Issue 1, 2008
From the journal:

Chemical Communications

Can large magnetic anisotropy and high spin really coexist?†

Eliseo Ruiz,*a   Jordi Cirera,a   Joan Cano,ab   Santiago Alvarez,a   Claudia Loosec  and  Jens Kortusc  

* Corresponding authors

a Departament de Química Inorgànica and Institut de Recerca de Química Teòrica i Computacional, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain
E-mail: eliseo.ruiz@qi.ub.es
Fax: +34 93490 7725
Tel: +34 93403 7058

b Institució Catalana de Recerca i Estudis Avançats, Passeig Lluís Companys 23, 08010 Barcelona, Spain

c Institut für Theoretische Physik, TU Bergakademie Freiberg, Leipziger Str. 23, 09596 Freiberg, Germany

Abstract

This theoretical study discusses the interplay of the magnetic anisotropy and magnetic exchange interaction of two Mn6 complexes and suggests that large magnetic anisotropy is not favoured by a high spin state of the ground state.

Graphical abstract: Can large magnetic anisotropy and high spin really coexist?

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Article information

DOI
https://doi.org/10.1039/B714715E
Article type
Communication
Submitted
24 Sep 2007
Accepted
26 Oct 2007
First published
07 Nov 2007

Chem. Commun., 2008, 52-54

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Can large magnetic anisotropy and high spin really coexist?

E. Ruiz, J. Cirera, J. Cano, S. Alvarez, C. Loose and J. Kortus, Chem. Commun., 2008, 52 DOI: 10.1039/B714715E

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