| Group | 11 | Melting point | 961.78 oC, 1763.204 oF, 1234.93 K |
| Period | 5 | Boiling point | 2162 oC, 3923.6 oF, 2435.15 K |
| Block | d | Density (kg m-3) | 10500 |
| Atomic number | 47 | Relative atomic mass | 107.868 |
| State at room temperature | Solid | Key isotopes | 107Ag |
| Electron configuration | [Kr] 4d105s1 | CAS number | 7440-22-4 |
| ChemSpider ID | 22394 | ChemSpider is a free chemical structure database | |
Image explanation
Silver was important to ancient civilisations (often both spiritually and economically) and the symbol is widely used throughout the history of alchemy to denote the metal, hence the use of this within the image. The background is a detail from the "Gundestrup Cauldron", the largest known example of European Iron Age silver work, which is thought to represent imagery from the Celtic pantheon. Click through to the alchemical symbol for Silver and other elements.
Appearance
Silver tarnishes slowly as sulfur compounds in the atmosphere react with the surface to form black silver sulfide. Silver has been used for jewellery and tableware since ancient times, but it is also employed for silvering glass and in photography, as well as for industrial uses. World production is about 10,000 tonnes per year. Silver is present in the human body but has no known role.
Uses
Sterling silver contains 92.5% silver, the remainder being copper or some other metal, and is used for jewellery and silverware where appearance is important. About 30% of silver produced is used in the photographic, electrical and electronic industry, mostly as silver(I) nitrate. Silver is used in dental alloys, solder and brazing alloys, electrical contacts and batteries. Silver paints are used for making printed circuits. The metal is used to make mirrors, as it is the best reflector of visible light known, although it does tarnish with time.
Biological role
Silver has no known biological role, although it is a suspected carcinogen. Silver compounds can be absorbed in the circulatory system and reduced silver deposited in various organs. This results in greyish pigmentation of the skin and mucous membranes, known as argyria. Silver has germicidal effects - it can kill lower organisms quite effectively.
Natural abundance
Silver occurs native in ores such as argentite and horn silver, but the principal sources are lead, lead-zinc, copper, gold and copper-nickel ores. Poland and the USA are the main silver producers in the Western hemisphere. The metal is either recovered from the ore, or during the electrolytic refining of copper.
| Atomic radius, non-bonded (Å) | 2.110 | Covalent radius (Å) | 1.36 |
| Electron affinity (kJ mol-1) | 125.58 |
Electronegativity (Pauling scale) |
1.930 |
|
Ionisation energies (kJ mol-1) |
1st
730.992
2nd
2072.258
3rd
3360.582
4th
-
5th
-
6th
-
7th
-
8th
-
|
||
|
|
| Common oxidation states | 2, 1 | ||||
| Isotopes | Isotope | Atomic mass | Natural abundance (%) | Half life | Mode of decay |
| 107Ag | 106.905 | 51.839 | - | - | |
| 109Ag | 108.905 | 48.161 | - | - | |
|
Molar heat capacity (J mol-1 K-1) |
25.35 | Young's modulus (GPa) | 82.7 | |||||||||||
| Shear modulus (GPa) | 30.3 | Bulk modulus (GPa) | 103.6 | |||||||||||
| Vapour pressure | ||||||||||||||
| Temperature (K) |
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| Pressure (Pa) |
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Images: Visual Elements © Murray Robertson 2011
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
