# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2014

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
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# 
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#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
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data_sad

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C60 H84 N6 O4 Pt'
_chemical_formula_weight         1148.42

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   6.7075(8)
_cell_length_b                   17.804(2)
_cell_length_c                   24.778(3)
_cell_angle_alpha                79.629(2)
_cell_angle_beta                 85.170(2)
_cell_angle_gamma                83.157(3)
_cell_volume                     2883.9(6)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    2544
_cell_measurement_theta_min      2.34
_cell_measurement_theta_max      17.16

_exptl_crystal_description       prismatic
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.03
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.322
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1192
_exptl_absorpt_coefficient_mu    2.482
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6366
_exptl_absorpt_correction_T_max  0.9293
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            22107
_diffrn_reflns_av_R_equivalents  0.0900
_diffrn_reflns_av_sigmaI/netI    0.1570
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_theta_min         1.17
_diffrn_reflns_theta_max         25.00
_reflns_number_total             9850
_reflns_number_gt                4874
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0670P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         9850
_refine_ls_number_parameters     640
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1548
_refine_ls_R_factor_gt           0.0608
_refine_ls_wR_factor_ref         0.1687
_refine_ls_wR_factor_gt          0.1277
_refine_ls_goodness_of_fit_ref   0.998
_refine_ls_restrained_S_all      0.998
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C3 C 0.8890(17) 0.8833(8) 0.2040(5) 0.069(4) Uani 1 1 d . . .
C4 C 0.9999(16) 0.8244(7) 0.1791(5) 0.070(4) Uani 1 1 d . . .
H4 H 1.1259 0.8258 0.1604 0.083 Uiso 1 1 calc R . .
C5 C 0.8797(15) 0.7636(8) 0.1888(4) 0.063(3) Uani 1 1 d . . .
C6 C 0.8981(16) 0.6870(7) 0.1782(4) 0.057(3) Uani 1 1 d . . .
C7 C 1.0546(16) 0.6511(8) 0.1501(5) 0.073(4) Uani 1 1 d . . .
H7 H 1.1647 0.6772 0.1357 0.088 Uiso 1 1 calc R . .
C8 C 1.0490(18) 0.5777(9) 0.1431(5) 0.082(4) Uani 1 1 d . . .
H8 H 1.1548 0.5538 0.1235 0.098 Uiso 1 1 calc R . .
C9 C 0.8903(17) 0.5384(7) 0.1646(5) 0.074(4) Uani 1 1 d . . .
H9 H 0.8904 0.4877 0.1601 0.089 Uiso 1 1 calc R . .
C10 C 0.7251(15) 0.5739(7) 0.1935(4) 0.058(3) Uani 1 1 d . . .
H10 H 0.6166 0.5473 0.2083 0.069 Uiso 1 1 calc R . .
C11 C 0.1435(15) 0.5348(7) 0.2865(5) 0.062(3) Uani 1 1 d . . .
C12 C 0.0405(16) 0.5935(7) 0.3089(4) 0.066(4) Uani 1 1 d . . .
H12 H -0.0847 0.5933 0.3281 0.079 Uiso 1 1 calc R . .
C13 C 0.1595(15) 0.6534(7) 0.2974(4) 0.054(3) Uani 1 1 d . . .
C14 C 0.1438(15) 0.7313(7) 0.3090(4) 0.056(3) Uani 1 1 d . . .
C15 C -0.0106(17) 0.7656(8) 0.3382(5) 0.082(4) Uani 1 1 d . . .
H15 H -0.1221 0.7400 0.3519 0.098 Uiso 1 1 calc R . .
C16 C 0.0015(18) 0.8366(8) 0.3468(5) 0.087(4) Uani 1 1 d . . .
H16 H -0.1020 0.8601 0.3674 0.105 Uiso 1 1 calc R . .
C17 C 0.1638(17) 0.8761(7) 0.3260(5) 0.076(4) Uani 1 1 d . . .
H17 H 0.1712 0.9258 0.3319 0.092 Uiso 1 1 calc R . .
C18 C 0.3131(15) 0.8393(7) 0.2964(4) 0.065(3) Uani 1 1 d . . .
H18 H 0.4223 0.8656 0.2816 0.078 Uiso 1 1 calc R . .
C19 C 0.9376(15) 0.9570(7) 0.2116(5) 0.061(3) Uani 1 1 d . . .
C20 C 1.1108(16) 0.9874(7) 0.1857(5) 0.069(3) Uani 1 1 d . . .
H20 H 1.1970 0.9606 0.1627 0.082 Uiso 1 1 calc R . .
C21 C 1.1524(17) 1.0593(8) 0.1950(5) 0.076(4) Uani 1 1 d . . .
C22 C 1.0241(16) 1.1020(6) 0.2283(5) 0.068(3) Uani 1 1 d . . .
H22 H 1.0518 1.1502 0.2332 0.082 Uiso 1 1 calc R . .
C23 C 0.8529(16) 1.0701(7) 0.2537(5) 0.071(4) Uani 1 1 d . . .
C24 C 0.8106(16) 0.9987(7) 0.2442(5) 0.068(3) Uani 1 1 d . . .
H24 H 0.6934 0.9790 0.2605 0.082 Uiso 1 1 calc R . .
C25 C 1.4545(18) 1.0579(7) 0.1344(5) 0.083(4) Uani 1 1 d . . .
H25A H 1.3826 1.0473 0.1047 0.099 Uiso 1 1 calc R . .
H25B H 1.5191 1.0098 0.1533 0.099 Uiso 1 1 calc R . .
C26 C 1.6092(17) 1.1127(7) 0.1122(5) 0.082(4) Uani 1 1 d . . .
H26A H 1.6790 1.1230 0.1424 0.098 Uiso 1 1 calc R . .
H26B H 1.5419 1.1609 0.0944 0.098 Uiso 1 1 calc R . .
C27 C 1.7610(17) 1.0796(8) 0.0712(5) 0.090(4) Uani 1 1 d . . .
H27A H 1.8276 1.0313 0.0892 0.107 Uiso 1 1 calc R . .
H27B H 1.6905 1.0691 0.0412 0.107 Uiso 1 1 calc R . .
C28 C 1.9182(17) 1.1335(8) 0.0481(5) 0.092(4) Uani 1 1 d . . .
H28A H 1.8501 1.1825 0.0319 0.111 Uiso 1 1 calc R . .
H28B H 1.9912 1.1423 0.0781 0.111 Uiso 1 1 calc R . .
C29 C 2.0672(19) 1.1050(9) 0.0055(6) 0.104(5) Uani 1 1 d . . .
H29A H 1.9940 1.0960 -0.0245 0.125 Uiso 1 1 calc R . .
H29B H 2.1356 1.0561 0.0217 0.125 Uiso 1 1 calc R . .
C30 C 2.2245(19) 1.1589(9) -0.0181(6) 0.107(5) Uani 1 1 d . . .
H30A H 2.1573 1.2070 -0.0361 0.128 Uiso 1 1 calc R . .
H30B H 2.2946 1.1698 0.0119 0.128 Uiso 1 1 calc R . .
C31 C 2.375(2) 1.1272(10) -0.0582(6) 0.125(6) Uani 1 1 d . . .
H31A H 2.3057 1.1177 -0.0888 0.150 Uiso 1 1 calc R . .
H31B H 2.4405 1.0786 -0.0405 0.150 Uiso 1 1 calc R . .
C32 C 2.532(2) 1.1821(12) -0.0797(7) 0.170(8) Uani 1 1 d . . .
H32A H 2.5003 1.2285 -0.0648 0.254 Uiso 1 1 calc R . .
H32B H 2.5342 1.1939 -0.1191 0.254 Uiso 1 1 calc R . .
H32C H 2.6625 1.1583 -0.0689 0.254 Uiso 1 1 calc R . .
C33 C 0.5561(16) 1.0842(7) 0.3117(5) 0.082(4) Uani 1 1 d . . .
H33A H 0.5931 1.0353 0.3349 0.098 Uiso 1 1 calc R . .
H33B H 0.4755 1.0748 0.2834 0.098 Uiso 1 1 calc R . .
C34 C 0.4311(18) 1.1365(8) 0.3462(5) 0.096(4) Uani 1 1 d . . .
H34A H 0.3896 1.1849 0.3230 0.115 Uiso 1 1 calc R . .
H34B H 0.5118 1.1470 0.3741 0.115 Uiso 1 1 calc R . .
C35 C 0.2491(18) 1.1009(8) 0.3731(5) 0.092(4) Uani 1 1 d . . .
H35A H 0.2928 1.0508 0.3937 0.111 Uiso 1 1 calc R . .
H35B H 0.1673 1.0929 0.3446 0.111 Uiso 1 1 calc R . .
C36 C 0.1189(18) 1.1457(8) 0.4113(5) 0.099(5) Uani 1 1 d . . .
H36A H 0.0686 1.1949 0.3907 0.119 Uiso 1 1 calc R . .
H36B H 0.2005 1.1555 0.4393 0.119 Uiso 1 1 calc R . .
C37 C -0.0599(19) 1.1044(8) 0.4394(6) 0.106(5) Uani 1 1 d . . .
H37A H -0.1395 1.0950 0.4109 0.128 Uiso 1 1 calc R . .
H37B H -0.0072 1.0547 0.4590 0.128 Uiso 1 1 calc R . .
C38 C -0.196(2) 1.1426(9) 0.4782(6) 0.114(5) Uani 1 1 d . . .
H38A H -0.2493 1.1922 0.4588 0.137 Uiso 1 1 calc R . .
H38B H -0.1168 1.1520 0.5069 0.137 Uiso 1 1 calc R . .
C39 C -0.369(2) 1.1005(10) 0.5048(7) 0.158(8) Uani 1 1 d . . .
H39A H -0.4482 1.0918 0.4760 0.190 Uiso 1 1 calc R . .
H39B H -0.3146 1.0505 0.5236 0.190 Uiso 1 1 calc R . .
C40 C -0.504(2) 1.1374(11) 0.5444(7) 0.163(8) Uani 1 1 d . . .
H40A H -0.4362 1.1354 0.5773 0.244 Uiso 1 1 calc R . .
H40B H -0.6222 1.1110 0.5530 0.244 Uiso 1 1 calc R . .
H40C H -0.5415 1.1900 0.5286 0.244 Uiso 1 1 calc R . .
C41 C 0.0882(15) 0.4573(7) 0.2845(4) 0.055(3) Uani 1 1 d . . .
C42 C -0.0945(15) 0.4358(7) 0.3122(4) 0.067(3) Uani 1 1 d . . .
H42 H -0.1770 0.4704 0.3303 0.080 Uiso 1 1 calc R . .
C43 C -0.1507(15) 0.3641(7) 0.3125(5) 0.060(3) Uani 1 1 d . . .
C44 C -0.0264(15) 0.3124(7) 0.2842(4) 0.066(3) Uani 1 1 d . . .
H44 H -0.0652 0.2641 0.2836 0.079 Uiso 1 1 calc R . .
C45 C 0.1499(16) 0.3329(8) 0.2578(5) 0.067(3) Uani 1 1 d . . .
C46 C 0.2074(16) 0.4053(7) 0.2573(4) 0.064(3) Uani 1 1 d . . .
H46 H 0.3272 0.4190 0.2385 0.076 Uiso 1 1 calc R . .
C47 C -0.4526(14) 0.3878(7) 0.3699(4) 0.064(3) Uani 1 1 d . . .
H47A H -0.5081 0.4329 0.3456 0.077 Uiso 1 1 calc R . .
H47B H -0.3780 0.4043 0.3967 0.077 Uiso 1 1 calc R . .
C48 C -0.6200(15) 0.3427(7) 0.3986(4) 0.069(3) Uani 1 1 d . . .
H48A H -0.5632 0.2971 0.4224 0.082 Uiso 1 1 calc R . .
H48B H -0.6941 0.3264 0.3716 0.082 Uiso 1 1 calc R . .
C49 C -0.7613(16) 0.3918(7) 0.4325(5) 0.072(3) Uani 1 1 d . . .
H49A H -0.8184 0.4370 0.4085 0.087 Uiso 1 1 calc R . .
H49B H -0.6858 0.4087 0.4589 0.087 Uiso 1 1 calc R . .
C50 C -0.9315(15) 0.3480(7) 0.4630(5) 0.079(4) Uani 1 1 d . . .
H50A H -1.0052 0.3304 0.4365 0.094 Uiso 1 1 calc R . .
H50B H -0.8738 0.3031 0.4872 0.094 Uiso 1 1 calc R . .
C51 C -1.0757(16) 0.3954(7) 0.4965(5) 0.079(4) Uani 1 1 d . . .
H51A H -1.1327 0.4403 0.4721 0.095 Uiso 1 1 calc R . .
H51B H -1.0011 0.4132 0.5227 0.095 Uiso 1 1 calc R . .
C52 C -1.2471(16) 0.3535(7) 0.5275(5) 0.080(4) Uani 1 1 d . . .
H52A H -1.3246 0.3370 0.5013 0.097 Uiso 1 1 calc R . .
H52B H -1.1908 0.3079 0.5513 0.097 Uiso 1 1 calc R . .
C53 C -1.3861(18) 0.4019(9) 0.5618(5) 0.100(5) Uani 1 1 d . . .
H53A H -1.3096 0.4171 0.5888 0.121 Uiso 1 1 calc R . .
H53B H -1.4395 0.4482 0.5382 0.121 Uiso 1 1 calc R . .
C54 C -1.560(2) 0.3607(11) 0.5913(6) 0.136(7) Uani 1 1 d . . .
H54A H -1.6152 0.3341 0.5666 0.205 Uiso 1 1 calc R . .
H54B H -1.6619 0.3974 0.6038 0.205 Uiso 1 1 calc R . .
H54C H -1.5125 0.3244 0.6224 0.205 Uiso 1 1 calc R . .
C55 C 0.4709(18) 0.2821(8) 0.2182(6) 0.102(5) Uani 1 1 d . . .
H55A H 0.5218 0.3101 0.2433 0.122 Uiso 1 1 calc R . .
H55B H 0.5375 0.2301 0.2244 0.122 Uiso 1 1 calc R . .
C56 C 0.5215(17) 0.3176(9) 0.1627(5) 0.100(5) Uani 1 1 d . . .
H56A H 0.4624 0.3707 0.1572 0.120 Uiso 1 1 calc R . .
H56B H 0.4630 0.2917 0.1376 0.120 Uiso 1 1 calc R . .
C57 C 0.7482(16) 0.3155(8) 0.1487(5) 0.093(4) Uani 1 1 d . . .
H57A H 0.8029 0.3438 0.1730 0.112 Uiso 1 1 calc R . .
H57B H 0.8060 0.2625 0.1574 0.112 Uiso 1 1 calc R . .
C58 C 0.8198(18) 0.3461(9) 0.0916(5) 0.098(4) Uani 1 1 d . . .
H58A H 0.7578 0.3984 0.0821 0.117 Uiso 1 1 calc R . .
H58B H 0.7717 0.3162 0.0673 0.117 Uiso 1 1 calc R . .
C59 C 1.0385(18) 0.3464(9) 0.0805(6) 0.108(5) Uani 1 1 d . . .
H59A H 1.1007 0.2943 0.0907 0.130 Uiso 1 1 calc R . .
H59B H 1.0862 0.3772 0.1043 0.130 Uiso 1 1 calc R . .
C60 C 1.112(2) 0.3759(11) 0.0226(7) 0.136(6) Uani 1 1 d . . .
H60A H 1.0657 0.3446 -0.0011 0.163 Uiso 1 1 calc R . .
H60B H 1.0477 0.4277 0.0122 0.163 Uiso 1 1 calc R . .
C61 C 1.330(2) 0.3773(12) 0.0116(7) 0.147(7) Uani 1 1 d . . .
H61A H 1.3735 0.4088 0.0356 0.177 Uiso 1 1 calc R . .
H61B H 1.3919 0.3255 0.0232 0.177 Uiso 1 1 calc R . .
C62 C 1.413(3) 0.4029(15) -0.0413(8) 0.213(12) Uani 1 1 d . . .
H62A H 1.4603 0.3595 -0.0587 0.320 Uiso 1 1 calc R . .
H62B H 1.5242 0.4314 -0.0389 0.320 Uiso 1 1 calc R . .
H62C H 1.3130 0.4353 -0.0625 0.320 Uiso 1 1 calc R . .
N1 N 0.7104(12) 0.7857(6) 0.2193(4) 0.066(3) Uani 1 1 d . . .
N2 N 0.7117(13) 0.8581(5) 0.2277(4) 0.061(2) Uani 1 1 d . . .
N3 N 0.7304(12) 0.6486(6) 0.1990(3) 0.061(2) Uani 1 1 d . . .
N4 N 0.3309(12) 0.6293(6) 0.2666(3) 0.061(3) Uani 1 1 d . . .
N5 N 0.3181(13) 0.5585(6) 0.2609(4) 0.065(3) Uani 1 1 d . . .
N6 N 0.3110(13) 0.7675(6) 0.2874(3) 0.059(2) Uani 1 1 d . . .
O1 O 1.3169(12) 1.0953(5) 0.1724(3) 0.087(3) Uani 1 1 d . . .
O2 O 0.7349(11) 1.1153(5) 0.2864(3) 0.087(3) Uani 1 1 d . . .
O3 O -0.3206(10) 0.3382(4) 0.3385(3) 0.078(2) Uani 1 1 d . . .
O4 O 0.2554(11) 0.2794(5) 0.2306(3) 0.090(3) Uani 1 1 d . . .
Pt1 Pt 0.51906(6) 0.70819(3) 0.243182(19) 0.0585(2) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C3 N2 1.370(12) . ?
C3 C19 1.435(15) . ?
C3 C4 1.415(15) . ?
C4 C5 1.401(15) . ?
C4 H4 0.9300 . ?
C5 N1 1.367(12) . ?
C5 C6 1.424(15) . ?
C6 N3 1.399(12) . ?
C6 C7 1.368(14) . ?
C7 C8 1.353(15) . ?
C7 H7 0.9300 . ?
C8 C9 1.361(15) . ?
C8 H8 0.9300 . ?
C9 C10 1.415(13) . ?
C9 H9 0.9300 . ?
C10 N3 1.365(12) . ?
C10 H10 0.9300 . ?
C11 N5 1.359(12) . ?
C11 C12 1.359(14) . ?
C11 C41 1.482(15) . ?
C12 C13 1.382(14) . ?
C12 H12 0.9300 . ?
C13 N4 1.393(12) . ?
C13 C14 1.456(14) . ?
C14 C15 1.362(14) . ?
C14 N6 1.381(12) . ?
C15 C16 1.331(15) . ?
C15 H15 0.9300 . ?
C16 C17 1.379(15) . ?
C16 H16 0.9300 . ?
C17 C18 1.366(14) . ?
C17 H17 0.9300 . ?
C18 N6 1.337(13) . ?
C18 H18 0.9300 . ?
C19 C24 1.372(14) . ?
C19 C20 1.398(13) . ?
C20 C21 1.405(15) . ?
C20 H20 0.9300 . ?
C21 O1 1.370(12) . ?
C21 C22 1.395(15) . ?
C22 C23 1.394(14) . ?
C22 H22 0.9300 . ?
C23 O2 1.380(12) . ?
C23 C24 1.399(15) . ?
C24 H24 0.9300 . ?
C25 O1 1.455(12) . ?
C25 C26 1.511(15) . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C26 C27 1.521(15) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C27 C28 1.518(15) . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C28 C29 1.505(16) . ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
C29 C30 1.520(16) . ?
C29 H29A 0.9700 . ?
C29 H29B 0.9700 . ?
C30 C31 1.489(17) . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C31 C32 1.525(19) . ?
C31 H31A 0.9700 . ?
C31 H31B 0.9700 . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C33 O2 1.431(12) . ?
C33 C34 1.509(14) . ?
C33 H33A 0.9700 . ?
C33 H33B 0.9700 . ?
C34 C35 1.495(15) . ?
C34 H34A 0.9700 . ?
C34 H34B 0.9700 . ?
C35 C36 1.504(15) . ?
C35 H35A 0.9700 . ?
C35 H35B 0.9700 . ?
C36 C37 1.532(16) . ?
C36 H36A 0.9700 . ?
C36 H36B 0.9700 . ?
C37 C38 1.468(15) . ?
C37 H37A 0.9700 . ?
C37 H37B 0.9700 . ?
C38 C39 1.499(18) . ?
C38 H38A 0.9700 . ?
C38 H38B 0.9700 . ?
C39 C40 1.468(18) . ?
C39 H39A 0.9700 . ?
C39 H39B 0.9700 . ?
C40 H40A 0.9600 . ?
C40 H40B 0.9600 . ?
C40 H40C 0.9600 . ?
C41 C46 1.381(14) . ?
C41 C42 1.412(13) . ?
C42 C43 1.372(14) . ?
C42 H42 0.9300 . ?
C43 O3 1.350(11) . ?
C43 C44 1.410(14) . ?
C44 C45 1.359(13) . ?
C44 H44 0.9300 . ?
C45 C46 1.388(15) . ?
C45 O4 1.359(12) . ?
C46 H46 0.9300 . ?
C47 O3 1.454(11) . ?
C47 C48 1.512(13) . ?
C47 H47A 0.9700 . ?
C47 H47B 0.9700 . ?
C48 C49 1.516(14) . ?
C48 H48A 0.9700 . ?
C48 H48B 0.9700 . ?
C49 C50 1.528(14) . ?
C49 H49A 0.9700 . ?
C49 H49B 0.9700 . ?
C50 C51 1.501(14) . ?
C50 H50A 0.9700 . ?
C50 H50B 0.9700 . ?
C51 C52 1.523(14) . ?
C51 H51A 0.9700 . ?
C51 H51B 0.9700 . ?
C52 C53 1.507(15) . ?
C52 H52A 0.9700 . ?
C52 H52B 0.9700 . ?
C53 C54 1.516(17) . ?
C53 H53A 0.9700 . ?
C53 H53B 0.9700 . ?
C54 H54A 0.9600 . ?
C54 H54B 0.9600 . ?
C54 H54C 0.9600 . ?
C55 C56 1.438(16) . ?
C55 O4 1.457(13) . ?
C55 H55A 0.9700 . ?
C55 H55B 0.9700 . ?
C56 C57 1.529(15) . ?
C56 H56A 0.9700 . ?
C56 H56B 0.9700 . ?
C57 C58 1.483(16) . ?
C57 H57A 0.9700 . ?
C57 H57B 0.9700 . ?
C58 C59 1.470(15) . ?
C58 H58A 0.9700 . ?
C58 H58B 0.9700 . ?
C59 C60 1.497(18) . ?
C59 H59A 0.9700 . ?
C59 H59B 0.9700 . ?
C60 C61 1.471(18) . ?
C60 H60A 0.9700 . ?
C60 H60B 0.9700 . ?
C61 C62 1.399(19) . ?
C61 H61A 0.9700 . ?
C61 H61B 0.9700 . ?
C62 H62A 0.9600 . ?
C62 H62B 0.9600 . ?
C62 H62C 0.9600 . ?
N1 N2 1.344(11) . ?
N1 Pt1 1.975(9) . ?
N3 Pt1 2.033(9) . ?
N4 N5 1.308(11) . ?
N4 Pt1 1.976(10) . ?
N6 Pt1 2.018(9) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 C3 C19 118.9(10) . . ?
N2 C3 C4 109.0(11) . . ?
C19 C3 C4 132.0(11) . . ?
C5 C4 C3 105.3(10) . . ?
C5 C4 H4 127.3 . . ?
C3 C4 H4 127.3 . . ?
N1 C5 C4 107.5(11) . . ?
N1 C5 C6 116.1(10) . . ?
C4 C5 C6 136.3(10) . . ?
N3 C6 C7 120.3(11) . . ?
N3 C6 C5 112.6(9) . . ?
C7 C6 C5 127.1(11) . . ?
C8 C7 C6 120.0(11) . . ?
C8 C7 H7 120.0 . . ?
C6 C7 H7 120.0 . . ?
C7 C8 C9 120.8(11) . . ?
C7 C8 H8 119.6 . . ?
C9 C8 H8 119.6 . . ?
C8 C9 C10 120.8(12) . . ?
C8 C9 H9 119.6 . . ?
C10 C9 H9 119.6 . . ?
N3 C10 C9 117.8(11) . . ?
N3 C10 H10 121.1 . . ?
C9 C10 H10 121.1 . . ?
N5 C11 C12 108.8(11) . . ?
N5 C11 C41 120.7(10) . . ?
C12 C11 C41 130.4(10) . . ?
C11 C12 C13 106.1(9) . . ?
C11 C12 H12 126.9 . . ?
C13 C12 H12 126.9 . . ?
N4 C13 C12 107.6(10) . . ?
N4 C13 C14 116.8(10) . . ?
C12 C13 C14 135.6(10) . . ?
C15 C14 N6 122.5(11) . . ?
C15 C14 C13 126.1(11) . . ?
N6 C14 C13 111.4(9) . . ?
C16 C15 C14 118.6(11) . . ?
C16 C15 H15 120.7 . . ?
C14 C15 H15 120.7 . . ?
C15 C16 C17 121.6(11) . . ?
C15 C16 H16 119.2 . . ?
C17 C16 H16 119.2 . . ?
C18 C17 C16 117.3(11) . . ?
C18 C17 H17 121.3 . . ?
C16 C17 H17 121.3 . . ?
N6 C18 C17 123.6(10) . . ?
N6 C18 H18 118.2 . . ?
C17 C18 H18 118.2 . . ?
C24 C19 C20 119.3(11) . . ?
C24 C19 C3 119.5(10) . . ?
C20 C19 C3 121.2(11) . . ?
C19 C20 C21 118.8(11) . . ?
C19 C20 H20 120.6 . . ?
C21 C20 H20 120.6 . . ?
O1 C21 C22 113.3(11) . . ?
O1 C21 C20 124.6(10) . . ?
C22 C21 C20 122.1(10) . . ?
C21 C22 C23 117.8(11) . . ?
C21 C22 H22 121.1 . . ?
C23 C22 H22 121.1 . . ?
O2 C23 C24 125.5(11) . . ?
O2 C23 C22 114.4(11) . . ?
C24 C23 C22 120.2(10) . . ?
C19 C24 C23 121.7(11) . . ?
C19 C24 H24 119.1 . . ?
C23 C24 H24 119.1 . . ?
O1 C25 C26 106.5(9) . . ?
O1 C25 H25A 110.4 . . ?
C26 C25 H25A 110.4 . . ?
O1 C25 H25B 110.4 . . ?
C26 C25 H25B 110.4 . . ?
H25A C25 H25B 108.6 . . ?
C25 C26 C27 111.2(10) . . ?
C25 C26 H26A 109.4 . . ?
C27 C26 H26A 109.4 . . ?
C25 C26 H26B 109.4 . . ?
C27 C26 H26B 109.4 . . ?
H26A C26 H26B 108.0 . . ?
C28 C27 C26 112.4(11) . . ?
C28 C27 H27A 109.1 . . ?
C26 C27 H27A 109.1 . . ?
C28 C27 H27B 109.1 . . ?
C26 C27 H27B 109.1 . . ?
H27A C27 H27B 107.9 . . ?
C29 C28 C27 114.6(11) . . ?
C29 C28 H28A 108.6 . . ?
C27 C28 H28A 108.6 . . ?
C29 C28 H28B 108.6 . . ?
C27 C28 H28B 108.6 . . ?
H28A C28 H28B 107.6 . . ?
C28 C29 C30 114.9(12) . . ?
C28 C29 H29A 108.6 . . ?
C30 C29 H29A 108.6 . . ?
C28 C29 H29B 108.6 . . ?
C30 C29 H29B 108.6 . . ?
H29A C29 H29B 107.5 . . ?
C31 C30 C29 113.2(13) . . ?
C31 C30 H30A 108.9 . . ?
C29 C30 H30A 108.9 . . ?
C31 C30 H30B 108.9 . . ?
C29 C30 H30B 108.9 . . ?
H30A C30 H30B 107.7 . . ?
C30 C31 C32 111.6(14) . . ?
C30 C31 H31A 109.3 . . ?
C32 C31 H31A 109.3 . . ?
C30 C31 H31B 109.3 . . ?
C32 C31 H31B 109.3 . . ?
H31A C31 H31B 108.0 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
O2 C33 C34 112.8(10) . . ?
O2 C33 H33A 109.0 . . ?
C34 C33 H33A 109.0 . . ?
O2 C33 H33B 109.0 . . ?
C34 C33 H33B 109.0 . . ?
H33A C33 H33B 107.8 . . ?
C33 C34 C35 111.0(11) . . ?
C33 C34 H34A 109.4 . . ?
C35 C34 H34A 109.4 . . ?
C33 C34 H34B 109.4 . . ?
C35 C34 H34B 109.4 . . ?
H34A C34 H34B 108.0 . . ?
C34 C35 C36 116.0(11) . . ?
C34 C35 H35A 108.3 . . ?
C36 C35 H35A 108.3 . . ?
C34 C35 H35B 108.3 . . ?
C36 C35 H35B 108.3 . . ?
H35A C35 H35B 107.4 . . ?
C35 C36 C37 113.3(12) . . ?
C35 C36 H36A 108.9 . . ?
C37 C36 H36A 108.9 . . ?
C35 C36 H36B 108.9 . . ?
C37 C36 H36B 108.9 . . ?
H36A C36 H36B 107.7 . . ?
C38 C37 C36 117.8(13) . . ?
C38 C37 H37A 107.8 . . ?
C36 C37 H37A 107.8 . . ?
C38 C37 H37B 107.8 . . ?
C36 C37 H37B 107.8 . . ?
H37A C37 H37B 107.2 . . ?
C37 C38 C39 116.3(14) . . ?
C37 C38 H38A 108.2 . . ?
C39 C38 H38A 108.2 . . ?
C37 C38 H38B 108.2 . . ?
C39 C38 H38B 108.2 . . ?
H38A C38 H38B 107.4 . . ?
C40 C39 C38 116.9(16) . . ?
C40 C39 H39A 108.1 . . ?
C38 C39 H39A 108.1 . . ?
C40 C39 H39B 108.1 . . ?
C38 C39 H39B 108.1 . . ?
H39A C39 H39B 107.3 . . ?
C39 C40 H40A 109.5 . . ?
C39 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C39 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C46 C41 C42 118.9(11) . . ?
C46 C41 C11 123.0(10) . . ?
C42 C41 C11 118.0(10) . . ?
C43 C42 C41 120.3(11) . . ?
C43 C42 H42 119.9 . . ?
C41 C42 H42 119.9 . . ?
O3 C43 C42 124.5(10) . . ?
O3 C43 C44 115.9(10) . . ?
C42 C43 C44 119.6(10) . . ?
C45 C44 C43 120.2(11) . . ?
C45 C44 H44 119.9 . . ?
C43 C44 H44 119.9 . . ?
C46 C45 O4 124.1(10) . . ?
C46 C45 C44 120.5(11) . . ?
O4 C45 C44 115.3(11) . . ?
C41 C46 C45 120.5(10) . . ?
C41 C46 H46 119.7 . . ?
C45 C46 H46 119.7 . . ?
O3 C47 C48 108.0(8) . . ?
O3 C47 H47A 110.1 . . ?
C48 C47 H47A 110.1 . . ?
O3 C47 H47B 110.1 . . ?
C48 C47 H47B 110.1 . . ?
H47A C47 H47B 108.4 . . ?
C47 C48 C49 110.1(9) . . ?
C47 C48 H48A 109.6 . . ?
C49 C48 H48A 109.6 . . ?
C47 C48 H48B 109.6 . . ?
C49 C48 H48B 109.6 . . ?
H48A C48 H48B 108.1 . . ?
C48 C49 C50 112.0(10) . . ?
C48 C49 H49A 109.2 . . ?
C50 C49 H49A 109.2 . . ?
C48 C49 H49B 109.2 . . ?
C50 C49 H49B 109.2 . . ?
H49A C49 H49B 107.9 . . ?
C51 C50 C49 113.3(10) . . ?
C51 C50 H50A 108.9 . . ?
C49 C50 H50A 108.9 . . ?
C51 C50 H50B 108.9 . . ?
C49 C50 H50B 108.9 . . ?
H50A C50 H50B 107.7 . . ?
C50 C51 C52 114.7(10) . . ?
C50 C51 H51A 108.6 . . ?
C52 C51 H51A 108.6 . . ?
C50 C51 H51B 108.6 . . ?
C52 C51 H51B 108.6 . . ?
H51A C51 H51B 107.6 . . ?
C53 C52 C51 113.4(10) . . ?
C53 C52 H52A 108.9 . . ?
C51 C52 H52A 108.9 . . ?
C53 C52 H52B 108.9 . . ?
C51 C52 H52B 108.9 . . ?
H52A C52 H52B 107.7 . . ?
C54 C53 C52 113.2(12) . . ?
C54 C53 H53A 108.9 . . ?
C52 C53 H53A 108.9 . . ?
C54 C53 H53B 108.9 . . ?
C52 C53 H53B 108.9 . . ?
H53A C53 H53B 107.8 . . ?
C53 C54 H54A 109.5 . . ?
C53 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C53 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C56 C55 O4 113.4(11) . . ?
C56 C55 H55A 108.9 . . ?
O4 C55 H55A 108.9 . . ?
C56 C55 H55B 108.9 . . ?
O4 C55 H55B 108.9 . . ?
H55A C55 H55B 107.7 . . ?
C55 C56 C57 113.2(11) . . ?
C55 C56 H56A 108.9 . . ?
C57 C56 H56A 108.9 . . ?
C55 C56 H56B 108.9 . . ?
C57 C56 H56B 108.9 . . ?
H56A C56 H56B 107.8 . . ?
C58 C57 C56 118.3(11) . . ?
C58 C57 H57A 107.7 . . ?
C56 C57 H57A 107.7 . . ?
C58 C57 H57B 107.7 . . ?
C56 C57 H57B 107.7 . . ?
H57A C57 H57B 107.1 . . ?
C57 C58 C59 116.7(12) . . ?
C57 C58 H58A 108.1 . . ?
C59 C58 H58A 108.1 . . ?
C57 C58 H58B 108.1 . . ?
C59 C58 H58B 108.1 . . ?
H58A C58 H58B 107.3 . . ?
C58 C59 C60 116.9(13) . . ?
C58 C59 H59A 108.1 . . ?
C60 C59 H59A 108.1 . . ?
C58 C59 H59B 108.1 . . ?
C60 C59 H59B 108.1 . . ?
H59A C59 H59B 107.3 . . ?
C61 C60 C59 116.9(14) . . ?
C61 C60 H60A 108.1 . . ?
C59 C60 H60A 108.1 . . ?
C61 C60 H60B 108.1 . . ?
C59 C60 H60B 108.1 . . ?
H60A C60 H60B 107.3 . . ?
C62 C61 C60 121.3(17) . . ?
C62 C61 H61A 107.0 . . ?
C60 C61 H61A 107.0 . . ?
C62 C61 H61B 107.0 . . ?
C60 C61 H61B 107.0 . . ?
H61A C61 H61B 106.7 . . ?
C61 C62 H62A 109.5 . . ?
C61 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C61 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
N2 N1 C5 110.8(9) . . ?
N2 N1 Pt1 132.7(7) . . ?
C5 N1 Pt1 116.5(8) . . ?
N1 N2 C3 107.4(9) . . ?
C6 N3 C10 120.3(9) . . ?
C6 N3 Pt1 115.1(7) . . ?
C10 N3 Pt1 124.3(7) . . ?
N5 N4 C13 107.8(9) . . ?
N5 N4 Pt1 137.9(7) . . ?
C13 N4 Pt1 114.4(8) . . ?
N4 N5 C11 109.7(10) . . ?
C18 N6 C14 116.3(9) . . ?
C18 N6 Pt1 127.2(7) . . ?
C14 N6 Pt1 116.5(7) . . ?
C21 O1 C25 117.8(9) . . ?
C23 O2 C33 115.0(9) . . ?
C43 O3 C47 118.8(8) . . ?
C45 O4 C55 119.4(10) . . ?
N4 Pt1 N1 179.0(4) . . ?
N4 Pt1 N6 80.8(4) . . ?
N1 Pt1 N6 100.2(4) . . ?
N4 Pt1 N3 99.5(4) . . ?
N1 Pt1 N3 79.6(4) . . ?
N6 Pt1 N3 179.5(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 C3 C4 C5 0.5(13) . . . . ?
C19 C3 C4 C5 174.7(12) . . . . ?
C3 C4 C5 N1 -1.8(13) . . . . ?
C3 C4 C5 C6 -176.8(13) . . . . ?
N1 C5 C6 N3 3.0(14) . . . . ?
C4 C5 C6 N3 177.7(12) . . . . ?
N1 C5 C6 C7 -178.3(11) . . . . ?
C4 C5 C6 C7 -4(2) . . . . ?
N3 C6 C7 C8 -1.1(18) . . . . ?
C5 C6 C7 C8 -179.7(12) . . . . ?
C6 C7 C8 C9 -1(2) . . . . ?
C7 C8 C9 C10 1.4(19) . . . . ?
C8 C9 C10 N3 0.2(17) . . . . ?
N5 C11 C12 C13 -1.3(13) . . . . ?
C41 C11 C12 C13 -178.2(11) . . . . ?
C11 C12 C13 N4 1.6(12) . . . . ?
C11 C12 C13 C14 -179.6(12) . . . . ?
N4 C13 C14 C15 -179.9(11) . . . . ?
C12 C13 C14 C15 1(2) . . . . ?
N4 C13 C14 N6 -1.5(13) . . . . ?
C12 C13 C14 N6 179.7(12) . . . . ?
N6 C14 C15 C16 -0.7(19) . . . . ?
C13 C14 C15 C16 177.6(12) . . . . ?
C14 C15 C16 C17 1(2) . . . . ?
C15 C16 C17 C18 0(2) . . . . ?
C16 C17 C18 N6 -1.0(19) . . . . ?
N2 C3 C19 C24 2.9(17) . . . . ?
C4 C3 C19 C24 -170.9(12) . . . . ?
N2 C3 C19 C20 -176.3(10) . . . . ?
C4 C3 C19 C20 10(2) . . . . ?
C24 C19 C20 C21 1.6(17) . . . . ?
C3 C19 C20 C21 -179.3(11) . . . . ?
C19 C20 C21 O1 179.8(11) . . . . ?
C19 C20 C21 C22 -1.6(19) . . . . ?
O1 C21 C22 C23 -179.4(10) . . . . ?
C20 C21 C22 C23 1.8(19) . . . . ?
C21 C22 C23 O2 179.2(10) . . . . ?
C21 C22 C23 C24 -2.1(18) . . . . ?
C20 C19 C24 C23 -2.0(18) . . . . ?
C3 C19 C24 C23 178.9(11) . . . . ?
O2 C23 C24 C19 -179.2(11) . . . . ?
C22 C23 C24 C19 2.2(19) . . . . ?
O1 C25 C26 C27 -179.4(10) . . . . ?
C25 C26 C27 C28 179.9(11) . . . . ?
C26 C27 C28 C29 -177.5(11) . . . . ?
C27 C28 C29 C30 179.8(12) . . . . ?
C28 C29 C30 C31 177.4(13) . . . . ?
C29 C30 C31 C32 -178.6(13) . . . . ?
O2 C33 C34 C35 -178.4(11) . . . . ?
C33 C34 C35 C36 176.5(12) . . . . ?
C34 C35 C36 C37 -177.6(12) . . . . ?
C35 C36 C37 C38 179.2(13) . . . . ?
C36 C37 C38 C39 -180.0(14) . . . . ?
C37 C38 C39 C40 179.0(15) . . . . ?
N5 C11 C41 C46 0.0(17) . . . . ?
C12 C11 C41 C46 176.6(12) . . . . ?
N5 C11 C41 C42 179.5(10) . . . . ?
C12 C11 C41 C42 -3.9(18) . . . . ?
C46 C41 C42 C43 0.8(16) . . . . ?
C11 C41 C42 C43 -178.8(10) . . . . ?
C41 C42 C43 O3 179.0(10) . . . . ?
C41 C42 C43 C44 -1.0(17) . . . . ?
O3 C43 C44 C45 -178.6(10) . . . . ?
C42 C43 C44 C45 1.3(17) . . . . ?
C43 C44 C45 C46 -1.4(17) . . . . ?
C43 C44 C45 O4 -178.4(10) . . . . ?
C42 C41 C46 C45 -0.8(17) . . . . ?
C11 C41 C46 C45 178.7(11) . . . . ?
O4 C45 C46 C41 177.8(10) . . . . ?
C44 C45 C46 C41 1.2(18) . . . . ?
O3 C47 C48 C49 179.4(9) . . . . ?
C47 C48 C49 C50 -179.1(9) . . . . ?
C48 C49 C50 C51 -179.3(10) . . . . ?
C49 C50 C51 C52 -179.9(10) . . . . ?
C50 C51 C52 C53 178.5(11) . . . . ?
C51 C52 C53 C54 178.3(11) . . . . ?
O4 C55 C56 C57 -176.2(11) . . . . ?
C55 C56 C57 C58 176.3(13) . . . . ?
C56 C57 C58 C59 177.2(13) . . . . ?
C57 C58 C59 C60 178.9(14) . . . . ?
C58 C59 C60 C61 179.1(16) . . . . ?
C59 C60 C61 C62 179.1(19) . . . . ?
C4 C5 N1 N2 2.5(13) . . . . ?
C6 C5 N1 N2 178.6(9) . . . . ?
C4 C5 N1 Pt1 -176.4(7) . . . . ?
C6 C5 N1 Pt1 -0.2(13) . . . . ?
C5 N1 N2 C3 -2.2(12) . . . . ?
Pt1 N1 N2 C3 176.4(8) . . . . ?
C19 C3 N2 N1 -174.1(10) . . . . ?
C4 C3 N2 N1 1.0(13) . . . . ?
C7 C6 N3 C10 2.7(16) . . . . ?
C5 C6 N3 C10 -178.5(9) . . . . ?
C7 C6 N3 Pt1 176.8(8) . . . . ?
C5 C6 N3 Pt1 -4.4(11) . . . . ?
C9 C10 N3 C6 -2.2(15) . . . . ?
C9 C10 N3 Pt1 -175.7(7) . . . . ?
C12 C13 N4 N5 -1.3(12) . . . . ?
C14 C13 N4 N5 179.6(9) . . . . ?
C12 C13 N4 Pt1 177.9(7) . . . . ?
C14 C13 N4 Pt1 -1.2(12) . . . . ?
C13 N4 N5 C11 0.5(12) . . . . ?
Pt1 N4 N5 C11 -178.4(8) . . . . ?
C12 C11 N5 N4 0.5(13) . . . . ?
C41 C11 N5 N4 177.8(10) . . . . ?
C17 C18 N6 C14 1.6(17) . . . . ?
C17 C18 N6 Pt1 178.6(9) . . . . ?
C15 C14 N6 C18 -0.7(16) . . . . ?
C13 C14 N6 C18 -179.2(9) . . . . ?
C15 C14 N6 Pt1 -178.0(9) . . . . ?
C13 C14 N6 Pt1 3.5(11) . . . . ?
C22 C21 O1 C25 -176.4(10) . . . . ?
C20 C21 O1 C25 2.4(18) . . . . ?
C26 C25 O1 C21 175.1(10) . . . . ?
C24 C23 O2 C33 0.0(17) . . . . ?
C22 C23 O2 C33 178.5(10) . . . . ?
C34 C33 O2 C23 -179.0(10) . . . . ?
C42 C43 O3 C47 -1.8(16) . . . . ?
C44 C43 O3 C47 178.2(9) . . . . ?
C48 C47 O3 C43 -175.1(9) . . . . ?
C46 C45 O4 C55 25.2(17) . . . . ?
C44 C45 O4 C55 -158.0(11) . . . . ?
C56 C55 O4 C45 -99.4(14) . . . . ?
N5 N4 Pt1 N1 -8(24) . . . . ?
C13 N4 Pt1 N1 173(100) . . . . ?
N5 N4 Pt1 N6 -178.8(11) . . . . ?
C13 N4 Pt1 N6 2.3(7) . . . . ?
N5 N4 Pt1 N3 0.8(11) . . . . ?
C13 N4 Pt1 N3 -178.1(7) . . . . ?
N2 N1 Pt1 N4 -172(100) . . . . ?
C5 N1 Pt1 N4 7(24) . . . . ?
N2 N1 Pt1 N6 -0.7(10) . . . . ?
C5 N1 Pt1 N6 177.9(8) . . . . ?
N2 N1 Pt1 N3 179.8(10) . . . . ?
C5 N1 Pt1 N3 -1.7(8) . . . . ?
C18 N6 Pt1 N4 179.7(10) . . . . ?
C14 N6 Pt1 N4 -3.3(7) . . . . ?
C18 N6 Pt1 N1 -0.2(10) . . . . ?
C14 N6 Pt1 N1 176.8(7) . . . . ?
C18 N6 Pt1 N3 58(55) . . . . ?
C14 N6 Pt1 N3 -125(55) . . . . ?
C6 N3 Pt1 N4 -176.5(7) . . . . ?
C10 N3 Pt1 N4 -2.6(9) . . . . ?
C6 N3 Pt1 N1 3.4(7) . . . . ?
C10 N3 Pt1 N1 177.2(9) . . . . ?
C6 N3 Pt1 N6 -55(55) . . . . ?
C10 N3 Pt1 N6 119(55) . . . . ?

_diffrn_measured_fraction_theta_max 0.974
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.974
_refine_diff_density_max         0.953
_refine_diff_density_min         -1.517
_refine_diff_density_rms         0.115



#=======================================================================END   
_database_code_depnum_ccdc_archive 'CCDC 1008267'
