ?
O2 C11 O1 Os1 180.0(4) . . . . ?
C10 C11 O1 Os1 0.9(5) . . . . ?
C21 N6 Os1 N5 178.7(4) . . . . ?
C17 N6 Os1 N5 1.5(3) . . . . ?
C21 N6 Os1 N8 -84.9(4) . . . . ?
C17 N6 Os1 N8 97.9(3) . . . . ?
C21 N6 Os1 N7 -6.7(4) . . . . ?
C17 N6 Os1 N7 176.1(3) . . . . ?
C21 N6 Os1 N1 90.8(4) . . . . ?
C17 N6 Os1 N1 -86.4(3) . . . . ?
C21 N6 Os1 O1 128.1(9) . . . . ?
C17 N6 Os1 O1 -49.1(11) . . . . ?
C12 N5 Os1 N6 177.2(4) . . . . ?
C16 N5 Os1 N6 1.3(3) . . . . ?
C12 N5 Os1 N8 89.3(4) . . . . ?
C16 N5 Os1 N8 -86.7(3) . . . . ?
C12 N5 Os1 N7 121.8(13) . . . . ?
C16 N5 Os1 N7 -54.1(14) . . . . ?
C12 N5 Os1 N1 -86.5(4) . . . . ?
C16 N5 Os1 N1 97.5(3) . . . . ?
C12 N5 Os1 O1 -9.2(4) . . . . ?
C16 N5 Os1 O1 174.8(3) . . . . ?
C22 N8 Os1 N6 -87.5(4) . . . . ?
C26 N8 Os1 N6 87.9(3) . . . . ?
C22 N8 Os1 N5 -9.0(4) . . . . ?
C26 N8 Os1 N5 166.4(3) . . . . ?
C22 N8 Os1 N7 174.5(4) . . . . ?
C26 N8 Os1 N7 -10.1(3) . . . . ?
C22 N8 Os1 N1 132.3(12) . . . . ?
C26 N8 Os1 N1 -52.3(14) . . . . ?
C22 N8 Os1 O1 87.9(4) . . . . ?
C26 N8 Os1 O1 -96.6(3) . . . . ?
C31 N7 Os1 N6 101.1(4) . . . . ?
C27 N7 Os1 N6 -79.8(3) . . . . ?
C31 N7 Os1 N5 155.7(12) . . . . ?
C27 N7 Os1 N5 -25.3(15) . . . . ?
C31 N7 Os1 N8 -171.2(4) . . . . ?
C27 N7 Os1 N8 7.8(3) . . . . ?
C31 N7 Os1 N1 4.2(4) . . . . ?
C27 N7 Os1 N1 -176.7(3) . . . . ?
C31 N7 Os1 O1 -73.0(4) . . . . ?
C27 N7 Os1 O1 106.1(3) . . . . ?
C1 N1 Os1 N6 -1.8(5) . . . . ?
C10 N1 Os1 N6 178.0(3) . . . . ?
C1 N1 Os1 N5 -80.2(5) . . . . ?
C10 N1 Os1 N5 99.6(3) . . . . ?
C1 N1 Os1 N8 138.2(12) . . . . ?
C10 N1 Os1 N8 -42.0(14) . . . . ?
C1 N1 Os1 N7 96.7(5) . . . . ?
C10 N1 Os1 N7 -83.5(3) . . . . ?
C1 N1 Os1 O1 -176.6(5) . . . . ?
C10 N1 Os1 O1 3.2(3) . . . . ?
C11 O1 Os1 N6 -40.4(11) . . . . ?
C11 O1 Os1 N5 -90.0(3) . . . . ?
C11 O1 Os1 N8 172.9(3) . . . . ?
C11 O1 Os1 N7 94.8(3) . . . . ?
C11 O1 Os1 N1 -2.3(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         1.212
_refine_diff_density_min         -1.420
_refine_diff_density_rms         0.094
