Issue 17, 2008
From the journal:

Dalton Transactions

Formation of acylruthenium promoted by coordination of AlMe3 to (η4-cyclopentadienone)Ru(CO)3†

Sensuke Ogoshi,*a   Tetsuya Kato,a   Masato Ohashia  and  Hideo Kurosawaa  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering, Osaka University, Osaka, Suita, Japan
E-mail: ogoshi@chem.eng.osaka-u.ac.jp
Fax: (+81) 6-6879-7394
Tel: (+81) 6-6879-7392

Abstract

The reaction of AlMe3 with (η4-tetraphenylcyclopentadienone)Ru(CO)3 leads to rapid and quantitative formation of an adduct arising from coordination of the enone oxygen to aluminium, which undergoes alkylation at the Ru(CO)3 moiety to give (η5-C4Ph4C(OAlMe2))Ru(CO)2(COMe) concomitant with a change of hapticity of the dienone ligand.

Graphical abstract: Formation of acylruthenium promoted by coordination of AlMe3 to (η4-cyclopentadienone)Ru(CO)3

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Article information

DOI
https://doi.org/10.1039/B802019C
Article type
Communication
Submitted
04 Feb 2008
Accepted
11 Feb 2008
First published
25 Feb 2008

Dalton Trans., 2008, 2232-2234

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Formation of acylruthenium promoted by coordination of AlMe3 to (η4-cyclopentadienone)Ru(CO)3

S. Ogoshi, T. Kato, M. Ohashi and H. Kurosawa, Dalton Trans., 2008, 2232 DOI: 10.1039/B802019C

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