Issue 8, 2006
From the journal:

Chemical Communications

“β-cis-SAr effect” on decarbonylation from α,β-unsaturated acyl and aroyl complexes†

Tomohiro Kato,a   Hitoshi Kuniyasu,*a   Takamichi Kajiura,a   Yasunori Minami,a   Atsushi Ohtaka,a   Masanori Kinomoto,a   Jun Terao,a   Hideo Kurosawaa  and  Nobuaki Kambe*a  

* Corresponding authors

a Department of Applied Chemistry & Frontier Research Center, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka Suita, Osaka, Japan
E-mail: kuni@chem.eng.osaka-u.ac.jp, kambe@chem.eng.osaka-u.ac.jp
Fax: +81 6 6879 7390
Tel: +81 6 6879 7389

Abstract

Lone pair of heteroatom located at the β-cis position in α,β-unsaturated acyl and aroyl group 10 metal complexes dramatically facilitated the stoichiometric and catalytic decarbonylation reactions.

Graphical abstract: “β-cis-SAr effect” on decarbonylation from α,β-unsaturated acyl and aroyl complexes

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Article information

DOI
https://doi.org/10.1039/B515616E
Article type
Communication
Submitted
03 Nov 2005
Accepted
12 Dec 2005
First published
18 Jan 2006

Chem. Commun., 2006, 868-870

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“β-cis-SAr effect” on decarbonylation from α,β-unsaturated acyl and aroyl complexes

T. Kato, H. Kuniyasu, T. Kajiura, Y. Minami, A. Ohtaka, M. Kinomoto, J. Terao, H. Kurosawa and N. Kambe, Chem. Commun., 2006, 868 DOI: 10.1039/B515616E

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