_tcm18-11400.gif )
The home of high impact reviews from across the chemical sciences.
Tutorial Review
Chem. Soc. Rev., 2007, 36, 367 - 377, DOI: 10.1039/b603847f
Multicoordinate ligands for actinide/lanthanide separations
Henk H. Dam, David N. Reinhoudt and Willem Verboom
In nuclear waste treatment processes there is a need for improved ligands for the separation of actinides (An(III)) and lanthanides (Ln(III)). Several research groups are involved in the design and synthesis of new An(III) ligands and in the confinement of these and existing An(III) ligands onto molecular platforms giving multicoordinate ligands. The preorganization of ligands considerably improves the An(III) extraction properties, which are largely dependent on the solubility and rigidity of the platform. This tutorial review summarizes the most important An(III) ligands with emphasis on the preorganization strategy using (macrocyclic) platforms.
RSS feed