Issue 12, 2005
From the journal:

Chemical Communications

Anion-assisted trans–cis isomerization of palladium(ii) phosphine complexes containing acetanilide functionalities through hydrogen bonding interactions†

Xiao-Xia Lu,a   Hau-San Tang,a   Chi-Chiu Ko,a   Jenny Ka-Yan Wong,a   Nianyong Zhua  and  Vivian Wing-Wah Yam*a  

* Corresponding authors

a Centre for Carbon-Rich Molecular and Nano-Scale Metal-Based Materials Research, Department of Chemistry, and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China
E-mail: wwyam@hku.hk
Fax: (852)2857-1586
Tel: (852)2859-2153

Abstract

The anion-assisted shift of trans–cis isomerization equilibrium of a palladium(II) complex containing acetanilide functionalities brought about by allosteric hydrogen bonding interactions has been established by UV/Vis, 1H NMR, 31P NMR and ESI-MS studies.

Graphical abstract: Anion-assisted trans–cis isomerization of palladium(ii) phosphine complexes containing acetanilide functionalities through hydrogen bonding interactions

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Article information

DOI
https://doi.org/10.1039/B418202B
Article type
Communication
Submitted
03 Dec 2004
Accepted
19 Jan 2005
First published
02 Feb 2005

Chem. Commun., 2005, 1572-1574

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Anion-assisted trans–cis isomerization of palladium(II) phosphine complexes containing acetanilide functionalities through hydrogen bonding interactions

X. Lu, H. Tang, C. Ko, J. Ka-Yan Wong, N. Zhu and V. W. Yam, Chem. Commun., 2005, 1572 DOI: 10.1039/B418202B

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