| Group | 15 | Melting point | 616 oC, 1140.8 oF, 889.15 K |
| Period | 4 | Boiling point | Sublimes |
| Block | p | Density (kg m-3) | 5776 |
| Atomic number | 33 | Relative atomic mass | 74.922 |
| State at room temperature | Solid | Key isotopes | 75As |
| Electron configuration | [Ar] 3d104s24p3 | CAS number | 7440-38-2 |
| ChemSpider ID | 4514330 | ChemSpider is a free chemical structure database | |
Image explanation
Prawns are known to contain quite high levels of arsenic. Click through to the alchemical symbol for Arsenic and other elements.
Appearance
Although it is now strongly linked with poison, arsenic was once used widely as a medicine. Dr Fowler’s Solution (potassium arsenate dissolved in water) was a popular cure-all tonic in Victorian times - even Charles Dickens used it. Arsenic compounds are still employed in making special glass and semi-conductors (gallium arsenide), preserving wood and, in some countries, to fatten poultry and pigs. Nowadays its use is strictly controlled, although some scientists claim it is an essential element in our diet in very low doses. Some foods such as prawns contain a surprising amount of arsenic.
Uses
Arsenic is used in bronzing, pyrotechnics and for hardening shot. It is increasingly being used as a doping agent in solid state devices.
Biological role
Arsenic may be an essential element, but it is certainly toxic in small doses and also a suspected carcinogen. Calcium and lead arsenic compounds are used as poisons for vermin.
Natural abundance
The most common arsenic-containing mineral is mispickel, and others include realgar and orpiment. Arsenic can also be found in the native state. It can be obtained from mispickel by heating, which causes the arsenic to sublime and leaves the iron(II) sulfide.
| Atomic radius, non-bonded (Å) | 1.850 | Covalent radius (Å) | 1.2 |
| Electron affinity (kJ mol-1) | 77.574 |
Electronegativity (Pauling scale) |
2.180 |
|
Ionisation energies (kJ mol-1) |
1st
944.456
2nd
1793.584
3rd
2735.454
4th
4836.806
5th
6042.872
6th
12311.519
7th
-
8th
-
|
||
| Covalent bonds |
|
|
|
| Common oxidation states | 5, 3, -3 | ||||
| Isotopes | Isotope | Atomic mass | Natural abundance (%) | Half life | Mode of decay |
| 75As | 74.922 | 100 | - | - | |
|
Molar heat capacity (J mol-1 K-1) |
24.64 | Young's modulus (GPa) | Unknown | |||||||||||
| Shear modulus (GPa) | Unknown | Bulk modulus (GPa) | 22 | |||||||||||
| Vapour pressure | ||||||||||||||
| Temperature (K) |
|
|||||||||||||
| Pressure (Pa) |
|
|||||||||||||
Videos of the elements. Additional videos will be coming in 2012.
Learn Chemistry: Your single route to hundreds of free-to-access chemistry teaching resources.
Images: Visual Elements © Murray Robertson 2011
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
