| Group | 6 | Melting point | 2622 oC, 4751.6 oF, 2895.15 K |
| Period | 5 | Boiling point | 4639 oC, 8382.2 oF, 4912.15 K |
| Block | d | Density (kg m-3) | 10222 |
| Atomic number | 42 | Relative atomic mass | 95.96 |
| State at room temperature | Solid | Key isotopes | 95Mo, 96Mo, 98Mo |
| Electron configuration | [Kr] 4d55s1 | CAS number | 7439-98-7 |
| ChemSpider ID | 22374 | ChemSpider is a free chemical structure database | |
Image explanation
The element and its alloys are used in the manufacture of valves and boiler plates.
Appearance
A silvery metal produced and sold as a grey powder and used in alloys, catalysts and electrodes. World production is 80,000 tonnes per year, most of which is converted to molybdenum sulfide, a lubricant additive. This element is essential for several living things, and probably for humans, although only in tiny amounts. The average human takes in about 0.3 grammes a day and stores about 5 milligrammes in the body
Uses
Molybdenum is a valuable alloying agent, as it contributes to the hardness and toughness of quenched and tempered steels. It is also used in certain nickel-based alloys which are heat-resistant and corrosion-resistant to chemical solutions. It has found use in electrical and nuclear applications, and as a catalyst in the refining of petroleum.
Biological role
Although it is toxic in anything other than small quantities, molybdenum is an essential element for animals and
plants. If soil lacks this element the land is barren. Leguminous plants use the nitrogen-fixing enzyme nitrogenase, which contains molybdenum.
Natural abundance
The main source of this element is the ore molybdenite. Molybdenum can be obtained from this ore, but most commercial production is as a by-product of copper production.
| Atomic radius, non-bonded (Å) | 2.170 | Covalent radius (Å) | 1.46 |
| Electron affinity (kJ mol-1) | 72.146 |
Electronegativity (Pauling scale) |
2.160 |
|
Ionisation energies (kJ mol-1) |
1st
684.315
2nd
1559.202
3rd
2617.645
4th
4476.916
5th
5257.482
6th
6640.849
7th
12124.723
8th
13855.283
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| Common oxidation states | 6, 5, 4, 3, 2, 0 | ||||
| Isotopes | Isotope | Atomic mass | Natural abundance (%) | Half life | Mode of decay |
| 92Mo | 91.907 | 14.77 | > 3 x 1017 y | β+-EC | |
| 94Mo | 93.905 | 9.23 | - | - | |
| 95Mo | 94.906 | 15.9 | - | - | |
| 96Mo | 95.905 | 16.68 | - | - | |
| 97Mo | 96.906 | 9.56 | - | - | |
| 98Mo | 97.905 | 24.19 | - | - | |
| 100Mo | 99.907 | 9.67 | 6 x 1020 y | β-β- | |
|
Molar heat capacity (J mol-1 K-1) |
24.06 | Young's modulus (GPa) | Unknown | |||||||||||
| Shear modulus (GPa) | Unknown | Bulk modulus (GPa) | 231 | |||||||||||
| Vapour pressure | ||||||||||||||
| Temperature (K) |
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| Pressure (Pa) |
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Videos of the elements. Additional videos will be coming in 2012.
Images: Visual Elements © Murray Robertson 2011
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
