| Group | 14 | Melting point | 231.93 oC, 449.474 oF, 505.08 K |
| Period | 5 | Boiling point | 2586 oC, 4686.8 oF, 2859.15 K |
| Block | p | Density (kg m-3) | 7285 |
| Atomic number | 50 | Relative atomic mass | 118.71 |
| State at room temperature | Solid | Key isotopes | 120Sn |
| Electron configuration | [Kr] 4d105s25p2 | CAS number | 7440-31-5 |
| ChemSpider ID | 4509318 | ChemSpider is a free chemical structure database | |
Image explanation
A common alchemical symbol for tin used here as an embossment for a “tin” can. Tin cans were traditionally made from tin coated steel. Click through to the alchemical symbol for Tin and other elements.
Appearance
A soft pliable metal but it is not used as such because, below 13° C, it slowly changes to a powder. Steel is plated with tin to make cans, and it is also used for solders. Some tin compounds are employed as anti-fouling paint for ships and boats to prevent barnacles, but even at low levels, these compounds are deadly to marine life especially oysters. Tin is thought to be an essential element for some living things and this may also be true for humans.
Uses
Tin has many uses. It takes a high polish and is used to coat other metals to prevent corrosion, such as in tin cans which are made of tin-coated steel. Alloys of tin are important, such as soft solder, pewter, bronze and phosphor bronze. The most important tin salt used is tin(II) chloride which is used as a reducing agent and as a mordant. Tin salts sprayed onto glass are used to produce electrically conductive coatings. Most window glass is made by floating molten glass on molten tin to produce a flat surface. Recently, a tin-niobium alloy that is superconductive at very low
temperatures has attracted interest.
Biological role
Tin is non-toxic. Trialkyl and triaryl tin compounds are used as biocides and must be handled with care.
Natural abundance
Tin is found mainly in the ore cassiterite, which is found in Brazil, China, Peru, Indonesia, Thailand and Nigeria. It is obtained commercially by reducing the ore with coal in a reverberatory furnace.
| Atomic radius, non-bonded (Å) | 2.170 | Covalent radius (Å) | 1.4 |
| Electron affinity (kJ mol-1) | 107.26 |
Electronegativity (Pauling scale) |
1.960 |
|
Ionisation energies (kJ mol-1) |
1st
708.578
2nd
1411.792
3rd
2943.051
4th
3930.329
5th
6973.954
6th
-
7th
-
8th
-
|
||
|
|
| Common oxidation states | 4, 2 | ||||
| Isotopes | Isotope | Atomic mass | Natural abundance (%) | Half life | Mode of decay |
| 112Sn | 111.905 | 0.97 | - | - | |
| 114Sn | 113.903 | 0.66 | - | - | |
| 115Sn | 114.903 | 0.34 | - | - | |
| 116Sn | 115.902 | 14.54 | - | - | |
| 117Sn | 116.903 | 7.68 | - | - | |
| 118Sn | 117.902 | 24.22 | - | - | |
| 119Sn | 118.903 | 8.59 | - | - | |
| 120Sn | 119.902 | 32.58 | - | - | |
| 122Sn | 121.903 | 4.63 | - | - | |
| 124Sn | 123.905 | 5.79 | > 2.2 x 1018 y | β-β- | |
|
Molar heat capacity (J mol-1 K-1) |
26.99 | Young's modulus (GPa) | 49.9 | |||||||||||
| Shear modulus (GPa) | 18.4 | Bulk modulus (GPa) | 58.2 | |||||||||||
| Vapour pressure | ||||||||||||||
| Temperature (K) |
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| Pressure (Pa) |
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Images: Visual Elements © Murray Robertson 2011
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
