Issue 19, 2000
From the journal:

Chemical Communications

A novel nonacoordinate bridging selenido ligand in a tricapped trigonal- prismatic geometry. X-Ray structure of Cu11(μ9-Se)(μ3-Br)3[Se 2P(OPri)2]6

C. W. Liu,*a   Chiu-Mine Hung,a   Hsiu-Chih Chen,a   Ju-Chung Wang,b   Tai-Chiun Kengb  and  Kermin Guob  

* Corresponding authors

a Department of Chemistry, Chung Yuan Christian University, Chung-Li, Taiwan, R. O. C.
E-mail: chenwei@mbox.cycu.edu.tw

b Department of Chemistry, Soochow University, Taipei, Taiwan, R. O. C.First published as an Advance Article on the web

Abstract

The first nonacoordinate bridging selenido ligand in a tricapped trigonal prismatic geometry, Cu11(μ9-Se)(μ3-Br)3[Se 2P(OPri)2]6, is prepared along with closed-shell ion-centered CuI8 cubes, Cu8(μ8-Se)[Se2P(OPri)2 ]6 and Cu8(μ8-Br)[Se2P(OPri)2 ]6(PF6), from the reaction of NH4Se2P(OPri)2, Cu(CH3CN)4PF6, and Bu4NBr in CH2Br2 at 0 °C.

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Article information

DOI
https://doi.org/10.1039/B005366J
Article type
Communication
Submitted
04 Jul 2000
Accepted
22 Aug 2000
First published
22 Sep 2000

Chem. Commun., 2000, 1897-1898

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A novel nonacoordinate bridging selenido ligand in a tricapped trigonal- prismatic geometry. X-Ray structure of Cu11(μ9-Se)(μ3-Br)3[Se 2P(OPri)2]6

C. W. Liu, C. Hung, H. Chen, J. Wang, T. Keng and K. Guo, Chem. Commun., 2000, 1897 DOI: 10.1039/B005366J

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