Issue 31, 2008
From the journal:

Chemical Communications

Photocatalytic hydrogen generation using a protein-coated photosensitizer with anionic patches and a monocationic electron mediator†

Takashi Matsuo,a   Atsushi Asano,a   Tsutomu Ando,b   Yoshio Hisaedab  and  Takashi Hayashi*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Japan
E-mail: thayashi@chem.eng.osaka-u.ac.jp
Fax: +81-6-6879-7930
Tel: +81-6-6879-7928

b Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka, Japan

Abstract

A reconstituted myoglobin with a synthetic cofactor having anionic binding sites effectively works as a photocatalyst for hydrogen generation in the presence of monomethylated bipyridinium.

Graphical abstract: Photocatalytic hydrogen generation using a protein-coated photosensitizer with anionic patches and a monocationic electron mediator

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Article information

DOI
https://doi.org/10.1039/B803491E
Article type
Communication
Submitted
28 Feb 2008
Accepted
16 May 2008
First published
23 Jun 2008

Chem. Commun., 2008, 3684-3686

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Photocatalytic hydrogen generation using a protein-coated photosensitizer with anionic patches and a monocationic electron mediator

T. Matsuo, A. Asano, T. Ando, Y. Hisaeda and T. Hayashi, Chem. Commun., 2008, 3684 DOI: 10.1039/B803491E

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