Periodic Table > Carbon
 

Terminology


Allotropes
Some elements exist in several different structural forms, these are called allotropes.


For more information on Murray Robertson’s image see Uses and properties facts below.

 

Fact box terminology


Group
Elements appear in columns or ‘groups’ in the periodic table. Members of a group typically have similar properties and electron configurations in their outer shell.


Period
Elements are laid out into rows or ‘periods’ so that similar chemical behaviour is observed in columns.


Block
Elements are organised into blocks by the orbital type in which the outer electrons are found. These blocks are named for the characteristic spectra they produce: sharp, principal, diffuse, and fundamental.


Atomic Number
The number of protons in the nucleus.


Atomic Radius/non -bonded (Å)
based on Van der Waals forces (where several isotopes exist, a value is presented for the most prevalent isotope). These values were calculated using a multitude of methods including crystallographic data, gas kinetic collision cross sections, critical densities, liquid state properties, for more details please refer to the CRC Handbook of Chemistry and Physics.


Electron Configuration
The arrangements of electrons above the last (closed shell) noble gas.


Isotopes
Elements are defined by the number of protons in its centre (nucleus), whilst the number of neutrons present can vary. The variations in the number of neutrons will create elements of different mass which are known as isotopes.


Melting Point (oC)
The temperature at which the solid-liquid phase change occurs.


Melting Point (K)
The temperature at which the solid-liquid phase change occurs.


Melting Point (oF)
The temperature at which the solid-liquid phase change occurs.


Boiling Point (oC)
The temperature at which the liquid-gas phase change occurs.


Boiling Point (K)
The temperature at which the liquid-gas phase change occurs.


Boiling Point (oF)
The temperature at which the liquid-gas phase change occurs.


Sublimation
Elements that do not possess a liquid phase at atmospheric pressure (1 atm) are described as going through a sublimation process.


Density (kgm-3)
Density is the weight of a substance that would fill 1 m3 (at 298 K unless otherwise stated).


Relative Atomic Mass
The mass of an atom relative to that of Carbon-12. This is approximately the sum of the number of protons and neutrons in the nucleus. Where more than one isotope exists the value given is the abundance weighted average.


Key Isotopes (% abundance)
An element must by definition have a fixed number of protons in its nucleus, and as such has a fixed atomic number, however variants of an element can exist with differing numbers of neutrons, and hence a different atomic masses (e.g. 12C has 6 protons and 6 neutrons and 13C has 6 protons and 7 neutrons).


CAS number
The Chemical Abstracts Service registry number is a unique identifier of a particular chemical, designed to prevent confusion arising from different languages and naming systems (where several isotopes exist, a value is presented for the most prevalent isotope).

Fact box

 
Group 14  Melting point 3825 oC, 6917 oF, 4098.15 K 
Period Boiling point Sublimes 
Block Density (kg m-3) 3513 (diamond); 2267 (graphite) 
Atomic number Relative atomic mass 12.011  
State at room temperature Solid  Key isotopes 12C, 13C, 14
Electron configuration [He] 2s22p2  CAS number 7440-44-0:1333-86-4 
ChemSpider ID 4575370 ChemSpider is a free chemical structure database
 

Uses and properties terminology


Image Explanation

Murray Robertson is the artist behind the images which make up Visual Elements. This is where the artist explains his interpretation of the element and the science behind the picture.


Natural Abundance

Where this element is most commonly found in nature.


Biological Roles

The elements role within the body of humans, animals and plants. Also functionality in medical advancements both today and years ago.


Appearance

The description of the element in its natural form.

Uses and properties

 
Image explanation

The three crowns represent the three states of Carbon in nature, plus the suggestion of a heraldic motif, emphasising Carbon’s regal status, the "King of the Elements", in the Periodic Table.

Appearance

There are a number of pure forms of this element including graphite, diamond, fullerenes and graphene.

Diamond is a colourless transparent crystalline solid, the hardest known material. Graphite is black and shiny but soft, and the nano-forms, fullerenes and graphene appear, in bulk, as black or dark brown soot-like powders

Uses

Carbon is unique among the elements in its ability to form strongly bonded chains, sealed off by hydrogen atoms. These hydrocarbons, extracted naturally as fossil fuels (coal, oil and natural gas), are mostly used, when combusted with oxygen, as a source of energy for transport, electrical energy generation and industry. A small but important fraction are used as feedstock for the petrochemical industries producing polymers, fibres, paints solvents, plastics etc. Impure carbon in the form of charcoal (from wood) and coke (from coal) is used in metal smelting, especially for the iron and steel industry. Industrial diamonds are used for cutting rocks and drilling. More recently the discovery of carbon nano-tubes, other fullerenes and atom-thin sheets of graphene are revolutionising hardware developments in the electronics industry and in nano-technology generally.

150 years ago the natural concentration of carbon dioxide in the earth’s atmosphere was 280 ppm. In 2013, as a result of combusting fossil fuels with oxygen, there were 390 ppm. Atmospheric carbon dioxide allows visible light in but prevents some infra-red escaping (the natural greenhouse effect), keeping the Earth warm enough to sustain life. However, an enhanced greenhouse effect due to human-induced rise in atmospheric carbon dioxide is being felt by living things as our climate changes.

Biological role

The carbon-based molecules of life were once thought to be obtainable only from living things – they were thought to contain a ‘spark of life’. The synthesis of urea in 1828 from inorganic reagents united the two branches of chemistry and this theory was forgotten. Living things get almost all their carbon from carbon dioxide, either from the atmosphere or dissolved in water, through photosynthesis in green plants and photosynthetic plankton. The sun’s energy splits water into oxygen (released to the atmosphere, into fresh water and the seas) and hydrogen (which joins with carbon dioxide to produce carbohydrates). 

With the addition of other elements, especially nitrogen and phosphorus, some of the carbohydrates are used to form the other monomer molecules of life, including bases and sugars for RNA and DNA, and amino acids for proteins. Life forms which do not photosynthesise have to rely on consuming other living things for their source of carbon molecules. Their digestive systems break the polymers in their diet into the simple monomers to build their own cellular structures. All these reactions need a source of energy, obtained by respiration, most commonly by allowing the oxygen previously vented to the environment by photosynthesis to rejoin the carbohydrate, thus reforming carbon dioxide and water, and making energy available for the cells. Anaerobic respiration (without oxygen) provides a small amount of energy by re-arranging the bonds in, usually, sugar molecules.

Natural abundance

Carbon is found in the sun and other stars formed from the debris of a previous supernova, and it is built up by nuclear fusion in bigger stars. It is present in the atmospheres of many planets usually as carbon dioxide (currently 390 ppm and rising for our own atmosphere). Graphite is found naturally in many locations. Diamond is found in the form of microscopic crystals in some meteorites. Natural diamonds are found in the mineral kimberlite, sources of which are in South Africa, Arkansas and elsewhere. Diamonds are now also being recovered from the ocean floor off the Cape of Good Hope. In combination, Carbon is found in all living things and as fossilised remains in the form of hydrocarbon gases, crude oil, oil shales and coal etc., and also as carbonates (eg. chalk limestone and dolomite).

 
Atomic data terminology

Atomic radius/non -bonded (Å)
Based on Van der Waals forces (where several isotopes exist, a value is presented for the most prevalent isotope). These values were calculated using a multitude of methods including crystallographic data, gas kinetic collision cross sections, critical densities, liquid state properties,for more details please refer to the CRC Handbook of Chemistry and Physics.


Electron affinity (kJ mol-1)
The energy released when an additional electron is attached to the neutral atom and a negative ion is formed (where several isotopes exist, a value is presented for the most prevalent isotope). *


Electronegativity (Pauling scale)
The degree to which an atom attracts electrons towards itself, expressed on a relative scale as a function bond dissociation energies, Ed in eV. χA - χB =(eV)-1/2sqrt(Ed(AB)-[Ed(AA)+Ed(BB)]/2), with χH set as 2.2 (where several isotopes exist, a value is presented for the most prevalent isotope).


1st Ionisation energy (kJ mol-1)
The minimum energy required to remove an electron from a neutral atom in its ground state (where several isotopes exist, a value is presented for the most prevalent isotope).


Covalent radius (Å)
The size of the atom within a covalent bond, given for typical oxidation number and coordination (where several isotopes exist, a value is presented for the most prevalent isotope). ***

Atomic data

 
Atomic radius, non-bonded (Å) 1.700 Covalent radius (Å) 0.75
Electron affinity (kJ mol-1) 121.733 Electronegativity
(Pauling scale)
2.550
Ionisation energies
(kJ mol-1)
 
1st
1086.453
2nd
2352.629
3rd
4620.467
4th
6222.711
5th
37830.615
6th
47277.133
7th
-
8th
-
 
Bond enthalpies terminology

Covalent Bonds
The strengths of several common covalent bonds.

Bond enthalpies

 
Covalent bonds
C–C  347  kJ mol -1 C=C  612  kJ mol -1 C≡C  838  kJ mol -1
C–H  413  kJ mol -1 C–H  435  kJ mol -1 C–F  467  kJ mol -1
C–F  452  kJ mol -1 C–F  485  kJ mol -1 C–Cl  346  kJ mol -1
C–Cl  327  kJ mol -1 C–Br  290  kJ mol -1 C–Br  285  kJ mol -1
C–I  228  kJ mol -1 C–I  234  kJ mol -1 C–N  286  kJ mol -1
C=N  615  kJ mol -1 C≡N  887  kJ mol -1 C–O  358  kJ mol -1
C–O  336  kJ mol -1 C=O  805  kJ mol -1 C=O  695  kJ mol -1
C=O  736  kJ mol -1 C=O  749  kJ mol -1 C≡O  1077  kJ mol -1
C–Si  307  kJ mol -1  
 

Mining/Sourcing Information

Data for this section of the data page has been provided by the British Geological Survey. To review the full report please click here or please look at their website here.


Key for numbers generated


Governance indicators

1 (low) = 0 to 2

2 (medium-low) = 3 to 4

3 (medium) = 5 to 6

4 (medium-high) = 7 to 8

5 (high) = 9


Reserve base distribution

1 (low) = 0 to 30 %

2 (medium-low) = 30 to 45 %

3 (medium) = 45 to 60 %

4 (medium-high) = 60 to 75 %

5 (high) = 75 %

(Where data are unavailable an arbitrary score of 2 was allocated. For example, Be, As, Na, S, In, Cl, Ca and Ge are allocated a score of 2 since reserve base information is unavailable. Reserve base data are also unavailable for coal; however, reserve data for 2008 are available from the Energy Information Administration (EIA).)


Production Concentration

1 (low) = 0 to 30 %

2 (medium-low) = 30 to 45 %

3 (medium) = 45 to 60 %

4 (medium-high) = 60 to 75 %

5 (high) = 75 %


Crustal Abundance

1 (low) = 100 to 1000 ppm

2 (medium-low) =10 to 100 ppm

3 (medium) = 1 to 10 ppm

4 (medium-high) = 0.1 to 1 ppm

5 (high) = 0.1 ppm

(Where data are unavailable an arbitrary score of 2 was allocated. For example, He is allocated a score of 2 since crustal abundance data is unavailable.)


Explanations for terminology


Crustal Abundance (ppm)

The abundance of an element in the Earth's crust in parts-per-million (ppm) i.e. The number of atoms of this element per 1 million atoms of crust.


Sourced

The country with the largest reserve base.


Reserve Base Distribution

This is a measure of the spread of future supplies, recording the percentage of a known resource likely to be available in the intermediate future (reserve base) located in the top three countries.


Production Concentrations

This reports the percentage of an element produced in the top three countries. The higher the value, the larger risk there is to supply.


Total Governance Factor

The World Bank produces a global percentile rank of political stability. The scoring system is given below, and the values for all three production countries were summed.


Relative Supply Risk Index

The Crustal Abundance, Reserve Base Distribution, Production Concentration and Governance Factor scores are summed and then divided by 2, to provide an overall Relative Supply Risk Index.

Supply risk

 
Coal
Scarcity factor 4.5
Country with largest reserve base USA
Crustal abundance (ppm) 200
Leading producer China
Reserve base distribution (%) 27.50
Production concentration (%) 46.10
Total governance factor(production) 8
Top 3 countries (mined)
  • 1) USA
  • 2) Russia
  • 3) China
Top 3 countries (production)
  • 1) China
  • 2) USA
  • 3) India
Diamond
Scarcity factor 4.0
Country with largest reserve base DRC
Crustal abundance (ppm) 200
Leading producer Russia
Reserve base distribution (%) 33.50
Production concentration (%) 28.60
Total governance factor(production) 7
Top 3 countries (mined)
  • 1) DRC
  • 2) Australia
  • 3) Botswana
Top 3 countries (production)
  • 1) Russia
  • 2) DRC
  • 3) Botswana
Graphite
Scarcity factor 7.0
Country with largest reserve base China
Crustal abundance (ppm) 200
Leading producer China
Reserve base distribution (%) 63.60
Production concentration (%) 81.80
Total governance factor(production) 8
Top 3 countries (mined)
  • 1) China
  • 2) Czech Republic
  • 3) India
Top 3 countries (production)
  • 1) China
  • 2) Bosnia-Herzegovina
  • 3) Brazil
 

Oxidation states and isotopes


Key for Isotopes


Half Life
  y years
  d days
  h hours
  m minutes
  s seconds
Mode of decay
  α alpha particle emission
  β negative beta (electron) emission
  β+ positron emission
  EC orbital electron capture
  sf spontaneous fission
  ββ double beta emission
  ECEC double orbital electron capture

Terminology


Common Oxidation states
The oxidation state of an atom is a measure of the degree of oxidation of an atom. It is defined as being the charge that an atom would have if all bonds were ionic. Free atoms have an oxidation state of 0, and the sum of oxidation numbers within a substance must equal the overall charge.


Important Oxidation states
The most common oxidation states of an element in its compounds.


Isotopes
Elements are defined by the number of protons in its centre (nucleus), whilst the number of neutrons present can vary. The variations in the number of neutrons will create elements of different mass which are known as isotopes.

Oxidation states and isotopes

 
Common oxidation states 4,3,2,1,0,-1,- 2,-3,-4
Isotopes Isotope Atomic mass Natural abundance (%) Half life Mode of decay
  12C 12 98.93
  13C 13.003 1.07
  14C 14.003 - 5717 y  β- 
 

Pressure and temperature - advanced terminology


Molar Heat Capacity (J mol-1 K-1)

Molar heat capacity is the energy required to heat a mole of a substance by 1 K.


Young's modulus (GPa)

Young's modulus is a measure of the stiffness of a substance, that is, it provides a measure of how difficult it is to extend a material, with a value given by the ratio of tensile strength to tensile strain.


Shear modulus (GPa)

The shear modulus of a material is a measure of how difficult it is to deform a material, and is given by the ratio of the shear stress to the shear strain.


Bulk modulus (GPa)

The bulk modulus is a measure of how difficult to compress a substance. Given by the ratio of the pressure on a body to the fractional decrease in volume.


Vapour Pressure (Pa)

Vapour pressure is the measure of the propensity of a substance to evaporate. It is defined as the equilibrium pressure exerted by the gas produced above a substance in a closed system.

Pressure and temperature data – advanced

 
Molar heat capacity
(J mol-1 K-1)
6.155 (diamond); 8.517 (graphite) Young's modulus (GPa) 1050 (diamond)
Shear modulus (GPa) 478 (diamond) Bulk modulus (GPa) 542 (diamond);33 (graphite)
Vapour pressure  
Temperature (K)
400 600 800 1000 1200 1400 1600 1800 2000 2200 2400
Pressure (Pa)
- - - - - - - - - - -
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History

Carbon occurs naturally as anthracite (a type of coal), graphite, and diamond. More readily available historically was soot or charcoal. Ultimately these various materials were recognised as forms of the same element. Not surprisingly, diamond posed the greatest difficulty of identification. Naturalist Giuseppe Averani and medic Cipriano Targioni of Florence were the first to discover that diamonds could be destroyed by heating. In 1694 they focussed sunlight on to a diamond using a large magnifying glass and the gem eventually disappeared. Pierre-Joseph Macquer and Godefroy de Villetaneuse repeated the experiment in 1771. Then, in 1796, the English chemist Smithson Tennant finally proved that diamond was just a form of carbon by showing that as it burned it formed only CO2.

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Podcasts

Listen to Carbon Podcast
Transcript :

Chemistry in Its Element - Carbon


 

  (Promo)

 

You're listening to Chemistry in its element brought to you by Chemistry World, the magazine of the Royal Society of Chemistry

(End promo)

 

Chris Smith

 

Hello, this week to the element that unites weddings, wars, conflicts and cremations and to explain how, here's Katherine Holt.

 

Katherine Holt

 

Any chemist could talk for days about carbon. It is after all an everyday, run-of 

-the-mill, found-in-pretty-much-everything, ubiquitous element for us carbon-based life forms. An entire branch of chemistry is devoted to its reactions. 

 

In its elemental form it throws up some surprises in the contrasting and fascinating forms of its allotropes. It seems that every few years a new form of carbon comes into fashion - A few years ago carbon nanotubes were the new black (or should I say 'the new bucky-ball') - but graphene is oh-so-now!  

 

But today I'm going to talk about the most glamorous form that carbon can take - diamond.   For millennia diamond has been associated with wealth and riches, as it can be cut to form gemstones of high clarity, brilliance and permanence. Diamonds truly are forever! Unfortunately, diamond also has a dark side - the greed that diamond induces leads to the trade of so-called 'conflict diamonds' that support and fund civil wars.  

 

Mans desire for diamond has led alchemists and chemists over many centuries to attempt to synthesise the material. After many fraudulous early claims diamond was finally synthesised artificially in the 1950s. Scientists took their inspiration from nature by noting the conditions under which diamond is formed naturally, deep under the earth's crust. They therefore used high temperatures (over 3000oC) and high pressures (>130 atms) to turn graphite into carbon. This was an impressive feat, but the extreme conditions required made it prohibitively expensive as a commercial process. Since then the process has been refined and the use of metal catalysts means that lower temperatures and pressures are required. Crystals of a few micron diameter can be formed in a few minutes, but a 2-carat gem quality crystal may takes several weeks. 

 

These techniques mean its now possible to artificially synthesise gemstone quality diamonds which, without the help of specialist equipment, cannot be distinguished from natural diamond. It goes without saying that this could cause headaches among the companies that trade in natural diamond! It is possible to turn any carbon based material into a diamond - including hair and even cremating remains! Yes - you can turn your dearly departed pet into a diamond to keep forever if you want to!    Artificial diamonds are chemically and physical identical to the natural stones and come without the ethical baggage. However, psychologically their remains a barrier - if he really loves you he'd buy you real diamond - wouldn't he? 

 

From the perspective of a chemist, materials scientist or engineer we soon run out of superlatives while describing the amazing physical, electronic and chemical properties of diamond. It is the hardest material known to man and more or less inert - able to withstand the strongest and most corrosive of acids.   It has the highest thermal conductivity of any material, so is excellent at dissipating heat. That is why diamonds are always cold to the touch.   Having a wide band gap, it is the text book example of an insulating material and for the same reason has amazing transparency and optical properties over the widest range of wavelengths of any solid material.   

 

You can see then why diamond is exciting to scientists. Its hardness and inert nature suggest applications as protective coatings against abrasion, chemical corrosion and radiation damage. Its high thermal conductivity and electrical insulation cry out for uses in high powered electronics. Its optical properties are ideal for windows and lenses and its biocompatibility could be exploited in coatings for implants. 

 

These properties have been known for centuries - so why then is the use of diamond not more widespread? The reason is that natural diamond and diamonds formed by high pressure high temperature synthesis are of limited size - usually a few millimeters at most, and can only be cut and shaped along specific crystal faces. This prevents the use of diamond in most of the suggested applications.

 

However, about 20 years ago scientists discovered a new way to synthesise diamond this time under low pressure, high temperature conditions, using chemical vapour deposition.   If one were to consider the thermodynamic stability of carbon, we would find that at room temperature and pressure the most stable form of carbon is actually graphite, not diamond. Strictly speaking, from a purely energetic or thermodynamic point of view, diamond should spontaneously turn into graphite under ambient conditions! Clearly this doesn't happen and that is because the energy required to break the strong bonds in diamond and rearrange them to form graphite requires a large input of energy and so the whole process is so slow that on the scale of millennia the reaction does not take place. 

 

  It is this metastability of diamond that is exploited in chemical vapour deposition. A gas mixture of 99 % hydrogen and 1 % of methane is used and some activation source like a hot filament employed to produce highly reactive hydrogen and methyl radicals. The carbon-based molecules then deposit on a surface to form a coating or thin film of diamond. Actually both graphite and diamond are initially formed, but under these highly reactive conditions, the graphitic deposits are etched off the surface, leaving only the diamond. The films are polycrystalline, consisting of crystallites in the micron size range so lack the clarity and brilliance of gemstone diamond. While they may not be as pretty, these diamond films can be deposited on a range of surfaces of different size and shapes and so hugely increase the potential applications of diamond. Challenges still remain to understand the complex chemistry of the intercrystalline boundaries and surface chemistry of the films and to learn how best to exploit them. This material will be keeping chemists, materials scientists, physicists and engineers busy for many years to come.   However, at present we can all agree that there is more to diamond than just a pretty face! 

 

Chris Smith

 

Katherine Holt extolling the virtues of the jewel in carbon's crown.   Next week we're heading to the top of group one to hear the story of the metal that revolutionised the treatment of manic depression.

 

Matt Wilkinson 

 

Its calming effect on the brain was first noted in 1949, by an Australian doctor, John Cade, of the Victoria Department of Mental Hygiene. He had injected guinea pigs with a 0.5% solution of lithium carbonate, and to his surprise these normally highly-strung animals became docile.   Cade then gave his most mentally disturbed patient an injection of the same solution. The man responded so well that within days he was transferred to a normal hospital ward and was soon back at work.

 

Chris Smith

 

And it's still used today although despite 50 years of medical progress we still don't know how it works.   That was Matt Wilkinson who will be here with the story of Lithium on next week's Chemistry in its Element, I do hope you can join us.   I'm Chris Smith, thank you for listening and goodbye.    

 

(Promo)

 

Chemistry in its elementis brought to you by the Royal Society of Chemistry and produced by thenakedscientists dot com. There's more information and other episodes of Chemistry in its element on our website at chemistryworld dot org forward slash elements. 

 

(End promo)

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Resources

Description :
In this experiment, carbon that has undergone special treatment to make it into decolourising carbon is shown to remove colour and odour from various solutions. This form of carbon is sometimes calle...
Description :
Some reactions of carbon dioxide
Description :
When carbon dioxide reacts with water a weak acid is formed. Carbon dioxide is present in exhaled breath. Observing a colour change using an acid-base indicator shows the reaction between carbon diox...
Description :
In each of the two experiments, illustrating the idea of competition between metals and carbon, students heat a metal oxide with powdered charcoal. If the carbon is more reactive than the metal it wi...
Description :
A video explaining about types of carbon and particularly about graphene - Nobel prize winning discovery, and its uses. It also covers how to make your own solar cell. A gridlocks allotropes of carbo...
Description :
The discovery of buckminsterfullerene, the third allotrope of carbon.
 

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References

 
Images:  Visual Elements © Murray Robertson 2011
Mining and Sourcing data:  British Geological Survey – natural environment research council.
Text:  John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Additional information for platinum, gold, neodymium and dysprosium obtained from Material Value Consultancy Ltd www.matvalue.com
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.