# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_q1
_database_code_depnum_ccdc_archive 'CCDC 966676'
_audit_update_record             
;
2013-10-16 deposited with the CCDC.
2015-01-21 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C34 H28 F6 N2 O4 Pt2'
_chemical_formula_weight         1032.76

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   'P-1   '

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.618(3)
_cell_length_b                   12.524(3)
_cell_length_c                   12.655(3)
_cell_angle_alpha                89.994(13)
_cell_angle_beta                 83.387(15)
_cell_angle_gamma                66.227(13)
_cell_volume                     1671.7(7)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    5097
_cell_measurement_theta_min      2.35
_cell_measurement_theta_max      28.24

_exptl_crystal_description       cuboid
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.052
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             976
_exptl_absorpt_coefficient_mu    8.433
_exptl_absorpt_correction_type   'multi scan'
_exptl_absorpt_correction_T_min  0.3570
_exptl_absorpt_correction_T_max  0.7464
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            19264
_diffrn_reflns_av_R_equivalents  0.0456
_diffrn_reflns_av_sigmaI/netI    0.0874
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         2.35
_diffrn_reflns_theta_max         32.33
_reflns_number_total             11471
_reflns_number_gt                6464
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'


_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0511P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         11471
_refine_ls_number_parameters     433
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0985
_refine_ls_R_factor_gt           0.0489
_refine_ls_wR_factor_ref         0.1269
_refine_ls_wR_factor_gt          0.1077
_refine_ls_goodness_of_fit_ref   0.925
_refine_ls_restrained_S_all      0.925
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.51010(3) 0.919182(19) 0.128727(18) 0.05022(9) Uani 1 1 d . . .
Pt2 Pt 0.55340(3) 0.567513(18) 0.618066(18) 0.05656(10) Uani 1 1 d . . .
C30 C 0.5863(12) 0.4178(7) 0.8344(7) 0.085(3) Uani 1 1 d . . .
H30A H 0.5975 0.3743 0.8948 0.101 Uiso 1 1 calc R . .
C32 C 0.3541(12) 0.4720(9) 0.8895(7) 0.101(3) Uani 1 1 d . . .
H32A H 0.2749 0.5192 0.8648 0.151 Uiso 1 1 calc R . .
H32B H 0.3555 0.4999 0.9598 0.151 Uiso 1 1 calc R . .
H32C H 0.3635 0.3923 0.8913 0.151 Uiso 1 1 calc R . .
C6 C 0.4206(8) 0.8274(6) -0.0326(6) 0.064(2) Uani 1 1 d . . .
N1 N 0.6212(6) 0.8156(4) 0.0030(4) 0.0499(13) Uani 1 1 d . . .
N2 N 0.4156(7) 0.6717(4) 0.5379(4) 0.0565(15) Uani 1 1 d . . .
O4 O 0.7046(5) 0.4644(4) 0.6869(3) 0.0704(14) Uani 1 1 d . . .
O2 O 0.3874(5) 1.0198(4) 0.2496(4) 0.0632(12) Uani 1 1 d . . .
C4 C 0.6275(11) 0.7127(7) -0.1563(6) 0.073(2) Uani 1 1 d . . .
H4A H 0.5864 0.6913 -0.2059 0.088 Uiso 1 1 calc R . .
C24 C 0.6628(7) 0.6000(5) 0.5007(5) 0.0550(16) Uani 1 1 d . . .
O1 O 0.6651(5) 0.9321(4) 0.1880(3) 0.0588(11) Uani 1 1 d . . .
C7 C 0.3759(7) 0.8969(5) 0.0630(5) 0.0561(17) Uani 1 1 d . . .
O3 O 0.4251(5) 0.5434(4) 0.7371(3) 0.0676(13) Uani 1 1 d . . .
C22 C 0.4560(7) 0.7144(5) 0.4471(5) 0.0515(15) Uani 1 1 d . . .
C18 C 0.2916(8) 0.6995(5) 0.5661(5) 0.0621(19) Uani 1 1 d . . .
H18A H 0.2654 0.6691 0.6267 0.075 Uiso 1 1 calc R . .
C23 C 0.5928(8) 0.6742(5) 0.4263(5) 0.0582(18) Uani 1 1 d . . .
C21 C 0.3639(9) 0.7891(6) 0.3874(6) 0.066(2) Uani 1 1 d . . .
H21A H 0.3896 0.8187 0.3261 0.079 Uiso 1 1 calc R . .
C33 C 0.8262(11) 0.3430(8) 0.8091(8) 0.108(4) Uani 1 1 d . . .
H33A H 0.8903 0.3497 0.7578 0.162 Uiso 1 1 calc R . .
H33B H 0.8396 0.2624 0.8131 0.162 Uiso 1 1 calc R . .
H33C H 0.8308 0.3728 0.8776 0.162 Uiso 1 1 calc R . .
C28 C 0.6569(10) 0.7055(7) 0.3393(6) 0.070(2) Uani 1 1 d . . .
H28A H 0.6109 0.7543 0.2898 0.084 Uiso 1 1 calc R . .
C25 C 0.7924(9) 0.5582(6) 0.4843(6) 0.079(2) Uani 1 1 d . . .
H25A H 0.8397 0.5079 0.5323 0.095 Uiso 1 1 calc R . .
C1 C 0.7449(8) 0.7802(6) -0.0136(5) 0.0623(18) Uani 1 1 d . . .
H1A H 0.7851 0.8037 0.0353 0.075 Uiso 1 1 calc R . .
C19 C 0.2022(8) 0.7729(6) 0.5059(6) 0.0656(19) Uani 1 1 d . . .
C5 C 0.5555(8) 0.7840(5) -0.0655(5) 0.0591(18) Uani 1 1 d . . .
C2 C 0.8172(10) 0.7094(6) -0.1007(6) 0.077(2) Uani 1 1 d . . .
C29 C 0.4621(11) 0.4793(6) 0.8147(5) 0.080(3) Uani 1 1 d . . .
C31 C 0.6942(11) 0.4140(6) 0.7748(7) 0.081(3) Uani 1 1 d . . .
C8 C 0.2465(9) 0.9409(7) 0.0975(7) 0.076(2) Uani 1 1 d . . .
H8A H 0.2136 0.9879 0.1599 0.092 Uiso 1 1 calc R . .
C11 C 0.3377(12) 0.8015(8) -0.0910(7) 0.088(3) Uani 1 1 d . . .
H11A H 0.3678 0.7551 -0.1539 0.105 Uiso 1 1 calc R . .
C13 C 0.5401(10) 1.0513(7) 0.3393(6) 0.072(2) Uani 1 1 d . . .
H13A H 0.5479 1.0890 0.3997 0.087 Uiso 1 1 calc R . .
C12 C 0.4205(8) 1.0638(6) 0.3284(5) 0.0635(19) Uani 1 1 d . . .
C14 C 0.6536(8) 0.9898(6) 0.2728(5) 0.0638(19) Uani 1 1 d . . .
C20 C 0.2396(10) 0.8189(7) 0.4166(6) 0.072(2) Uani 1 1 d . . .
H20A H 0.1798 0.8698 0.3769 0.086 Uiso 1 1 calc R . .
C26 C 0.8542(10) 0.5895(7) 0.3978(7) 0.088(3) Uani 1 1 d . . .
H26A H 0.9423 0.5596 0.3875 0.105 Uiso 1 1 calc R . .
F4 F 0.0394(7) 0.7238(6) 0.5883(8) 0.171(3) Uani 1 1 d . . .
C16 C 0.7807(9) 0.9858(8) 0.3025(7) 0.087(3) Uani 1 1 d . . .
H16A H 0.8484 0.9401 0.2488 0.131 Uiso 1 1 calc R . .
H16B H 0.7960 0.9510 0.3699 0.131 Uiso 1 1 calc R . .
H16C H 0.7767 1.0637 0.3073 0.131 Uiso 1 1 calc R . .
C15 C 0.3116(10) 1.1319(8) 0.4074(7) 0.088(3) Uani 1 1 d . . .
H15A H 0.2357 1.1303 0.3857 0.131 Uiso 1 1 calc R . .
H15B H 0.3034 1.2112 0.4123 0.131 Uiso 1 1 calc R . .
H15C H 0.3247 1.0985 0.4756 0.131 Uiso 1 1 calc R . .
C34 C 0.0673(10) 0.8026(8) 0.5425(9) 0.093(3) Uani 1 1 d . . .
C3 C 0.7532(13) 0.6755(7) -0.1723(7) 0.090(3) Uani 1 1 d . . .
H3A H 0.7989 0.6266 -0.2316 0.108 Uiso 1 1 calc R . .
C10 C 0.2094(11) 0.8476(9) -0.0515(9) 0.095(3) Uani 1 1 d . . .
H10A H 0.1528 0.8315 -0.0882 0.114 Uiso 1 1 calc R . .
C9 C 0.1666(10) 0.9149(9) 0.0392(9) 0.096(3) Uani 1 1 d . . .
H9A H 0.0804 0.9450 0.0635 0.115 Uiso 1 1 calc R . .
C27 C 0.7845(11) 0.6656(8) 0.3267(7) 0.085(3) Uani 1 1 d . . .
H27A H 0.8257 0.6892 0.2701 0.102 Uiso 1 1 calc R . .
F1 F 1.0056(7) 0.6719(11) -0.0280(8) 0.207(5) Uani 1 1 d . . .
F3 F 1.0171(9) 0.5731(12) -0.1571(14) 0.294(9) Uani 1 1 d . . .
C17 C 0.9586(13) 0.6680(15) -0.1105(11) 0.127(4) Uani 1 1 d . . .
F2 F 0.9959(11) 0.7346(14) -0.1709(11) 0.247(7) Uani 1 1 d . . .
F6 F -0.0051(8) 0.8269(14) 0.4669(7) 0.243(7) Uani 1 1 d . . .
F5 F 0.0119(8) 0.8915(8) 0.6048(11) 0.221(6) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C7 1.963(7) . ?
Pt1 O2 2.003(5) . ?
Pt1 N1 2.015(5) . ?
Pt1 O1 2.092(4) . ?
Pt2 C24 1.992(7) . ?
Pt2 N2 1.996(5) . ?
Pt2 O4 2.009(5) . ?
Pt2 O3 2.105(5) . ?
C30 C31 1.369(14) . ?
C30 C29 1.387(14) . ?
C30 H30A 0.9300 . ?
C32 C29 1.516(14) . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C6 C7 1.408(10) . ?
C6 C11 1.412(11) . ?
C6 C5 1.446(11) . ?
N1 C1 1.312(9) . ?
N1 C5 1.374(8) . ?
N2 C18 1.343(9) . ?
N2 C22 1.380(8) . ?
O4 C31 1.296(9) . ?
O2 C12 1.306(8) . ?
C4 C3 1.332(14) . ?
C4 C5 1.412(11) . ?
C4 H4A 0.9300 . ?
C24 C25 1.370(11) . ?
C24 C23 1.407(9) . ?
O1 C14 1.257(7) . ?
C7 C8 1.391(11) . ?
O3 C29 1.269(8) . ?
C22 C21 1.403(10) . ?
C22 C23 1.452(10) . ?
C18 C19 1.384(10) . ?
C18 H18A 0.9300 . ?
C23 C28 1.402(11) . ?
C21 C20 1.343(12) . ?
C21 H21A 0.9300 . ?
C33 C31 1.544(14) . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
C28 C27 1.350(13) . ?
C28 H28A 0.9300 . ?
C25 C26 1.383(12) . ?
C25 H25A 0.9300 . ?
C1 C2 1.376(10) . ?
C1 H1A 0.9300 . ?
C19 C20 1.374(11) . ?
C19 C34 1.473(13) . ?
C2 C3 1.402(13) . ?
C2 C17 1.499(16) . ?
C8 C9 1.384(12) . ?
C8 H8A 0.9300 . ?
C11 C10 1.393(15) . ?
C11 H11A 0.9300 . ?
C13 C12 1.357(12) . ?
C13 C14 1.402(12) . ?
C13 H13A 0.9300 . ?
C12 C15 1.472(12) . ?
C14 C16 1.547(11) . ?
C20 H20A 0.9300 . ?
C26 C27 1.386(12) . ?
C26 H26A 0.9300 . ?
F4 C34 1.276(10) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C34 F5 1.257(12) . ?
C34 F6 1.302(11) . ?
C3 H3A 0.9300 . ?
C10 C9 1.343(14) . ?
C10 H10A 0.9300 . ?
C9 H9A 0.9300 . ?
C27 H27A 0.9300 . ?
F1 C17 1.242(14) . ?
F3 C17 1.217(14) . ?
C17 F2 1.298(17) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C7 Pt1 O2 92.5(3) . . ?
C7 Pt1 N1 82.7(3) . . ?
O2 Pt1 N1 175.1(2) . . ?
C7 Pt1 O1 174.8(3) . . ?
O2 Pt1 O1 92.72(19) . . ?
N1 Pt1 O1 92.1(2) . . ?
C24 Pt2 N2 82.3(3) . . ?
C24 Pt2 O4 91.9(2) . . ?
N2 Pt2 O4 174.2(2) . . ?
C24 Pt2 O3 175.4(2) . . ?
N2 Pt2 O3 93.1(2) . . ?
O4 Pt2 O3 92.7(2) . . ?
C31 C30 C29 127.4(7) . . ?
C31 C30 H30A 116.3 . . ?
C29 C30 H30A 116.3 . . ?
C29 C32 H32A 109.5 . . ?
C29 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C29 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C7 C6 C11 121.4(9) . . ?
C7 C6 C5 115.8(6) . . ?
C11 C6 C5 122.8(8) . . ?
C1 N1 C5 122.0(6) . . ?
C1 N1 Pt1 124.2(4) . . ?
C5 N1 Pt1 113.7(5) . . ?
C18 N2 C22 120.3(6) . . ?
C18 N2 Pt2 124.5(4) . . ?
C22 N2 Pt2 115.2(5) . . ?
C31 O4 Pt2 122.6(6) . . ?
C12 O2 Pt1 123.8(5) . . ?
C3 C4 C5 121.2(8) . . ?
C3 C4 H4A 119.4 . . ?
C5 C4 H4A 119.4 . . ?
C25 C24 C23 118.6(7) . . ?
C25 C24 Pt2 128.6(5) . . ?
C23 C24 Pt2 112.8(6) . . ?
C14 O1 Pt1 122.4(5) . . ?
C8 C7 C6 117.7(7) . . ?
C8 C7 Pt1 128.9(5) . . ?
C6 C7 Pt1 113.4(6) . . ?
C29 O3 Pt2 122.0(6) . . ?
N2 C22 C21 118.2(7) . . ?
N2 C22 C23 113.6(5) . . ?
C21 C22 C23 128.3(6) . . ?
N2 C18 C19 120.7(7) . . ?
N2 C18 H18A 119.6 . . ?
C19 C18 H18A 119.6 . . ?
C28 C23 C24 119.4(8) . . ?
C28 C23 C22 124.4(7) . . ?
C24 C23 C22 116.2(6) . . ?
C20 C21 C22 121.7(7) . . ?
C20 C21 H21A 119.2 . . ?
C22 C21 H21A 119.2 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C27 C28 C23 120.7(8) . . ?
C27 C28 H28A 119.6 . . ?
C23 C28 H28A 119.6 . . ?
C24 C25 C26 121.2(8) . . ?
C24 C25 H25A 119.4 . . ?
C26 C25 H25A 119.4 . . ?
N1 C1 C2 122.4(7) . . ?
N1 C1 H1A 118.8 . . ?
C2 C1 H1A 118.8 . . ?
C20 C19 C18 120.2(8) . . ?
C20 C19 C34 121.6(8) . . ?
C18 C19 C34 118.2(7) . . ?
N1 C5 C4 116.7(8) . . ?
N1 C5 C6 114.5(6) . . ?
C4 C5 C6 128.8(7) . . ?
C1 C2 C3 117.1(9) . . ?
C1 C2 C17 118.8(8) . . ?
C3 C2 C17 124.0(9) . . ?
O3 C29 C30 126.9(9) . . ?
O3 C29 C32 113.2(9) . . ?
C30 C29 C32 119.9(8) . . ?
O4 C31 C30 128.4(8) . . ?
O4 C31 C33 110.5(9) . . ?
C30 C31 C33 121.0(7) . . ?
C9 C8 C7 120.1(9) . . ?
C9 C8 H8A 120.0 . . ?
C7 C8 H8A 120.0 . . ?
C10 C11 C6 117.9(9) . . ?
C10 C11 H11A 121.1 . . ?
C6 C11 H11A 121.1 . . ?
C12 C13 C14 129.4(7) . . ?
C12 C13 H13A 115.3 . . ?
C14 C13 H13A 115.3 . . ?
O2 C12 C13 125.8(7) . . ?
O2 C12 C15 112.3(8) . . ?
C13 C12 C15 121.9(7) . . ?
O1 C14 C13 125.9(7) . . ?
O1 C14 C16 113.6(7) . . ?
C13 C14 C16 120.4(7) . . ?
C21 C20 C19 119.0(7) . . ?
C21 C20 H20A 120.5 . . ?
C19 C20 H20A 120.5 . . ?
C25 C26 C27 119.8(10) . . ?
C25 C26 H26A 120.1 . . ?
C27 C26 H26A 120.1 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C12 C15 H15A 109.5 . . ?
C12 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C12 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
F5 C34 F4 104.3(10) . . ?
F5 C34 F6 101.8(11) . . ?
F4 C34 F6 100.7(11) . . ?
F5 C34 C19 116.0(9) . . ?
F4 C34 C19 117.3(8) . . ?
F6 C34 C19 114.6(9) . . ?
C4 C3 C2 120.6(8) . . ?
C4 C3 H3A 119.7 . . ?
C2 C3 H3A 119.7 . . ?
C9 C10 C11 120.7(9) . . ?
C9 C10 H10A 119.7 . . ?
C11 C10 H10A 119.7 . . ?
C10 C9 C8 122.2(10) . . ?
C10 C9 H9A 118.9 . . ?
C8 C9 H9A 118.9 . . ?
C28 C27 C26 120.1(9) . . ?
C28 C27 H27A 119.9 . . ?
C26 C27 H27A 119.9 . . ?
F3 C17 F1 109.6(17) . . ?
F3 C17 F2 101.5(12) . . ?
F1 C17 F2 101.6(15) . . ?
F3 C17 C2 114.5(12) . . ?
F1 C17 C2 117.2(9) . . ?
F2 C17 C2 110.6(14) . . ?

_diffrn_measured_fraction_theta_max 0.961
_diffrn_reflns_theta_full        32.33
_diffrn_measured_fraction_theta_full 0.961
_refine_diff_density_max         2.195
_refine_diff_density_min         -1.433
_refine_diff_density_rms         0.173
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_q11
_database_code_depnum_ccdc_archive 'CCDC 966677'
_audit_update_record             
;
2013-10-16 deposited with the CCDC.
2015-01-21 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C36 H32 F6 N2 O6 Pt2'
_chemical_formula_weight         1092.82

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P2(1)/c  '

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   23.2937(10)
_cell_length_b                   11.9955(5)
_cell_length_c                   13.1606(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 100.226(2)
_cell_angle_gamma                90.00
_cell_volume                     3618.9(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    6900
_cell_measurement_theta_min      2.38
_cell_measurement_theta_max      25.88

_exptl_crystal_description       hexahedron
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_exptl_crystal_density_meas      0
_exptl_crystal_density_diffrn    2.006
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2080
_exptl_absorpt_coefficient_mu    7.801
_exptl_absorpt_correction_type   'multi scan'
_exptl_absorpt_correction_T_min  0.3414
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            23169
_diffrn_reflns_av_R_equivalents  0.0359
_diffrn_reflns_av_sigmaI/netI    0.0359
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         1.78
_diffrn_reflns_theta_max         25.00
_reflns_number_total             6369
_reflns_number_gt                5247
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6369
_refine_ls_number_parameters     469
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0416
_refine_ls_R_factor_gt           0.0299
_refine_ls_wR_factor_ref         0.0998
_refine_ls_wR_factor_gt          0.0916
_refine_ls_goodness_of_fit_ref   0.745
_refine_ls_restrained_S_all      0.745
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.508487(10) 0.084285(19) -0.635946(15) 0.04528(10) Uani 1 1 d . . .
Pt2 Pt 0.019499(12) 1.11907(2) -0.077522(16) 0.05122(11) Uani 1 1 d . . .
O1 O 0.43110(18) 0.0294(4) -0.7266(3) 0.0573(11) Uani 1 1 d . . .
O2 O 0.55585(18) 0.0251(4) -0.7369(3) 0.0551(11) Uani 1 1 d . . .
N1 N 0.4677(2) 0.1458(4) -0.5275(4) 0.0491(12) Uani 1 1 d . . .
C6 C 0.5775(3) 0.1437(5) -0.5416(4) 0.0481(14) Uani 1 1 d . . .
C1 C 0.4289(3) -0.0258(5) -0.8086(5) 0.0579(16) Uani 1 1 d . . .
C8 C 0.5033(3) 0.1954(5) -0.4453(4) 0.0504(15) Uani 1 1 d . . .
C7 C 0.5636(3) 0.1941(5) -0.4529(4) 0.0544(16) Uani 1 1 d . . .
C2 C 0.4769(3) -0.0566(6) -0.8531(5) 0.0651(18) Uani 1 1 d . . .
H2A H 0.4690 -0.0996 -0.9127 0.078 Uiso 1 1 calc R . .
C9 C 0.4780(4) 0.2406(6) -0.3665(4) 0.0609(18) Uani 1 1 d . . .
H9A H 0.5015 0.2742 -0.3104 0.073 Uiso 1 1 calc R . .
C12 C 0.4106(3) 0.1403(5) -0.5304(5) 0.0553(16) Uani 1 1 d . . .
H12A H 0.3874 0.1046 -0.5857 0.066 Uiso 1 1 calc R . .
C14 C 0.6090(3) 0.2398(6) -0.3796(5) 0.0661(19) Uani 1 1 d . . .
H14A H 0.6003 0.2731 -0.3204 0.079 Uiso 1 1 calc R . .
C10 C 0.4190(4) 0.2362(6) -0.3705(5) 0.0677(19) Uani 1 1 d . . .
H10A H 0.4023 0.2668 -0.3178 0.081 Uiso 1 1 calc R . .
C17 C 0.6348(3) 0.1399(6) -0.5558(5) 0.0580(16) Uani 1 1 d . . .
H17A H 0.6441 0.1054 -0.6141 0.070 Uiso 1 1 calc R . .
C11 C 0.3847(3) 0.1853(6) -0.4544(5) 0.0647(18) Uani 1 1 d . . .
C16 C 0.6784(3) 0.1872(6) -0.4835(6) 0.0687(19) Uani 1 1 d . . .
C5 C 0.5808(3) -0.0681(7) -0.8779(6) 0.075(2) Uani 1 1 d . . .
H5A H 0.6186 -0.0430 -0.8441 0.112 Uiso 1 1 calc R . .
H5B H 0.5724 -0.0376 -0.9464 0.112 Uiso 1 1 calc R . .
H5C H 0.5806 -0.1480 -0.8816 0.112 Uiso 1 1 calc R . .
F1 F 0.2930(3) 0.1167(8) -0.5313(7) 0.169(4) Uani 1 1 d . . .
O3 O 0.7356(3) 0.1918(6) -0.4915(5) 0.105(2) Uani 1 1 d . . .
C3 C 0.5353(3) -0.0298(6) -0.8177(5) 0.0581(17) Uani 1 1 d . . .
C15 C 0.6650(3) 0.2359(7) -0.3941(5) 0.075(2) Uani 1 1 d . . .
H15A H 0.6945 0.2657 -0.3447 0.090 Uiso 1 1 calc R . .
F3 F 0.2963(3) 0.2773(6) -0.4764(9) 0.189(4) Uani 1 1 d . . .
C13 C 0.3208(4) 0.1823(8) -0.4622(7) 0.083(2) Uani 1 1 d . . .
C4 C 0.3685(3) -0.0565(7) -0.8621(6) 0.077(2) Uani 1 1 d . . .
H4A H 0.3405 -0.0301 -0.8224 0.116 Uiso 1 1 calc R . .
H4B H 0.3656 -0.1361 -0.8688 0.116 Uiso 1 1 calc R . .
H4C H 0.3610 -0.0230 -0.9294 0.116 Uiso 1 1 calc R . .
F2 F 0.3048(3) 0.1440(9) -0.3754(7) 0.184(4) Uani 1 1 d . . .
C18 C 0.7515(5) 0.1534(11) -0.5767(11) 0.126(4) Uani 1 1 d . . .
H18A H 0.7930 0.1615 -0.5715 0.189 Uiso 1 1 calc R . .
H18B H 0.7319 0.1948 -0.6351 0.189 Uiso 1 1 calc R . .
H18C H 0.7412 0.0761 -0.5853 0.189 Uiso 1 1 calc R . .
O6 O -0.0381(2) 1.2190(4) -0.0142(3) 0.0646(12) Uani 1 1 d . . .
O5 O 0.0885(2) 1.2094(4) -0.0126(3) 0.0665(12) Uani 1 1 d . . .
N2 N -0.0449(2) 1.0222(4) -0.1506(4) 0.0531(13) Uani 1 1 d . . .
O4 O 0.2115(3) 0.9421(6) -0.2015(6) 0.106(2) Uani 1 1 d . . .
C31 C -0.0269(3) 0.9380(5) -0.2073(5) 0.0574(17) Uani 1 1 d . . .
C24 C 0.0669(3) 1.0179(5) -0.1466(4) 0.0519(15) Uani 1 1 d . . .
C35 C -0.1012(3) 1.0363(6) -0.1457(5) 0.0607(17) Uani 1 1 d . . .
H35A H -0.1120 1.0938 -0.1055 0.073 Uiso 1 1 calc R . .
C32 C -0.0701(4) 0.8669(6) -0.2622(5) 0.0667(19) Uani 1 1 d . . .
H32A H -0.0589 0.8091 -0.3016 0.080 Uiso 1 1 calc R . .
C21 C -0.0223(4) 1.3052(6) 0.0391(5) 0.068(2) Uani 1 1 d . . .
C29 C 0.0354(3) 0.9343(5) -0.2057(5) 0.0560(16) Uani 1 1 d . . .
C25 C 0.1271(3) 1.0218(6) -0.1427(5) 0.0632(17) Uani 1 1 d . . .
H25A H 0.1495 1.0758 -0.1032 0.076 Uiso 1 1 calc R . .
C27 C 0.1207(4) 0.8625(6) -0.2568(6) 0.076(2) Uani 1 1 d . . .
H27A H 0.1387 0.8116 -0.2944 0.091 Uiso 1 1 calc R . .
C33 C -0.1269(4) 0.8814(7) -0.2585(6) 0.077(2) Uani 1 1 d . . .
H33A H -0.1548 0.8343 -0.2954 0.092 Uiso 1 1 calc R . .
C28 C 0.0630(4) 0.8578(6) -0.2584(6) 0.070(2) Uani 1 1 d . . .
H28A H 0.0412 0.8016 -0.2958 0.084 Uiso 1 1 calc R . .
C20 C 0.0358(4) 1.3454(6) 0.0648(6) 0.078(2) Uani 1 1 d . . .
H20A H 0.0408 1.4113 0.1025 0.093 Uiso 1 1 calc R . .
C19 C 0.0850(4) 1.2994(6) 0.0411(5) 0.074(2) Uani 1 1 d . . .
C34 C -0.1438(3) 0.9679(7) -0.1987(6) 0.0707(19) Uani 1 1 d . . .
C26 C 0.1532(3) 0.9448(7) -0.1982(6) 0.073(2) Uani 1 1 d . . .
C23 C -0.0716(4) 1.3692(8) 0.0735(7) 0.098(3) Uani 1 1 d . . .
H23A H -0.1077 1.3308 0.0508 0.146 Uiso 1 1 calc R . .
H23B H -0.0738 1.4426 0.0440 0.146 Uiso 1 1 calc R . .
H23C H -0.0644 1.3747 0.1474 0.146 Uiso 1 1 calc R . .
C22 C 0.1437(4) 1.3535(7) 0.0752(7) 0.102(3) Uani 1 1 d . . .
H22A H 0.1733 1.3096 0.0519 0.153 Uiso 1 1 calc R . .
H22B H 0.1518 1.3583 0.1492 0.153 Uiso 1 1 calc R . .
H22C H 0.1433 1.4270 0.0463 0.153 Uiso 1 1 calc R . .
F5 F -0.2356(4) 1.0199(15) -0.2758(8) 0.265(7) Uani 1 1 d . . .
C36 C -0.2044(5) 0.9910(11) -0.1976(9) 0.103(3) Uani 1 1 d . . .
F6 F -0.2146(3) 1.0619(12) -0.1358(12) 0.264(8) Uani 1 1 d . . .
F4 F -0.2304(4) 0.9123(8) -0.1623(15) 0.284(9) Uani 1 1 d . . .
C30 C 0.2481(4) 1.0216(11) -0.1416(10) 0.133(5) Uani 1 1 d . . .
H30A H 0.2877 1.0104 -0.1505 0.199 Uiso 1 1 calc R . .
H30B H 0.2456 1.0126 -0.0700 0.199 Uiso 1 1 calc R . .
H30C H 0.2358 1.0954 -0.1637 0.199 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C6 1.981(6) . ?
Pt1 N1 1.992(5) . ?
Pt1 O2 2.002(4) . ?
Pt1 O1 2.084(4) . ?
Pt2 C24 1.968(6) . ?
Pt2 N2 2.004(5) . ?
Pt2 O5 2.001(5) . ?
Pt2 O6 2.081(4) . ?
O1 C1 1.259(7) . ?
O2 C3 1.270(7) . ?
N1 C12 1.325(8) . ?
N1 C8 1.376(8) . ?
C6 C17 1.380(9) . ?
C6 C7 1.403(8) . ?
C1 C2 1.401(10) . ?
C1 C4 1.503(10) . ?
C8 C9 1.390(8) . ?
C8 C7 1.425(9) . ?
C7 C14 1.410(9) . ?
C2 C3 1.395(10) . ?
C2 H2A 0.9300 . ?
C9 C10 1.367(10) . ?
C9 H9A 0.9300 . ?
C12 C11 1.367(9) . ?
C12 H12A 0.9300 . ?
C14 C15 1.352(10) . ?
C14 H14A 0.9300 . ?
C10 C11 1.385(10) . ?
C10 H10A 0.9300 . ?
C17 C16 1.385(10) . ?
C17 H17A 0.9300 . ?
C11 C13 1.474(11) . ?
C16 O3 1.355(9) . ?
C16 C15 1.398(10) . ?
C5 C3 1.503(9) . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
F1 C13 1.286(11) . ?
O3 C18 1.325(13) . ?
C15 H15A 0.9300 . ?
F3 C13 1.273(10) . ?
C13 F2 1.344(11) . ?
C4 H4A 0.9600 . ?
C4 H4B 0.9600 . ?
C4 H4C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
O6 C21 1.267(8) . ?
O5 C19 1.300(8) . ?
N2 C35 1.335(8) . ?
N2 C31 1.366(8) . ?
O4 C26 1.366(9) . ?
O4 C30 1.421(12) . ?
C31 C32 1.415(10) . ?
C31 C29 1.449(10) . ?
C24 C25 1.396(9) . ?
C24 C29 1.395(9) . ?
C35 C34 1.377(10) . ?
C35 H35A 0.9300 . ?
C32 C33 1.344(11) . ?
C32 H32A 0.9300 . ?
C21 C20 1.419(11) . ?
C21 C23 1.516(10) . ?
C29 C28 1.376(9) . ?
C25 C26 1.383(10) . ?
C25 H25A 0.9300 . ?
C27 C28 1.342(11) . ?
C27 C26 1.392(11) . ?
C27 H27A 0.9300 . ?
C33 C34 1.401(11) . ?
C33 H33A 0.9300 . ?
C28 H28A 0.9300 . ?
C20 C19 1.356(11) . ?
C20 H20A 0.9300 . ?
C19 C22 1.509(11) . ?
C34 C36 1.443(12) . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
F5 C36 1.201(13) . ?
C36 F6 1.229(14) . ?
C36 F4 1.255(13) . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 Pt1 N1 81.7(2) . . ?
C6 Pt1 O2 93.6(2) . . ?
N1 Pt1 O2 175.18(19) . . ?
C6 Pt1 O1 174.6(2) . . ?
N1 Pt1 O1 93.02(19) . . ?
O2 Pt1 O1 91.75(17) . . ?
C24 Pt2 N2 81.6(3) . . ?
C24 Pt2 O5 93.3(2) . . ?
N2 Pt2 O5 174.8(2) . . ?
C24 Pt2 O6 174.1(2) . . ?
N2 Pt2 O6 92.6(2) . . ?
O5 Pt2 O6 92.46(19) . . ?
C1 O1 Pt1 123.8(4) . . ?
C3 O2 Pt1 124.7(4) . . ?
C12 N1 C8 120.4(6) . . ?
C12 N1 Pt1 124.4(4) . . ?
C8 N1 Pt1 115.2(4) . . ?
C17 C6 C7 119.9(6) . . ?
C17 C6 Pt1 126.8(5) . . ?
C7 C6 Pt1 113.3(5) . . ?
O1 C1 C2 125.7(6) . . ?
O1 C1 C4 115.0(6) . . ?
C2 C1 C4 119.3(6) . . ?
N1 C8 C9 118.6(6) . . ?
N1 C8 C7 113.9(5) . . ?
C9 C8 C7 127.6(6) . . ?
C6 C7 C14 118.7(7) . . ?
C6 C7 C8 116.0(6) . . ?
C14 C7 C8 125.2(6) . . ?
C1 C2 C3 127.1(6) . . ?
C1 C2 H2A 116.4 . . ?
C3 C2 H2A 116.4 . . ?
C10 C9 C8 120.8(6) . . ?
C10 C9 H9A 119.6 . . ?
C8 C9 H9A 119.6 . . ?
N1 C12 C11 122.0(7) . . ?
N1 C12 H12A 119.0 . . ?
C11 C12 H12A 119.0 . . ?
C15 C14 C7 121.1(7) . . ?
C15 C14 H14A 119.5 . . ?
C7 C14 H14A 119.5 . . ?
C9 C10 C11 118.9(6) . . ?
C9 C10 H10A 120.6 . . ?
C11 C10 H10A 120.6 . . ?
C6 C17 C16 120.2(7) . . ?
C6 C17 H17A 119.9 . . ?
C16 C17 H17A 119.9 . . ?
C12 C11 C10 119.3(7) . . ?
C12 C11 C13 120.7(7) . . ?
C10 C11 C13 120.0(7) . . ?
O3 C16 C15 114.7(7) . . ?
O3 C16 C17 125.1(7) . . ?
C15 C16 C17 120.2(7) . . ?
C3 C5 H5A 109.5 . . ?
C3 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C3 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C18 O3 C16 118.6(8) . . ?
O2 C3 C2 126.8(6) . . ?
O2 C3 C5 113.8(6) . . ?
C2 C3 C5 119.4(6) . . ?
C14 C15 C16 119.9(7) . . ?
C14 C15 H15A 120.0 . . ?
C16 C15 H15A 120.0 . . ?
F1 C13 F3 106.8(9) . . ?
F1 C13 F2 102.3(9) . . ?
F3 C13 F2 104.3(8) . . ?
F1 C13 C11 116.0(7) . . ?
F3 C13 C11 114.0(8) . . ?
F2 C13 C11 112.2(8) . . ?
C1 C4 H4A 109.5 . . ?
C1 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C1 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
O3 C18 H18A 109.5 . . ?
O3 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
O3 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C21 O6 Pt2 123.1(5) . . ?
C19 O5 Pt2 123.9(5) . . ?
C35 N2 C31 121.3(6) . . ?
C35 N2 Pt2 124.2(5) . . ?
C31 N2 Pt2 114.5(5) . . ?
C26 O4 C30 118.0(7) . . ?
N2 C31 C32 117.7(7) . . ?
N2 C31 C29 114.8(6) . . ?
C32 C31 C29 127.4(6) . . ?
C25 C24 C29 118.0(6) . . ?
C25 C24 Pt2 127.2(5) . . ?
C29 C24 Pt2 114.8(5) . . ?
N2 C35 C34 121.6(7) . . ?
N2 C35 H35A 119.2 . . ?
C34 C35 H35A 119.2 . . ?
C31 C32 C33 121.2(7) . . ?
C31 C32 H32A 119.4 . . ?
C33 C32 H32A 119.4 . . ?
O6 C21 C20 125.5(7) . . ?
O6 C21 C23 114.6(8) . . ?
C20 C21 C23 119.8(7) . . ?
C28 C29 C24 121.0(7) . . ?
C28 C29 C31 124.7(7) . . ?
C24 C29 C31 114.3(6) . . ?
C26 C25 C24 119.4(7) . . ?
C26 C25 H25A 120.3 . . ?
C24 C25 H25A 120.3 . . ?
C28 C27 C26 118.9(7) . . ?
C28 C27 H27A 120.5 . . ?
C26 C27 H27A 120.5 . . ?
C34 C33 C32 119.5(7) . . ?
C34 C33 H33A 120.2 . . ?
C32 C33 H33A 120.2 . . ?
C27 C28 C29 121.3(7) . . ?
C27 C28 H28A 119.3 . . ?
C29 C28 H28A 119.3 . . ?
C21 C20 C19 127.9(7) . . ?
C21 C20 H20A 116.0 . . ?
C19 C20 H20A 116.0 . . ?
O5 C19 C20 126.9(8) . . ?
O5 C19 C22 112.1(7) . . ?
C20 C19 C22 121.0(7) . . ?
C35 C34 C33 118.5(7) . . ?
C35 C34 C36 119.9(8) . . ?
C33 C34 C36 121.4(8) . . ?
O4 C26 C25 124.4(8) . . ?
O4 C26 C27 114.3(7) . . ?
C25 C26 C27 121.3(7) . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C19 C22 H22A 109.5 . . ?
C19 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C19 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
F5 C36 F6 102.1(14) . . ?
F5 C36 F4 106.1(13) . . ?
F6 C36 F4 96.5(12) . . ?
F5 C36 C34 119.4(10) . . ?
F6 C36 C34 116.4(10) . . ?
F4 C36 C34 113.4(11) . . ?
O4 C30 H30A 109.5 . . ?
O4 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
O4 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?

_diffrn_measured_fraction_theta_max 1.000
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         0.860
_refine_diff_density_min         -0.992
_refine_diff_density_rms         0.101
