First selenide-centered CuI8 cubic clusters containing dialkyl diselenophosphate ligands. X-Ray structure of {Cu8(µ8-Se)[Se2P(OPri)2]6}
Abstract
[Cu8(µ8-Se)[Se2P(OPri)2]6}, the first discrete CuI8 cubane in which each face of the cube is bridged by a diselenophosphate ligand and has an interstitial selenide ion (Se2–), is reported.