Issue 28, 2008
From the journal:

Chemical Communications

Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling†

Shelli R. Waetziga  and  Jon A. Tunge*a  

* Corresponding authors

a Department of Chemistry, The University of Kansas, 2010 Malott Hall 1251 Wescoe Hall Drive, Lawrence KS, USA
E-mail: tunge@ku.edu

Abstract

This communication details the Pd-catalyzed decarboxylation of selenocarbonates; use of a chiral nonracemic catalyst affords enantioenriched allyl selenides which undergo stereospecific [2,3]-sigmatropic rearrangements to form enantioenriched allylic amines and chlorides.

Graphical abstract: Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling

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Article information

DOI
https://doi.org/10.1039/B806949B
Article type
Communication
Submitted
25 Apr 2008
Accepted
02 May 2008
First published
10 Jun 2008

Chem. Commun., 2008, 3311-3313

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Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling

S. R. Waetzig and J. A. Tunge, Chem. Commun., 2008, 3311 DOI: 10.1039/B806949B

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