Periodic Table > Hassium
 

Terminology


Allotropes
Some elements exist in several different structural forms, these are called allotropes.


For more information on Murray Robertson’s image see Uses and properties facts below.

 

Fact box terminology


Group
Elements appear in columns or ‘groups’ in the periodic table. Members of a group typically have similar properties and electron configurations in their outer shell.


Period
Elements are laid out into rows or ‘periods’ so that similar chemical behaviour is observed in columns.


Block
Elements are organised into blocks by the orbital type in which the outer electrons are found. These blocks are named for the characteristic spectra they produce: sharp, principal, diffuse, and fundamental.


Atomic Number
The number of protons in the nucleus.


Atomic Radius/non -bonded (Å)
based on Van der Waals forces (where several isotopes exist, a value is presented for the most prevalent isotope). These values were calculated using a multitude of methods including crystallographic data, gas kinetic collision cross sections, critical densities, liquid state properties, for more details please refer to the CRC Handbook of Chemistry and Physics.


Electron Configuration
The arrangements of electrons above the last (closed shell) noble gas.


Isotopes
Elements are defined by the number of protons in its centre (nucleus), whilst the number of neutrons present can vary. The variations in the number of neutrons will create elements of different mass which are known as isotopes.


Melting Point (oC)
The temperature at which the solid-liquid phase change occurs.


Melting Point (K)
The temperature at which the solid-liquid phase change occurs.


Melting Point (oF)
The temperature at which the solid-liquid phase change occurs.


Boiling Point (oC)
The temperature at which the liquid-gas phase change occurs.


Boiling Point (K)
The temperature at which the liquid-gas phase change occurs.


Boiling Point (oF)
The temperature at which the liquid-gas phase change occurs.


Sublimation
Elements that do not possess a liquid phase at atmospheric pressure (1 atm) are described as going through a sublimation process.


Density (g cm-3)
Density is the mass of a substance that would fill 1 cm3 at room temperature.


Relative Atomic Mass
The mass of an atom relative to that of Carbon-12. This is approximately the sum of the number of protons and neutrons in the nucleus. Where more than one isotope exists the value given is the abundance weighted average.


Key Isotopes (% abundance)
An element must by definition have a fixed number of protons in its nucleus, and as such has a fixed atomic number, however variants of an element can exist with differing numbers of neutrons, and hence a different atomic masses (e.g. 12C has 6 protons and 6 neutrons and 13C has 6 protons and 7 neutrons).


CAS number
The Chemical Abstracts Service registry number is a unique identifier of a particular chemical, designed to prevent confusion arising from different languages and naming systems (where several isotopes exist, a value is presented for the most prevalent isotope).

Fact box

 
Group Melting point Unknown 
Period Boiling point Unknown 
Block Density (g cm-3) Unknown 
Atomic number 108  Relative atomic mass 265.13  
State at room temperature Solid  Key isotopes 270Hs 
Electron configuration [Rn] 5f146d67s2  CAS number 54037-57-9 
ChemSpider ID - ChemSpider is a free chemical structure database
 

Uses and properties terminology


Image Explanation

Murray Robertson is the artist behind the images which make up Visual Elements. This is where the artist explains his interpretation of the element and the science behind the picture.


Natural Abundance

Where this element is most commonly found in nature.


Biological Roles

The elements role within the body of humans, animals and plants. Also functionality in medical advancements both today and years ago.


Appearance

The description of the element in its natural form.

Uses and properties

 
Image explanation
The image is inspired by the coat of arms for the German state of Hesse, which gives the element its name.
Appearance
A highly radioactive metal, of which only a few atoms have ever been made.
Uses
At present it is only used in research.
Biological role
Hassium has no known biological role.
Natural abundance
Hassium does not occur naturally and it will probably never be isolated in observable quantities. It is created by bombarding lead with iron atoms
 
Atomic data terminology

Atomic radius/non -bonded (Å)
Based on Van der Waals forces (where several isotopes exist, a value is presented for the most prevalent isotope). These values were calculated using a multitude of methods including crystallographic data, gas kinetic collision cross sections, critical densities, liquid state properties,for more details please refer to the CRC Handbook of Chemistry and Physics.


Electron affinity (kJ mol-1)
The energy released when an additional electron is attached to the neutral atom and a negative ion is formed (where several isotopes exist, a value is presented for the most prevalent isotope). *


Electronegativity (Pauling scale)
The degree to which an atom attracts electrons towards itself, expressed on a relative scale as a function bond dissociation energies, Ed in eV. χA - χB =(eV)-1/2sqrt(Ed(AB)-[Ed(AA)+Ed(BB)]/2), with χH set as 2.2 (where several isotopes exist, a value is presented for the most prevalent isotope).


1st Ionisation energy (kJ mol-1)
The minimum energy required to remove an electron from a neutral atom in its ground state (where several isotopes exist, a value is presented for the most prevalent isotope).


Covalent radius (Å)
The size of the atom within a covalent bond, given for typical oxidation number and coordination (where several isotopes exist, a value is presented for the most prevalent isotope). ***

Atomic data

 
Atomic radius, non-bonded (Å) Unknown Covalent radius (Å) 1.34
Electron affinity (kJ mol-1) Unknown Electronegativity
(Pauling scale)
Unknown
Ionisation energies
(kJ mol-1)
 
1st
-
2nd
-
3rd
-
4th
-
5th
-
6th
-
7th
-
8th
-
 

Mining/Sourcing Information

Data for this section of the data page has been provided by the British Geological Survey. To review the full report please click here or please look at their website here.


Key for numbers generated


Governance indicators

1 (low) = 0 to 2

2 (medium-low) = 3 to 4

3 (medium) = 5 to 6

4 (medium-high) = 7 to 8

5 (high) = 9


Reserve distribution (%)

1 (low) = 0 to 30 %

2 (medium-low) = 30 to 45 %

3 (medium) = 45 to 60 %

4 (medium-high) = 60 to 75 %

5 (high) = 75 %

(Where data are unavailable an arbitrary score of 2 was allocated. For example, Be, As, Na, S, In, Cl, Ca and Ge are allocated a score of 2 since reserve base information is unavailable. Reserve base data are also unavailable for coal; however, reserve data for 2008 are available from the Energy Information Administration (EIA).)


Production Concentration

1 (low) = 0 to 30 %

2 (medium-low) = 30 to 45 %

3 (medium) = 45 to 60 %

4 (medium-high) = 60 to 75 %

5 (high) = 75 %


Crustal Abundance

1 (low) = 100 to 1000 ppm

2 (medium-low) =10 to 100 ppm

3 (medium) = 1 to 10 ppm

4 (medium-high) = 0.1 to 1 ppm

5 (high) = 0.1 ppm

(Where data are unavailable an arbitrary score of 2 was allocated. For example, He is allocated a score of 2 since crustal abundance data is unavailable.)


Explanations for terminology


Crustal Abundance (ppm)

The abundance of an element in the Earth's crust in parts-per-million (ppm) i.e. The number of atoms of this element per 1 million atoms of crust.


Sourced

The country with the largest reserve base.


Reserve distribution (%)

This is a measure of the spread of future supplies, recording the percentage of a known resource likely to be available in the intermediate future (reserve base) located in the top three countries.


Production Concentrations

This reports the percentage of an element produced in the top three countries. The higher the value, the larger risk there is to supply.


Political stability of top producer

The World Bank produces a global percentile rank of political stability. The scoring system is given below, and the values for all three production countries were summed.


Relative Supply Risk Index

The Crustal Abundance, Reserve distribution (%), Production Concentration and Governance Factor scores are summed and then divided by 2, to provide an overall Relative Supply Risk Index.

Supply risk

 
Relative supply risk Unknown
Crustal abundance (ppm) Unknown
Recycling rate (%) Unknown
Substitutability Unknown
Production concentration (%) Unknown
Reserve distribution (%) Unknown
Top 3 producers
  • Unknown
Top 3 reserve holders
  • Unknown
Political stability of top producer Unknown
Political stability of top reserve holder Unknown
 

Oxidation states and isotopes


Key for Isotopes


Half Life
  y years
  d days
  h hours
  m minutes
  s seconds
Mode of decay
  α alpha particle emission
  β negative beta (electron) emission
  β+ positron emission
  EC orbital electron capture
  sf spontaneous fission
  ββ double beta emission
  ECEC double orbital electron capture

Terminology


Common Oxidation states
The oxidation state of an atom is a measure of the degree of oxidation of an atom. It is defined as being the charge that an atom would have if all bonds were ionic. Free atoms have an oxidation state of 0, and the sum of oxidation numbers within a substance must equal the overall charge.


Important Oxidation states
The most common oxidation states of an element in its compounds.


Isotopes
Elements are defined by the number of protons in its centre (nucleus), whilst the number of neutrons present can vary. The variations in the number of neutrons will create elements of different mass which are known as isotopes.

Oxidation states and isotopes

 
Common oxidation states Unknown
Isotopes Isotope Atomic mass Natural abundance (%) Half life Mode of decay
  270Hs 270.135 - 0.3 m  α 
 

Pressure and temperature - advanced terminology


Specific heat capacity (J kg-1 K-1)

Specific heat capacity is the amount of energy needed to change the temperature of a kilogram of a substance by 1 K.


Young's modulus (GPa)

Young's modulus is a measure of the stiffness of a substance, that is, it provides a measure of how difficult it is to extend a material, with a value given by the ratio of tensile strength to tensile strain.


Shear modulus (GPa)

The shear modulus of a material is a measure of how difficult it is to deform a material, and is given by the ratio of the shear stress to the shear strain.


Bulk modulus (GPa)

The bulk modulus is a measure of how difficult to compress a substance. Given by the ratio of the pressure on a body to the fractional decrease in volume.


Vapour Pressure (Pa)

Vapour pressure is the measure of the propensity of a substance to evaporate. It is defined as the equilibrium pressure exerted by the gas produced above a substance in a closed system.

Pressure and temperature data – advanced

 
Specific heat capacity
(J kg-1 K-1)
Unknown Young's modulus (GPa) Unknown
Shear modulus (GPa) Unknown Bulk modulus (GPa) Unknown
Vapour pressure  
Temperature (K)
400 600 800 1000 1200 1400 1600 1800 2000 2200 2400
Pressure (Pa)
- - - - - - - - - - -
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History

There are 15 known isotopes of hassium with mass numbers 263 to 277, with isotope-276 having the longest half-life of 1.1 hour. The first attempt to synthesize element 108 took place in 1978 at Russia’s Joint Institute for Nuclear Research (JINR) in Dubna, where a team headed by Yuri Oganessian and Vladimir Utyonkov bombarded radium with calcium and got isotope 270. In 1983, they obtained other isotopes: by bombarding bismuth with manganese they got isotope 263, by bombarding californium with neon they got isotope 270, and by bombarding lead with iron they got isotope 264.


In 1984, at Germany’s Gesellschaft für Schwerionenforschung (GSI) in Darmstadt, a team headed by Peter Armbruster and Gottfried Münzenberg bombarded lead with iron and synthesised isotope 265. Their data which was considered more reliable than that from JINR and so they were allowed to name the element which they did, basing it on Hesse, the state in which the GSI is located.

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Podcasts

Listen to Hassium Podcast
Transcript :

Chemistry in its element - hassium


(Promo) 

You're listening to Chemistry in its element brought to you by Chemistry World, the magazine of the Royal Society of Chemistry

(End promo) 

Meera Senthilingam

 

This week we are going back in time to resolve an identity crisis. Here's Anna Lewcock.

 

Anna Lewcock

 

Do you remember the 80s? The leg warmers, the big hair, the shoulder pads? Many fashion crimes were committed and statements made as a generation fought to carve out its identity.

 

Looking back on those photos a couple of decades down the line, some might wish they hadn't fought so hard. But it's not just rebellious teenagers or disillusioned 40-somethings that suffer identity crises - elements can too.

 

In 1984, alongside the introduction of the first Apple Mac computers, GCSEs and the discovery of the Aids virus, a team of researchers in Germany managed to synthesise element 108 for the very first time.

 

Element 108, today known as hassium, is one of the transactinides and it's most stable isotope - hassium-277 - has a half life of around 12 minutes. 

 

By bombarding lead with iron ions in a linear accelerator, a team lead by Peter Armbruster and Gottfried Münzenber at the Heavy Ion Research Laboratory in Darmstadt, Germany, managed to make three atoms of hassium-265, an isotope with the princely half-life of about 2 milliseconds. 

 

There are only a handful of research centres that have the appropriate equipment to make these superheavy elements, and on occasion more than one institution would claim to be the first to have made an element, and therefore claim the right to name it. Unfortunately, this caused a fair amount of arguing and confusion when several elements ended up with more than one name.

 

Perhaps most controversial were the American suggestion for element 106 - seaborgium - which was initially objected to on the grounds that Glenn Seaborg, the Nobel prize-winning chemist the element was to be named after, was still alive (which is against the rules according to element naming guidelines) - and then there was the Russian proposal of kurchatovium for element 104, named after nuclear physicist Igor Kurchatov, who led the Soviet project to develop an atomic bomb.

 

To deal with this, Iupac, the  international body responsible for naming elements, decided that elements from atomic number 104 onwards would have temporary names to act as place holders while the wrangling over the official names was sorted out.

 

These temporary names were based on the Latin for the relevant atomic number - so unnilquandium for 104, unnilpentium for 105 and so on. Element 108 was therefore known as unniloctium. The element's German discoverers wanted the new element to be called hassium, after the Latin name for the German state of Hesse, where their research centre was based.

 

However, after much talk, Iupac in 1994 decided to call element 108 Hahnium, after Nobel-prize winning chemist Otto Hahn. Hahnium had in fact been the American suggestion for element 105 (now known as dubnium - which had itself been a previous suggestion for element 104). I told you it got messy.

 

But, by 1997 Iupac had changed its mind again, finally deciding to go with hassium for element 108 around the time of the discovery's 13th anniversary. 

 

As we tipped over into the 21st century the first measurements of hassium's chemical properties were finally reported. By this time the discovery was approaching its 18th birthday, and as an unstable element that reinvented itself in next to no time, it proved just as hard to characterise as any teenager.

 

Any lingering hard feelings over the naming process were put to one side as an international team of researchers from across the globe (including scientists from Russia, Germany and the US) came together to try and figure out what hassium was all about. 

 

By bombarding curium-248 with energetic magnesium-26 ions, the team formed seven hassium atoms, generated as 269Hs and 270Hs. These two isotopes have half lives of around 10 seconds and 4 seconds respectively - long enough for the researchers to get a good look at some of its chemical properties.

 

Theoretical calculations suggested that hassium should have similar chemical properties to the group 8 elements such as osmium and ruthenium, for example quickly reacting with oxygen to form hassium tetroxide. 

 

When the researchers tested this theory with their seven atoms, they found that they did indeed immediately oxidise to form seven molecules of hassium tetroxide, providing strong evidence that the element has similar properties to osmium, and cementing its position in the periodic table.

 

So it turns out hassium doesn't have an identity crisis after all - it knew where it would fit all along.

 

Meera Senthilingam

 

So elements, like people, like to fit in as well. And hassium it seems has a firm place in the periodic table. That was Chemistry World's Anna Lewcock with the reassuring chemistry of hassium. Now next week, an element whose placing is still in question.

 

Eric Scerri

 

Starting in 1969 the chemical properties of lawrencium began to be explored.   In the gas phase the element forms a tri-chloride.   Studies of its aqueous phase also show that it displays tri-valency.   You might think that these experiments and others like it would have settled the precise position of lawrencium in the periodic table but this has not been the case.

 

Meera Senthilingam

 

And to find out how the positioning of lawrencium was decided and whether it stayed that way, join UCLA scientist and author Eric Scerri for the last of our chemical elements. But not to worry, after the elements we'll be bringing you the exciting chemistry of compounds in a brand new series of Chemistry in its element. But until next week's finale, thank you for listening, I'm Meera Senthilingam.

 

(Promo) 

Chemistry in its element is brought to you by the Royal Society of Chemistry and produced by thenakedscientists dot com. There's more information and other episodes of Chemistry in its element on our website at chemistryworld dot org forward slash elements. 

(End promo)

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References

 
Images:  Visual Elements © Murray Robertson 2011
Mining and Sourcing data:  British Geological Survey – natural environment research council.
Text:  John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Additional information for platinum, gold, neodymium and dysprosium obtained from Material Value Consultancy Ltd www.matvalue.com
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.