# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C
# This journal is © The Royal Society of Chemistry 2013

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
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# 
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#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
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data_a14673
#TrackingRef '16913_web_deposit_cif_file_0_Chen-NiChen_1358352771.a14673.cif'


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C60 H132 Ag4 N12 O10'
_chemical_formula_sum            'C60 H132 Ag4 N12 O10'
_chemical_formula_weight         1613.26

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.3610(4)
_cell_length_b                   14.0189(4)
_cell_length_c                   14.7013(4)
_cell_angle_alpha                81.415(2)
_cell_angle_beta                 71.874(2)
_cell_angle_gamma                70.406(2)
_cell_volume                     1909.47(11)
_cell_formula_units_Z            1
_cell_measurement_temperature    200(2)
_cell_measurement_reflns_used    0
_cell_measurement_theta_min      0
_cell_measurement_theta_max      0

_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.72
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.04
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.403
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             844
_exptl_absorpt_coefficient_mu    1.067
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5138
_exptl_absorpt_correction_T_max  0.9586
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      200(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            14975
_diffrn_reflns_av_R_equivalents  0.0262
_diffrn_reflns_av_sigmaI/netI    0.0377
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         1.54
_diffrn_reflns_theta_max         25.08
_reflns_number_total             6713
_reflns_number_gt                5378
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1986)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0571P)^2^+0.1618P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6713
_refine_ls_number_parameters     386
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0496
_refine_ls_R_factor_gt           0.0334
_refine_ls_wR_factor_ref         0.1059
_refine_ls_wR_factor_gt          0.0881
_refine_ls_goodness_of_fit_ref   1.127
_refine_ls_restrained_S_all      1.127
_refine_ls_shift/su_max          0.009
_refine_ls_shift/su_mean         0.003

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.7803(5) -0.1647(3) 0.3643(3) 0.0431(10) Uani 1 1 d . . .
H1A H 0.8544 -0.2216 0.3849 0.052 Uiso 1 1 calc R . .
H1B H 0.7152 -0.1930 0.3479 0.052 Uiso 1 1 calc R . .
C2 C 0.6979(4) -0.0935(3) 0.4443(3) 0.0396(10) Uani 1 1 d . . .
H2A H 0.6277 -0.0349 0.4218 0.048 Uiso 1 1 calc R . .
H2B H 0.6445 -0.1289 0.4986 0.048 Uiso 1 1 calc R . .
C3 C 0.7137(4) 0.0366(3) 0.5291(3) 0.0327(9) Uani 1 1 d . . .
H3A H 0.6336 0.0251 0.5826 0.039 Uiso 1 1 calc R . .
H3B H 0.6729 0.0908 0.4852 0.039 Uiso 1 1 calc R . .
C4 C 0.8075(4) 0.0710(2) 0.5683(3) 0.0292(8) Uani 1 1 d . . .
H4A H 0.8951 0.0716 0.5162 0.035 Uiso 1 1 calc R . .
H4B H 0.7570 0.1416 0.5880 0.035 Uiso 1 1 calc R . .
C5 C 1.1092(5) 0.2471(3) 0.1370(3) 0.0490(12) Uani 1 1 d . . .
H5A H 1.1376 0.2873 0.1729 0.059 Uiso 1 1 calc R . .
H5B H 1.0940 0.2869 0.0775 0.059 Uiso 1 1 calc R . .
C6 C 1.2271(5) 0.1487(3) 0.1114(3) 0.0446(11) Uani 1 1 d . . .
H6A H 1.3163 0.1630 0.0728 0.053 Uiso 1 1 calc R . .
H6B H 1.2443 0.1096 0.1706 0.053 Uiso 1 1 calc R . .
C7 C 1.2898(4) -0.0127(3) 0.0388(3) 0.0373(9) Uani 1 1 d . . .
H7A H 1.3142 -0.0442 0.0987 0.045 Uiso 1 1 calc R . .
H7B H 1.3787 -0.0079 -0.0098 0.045 Uiso 1 1 calc R . .
C8 C 1.2269(4) -0.0775(3) 0.0039(3) 0.0344(9) Uani 1 1 d . . .
H8A H 1.2971 -0.1459 -0.0071 0.041 Uiso 1 1 calc R . .
H8B H 1.1412 -0.0848 0.0545 0.041 Uiso 1 1 calc R . .
C9 C 0.0190(4) 0.2849(2) 0.4016(2) 0.0238(7) Uani 1 1 d . . .
C10 C -0.1225(4) 0.3661(2) 0.4500(3) 0.0281(8) Uani 1 1 d . . .
C11 C -0.2483(4) 0.3486(3) 0.4289(3) 0.0465(11) Uani 1 1 d . . .
H11A H -0.2376 0.3583 0.3598 0.070 Uiso 1 1 calc R . .
H11B H -0.3377 0.3970 0.4630 0.070 Uiso 1 1 calc R . .
H11C H -0.2502 0.2793 0.4503 0.070 Uiso 1 1 calc R . .
C12 C -0.1393(4) 0.3505(3) 0.5575(3) 0.0396(10) Uani 1 1 d . . .
H12A H -0.0585 0.3612 0.5711 0.059 Uiso 1 1 calc R . .
H12B H -0.1419 0.2814 0.5786 0.059 Uiso 1 1 calc R . .
H12C H -0.2284 0.3991 0.5917 0.059 Uiso 1 1 calc R . .
C13 C -0.1230(4) 0.4758(3) 0.4182(3) 0.0396(10) Uani 1 1 d . . .
H13A H -0.0417 0.4873 0.4304 0.059 Uiso 1 1 calc R . .
H13B H -0.2120 0.5228 0.4544 0.059 Uiso 1 1 calc R . .
H13C H -0.1154 0.4871 0.3496 0.059 Uiso 1 1 calc R . .
C14 C 0.1463(4) 0.3098(2) 0.3716(3) 0.0289(8) Uani 1 1 d . . .
H14 H 0.1400 0.3766 0.3824 0.035 Uiso 1 1 calc R . .
C15 C 0.2829(4) 0.2459(2) 0.3269(2) 0.0226(7) Uani 1 1 d . . .
C16 C 0.4112(4) 0.2870(2) 0.2915(3) 0.0289(8) Uani 1 1 d . . .
C17 C 0.3760(5) 0.3984(3) 0.3125(4) 0.0515(12) Uani 1 1 d . . .
H17A H 0.3384 0.4063 0.3818 0.077 Uiso 1 1 calc R . .
H17B H 0.3043 0.4412 0.2809 0.077 Uiso 1 1 calc R . .
H17C H 0.4627 0.4189 0.2883 0.077 Uiso 1 1 calc R . .
C18 C 0.5285(4) 0.2245(3) 0.3383(3) 0.0429(10) Uani 1 1 d . . .
H18A H 0.4921 0.2302 0.4079 0.064 Uiso 1 1 calc R . .
H18B H 0.6108 0.2500 0.3137 0.064 Uiso 1 1 calc R . .
H18C H 0.5575 0.1532 0.3232 0.064 Uiso 1 1 calc R . .
C19 C 0.4684(5) 0.2775(3) 0.1827(3) 0.0451(11) Uani 1 1 d . . .
H19A H 0.4913 0.2069 0.1677 0.068 Uiso 1 1 calc R . .
H19B H 0.5547 0.2985 0.1587 0.068 Uiso 1 1 calc R . .
H19C H 0.3958 0.3210 0.1522 0.068 Uiso 1 1 calc R . .
C20 C 0.7049(4) 0.7448(2) 0.1543(2) 0.0274(8) Uani 1 1 d . A .
C21 C 0.5829(4) 0.6970(3) 0.1884(3) 0.0436(11) Uani 1 1 d . . .
C22 C 0.4573(11) 0.7671(8) 0.2502(8) 0.041(3) Uiso 0.448(9) 1 d P A 1
H22A H 0.4884 0.8042 0.2864 0.061 Uiso 0.448(9) 1 calc PR A 1
H22B H 0.3983 0.7287 0.2948 0.061 Uiso 0.448(9) 1 calc PR A 1
H22C H 0.4015 0.8153 0.2105 0.061 Uiso 0.448(9) 1 calc PR A 1
C23 C 0.5934(18) 0.6183(13) 0.1333(12) 0.107(6) Uiso 0.448(9) 1 d P A 1
H23A H 0.6942 0.5835 0.1029 0.160 Uiso 0.448(9) 1 calc PR A 1
H23B H 0.5441 0.6473 0.0838 0.160 Uiso 0.448(9) 1 calc PR A 1
H23C H 0.5493 0.5697 0.1752 0.160 Uiso 0.448(9) 1 calc PR A 1
C24 C 0.5921(18) 0.6362(12) 0.2918(12) 0.101(5) Uiso 0.448(9) 1 d P A 1
H24A H 0.5894 0.6829 0.3363 0.152 Uiso 0.448(9) 1 calc PR A 1
H24B H 0.6815 0.5801 0.2826 0.152 Uiso 0.448(9) 1 calc PR A 1
H24C H 0.5111 0.6095 0.3182 0.152 Uiso 0.448(9) 1 calc PR A 1
C22' C 0.4368(11) 0.7716(8) 0.2143(9) 0.064(3) Uiso 0.552(9) 1 d P A 2
H22D H 0.4414 0.8391 0.1876 0.096 Uiso 0.552(9) 1 calc PR A 2
H22E H 0.3990 0.7729 0.2842 0.096 Uiso 0.552(9) 1 calc PR A 2
H22F H 0.3740 0.7516 0.1880 0.096 Uiso 0.552(9) 1 calc PR A 2
C23' C 0.5487(10) 0.6946(7) 0.0856(7) 0.059(3) Uiso 0.552(9) 1 d P A 2
H23D H 0.5195 0.7639 0.0581 0.088 Uiso 0.552(9) 1 calc PR A 2
H23E H 0.4718 0.6645 0.0974 0.088 Uiso 0.552(9) 1 calc PR A 2
H23F H 0.6348 0.6539 0.0407 0.088 Uiso 0.552(9) 1 calc PR A 2
C24' C 0.6218(10) 0.5906(7) 0.2204(7) 0.063(3) Uiso 0.552(9) 1 d P A 2
H24D H 0.7245 0.5590 0.1936 0.095 Uiso 0.552(9) 1 calc PR A 2
H24E H 0.5693 0.5562 0.1987 0.095 Uiso 0.552(9) 1 calc PR A 2
H24F H 0.5977 0.5850 0.2905 0.095 Uiso 0.552(9) 1 calc PR A 2
C25 C 0.8460(4) 0.6803(2) 0.1366(3) 0.0274(8) Uani 1 1 d . . .
H25 H 0.8583 0.6097 0.1473 0.033 Uiso 1 1 calc R A .
C26 C 0.9704(4) 0.7088(2) 0.1050(2) 0.0238(7) Uani 1 1 d . A .
C27 C 1.1167(4) 0.6268(3) 0.0951(3) 0.0301(8) Uani 1 1 d . . .
C28 C 1.1139(4) 0.5179(3) 0.1110(3) 0.0430(10) Uani 1 1 d . A .
H28A H 1.0523 0.5084 0.1753 0.065 Uiso 1 1 calc R . .
H28B H 1.2109 0.4720 0.1052 0.065 Uiso 1 1 calc R . .
H28C H 1.0766 0.5030 0.0630 0.065 Uiso 1 1 calc R . .
C29 C 1.2129(5) 0.6394(3) -0.0047(3) 0.0606(14) Uani 1 1 d . A .
H29A H 1.1746 0.6250 -0.0524 0.091 Uiso 1 1 calc R . .
H29B H 1.3090 0.5922 -0.0102 0.091 Uiso 1 1 calc R . .
H29C H 1.2171 0.7091 -0.0158 0.091 Uiso 1 1 calc R . .
C30 C 1.1785(5) 0.6485(4) 0.1685(4) 0.0600(13) Uani 1 1 d . A .
H30A H 1.1174 0.6403 0.2332 0.090 Uiso 1 1 calc R . .
H30B H 1.1830 0.7182 0.1574 0.090 Uiso 1 1 calc R . .
H30C H 1.2747 0.6012 0.1621 0.090 Uiso 1 1 calc R . .
N1 N 0.8477(4) -0.1096(2) 0.2798(2) 0.0366(8) Uani 1 1 d . . .
H1C H 0.7787 -0.0585 0.2589 0.044 Uiso 1 1 calc R . .
H1D H 0.8996 -0.1530 0.2310 0.044 Uiso 1 1 calc R . .
N2 N 0.7914(3) -0.0568(2) 0.4774(2) 0.0297(7) Uani 1 1 d . . .
H2 H 0.8328 -0.1066 0.5182 0.036 Uiso 1 1 calc R . .
N3 N 0.8495(3) 0.0081(2) 0.6508(2) 0.0273(7) Uani 1 1 d . . .
H3C H 0.8815 -0.0592 0.6373 0.033 Uiso 1 1 calc R . .
H3D H 0.7712 0.0177 0.7037 0.033 Uiso 1 1 calc R . .
N4 N 0.9751(4) 0.2287(2) 0.1956(2) 0.0467(9) Uani 1 1 d . . .
H4C H 0.9004 0.2879 0.1995 0.056 Uiso 1 1 calc R . .
H4D H 0.9812 0.2063 0.2567 0.056 Uiso 1 1 calc R . .
N5 N 1.1881(3) 0.0891(2) 0.0568(2) 0.0318(7) Uani 1 1 d . . .
H5 H 1.1949 0.1225 -0.0033 0.038 Uiso 1 1 calc R . .
N6 N 1.1866(3) -0.0362(2) -0.0856(2) 0.0293(7) Uani 1 1 d . . .
H6C H 1.2687 -0.0400 -0.1347 0.035 Uiso 1 1 calc R . .
H6D H 1.1351 0.0313 -0.0788 0.035 Uiso 1 1 calc R . .
O1 O 0.0081(3) 0.19935(16) 0.39622(18) 0.0301(6) Uani 1 1 d . . .
O2 O 0.3087(2) 0.15403(16) 0.31219(17) 0.0270(5) Uani 1 1 d . . .
O3 O 0.6706(3) 0.83923(17) 0.14115(19) 0.0360(6) Uani 1 1 d . . .
O4 O 0.9735(3) 0.79902(16) 0.08625(17) 0.0293(6) Uani 1 1 d . . .
O5 O 0.5620(3) 0.00902(19) 0.2415(2) 0.0402(7) Uani 1 1 d . . .
H5C H 0.4661 0.0582 0.2675 0.048 Uiso 1 1 d R . .
H5D H 0.5633 -0.0401 0.2095 0.048 Uiso 1 1 d R . .
Ag1 Ag 0.98595(3) -0.04667(2) 0.31783(2) 0.03382(11) Uani 1 1 d . . .
Ag2 Ag 0.93755(3) 0.11111(2) 0.12708(2) 0.03985(11) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
C1 0.058(3) 0.038(2) 0.049(3) 0.0036(19) -0.031(2) -0.021(2)
C2 0.042(2) 0.057(3) 0.030(2) 0.0075(19) -0.0129(18) -0.030(2)
C3 0.028(2) 0.034(2) 0.030(2) 0.0046(16) -0.0068(16) -0.0066(17)
C4 0.028(2) 0.0219(17) 0.031(2) 0.0003(15) -0.0018(16) -0.0062(15)
C5 0.090(4) 0.042(2) 0.039(2) 0.0049(19) -0.033(2) -0.041(3)
C6 0.066(3) 0.050(2) 0.040(2) 0.005(2) -0.030(2) -0.037(2)
C7 0.032(2) 0.042(2) 0.041(2) 0.0026(18) -0.0176(19) -0.0106(18)
C8 0.035(2) 0.0281(19) 0.037(2) 0.0017(16) -0.0091(18) -0.0084(17)
C9 0.029(2) 0.0236(17) 0.0191(17) -0.0021(14) -0.0082(15) -0.0068(15)
C10 0.026(2) 0.0248(17) 0.0316(19) -0.0063(15) -0.0065(16) -0.0051(15)
C11 0.027(2) 0.050(2) 0.060(3) -0.019(2) -0.013(2) -0.0012(19)
C12 0.040(2) 0.036(2) 0.033(2) -0.0102(17) 0.0009(19) -0.0061(18)
C13 0.035(2) 0.0294(19) 0.043(2) 0.0011(18) -0.0062(19) -0.0009(17)
C14 0.031(2) 0.0195(16) 0.037(2) -0.0078(15) -0.0062(17) -0.0093(15)
C15 0.0262(19) 0.0221(17) 0.0215(17) 0.0003(14) -0.0100(15) -0.0074(14)
C16 0.026(2) 0.0234(17) 0.037(2) -0.0006(15) -0.0071(16) -0.0099(15)
C17 0.046(3) 0.027(2) 0.078(3) -0.006(2) -0.007(2) -0.016(2)
C18 0.040(3) 0.044(2) 0.055(3) 0.002(2) -0.023(2) -0.020(2)
C19 0.040(3) 0.056(3) 0.038(2) 0.009(2) -0.005(2) -0.023(2)
C20 0.031(2) 0.0224(17) 0.0274(19) -0.0026(15) -0.0067(16) -0.0072(15)
C21 0.027(2) 0.029(2) 0.071(3) -0.002(2) -0.010(2) -0.0073(17)
C25 0.030(2) 0.0168(16) 0.037(2) 0.0011(15) -0.0104(17) -0.0087(15)
C26 0.031(2) 0.0241(17) 0.0188(17) -0.0011(14) -0.0095(15) -0.0087(15)
C27 0.027(2) 0.0250(18) 0.036(2) 0.0027(16) -0.0080(17) -0.0071(16)
C28 0.031(2) 0.0281(19) 0.062(3) 0.0022(19) -0.010(2) -0.0030(17)
C29 0.047(3) 0.040(2) 0.059(3) 0.009(2) 0.015(2) 0.000(2)
C30 0.049(3) 0.059(3) 0.084(4) -0.002(3) -0.043(3) -0.009(2)
N1 0.040(2) 0.0418(18) 0.0301(17) -0.0091(15) -0.0119(15) -0.0105(16)
N2 0.0288(17) 0.0361(16) 0.0270(16) 0.0020(13) -0.0123(14) -0.0108(14)
N3 0.0299(17) 0.0263(15) 0.0239(15) -0.0051(12) -0.0028(13) -0.0091(13)
N4 0.075(3) 0.0375(18) 0.0316(18) -0.0078(15) -0.0188(19) -0.0164(18)
N5 0.044(2) 0.0339(16) 0.0281(16) 0.0047(13) -0.0176(15) -0.0217(15)
N6 0.0254(17) 0.0274(15) 0.0314(16) -0.0048(13) -0.0049(13) -0.0049(13)
O1 0.0292(14) 0.0222(12) 0.0386(15) -0.0053(11) -0.0066(12) -0.0087(11)
O2 0.0254(14) 0.0218(12) 0.0322(13) -0.0058(10) -0.0046(11) -0.0065(10)
O3 0.0313(15) 0.0195(12) 0.0498(17) -0.0036(11) -0.0059(13) -0.0029(11)
O4 0.0329(15) 0.0210(12) 0.0357(14) 0.0021(10) -0.0101(12) -0.0116(11)
O5 0.0274(15) 0.0390(14) 0.0512(17) -0.0194(13) -0.0040(13) -0.0053(12)
Ag1 0.03586(19) 0.03424(17) 0.03490(18) -0.00751(13) -0.01037(14) -0.01241(13)
Ag2 0.0439(2) 0.04038(19) 0.0420(2) -0.01004(14) -0.01280(15) -0.01745(15)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.470(5) . ?
C1 C2 1.505(6) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 N2 1.464(5) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 N2 1.467(4) . ?
C3 C4 1.501(5) . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C4 N3 1.481(4) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 N4 1.473(6) . ?
C5 C6 1.508(6) . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C6 N5 1.461(4) . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C7 N5 1.465(5) . ?
C7 C8 1.503(5) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 N6 1.481(5) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 O1 1.258(4) . ?
C9 C14 1.398(5) . ?
C9 C10 1.557(5) . ?
C10 C12 1.526(5) . ?
C10 C11 1.531(5) . ?
C10 C13 1.538(5) . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 C15 1.409(5) . ?
C14 H14 0.9500 . ?
C15 O2 1.262(4) . ?
C15 C16 1.537(5) . ?
C16 C18 1.531(5) . ?
C16 C19 1.532(5) . ?
C16 C17 1.536(5) . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 O3 1.252(4) . ?
C20 C25 1.403(5) . ?
C20 C21 1.540(5) . ?
C21 C23 1.419(15) . ?
C21 C24' 1.453(10) . ?
C21 C22 1.469(11) . ?
C21 C22' 1.493(11) . ?
C21 C24 1.641(16) . ?
C21 C23' 1.663(10) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C22' H22D 0.9800 . ?
C22' H22E 0.9800 . ?
C22' H22F 0.9800 . ?
C23' H23D 0.9800 . ?
C23' H23E 0.9800 . ?
C23' H23F 0.9800 . ?
C24' H24D 0.9800 . ?
C24' H24E 0.9800 . ?
C24' H24F 0.9800 . ?
C25 C26 1.398(5) . ?
C25 H25 0.9500 . ?
C26 O4 1.263(4) . ?
C26 C27 1.544(5) . ?
C27 C28 1.518(5) . ?
C27 C29 1.519(5) . ?
C27 C30 1.526(6) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
N1 Ag1 2.153(3) . ?
N1 H1C 0.9200 . ?
N1 H1D 0.9200 . ?
N2 Ag1 2.595(3) . ?
N2 H2 0.9300 . ?
N3 Ag1 2.143(3) 2_756 ?
N3 H3C 0.9200 . ?
N3 H3D 0.9200 . ?
N4 Ag2 2.248(3) . ?
N4 H4C 0.9200 . ?
N4 H4D 0.9200 . ?
N5 Ag2 2.407(3) . ?
N5 H5 0.9300 . ?
N6 Ag2 2.171(3) 2_755 ?
N6 H6C 0.9200 . ?
N6 H6D 0.9200 . ?
O5 H5C 0.9963 . ?
O5 H5D 0.8848 . ?
Ag1 N3 2.143(3) 2_756 ?
Ag1 Ag2 3.3597(4) . ?
Ag2 N6 2.171(3) 2_755 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 109.5(3) . . ?
N1 C1 H1A 109.8 . . ?
C2 C1 H1A 109.8 . . ?
N1 C1 H1B 109.8 . . ?
C2 C1 H1B 109.8 . . ?
H1A C1 H1B 108.2 . . ?
N2 C2 C1 112.0(3) . . ?
N2 C2 H2A 109.2 . . ?
C1 C2 H2A 109.2 . . ?
N2 C2 H2B 109.2 . . ?
C1 C2 H2B 109.2 . . ?
H2A C2 H2B 107.9 . . ?
N2 C3 C4 112.3(3) . . ?
N2 C3 H3A 109.1 . . ?
C4 C3 H3A 109.1 . . ?
N2 C3 H3B 109.1 . . ?
C4 C3 H3B 109.1 . . ?
H3A C3 H3B 107.9 . . ?
N3 C4 C3 114.9(3) . . ?
N3 C4 H4A 108.5 . . ?
C3 C4 H4A 108.5 . . ?
N3 C4 H4B 108.5 . . ?
C3 C4 H4B 108.5 . . ?
H4A C4 H4B 107.5 . . ?
N4 C5 C6 111.1(3) . . ?
N4 C5 H5A 109.4 . . ?
C6 C5 H5A 109.4 . . ?
N4 C5 H5B 109.4 . . ?
C6 C5 H5B 109.4 . . ?
H5A C5 H5B 108.0 . . ?
N5 C6 C5 110.2(3) . . ?
N5 C6 H6A 109.6 . . ?
C5 C6 H6A 109.6 . . ?
N5 C6 H6B 109.6 . . ?
C5 C6 H6B 109.6 . . ?
H6A C6 H6B 108.1 . . ?
N5 C7 C8 110.4(3) . . ?
N5 C7 H7A 109.6 . . ?
C8 C7 H7A 109.6 . . ?
N5 C7 H7B 109.6 . . ?
C8 C7 H7B 109.6 . . ?
H7A C7 H7B 108.1 . . ?
N6 C8 C7 113.6(3) . . ?
N6 C8 H8A 108.8 . . ?
C7 C8 H8A 108.8 . . ?
N6 C8 H8B 108.8 . . ?
C7 C8 H8B 108.8 . . ?
H8A C8 H8B 107.7 . . ?
O1 C9 C14 125.3(3) . . ?
O1 C9 C10 115.4(3) . . ?
C14 C9 C10 119.3(3) . . ?
C12 C10 C11 109.3(3) . . ?
C12 C10 C13 108.9(3) . . ?
C11 C10 C13 108.9(3) . . ?
C12 C10 C9 106.0(3) . . ?
C11 C10 C9 109.9(3) . . ?
C13 C10 C9 113.7(3) . . ?
C10 C11 H11A 109.5 . . ?
C10 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C10 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C10 C12 H12A 109.5 . . ?
C10 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C10 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C10 C13 H13A 109.5 . . ?
C10 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C10 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C9 C14 C15 126.6(3) . . ?
C9 C14 H14 116.7 . . ?
C15 C14 H14 116.7 . . ?
O2 C15 C14 123.8(3) . . ?
O2 C15 C16 115.9(3) . . ?
C14 C15 C16 120.3(3) . . ?
C18 C16 C19 109.2(3) . . ?
C18 C16 C17 107.3(3) . . ?
C19 C16 C17 108.1(3) . . ?
C18 C16 C15 110.1(3) . . ?
C19 C16 C15 107.7(3) . . ?
C17 C16 C15 114.3(3) . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C16 C18 H18A 109.5 . . ?
C16 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C16 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C16 C19 H19A 109.5 . . ?
C16 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C16 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
O3 C20 C25 124.5(3) . . ?
O3 C20 C21 117.1(3) . . ?
C25 C20 C21 118.4(3) . . ?
C23 C21 C24' 57.1(8) . . ?
C23 C21 C22 130.5(9) . . ?
C24' C21 C22 117.6(7) . . ?
C23 C21 C22' 112.9(9) . . ?
C24' C21 C22' 126.1(6) . . ?
C22 C21 C22' 24.0(5) . . ?
C23 C21 C20 116.4(7) . . ?
C24' C21 C20 116.1(5) . . ?
C22 C21 C20 109.0(5) . . ?
C22' C21 C20 114.5(5) . . ?
C23 C21 C24 101.6(9) . . ?
C24' C21 C24 45.7(6) . . ?
C22 C21 C24 81.9(8) . . ?
C22' C21 C24 101.9(8) . . ?
C20 C21 C24 107.3(6) . . ?
C23 C21 C23' 45.9(7) . . ?
C24' C21 C23' 102.9(5) . . ?
C22 C21 C23' 108.2(6) . . ?
C22' C21 C23' 84.2(6) . . ?
C20 C21 C23' 101.2(4) . . ?
C24 C21 C23' 144.8(7) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.4 . . ?
H23A C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C21 C24 H24A 109.5 . . ?
C21 C24 H24B 109.4 . . ?
H24A C24 H24B 109.5 . . ?
C21 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C21 C22' H22D 109.5 . . ?
C21 C22' H22E 109.5 . . ?
H22D C22' H22E 109.5 . . ?
C21 C22' H22F 109.5 . . ?
H22D C22' H22F 109.5 . . ?
H22E C22' H22F 109.5 . . ?
C21 C23' H23D 109.5 . . ?
C21 C23' H23E 109.5 . . ?
H23D C23' H23E 109.5 . . ?
C21 C23' H23F 109.5 . . ?
H23D C23' H23F 109.5 . . ?
H23E C23' H23F 109.5 . . ?
C21 C24' H24D 109.5 . . ?
C21 C24' H24E 109.4 . . ?
H24D C24' H24E 109.5 . . ?
C21 C24' H24F 109.5 . . ?
H24D C24' H24F 109.5 . . ?
H24E C24' H24F 109.5 . . ?
C26 C25 C20 127.0(3) . . ?
C26 C25 H25 116.5 . . ?
C20 C25 H25 116.5 . . ?
O4 C26 C25 124.8(3) . . ?
O4 C26 C27 115.7(3) . . ?
C25 C26 C27 119.5(3) . . ?
C28 C27 C29 108.4(3) . . ?
C28 C27 C30 109.1(3) . . ?
C29 C27 C30 108.8(4) . . ?
C28 C27 C26 115.7(3) . . ?
C29 C27 C26 108.4(3) . . ?
C30 C27 C26 106.2(3) . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C27 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C27 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C27 C30 H30A 109.5 . . ?
C27 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C27 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C1 N1 Ag1 109.1(2) . . ?
C1 N1 H1C 109.9 . . ?
Ag1 N1 H1C 109.9 . . ?
C1 N1 H1D 109.9 . . ?
Ag1 N1 H1D 109.9 . . ?
H1C N1 H1D 108.3 . . ?
C2 N2 C3 112.2(3) . . ?
C2 N2 Ag1 100.7(2) . . ?
C3 N2 Ag1 117.4(2) . . ?
C2 N2 H2 108.7 . . ?
C3 N2 H2 108.7 . . ?
Ag1 N2 H2 108.7 . . ?
C4 N3 Ag1 111.1(2) . 2_756 ?
C4 N3 H3C 109.4 . . ?
Ag1 N3 H3C 109.4 2_756 . ?
C4 N3 H3D 109.4 . . ?
Ag1 N3 H3D 109.4 2_756 . ?
H3C N3 H3D 108.0 . . ?
C5 N4 Ag2 108.6(2) . . ?
C5 N4 H4C 110.0 . . ?
Ag2 N4 H4C 110.0 . . ?
C5 N4 H4D 110.0 . . ?
Ag2 N4 H4D 110.0 . . ?
H4C N4 H4D 108.3 . . ?
C6 N5 C7 113.4(3) . . ?
C6 N5 Ag2 106.5(2) . . ?
C7 N5 Ag2 120.3(2) . . ?
C6 N5 H5 105.1 . . ?
C7 N5 H5 105.1 . . ?
Ag2 N5 H5 105.1 . . ?
C8 N6 Ag2 115.6(2) . 2_755 ?
C8 N6 H6C 108.4 . . ?
Ag2 N6 H6C 108.4 2_755 . ?
C8 N6 H6D 108.4 . . ?
Ag2 N6 H6D 108.4 2_755 . ?
H6C N6 H6D 107.4 . . ?
H5C O5 H5D 115.2 . . ?
N3 Ag1 N1 170.31(11) 2_756 . ?
N3 Ag1 N2 108.27(10) 2_756 . ?
N1 Ag1 N2 75.77(10) . . ?
N3 Ag1 Ag2 101.31(8) 2_756 . ?
N1 Ag1 Ag2 82.52(9) . . ?
N2 Ag1 Ag2 126.02(7) . . ?
N6 Ag2 N4 156.58(13) 2_755 . ?
N6 Ag2 N5 125.79(10) 2_755 . ?
N4 Ag2 N5 76.71(12) . . ?
N6 Ag2 Ag1 95.58(8) 2_755 . ?
N4 Ag2 Ag1 88.35(9) . . ?
N5 Ag2 Ag1 94.08(7) . . ?

_diffrn_measured_fraction_theta_max 0.988
_diffrn_reflns_theta_full        25.08
_diffrn_measured_fraction_theta_full 0.988
_refine_diff_density_max         1.288
_refine_diff_density_min         -0.848
_refine_diff_density_rms         0.240


_database_code_depnum_ccdc_archive 'CCDC 920119'