| Group | 1 | Melting point | 63.5 oC, 146.3 oF, 336.65 K |
| Period | 4 | Boiling point | 759 oC, 1398.2 oF, 1032.15 K |
| Block | s | Density (kg m-3) | 862 |
| Atomic number | 19 | Relative atomic mass | 39.098 |
| State at room temperature | Solid | Key isotopes | 39K |
| Electron configuration | [Ar] 4s1 | CAS number | 7440-09-7 |
| ChemSpider ID | 4575326 | ChemSpider is a free chemical structure database | |
Image explanation
The image features the alchemical symbol for Potash from which it was first isolated. Click through to the alchemical symbol for Potassium and other elements.
Appearance
A soft, silvery metal that tarnishes within minutes. In water, it reacts rapidly and often explosively to release hydrogen, which burns with a lilac flame. There are deposits of billions of tonnes of potassium chloride throughout the world and mining extracts about 50 million tonnes a year, mainly for use in fertilisers. Potassium is essential to all living things, and the average human consumes up to 7 grammes a day, and has a store of some 140 grammes in the human body, mainly in the muscles. Normal diets contain enough potassium, but some foods such as instant coffee, sardines, nuts, raisins, potatoes and chocolate have more than average.
Uses
The greatest demand for potassium compounds is in fertilisers. Many other potassium salts are of great importance, including the nitrate, carbonate, chloride, bromide, cyanide and sulphate.
Biological role
Potassium is essential to life, and non-toxic. Potassium is essential to all living things, and the average human consumes up to 7 grammes a day, and has a store of some 140 grammes in the human body, mainly in the muscles. Normal diets contain enough potassium, but some foods such as instant coffee, sardines, nuts, raisins, potatoes and chocolate have more than average.
One of its natural isotopes is radioactive, and although this radioactivity is mild, it may be one natural cause of genetic mutation in man.
Natural abundance
Potassium is the seventh most abundant metal and makes up 2.4% by mass of the Earth’s crust. There are deposits of billions of tonnes of potassium chloride throughout the world and mining extracts about 50 million tonnes a year, mainly for use in fertilisers. Most minerals containing potassium are sparingly soluble and the metal is difficult to obtain from them. Certain minerals, however, such as sylvite, sylvinite and carnallite, are found in deposits formed by evaporation of old seas or lakes, and potassium salts can be easily recovered from these. Potassium is also found in the ocean in small amounts compared with sodium.
| Atomic radius, non-bonded (Å) | 2.750 | Covalent radius (Å) | 2 |
| Electron affinity (kJ mol-1) | 48.367 |
Electronegativity (Pauling scale) |
0.820 |
|
Ionisation energies (kJ mol-1) |
1st
418.810
2nd
3051.829
3rd
4419.604
4th
5876.917
5th
7975.471
6th
9590.635
7th
11342.807
8th
14943.637
|
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| Covalent bonds |
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| Common oxidation states | 1 | ||||
| Isotopes | Isotope | Atomic mass | Natural abundance (%) | Half life | Mode of decay |
| 39K | 38.964 | 93.258 | - | - | |
| 40K | 39.964 | 0.012 | 1.248 x 109 y | β- | |
| - | β+ | ||||
| 41K | 40.962 | 6.73 | - | - | |
|
Molar heat capacity (J mol-1 K-1) |
29.6 | Young's modulus (GPa) | Unknown | |||||||||||
| Shear modulus (GPa) | Unknown | Bulk modulus (GPa) | 3.1 | |||||||||||
| Vapour pressure | ||||||||||||||
| Temperature (K) |
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| Pressure (Pa) |
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Images: Visual Elements © Murray Robertson 2011
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
