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Communication
Chem. Commun., 2006, 3894 - 3896, DOI: 10.1039/b607277a
Single-turnover intermolecular reaction between a FeIII–superoxide–CuI cytochrome c oxidase model and exogeneous Tyr244 mimics
James P. Collman, Richard A. Decréau and Christopher J. Sunderland
An FeIII–superoxide–CuI cytochrome c oxidase model reacts intermolecularly with hindered phenols leading to phenoxyl radicals, as was observed in the enzyme and evidence for the formation of an FeIV–oxo is presented.
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