| Group | 2 | Melting point | 842 oC, 1547.6 oF, 1115.15 K |
| Period | 4 | Boiling point | 1484 oC, 2703.2 oF, 1757.15 K |
| Block | s | Density (kg m-3) | 1530 |
| Atomic number | 20 | Relative atomic mass | 40.078 |
| State at room temperature | Solid | Key isotopes | 40Ca |
| Electron configuration | [Ar] 4s2 | CAS number | 7440-70-2 |
| ChemSpider ID | 4573905 | ChemSpider is a free chemical structure database | |
Image explanation
The spiral shell and bones reflect the essential presence of calcium in all living things.
Appearance
A silvery white, soft metal that reacts with water. It is used in alloys and in the extraction of other metals, such as thorium, from their ores. Calcium is one of the most abundant elements on Earth. There are vast deposits of limestone (calcium carbonate); when heated in kilns, this gives off carbon dioxide gas to leave quicklime (calcium oxide). This reacts violently with water to give slaked lime (calcium hydroxide). This is used to make cement, as a soil conditioner and in water treatment to reduce acidity, and in the chemicals industry. Calcium is essential to all living things, and calcium phosphate is the main component of bone. The average human contains about 1 kilogramme of calcium. Children and pregnant women are encouraged to eat foods rich in calcium, such as cheese, milk and white bread, to promote the growth of healthy teeth and bones.
Uses
Calcium and its compounds are widely used. It is used in alloys and in the extraction of other metals, such as thorium, from their ores. There are vast deposits of limestone (calcium carbonate); when heated in kilns, this gives off carbon dioxide gas to leave quicklime (calcium oxide). This reacts violently with water to give slaked lime (calcium hydroxide). This is used to make cement, as a soil conditioner and in water treatment to reduce acidity, and in the chemicals industry. It has the advantage of being cheap and readily available. When mixed with sand it takes up carbon dioxide from the air and hardens as mortar and plaster. Calcium from limestone is an important constituent of Portland Cement. Calcium is also used as a reducing agent in preparing other metals such as thorium and uranium, and as an alloying agent for aluminium, beryllium, copper, lead and magnesium alloys.
Biological role
Calcium is essential to all living things, and calcium phosphate is the main component of bone. The average human contains about 1 kilogramme of calcium. Children and pregnant women are encouraged to eat foods rich in calcium, such as cheese, milk and white bread, to promote the growth of healthy teeth and bones.
Natural abundance
Calcium is the fifth most abundant metal in the Earth’s crust, greater than 3% by mass. It is not found uncombined in nature, but occurs abundantly as limestone (calcium carbonate), gypsum (calcium sulphate), fluorite (calcium fluoride) and apatite (calcium chloro- or fluoro-phosphate). Calcium is prepared commercially by the electrolysis of fused calcium chloride to which calcium fluoride is added to lower the melting point.
| Atomic radius, non-bonded (Å) | 2.310 | Covalent radius (Å) | 1.74 |
| Electron affinity (kJ mol-1) | 2.368 |
Electronegativity (Pauling scale) |
1.000 |
|
Ionisation energies (kJ mol-1) |
1st
589.830
2nd
1145.446
3rd
4912.364
4th
6490.563
5th
8153.004
6th
10495.666
7th
12272.925
8th
14206.489
|
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|
|
| Common oxidation states | 2 | ||||
| Isotopes | Isotope | Atomic mass | Natural abundance (%) | Half life | Mode of decay |
| 40Ca | 39.963 | 96.941 | 5.92 x 1021 y | EC-EC | |
| 42Ca | 41.959 | 0.647 | - | - | |
| 43Ca | 42.959 | 0.135 | - | - | |
| 44Ca | 43.955 | 2.086 | - | - | |
| 46Ca | 45.954 | 0.004 | > 0.4 x 1016 y | β-β- | |
| 48Ca | 47.953 | 0.187 | 4.3 x 1019 y | β-β- | |
| > 7.1 x 1019 y | β- | ||||
|
Molar heat capacity (J mol-1 K-1) |
25.929 | Young's modulus (GPa) | Unknown | |||||||||||
| Shear modulus (GPa) | Unknown | Bulk modulus (GPa) | 17.2 | |||||||||||
| Vapour pressure | ||||||||||||||
| Temperature (K) |
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| Pressure (Pa) |
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Images: Visual Elements © Murray Robertson 2011
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
