# Electronic Supplementary Material (ESI) for Chemical Science # This journal is © The Royal Society of Chemistry 2012 data_publication_text _journal_name_full 'Chemical Science' _journal_coden_cambridge 1475 _publ_contact_author_name 'Zhang-Jie Shi' _publ_contact_author_address ; College of Chemistry, Peking University,Beijing 100871,China ; _publ_contact_author_email 'zshi@pku.edu.cn, whwang@pku.edu.cn' loop_ _publ_author_address ; College of Chemistry, Peking University,Beijing 100871,China ; ; College of Chemistry, Peking University,Beijing 100871,China ; loop_ _publ_author_name 'Zhang-Jie Shi' 'Yang Li' 'Hu Li' 'Wen-Hua Wang' 'Xi-Sha Zhang' 'Kang Chen' 'Bi-Jie Li' data_3 _database_code_depnum_ccdc_archive 'CCDC 793687' #TrackingRef '3.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety '2(C23 H26 N2 Rh), 2(F6 Sb), C H2 Cl2' _chemical_formula_sum 'C47 H54 Cl2 F12 N4 Rh2 Sb2' _chemical_formula_weight 1423.16 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M P2(1)/c loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 24.200(3) _cell_length_b 13.4270(16) _cell_length_c 16.2572(19) _cell_angle_alpha 90.00 _cell_angle_beta 95.747(2) _cell_angle_gamma 90.00 _cell_volume 5256.0(11) _cell_formula_units_Z 4 _cell_measurement_temperature 173(2) _cell_measurement_reflns_used 678 _cell_measurement_theta_min 2.17 _cell_measurement_theta_max 27.48 _exptl_crystal_description plate _exptl_crystal_colour yellow _exptl_crystal_size_max 0.18 _exptl_crystal_size_mid 0.15 _exptl_crystal_size_min 0.10 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.799 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 2792 _exptl_absorpt_coefficient_mu 1.815 _exptl_absorpt_correction_type numerical _exptl_absorpt_correction_T_min 0.7359 _exptl_absorpt_correction_T_max 0.8394 _exptl_absorpt_process_details 'CrystalClear (Rigaku Inc., 2007)' _exptl_special_details ; ? ; _diffrn_ambient_temperature 173(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'rotating anode' _diffrn_radiation_monochromator Confocal _diffrn_measurement_device_type 'MM007-HF CCD(Saturn 724+)' _diffrn_measurement_method '\w scans at fixed \c = 45\%' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 42401 _diffrn_reflns_av_R_equivalents 0.0399 _diffrn_reflns_av_sigmaI/netI 0.0378 _diffrn_reflns_limit_h_min -30 _diffrn_reflns_limit_h_max 31 _diffrn_reflns_limit_k_min -17 _diffrn_reflns_limit_k_max 16 _diffrn_reflns_limit_l_min -20 _diffrn_reflns_limit_l_max 20 _diffrn_reflns_theta_min 1.69 _diffrn_reflns_theta_max 27.47 _reflns_number_total 11879 _reflns_number_gt 11106 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'CrystalClear (Rigaku Inc., 2007)' _computing_cell_refinement 'CrystalClear (Rigaku Inc., 2007)' _computing_data_reduction 'CrystalClear (Rigaku Inc., 2007)' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'XP in Siemens SHELXTL (Sheldrick, 1994)' _computing_publication_material 'SHELX97 (Sheldrick, 1997)' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0650P)^2^+22.8329P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 11879 _refine_ls_number_parameters 633 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0684 _refine_ls_R_factor_gt 0.0636 _refine_ls_wR_factor_ref 0.1565 _refine_ls_wR_factor_gt 0.1524 _refine_ls_goodness_of_fit_ref 1.092 _refine_ls_restrained_S_all 1.092 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Rh1 Rh 0.128719(17) 0.19709(3) 0.32105(3) 0.03479(12) Uani 1 1 d . . . Rh2 Rh 0.397769(16) -0.24351(3) 0.21492(2) 0.02960(11) Uani 1 1 d . . . Sb1 Sb 0.358990(19) 0.20178(4) 0.00054(3) 0.05425(14) Uani 1 1 d . . . Sb2 Sb 0.188021(19) -0.10333(4) 0.64233(3) 0.05491(14) Uani 1 1 d . . . Cl1 Cl 0.12615(14) -0.1773(3) 0.8878(3) 0.1289(13) Uani 1 1 d . . . Cl2 Cl 0.03976(10) -0.2867(2) 0.95290(18) 0.0922(7) Uani 1 1 d . . . F1 F 0.3742(4) 0.0721(5) -0.0207(7) 0.170(4) Uani 1 1 d . . . F2 F 0.2852(2) 0.1705(6) 0.0077(4) 0.129(3) Uani 1 1 d . . . F3 F 0.3749(2) 0.1822(5) 0.1142(3) 0.102(2) Uani 1 1 d . . . F4 F 0.3416(2) 0.2300(5) -0.1119(3) 0.0938(17) Uani 1 1 d . . . F5 F 0.3419(3) 0.3340(5) 0.0221(4) 0.1038(19) Uani 1 1 d . . . F6 F 0.43172(19) 0.2380(4) -0.0071(4) 0.0860(15) Uani 1 1 d . . . F7 F 0.1144(4) -0.1044(13) 0.6265(10) 0.291(9) Uani 1 1 d . . . F8 F 0.1825(6) -0.0052(9) 0.5673(6) 0.264(8) Uani 1 1 d . . . F9 F 0.1974(7) -0.2024(5) 0.7145(6) 0.259(8) Uani 1 1 d . . . F10 F 0.2622(3) -0.0919(7) 0.6495(7) 0.181(4) Uani 1 1 d . . . F11 F 0.1956(4) -0.1929(6) 0.5565(5) 0.158(4) Uani 1 1 d . . . F12 F 0.1852(3) -0.0132(5) 0.7285(4) 0.118(2) Uani 1 1 d . . . N1 N 0.18364(19) 0.0783(3) 0.3465(3) 0.0361(10) Uani 1 1 d . . . N2 N 0.1904(2) 0.2580(3) 0.2569(3) 0.0377(10) Uani 1 1 d . . . N3 N 0.33428(19) -0.1395(3) 0.1810(3) 0.0369(10) Uani 1 1 d . . . N4 N 0.34886(19) -0.3043(3) 0.2999(3) 0.0360(10) Uani 1 1 d . . . C1 C 0.1050(2) 0.1029(4) 0.2260(4) 0.0406(12) Uani 1 1 d . . . C2 C 0.0675(3) 0.1226(5) 0.1567(4) 0.0509(15) Uani 1 1 d . . . H2A H 0.0517 0.1871 0.1492 0.061 Uiso 1 1 calc R . . C3 C 0.0533(3) 0.0485(7) 0.0990(5) 0.064(2) Uani 1 1 d . . . H3A H 0.0277 0.0630 0.0524 0.077 Uiso 1 1 calc R . . C4 C 0.0758(3) -0.0461(6) 0.1081(5) 0.0630(19) Uani 1 1 d . . . H4A H 0.0648 -0.0965 0.0688 0.076 Uiso 1 1 calc R . . C5 C 0.1143(3) -0.0670(5) 0.1745(4) 0.0548(16) Uani 1 1 d . . . H5A H 0.1305 -0.1314 0.1804 0.066 Uiso 1 1 calc R . . C6 C 0.1293(2) 0.0074(4) 0.2334(4) 0.0408(12) Uani 1 1 d . . . C7 C 0.1740(2) -0.0044(4) 0.3003(3) 0.0366(11) Uani 1 1 d . . . C8 C 0.2081(3) -0.0879(4) 0.3145(4) 0.0453(13) Uani 1 1 d . . . H8A H 0.2010 -0.1469 0.2830 0.054 Uiso 1 1 calc R . . C9 C 0.2522(3) -0.0834(5) 0.3746(4) 0.0513(15) Uani 1 1 d . . . H9A H 0.2749 -0.1404 0.3862 0.062 Uiso 1 1 calc R . . C10 C 0.2635(3) 0.0030(5) 0.4179(4) 0.0484(14) Uani 1 1 d . . . H10A H 0.2950 0.0077 0.4576 0.058 Uiso 1 1 calc R . . C11 C 0.2280(2) 0.0834(5) 0.4023(4) 0.0427(13) Uani 1 1 d . . . H11A H 0.2353 0.1436 0.4321 0.051 Uiso 1 1 calc R . . C12 C 0.0733(3) 0.1780(5) 0.4133(5) 0.0549(18) Uani 1 1 d . . . C13 C 0.0440(3) 0.2301(5) 0.3459(5) 0.0491(15) Uani 1 1 d . . . C14 C 0.0722(3) 0.3202(4) 0.3352(4) 0.0461(14) Uani 1 1 d . . . C15 C 0.1162(3) 0.3283(5) 0.4017(4) 0.0470(14) Uani 1 1 d . . . C16 C 0.1161(3) 0.2431(5) 0.4508(4) 0.0507(16) Uani 1 1 d . . . C17 C 0.0574(4) 0.0775(6) 0.4452(7) 0.088(3) Uani 1 1 d . . . H17A H 0.0371 0.0865 0.4939 0.132 Uiso 1 1 calc R . . H17B H 0.0911 0.0384 0.4605 0.132 Uiso 1 1 calc R . . H17C H 0.0338 0.0425 0.4021 0.132 Uiso 1 1 calc R . . C18 C -0.0088(3) 0.1976(7) 0.2975(6) 0.075(2) Uani 1 1 d . . . H18A H -0.0406 0.2198 0.3257 0.112 Uiso 1 1 calc R . . H18B H -0.0093 0.1248 0.2931 0.112 Uiso 1 1 calc R . . H18C H -0.0111 0.2269 0.2420 0.112 Uiso 1 1 calc R . . C19 C 0.0563(3) 0.3994(6) 0.2721(5) 0.064(2) Uani 1 1 d . . . H19A H 0.0380 0.4544 0.2984 0.096 Uiso 1 1 calc R . . H19B H 0.0308 0.3714 0.2275 0.096 Uiso 1 1 calc R . . H19C H 0.0897 0.4242 0.2494 0.096 Uiso 1 1 calc R . . C20 C 0.1548(3) 0.4161(6) 0.4173(6) 0.069(2) Uani 1 1 d . . . H20A H 0.1370 0.4670 0.4487 0.104 Uiso 1 1 calc R . . H20B H 0.1633 0.4441 0.3643 0.104 Uiso 1 1 calc R . . H20C H 0.1893 0.3941 0.4488 0.104 Uiso 1 1 calc R . . C21 C 0.1529(4) 0.2224(8) 0.5287(5) 0.084(3) Uani 1 1 d . . . H21A H 0.1348 0.2460 0.5764 0.126 Uiso 1 1 calc R . . H21B H 0.1884 0.2570 0.5268 0.126 Uiso 1 1 calc R . . H21C H 0.1595 0.1505 0.5339 0.126 Uiso 1 1 calc R . . C22 C 0.2780(3) 0.3297(6) 0.2011(5) 0.0597(18) Uani 1 1 d . . . H22A H 0.3044 0.3505 0.2476 0.090 Uiso 1 1 calc R . . H22B H 0.2680 0.3871 0.1655 0.090 Uiso 1 1 calc R . . H22C H 0.2951 0.2783 0.1691 0.090 Uiso 1 1 calc R . . C23 C 0.2285(3) 0.2899(4) 0.2322(4) 0.0423(13) Uani 1 1 d . . . C24 C 0.4188(2) -0.1302(4) 0.2947(3) 0.0364(11) Uani 1 1 d . . . C25 C 0.4627(3) -0.1311(5) 0.3568(4) 0.0436(13) Uani 1 1 d . . . H25A H 0.4847 -0.1894 0.3666 0.052 Uiso 1 1 calc R . . C26 C 0.4742(3) -0.0462(5) 0.4045(4) 0.0551(17) Uani 1 1 d . . . H26A H 0.5049 -0.0466 0.4458 0.066 Uiso 1 1 calc R . . C27 C 0.4425(3) 0.0375(5) 0.3933(4) 0.0564(18) Uani 1 1 d . . . H27A H 0.4512 0.0946 0.4266 0.068 Uiso 1 1 calc R . . C28 C 0.3976(3) 0.0395(4) 0.3335(4) 0.0517(16) Uani 1 1 d . . . H28A H 0.3749 0.0972 0.3263 0.062 Uiso 1 1 calc R . . C29 C 0.3859(2) -0.0446(4) 0.2834(4) 0.0394(12) Uani 1 1 d . . . C30 C 0.3395(2) -0.0501(4) 0.2200(4) 0.0380(12) Uani 1 1 d . . . C31 C 0.3007(3) 0.0245(5) 0.1990(4) 0.0504(16) Uani 1 1 d . . . H31A H 0.3047 0.0875 0.2255 0.060 Uiso 1 1 calc R . . C32 C 0.2570(3) 0.0080(5) 0.1407(5) 0.0589(19) Uani 1 1 d . . . H32A H 0.2310 0.0595 0.1260 0.071 Uiso 1 1 calc R . . C33 C 0.2511(3) -0.0845(5) 0.1032(4) 0.0520(16) Uani 1 1 d . . . H33A H 0.2206 -0.0984 0.0633 0.062 Uiso 1 1 calc R . . C34 C 0.2908(2) -0.1557(5) 0.1255(3) 0.0406(12) Uani 1 1 d . . . H34A H 0.2870 -0.2194 0.1002 0.049 Uiso 1 1 calc R . . C35 C 0.4824(2) -0.2627(4) 0.1815(3) 0.0322(10) Uani 1 1 d . . . C36 C 0.4631(2) -0.3532(4) 0.2147(3) 0.0338(11) Uani 1 1 d . . . C37 C 0.4170(2) -0.3904(4) 0.1584(3) 0.0352(11) Uani 1 1 d . . . C38 C 0.4062(2) -0.3218(4) 0.0945(3) 0.0356(11) Uani 1 1 d . . . C39 C 0.4450(2) -0.2389(4) 0.1104(3) 0.0345(11) Uani 1 1 d . . . C40 C 0.5339(2) -0.2076(4) 0.2111(4) 0.0422(13) Uani 1 1 d . . . H40A H 0.5621 -0.2188 0.1728 0.063 Uiso 1 1 calc R . . H40B H 0.5478 -0.2315 0.2662 0.063 Uiso 1 1 calc R . . H40C H 0.5257 -0.1363 0.2136 0.063 Uiso 1 1 calc R . . C41 C 0.4890(3) -0.4086(4) 0.2892(4) 0.0441(13) Uani 1 1 d . . . H41A H 0.5118 -0.4632 0.2713 0.066 Uiso 1 1 calc R . . H41B H 0.4597 -0.4356 0.3202 0.066 Uiso 1 1 calc R . . H41C H 0.5123 -0.3630 0.3246 0.066 Uiso 1 1 calc R . . C42 C 0.3880(3) -0.4871(4) 0.1682(4) 0.0488(15) Uani 1 1 d . . . H42A H 0.4067 -0.5398 0.1398 0.073 Uiso 1 1 calc R . . H42B H 0.3493 -0.4817 0.1443 0.073 Uiso 1 1 calc R . . H42C H 0.3890 -0.5034 0.2271 0.073 Uiso 1 1 calc R . . C43 C 0.3649(3) -0.3315(6) 0.0205(4) 0.0504(15) Uani 1 1 d . . . H43A H 0.3800 -0.3748 -0.0204 0.076 Uiso 1 1 calc R . . H43B H 0.3571 -0.2655 -0.0038 0.076 Uiso 1 1 calc R . . H43C H 0.3305 -0.3605 0.0369 0.076 Uiso 1 1 calc R . . C44 C 0.4497(3) -0.1503(5) 0.0549(4) 0.0478(14) Uani 1 1 d . . . H44A H 0.4716 -0.1684 0.0096 0.072 Uiso 1 1 calc R . . H44B H 0.4681 -0.0956 0.0869 0.072 Uiso 1 1 calc R . . H44C H 0.4125 -0.1292 0.0322 0.072 Uiso 1 1 calc R . . C45 C 0.2839(3) -0.4034(7) 0.3869(5) 0.070(2) Uani 1 1 d . . . H45A H 0.2566 -0.4398 0.3496 0.105 Uiso 1 1 calc R . . H45B H 0.2646 -0.3570 0.4206 0.105 Uiso 1 1 calc R . . H45C H 0.3055 -0.4507 0.4230 0.105 Uiso 1 1 calc R . . C46 C 0.3212(3) -0.3478(5) 0.3381(4) 0.0441(13) Uani 1 1 d . . . C47 C 0.1015(4) -0.2928(7) 0.9076(6) 0.075(2) Uani 1 1 d . . . H47A H 0.1296 -0.3289 0.9449 0.090 Uiso 1 1 calc R . . H47B H 0.0955 -0.3307 0.8552 0.090 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Rh1 0.0348(2) 0.0298(2) 0.0404(2) 0.00109(16) 0.00659(17) 0.00388(15) Rh2 0.0314(2) 0.02562(19) 0.0317(2) -0.00270(15) 0.00313(15) 0.00080(14) Sb1 0.0452(2) 0.0562(3) 0.0614(3) 0.0156(2) 0.0055(2) -0.00394(19) Sb2 0.0445(2) 0.0490(3) 0.0700(3) 0.0080(2) -0.0001(2) -0.00609(18) Cl1 0.106(2) 0.107(2) 0.174(3) 0.056(2) 0.020(2) -0.0274(18) Cl2 0.0677(13) 0.1003(18) 0.1089(19) 0.0253(15) 0.0109(13) -0.0039(12) F1 0.172(8) 0.051(3) 0.273(11) -0.033(5) -0.045(7) 0.015(4) F2 0.055(3) 0.195(7) 0.132(5) 0.091(5) -0.011(3) -0.038(4) F3 0.075(3) 0.154(6) 0.074(3) 0.050(4) -0.005(3) -0.009(3) F4 0.091(4) 0.135(5) 0.055(3) -0.002(3) 0.007(3) -0.013(3) F5 0.125(5) 0.087(4) 0.098(4) -0.007(3) 0.004(4) 0.040(4) F6 0.052(3) 0.109(4) 0.099(4) 0.013(3) 0.017(2) -0.010(3) F7 0.065(5) 0.44(2) 0.368(18) -0.148(17) 0.025(8) -0.052(9) F8 0.422(19) 0.211(10) 0.180(9) 0.133(8) 0.139(11) 0.215(12) F9 0.59(2) 0.053(4) 0.158(8) 0.041(4) 0.157(12) 0.015(8) F10 0.063(4) 0.178(8) 0.299(12) -0.113(8) 0.014(5) -0.001(4) F11 0.201(8) 0.146(7) 0.109(5) -0.059(5) -0.077(5) 0.051(6) F12 0.157(6) 0.086(4) 0.115(5) -0.017(4) 0.027(4) 0.039(4) N1 0.040(2) 0.032(2) 0.037(2) 0.0022(18) 0.0098(19) 0.0050(18) N2 0.041(3) 0.033(2) 0.040(3) 0.0025(19) 0.008(2) -0.0004(19) N3 0.038(2) 0.035(2) 0.039(2) 0.0034(19) 0.0086(19) 0.0084(19) N4 0.040(2) 0.031(2) 0.037(2) 0.0012(18) 0.0052(19) -0.0035(18) C1 0.034(3) 0.044(3) 0.044(3) -0.003(2) 0.006(2) -0.003(2) C2 0.038(3) 0.056(4) 0.058(4) -0.002(3) -0.001(3) 0.002(3) C3 0.044(4) 0.088(6) 0.058(4) -0.007(4) -0.009(3) -0.010(4) C4 0.057(4) 0.066(5) 0.066(5) -0.021(4) 0.003(3) -0.005(4) C5 0.049(4) 0.053(4) 0.064(4) -0.018(3) 0.012(3) -0.006(3) C6 0.037(3) 0.040(3) 0.047(3) -0.007(2) 0.011(2) 0.000(2) C7 0.038(3) 0.032(3) 0.041(3) 0.001(2) 0.013(2) 0.001(2) C8 0.051(3) 0.036(3) 0.051(3) 0.002(3) 0.016(3) 0.007(3) C9 0.058(4) 0.045(3) 0.052(4) 0.011(3) 0.014(3) 0.018(3) C10 0.052(3) 0.047(3) 0.046(3) 0.007(3) 0.001(3) 0.014(3) C11 0.042(3) 0.040(3) 0.046(3) 0.001(2) 0.002(2) 0.008(2) C12 0.060(4) 0.044(3) 0.067(4) 0.011(3) 0.041(4) 0.012(3) C13 0.037(3) 0.041(3) 0.072(4) -0.001(3) 0.022(3) 0.007(2) C14 0.044(3) 0.035(3) 0.061(4) 0.002(3) 0.017(3) 0.017(2) C15 0.047(3) 0.039(3) 0.057(4) -0.008(3) 0.014(3) 0.008(3) C16 0.062(4) 0.050(4) 0.044(3) -0.005(3) 0.024(3) 0.021(3) C17 0.107(7) 0.048(4) 0.122(8) 0.022(5) 0.073(6) 0.017(4) C18 0.034(3) 0.076(5) 0.116(7) -0.011(5) 0.013(4) -0.006(3) C19 0.059(4) 0.055(4) 0.079(5) 0.018(4) 0.011(4) 0.020(3) C20 0.060(4) 0.057(4) 0.092(6) -0.027(4) 0.011(4) 0.000(4) C21 0.107(7) 0.108(7) 0.040(4) -0.001(4) 0.014(4) 0.055(6) C22 0.050(4) 0.065(4) 0.067(4) 0.010(4) 0.023(3) -0.003(3) C23 0.052(3) 0.036(3) 0.038(3) 0.002(2) 0.005(3) 0.006(3) C24 0.044(3) 0.028(2) 0.039(3) -0.011(2) 0.015(2) -0.006(2) C25 0.051(3) 0.042(3) 0.038(3) -0.009(2) 0.007(2) -0.002(3) C26 0.062(4) 0.059(4) 0.046(3) -0.024(3) 0.013(3) -0.020(3) C27 0.076(5) 0.045(4) 0.052(4) -0.021(3) 0.025(3) -0.014(3) C28 0.069(4) 0.029(3) 0.062(4) -0.007(3) 0.030(3) -0.005(3) C29 0.050(3) 0.032(3) 0.040(3) -0.006(2) 0.021(2) -0.004(2) C30 0.041(3) 0.027(2) 0.049(3) 0.006(2) 0.017(2) 0.003(2) C31 0.058(4) 0.034(3) 0.064(4) 0.012(3) 0.027(3) 0.009(3) C32 0.055(4) 0.057(4) 0.069(4) 0.030(4) 0.027(3) 0.023(3) C33 0.046(3) 0.065(4) 0.045(3) 0.018(3) 0.006(3) 0.014(3) C34 0.041(3) 0.043(3) 0.038(3) 0.002(2) 0.006(2) 0.009(2) C35 0.028(2) 0.030(2) 0.039(3) -0.008(2) 0.009(2) 0.0021(19) C36 0.035(3) 0.028(2) 0.039(3) -0.004(2) 0.003(2) 0.010(2) C37 0.034(3) 0.028(2) 0.043(3) -0.008(2) 0.007(2) 0.002(2) C38 0.034(3) 0.037(3) 0.036(3) -0.012(2) 0.008(2) 0.001(2) C39 0.032(3) 0.037(3) 0.035(3) 0.000(2) 0.008(2) 0.003(2) C40 0.041(3) 0.040(3) 0.047(3) -0.005(2) 0.007(2) -0.002(2) C41 0.046(3) 0.036(3) 0.050(3) 0.001(2) 0.004(3) 0.009(2) C42 0.044(3) 0.031(3) 0.071(4) -0.012(3) 0.003(3) -0.001(2) C43 0.045(3) 0.066(4) 0.040(3) -0.014(3) 0.000(3) 0.003(3) C44 0.047(3) 0.049(3) 0.048(3) 0.006(3) 0.010(3) 0.004(3) C45 0.072(5) 0.082(6) 0.058(4) 0.008(4) 0.020(4) -0.028(4) C46 0.047(3) 0.045(3) 0.041(3) -0.002(3) 0.003(3) -0.002(3) C47 0.067(5) 0.069(5) 0.088(6) -0.008(4) 0.006(4) 0.015(4) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Rh1 C1 2.035(6) . ? Rh1 N2 2.072(5) . ? Rh1 N1 2.091(4) . ? Rh1 C12 2.125(6) . ? Rh1 C14 2.171(5) . ? Rh1 C13 2.176(6) . ? Rh1 C15 2.235(6) . ? Rh1 C16 2.248(6) . ? Rh2 C24 2.031(5) . ? Rh2 N4 2.074(5) . ? Rh2 N3 2.109(4) . ? Rh2 C39 2.142(5) . ? Rh2 C36 2.161(5) . ? Rh2 C35 2.187(5) . ? Rh2 C37 2.245(5) . ? Rh2 C38 2.249(5) . ? Sb1 F1 1.819(6) . ? Sb1 F6 1.842(5) . ? Sb1 F2 1.850(5) . ? Sb1 F5 1.864(6) . ? Sb1 F3 1.868(5) . ? Sb1 F4 1.873(5) . ? Sb2 F9 1.773(8) . ? Sb2 F7 1.774(9) . ? Sb2 F8 1.791(8) . ? Sb2 F10 1.793(7) . ? Sb2 F12 1.857(6) . ? Sb2 F11 1.866(7) . ? Cl1 C47 1.704(10) . ? Cl2 C47 1.733(9) . ? N1 C11 1.335(7) . ? N1 C7 1.348(7) . ? N2 C23 1.126(8) . ? N3 C34 1.334(7) . ? N3 C30 1.357(7) . ? N4 C46 1.121(7) . ? C1 C2 1.399(9) . ? C1 C6 1.411(8) . ? C2 C3 1.387(10) . ? C2 H2A 0.9500 . ? C3 C4 1.385(11) . ? C3 H3A 0.9500 . ? C4 C5 1.383(10) . ? C4 H4A 0.9500 . ? C5 C6 1.406(8) . ? C5 H5A 0.9500 . ? C6 C7 1.463(8) . ? C7 C8 1.397(8) . ? C8 C9 1.373(9) . ? C8 H8A 0.9500 . ? C9 C10 1.370(9) . ? C9 H9A 0.9500 . ? C10 C11 1.388(8) . ? C10 H10A 0.9500 . ? C11 H11A 0.9500 . ? C12 C13 1.427(10) . ? C12 C16 1.443(11) . ? C12 C17 1.509(10) . ? C13 C14 1.408(9) . ? C13 C18 1.497(10) . ? C14 C15 1.443(9) . ? C14 C19 1.502(9) . ? C15 C16 1.394(9) . ? C15 C20 1.511(10) . ? C16 C21 1.500(10) . ? C17 H17A 0.9800 . ? C17 H17B 0.9800 . ? C17 H17C 0.9800 . ? C18 H18A 0.9800 . ? C18 H18B 0.9800 . ? C18 H18C 0.9800 . ? C19 H19A 0.9800 . ? C19 H19B 0.9800 . ? C19 H19C 0.9800 . ? C20 H20A 0.9800 . ? C20 H20B 0.9800 . ? C20 H20C 0.9800 . ? C21 H21A 0.9800 . ? C21 H21B 0.9800 . ? C21 H21C 0.9800 . ? C22 C23 1.449(9) . ? C22 H22A 0.9800 . ? C22 H22B 0.9800 . ? C22 H22C 0.9800 . ? C24 C25 1.390(8) . ? C24 C29 1.400(8) . ? C25 C26 1.391(8) . ? C25 H25A 0.9500 . ? C26 C27 1.363(11) . ? C26 H26A 0.9500 . ? C27 C28 1.384(10) . ? C27 H27A 0.9500 . ? C28 C29 1.404(8) . ? C28 H28A 0.9500 . ? C29 C30 1.448(8) . ? C30 C31 1.390(8) . ? C31 C32 1.366(11) . ? C31 H31A 0.9500 . ? C32 C33 1.385(11) . ? C32 H32A 0.9500 . ? C33 C34 1.378(8) . ? C33 H33A 0.9500 . ? C34 H34A 0.9500 . ? C35 C36 1.428(7) . ? C35 C39 1.431(8) . ? C35 C40 1.486(7) . ? C36 C37 1.458(7) . ? C36 C41 1.503(8) . ? C37 C38 1.393(8) . ? C37 C42 1.492(8) . ? C38 C39 1.462(7) . ? C38 C43 1.492(8) . ? C39 C44 1.504(8) . ? C40 H40A 0.9800 . ? C40 H40B 0.9800 . ? C40 H40C 0.9800 . ? C41 H41A 0.9800 . ? C41 H41B 0.9800 . ? C41 H41C 0.9800 . ? C42 H42A 0.9800 . ? C42 H42B 0.9800 . ? C42 H42C 0.9800 . ? C43 H43A 0.9800 . ? C43 H43B 0.9800 . ? C43 H43C 0.9800 . ? C44 H44A 0.9800 . ? C44 H44B 0.9800 . ? C44 H44C 0.9800 . ? C45 C46 1.465(9) . ? C45 H45A 0.9800 . ? C45 H45B 0.9800 . ? C45 H45C 0.9800 . ? C47 H47A 0.9900 . ? C47 H47B 0.9900 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C1 Rh1 N2 91.5(2) . . ? C1 Rh1 N1 78.5(2) . . ? N2 Rh1 N1 85.72(18) . . ? C1 Rh1 C12 108.1(3) . . ? N2 Rh1 C12 160.0(2) . . ? N1 Rh1 C12 101.7(2) . . ? C1 Rh1 C14 114.9(2) . . ? N2 Rh1 C14 104.2(2) . . ? N1 Rh1 C14 162.6(2) . . ? C12 Rh1 C14 64.4(2) . . ? C1 Rh1 C13 93.9(2) . . ? N2 Rh1 C13 138.8(2) . . ? N1 Rh1 C13 135.3(2) . . ? C12 Rh1 C13 38.7(3) . . ? C14 Rh1 C13 37.8(2) . . ? C1 Rh1 C15 153.0(2) . . ? N2 Rh1 C15 97.5(2) . . ? N1 Rh1 C15 127.3(2) . . ? C12 Rh1 C15 63.2(3) . . ? C14 Rh1 C15 38.2(2) . . ? C13 Rh1 C15 62.9(2) . . ? C1 Rh1 C16 146.0(3) . . ? N2 Rh1 C16 122.4(2) . . ? N1 Rh1 C16 99.7(2) . . ? C12 Rh1 C16 38.4(3) . . ? C14 Rh1 C16 62.9(2) . . ? C13 Rh1 C16 63.3(3) . . ? C15 Rh1 C16 36.2(2) . . ? C24 Rh2 N4 89.6(2) . . ? C24 Rh2 N3 78.5(2) . . ? N4 Rh2 N3 89.16(18) . . ? C24 Rh2 C39 111.5(2) . . ? N4 Rh2 C39 157.69(19) . . ? N3 Rh2 C39 101.91(19) . . ? C24 Rh2 C36 112.0(2) . . ? N4 Rh2 C36 101.48(19) . . ? N3 Rh2 C36 164.83(19) . . ? C39 Rh2 C36 64.5(2) . . ? C24 Rh2 C35 93.8(2) . . ? N4 Rh2 C35 136.93(19) . . ? N3 Rh2 C35 133.57(19) . . ? C39 Rh2 C35 38.6(2) . . ? C36 Rh2 C35 38.4(2) . . ? C24 Rh2 C37 150.6(2) . . ? N4 Rh2 C37 94.73(19) . . ? N3 Rh2 C37 130.60(19) . . ? C39 Rh2 C37 63.3(2) . . ? C36 Rh2 C37 38.60(19) . . ? C35 Rh2 C37 63.71(19) . . ? C24 Rh2 C38 150.1(2) . . ? N4 Rh2 C38 120.22(19) . . ? N3 Rh2 C38 102.09(19) . . ? C39 Rh2 C38 38.8(2) . . ? C36 Rh2 C38 63.2(2) . . ? C35 Rh2 C38 63.88(19) . . ? C37 Rh2 C38 36.1(2) . . ? F1 Sb1 F6 91.6(4) . . ? F1 Sb1 F2 90.5(4) . . ? F6 Sb1 F2 177.8(3) . . ? F1 Sb1 F5 178.8(4) . . ? F6 Sb1 F5 89.6(3) . . ? F2 Sb1 F5 88.3(4) . . ? F1 Sb1 F3 91.6(4) . . ? F6 Sb1 F3 90.0(2) . . ? F2 Sb1 F3 90.6(3) . . ? F5 Sb1 F3 88.6(3) . . ? F1 Sb1 F4 92.2(4) . . ? F6 Sb1 F4 90.2(2) . . ? F2 Sb1 F4 89.0(3) . . ? F5 Sb1 F4 87.6(3) . . ? F3 Sb1 F4 176.2(3) . . ? F9 Sb2 F7 98.6(8) . . ? F9 Sb2 F8 176.5(6) . . ? F7 Sb2 F8 84.4(8) . . ? F9 Sb2 F10 87.7(7) . . ? F7 Sb2 F10 173.6(7) . . ? F8 Sb2 F10 89.3(6) . . ? F9 Sb2 F12 90.1(4) . . ? F7 Sb2 F12 90.2(5) . . ? F8 Sb2 F12 91.6(5) . . ? F10 Sb2 F12 90.4(4) . . ? F9 Sb2 F11 89.7(4) . . ? F7 Sb2 F11 93.4(5) . . ? F8 Sb2 F11 88.3(5) . . ? F10 Sb2 F11 86.0(4) . . ? F12 Sb2 F11 176.4(4) . . ? C11 N1 C7 120.2(5) . . ? C11 N1 Rh1 123.1(4) . . ? C7 N1 Rh1 116.6(4) . . ? C23 N2 Rh1 170.3(5) . . ? C34 N3 C30 119.3(5) . . ? C34 N3 Rh2 125.0(4) . . ? C30 N3 Rh2 115.6(4) . . ? C46 N4 Rh2 170.3(5) . . ? C2 C1 C6 118.2(6) . . ? C2 C1 Rh1 127.2(5) . . ? C6 C1 Rh1 114.6(4) . . ? C3 C2 C1 120.4(7) . . ? C3 C2 H2A 119.8 . . ? C1 C2 H2A 119.8 . . ? C4 C3 C2 121.2(7) . . ? C4 C3 H3A 119.4 . . ? C2 C3 H3A 119.4 . . ? C5 C4 C3 119.8(7) . . ? C5 C4 H4A 120.1 . . ? C3 C4 H4A 120.1 . . ? C4 C5 C6 119.7(7) . . ? C4 C5 H5A 120.1 . . ? C6 C5 H5A 120.1 . . ? C5 C6 C1 120.7(6) . . ? C5 C6 C7 123.4(6) . . ? C1 C6 C7 115.7(5) . . ? N1 C7 C8 120.2(5) . . ? N1 C7 C6 113.5(5) . . ? C8 C7 C6 126.2(5) . . ? C9 C8 C7 119.1(6) . . ? C9 C8 H8A 120.5 . . ? C7 C8 H8A 120.5 . . ? C10 C9 C8 120.3(6) . . ? C10 C9 H9A 119.9 . . ? C8 C9 H9A 119.9 . . ? C9 C10 C11 118.4(6) . . ? C9 C10 H10A 120.8 . . ? C11 C10 H10A 120.8 . . ? N1 C11 C10 121.7(6) . . ? N1 C11 H11A 119.2 . . ? C10 C11 H11A 119.2 . . ? C13 C12 C16 107.9(6) . . ? C13 C12 C17 125.4(8) . . ? C16 C12 C17 126.3(8) . . ? C13 C12 Rh1 72.5(3) . . ? C16 C12 Rh1 75.4(4) . . ? C17 C12 Rh1 123.4(5) . . ? C14 C13 C12 107.8(6) . . ? C14 C13 C18 125.8(7) . . ? C12 C13 C18 126.3(7) . . ? C14 C13 Rh1 70.9(3) . . ? C12 C13 Rh1 68.7(3) . . ? C18 C13 Rh1 127.8(5) . . ? C13 C14 C15 107.7(6) . . ? C13 C14 C19 126.7(7) . . ? C15 C14 C19 125.3(6) . . ? C13 C14 Rh1 71.3(3) . . ? C15 C14 Rh1 73.3(3) . . ? C19 C14 Rh1 126.1(5) . . ? C16 C15 C14 108.8(6) . . ? C16 C15 C20 125.5(7) . . ? C14 C15 C20 125.6(6) . . ? C16 C15 Rh1 72.4(3) . . ? C14 C15 Rh1 68.5(3) . . ? C20 C15 Rh1 126.5(5) . . ? C15 C16 C12 107.3(6) . . ? C15 C16 C21 126.9(8) . . ? C12 C16 C21 125.8(7) . . ? C15 C16 Rh1 71.4(4) . . ? C12 C16 Rh1 66.2(3) . . ? C21 C16 Rh1 128.0(5) . . ? C12 C17 H17A 109.5 . . ? C12 C17 H17B 109.5 . . ? H17A C17 H17B 109.5 . . ? C12 C17 H17C 109.5 . . ? H17A C17 H17C 109.5 . . ? H17B C17 H17C 109.5 . . ? C13 C18 H18A 109.5 . . ? C13 C18 H18B 109.5 . . ? H18A C18 H18B 109.5 . . ? C13 C18 H18C 109.5 . . ? H18A C18 H18C 109.5 . . ? H18B C18 H18C 109.5 . . ? C14 C19 H19A 109.5 . . ? C14 C19 H19B 109.5 . . ? H19A C19 H19B 109.5 . . ? C14 C19 H19C 109.5 . . ? H19A C19 H19C 109.5 . . ? H19B C19 H19C 109.5 . . ? C15 C20 H20A 109.5 . . ? C15 C20 H20B 109.5 . . ? H20A C20 H20B 109.5 . . ? C15 C20 H20C 109.5 . . ? H20A C20 H20C 109.5 . . ? H20B C20 H20C 109.5 . . ? C16 C21 H21A 109.5 . . ? C16 C21 H21B 109.5 . . ? H21A C21 H21B 109.5 . . ? C16 C21 H21C 109.5 . . ? H21A C21 H21C 109.5 . . ? H21B C21 H21C 109.5 . . ? C23 C22 H22A 109.5 . . ? C23 C22 H22B 109.5 . . ? H22A C22 H22B 109.5 . . ? C23 C22 H22C 109.5 . . ? H22A C22 H22C 109.5 . . ? H22B C22 H22C 109.5 . . ? N2 C23 C22 179.2(7) . . ? C25 C24 C29 119.1(5) . . ? C25 C24 Rh2 125.5(4) . . ? C29 C24 Rh2 115.3(4) . . ? C24 C25 C26 119.5(6) . . ? C24 C25 H25A 120.2 . . ? C26 C25 H25A 120.2 . . ? C27 C26 C25 121.5(7) . . ? C27 C26 H26A 119.2 . . ? C25 C26 H26A 119.2 . . ? C26 C27 C28 120.1(6) . . ? C26 C27 H27A 120.0 . . ? C28 C27 H27A 120.0 . . ? C27 C28 C29 119.4(6) . . ? C27 C28 H28A 120.3 . . ? C29 C28 H28A 120.3 . . ? C24 C29 C28 120.3(6) . . ? C24 C29 C30 116.3(5) . . ? C28 C29 C30 123.4(6) . . ? N3 C30 C31 119.5(6) . . ? N3 C30 C29 114.0(5) . . ? C31 C30 C29 126.5(6) . . ? C32 C31 C30 120.7(6) . . ? C32 C31 H31A 119.7 . . ? C30 C31 H31A 119.7 . . ? C31 C32 C33 119.3(6) . . ? C31 C32 H32A 120.3 . . ? C33 C32 H32A 120.3 . . ? C34 C33 C32 117.8(6) . . ? C34 C33 H33A 121.1 . . ? C32 C33 H33A 121.1 . . ? N3 C34 C33 123.2(6) . . ? N3 C34 H34A 118.4 . . ? C33 C34 H34A 118.4 . . ? C36 C35 C39 106.9(4) . . ? C36 C35 C40 126.6(5) . . ? C39 C35 C40 126.4(5) . . ? C36 C35 Rh2 69.8(3) . . ? C39 C35 Rh2 69.0(3) . . ? C40 C35 Rh2 129.6(4) . . ? C35 C36 C37 108.3(5) . . ? C35 C36 C41 126.9(5) . . ? C37 C36 C41 124.5(5) . . ? C35 C36 Rh2 71.8(3) . . ? C37 C36 Rh2 73.8(3) . . ? C41 C36 Rh2 125.6(4) . . ? C38 C37 C36 108.4(5) . . ? C38 C37 C42 126.9(5) . . ? C36 C37 C42 124.7(5) . . ? C38 C37 Rh2 72.1(3) . . ? C36 C37 Rh2 67.6(3) . . ? C42 C37 Rh2 127.0(4) . . ? C37 C38 C39 107.6(5) . . ? C37 C38 C43 127.2(5) . . ? C39 C38 C43 125.1(5) . . ? C37 C38 Rh2 71.8(3) . . ? C39 C38 Rh2 66.6(3) . . ? C43 C38 Rh2 129.1(4) . . ? C35 C39 C38 108.4(5) . . ? C35 C39 C44 125.5(5) . . ? C38 C39 C44 125.6(5) . . ? C35 C39 Rh2 72.4(3) . . ? C38 C39 Rh2 74.6(3) . . ? C44 C39 Rh2 125.2(4) . . ? C35 C40 H40A 109.5 . . ? C35 C40 H40B 109.5 . . ? H40A C40 H40B 109.5 . . ? C35 C40 H40C 109.5 . . ? H40A C40 H40C 109.5 . . ? H40B C40 H40C 109.5 . . ? C36 C41 H41A 109.5 . . ? C36 C41 H41B 109.5 . . ? H41A C41 H41B 109.5 . . ? C36 C41 H41C 109.5 . . ? H41A C41 H41C 109.5 . . ? H41B C41 H41C 109.5 . . ? C37 C42 H42A 109.5 . . ? C37 C42 H42B 109.5 . . ? H42A C42 H42B 109.5 . . ? C37 C42 H42C 109.5 . . ? H42A C42 H42C 109.5 . . ? H42B C42 H42C 109.5 . . ? C38 C43 H43A 109.5 . . ? C38 C43 H43B 109.5 . . ? H43A C43 H43B 109.5 . . ? C38 C43 H43C 109.5 . . ? H43A C43 H43C 109.5 . . ? H43B C43 H43C 109.5 . . ? C39 C44 H44A 109.5 . . ? C39 C44 H44B 109.5 . . ? H44A C44 H44B 109.5 . . ? C39 C44 H44C 109.5 . . ? H44A C44 H44C 109.5 . . ? H44B C44 H44C 109.5 . . ? C46 C45 H45A 109.5 . . ? C46 C45 H45B 109.5 . . ? H45A C45 H45B 109.5 . . ? C46 C45 H45C 109.5 . . ? H45A C45 H45C 109.5 . . ? H45B C45 H45C 109.5 . . ? N4 C46 C45 178.6(7) . . ? Cl1 C47 Cl2 111.7(5) . . ? Cl1 C47 H47A 109.3 . . ? Cl2 C47 H47A 109.3 . . ? Cl1 C47 H47B 109.3 . . ? Cl2 C47 H47B 109.3 . . ? H47A C47 H47B 107.9 . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C1 Rh1 N1 C11 168.0(5) . . . . ? N2 Rh1 N1 C11 75.6(5) . . . . ? C12 Rh1 N1 C11 -85.6(5) . . . . ? C14 Rh1 N1 C11 -50.0(9) . . . . ? C13 Rh1 N1 C11 -108.1(5) . . . . ? C15 Rh1 N1 C11 -20.6(6) . . . . ? C16 Rh1 N1 C11 -46.5(5) . . . . ? C1 Rh1 N1 C7 -8.7(4) . . . . ? N2 Rh1 N1 C7 -101.1(4) . . . . ? C12 Rh1 N1 C7 97.7(4) . . . . ? C14 Rh1 N1 C7 133.3(7) . . . . ? C13 Rh1 N1 C7 75.2(5) . . . . ? C15 Rh1 N1 C7 162.7(4) . . . . ? C16 Rh1 N1 C7 136.7(4) . . . . ? C1 Rh1 N2 C23 -135(3) . . . . ? N1 Rh1 N2 C23 -56(3) . . . . ? C12 Rh1 N2 C23 57(3) . . . . ? C14 Rh1 N2 C23 109(3) . . . . ? C13 Rh1 N2 C23 128(3) . . . . ? C15 Rh1 N2 C23 71(3) . . . . ? C16 Rh1 N2 C23 43(3) . . . . ? C24 Rh2 N3 C34 -174.8(5) . . . . ? N4 Rh2 N3 C34 -85.1(5) . . . . ? C39 Rh2 N3 C34 75.4(5) . . . . ? C36 Rh2 N3 C34 49.8(10) . . . . ? C35 Rh2 N3 C34 101.0(5) . . . . ? C37 Rh2 N3 C34 10.4(6) . . . . ? C38 Rh2 N3 C34 35.7(5) . . . . ? C24 Rh2 N3 C30 5.1(4) . . . . ? N4 Rh2 N3 C30 94.8(4) . . . . ? C39 Rh2 N3 C30 -104.7(4) . . . . ? C36 Rh2 N3 C30 -130.2(7) . . . . ? C35 Rh2 N3 C30 -79.1(4) . . . . ? C37 Rh2 N3 C30 -169.6(4) . . . . ? C38 Rh2 N3 C30 -144.4(4) . . . . ? C24 Rh2 N4 C46 -176(3) . . . . ? N3 Rh2 N4 C46 105(3) . . . . ? C39 Rh2 N4 C46 -15(3) . . . . ? C36 Rh2 N4 C46 -64(3) . . . . ? C35 Rh2 N4 C46 -81(3) . . . . ? C37 Rh2 N4 C46 -25(3) . . . . ? C38 Rh2 N4 C46 2(3) . . . . ? N2 Rh1 C1 C2 -86.2(6) . . . . ? N1 Rh1 C1 C2 -171.5(6) . . . . ? C12 Rh1 C1 C2 89.8(6) . . . . ? C14 Rh1 C1 C2 20.2(6) . . . . ? C13 Rh1 C1 C2 53.0(6) . . . . ? C15 Rh1 C1 C2 23.7(9) . . . . ? C16 Rh1 C1 C2 98.2(7) . . . . ? N2 Rh1 C1 C6 94.8(4) . . . . ? N1 Rh1 C1 C6 9.5(4) . . . . ? C12 Rh1 C1 C6 -89.2(5) . . . . ? C14 Rh1 C1 C6 -158.8(4) . . . . ? C13 Rh1 C1 C6 -126.0(4) . . . . ? C15 Rh1 C1 C6 -155.3(5) . . . . ? C16 Rh1 C1 C6 -80.8(6) . . . . ? C6 C1 C2 C3 2.4(9) . . . . ? Rh1 C1 C2 C3 -176.5(5) . . . . ? C1 C2 C3 C4 -0.2(11) . . . . ? C2 C3 C4 C5 -1.8(12) . . . . ? C3 C4 C5 C6 1.5(11) . . . . ? C4 C5 C6 C1 0.8(10) . . . . ? C4 C5 C6 C7 -172.9(6) . . . . ? C2 C1 C6 C5 -2.7(9) . . . . ? Rh1 C1 C6 C5 176.4(5) . . . . ? C2 C1 C6 C7 171.5(5) . . . . ? Rh1 C1 C6 C7 -9.4(7) . . . . ? C11 N1 C7 C8 4.4(8) . . . . ? Rh1 N1 C7 C8 -178.7(4) . . . . ? C11 N1 C7 C6 -170.7(5) . . . . ? Rh1 N1 C7 C6 6.1(6) . . . . ? C5 C6 C7 N1 176.1(5) . . . . ? C1 C6 C7 N1 2.1(7) . . . . ? C5 C6 C7 C8 1.3(9) . . . . ? C1 C6 C7 C8 -172.7(6) . . . . ? N1 C7 C8 C9 -1.5(9) . . . . ? C6 C7 C8 C9 173.0(6) . . . . ? C7 C8 C9 C10 -2.3(9) . . . . ? C8 C9 C10 C11 3.1(10) . . . . ? C7 N1 C11 C10 -3.6(9) . . . . ? Rh1 N1 C11 C10 179.8(5) . . . . ? C9 C10 C11 N1 -0.2(10) . . . . ? C1 Rh1 C12 C13 -73.0(4) . . . . ? N2 Rh1 C12 C13 95.2(8) . . . . ? N1 Rh1 C12 C13 -154.6(4) . . . . ? C14 Rh1 C12 C13 36.6(4) . . . . ? C15 Rh1 C12 C13 79.3(4) . . . . ? C16 Rh1 C12 C13 114.5(5) . . . . ? C1 Rh1 C12 C16 172.5(4) . . . . ? N2 Rh1 C12 C16 -19.3(9) . . . . ? N1 Rh1 C12 C16 90.9(4) . . . . ? C14 Rh1 C12 C16 -78.0(4) . . . . ? C13 Rh1 C12 C16 -114.5(5) . . . . ? C15 Rh1 C12 C16 -35.2(4) . . . . ? C1 Rh1 C12 C17 48.3(8) . . . . ? N2 Rh1 C12 C17 -143.5(7) . . . . ? N1 Rh1 C12 C17 -33.3(8) . . . . ? C14 Rh1 C12 C17 157.9(9) . . . . ? C13 Rh1 C12 C17 121.3(10) . . . . ? C15 Rh1 C12 C17 -159.4(9) . . . . ? C16 Rh1 C12 C17 -124.2(9) . . . . ? C16 C12 C13 C14 7.3(7) . . . . ? C17 C12 C13 C14 -179.5(6) . . . . ? Rh1 C12 C13 C14 -60.4(4) . . . . ? C16 C12 C13 C18 -170.2(6) . . . . ? C17 C12 C13 C18 3.0(11) . . . . ? Rh1 C12 C13 C18 122.0(7) . . . . ? C16 C12 C13 Rh1 67.7(4) . . . . ? C17 C12 C13 Rh1 -119.0(7) . . . . ? C1 Rh1 C13 C14 -126.9(4) . . . . ? N2 Rh1 C13 C14 -30.1(6) . . . . ? N1 Rh1 C13 C14 155.5(4) . . . . ? C12 Rh1 C13 C14 118.8(6) . . . . ? C15 Rh1 C13 C14 38.7(4) . . . . ? C16 Rh1 C13 C14 79.5(4) . . . . ? C1 Rh1 C13 C12 114.4(4) . . . . ? N2 Rh1 C13 C12 -148.9(4) . . . . ? N1 Rh1 C13 C12 36.7(6) . . . . ? C14 Rh1 C13 C12 -118.8(6) . . . . ? C15 Rh1 C13 C12 -80.1(5) . . . . ? C16 Rh1 C13 C12 -39.3(4) . . . . ? C1 Rh1 C13 C18 -5.8(7) . . . . ? N2 Rh1 C13 C18 90.9(7) . . . . ? N1 Rh1 C13 C18 -83.5(8) . . . . ? C12 Rh1 C13 C18 -120.2(8) . . . . ? C14 Rh1 C13 C18 121.0(9) . . . . ? C15 Rh1 C13 C18 159.7(8) . . . . ? C16 Rh1 C13 C18 -159.5(8) . . . . ? C12 C13 C14 C15 -5.7(7) . . . . ? C18 C13 C14 C15 171.8(6) . . . . ? Rh1 C13 C14 C15 -64.8(4) . . . . ? C12 C13 C14 C19 -179.5(6) . . . . ? C18 C13 C14 C19 -1.9(11) . . . . ? Rh1 C13 C14 C19 121.5(7) . . . . ? C12 C13 C14 Rh1 59.1(4) . . . . ? C18 C13 C14 Rh1 -123.4(7) . . . . ? C1 Rh1 C14 C13 61.6(5) . . . . ? N2 Rh1 C14 C13 160.1(4) . . . . ? N1 Rh1 C14 C13 -76.6(9) . . . . ? C12 Rh1 C14 C13 -37.4(4) . . . . ? C15 Rh1 C14 C13 -115.8(6) . . . . ? C16 Rh1 C14 C13 -80.5(5) . . . . ? C1 Rh1 C14 C15 177.5(4) . . . . ? N2 Rh1 C14 C15 -84.1(4) . . . . ? N1 Rh1 C14 C15 39.2(9) . . . . ? C12 Rh1 C14 C15 78.4(4) . . . . ? C13 Rh1 C14 C15 115.8(6) . . . . ? C16 Rh1 C14 C15 35.4(4) . . . . ? C1 Rh1 C14 C19 -60.6(7) . . . . ? N2 Rh1 C14 C19 37.8(7) . . . . ? N1 Rh1 C14 C19 161.1(6) . . . . ? C12 Rh1 C14 C19 -159.7(7) . . . . ? C13 Rh1 C14 C19 -122.3(8) . . . . ? C15 Rh1 C14 C19 121.9(8) . . . . ? C16 Rh1 C14 C19 157.3(7) . . . . ? C13 C14 C15 C16 2.0(7) . . . . ? C19 C14 C15 C16 175.9(6) . . . . ? Rh1 C14 C15 C16 -61.4(4) . . . . ? C13 C14 C15 C20 -176.3(6) . . . . ? C19 C14 C15 C20 -2.5(10) . . . . ? Rh1 C14 C15 C20 120.3(6) . . . . ? C13 C14 C15 Rh1 63.4(4) . . . . ? C19 C14 C15 Rh1 -122.7(6) . . . . ? C1 Rh1 C15 C16 114.3(6) . . . . ? N2 Rh1 C15 C16 -137.3(4) . . . . ? N1 Rh1 C15 C16 -46.9(5) . . . . ? C12 Rh1 C15 C16 37.3(4) . . . . ? C14 Rh1 C15 C16 119.3(6) . . . . ? C13 Rh1 C15 C16 81.0(4) . . . . ? C1 Rh1 C15 C14 -5.0(7) . . . . ? N2 Rh1 C15 C14 103.4(4) . . . . ? N1 Rh1 C15 C14 -166.2(3) . . . . ? C12 Rh1 C15 C14 -82.0(4) . . . . ? C13 Rh1 C15 C14 -38.3(4) . . . . ? C16 Rh1 C15 C14 -119.3(6) . . . . ? C1 Rh1 C15 C20 -124.1(7) . . . . ? N2 Rh1 C15 C20 -15.7(7) . . . . ? N1 Rh1 C15 C20 74.7(7) . . . . ? C12 Rh1 C15 C20 158.9(7) . . . . ? C14 Rh1 C15 C20 -119.1(8) . . . . ? C13 Rh1 C15 C20 -157.4(7) . . . . ? C16 Rh1 C15 C20 121.6(8) . . . . ? C14 C15 C16 C12 2.5(7) . . . . ? C20 C15 C16 C12 -179.2(6) . . . . ? Rh1 C15 C16 C12 -56.6(4) . . . . ? C14 C15 C16 C21 -176.9(6) . . . . ? C20 C15 C16 C21 1.4(10) . . . . ? Rh1 C15 C16 C21 124.0(7) . . . . ? C14 C15 C16 Rh1 59.0(4) . . . . ? C20 C15 C16 Rh1 -122.7(6) . . . . ? C13 C12 C16 C15 -6.0(7) . . . . ? C17 C12 C16 C15 -179.2(6) . . . . ? Rh1 C12 C16 C15 59.8(4) . . . . ? C13 C12 C16 C21 173.4(6) . . . . ? C17 C12 C16 C21 0.2(10) . . . . ? Rh1 C12 C16 C21 -120.8(6) . . . . ? C13 C12 C16 Rh1 -65.8(4) . . . . ? C17 C12 C16 Rh1 121.0(7) . . . . ? C1 Rh1 C16 C15 -132.3(5) . . . . ? N2 Rh1 C16 C15 52.8(5) . . . . ? N1 Rh1 C16 C15 143.9(4) . . . . ? C12 Rh1 C16 C15 -119.5(6) . . . . ? C14 Rh1 C16 C15 -37.3(4) . . . . ? C13 Rh1 C16 C15 -79.9(4) . . . . ? C1 Rh1 C16 C12 -12.8(6) . . . . ? N2 Rh1 C16 C12 172.3(3) . . . . ? N1 Rh1 C16 C12 -96.6(4) . . . . ? C14 Rh1 C16 C12 82.2(4) . . . . ? C13 Rh1 C16 C12 39.6(4) . . . . ? C15 Rh1 C16 C12 119.5(6) . . . . ? C1 Rh1 C16 C21 105.0(8) . . . . ? N2 Rh1 C16 C21 -69.9(8) . . . . ? N1 Rh1 C16 C21 21.2(8) . . . . ? C12 Rh1 C16 C21 117.8(9) . . . . ? C14 Rh1 C16 C21 -160.0(9) . . . . ? C13 Rh1 C16 C21 157.4(9) . . . . ? C15 Rh1 C16 C21 -122.7(10) . . . . ? Rh1 N2 C23 C22 44(59) . . . . ? N4 Rh2 C24 C25 87.4(5) . . . . ? N3 Rh2 C24 C25 176.6(5) . . . . ? C39 Rh2 C24 C25 -85.0(5) . . . . ? C36 Rh2 C24 C25 -14.8(6) . . . . ? C35 Rh2 C24 C25 -49.6(5) . . . . ? C37 Rh2 C24 C25 -11.5(8) . . . . ? C38 Rh2 C24 C25 -89.1(6) . . . . ? N4 Rh2 C24 C29 -93.7(4) . . . . ? N3 Rh2 C24 C29 -4.5(4) . . . . ? C39 Rh2 C24 C29 93.9(4) . . . . ? C36 Rh2 C24 C29 164.1(4) . . . . ? C35 Rh2 C24 C29 129.3(4) . . . . ? C37 Rh2 C24 C29 167.4(4) . . . . ? C38 Rh2 C24 C29 89.8(6) . . . . ? C29 C24 C25 C26 -2.1(9) . . . . ? Rh2 C24 C25 C26 176.7(5) . . . . ? C24 C25 C26 C27 1.7(10) . . . . ? C25 C26 C27 C28 0.1(10) . . . . ? C26 C27 C28 C29 -1.4(10) . . . . ? C25 C24 C29 C28 0.8(8) . . . . ? Rh2 C24 C29 C28 -178.1(4) . . . . ? C25 C24 C29 C30 -177.5(5) . . . . ? Rh2 C24 C29 C30 3.5(6) . . . . ? C27 C28 C29 C24 0.9(9) . . . . ? C27 C28 C29 C30 179.2(6) . . . . ? C34 N3 C30 C31 -2.7(8) . . . . ? Rh2 N3 C30 C31 177.4(4) . . . . ? C34 N3 C30 C29 175.3(5) . . . . ? Rh2 N3 C30 C29 -4.7(6) . . . . ? C24 C29 C30 N3 0.9(7) . . . . ? C28 C29 C30 N3 -177.4(5) . . . . ? C24 C29 C30 C31 178.6(5) . . . . ? C28 C29 C30 C31 0.3(9) . . . . ? N3 C30 C31 C32 1.1(9) . . . . ? C29 C30 C31 C32 -176.5(6) . . . . ? C30 C31 C32 C33 0.9(9) . . . . ? C31 C32 C33 C34 -1.4(9) . . . . ? C30 N3 C34 C33 2.2(9) . . . . ? Rh2 N3 C34 C33 -177.9(4) . . . . ? C32 C33 C34 N3 -0.1(9) . . . . ? C24 Rh2 C35 C36 121.5(3) . . . . ? N4 Rh2 C35 C36 28.1(4) . . . . ? N3 Rh2 C35 C36 -160.8(3) . . . . ? C39 Rh2 C35 C36 -118.1(4) . . . . ? C37 Rh2 C35 C36 -38.7(3) . . . . ? C38 Rh2 C35 C36 -79.1(3) . . . . ? C24 Rh2 C35 C39 -120.3(3) . . . . ? N4 Rh2 C35 C39 146.2(3) . . . . ? N3 Rh2 C35 C39 -42.7(4) . . . . ? C36 Rh2 C35 C39 118.1(4) . . . . ? C37 Rh2 C35 C39 79.4(3) . . . . ? C38 Rh2 C35 C39 39.0(3) . . . . ? C24 Rh2 C35 C40 0.1(5) . . . . ? N4 Rh2 C35 C40 -93.3(5) . . . . ? N3 Rh2 C35 C40 77.7(6) . . . . ? C39 Rh2 C35 C40 120.4(6) . . . . ? C36 Rh2 C35 C40 -121.4(6) . . . . ? C37 Rh2 C35 C40 -160.1(6) . . . . ? C38 Rh2 C35 C40 159.4(6) . . . . ? C39 C35 C36 C37 6.0(6) . . . . ? C40 C35 C36 C37 -169.8(5) . . . . ? Rh2 C35 C36 C37 65.3(3) . . . . ? C39 C35 C36 C41 179.4(5) . . . . ? C40 C35 C36 C41 3.7(9) . . . . ? Rh2 C35 C36 C41 -121.3(5) . . . . ? C39 C35 C36 Rh2 -59.3(3) . . . . ? C40 C35 C36 Rh2 124.9(5) . . . . ? C24 Rh2 C36 C35 -66.6(3) . . . . ? N4 Rh2 C36 C35 -160.8(3) . . . . ? N3 Rh2 C36 C35 65.4(8) . . . . ? C39 Rh2 C36 C35 37.5(3) . . . . ? C37 Rh2 C36 C35 116.0(4) . . . . ? C38 Rh2 C36 C35 80.9(3) . . . . ? C24 Rh2 C36 C37 177.4(3) . . . . ? N4 Rh2 C36 C37 83.1(3) . . . . ? N3 Rh2 C36 C37 -50.7(9) . . . . ? C39 Rh2 C36 C37 -78.5(3) . . . . ? C35 Rh2 C36 C37 -116.0(4) . . . . ? C38 Rh2 C36 C37 -35.1(3) . . . . ? C24 Rh2 C36 C41 56.2(5) . . . . ? N4 Rh2 C36 C41 -38.1(5) . . . . ? N3 Rh2 C36 C41 -171.9(6) . . . . ? C39 Rh2 C36 C41 160.3(5) . . . . ? C35 Rh2 C36 C41 122.8(6) . . . . ? C37 Rh2 C36 C41 -121.2(6) . . . . ? C38 Rh2 C36 C41 -156.3(5) . . . . ? C35 C36 C37 C38 -3.2(6) . . . . ? C41 C36 C37 C38 -176.8(5) . . . . ? Rh2 C36 C37 C38 60.8(4) . . . . ? C35 C36 C37 C42 175.6(5) . . . . ? C41 C36 C37 C42 2.0(8) . . . . ? Rh2 C36 C37 C42 -120.4(5) . . . . ? C35 C36 C37 Rh2 -64.0(3) . . . . ? C41 C36 C37 Rh2 122.4(5) . . . . ? C24 Rh2 C37 C38 -124.5(4) . . . . ? N4 Rh2 C37 C38 138.0(3) . . . . ? N3 Rh2 C37 C38 45.1(4) . . . . ? C39 Rh2 C37 C38 -37.7(3) . . . . ? C36 Rh2 C37 C38 -119.5(5) . . . . ? C35 Rh2 C37 C38 -81.0(3) . . . . ? C24 Rh2 C37 C36 -5.0(6) . . . . ? N4 Rh2 C37 C36 -102.5(3) . . . . ? N3 Rh2 C37 C36 164.5(3) . . . . ? C39 Rh2 C37 C36 81.8(3) . . . . ? C35 Rh2 C37 C36 38.5(3) . . . . ? C38 Rh2 C37 C36 119.5(5) . . . . ? C24 Rh2 C37 C42 112.4(6) . . . . ? N4 Rh2 C37 C42 14.9(5) . . . . ? N3 Rh2 C37 C42 -78.1(6) . . . . ? C39 Rh2 C37 C42 -160.8(6) . . . . ? C36 Rh2 C37 C42 117.4(6) . . . . ? C35 Rh2 C37 C42 155.8(6) . . . . ? C38 Rh2 C37 C42 -123.1(6) . . . . ? C36 C37 C38 C39 -0.9(6) . . . . ? C42 C37 C38 C39 -179.6(5) . . . . ? Rh2 C37 C38 C39 57.1(3) . . . . ? C36 C37 C38 C43 176.2(5) . . . . ? C42 C37 C38 C43 -2.5(9) . . . . ? Rh2 C37 C38 C43 -125.8(6) . . . . ? C36 C37 C38 Rh2 -58.0(3) . . . . ? C42 C37 C38 Rh2 123.3(6) . . . . ? C24 Rh2 C38 C37 125.5(5) . . . . ? N4 Rh2 C38 C37 -50.5(4) . . . . ? N3 Rh2 C38 C37 -146.7(3) . . . . ? C39 Rh2 C38 C37 119.3(4) . . . . ? C36 Rh2 C38 C37 37.5(3) . . . . ? C35 Rh2 C38 C37 80.5(3) . . . . ? C24 Rh2 C38 C39 6.2(6) . . . . ? N4 Rh2 C38 C39 -169.8(3) . . . . ? N3 Rh2 C38 C39 94.0(3) . . . . ? C36 Rh2 C38 C39 -81.8(3) . . . . ? C35 Rh2 C38 C39 -38.8(3) . . . . ? C37 Rh2 C38 C39 -119.3(4) . . . . ? C24 Rh2 C38 C43 -111.0(6) . . . . ? N4 Rh2 C38 C43 73.0(6) . . . . ? N3 Rh2 C38 C43 -23.1(6) . . . . ? C39 Rh2 C38 C43 -117.2(7) . . . . ? C36 Rh2 C38 C43 161.0(6) . . . . ? C35 Rh2 C38 C43 -156.0(6) . . . . ? C37 Rh2 C38 C43 123.5(7) . . . . ? C36 C35 C39 C38 -6.5(6) . . . . ? C40 C35 C39 C38 169.2(5) . . . . ? Rh2 C35 C39 C38 -66.4(4) . . . . ? C36 C35 C39 C44 -179.0(5) . . . . ? C40 C35 C39 C44 -3.3(9) . . . . ? Rh2 C35 C39 C44 121.1(5) . . . . ? C36 C35 C39 Rh2 59.9(3) . . . . ? C40 C35 C39 Rh2 -124.4(5) . . . . ? C37 C38 C39 C35 4.6(6) . . . . ? C43 C38 C39 C35 -172.5(5) . . . . ? Rh2 C38 C39 C35 65.0(4) . . . . ? C37 C38 C39 C44 177.1(5) . . . . ? C43 C38 C39 C44 -0.1(9) . . . . ? Rh2 C38 C39 C44 -122.5(5) . . . . ? C37 C38 C39 Rh2 -60.3(4) . . . . ? C43 C38 C39 Rh2 122.5(5) . . . . ? C24 Rh2 C39 C35 67.7(3) . . . . ? N4 Rh2 C39 C35 -91.8(6) . . . . ? N3 Rh2 C39 C35 149.9(3) . . . . ? C36 Rh2 C39 C35 -37.3(3) . . . . ? C37 Rh2 C39 C35 -80.5(3) . . . . ? C38 Rh2 C39 C35 -115.6(4) . . . . ? C24 Rh2 C39 C38 -176.7(3) . . . . ? N4 Rh2 C39 C38 23.8(7) . . . . ? N3 Rh2 C39 C38 -94.5(3) . . . . ? C36 Rh2 C39 C38 78.3(3) . . . . ? C35 Rh2 C39 C38 115.6(4) . . . . ? C37 Rh2 C39 C38 35.1(3) . . . . ? C24 Rh2 C39 C44 -53.7(5) . . . . ? N4 Rh2 C39 C44 146.8(5) . . . . ? N3 Rh2 C39 C44 28.4(5) . . . . ? C36 Rh2 C39 C44 -158.7(6) . . . . ? C35 Rh2 C39 C44 -121.4(6) . . . . ? C37 Rh2 C39 C44 158.1(6) . . . . ? C38 Rh2 C39 C44 123.0(6) . . . . ? Rh2 N4 C46 C45 -86(30) . . . . ? _diffrn_measured_fraction_theta_max 0.987 _diffrn_reflns_theta_full 27.47 _diffrn_measured_fraction_theta_full 0.987 _refine_diff_density_max 2.890 _refine_diff_density_min -1.987 _refine_diff_density_rms 0.131 # Attachment '9.cif' data_9 _database_code_depnum_ccdc_archive 'CCDC 793689' #TrackingRef '9.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'C35 H36 N2 O2 Rh S, F6 Sb ' _chemical_formula_sum 'C35 H36 F6 N2 O2 Rh S Sb' _chemical_formula_weight 887.38 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M P2(1)/c loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 18.507(7) _cell_length_b 10.873(4) _cell_length_c 17.673(7) _cell_angle_alpha 90.00 _cell_angle_beta 103.416(8) _cell_angle_gamma 90.00 _cell_volume 3459(2) _cell_formula_units_Z 4 _cell_measurement_temperature 173(2) _cell_measurement_reflns_used 736 _cell_measurement_theta_min 2.17 _cell_measurement_theta_max 27.48 _exptl_crystal_description plate _exptl_crystal_colour yellow _exptl_crystal_size_max 0.16 _exptl_crystal_size_mid 0.13 _exptl_crystal_size_min 0.03 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.704 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1768 _exptl_absorpt_coefficient_mu 1.385 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.8088 _exptl_absorpt_correction_T_max 0.9596 _exptl_absorpt_process_details 'CrystalClear (Rigaku Inc., 2007)' _exptl_special_details ; ? ; _diffrn_ambient_temperature 173(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'rotating anode' _diffrn_radiation_monochromator Confocal _diffrn_measurement_device_type 'MM007-HF CCD(Saturn 724+)' _diffrn_measurement_method '\w scans at fixed \c = 45\%' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 14917 _diffrn_reflns_av_R_equivalents 0.0814 _diffrn_reflns_av_sigmaI/netI 0.1121 _diffrn_reflns_limit_h_min -21 _diffrn_reflns_limit_h_max 22 _diffrn_reflns_limit_k_min -13 _diffrn_reflns_limit_k_max 10 _diffrn_reflns_limit_l_min -21 _diffrn_reflns_limit_l_max 16 _diffrn_reflns_theta_min 2.19 _diffrn_reflns_theta_max 25.28 _reflns_number_total 6225 _reflns_number_gt 4836 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'CrystalClear (Rigaku Inc., 2007)' _computing_cell_refinement 'CrystalClear (Rigaku Inc., 2007)' _computing_data_reduction 'CrystalClear (Rigaku Inc., 2007)' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'XP in Siemens SHELXTL (Sheldrick, 1994)' _computing_publication_material 'SHELX97 (Sheldrick, 1997)' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0115P)^2^+40.4672P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 6225 _refine_ls_number_parameters 439 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.1336 _refine_ls_R_factor_gt 0.1045 _refine_ls_wR_factor_ref 0.1770 _refine_ls_wR_factor_gt 0.1633 _refine_ls_goodness_of_fit_ref 1.178 _refine_ls_restrained_S_all 1.178 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Rh1 Rh 0.27252(5) 0.41731(8) 0.41754(5) 0.0329(2) Uani 1 1 d . . . Sb1 Sb 0.35220(5) 0.66919(7) 0.14796(5) 0.0376(2) Uani 1 1 d . . . S1 S 0.15998(18) 0.3433(3) 0.48772(19) 0.0428(8) Uani 1 1 d . . . F1 F 0.4147(5) 0.8057(7) 0.1693(6) 0.085(3) Uani 1 1 d . . . F2 F 0.3983(5) 0.6211(8) 0.0696(5) 0.080(3) Uani 1 1 d . . . F3 F 0.3074(5) 0.7179(7) 0.2267(5) 0.081(3) Uani 1 1 d . . . F4 F 0.2901(5) 0.5322(7) 0.1295(5) 0.075(3) Uani 1 1 d . . . F5 F 0.4219(4) 0.5763(7) 0.2193(5) 0.070(2) Uani 1 1 d . . . F6 F 0.2853(4) 0.7634(7) 0.0767(4) 0.066(2) Uani 1 1 d . . . O1 O 0.1986(4) 0.4646(6) 0.4944(5) 0.041(2) Uani 1 1 d . . . O2 O 0.1581(5) 0.2800(7) 0.5590(5) 0.053(2) Uani 1 1 d . . . N1 N 0.3424(6) 0.3491(8) 0.5207(6) 0.041(2) Uani 1 1 d . . . N2 N 0.1994(5) 0.2704(8) 0.4306(6) 0.038(2) Uani 1 1 d . . . C1 C 0.3595(6) 0.4244(11) 0.5837(7) 0.036(3) Uani 1 1 d . . . H1A H 0.3370 0.5034 0.5795 0.044 Uiso 1 1 calc R . . C2 C 0.4065(7) 0.3940(11) 0.6520(7) 0.040(3) Uani 1 1 d . . . H2B H 0.4179 0.4511 0.6938 0.048 Uiso 1 1 calc R . . C3 C 0.4376(7) 0.2768(11) 0.6593(8) 0.050(4) Uani 1 1 d . . . H3A H 0.4711 0.2524 0.7062 0.060 Uiso 1 1 calc R . . C4 C 0.4190(7) 0.1975(11) 0.5979(8) 0.045(3) Uani 1 1 d . . . H4A H 0.4379 0.1159 0.6033 0.054 Uiso 1 1 calc R . . C5 C 0.3732(6) 0.2338(10) 0.5279(7) 0.034(3) Uani 1 1 d . . . C6 C 0.3592(7) 0.1485(9) 0.4593(7) 0.041(3) Uani 1 1 d . . . C7 C 0.4228(6) 0.1088(10) 0.4349(7) 0.040(3) Uani 1 1 d . . . H7A H 0.4707 0.1371 0.4611 0.048 Uiso 1 1 calc R . . C8 C 0.4156(7) 0.0303(12) 0.3741(8) 0.052(4) Uani 1 1 d . . . H8A H 0.4584 0.0060 0.3568 0.062 Uiso 1 1 calc R . . C9 C 0.3466(8) -0.0149(10) 0.3368(8) 0.049(3) Uani 1 1 d . . . H9A H 0.3417 -0.0698 0.2941 0.059 Uiso 1 1 calc R . . C10 C 0.2845(7) 0.0214(10) 0.3629(7) 0.040(3) Uani 1 1 d . . . H10A H 0.2372 -0.0114 0.3389 0.048 Uiso 1 1 calc R . . C11 C 0.2906(7) 0.1051(10) 0.4237(7) 0.037(3) Uani 1 1 d . . . C12 C 0.2191(7) 0.1405(10) 0.4513(8) 0.044(3) Uani 1 1 d . . . H12A H 0.2317 0.1354 0.5094 0.053 Uiso 1 1 calc R . . C13 C 0.1540(7) 0.0532(10) 0.4219(7) 0.041(3) Uani 1 1 d . . . C14 C 0.1402(8) -0.0426(11) 0.4686(8) 0.053(4) Uani 1 1 d . . . H14A H 0.1705 -0.0547 0.5193 0.064 Uiso 1 1 calc R . . C15 C 0.0812(8) -0.1198(13) 0.4392(9) 0.059(4) Uani 1 1 d . . . H15A H 0.0712 -0.1855 0.4707 0.071 Uiso 1 1 calc R . . C16 C 0.0364(8) -0.1051(13) 0.3663(10) 0.065(4) Uani 1 1 d . . . H16A H -0.0031 -0.1609 0.3471 0.078 Uiso 1 1 calc R . . C17 C 0.0496(9) -0.0097(15) 0.3221(10) 0.074(5) Uani 1 1 d . . . H17A H 0.0185 0.0030 0.2719 0.088 Uiso 1 1 calc R . . C18 C 0.1082(7) 0.0693(12) 0.3499(8) 0.052(4) Uani 1 1 d . . . H18A H 0.1169 0.1360 0.3184 0.063 Uiso 1 1 calc R . . C19 C 0.0660(8) 0.3731(11) 0.4404(8) 0.050(3) Uani 1 1 d . . . C20 C 0.0151(8) 0.2785(12) 0.4275(9) 0.060(4) Uani 1 1 d . . . H20A H 0.0306 0.1973 0.4435 0.072 Uiso 1 1 calc R . . C21 C -0.0601(8) 0.3015(12) 0.3906(9) 0.063(4) Uani 1 1 d . . . H21A H -0.0946 0.2355 0.3802 0.076 Uiso 1 1 calc R . . C22 C -0.0834(8) 0.4208(13) 0.3697(8) 0.052(4) Uani 1 1 d . . . C23 C -0.0314(7) 0.5179(12) 0.3831(7) 0.048(3) Uani 1 1 d . . . H23A H -0.0465 0.5993 0.3675 0.058 Uiso 1 1 calc R . . C24 C 0.0422(8) 0.4931(12) 0.4194(8) 0.057(4) Uani 1 1 d . . . H24A H 0.0769 0.5588 0.4301 0.068 Uiso 1 1 calc R . . C25 C -0.1631(7) 0.4453(14) 0.3332(8) 0.059(4) Uani 1 1 d . . . H25A H -0.1936 0.4210 0.3692 0.089 Uiso 1 1 calc R . . H25B H -0.1780 0.3977 0.2850 0.089 Uiso 1 1 calc R . . H25C H -0.1700 0.5331 0.3215 0.089 Uiso 1 1 calc R . . C26 C 0.2880(6) 0.4022(10) 0.3018(7) 0.039(3) Uani 1 1 d . . . C27 C 0.2287(6) 0.4864(11) 0.3026(7) 0.039(3) Uani 1 1 d . . . C28 C 0.2573(7) 0.5858(10) 0.3498(7) 0.040(3) Uani 1 1 d . . . C29 C 0.3354(7) 0.5656(10) 0.3827(7) 0.038(3) Uani 1 1 d . . . C30 C 0.3533(7) 0.4491(10) 0.3497(7) 0.038(3) Uani 1 1 d . . . C31 C 0.2818(9) 0.2891(11) 0.2534(8) 0.060(4) Uani 1 1 d . . . H31A H 0.2866 0.3107 0.2009 0.090 Uiso 1 1 calc R . . H31B H 0.2334 0.2505 0.2503 0.090 Uiso 1 1 calc R . . H31C H 0.3214 0.2315 0.2770 0.090 Uiso 1 1 calc R . . C32 C 0.1520(7) 0.4714(13) 0.2549(8) 0.063(4) Uani 1 1 d . . . H32A H 0.1483 0.5090 0.2037 0.095 Uiso 1 1 calc R . . H32B H 0.1170 0.5116 0.2809 0.095 Uiso 1 1 calc R . . H32C H 0.1401 0.3837 0.2484 0.095 Uiso 1 1 calc R . . C33 C 0.2155(8) 0.6946(11) 0.3705(8) 0.060(4) Uani 1 1 d . . . H33A H 0.2310 0.7693 0.3475 0.091 Uiso 1 1 calc R . . H33B H 0.2261 0.7036 0.4272 0.091 Uiso 1 1 calc R . . H33C H 0.1620 0.6819 0.3503 0.091 Uiso 1 1 calc R . . C34 C 0.3897(8) 0.6484(13) 0.4337(8) 0.067(4) Uani 1 1 d . . . H34A H 0.4183 0.6930 0.4023 0.100 Uiso 1 1 calc R . . H34B H 0.4235 0.5994 0.4732 0.100 Uiso 1 1 calc R . . H34C H 0.3630 0.7073 0.4592 0.100 Uiso 1 1 calc R . . C35 C 0.4318(7) 0.3961(13) 0.3641(8) 0.065(4) Uani 1 1 d . . . H35A H 0.4579 0.4324 0.3271 0.098 Uiso 1 1 calc R . . H35B H 0.4290 0.3067 0.3569 0.098 Uiso 1 1 calc R . . H35C H 0.4589 0.4151 0.4173 0.098 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Rh1 0.0353(5) 0.0303(5) 0.0332(6) 0.0026(4) 0.0082(4) 0.0004(4) Sb1 0.0455(5) 0.0335(4) 0.0324(5) 0.0028(4) 0.0060(4) -0.0012(4) S1 0.0425(19) 0.0416(17) 0.045(2) -0.0003(15) 0.0121(16) 0.0014(14) F1 0.084(7) 0.052(5) 0.108(8) 0.013(5) 0.001(6) -0.029(5) F2 0.104(7) 0.083(6) 0.071(6) 0.017(5) 0.055(6) 0.041(5) F3 0.133(8) 0.064(5) 0.064(6) 0.011(4) 0.058(6) 0.024(5) F4 0.086(7) 0.045(5) 0.083(7) 0.005(4) -0.003(5) -0.020(4) F5 0.056(5) 0.079(6) 0.064(6) 0.030(5) -0.009(4) 0.000(4) F6 0.072(6) 0.072(5) 0.053(5) 0.018(4) 0.009(4) 0.020(4) O1 0.042(5) 0.033(4) 0.051(6) -0.001(4) 0.018(4) 0.003(4) O2 0.070(7) 0.055(5) 0.045(6) 0.012(4) 0.035(5) -0.001(5) N1 0.052(7) 0.032(5) 0.039(6) 0.007(5) 0.014(5) 0.001(5) N2 0.041(6) 0.033(5) 0.045(7) 0.000(5) 0.019(5) -0.001(4) C1 0.037(7) 0.040(7) 0.035(7) 0.001(6) 0.014(6) 0.000(5) C2 0.044(7) 0.046(7) 0.025(7) 0.002(6) -0.004(6) -0.009(6) C3 0.040(8) 0.046(8) 0.059(10) 0.014(7) 0.003(7) -0.019(6) C4 0.037(7) 0.038(7) 0.057(9) 0.010(6) 0.006(7) -0.005(6) C5 0.022(6) 0.044(7) 0.037(7) 0.015(6) 0.006(5) -0.001(5) C6 0.055(8) 0.020(6) 0.049(8) 0.007(5) 0.015(7) -0.004(5) C7 0.027(6) 0.045(7) 0.044(8) 0.003(6) 0.002(6) 0.008(5) C8 0.045(8) 0.061(9) 0.051(9) -0.008(7) 0.013(7) 0.027(7) C9 0.075(10) 0.031(7) 0.042(8) -0.005(6) 0.011(8) 0.003(7) C10 0.031(7) 0.040(7) 0.045(8) 0.005(6) -0.001(6) -0.010(5) C11 0.039(7) 0.031(6) 0.040(8) -0.004(5) 0.006(6) -0.001(5) C12 0.053(8) 0.033(7) 0.048(8) 0.007(6) 0.015(7) -0.004(6) C13 0.054(8) 0.032(6) 0.039(8) 0.010(6) 0.012(7) 0.003(6) C14 0.058(9) 0.047(8) 0.053(9) 0.009(7) 0.010(7) 0.008(7) C15 0.052(9) 0.063(9) 0.063(11) 0.012(8) 0.013(8) -0.019(7) C16 0.035(8) 0.058(9) 0.095(13) -0.004(9) 0.000(8) -0.014(7) C17 0.062(11) 0.082(12) 0.080(13) -0.015(10) 0.024(9) -0.030(9) C18 0.051(9) 0.052(8) 0.053(9) 0.021(7) 0.012(7) 0.009(7) C19 0.059(9) 0.042(7) 0.053(9) -0.013(6) 0.024(7) -0.007(6) C20 0.059(10) 0.040(8) 0.086(12) 0.003(7) 0.023(9) 0.009(7) C21 0.053(9) 0.043(8) 0.097(13) 0.008(8) 0.026(9) -0.001(7) C22 0.049(8) 0.073(10) 0.041(8) -0.006(7) 0.024(7) -0.021(7) C23 0.049(8) 0.050(8) 0.043(8) -0.001(6) 0.007(7) 0.013(7) C24 0.063(10) 0.053(9) 0.059(10) 0.010(7) 0.024(8) -0.010(7) C25 0.040(8) 0.086(11) 0.050(9) 0.003(8) 0.008(7) 0.001(7) C26 0.036(7) 0.043(7) 0.047(8) 0.019(6) 0.027(6) 0.010(5) C27 0.031(7) 0.042(7) 0.039(8) 0.006(6) -0.002(6) -0.004(5) C28 0.051(8) 0.038(7) 0.037(7) 0.004(6) 0.019(6) 0.008(6) C29 0.049(8) 0.031(6) 0.034(7) 0.002(5) 0.009(6) -0.013(5) C30 0.049(8) 0.036(6) 0.029(7) 0.009(5) 0.008(6) 0.003(6) C31 0.104(13) 0.043(8) 0.041(9) -0.014(6) 0.033(9) -0.009(8) C32 0.049(9) 0.075(10) 0.060(10) 0.031(8) -0.001(8) -0.011(8) C33 0.084(11) 0.040(8) 0.060(10) 0.018(7) 0.023(9) 0.025(7) C34 0.087(12) 0.064(9) 0.050(9) -0.003(7) 0.015(9) -0.038(8) C35 0.056(10) 0.077(10) 0.066(11) 0.030(8) 0.021(8) 0.013(8) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Rh1 N1 2.110(10) . ? Rh1 C26 2.137(11) . ? Rh1 N2 2.140(9) . ? Rh1 C27 2.140(12) . ? Rh1 C30 2.149(11) . ? Rh1 C29 2.161(10) . ? Rh1 C28 2.171(11) . ? Rh1 O1 2.201(7) . ? Rh1 S1 2.779(3) . ? Sb1 F3 1.855(7) . ? Sb1 F6 1.856(7) . ? Sb1 F2 1.862(7) . ? Sb1 F4 1.863(7) . ? Sb1 F1 1.866(7) . ? Sb1 F5 1.875(7) . ? S1 O2 1.443(8) . ? S1 O1 1.492(8) . ? S1 N2 1.589(9) . ? S1 C19 1.776(14) . ? N1 C1 1.359(14) . ? N1 C5 1.371(14) . ? N2 C12 1.483(14) . ? C1 C2 1.356(15) . ? C1 H1A 0.9500 . ? C2 C3 1.392(16) . ? C2 H2B 0.9500 . ? C3 C4 1.366(17) . ? C3 H3A 0.9500 . ? C4 C5 1.385(16) . ? C4 H4A 0.9500 . ? C5 C6 1.499(16) . ? C6 C11 1.363(16) . ? C6 C7 1.414(15) . ? C7 C8 1.354(16) . ? C7 H7A 0.9500 . ? C8 C9 1.386(17) . ? C8 H8A 0.9500 . ? C9 C10 1.391(16) . ? C9 H9A 0.9500 . ? C10 C11 1.392(15) . ? C10 H10A 0.9500 . ? C11 C12 1.561(15) . ? C12 C13 1.527(16) . ? C12 H12A 1.0000 . ? C13 C18 1.366(17) . ? C13 C14 1.389(16) . ? C14 C15 1.379(18) . ? C14 H14A 0.9500 . ? C15 C16 1.370(19) . ? C15 H15A 0.9500 . ? C16 C17 1.355(19) . ? C16 H16A 0.9500 . ? C17 C18 1.382(18) . ? C17 H17A 0.9500 . ? C18 H18A 0.9500 . ? C19 C20 1.377(17) . ? C19 C24 1.400(17) . ? C20 C21 1.416(18) . ? C20 H20A 0.9500 . ? C21 C22 1.390(18) . ? C21 H21A 0.9500 . ? C22 C23 1.411(17) . ? C22 C25 1.489(17) . ? C23 C24 1.391(18) . ? C23 H23A 0.9500 . ? C24 H24A 0.9500 . ? C25 H25A 0.9800 . ? C25 H25B 0.9800 . ? C25 H25C 0.9800 . ? C26 C30 1.401(17) . ? C26 C27 1.432(15) . ? C26 C31 1.487(16) . ? C27 C28 1.393(16) . ? C27 C32 1.482(16) . ? C28 C29 1.444(16) . ? C28 C33 1.505(15) . ? C29 C30 1.463(15) . ? C29 C34 1.487(16) . ? C30 C35 1.530(16) . ? C31 H31A 0.9800 . ? C31 H31B 0.9800 . ? C31 H31C 0.9800 . ? C32 H32A 0.9800 . ? C32 H32B 0.9800 . ? C32 H32C 0.9800 . ? C33 H33A 0.9800 . ? C33 H33B 0.9800 . ? C33 H33C 0.9800 . ? C34 H34A 0.9800 . ? C34 H34B 0.9800 . ? C34 H34C 0.9800 . ? C35 H35A 0.9800 . ? C35 H35B 0.9800 . ? C35 H35C 0.9800 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag N1 Rh1 C26 127.5(4) . . ? N1 Rh1 N2 85.5(4) . . ? C26 Rh1 N2 105.9(4) . . ? N1 Rh1 C27 164.7(4) . . ? C26 Rh1 C27 39.1(4) . . ? N2 Rh1 C27 104.7(4) . . ? N1 Rh1 C30 99.9(4) . . ? C26 Rh1 C30 38.2(4) . . ? N2 Rh1 C30 136.0(4) . . ? C27 Rh1 C30 64.8(5) . . ? N1 Rh1 C29 104.2(4) . . ? C26 Rh1 C29 65.4(4) . . ? N2 Rh1 C29 169.7(4) . . ? C27 Rh1 C29 65.1(4) . . ? C30 Rh1 C29 39.7(4) . . ? N1 Rh1 C28 138.4(4) . . ? C26 Rh1 C28 64.3(4) . . ? N2 Rh1 C28 133.3(4) . . ? C27 Rh1 C28 37.7(4) . . ? C30 Rh1 C28 64.8(4) . . ? C29 Rh1 C28 38.9(4) . . ? N1 Rh1 O1 83.9(3) . . ? C26 Rh1 O1 148.2(4) . . ? N2 Rh1 O1 67.0(3) . . ? C27 Rh1 O1 110.5(4) . . ? C30 Rh1 O1 156.7(4) . . ? C29 Rh1 O1 117.0(4) . . ? C28 Rh1 O1 97.1(3) . . ? N1 Rh1 S1 83.4(3) . . ? C26 Rh1 S1 133.3(3) . . ? N2 Rh1 S1 34.7(2) . . ? C27 Rh1 S1 111.5(3) . . ? C30 Rh1 S1 170.2(3) . . ? C29 Rh1 S1 148.5(3) . . ? C28 Rh1 S1 118.4(3) . . ? O1 Rh1 S1 32.3(2) . . ? F3 Sb1 F6 90.4(4) . . ? F3 Sb1 F2 179.3(5) . . ? F6 Sb1 F2 89.9(4) . . ? F3 Sb1 F4 89.7(4) . . ? F6 Sb1 F4 92.0(4) . . ? F2 Sb1 F4 90.9(4) . . ? F3 Sb1 F1 89.2(4) . . ? F6 Sb1 F1 89.0(4) . . ? F2 Sb1 F1 90.2(4) . . ? F4 Sb1 F1 178.5(4) . . ? F3 Sb1 F5 90.4(4) . . ? F6 Sb1 F5 178.5(3) . . ? F2 Sb1 F5 89.2(4) . . ? F4 Sb1 F5 89.3(4) . . ? F1 Sb1 F5 89.7(4) . . ? O2 S1 O1 117.4(5) . . ? O2 S1 N2 115.2(5) . . ? O1 S1 N2 102.1(5) . . ? O2 S1 C19 106.2(6) . . ? O1 S1 C19 106.0(5) . . ? N2 S1 C19 109.6(6) . . ? O2 S1 Rh1 134.4(4) . . ? O1 S1 Rh1 52.0(3) . . ? N2 S1 Rh1 50.1(3) . . ? C19 S1 Rh1 119.4(4) . . ? S1 O1 Rh1 95.7(4) . . ? C1 N1 C5 117.6(10) . . ? C1 N1 Rh1 118.4(8) . . ? C5 N1 Rh1 124.1(8) . . ? C12 N2 S1 116.1(8) . . ? C12 N2 Rh1 127.8(7) . . ? S1 N2 Rh1 95.2(4) . . ? C2 C1 N1 124.2(11) . . ? C2 C1 H1A 117.9 . . ? N1 C1 H1A 117.9 . . ? C1 C2 C3 118.1(12) . . ? C1 C2 H2B 120.9 . . ? C3 C2 H2B 120.9 . . ? C4 C3 C2 118.8(13) . . ? C4 C3 H3A 120.6 . . ? C2 C3 H3A 120.6 . . ? C3 C4 C5 121.3(12) . . ? C3 C4 H4A 119.4 . . ? C5 C4 H4A 119.4 . . ? N1 C5 C4 119.9(12) . . ? N1 C5 C6 120.0(10) . . ? C4 C5 C6 120.1(11) . . ? C11 C6 C7 120.4(11) . . ? C11 C6 C5 123.7(11) . . ? C7 C6 C5 115.8(11) . . ? C8 C7 C6 120.0(12) . . ? C8 C7 H7A 120.0 . . ? C6 C7 H7A 120.0 . . ? C7 C8 C9 120.7(11) . . ? C7 C8 H8A 119.6 . . ? C9 C8 H8A 119.6 . . ? C8 C9 C10 118.9(12) . . ? C8 C9 H9A 120.5 . . ? C10 C9 H9A 120.5 . . ? C9 C10 C11 121.1(12) . . ? C9 C10 H10A 119.5 . . ? C11 C10 H10A 119.5 . . ? C6 C11 C10 118.8(11) . . ? C6 C11 C12 122.4(11) . . ? C10 C11 C12 118.6(11) . . ? N2 C12 C13 112.3(10) . . ? N2 C12 C11 109.6(9) . . ? C13 C12 C11 113.5(10) . . ? N2 C12 H12A 107.0 . . ? C13 C12 H12A 107.0 . . ? C11 C12 H12A 107.0 . . ? C18 C13 C14 119.3(13) . . ? C18 C13 C12 120.5(11) . . ? C14 C13 C12 120.2(12) . . ? C15 C14 C13 118.1(13) . . ? C15 C14 H14A 120.9 . . ? C13 C14 H14A 120.9 . . ? C16 C15 C14 122.4(13) . . ? C16 C15 H15A 118.8 . . ? C14 C15 H15A 118.8 . . ? C17 C16 C15 118.7(14) . . ? C17 C16 H16A 120.6 . . ? C15 C16 H16A 120.6 . . ? C16 C17 C18 120.2(16) . . ? C16 C17 H17A 119.9 . . ? C18 C17 H17A 119.9 . . ? C13 C18 C17 121.2(13) . . ? C13 C18 H18A 119.4 . . ? C17 C18 H18A 119.4 . . ? C20 C19 C24 119.4(13) . . ? C20 C19 S1 119.9(11) . . ? C24 C19 S1 120.6(10) . . ? C19 C20 C21 120.3(13) . . ? C19 C20 H20A 119.8 . . ? C21 C20 H20A 119.8 . . ? C22 C21 C20 120.0(13) . . ? C22 C21 H21A 120.0 . . ? C20 C21 H21A 120.0 . . ? C21 C22 C23 119.7(13) . . ? C21 C22 C25 119.8(13) . . ? C23 C22 C25 120.5(13) . . ? C24 C23 C22 119.3(13) . . ? C24 C23 H23A 120.3 . . ? C22 C23 H23A 120.3 . . ? C23 C24 C19 121.2(13) . . ? C23 C24 H24A 119.4 . . ? C19 C24 H24A 119.4 . . ? C22 C25 H25A 109.5 . . ? C22 C25 H25B 109.5 . . ? H25A C25 H25B 109.5 . . ? C22 C25 H25C 109.5 . . ? H25A C25 H25C 109.5 . . ? H25B C25 H25C 109.5 . . ? C30 C26 C27 108.4(11) . . ? C30 C26 C31 126.1(11) . . ? C27 C26 C31 125.3(12) . . ? C30 C26 Rh1 71.4(7) . . ? C27 C26 Rh1 70.6(7) . . ? C31 C26 Rh1 127.2(8) . . ? C28 C27 C26 108.4(11) . . ? C28 C27 C32 127.4(12) . . ? C26 C27 C32 124.0(12) . . ? C28 C27 Rh1 72.3(7) . . ? C26 C27 Rh1 70.3(7) . . ? C32 C27 Rh1 127.2(8) . . ? C27 C28 C29 109.2(10) . . ? C27 C28 C33 127.6(12) . . ? C29 C28 C33 123.1(12) . . ? C27 C28 Rh1 70.0(7) . . ? C29 C28 Rh1 70.1(6) . . ? C33 C28 Rh1 122.5(8) . . ? C28 C29 C30 105.6(10) . . ? C28 C29 C34 128.6(12) . . ? C30 C29 C34 125.6(12) . . ? C28 C29 Rh1 70.9(6) . . ? C30 C29 Rh1 69.7(6) . . ? C34 C29 Rh1 127.7(8) . . ? C26 C30 C29 108.3(11) . . ? C26 C30 C35 128.0(11) . . ? C29 C30 C35 123.6(12) . . ? C26 C30 Rh1 70.4(7) . . ? C29 C30 Rh1 70.6(6) . . ? C35 C30 Rh1 127.2(8) . . ? C26 C31 H31A 109.5 . . ? C26 C31 H31B 109.5 . . ? H31A C31 H31B 109.5 . . ? C26 C31 H31C 109.5 . . ? H31A C31 H31C 109.5 . . ? H31B C31 H31C 109.5 . . ? C27 C32 H32A 109.5 . . ? C27 C32 H32B 109.5 . . ? H32A C32 H32B 109.5 . . ? C27 C32 H32C 109.5 . . ? H32A C32 H32C 109.5 . . ? H32B C32 H32C 109.5 . . ? C28 C33 H33A 109.5 . . ? C28 C33 H33B 109.5 . . ? H33A C33 H33B 109.5 . . ? C28 C33 H33C 109.5 . . ? H33A C33 H33C 109.5 . . ? H33B C33 H33C 109.5 . . ? C29 C34 H34A 109.5 . . ? C29 C34 H34B 109.5 . . ? H34A C34 H34B 109.5 . . ? C29 C34 H34C 109.5 . . ? H34A C34 H34C 109.5 . . ? H34B C34 H34C 109.5 . . ? C30 C35 H35A 109.5 . . ? C30 C35 H35B 109.5 . . ? H35A C35 H35B 109.5 . . ? C30 C35 H35C 109.5 . . ? H35A C35 H35C 109.5 . . ? H35B C35 H35C 109.5 . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag N1 Rh1 S1 O2 -4.1(6) . . . . ? C26 Rh1 S1 O2 133.1(7) . . . . ? N2 Rh1 S1 O2 87.5(7) . . . . ? C27 Rh1 S1 O2 172.3(6) . . . . ? C30 Rh1 S1 O2 106(2) . . . . ? C29 Rh1 S1 O2 -110.6(8) . . . . ? C28 Rh1 S1 O2 -146.6(6) . . . . ? O1 Rh1 S1 O2 -93.0(7) . . . . ? N1 Rh1 S1 O1 89.0(5) . . . . ? C26 Rh1 S1 O1 -133.9(6) . . . . ? N2 Rh1 S1 O1 -179.5(7) . . . . ? C27 Rh1 S1 O1 -94.7(5) . . . . ? C30 Rh1 S1 O1 -160.5(19) . . . . ? C29 Rh1 S1 O1 -17.6(8) . . . . ? C28 Rh1 S1 O1 -53.6(6) . . . . ? N1 Rh1 S1 N2 -91.5(5) . . . . ? C26 Rh1 S1 N2 45.6(6) . . . . ? C27 Rh1 S1 N2 84.9(6) . . . . ? C30 Rh1 S1 N2 19(2) . . . . ? C29 Rh1 S1 N2 161.9(8) . . . . ? C28 Rh1 S1 N2 126.0(6) . . . . ? O1 Rh1 S1 N2 179.5(7) . . . . ? N1 Rh1 S1 C19 176.7(5) . . . . ? C26 Rh1 S1 C19 -46.2(6) . . . . ? N2 Rh1 S1 C19 -91.8(7) . . . . ? C27 Rh1 S1 C19 -6.9(6) . . . . ? C30 Rh1 S1 C19 -73(2) . . . . ? C29 Rh1 S1 C19 70.1(8) . . . . ? C28 Rh1 S1 C19 34.2(6) . . . . ? O1 Rh1 S1 C19 87.8(6) . . . . ? O2 S1 O1 Rh1 126.6(5) . . . . ? N2 S1 O1 Rh1 -0.4(5) . . . . ? C19 S1 O1 Rh1 -115.1(5) . . . . ? N1 Rh1 O1 S1 -87.4(4) . . . . ? C26 Rh1 O1 S1 83.4(8) . . . . ? N2 Rh1 O1 S1 0.3(4) . . . . ? C27 Rh1 O1 S1 98.1(5) . . . . ? C30 Rh1 O1 S1 171.8(9) . . . . ? C29 Rh1 O1 S1 169.8(5) . . . . ? C28 Rh1 O1 S1 134.5(5) . . . . ? C26 Rh1 N1 C1 133.9(8) . . . . ? N2 Rh1 N1 C1 -119.5(8) . . . . ? C27 Rh1 N1 C1 108.2(16) . . . . ? C30 Rh1 N1 C1 104.6(8) . . . . ? C29 Rh1 N1 C1 64.2(9) . . . . ? C28 Rh1 N1 C1 41.6(11) . . . . ? O1 Rh1 N1 C1 -52.2(8) . . . . ? S1 Rh1 N1 C1 -84.7(8) . . . . ? C26 Rh1 N1 C5 -44.7(10) . . . . ? N2 Rh1 N1 C5 61.9(8) . . . . ? C27 Rh1 N1 C5 -70.4(18) . . . . ? C30 Rh1 N1 C5 -74.0(9) . . . . ? C29 Rh1 N1 C5 -114.4(9) . . . . ? C28 Rh1 N1 C5 -137.0(8) . . . . ? O1 Rh1 N1 C5 129.2(9) . . . . ? S1 Rh1 N1 C5 96.7(8) . . . . ? O2 S1 N2 C12 8.9(11) . . . . ? O1 S1 N2 C12 137.3(9) . . . . ? C19 S1 N2 C12 -110.7(9) . . . . ? Rh1 S1 N2 C12 136.9(10) . . . . ? O2 S1 N2 Rh1 -128.0(5) . . . . ? O1 S1 N2 Rh1 0.4(5) . . . . ? C19 S1 N2 Rh1 112.4(5) . . . . ? N1 Rh1 N2 C12 -44.1(10) . . . . ? C26 Rh1 N2 C12 83.6(10) . . . . ? C27 Rh1 N2 C12 124.2(10) . . . . ? C30 Rh1 N2 C12 55.5(12) . . . . ? C29 Rh1 N2 C12 116(2) . . . . ? C28 Rh1 N2 C12 153.1(9) . . . . ? O1 Rh1 N2 C12 -129.4(10) . . . . ? S1 Rh1 N2 C12 -129.1(12) . . . . ? N1 Rh1 N2 S1 85.0(5) . . . . ? C26 Rh1 N2 S1 -147.3(5) . . . . ? C27 Rh1 N2 S1 -106.7(5) . . . . ? C30 Rh1 N2 S1 -175.4(5) . . . . ? C29 Rh1 N2 S1 -115(2) . . . . ? C28 Rh1 N2 S1 -77.8(7) . . . . ? O1 Rh1 N2 S1 -0.3(4) . . . . ? C5 N1 C1 C2 2.0(16) . . . . ? Rh1 N1 C1 C2 -176.7(9) . . . . ? N1 C1 C2 C3 -2.1(17) . . . . ? C1 C2 C3 C4 -0.6(17) . . . . ? C2 C3 C4 C5 3.3(17) . . . . ? C1 N1 C5 C4 0.9(15) . . . . ? Rh1 N1 C5 C4 179.4(8) . . . . ? C1 N1 C5 C6 -177.3(10) . . . . ? Rh1 N1 C5 C6 1.3(14) . . . . ? C3 C4 C5 N1 -3.5(17) . . . . ? C3 C4 C5 C6 174.7(10) . . . . ? N1 C5 C6 C11 -63.0(15) . . . . ? C4 C5 C6 C11 118.8(13) . . . . ? N1 C5 C6 C7 120.2(11) . . . . ? C4 C5 C6 C7 -58.0(14) . . . . ? C11 C6 C7 C8 2.2(18) . . . . ? C5 C6 C7 C8 179.1(11) . . . . ? C6 C7 C8 C9 -2.1(19) . . . . ? C7 C8 C9 C10 0(2) . . . . ? C8 C9 C10 C11 2.2(19) . . . . ? C7 C6 C11 C10 -0.2(17) . . . . ? C5 C6 C11 C10 -176.8(10) . . . . ? C7 C6 C11 C12 176.7(10) . . . . ? C5 C6 C11 C12 0.0(18) . . . . ? C9 C10 C11 C6 -2.1(18) . . . . ? C9 C10 C11 C12 -179.0(11) . . . . ? S1 N2 C12 C13 84.3(12) . . . . ? Rh1 N2 C12 C13 -155.1(8) . . . . ? S1 N2 C12 C11 -148.6(8) . . . . ? Rh1 N2 C12 C11 -28.0(14) . . . . ? C6 C11 C12 N2 71.9(15) . . . . ? C10 C11 C12 N2 -111.3(12) . . . . ? C6 C11 C12 C13 -161.7(11) . . . . ? C10 C11 C12 C13 15.2(15) . . . . ? N2 C12 C13 C18 40.4(16) . . . . ? C11 C12 C13 C18 -84.6(14) . . . . ? N2 C12 C13 C14 -138.9(11) . . . . ? C11 C12 C13 C14 96.2(14) . . . . ? C18 C13 C14 C15 1.4(19) . . . . ? C12 C13 C14 C15 -179.4(12) . . . . ? C13 C14 C15 C16 0(2) . . . . ? C14 C15 C16 C17 -2(2) . . . . ? C15 C16 C17 C18 1(2) . . . . ? C14 C13 C18 C17 -1(2) . . . . ? C12 C13 C18 C17 179.3(12) . . . . ? C16 C17 C18 C13 0(2) . . . . ? O2 S1 C19 C20 -52.6(12) . . . . ? O1 S1 C19 C20 -178.2(11) . . . . ? N2 S1 C19 C20 72.4(12) . . . . ? Rh1 S1 C19 C20 126.8(10) . . . . ? O2 S1 C19 C24 124.1(11) . . . . ? O1 S1 C19 C24 -1.4(12) . . . . ? N2 S1 C19 C24 -110.9(11) . . . . ? Rh1 S1 C19 C24 -56.4(12) . . . . ? C24 C19 C20 C21 3(2) . . . . ? S1 C19 C20 C21 179.3(11) . . . . ? C19 C20 C21 C22 -2(2) . . . . ? C20 C21 C22 C23 2(2) . . . . ? C20 C21 C22 C25 -178.0(13) . . . . ? C21 C22 C23 C24 -2.0(19) . . . . ? C25 C22 C23 C24 178.1(12) . . . . ? C22 C23 C24 C19 2(2) . . . . ? C20 C19 C24 C23 -2(2) . . . . ? S1 C19 C24 C23 -179.2(10) . . . . ? N1 Rh1 C26 C30 -51.3(8) . . . . ? N2 Rh1 C26 C30 -147.9(6) . . . . ? C27 Rh1 C26 C30 118.2(10) . . . . ? C29 Rh1 C26 C30 38.1(7) . . . . ? C28 Rh1 C26 C30 81.3(7) . . . . ? O1 Rh1 C26 C30 140.2(7) . . . . ? S1 Rh1 C26 C30 -172.9(5) . . . . ? N1 Rh1 C26 C27 -169.5(6) . . . . ? N2 Rh1 C26 C27 93.9(7) . . . . ? C30 Rh1 C26 C27 -118.2(10) . . . . ? C29 Rh1 C26 C27 -80.1(7) . . . . ? C28 Rh1 C26 C27 -36.9(7) . . . . ? O1 Rh1 C26 C27 22.1(11) . . . . ? S1 Rh1 C26 C27 68.9(8) . . . . ? N1 Rh1 C26 C31 70.4(13) . . . . ? N2 Rh1 C26 C31 -26.2(12) . . . . ? C27 Rh1 C26 C31 -120.1(14) . . . . ? C30 Rh1 C26 C31 121.7(14) . . . . ? C29 Rh1 C26 C31 159.8(13) . . . . ? C28 Rh1 C26 C31 -157.0(13) . . . . ? O1 Rh1 C26 C31 -98.0(12) . . . . ? S1 Rh1 C26 C31 -51.2(13) . . . . ? C30 C26 C27 C28 1.0(13) . . . . ? C31 C26 C27 C28 -174.9(10) . . . . ? Rh1 C26 C27 C28 62.7(8) . . . . ? C30 C26 C27 C32 176.1(11) . . . . ? C31 C26 C27 C32 0.2(18) . . . . ? Rh1 C26 C27 C32 -122.2(12) . . . . ? C30 C26 C27 Rh1 -61.7(8) . . . . ? C31 C26 C27 Rh1 122.4(11) . . . . ? N1 Rh1 C27 C28 -84.7(17) . . . . ? C26 Rh1 C27 C28 -117.8(10) . . . . ? N2 Rh1 C27 C28 144.9(7) . . . . ? C30 Rh1 C27 C28 -80.8(7) . . . . ? C29 Rh1 C27 C28 -36.8(7) . . . . ? O1 Rh1 C27 C28 74.4(7) . . . . ? S1 Rh1 C27 C28 109.1(6) . . . . ? N1 Rh1 C27 C26 33.1(19) . . . . ? N2 Rh1 C27 C26 -97.2(7) . . . . ? C30 Rh1 C27 C26 37.0(7) . . . . ? C29 Rh1 C27 C26 81.0(7) . . . . ? C28 Rh1 C27 C26 117.8(10) . . . . ? O1 Rh1 C27 C26 -167.8(6) . . . . ? S1 Rh1 C27 C26 -133.1(6) . . . . ? N1 Rh1 C27 C32 151.4(14) . . . . ? C26 Rh1 C27 C32 118.3(14) . . . . ? N2 Rh1 C27 C32 21.0(12) . . . . ? C30 Rh1 C27 C32 155.3(13) . . . . ? C29 Rh1 C27 C32 -160.7(13) . . . . ? C28 Rh1 C27 C32 -123.9(15) . . . . ? O1 Rh1 C27 C32 -49.5(12) . . . . ? S1 Rh1 C27 C32 -14.9(12) . . . . ? C26 C27 C28 C29 -2.1(13) . . . . ? C32 C27 C28 C29 -177.0(12) . . . . ? Rh1 C27 C28 C29 59.3(8) . . . . ? C26 C27 C28 C33 -177.6(11) . . . . ? C32 C27 C28 C33 7(2) . . . . ? Rh1 C27 C28 C33 -116.2(12) . . . . ? C26 C27 C28 Rh1 -61.4(8) . . . . ? C32 C27 C28 Rh1 123.7(13) . . . . ? N1 Rh1 C28 C27 156.6(7) . . . . ? C26 Rh1 C28 C27 38.3(7) . . . . ? N2 Rh1 C28 C27 -49.7(9) . . . . ? C30 Rh1 C28 C27 80.7(7) . . . . ? C29 Rh1 C28 C27 120.3(10) . . . . ? O1 Rh1 C28 C27 -114.6(7) . . . . ? S1 Rh1 C28 C27 -89.0(7) . . . . ? N1 Rh1 C28 C29 36.3(9) . . . . ? C26 Rh1 C28 C29 -82.0(7) . . . . ? N2 Rh1 C28 C29 -170.0(6) . . . . ? C27 Rh1 C28 C29 -120.3(10) . . . . ? C30 Rh1 C28 C29 -39.6(7) . . . . ? O1 Rh1 C28 C29 125.1(7) . . . . ? S1 Rh1 C28 C29 150.8(6) . . . . ? N1 Rh1 C28 C33 -80.9(13) . . . . ? C26 Rh1 C28 C33 160.8(13) . . . . ? N2 Rh1 C28 C33 72.8(13) . . . . ? C27 Rh1 C28 C33 122.5(14) . . . . ? C30 Rh1 C28 C33 -156.8(13) . . . . ? C29 Rh1 C28 C33 -117.2(14) . . . . ? O1 Rh1 C28 C33 7.9(12) . . . . ? S1 Rh1 C28 C33 33.5(12) . . . . ? C27 C28 C29 C30 2.3(13) . . . . ? C33 C28 C29 C30 178.1(10) . . . . ? Rh1 C28 C29 C30 61.5(7) . . . . ? C27 C28 C29 C34 177.3(11) . . . . ? C33 C28 C29 C34 -6.9(19) . . . . ? Rh1 C28 C29 C34 -123.5(12) . . . . ? C27 C28 C29 Rh1 -59.2(8) . . . . ? C33 C28 C29 Rh1 116.6(11) . . . . ? N1 Rh1 C29 C28 -156.1(6) . . . . ? C26 Rh1 C29 C28 78.9(7) . . . . ? N2 Rh1 C29 C28 45(2) . . . . ? C27 Rh1 C29 C28 35.6(7) . . . . ? C30 Rh1 C29 C28 115.5(10) . . . . ? O1 Rh1 C29 C28 -65.7(7) . . . . ? S1 Rh1 C29 C28 -55.2(10) . . . . ? N1 Rh1 C29 C30 88.4(7) . . . . ? C26 Rh1 C29 C30 -36.6(7) . . . . ? N2 Rh1 C29 C30 -71(2) . . . . ? C27 Rh1 C29 C30 -79.9(7) . . . . ? C28 Rh1 C29 C30 -115.5(10) . . . . ? O1 Rh1 C29 C30 178.8(6) . . . . ? S1 Rh1 C29 C30 -170.8(6) . . . . ? N1 Rh1 C29 C34 -31.5(12) . . . . ? C26 Rh1 C29 C34 -156.6(13) . . . . ? N2 Rh1 C29 C34 169.5(18) . . . . ? C27 Rh1 C29 C34 160.2(13) . . . . ? C30 Rh1 C29 C34 -119.9(15) . . . . ? C28 Rh1 C29 C34 124.6(15) . . . . ? O1 Rh1 C29 C34 58.8(13) . . . . ? S1 Rh1 C29 C34 69.3(14) . . . . ? C27 C26 C30 C29 0.4(13) . . . . ? C31 C26 C30 C29 176.3(10) . . . . ? Rh1 C26 C30 C29 -60.7(8) . . . . ? C27 C26 C30 C35 -176.4(11) . . . . ? C31 C26 C30 C35 -0.6(19) . . . . ? Rh1 C26 C30 C35 122.4(12) . . . . ? C27 C26 C30 Rh1 61.2(8) . . . . ? C31 C26 C30 Rh1 -123.0(11) . . . . ? C28 C29 C30 C26 -1.6(12) . . . . ? C34 C29 C30 C26 -176.9(11) . . . . ? Rh1 C29 C30 C26 60.6(8) . . . . ? C28 C29 C30 C35 175.4(10) . . . . ? C34 C29 C30 C35 0.2(18) . . . . ? Rh1 C29 C30 C35 -122.3(11) . . . . ? C28 C29 C30 Rh1 -62.3(7) . . . . ? C34 C29 C30 Rh1 122.5(12) . . . . ? N1 Rh1 C30 C26 141.0(7) . . . . ? N2 Rh1 C30 C26 47.3(9) . . . . ? C27 Rh1 C30 C26 -37.9(7) . . . . ? C29 Rh1 C30 C26 -118.6(10) . . . . ? C28 Rh1 C30 C26 -79.8(7) . . . . ? O1 Rh1 C30 C26 -121.4(10) . . . . ? S1 Rh1 C30 C26 32(2) . . . . ? N1 Rh1 C30 C29 -100.4(7) . . . . ? C26 Rh1 C30 C29 118.6(10) . . . . ? N2 Rh1 C30 C29 165.9(7) . . . . ? C27 Rh1 C30 C29 80.7(7) . . . . ? C28 Rh1 C30 C29 38.8(7) . . . . ? O1 Rh1 C30 C29 -2.8(14) . . . . ? S1 Rh1 C30 C29 150.4(16) . . . . ? N1 Rh1 C30 C35 17.6(12) . . . . ? C26 Rh1 C30 C35 -123.4(14) . . . . ? N2 Rh1 C30 C35 -76.1(13) . . . . ? C27 Rh1 C30 C35 -161.3(13) . . . . ? C29 Rh1 C30 C35 118.0(14) . . . . ? C28 Rh1 C30 C35 156.8(13) . . . . ? O1 Rh1 C30 C35 115.2(12) . . . . ? S1 Rh1 C30 C35 -92(2) . . . . ? _diffrn_measured_fraction_theta_max 0.992 _diffrn_reflns_theta_full 25.28 _diffrn_measured_fraction_theta_full 0.992 _refine_diff_density_max 0.941 _refine_diff_density_min -0.833 _refine_diff_density_rms 0.154