Issue 12, 2009
From the journal:

CrystEngComm

Polymerisation of a Cu(II) dimer into 1D chains using high pressure†‡

Stephen A. Moggach,a   Kyle W. Galloway,b   Alistair R. Lennie,c   Pascal Parois,b   Niall Rowantree,b   Euan K. Brechin,a   John E. Warren,c   Mark Murrie*b  and  Simon Parsons*a  

* Corresponding authors

a School of Chemistry and Centre for Science at Extreme Conditions, The University of Edinburgh, King's Buildings, W. Mains Rd, Edinburgh, UK
E-mail: S.Parsons@ed.ac.uk
Fax: (+)44 (0)131 650 4743

b Department of Chemistry, University of Glasgow, University Avenue, Glasgow, UK
E-mail: markm@chem.gla.ac.uk
Fax: (+)44 (0)141 330 4888

c STFC Daresbury Laboratory, Warrington, Cheshire, UK

Abstract

Long intermolecular interactions are converted into covalent bonds when the complex [Cu2(OH)(citrate)(Guanidine)2]− is exposed to a pressure of 2.9 GPa; the coordination of the Cu centres changes from [4 + 1] to [4 + 2], but on increasing the pressure to 4.2 GPa some of the Cu centres become [4 + 1]-coordinate again.

Graphical abstract: Polymerisation of a Cu(II) dimer into 1D chains using high pressure

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Article information

DOI
https://doi.org/10.1039/B912707K
Article type
Communication
Submitted
26 Jun 2009
Accepted
13 Aug 2009
First published
21 Aug 2009

CrystEngComm, 2009,11, 2601-2604

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Polymerisation of a Cu(II) dimer into 1D chains using high pressure

S. A. Moggach, K. W. Galloway, A. R. Lennie, P. Parois, N. Rowantree, E. K. Brechin, J. E. Warren, M. Murrie and S. Parsons, CrystEngComm, 2009, 11, 2601 DOI: 10.1039/B912707K

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