# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A
# This journal is © The Royal Society of Chemistry 2013

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
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# 
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#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_p
#TrackingRef '7044_web_deposit_cif_file_0_Yi-MinZhu_1315277797.Eu-bqdc (deposit).cif'

_database_code_depnum_ccdc_archive 'CCDC 843071'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
catena-((\m~4~-2,2'-biquinoline-4,4'-dicarboxylato-O,O',O'',O''')-bis(\m~3~-2,2'-biquinoline-4,4'-dicarboxylato-O,O,O',O'',O''')-aqua-tris(N,N-dimethylformamide-O)-bis-europium(iii) hemi(dimethylformamide) solvate monohydrate)
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
'C34.5 H26.5 Eu N4.5 O8,0.25(C3 H7 N O),0.5(H2 O)'
_chemical_formula_sum            'C35.25 H29.25 Eu N4.75 O8.75'
_chemical_formula_weight         811.34

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1
_symmetry_space_group_name_Hall  '-P 1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.1220(13)
_cell_length_b                   11.9382(14)
_cell_length_c                   14.1843(17)
_cell_angle_alpha                74.869(2)
_cell_angle_beta                 76.480(2)
_cell_angle_gamma                73.859(2)
_cell_volume                     1719.8(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    5575
_cell_measurement_theta_min      2.23
_cell_measurement_theta_max      25.96

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.11
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.567
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             814
_exptl_absorpt_coefficient_mu    1.884
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6931
_exptl_absorpt_correction_T_max  0.8195
_exptl_absorpt_process_details   'SADABS,(Bruker, 1997)'

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            13536
_diffrn_reflns_av_R_equivalents  0.0351
_diffrn_reflns_av_sigmaI/netI    0.0583
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         1.51
_diffrn_reflns_theta_max         26.08
_reflns_number_total             6684
_reflns_number_gt                5484
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0774P)^2^+0.9026P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6684
_refine_ls_number_parameters     514
_refine_ls_number_restraints     57
_refine_ls_R_factor_all          0.0593
_refine_ls_R_factor_gt           0.0421
_refine_ls_wR_factor_ref         0.1324
_refine_ls_wR_factor_gt          0.1163
_refine_ls_goodness_of_fit_ref   1.127
_refine_ls_restrained_S_all      1.131
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu -0.08936(3) -0.12205(2) -0.89869(2) 0.01683(11) Uani 1 1 d . . .
O1 O 0.1060(4) -0.2109(4) -0.9898(3) 0.0292(11) Uani 1 1 d . A .
O2 O 0.2113(4) -0.0772(4) -1.0898(3) 0.0310(11) Uani 1 1 d . . .
O3 O 0.0550(4) -0.0013(3) -0.9150(3) 0.0202(9) Uani 1 1 d . . .
O4 O 0.1625(5) 0.1351(4) -0.9504(3) 0.0369(12) Uani 1 1 d . . .
O5 O 0.0345(4) -0.2366(4) -0.7681(3) 0.0270(10) Uani 1 1 d . A .
O6 O -0.1317(5) -0.1002(4) -0.7231(3) 0.0345(11) Uani 1 1 d . A .
O7 O -0.0907(7) -0.3330(5) -0.8762(4) 0.0594(18) Uani 1 1 d . A .
N1 N 0.5053(5) -0.4698(5) -1.1302(4) 0.0255(12) Uani 1 1 d . . .
N2 N 0.1961(5) -0.0165(4) -0.5935(4) 0.0209(11) Uani 1 1 d . . .
N3 N 0.0280(5) -0.2632(4) -0.4011(4) 0.0241(11) Uani 1 1 d . A .
N4 N 0.0217(10) -0.5274(6) -0.8627(5) 0.068(3) Uani 1 1 d . A .
C1 C 0.4655(6) -0.4564(6) -1.0390(5) 0.0277(15) Uani 1 1 d . . .
C2 C 0.3625(7) -0.3634(6) -1.0116(5) 0.0346(17) Uani 1 1 d . . .
H2B H 0.3344 -0.3588 -0.9438 0.041 Uiso 1 1 calc R . .
C3 C 0.3045(6) -0.2815(6) -1.0824(5) 0.0299(15) Uani 1 1 d . A .
C4 C 0.3426(6) -0.2912(5) -1.1825(4) 0.0216(13) Uani 1 1 d . . .
C5 C 0.2847(6) -0.2144(6) -1.2616(5) 0.0259(14) Uani 1 1 d . . .
H5A H 0.2204 -0.1457 -1.2496 0.031 Uiso 1 1 calc R . .
C6 C 0.3185(7) -0.2364(6) -1.3537(5) 0.0364(17) Uani 1 1 d . . .
H6A H 0.2763 -0.1854 -1.4057 0.044 Uiso 1 1 calc R . .
C7 C 0.4178(8) -0.3365(7) -1.3723(5) 0.047(2) Uani 1 1 d . . .
H7A H 0.4402 -0.3529 -1.4371 0.056 Uiso 1 1 calc R . .
C8 C 0.4820(7) -0.4099(6) -1.3000(5) 0.0327(16) Uani 1 1 d . . .
H8A H 0.5517 -0.4735 -1.3151 0.039 Uiso 1 1 calc R . .
C9 C 0.4434(6) -0.3901(6) -1.2021(5) 0.0264(14) Uani 1 1 d . . .
C10 C 0.1978(6) -0.1807(6) -1.0524(4) 0.0269(15) Uani 1 1 d . . .
C11 C 0.1084(5) 0.0760(5) -0.6259(4) 0.0176(12) Uani 1 1 d . . .
C12 C 0.0769(5) 0.1002(5) -0.7213(4) 0.0170(12) Uani 1 1 d . . .
H12A H 0.0121 0.1677 -0.7412 0.020 Uiso 1 1 calc R . .
C13 C 0.1398(5) 0.0265(5) -0.7841(4) 0.0179(12) Uani 1 1 d . A .
C14 C 0.2365(6) -0.0758(5) -0.7531(5) 0.0225(13) Uani 1 1 d . . .
C15 C 0.3081(6) -0.1590(6) -0.8134(5) 0.0301(15) Uani 1 1 d . . .
H15A H 0.2904 -0.1498 -0.8776 0.036 Uiso 1 1 calc R . .
C16 C 0.4017(7) -0.2512(6) -0.7793(5) 0.0386(18) Uani 1 1 d . . .
H16A H 0.4510 -0.3050 -0.8203 0.046 Uiso 1 1 calc R . .
C17 C 0.4252(8) -0.2665(6) -0.6826(5) 0.0402(19) Uani 1 1 d . . .
H17A H 0.4889 -0.3325 -0.6584 0.048 Uiso 1 1 calc R . .
C18 C 0.3590(7) -0.1893(6) -0.6237(5) 0.0376(17) Uani 1 1 d . . .
H18A H 0.3792 -0.2005 -0.5599 0.045 Uiso 1 1 calc R . .
C19 C 0.2598(6) -0.0918(5) -0.6553(4) 0.0233(13) Uani 1 1 d . . .
C20 C 0.1175(6) 0.0563(5) -0.8898(4) 0.0185(12) Uani 1 1 d . . .
C21 C -0.0451(6) -0.1624(5) -0.4403(4) 0.0187(12) Uani 1 1 d . . .
C22 C -0.0660(5) -0.1365(5) -0.5398(4) 0.0174(12) Uani 1 1 d . A .
H22A H -0.1182 -0.0621 -0.5657 0.021 Uiso 1 1 calc R . .
C23 C -0.0116(5) -0.2178(5) -0.5977(4) 0.0184(12) Uani 1 1 d . . .
C24 C 0.0672(6) -0.3298(5) -0.5578(4) 0.0200(12) Uani 1 1 d . A .
C25 C 0.1244(6) -0.4253(6) -0.6068(5) 0.0303(15) Uani 1 1 d . . .
H25A H 0.1153 -0.4161 -0.6735 0.036 Uiso 1 1 calc R A .
C26 C 0.1922(7) -0.5302(6) -0.5604(6) 0.0406(18) Uani 1 1 d . A .
H26A H 0.2275 -0.5938 -0.5945 0.049 Uiso 1 1 calc R . .
C27 C 0.2109(7) -0.5460(6) -0.4633(5) 0.0377(17) Uani 1 1 d . . .
H27A H 0.2601 -0.6192 -0.4323 0.045 Uiso 1 1 calc R A .
C28 C 0.1576(7) -0.4547(6) -0.4125(5) 0.0370(17) Uani 1 1 d . A .
H28A H 0.1707 -0.4652 -0.3466 0.044 Uiso 1 1 calc R . .
C29 C 0.0836(6) -0.3456(6) -0.4582(5) 0.0231(13) Uani 1 1 d . . .
C30 C -0.0374(6) -0.1841(5) -0.7035(4) 0.0195(12) Uani 1 1 d . A .
C31 C 0.0097(11) -0.4136(7) -0.8665(6) 0.056(3) Uani 1 1 d . . .
H31A H 0.0825 -0.3900 -0.8616 0.067 Uiso 1 1 calc R A .
C32 C 0.1378(14) -0.6130(8) -0.8461(8) 0.097(5) Uani 1 1 d . . .
H32A H 0.2020 -0.5718 -0.8447 0.145 Uiso 1 1 calc R A .
H32B H 0.1680 -0.6571 -0.8998 0.145 Uiso 1 1 calc R . .
H32C H 0.1229 -0.6687 -0.7826 0.145 Uiso 1 1 calc R . .
C33 C -0.0834(13) -0.5726(9) -0.8681(7) 0.092(4) Uani 1 1 d . . .
H33A H -0.1571 -0.5061 -0.8792 0.138 Uiso 1 1 calc R A .
H33B H -0.1049 -0.6280 -0.8057 0.138 Uiso 1 1 calc R . .
H33C H -0.0596 -0.6145 -0.9230 0.138 Uiso 1 1 calc R . .
O1W O -0.2935(16) -0.1548(15) -0.8379(16) 0.064(5) Uani 0.50 1 d P A 1
H1WA H -0.3003 -0.2128 -0.8577 0.096 Uiso 0.50 1 calc PR A 1
O8 O -0.3229(15) -0.1015(12) -0.8463(14) 0.042(4) Uani 0.50 1 d PU A 2
N5 N -0.4865(10) 0.0487(10) -0.8079(10) 0.039(3) Uani 0.50 1 d PU A 2
C34 C -0.3943(14) -0.0357(13) -0.7934(13) 0.041(4) Uani 0.50 1 d P A 2
H34A H -0.3752 -0.0528 -0.7285 0.049 Uiso 0.50 1 calc PR A 2
C35 C -0.551(2) 0.103(2) -0.710(2) 0.065(6) Uani 0.50 1 d PU A 2
H35A H -0.5229 0.0458 -0.6519 0.098 Uiso 0.50 1 calc PR A 2
H35B H -0.6438 0.1190 -0.7026 0.098 Uiso 0.50 1 calc PR A 2
H35C H -0.5259 0.1776 -0.7172 0.098 Uiso 0.50 1 calc PR A 2
C36 C -0.5016(15) 0.0941(17) -0.9239(14) 0.060(5) Uani 0.50 1 d P A 2
H36A H -0.4437 0.0368 -0.9620 0.090 Uiso 0.50 1 calc PR A 2
H36B H -0.4807 0.1723 -0.9495 0.090 Uiso 0.50 1 calc PR A 2
H36C H -0.5894 0.1007 -0.9300 0.090 Uiso 0.50 1 calc PR A 2
O9 O -0.577(2) 0.139(2) -0.7509(16) 0.042(6) Uani 0.25 1 d PDU B 3
N6 N -0.5187(18) 0.0475(17) -0.5984(14) 0.083(5) Uani 0.50 1 d PDU B 3
C37 C -0.515(5) 0.054(4) -0.693(2) 0.083(17) Uani 0.25 1 d PDU B 3
H37A H -0.4614 -0.0113 -0.7212 0.100 Uiso 0.25 1 calc PR B 3
C38 C -0.600(2) 0.097(2) -0.514(2) 0.025(5) Uani 0.25 1 d PU . 3
C39 C -0.408(2) -0.059(2) -0.562(2) 0.031(6) Uani 0.25 1 d PU . 3
O2W O -0.323(2) -0.339(2) -0.9005(19) 0.145(8) Uani 0.50 1 d PU . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Eu1 0.02412(18) 0.01650(17) 0.01047(16) -0.00381(10) -0.00366(11) -0.00421(11)
O1 0.039(3) 0.020(2) 0.017(2) -0.0082(18) -0.001(2) 0.013(2)
O2 0.021(2) 0.029(3) 0.032(3) -0.005(2) -0.0018(19) 0.0077(19)
O3 0.027(2) 0.020(2) 0.016(2) -0.0041(16) -0.0080(17) -0.0050(18)
O4 0.057(3) 0.044(3) 0.020(2) 0.001(2) -0.011(2) -0.031(3)
O5 0.033(2) 0.031(2) 0.014(2) -0.0121(18) -0.0048(18) 0.005(2)
O6 0.039(3) 0.040(3) 0.020(2) -0.013(2) -0.012(2) 0.012(2)
O7 0.096(5) 0.038(3) 0.061(4) 0.016(3) -0.046(4) -0.042(4)
N1 0.026(3) 0.025(3) 0.018(3) -0.013(2) -0.003(2) 0.012(2)
N2 0.024(3) 0.024(3) 0.014(2) -0.005(2) -0.005(2) -0.003(2)
N3 0.031(3) 0.021(3) 0.021(3) -0.005(2) -0.011(2) 0.000(2)
N4 0.156(9) 0.030(4) 0.035(4) 0.007(3) -0.030(5) -0.050(5)
C1 0.028(3) 0.026(3) 0.027(4) -0.010(3) -0.016(3) 0.012(3)
C2 0.040(4) 0.033(4) 0.020(3) -0.015(3) -0.013(3) 0.024(3)
C3 0.030(4) 0.026(3) 0.029(4) -0.012(3) -0.010(3) 0.012(3)
C4 0.023(3) 0.020(3) 0.020(3) -0.007(2) -0.007(2) 0.005(2)
C5 0.025(3) 0.024(3) 0.025(3) -0.004(3) -0.007(3) 0.002(3)
C6 0.043(4) 0.027(4) 0.024(4) 0.002(3) -0.009(3) 0.012(3)
C7 0.066(5) 0.038(4) 0.022(4) -0.012(3) -0.009(4) 0.016(4)
C8 0.040(4) 0.025(3) 0.022(3) -0.005(3) -0.006(3) 0.012(3)
C9 0.023(3) 0.027(3) 0.023(3) -0.008(3) -0.001(3) 0.004(3)
C10 0.033(4) 0.025(3) 0.014(3) -0.006(3) -0.011(3) 0.013(3)
C11 0.022(3) 0.021(3) 0.014(3) -0.004(2) -0.006(2) -0.009(2)
C12 0.021(3) 0.020(3) 0.013(3) -0.004(2) -0.006(2) -0.006(2)
C13 0.020(3) 0.020(3) 0.014(3) -0.002(2) -0.002(2) -0.007(2)
C14 0.030(3) 0.019(3) 0.024(3) -0.007(2) -0.010(3) -0.008(3)
C15 0.038(4) 0.030(4) 0.023(3) -0.010(3) -0.013(3) -0.001(3)
C16 0.049(4) 0.031(4) 0.033(4) -0.019(3) -0.012(3) 0.012(3)
C17 0.056(5) 0.025(4) 0.035(4) -0.011(3) -0.022(4) 0.014(3)
C18 0.054(5) 0.031(4) 0.024(4) -0.002(3) -0.020(3) 0.005(3)
C19 0.029(3) 0.024(3) 0.018(3) -0.005(2) -0.010(3) -0.003(3)
C20 0.025(3) 0.017(3) 0.017(3) -0.010(2) -0.006(2) -0.002(2)
C21 0.023(3) 0.020(3) 0.013(3) -0.005(2) -0.002(2) -0.006(2)
C22 0.021(3) 0.019(3) 0.014(3) -0.004(2) -0.009(2) -0.002(2)
C23 0.017(3) 0.023(3) 0.014(3) -0.005(2) -0.001(2) -0.002(2)
C24 0.023(3) 0.019(3) 0.016(3) -0.004(2) -0.005(2) 0.000(2)
C25 0.033(4) 0.034(4) 0.023(3) -0.015(3) -0.008(3) 0.003(3)
C26 0.050(5) 0.024(4) 0.042(4) -0.013(3) -0.014(4) 0.013(3)
C27 0.047(4) 0.024(4) 0.035(4) -0.003(3) -0.019(3) 0.010(3)
C28 0.042(4) 0.034(4) 0.031(4) -0.006(3) -0.020(3) 0.008(3)
C29 0.019(3) 0.026(3) 0.021(3) -0.007(3) -0.001(2) 0.000(3)
C30 0.027(3) 0.020(3) 0.013(3) -0.003(2) -0.004(2) -0.007(3)
C31 0.107(8) 0.029(4) 0.040(5) 0.012(4) -0.033(5) -0.032(5)
C32 0.193(14) 0.020(5) 0.070(7) -0.003(5) -0.030(8) -0.013(7)
C33 0.200(14) 0.057(6) 0.052(6) 0.013(5) -0.052(8) -0.082(8)
O1W 0.031(9) 0.063(11) 0.116(14) -0.059(12) 0.016(8) -0.024(9)
O8 0.031(7) 0.037(7) 0.059(7) -0.028(6) 0.008(5) -0.008(6)
N5 0.011(5) 0.030(5) 0.072(7) -0.025(5) 0.018(5) -0.005(4)
C34 0.028(8) 0.038(9) 0.062(11) -0.013(8) 0.002(7) -0.020(7)
C35 0.051(9) 0.058(10) 0.083(10) -0.018(8) 0.006(8) -0.018(8)
C36 0.036(9) 0.067(12) 0.076(13) 0.027(10) -0.022(9) -0.040(9)
O9 0.036(9) 0.057(10) 0.043(9) 0.006(7) -0.024(7) -0.030(7)
N6 0.082(9) 0.093(9) 0.103(10) -0.034(7) -0.019(7) -0.051(7)
C37 0.076(18) 0.085(19) 0.091(19) 0.000(10) -0.027(10) -0.028(10)
C38 0.020(9) 0.030(9) 0.032(9) -0.014(8) -0.005(7) -0.007(7)
C39 0.014(8) 0.031(9) 0.041(10) -0.006(8) 0.004(7) -0.001(7)
O2W 0.147(11) 0.143(11) 0.167(12) -0.059(9) -0.021(9) -0.047(9)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1W 2.335(17) . ?
Eu1 O2 2.373(4) 2_553 ?
Eu1 O1 2.375(4) . ?
Eu1 O3 2.377(4) . ?
Eu1 O5 2.454(4) . ?
Eu1 O7 2.458(5) . ?
Eu1 O8 2.489(17) . ?
Eu1 O6 2.494(4) . ?
Eu1 O4 2.516(4) 2_553 ?
Eu1 O3 2.666(4) 2_553 ?
Eu1 C30 2.826(6) . ?
Eu1 C20 2.964(6) 2_553 ?
O1 C10 1.255(8) . ?
O2 C10 1.247(8) . ?
O2 Eu1 2.373(4) 2_553 ?
O3 C20 1.262(7) . ?
O3 Eu1 2.666(4) 2_553 ?
O4 C20 1.230(7) . ?
O4 Eu1 2.516(4) 2_553 ?
O5 C30 1.245(7) . ?
O6 C30 1.259(7) . ?
O7 C31 1.264(11) . ?
N1 C1 1.302(8) . ?
N1 C9 1.370(8) . ?
N2 C11 1.314(8) . ?
N2 C19 1.359(8) . ?
N3 C21 1.317(7) . ?
N3 C29 1.360(8) . ?
N4 C31 1.316(10) . ?
N4 C32 1.432(14) . ?
N4 C33 1.442(13) . ?
C1 C2 1.416(9) . ?
C1 C1 1.499(12) 2_643 ?
C2 C3 1.350(9) . ?
C2 H2B 0.9500 . ?
C3 C4 1.409(9) . ?
C3 C10 1.508(8) . ?
C4 C5 1.410(8) . ?
C4 C9 1.420(8) . ?
C5 C6 1.346(9) . ?
C5 H5A 0.9500 . ?
C6 C7 1.419(10) . ?
C6 H6A 0.9500 . ?
C7 C8 1.361(10) . ?
C7 H7A 0.9500 . ?
C8 C9 1.417(9) . ?
C8 H8A 0.9500 . ?
C11 C12 1.413(8) . ?
C11 C21 1.495(8) 2_554 ?
C12 C13 1.353(8) . ?
C12 H12A 0.9500 . ?
C13 C14 1.433(8) . ?
C13 C20 1.511(8) . ?
C14 C19 1.425(8) . ?
C14 C15 1.426(9) . ?
C15 C16 1.360(9) . ?
C15 H15A 0.9500 . ?
C16 C17 1.412(10) . ?
C16 H16A 0.9500 . ?
C17 C18 1.352(10) . ?
C17 H17A 0.9500 . ?
C18 C19 1.420(9) . ?
C18 H18A 0.9500 . ?
C20 Eu1 2.964(6) 2_553 ?
C21 C22 1.424(8) . ?
C21 C11 1.495(8) 2_554 ?
C22 C23 1.357(8) . ?
C22 H22A 0.9500 . ?
C23 C24 1.436(8) . ?
C23 C30 1.522(8) . ?
C24 C25 1.411(9) . ?
C24 C29 1.425(8) . ?
C25 C26 1.359(10) . ?
C25 H25A 0.9500 . ?
C26 C27 1.397(10) . ?
C26 H26A 0.9500 . ?
C27 C28 1.382(10) . ?
C27 H27A 0.9500 . ?
C28 C29 1.417(9) . ?
C28 H28A 0.9500 . ?
C31 H31A 0.9500 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
O1W H1WA 0.8400 . ?
O8 C34 1.22(2) . ?
N5 C34 1.235(19) . ?
N5 C35 1.61(3) . ?
N5 C36 1.62(2) . ?
C34 H34A 0.9500 . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
O9 C37 1.27(3) . ?
N6 C37 1.32(2) . ?
N6 C38 1.47(3) . ?
N6 C39 1.58(3) . ?
C37 H37A 0.9500 . ?
C38 C39 1.06(4) 2_454 ?
C39 C38 1.06(4) 2_454 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1W Eu1 O2 79.4(4) . 2_553 ?
O1W Eu1 O1 138.9(4) . . ?
O2 Eu1 O1 133.16(15) 2_553 . ?
O1W Eu1 O3 147.8(4) . . ?
O2 Eu1 O3 73.38(15) 2_553 . ?
O1 Eu1 O3 73.23(15) . . ?
O1W Eu1 O5 105.0(6) . . ?
O2 Eu1 O5 126.06(15) 2_553 . ?
O1 Eu1 O5 77.20(14) . . ?
O3 Eu1 O5 78.56(14) . . ?
O1W Eu1 O7 68.4(4) . . ?
O2 Eu1 O7 146.7(2) 2_553 . ?
O1 Eu1 O7 73.7(2) . . ?
O3 Eu1 O7 139.86(18) . . ?
O5 Eu1 O7 72.46(17) . . ?
O1W Eu1 O8 14.4(5) . . ?
O2 Eu1 O8 65.1(3) 2_553 . ?
O1 Eu1 O8 149.2(4) . . ?
O3 Eu1 O8 135.7(3) . . ?
O5 Eu1 O8 114.0(4) . . ?
O7 Eu1 O8 82.4(3) . . ?
O1W Eu1 O6 76.2(5) . . ?
O2 Eu1 O6 78.24(15) 2_553 . ?
O1 Eu1 O6 127.37(15) . . ?
O3 Eu1 O6 81.71(15) . . ?
O5 Eu1 O6 52.51(14) . . ?
O7 Eu1 O6 101.13(19) . . ?
O8 Eu1 O6 75.7(4) . . ?
O1W Eu1 O4 76.2(5) . 2_553 ?
O2 Eu1 O4 90.08(17) 2_553 2_553 ?
O1 Eu1 O4 79.25(16) . 2_553 ?
O3 Eu1 O4 119.99(14) . 2_553 ?
O5 Eu1 O4 143.74(16) . 2_553 ?
O7 Eu1 O4 74.70(17) . 2_553 ?
O8 Eu1 O4 75.8(4) . 2_553 ?
O6 Eu1 O4 151.52(17) . 2_553 ?
O1W Eu1 O3 114.8(6) . 2_553 ?
O2 Eu1 O3 69.35(14) 2_553 2_553 ?
O1 Eu1 O3 69.30(13) . 2_553 ?
O3 Eu1 O3 71.04(14) . 2_553 ?
O5 Eu1 O3 139.76(14) . 2_553 ?
O7 Eu1 O3 116.58(16) . 2_553 ?
O8 Eu1 O3 106.1(4) . 2_553 ?
O6 Eu1 O3 142.23(14) . 2_553 ?
O4 Eu1 O3 49.39(13) 2_553 2_553 ?
O1W Eu1 C30 90.3(6) . . ?
O2 Eu1 C30 102.80(16) 2_553 . ?
O1 Eu1 C30 102.39(16) . . ?
O3 Eu1 C30 79.57(15) . . ?
O5 Eu1 C30 26.07(15) . . ?
O7 Eu1 C30 85.95(18) . . ?
O8 Eu1 C30 94.9(4) . . ?
O6 Eu1 C30 26.45(15) . . ?
O4 Eu1 C30 159.37(16) 2_553 . ?
O3 Eu1 C30 150.60(15) 2_553 . ?
O1W Eu1 C20 95.2(6) . 2_553 ?
O2 Eu1 C20 78.97(15) 2_553 2_553 ?
O1 Eu1 C20 72.92(15) . 2_553 ?
O3 Eu1 C20 96.03(15) . 2_553 ?
O5 Eu1 C20 149.90(15) . 2_553 ?
O7 Eu1 C20 95.43(17) . 2_553 ?
O8 Eu1 C20 90.7(4) . 2_553 ?
O6 Eu1 C20 156.78(16) . 2_553 ?
O4 Eu1 C20 24.20(15) 2_553 2_553 ?
O3 Eu1 C20 25.19(14) 2_553 2_553 ?
C30 Eu1 C20 174.44(16) . 2_553 ?
C10 O1 Eu1 139.4(4) . . ?
C10 O2 Eu1 139.1(4) . 2_553 ?
C20 O3 Eu1 159.0(4) . . ?
C20 O3 Eu1 90.7(3) . 2_553 ?
Eu1 O3 Eu1 108.96(14) . 2_553 ?
C20 O4 Eu1 98.8(4) . 2_553 ?
C30 O5 Eu1 93.9(3) . . ?
C30 O6 Eu1 91.7(3) . . ?
C31 O7 Eu1 120.6(5) . . ?
C1 N1 C9 117.9(5) . . ?
C11 N2 C19 118.1(5) . . ?
C21 N3 C29 118.2(5) . . ?
C31 N4 C32 121.1(9) . . ?
C31 N4 C33 121.7(10) . . ?
C32 N4 C33 117.0(8) . . ?
N1 C1 C2 123.0(6) . . ?
N1 C1 C1 117.4(7) . 2_643 ?
C2 C1 C1 119.6(7) . 2_643 ?
C3 C2 C1 119.5(6) . . ?
C3 C2 H2B 120.2 . . ?
C1 C2 H2B 120.2 . . ?
C2 C3 C4 120.2(6) . . ?
C2 C3 C10 118.9(6) . . ?
C4 C3 C10 120.9(6) . . ?
C3 C4 C5 125.0(5) . . ?
C3 C4 C9 116.0(5) . . ?
C5 C4 C9 118.9(5) . . ?
C6 C5 C4 121.4(6) . . ?
C6 C5 H5A 119.3 . . ?
C4 C5 H5A 119.3 . . ?
C5 C6 C7 119.3(6) . . ?
C5 C6 H6A 120.4 . . ?
C7 C6 H6A 120.4 . . ?
C8 C7 C6 121.8(6) . . ?
C8 C7 H7A 119.1 . . ?
C6 C7 H7A 119.1 . . ?
C7 C8 C9 119.1(6) . . ?
C7 C8 H8A 120.4 . . ?
C9 C8 H8A 120.4 . . ?
N1 C9 C8 117.5(5) . . ?
N1 C9 C4 123.2(5) . . ?
C8 C9 C4 119.3(6) . . ?
O2 C10 O1 127.0(6) . . ?
O2 C10 C3 117.1(6) . . ?
O1 C10 C3 115.8(6) . . ?
N2 C11 C12 123.2(5) . . ?
N2 C11 C21 117.5(5) . 2_554 ?
C12 C11 C21 119.2(5) . 2_554 ?
C13 C12 C11 119.5(5) . . ?
C13 C12 H12A 120.2 . . ?
C11 C12 H12A 120.2 . . ?
C12 C13 C14 119.9(5) . . ?
C12 C13 C20 120.8(5) . . ?
C14 C13 C20 119.1(5) . . ?
C19 C14 C15 119.9(6) . . ?
C19 C14 C13 115.8(5) . . ?
C15 C14 C13 124.3(6) . . ?
C16 C15 C14 120.3(6) . . ?
C16 C15 H15A 119.8 . . ?
C14 C15 H15A 119.8 . . ?
C15 C16 C17 119.6(6) . . ?
C15 C16 H16A 120.2 . . ?
C17 C16 H16A 120.2 . . ?
C18 C17 C16 121.4(6) . . ?
C18 C17 H17A 119.3 . . ?
C16 C17 H17A 119.3 . . ?
C17 C18 C19 121.3(6) . . ?
C17 C18 H18A 119.4 . . ?
C19 C18 H18A 119.4 . . ?
N2 C19 C18 119.1(5) . . ?
N2 C19 C14 123.5(5) . . ?
C18 C19 C14 117.3(6) . . ?
O4 C20 O3 121.1(5) . . ?
O4 C20 C13 119.3(5) . . ?
O3 C20 C13 119.6(5) . . ?
O4 C20 Eu1 57.0(3) . 2_553 ?
O3 C20 Eu1 64.1(3) . 2_553 ?
C13 C20 Eu1 176.1(4) . 2_553 ?
N3 C21 C22 122.5(5) . . ?
N3 C21 C11 116.6(5) . 2_554 ?
C22 C21 C11 120.9(5) . 2_554 ?
C23 C22 C21 120.1(5) . . ?
C23 C22 H22A 120.0 . . ?
C21 C22 H22A 120.0 . . ?
C22 C23 C24 119.4(5) . . ?
C22 C23 C30 117.4(5) . . ?
C24 C23 C30 123.2(5) . . ?
C25 C24 C29 118.1(5) . . ?
C25 C24 C23 126.0(5) . . ?
C29 C24 C23 115.9(5) . . ?
C26 C25 C24 121.3(6) . . ?
C26 C25 H25A 119.3 . . ?
C24 C25 H25A 119.3 . . ?
C25 C26 C27 121.1(6) . . ?
C25 C26 H26A 119.5 . . ?
C27 C26 H26A 119.5 . . ?
C28 C27 C26 119.8(6) . . ?
C28 C27 H27A 120.1 . . ?
C26 C27 H27A 120.1 . . ?
C27 C28 C29 120.3(6) . . ?
C27 C28 H28A 119.9 . . ?
C29 C28 H28A 119.9 . . ?
N3 C29 C28 116.7(6) . . ?
N3 C29 C24 123.9(5) . . ?
C28 C29 C24 119.4(6) . . ?
O5 C30 O6 121.9(5) . . ?
O5 C30 C23 120.5(5) . . ?
O6 C30 C23 117.6(5) . . ?
O5 C30 Eu1 60.0(3) . . ?
O6 C30 Eu1 61.9(3) . . ?
C23 C30 Eu1 179.1(4) . . ?
O7 C31 N4 125.4(9) . . ?
O7 C31 H31A 117.3 . . ?
N4 C31 H31A 117.3 . . ?
N4 C32 H32A 109.5 . . ?
N4 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
N4 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
N4 C33 H33A 109.5 . . ?
N4 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
N4 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
Eu1 O1W H1WA 109.5 . . ?
C34 O8 Eu1 126.3(13) . . ?
C34 N5 C35 112.2(17) . . ?
C34 N5 C36 113.4(14) . . ?
C35 N5 C36 133.5(15) . . ?
O8 C34 N5 132.4(19) . . ?
O8 C34 H34A 113.8 . . ?
N5 C34 H34A 113.8 . . ?
N5 C35 H35A 109.5 . . ?
N5 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
N5 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
N5 C36 H36A 109.5 . . ?
N5 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
N5 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C37 N6 C38 141(3) . . ?
C37 N6 C39 109(3) . . ?
C38 N6 C39 110.0(18) . . ?
O9 C37 N6 125(4) . . ?
O9 C37 H37A 117.3 . . ?
N6 C37 H37A 117.3 . . ?
C39 C38 N6 124(3) 2_454 . ?
C38 C39 N6 125(3) 2_454 . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1W Eu1 O1 C10 145.9(10) . . . . ?
O2 Eu1 O1 C10 12.1(7) 2_553 . . . ?
O3 Eu1 O1 C10 -34.1(6) . . . . ?
O5 Eu1 O1 C10 -115.8(6) . . . . ?
O7 Eu1 O1 C10 169.0(6) . . . . ?
O8 Eu1 O1 C10 128.4(10) . . . . ?
O6 Eu1 O1 C10 -99.3(6) . . . . ?
O4 Eu1 O1 C10 92.0(6) 2_553 . . . ?
O3 Eu1 O1 C10 41.5(6) 2_553 . . . ?
C30 Eu1 O1 C10 -109.0(6) . . . . ?
C20 Eu1 O1 C10 67.9(6) 2_553 . . . ?
O1W Eu1 O3 C20 51.8(15) . . . . ?
O2 Eu1 O3 C20 85.2(11) 2_553 . . . ?
O1 Eu1 O3 C20 -128.2(11) . . . . ?
O5 Eu1 O3 C20 -48.2(10) . . . . ?
O7 Eu1 O3 C20 -92.4(11) . . . . ?
O8 Eu1 O3 C20 64.6(12) . . . . ?
O6 Eu1 O3 C20 5.0(11) . . . . ?
O4 Eu1 O3 C20 165.4(10) 2_553 . . . ?
O3 Eu1 O3 C20 158.5(11) 2_553 . . . ?
C30 Eu1 O3 C20 -21.7(10) . . . . ?
C20 Eu1 O3 C20 161.7(10) 2_553 . . . ?
O1W Eu1 O3 Eu1 -106.7(10) . . . 2_553 ?
O2 Eu1 O3 Eu1 -73.34(16) 2_553 . . 2_553 ?
O1 Eu1 O3 Eu1 73.33(16) . . . 2_553 ?
O5 Eu1 O3 Eu1 153.25(17) . . . 2_553 ?
O7 Eu1 O3 Eu1 109.1(3) . . . 2_553 ?
O8 Eu1 O3 Eu1 -93.9(6) . . . 2_553 ?
O6 Eu1 O3 Eu1 -153.48(17) . . . 2_553 ?
O4 Eu1 O3 Eu1 6.8(2) 2_553 . . 2_553 ?
O3 Eu1 O3 Eu1 0.0 2_553 . . 2_553 ?
C30 Eu1 O3 Eu1 179.80(19) . . . 2_553 ?
C20 Eu1 O3 Eu1 3.23(17) 2_553 . . 2_553 ?
O1W Eu1 O5 C30 -57.5(5) . . . . ?
O2 Eu1 O5 C30 30.2(4) 2_553 . . . ?
O1 Eu1 O5 C30 164.8(4) . . . . ?
O3 Eu1 O5 C30 89.6(4) . . . . ?
O7 Eu1 O5 C30 -118.5(4) . . . . ?
O8 Eu1 O5 C30 -45.6(5) . . . . ?
O6 Eu1 O5 C30 1.3(3) . . . . ?
O4 Eu1 O5 C30 -144.5(4) 2_553 . . . ?
O3 Eu1 O5 C30 130.8(3) 2_553 . . . ?
C20 Eu1 O5 C30 171.8(3) 2_553 . . . ?
O1W Eu1 O6 C30 120.3(6) . . . . ?
O2 Eu1 O6 C30 -157.9(4) 2_553 . . . ?
O1 Eu1 O6 C30 -21.8(5) . . . . ?
O3 Eu1 O6 C30 -83.2(4) . . . . ?
O5 Eu1 O6 C30 -1.3(3) . . . . ?
O7 Eu1 O6 C30 56.1(4) . . . . ?
O8 Eu1 O6 C30 135.2(5) . . . . ?
O4 Eu1 O6 C30 134.5(4) 2_553 . . . ?
O3 Eu1 O6 C30 -126.8(4) 2_553 . . . ?
C20 Eu1 O6 C30 -169.2(4) 2_553 . . . ?
O1W Eu1 O7 C31 -158.0(9) . . . . ?
O2 Eu1 O7 C31 -173.3(5) 2_553 . . . ?
O1 Eu1 O7 C31 38.1(6) . . . . ?
O3 Eu1 O7 C31 2.5(8) . . . . ?
O5 Eu1 O7 C31 -43.3(6) . . . . ?
O8 Eu1 O7 C31 -161.5(8) . . . . ?
O6 Eu1 O7 C31 -87.8(6) . . . . ?
O4 Eu1 O7 C31 121.1(7) 2_553 . . . ?
O3 Eu1 O7 C31 94.2(6) 2_553 . . . ?
C30 Eu1 O7 C31 -66.1(6) . . . . ?
C20 Eu1 O7 C31 108.5(6) 2_553 . . . ?
C9 N1 C1 C2 -0.4(11) . . . . ?
C9 N1 C1 C1 -179.6(7) . . . 2_643 ?
N1 C1 C2 C3 -2.5(12) . . . . ?
C1 C1 C2 C3 176.7(8) 2_643 . . . ?
C1 C2 C3 C4 2.7(12) . . . . ?
C1 C2 C3 C10 -178.0(7) . . . . ?
C2 C3 C4 C5 176.6(7) . . . . ?
C10 C3 C4 C5 -2.6(11) . . . . ?
C2 C3 C4 C9 -0.2(10) . . . . ?
C10 C3 C4 C9 -179.5(6) . . . . ?
C3 C4 C5 C6 -173.4(7) . . . . ?
C9 C4 C5 C6 3.4(10) . . . . ?
C4 C5 C6 C7 -2.4(11) . . . . ?
C5 C6 C7 C8 -1.4(13) . . . . ?
C6 C7 C8 C9 4.0(13) . . . . ?
C1 N1 C9 C8 -176.1(6) . . . . ?
C1 N1 C9 C4 3.1(10) . . . . ?
C7 C8 C9 N1 176.3(7) . . . . ?
C7 C8 C9 C4 -2.9(11) . . . . ?
C3 C4 C9 N1 -2.8(10) . . . . ?
C5 C4 C9 N1 -179.8(6) . . . . ?
C3 C4 C9 C8 176.3(7) . . . . ?
C5 C4 C9 C8 -0.7(10) . . . . ?
Eu1 O2 C10 O1 -12.2(11) 2_553 . . . ?
Eu1 O2 C10 C3 169.8(4) 2_553 . . . ?
Eu1 O1 C10 O2 -0.8(11) . . . . ?
Eu1 O1 C10 C3 177.1(4) . . . . ?
C2 C3 C10 O2 121.2(8) . . . . ?
C4 C3 C10 O2 -59.5(9) . . . . ?
C2 C3 C10 O1 -57.0(9) . . . . ?
C4 C3 C10 O1 122.3(7) . . . . ?
C19 N2 C11 C12 0.4(9) . . . . ?
C19 N2 C11 C21 -176.1(5) . . . 2_554 ?
N2 C11 C12 C13 -0.8(9) . . . . ?
C21 C11 C12 C13 175.7(5) 2_554 . . . ?
C11 C12 C13 C14 0.6(8) . . . . ?
C11 C12 C13 C20 -174.0(5) . . . . ?
C12 C13 C14 C19 -0.3(8) . . . . ?
C20 C13 C14 C19 174.4(5) . . . . ?
C12 C13 C14 C15 179.9(6) . . . . ?
C20 C13 C14 C15 -5.4(9) . . . . ?
C19 C14 C15 C16 -2.3(10) . . . . ?
C13 C14 C15 C16 177.5(7) . . . . ?
C14 C15 C16 C17 1.9(12) . . . . ?
C15 C16 C17 C18 -1.9(13) . . . . ?
C16 C17 C18 C19 2.3(13) . . . . ?
C11 N2 C19 C18 177.1(6) . . . . ?
C11 N2 C19 C14 0.0(9) . . . . ?
C17 C18 C19 N2 -179.9(7) . . . . ?
C17 C18 C19 C14 -2.6(11) . . . . ?
C15 C14 C19 N2 179.8(6) . . . . ?
C13 C14 C19 N2 -0.1(9) . . . . ?
C15 C14 C19 C18 2.6(9) . . . . ?
C13 C14 C19 C18 -177.2(6) . . . . ?
Eu1 O4 C20 O3 -0.5(6) 2_553 . . . ?
Eu1 O4 C20 C13 178.3(4) 2_553 . . . ?
Eu1 O3 C20 O4 -159.3(8) . . . . ?
Eu1 O3 C20 O4 0.4(6) 2_553 . . . ?
Eu1 O3 C20 C13 21.9(14) . . . . ?
Eu1 O3 C20 C13 -178.3(5) 2_553 . . . ?
Eu1 O3 C20 Eu1 -159.7(11) . . . 2_553 ?
C12 C13 C20 O4 74.4(8) . . . . ?
C14 C13 C20 O4 -100.2(7) . . . . ?
C12 C13 C20 O3 -106.8(7) . . . . ?
C14 C13 C20 O3 78.5(7) . . . . ?
C12 C13 C20 Eu1 96(6) . . . 2_553 ?
C14 C13 C20 Eu1 -79(6) . . . 2_553 ?
C29 N3 C21 C22 -0.9(9) . . . . ?
C29 N3 C21 C11 177.8(5) . . . 2_554 ?
N3 C21 C22 C23 1.2(9) . . . . ?
C11 C21 C22 C23 -177.5(5) 2_554 . . . ?
C21 C22 C23 C24 -0.1(9) . . . . ?
C21 C22 C23 C30 -179.7(5) . . . . ?
C22 C23 C24 C25 176.4(6) . . . . ?
C30 C23 C24 C25 -4.1(10) . . . . ?
C22 C23 C24 C29 -1.0(8) . . . . ?
C30 C23 C24 C29 178.6(5) . . . . ?
C29 C24 C25 C26 0.7(11) . . . . ?
C23 C24 C25 C26 -176.6(7) . . . . ?
C24 C25 C26 C27 -1.9(12) . . . . ?
C25 C26 C27 C28 1.3(13) . . . . ?
C26 C27 C28 C29 0.4(12) . . . . ?
C21 N3 C29 C28 -177.7(6) . . . . ?
C21 N3 C29 C24 -0.3(9) . . . . ?
C27 C28 C29 N3 176.0(7) . . . . ?
C27 C28 C29 C24 -1.5(11) . . . . ?
C25 C24 C29 N3 -176.3(6) . . . . ?
C23 C24 C29 N3 1.2(9) . . . . ?
C25 C24 C29 C28 1.0(9) . . . . ?
C23 C24 C29 C28 178.6(6) . . . . ?
Eu1 O5 C30 O6 -2.5(6) . . . . ?
Eu1 O5 C30 C23 179.1(5) . . . . ?
Eu1 O6 C30 O5 2.4(6) . . . . ?
Eu1 O6 C30 C23 -179.1(5) . . . . ?
C22 C23 C30 O5 159.7(6) . . . . ?
C24 C23 C30 O5 -19.8(9) . . . . ?
C22 C23 C30 O6 -18.7(8) . . . . ?
C24 C23 C30 O6 161.7(6) . . . . ?
C22 C23 C30 Eu1 -74(26) . . . . ?
C24 C23 C30 Eu1 106(26) . . . . ?
O1W Eu1 C30 O5 125.4(5) . . . . ?
O2 Eu1 C30 O5 -155.4(4) 2_553 . . . ?
O1 Eu1 C30 O5 -15.2(4) . . . . ?
O3 Eu1 C30 O5 -85.3(4) . . . . ?
O7 Eu1 C30 O5 57.1(4) . . . . ?
O8 Eu1 C30 O5 139.1(5) . . . . ?
O6 Eu1 C30 O5 -177.6(6) . . . . ?
O4 Eu1 C30 O5 77.2(6) 2_553 . . . ?
O3 Eu1 C30 O5 -84.9(5) 2_553 . . . ?
C20 Eu1 C30 O5 -47.4(17) 2_553 . . . ?
O1W Eu1 C30 O6 -56.9(5) . . . . ?
O2 Eu1 C30 O6 22.2(4) 2_553 . . . ?
O1 Eu1 C30 O6 162.4(4) . . . . ?
O3 Eu1 C30 O6 92.4(4) . . . . ?
O5 Eu1 C30 O6 177.6(6) . . . . ?
O7 Eu1 C30 O6 -125.2(4) . . . . ?
O8 Eu1 C30 O6 -43.3(5) . . . . ?
O4 Eu1 C30 O6 -105.2(6) 2_553 . . . ?
O3 Eu1 C30 O6 92.7(5) 2_553 . . . ?
C20 Eu1 C30 O6 130.2(15) 2_553 . . . ?
O1W Eu1 C30 C23 -1(26) . . . . ?
O2 Eu1 C30 C23 78(26) 2_553 . . . ?
O1 Eu1 C30 C23 -142(26) . . . . ?
O3 Eu1 C30 C23 148(26) . . . . ?
O5 Eu1 C30 C23 -126(26) . . . . ?
O7 Eu1 C30 C23 -69(26) . . . . ?
O8 Eu1 C30 C23 13(26) . . . . ?
O6 Eu1 C30 C23 56(26) . . . . ?
O4 Eu1 C30 C23 -49(26) 2_553 . . . ?
O3 Eu1 C30 C23 149(26) 2_553 . . . ?
C20 Eu1 C30 C23 -174(100) 2_553 . . . ?
Eu1 O7 C31 N4 -173.8(6) . . . . ?
C32 N4 C31 O7 -176.5(9) . . . . ?
C33 N4 C31 O7 -0.9(14) . . . . ?
O1W Eu1 O8 C34 129(5) . . . . ?
O2 Eu1 O8 C34 -44.8(16) 2_553 . . . ?
O1 Eu1 O8 C34 -178.7(12) . . . . ?
O3 Eu1 O8 C34 -23(2) . . . . ?
O5 Eu1 O8 C34 75.4(17) . . . . ?
O7 Eu1 O8 C34 142.3(17) . . . . ?
O6 Eu1 O8 C34 38.7(16) . . . . ?
O4 Eu1 O8 C34 -141.7(17) 2_553 . . . ?
O3 Eu1 O8 C34 -102.2(17) 2_553 . . . ?
C30 Eu1 O8 C34 57.0(17) . . . . ?
C20 Eu1 O8 C34 -122.3(17) 2_553 . . . ?
Eu1 O8 C34 N5 118.1(18) . . . . ?
C35 N5 C34 O8 178.1(19) . . . . ?
C36 N5 C34 O8 -11(2) . . . . ?
C38 N6 C37 O9 21(8) . . . . ?
C39 N6 C37 O9 -168(4) . . . . ?
C37 N6 C38 C39 162(5) . . . 2_454 ?
C39 N6 C38 C39 -9(4) . . . 2_454 ?
C37 N6 C39 C38 -165(4) . . . 2_454 ?
C38 N6 C39 C38 9(4) . . . 2_454 ?

_diffrn_measured_fraction_theta_max 0.980
_diffrn_reflns_theta_full        26.08
_diffrn_measured_fraction_theta_full 0.980
_refine_diff_density_max         2.026
_refine_diff_density_min         -0.923
_refine_diff_density_rms         0.200