| Group | 14 | Melting point | 938.25 oC, 1720.85 oF, 1211.4 K |
| Period | 4 | Boiling point | 2833 oC, 5131.4 oF, 3106.15 K |
| Block | p | Density (kg m-3) | 5323 |
| Atomic number | 32 | Relative atomic mass | 72.63 |
| State at room temperature | Solid | Key isotopes | 73Ge, 74Ge |
| Electron configuration | [Ar] 3d104s24p2 | CAS number | 7440-56-4 |
| ChemSpider ID | 4885606 | ChemSpider is a free chemical structure database | |
Image explanation
Germanium was used in early transistors similar to the one featured here.
Appearance
A silvery semi-metal element used in semi-conductors and speciality glass for infrared devices. Germanium ores are very rare, and the element is recovered as a by-product of zinc and copper refining. Our daily diet may contain as much as 1 milligramme, but theories that germanium is important to our health have been discredited.
Uses
Germanium is a very important semiconductor. The pure element is doped with arsenic, gallium or other elements and used as a transistor in thousands of electronic applications. Germanium is also finding use as an alloying agent, in fluorescent lamps and as a catalyst. Both germanium and germanium oxide are transparent to infrared radiation and so are used in infrared spectroscopes. Germanium oxide has a high index of refraction and dispersion and is used in wide-angle camera lenses and microscope objectives.
Biological role
Germanium has no known biological role. It is non-toxic. Certain germanium compounds have low mammalian toxicity but marked activity against some bacteria, which has stimulated interest in their use in pharmaceutical products.
Natural abundance
Germanium is found in small quantities in the minerals germanite and argyrodite. It is also present in zinc ores, and commercial production of germanium is by processing zinc smelter flue dust. It can also be recovered from the by-products of combustion of certain coals.
| Atomic radius, non-bonded (Å) | 2.110 | Covalent radius (Å) | 1.2 |
| Electron affinity (kJ mol-1) | 118.966 |
Electronegativity (Pauling scale) |
2.010 |
|
Ionisation energies (kJ mol-1) |
1st
762.176
2nd
1537.455
3rd
3302.121
4th
4410.640
5th
9021.372
6th
-
7th
-
8th
-
|
||
| Covalent bonds |
|
|
|
| Common oxidation states | 4 | ||||
| Isotopes | Isotope | Atomic mass | Natural abundance (%) | Half life | Mode of decay |
| 70Ge | 69.924 | 20.38 | - | - | |
| 72Ge | 71.922 | 27.31 | - | - | |
| 73Ge | 72.923 | 7.76 | > 1.8 x 1023 y | β- | |
| 74Ge | 73.921 | 36.72 | - | - | |
| 76Ge | 75.921 | 7.83 | 1.6 X 1021 y | β-β- | |
|
Molar heat capacity (J mol-1 K-1) |
23.222 | Young's modulus (GPa) | Unknown | |||||||||||
| Shear modulus (GPa) | Unknown | Bulk modulus (GPa) | Unknown | |||||||||||
| Vapour pressure | ||||||||||||||
| Temperature (K) |
|
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| Pressure (Pa) |
|
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Videos of the elements. Additional videos will be coming in 2012.
Images: Visual Elements © Murray Robertson 2011
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
