Oxidation of ethanol
by acidified sodium dichromate in a test-tube reaction, firstly to form oxidised (acetaldehyde), and with further oxidation, ethanal (acetic acid). The experiment is most appropriate for post-16 students. ethanoic acid
This is a straightforward class experiment that will take about 10 minutes.
Each group will require:
Goggles to be worn
Boiling tube (Note 1)
Heat resistant mat
Ethanol (IDA, Industrial Denatured Alcohol) (HIGHLY FLAMMABLE, HARMFUL), 2 - 3 cm
3, provided in small bottles
Acidified sodium dichromate(VI) solution, 10 cm
3 (VERY TOXIC, CORROSIVE) (Note 2)
Refer to Health & Safety and Technical notes section below for additional information.
Health & Safety and Technical notes
Read our standard health & safety guidance
Ethanol or IDA (Industrial Denature Alcohol), C
2H 5OH(l), (HIGHLY FLAMMABLE, HARMFUL) - see CLEAPSS Hazcard.
Acidified sodium dichromate(VI) solution, Na
2Cr 2O 7(aq) (VERY TOXIC, OXIDISING, DANGEROUS FOR THE ENVIRONMENT) - see CLEAPSS Hazcard and Note 2 below.
Concentrated sulfuric acid, H
2SO 4(l) (CORROSIVE) - see CLEAPSS Hazcard.
1 A large, 150 x 25 mm, test-tube.
2 Student should be provided with the acidified dichromate(VI) solution already prepared as described here. Wearing goggles (or a face shield), prepare the solution by completely dissolving 25 g of sodium dichromate(VI)-2-water (Na 2Cr 2O 7.2H 2O) in 75 cm 3 of water in a beaker or conical flask. Slowly and carefully add 10 cm 3 of concentrated sulfuric acid and mix thoroughly. Provide this solution in small, appropriately labelled bottles with pipettes. Students should be instructed in the safe use of this solution.
a Place about 3 cm 3 of acidified sodium dichromate solution in a boiling tube.
b Use a teat pipette to add 5 -7 drops of ethanol, with shaking.
c Cool the mixture in the tube under a tap. Note the sweetish smell of ethanal (acetaldehyde) at first, then becoming sharper as oxidation continues and forms ethanoic acid (acetic acid).
d When the reaction has subsided, the mixture can be warmed gently; the smell of ethanoic acid will become more noticeable.
This experiment would usually form part of the teaching and learning sequence for the chemistry of alcohols, aldehydes and acids. The colour of the solution turns from orange to blue-green as the dichromate(VI) ion, Cr
2O 7 2-, is reduced to the chromium(III) ion, Cr 3+.
Note that the sodium dichromate solution is more concentrated than 0.2 mol dm
-3, so the toxicity level is high, and students need to be instructed in safe handling. Consider wearing protective (nitrile) gloves. A more dilute solution can be used if preferred, with longer reaction time - the mixture may need gentle heating in a water bath.
Ball and stick molecular models will be useful for modelling both stages of the reaction scheme.
Students could be asked to write equations for the reactions involved when ethanol is oxidised by sodium dichromate in acid solution to (i) ethanal (ii) ethanoic acid, using [O] to represent oxygen coming from the dichromate.
A variant on this experiment as a demonstration for advanced students is to place four petri dishes on an overhead projector (protected from spillage with ‘cling’ film), and pour the same volume of acidified sodium dichromate solution into each dish. Then add 1 cm
3 of 3 different alcohols, one to each dish (leave the fourth dish is a control), and observe the different rates of oxidation from the rate of the colour change. This approach can be used to investigate the effect of chain length of primary alcohols, or the differences between the reactions of oxidising agents with primary, secondary and tertiary alcohols.
The ‘breathalyser’ reaction is a nice linked experiment demonstrating a real world application of this type of chemistry (see ‘also of interest’ below)
This reaction can be easily adapted to analyse alcoholic drinks for their ethanol content.
Health & Safety checked, September 2014
This Practical Chemistry resource was developed by the Nuffield Foundation and the Royal Society of Chemistry.
© Nuffield Foundation and the Royal Society of Chemistry
Page last updated October 2015