Issue 29, 2009
From the journal:

Physical Chemistry Chemical Physics

Evidence for a ball-shaped cyclen cyclophane: an experimental and first principles study†

Jonathan P. Hill,*ab   Roberto Scipioni,b   Mauro Boero,‡c   Yutaka Wakayama,d   Misaho Akada,a   Tsuyoshi Miyazakie  and  Katsuhiko Arigaa  

* Corresponding authors

a Supermolecules Group, WPI-Center for Materials Nanoarchitectonics, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
E-mail: Jonathan.Hill@nims.go.jp
Tel: +81-29-860-4832

b WPI-Center for Materials Nanoarchitectonics, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan

c Center for Computational Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577, Japan

d Advanced Electronic Materials Center, National Institute for Materials Science, Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan

e Computational Materials Science Center, National Institute for Materials Science, Sengen 1-2-1, Tsukuba, Ibaraki 305-0047, Japan

Abstract

Conformational isomerism of a ball-shaped cyclophane of cyclen was studied using NMR and computational methods with the most notable conformer containing a highly symmetric cyclic benzene tetramer.

Graphical abstract: Evidence for a ball-shaped cyclen cyclophane: an experimental and first principles study

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B822802G
Article type
Communication
Submitted
19 Dec 2008
Accepted
01 May 2009
First published
14 May 2009

Phys. Chem. Chem. Phys., 2009,11, 6038-6041

Permissions

Request permissions

Evidence for a ball-shaped cyclen cyclophane: an experimental and first principles study

J. P. Hill, R. Scipioni, M. Boero, Y. Wakayama, M. Akada, T. Miyazaki and K. Ariga, Phys. Chem. Chem. Phys., 2009, 11, 6038 DOI: 10.1039/B822802G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements