Periodic Table > Lanthanum


Some elements exist in several different structural forms, called allotropes. Each allotrope has different physical properties.

For more information on the Visual Elements image see the Uses and properties section below.



A vertical column in the periodic table. Members of a group typically have similar properties and electron configurations in their outer shell.

A horizontal row in the periodic table. The atomic number of each element increases by one, reading from left to right.

Elements are organised into blocks by the orbital type in which the outer electrons are found. These blocks are named for the characteristic spectra they produce: sharp (s), principal (p), diffuse (d), and fundamental (f).

Atomic number
The number of protons in an atom.

Electron configuration
The arrangements of electrons above the last (closed shell) noble gas.

Melting point
The temperature at which the solid–liquid phase change occurs.

Boiling point
The temperature at which the liquid–gas phase change occurs.

The transition of a substance directly from the solid to the gas phase without passing through a liquid phase.

Density (g cm−3)
Density is the mass of a substance that would fill 1 cm3 at room temperature.

Relative atomic mass
The mass of an atom relative to that of carbon-12. This is approximately the sum of the number of protons and neutrons in the nucleus. Where more than one isotope exists, the value given is the abundance weighted average.

Atoms of the same element with different numbers of neutrons.

CAS number
The Chemical Abstracts Service registry number is a unique identifier of a particular chemical, designed to prevent confusion arising from different languages and naming systems.

Fact box

Group Lanthanides  Melting point 920°C, 1688°F, 1193 K 
Period Boiling point 3464°C, 6267°F, 3737 K 
Block Density (g cm−3) 6.15 
Atomic number 57  Relative atomic mass 138.905  
State at 20°C Solid  Key isotopes 139La 
Electron configuration [Xe] 5d16s2  CAS number 7439-91-0 
ChemSpider ID 22369 ChemSpider is a free chemical structure database


Image explanation

Murray Robertson is the artist behind the images which make up Visual Elements. This is where the artist explains his interpretation of the element and the science behind the picture.


The description of the element in its natural form.

Biological role

The role of the element in humans, animals and plants.

Natural abundance

Where the element is most commonly found in nature, and how it is sourced commercially.

Uses and properties

Image explanation
The image is of a camera lens. Lanthanum is added to glass used in some camera lenses to improve the clarity of the images it can produce. The flames in the background reflect the ease with which the element burns when ignited.
A soft, silvery-white metal. It rapidly tarnishes in air and burns easily when ignited.
Lanthanum metal has no commercial uses. However, its alloys have a variety of uses. A lanthanum-nickel alloy is used to store hydrogen gas for use in hydrogen-powered vehicles. Lanthanum is also found in the anode of nickel metal hydride batteries used in hybrid cars.

Lanthanum is an important component of mischmetal alloy (about 20%). The best-known use for this alloy is in ‘flints’ for cigarette lighters.

‘Rare earth’ compounds containing lanthanum are used extensively in carbon lighting applications, such as studio lighting and cinema projection. They increase the brightness and give an emission spectrum similar to sunlight.

Lanthanum(III) oxide is used in making special optical glasses, as it improves the optical properties and alkali resistance of the glass. Lanthanum salts are used in catalysts for petroleum refining.

The ion La3+ is used as a biological tracer for Ca2+, and radioactive lanthanum has been tested for use in treating cancer.
Biological role
Lanthanum has no known biological role. Both the element and its compounds are moderately toxic.
Natural abundance
Lanthanum is found in ‘rare earth’ minerals, principally monazite (25% lanthanum) and bastnaesite (38% lanthanum). Ion-exchange and solvent extraction techniques are used to isolate the ‘rare earth’ elements from the minerals. Lanthanum metal is usually obtained by reducing the anhydrous fluoride with calcium.
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Lanthanum was discovered in January 1839 by Carl Gustav Mosander at the Karolinska Institute, Stockholm. He extracted it from cerium which had been discovered in 1803. Mosander noticed that while most of his sample of cerium oxide was insoluble, some was soluble and he deduced that this was the oxide of a new element. News of his discovery spread, but Mosander was strangely silent.

That same year, Axel Erdmann, a student also at the Karolinska Institute, discovered lanthanum in a new mineral from Låven island located in a Norwegian fjord.

Finally, Mosander explained his delay, saying that he had extracted a second element from cerium, and this he called didymium. Although he didn’t realise it, didymium too was a mixture, and in 1885 it was separated into praseodymium and neodymium.

Atomic radius, non-bonded
Half of the distance between two unbonded atoms of the same element when the electrostatic forces are balanced. These values were determined using several different methods.

Covalent radius
Half of the distance between two atoms within a single covalent bond. Values are given for typical oxidation number and coordination.

Electron affinity
The energy released when an electron is added to the neutral atom and a negative ion is formed.

Electronegativity (Pauling scale)
The tendency of an atom to attract electrons towards itself, expressed on a relative scale.

First ionisation energy
The minimum energy required to remove an electron from a neutral atom in its ground state.

Atomic data

Atomic radius, non-bonded (Å) 2.43 Covalent radius (Å) 1.94
Electron affinity (kJ mol−1) 45.35 Electronegativity
(Pauling scale)
Ionisation energies
(kJ mol−1)


Common oxidation states

The oxidation state of an atom is a measure of the degree of oxidation of an atom. It is defined as being the charge that an atom would have if all bonds were ionic. Uncombined elements have an oxidation state of 0. The sum of the oxidation states within a compound or ion must equal the overall charge.


Atoms of the same element with different numbers of neutrons.

Key for isotopes

Half life
  y years
  d days
  h hours
  m minutes
  s seconds
Mode of decay
  α alpha particle emission
  β negative beta (electron) emission
  β+ positron emission
  EC orbital electron capture
  sf spontaneous fission
  ββ double beta emission
  ECEC double orbital electron capture

Oxidation states and isotopes

Common oxidation states 3
Isotopes Isotope Atomic mass Natural abundance (%) Half life Mode of decay
  138La 137.907 0.09 1.06 x 1011
  139La 138.906 99.91


Data for this section been provided by the British Geological Survey.

Relative supply risk

An integrated supply risk index from 1 (very low risk) to 10 (very high risk). This is calculated by combining the scores for crustal abundance, reserve distribution, production concentration, substitutability, recycling rate and political stability scores.

Crustal abundance (ppm)

The number of atoms of the element per 1 million atoms of the Earth’s crust.

Recycling rate

The percentage of a commodity which is recycled. A higher recycling rate may reduce risk to supply.


The availability of suitable substitutes for a given commodity.
High = substitution not possible or very difficult.
Medium = substitution is possible but there may be an economic and/or performance impact
Low = substitution is possible with little or no economic and/or performance impact

Production concentration

The percentage of an element produced in the top producing country. The higher the value, the larger risk there is to supply.

Reserve distribution

The percentage of the world reserves located in the country with the largest reserves. The higher the value, the larger risk there is to supply.

Political stability of top producer

A percentile rank for the political stability of the top producing country, derived from World Bank governance indicators.

Political stability of top reserve holder

A percentile rank for the political stability of the country with the largest reserves, derived from World Bank governance indicators.

Supply risk

Relative supply risk 9.5
Crustal abundance (ppm) 0.3
Recycling rate (%) <10
Substitutability High
Production concentration (%) 97
Reserve distribution (%) 50
Top 3 producers
  • 1) China
  • 2) Russia
  • 3) Malaysia
Top 3 reserve holders
  • 1) China
  • 2) CIS Countries (inc. Russia)
  • 3) USA
Political stability of top producer 24.1
Political stability of top reserve holder 24.1


Specific heat capacity (J kg−1 K−1)

Specific heat capacity is the amount of energy needed to change the temperature of a kilogram of a substance by 1 K.

Young's modulus

A measure of the stiffness of a substance. It provides a measure of how difficult it is to extend a material, with a value given by the ratio of tensile strength to tensile strain.

Shear modulus

A measure of how difficult it is to deform a material. It is given by the ratio of the shear stress to the shear strain.

Bulk modulus

A measure of how difficult it is to compress a substance. It is given by the ratio of the pressure on a body to the fractional decrease in volume.

Vapour pressure

A measure of the propensity of a substance to evaporate. It is defined as the equilibrium pressure exerted by the gas produced above a substance in a closed system.

Pressure and temperature data – advanced

Specific heat capacity
(J kg−1 K−1)
195 Young's modulus (GPa) 36.6
Shear modulus (GPa) 14.3 Bulk modulus (GPa) 27.9
Vapour pressure  
Temperature (K)
400 600 800 1000 1200 1400 1600 1800 2000 2200 2400
Pressure (Pa)
- - - - 5.09
x 10-8
x 10-5
0.00181 0.0596 0.976 9.61 64.7
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Listen to Lanthanum Podcast
Transcript :

Chemistry in its element: lanthanum


You're listening to Chemistry in its element brought to you by Chemistry World, the magazine of the Royal Society of Chemistry.

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Meera Senthilingam

Hello and welcome to Chemistry in its Element, I'm Meera Senthilingam. This week the element that resembles a humble, but crucial film star, that appears everywhere but is often forgotten about. Brian Clegg uncovers the secret world of Lanthanum.

Brian Clegg

The periodic table is a wonderful structure. In its neat, ordered way, it predicts the behaviour of atoms as they follow a step-by-step pattern of increasing atomic number. At first glance, it's a simple matter of running across row after row. But take a closer look at barium and its obscure neighbour to the right, hafnium. Barium is atomic number 56. hafnium is 72. There are 15 elements missing. On a modern table, these appear at the bottom in a separate, floating row. They are the lanthanides - and we're taking a look at the element that gave its name to the whole group, lanthanum.

For most of us, giving the name to that group is about all lanthanum is known for - so it comes as quite a surprise to discover just how many ways it is used - we'll find it everywhere from cameras to swimming pools. But before we uncover the secret world of lanthanum, how did it end up sounding like a Victorian opium drink? It was one of the earlier lanthanides to be discovered, by the Swedish scientist Carl Gustav Mosander, working at the famous Karolinska Institute in 1839, though it was 1923 before the pure metal was produced.

One of the most reactive of the lanthanides, readily oxidising and bubbling away in water, lanthanum turned up unexpectedly in a cerium salt sample Mosander was working on. It was because of its sneakily unexpected appearance in the sample that Mosander called it lanthanum, from the Greek word lanthano, meaning to escape notice - in fact the first recorded reference to it in 1841 calls it 'another metallic oxide, which has hitherto lain concealed in oxide of cerium'.

When it comes to using lanthanum, it best resembles a successful movie bit part player. Someone who never gets the lead role, but appears in film after film, solidly portraying different characters. Not a particularly expensive material to produce, lanthanum's many roles remain of a supporting kind, playing an essential part but avoiding the limelight.

It is often added in small quantities to metals like iron and steel to make them less brittle, or to tungsten to improve the quality of electrodes used in arc welding. On a lesser scale of heat it also contributes to the spark produced by cigarette lighters using a material called mischmetal (literally mix metal in German) at least a quarter of which is usually lanthanum, giving the element its one starring role.

Much of the lanthanum we experience is invisible, incorporated into glass. For many years, lead has been added to glass to give it an increased refractive index, producing an extra-shiny crystal effect. As the refractive index goes up, light travels slower in the material and the light is bent more as it travels from air into the glass. Lanthanum is much better than lead at pushing up the refractive index without dispersing the light too much, this extra clarity means that lanthanum oxide is now used widely in lenses for cameras and telescopes.

Some of those lenses will be pointed at celebrity swimming pools, where one of the many chemicals likely to be added to the water is a lanthanum salt, aimed at latching onto phosphates that would otherwise act as in-water fertiliser, encouraging green algae to discolour the pool. And I could go on about its use in rechargeable Nickel Metal Hydride batteries or gas mantles - but I'm sure you get the point.

Lanthanum may be useful for scanning distant views through binoculars, but a final use of the element is in peering into the past. We're familiar with radiocarbon dating, based on the decay rate of carbon 14, being used to date biological specimens. Such radiometric dating relies on the fact that radioactive materials decay with a known half life. This means that, for instance, with carbon 14, half of the original amount will be left after around 6,000 years. The remainder will half again in the next 6,000 years, and so on. By measuring the amount of the radioactive substance in an object, relative to the product of its decay, we can determine its age.

But to use carbon dating we need something with a reasonable amount of carbon in it - usually something that was originally living - and for the object to have been formed no more than about 60,000 years ago, after which too little of the carbon 14 is left. This makes it useless when attempting to date rocks that are hundreds of millions of years old. Here, one of the alternative dating approaches is so called La-Ba dating.

Lanthanum and the element before it in the periodic table, barium, have an exotic relationship. Barium 139, for example, has a half-life of just 68 minutes before it breaks down to form lanthanum 139 - not suitable for dating anything older than a loaf of bread. But lanthanum 138 has a hefty half-life of around 100 billion years on the way to forming barium 138, making it ideal for dating ancient granites. Working on these timescales makes for a fairly loose idea of accuracy. One paper on the La-Ba technique proudly announces that rocks have been dated 'with the high precision of plus or minus 3.7 million years'.

This is not the kind of accuracy we hope for in train timetables, but when you're dealing with something half a billion years old, it makes a pretty good hit for lanthanum, the element that despite its name, shouldn't escape notice.

Meera Senthilingam

So it makes metal stronger, camera lenses better and keeps swimming pools clean. This element really does like to get around. That was Brian Clegg with the hidden depths of lanthanum. Next week an element that may appear just normal or indistinct but is truly adored by the people that know it - a trait it seems to share with a famous mermaid.

Eric Scerri

On my recent trip to Copenhagen I spent a long time looking for the famous little mermaid that is symbolic of the city. When I found it I was surprised to see that it is rather insignificant, but this did not seem to lessen the special attention that it held for tourists from all over the world. I think it's a bit like the metal hafnium, first discovered in the mermaid's city of Copenhagen. It too seems rather insignificant at first sight and yet it holds the attention of a variety of scientists because of its rather special properties.

Meera Senthilingam

And you can learn the history and uses of Hafnium that make this element so loved by scientists worldwide with Eric Scerri in next week's Chemistry in its element. I'm Meera Senthilingam, thank you for listening and see you next week.


Chemistry in its element is brought to you by the Royal Society of Chemistry and produced by There's more information and other episodes of Chemistry in its element on our website at

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Visual Elements images and videos
© Murray Robertson 2011.



W. M. Haynes, ed., CRC Handbook of Chemistry and Physics, CRC Press/Taylor and Francis, Boca Raton, FL, 95th Edition, Internet Version 2015, accessed December 2014.
Tables of Physical & Chemical Constants, Kaye & Laby Online, 16th edition, 1995. Version 1.0 (2005), accessed December 2014.
J. S. Coursey, D. J. Schwab, J.J. Tsai, and R. A. Dragoset, Atomic Weights and Isotopic Compositions(version 3.0), 2010, National Institute of Standards and Technology, Gaithersburg, MD, accessed December 2014.
T. L. Cottrell, The Strengths of Chemical Bonds, Butterworth, London, 1954.


Uses and properties

John Emsley, Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, New York, 2nd Edition, 2011.
Thomas Jefferson National Accelerator Facility - Office of Science Education, It’s Elemental - The Periodic Table of Elements, accessed December 2014.
Periodic Table of Videos, accessed December 2014.


Supply risk data

Derived in part from material provided by the British Geological Survey © NERC.


History text

© John Emsley 2012.



Produced by The Naked Scientists.


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