Issue 26, 2010

Synthesis and theoretical studies of gallium complexes back-shielded by a cage-shaped framework of tris(m-oxybenzyl)arene

Abstract

Cage-shaped gallium complexes with a back-shielding framework of tris(m-oxybenzyl)arene were synthesized, their bottom arene rings tuned their characteristic Lewis acidity, which was supported by theoretical calculation as well as catalytic application in a hetero Diels–Alder reaction.

Graphical abstract: Synthesis and theoretical studies of gallium complexes back-shielded by a cage-shaped framework of tris(m-oxybenzyl)arene

Supplementary files

Article information

Article type
Communication
Submitted
06 Mar 2010
Accepted
28 Apr 2010
First published
25 May 2010

Chem. Commun., 2010,46, 4794-4796

Synthesis and theoretical studies of gallium complexes back-shielded by a cage-shaped framework of tris(m-oxybenzyl)arene

H. Nakajima, M. Yasuda, K. Chiba and A. Baba, Chem. Commun., 2010, 46, 4794 DOI: 10.1039/C0CC00253D

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