Claisen rearrangement

Definition: The [3,3]-sigmatropic rearrangement of an allyl vinyl ether to give a gamma,delta-unsaturated carbonyl compound.

ID: RXNO:0000148

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Articles referencing this term

Stereocontrolled synthesis of carbocycles via four successive pericyclic reactions
Roxanne Clément, Christiane M. Grisé and Louis Barriault, Chem. Commun., 2008 , 3004
DOI: 10.1039/b803898h

Double decarboxylative Claisen rearrangement reactions: microwave-assisted de novo synthesis of pyridines
Donald Craig, Federica Paina and Stephen C. Smith, Chem. Commun., 2008 , 3408
DOI: 10.1039/b805078c

A quantitative structure–reactivity relationship in decarboxylative Claisen rearrangement reactions of allylic tosylmalonate esters
Donald Craig and Nikolay K. Slavov, Chem. Commun., 2008 , 6054
DOI: 10.1039/b812306c

Stereoselective Reformatskii–Claisen rearrangement: synthesis of 2′,3′-dideoxy-6′,6′-difluoro-2′-thionucleosides
Feng Zheng, Xingang Zhang and Feng-Ling Qing, Chem. Commun., 2009 , 1505
DOI: 10.1039/b819289h

Enantiopure sulfoxides: recent applications in asymmetric synthesis
M. Carmen Carreño, Gloria Hernández-Torres, María Ribagorda and Antonio Urbano, Chem. Commun., 2009 , 6129
DOI: 10.1039/b908043k

Intramolecular Michael addition reaction for the synthesis of benzylbutyrolactones
Hu He, Li-Xin Dai and Shu-Li You, Org. Biomol. Chem., 2010 , 8 , 3207
DOI: 10.1039/b924770j

Stereoselective synthesis of epi-jasmonic acid, tuberonic acid, and 12-oxo-PDA
Hisato Nonaka, Narihito Ogawa, Noriaki Maeda, Yong-Gang Wang and Yuichi Kobayashi, Org. Biomol. Chem., 2010 , 8 , 5212
DOI: 10.1039/c0ob00218f

Catalytic asymmetric allylic alkylation employing heteroatom nucleophiles: a powerful method for C–X bond formation
Barry M. Trost, Ting Zhang and Joshua D. Sieber, Chem. Sci., 2010 , 1 , 427
DOI: 10.1039/c0sc00234h