Issue 11, 2001
From the journal:

Chemical Communications

Ambient temperature crystallisation of a lamellar gallium fluorophosphate from the synthesis solution of microporous ULM-5

Carine Livage,a   Franck Millange,a   Richard I. Walton,b   Thierry Loiseau,a   Nathalie Simon,a   Dermot O’Harec  and  Gérard Férey*a  

* Corresponding authors

a Institut Lavoisier, UMR CNRS 8637, Université de Versailles Saint Quentin-en-Yvelines, 45 Avenue des Etats-Unis, Versailles Cedex, France.
E-mail: ferey@chimie.uvsq.fr

b School of Chemistry, University of Exeter, Stocker Road, Exeter, Devon, UK

c Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, UK

Abstract

The layered gallium fluorophosphate Ga3F2(OH)4(H2- PO4)(HPO4)3 [H3N(CH2)6NH3]2 ·3.5H2O (1) crystallises at room temperature from the supernatant liquid taken during the hydrothermal synthesis of the large-pore material ULM-5; the phase has a topology not previously seen among the Group 13 phosphates.

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Article information

DOI
https://doi.org/10.1039/B102753K
Article type
Communication
Submitted
26 Mar 2001
Accepted
19 Apr 2001
First published
15 May 2001

Chem. Commun., 2001, 994-995

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Ambient temperature crystallisation of a lamellar gallium fluorophosphate from the synthesis solution of microporous ULM-5

C. Livage, F. Millange, R. I. Walton, T. Loiseau, N. Simon, D. O’Hare and G. Férey, Chem. Commun., 2001, 994 DOI: 10.1039/B102753K

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