Issue 38, 2006
From the journal:

Chemical Communications

First mixed hydrazide/hydroxylamide metal aggregates†

Surajit Jana,a   Raphael J. F. Berger,a   Roland Fröhlichb  and  Norbert W. Mitzel*a  

* Corresponding authors

a Institut für Anorganische und Analytische Chemie and NRW Graduate School of Chemistry, Westfälische Wilhelms-Universität Münster, Corrensstrasse 30, Münster, Germany
E-mail: Mitzel@uni-muenster.de
Fax: Int+49 251 8336007

b Organisch-chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, Münster, Germany

Abstract

The first organometallic clusters of mixed hydrazide/hydroxylamide clusters of zinc, [Zn(MeZn)4(HNNMe2)2(ONEt2)4] and {Zn(EtZn)4[HNN(CH2)5]2(ONEt2)4} were synthesized in one-pot synthesis protocols from dialkylzinc solutions, substituted hydrazines and N,N-diethylhydroxylamine; competing for the Zn atoms, the different binding properties of hydrazide and hydroxylamide ligands in these heteroleptic clusters are discussed.

Graphical abstract: First mixed hydrazide/hydroxylamide metal aggregates

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Article information

DOI
https://doi.org/10.1039/B608135E
Article type
Communication
Submitted
07 Jun 2006
Accepted
25 Jul 2006
First published
10 Aug 2006

Chem. Commun., 2006, 3993-3995

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First mixed hydrazide/hydroxylamide metal aggregates

S. Jana, R. J. F. Berger, R. Fröhlich and N. W. Mitzel, Chem. Commun., 2006, 3993 DOI: 10.1039/B608135E

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