Fleming-Tamao oxidation


Definition: The stereospecific oxidation of a (phenyldimethylsilyl)alkane to the corresponding alcohol using bromine, usually generated in situ from potassium bromide and peracetic acid.

ID: RXNO:0000210

Synonyms:

More about the RSC Name Reaction Ontology (RXNO)


Articles referencing this term

A palladium-mediated cascade cyclisation approach to the CDE cores of rubriflordilactone A and lancifodilactone G
Marie-Caroline A. Cordonnier, S. B. Jennifer Kan and Edward A. Anderson, Chem. Commun., 2008 , 5818
DOI: 10.1039/b814360a

Organosilicon-mediated total synthesis of the triquinane sesquiterpenes (±)-β-isocomene and (±)-isocomene
Arndt W. Schmidt, Thomas Olpp, Elke Baum, Tina Stiffel and Hans-Joachim Knölker, Org. Biomol. Chem., 2010 , 8 , 4562
DOI: 10.1039/c0ob00051e