Issue 7, 2007

Oxidation of secondary amines catalyzed by dirhodium caprolactamate

Abstract

The dirhodium caprolactamate [Rh2(cap)4] catalyzed oxidation of secondary amines to imines by tert-butyl hydroperoxide (TBHP) occurs with high chemo- and regioselectivity.

Graphical abstract: Oxidation of secondary amines catalyzed by dirhodium caprolactamate

Supplementary files

Article information

Article type
Communication
Submitted
31 Oct 2006
Accepted
08 Dec 2006
First published
09 Jan 2007

Chem. Commun., 2007, 745-747

Oxidation of secondary amines catalyzed by dirhodium caprolactamate

H. Choi and M. P. Doyle, Chem. Commun., 2007, 745 DOI: 10.1039/B615805F

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